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HomeMy WebLinkAboutGMC Data Report No. 116Geochemical data (lithology, source rock parameters, and hydrocarbons data) of cuttings from the Union Oil Company OCS Y-0849-1 (Hammerhead No. 1) well Received 27 February 1989 Total of 44 pages in report and 4 pages in Supplement A (Total of 48 pages in all) Geologic Materials Center Data-Report No. 116 February 21, 1989 Dr. J. Reeder Alaska Division of Geological and Geophysical Surveys P. O. Box 772116 Eagle River, AK 99577 Dear John: Please find attached the geochemical data for Hammerhead-1 cuttings samples. Most of the analytic data are industry standard and a glossary is attached to explain any BP specific terminology. In general, the samples were poor yielding small amounts of cutting material when the mudcake had been washed off. There is also some doubt as to whether drilling additive contamination has occurred but this cannot be conclusively demonstrated. GMC Data Report 116 Page 1/44 GLOSSARY OF TERMS · Source Rock Parameters P 1, P2 = Pyrolysis yields obtained from Rock Eval type pyrolysis, equivalent to IFP S1 and S2. HI = Hydrogen index derived from p2 xl0O TOC (~OGI units of mg hydrocarbon/g organic carbon. = Gas Off Generation Index. This is a measurement of source proneness from pyrolysis - C,C (pyrogram~ included) analysis. c,(~[ = (Ec~ -cs) (Ec6- cz~) Empirically: GOGI < 0.2 GOGI 0.2 - 0.5 GOGI > 0_5 = Oil Prone = Oil + Gas Prone = Gas Only prone. 2. Hydrocarbons Data TSE = Total Soluble Extract, obtained by soxhlet exlxaction in refluxing dichloromethane. FRACtiONS: SAC AROM RES = Saturate Alkane Content = Aromatic Hydrocarbon Content = Residue ~valent to NSO Conten0 All Obtained by HPLC Separation. As~h = Asphaltene ~Fraction by precipits_gon from n-hexane, prior to I-IPI~ separatioa. ~13C KEP. = Stable carbon isotol~ composition of kerogen. ~l~ TSE = Stable carbon isotope com~sition of Total Soluble Extract GMC Data Report 116 Page 2/44 BIO~ IDENTIFICATION - PENTACYCLIC HYDROCARBONS Page BP CODE TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 191) I Ts T. X Y D A B G H K N 0 S P R U V J L 9-DODECYLPERHYDROANTHRACENE [ INTERNAL STANDARD ] 18~(H)-22,29,30-TRI SNORNEOHOPANE 17 ~(H)-22,29,30-TRI SNORHOPANE 17 ~(H)-22,29,30-TRI SNORHOPANE 17 (z(H) -25,30-BI SNOBHOPANE 17 ~(H), 18~(H), 21~(H)-28,30-BI SNORHOPANE 17 ~( H ) - 25-NORH0 PANE 17 ~(H), 21 ~(H)- 30-NORHOPANE C3o PENTACYCLIC TRITERPANE 17 ~(H), 2 I~(H)-30-NORMORETANE 18a(H)-OLEANANE 17~(H), 21~(H)-HOPANE 17 ~(H), 21 ~( H ) - 30-NORHOPANE 17 ~(H), 21 :(H)-MORETANE (22S)-17 ~(H), 21 ~(H)-30-METHYLHOPANE ( 22R)-17 ~(it), 211~(H) - 30-METltYLHOPANE GAMMACER/hNE I?~(H), 21~(n)-nOPANE l?~(n), 2~=(H)-30-METHYLM0~TANE ( 22S)- 17 =(H), 21 ~(H) -30-ETHYLHOPANE ( 22R)-17 =(H), 2 l~(a)- 30-ETHYLHOPANE ~ ? O(H), 21 ~(n)-MET~YLHO?ANE (22S)-17 =(H), 21~(H)-30-n-PROPYLHOPAI~ ( 22R)-17 c~(It), 21 ~(H) - 30-n-PROPYI~OPAI~ 1 ? ~(n), 2 I~(n)-ETnYLHO?ANE ( 22S )-17 =(H), 21 ~(H) - 30-n-BUTYIJtOPANE (22R)-17=(H), 21~(H)-30-n-BUTYLHOPANE ( 22S)-17 ~:(H), 2 IlB(H)-30-n-PENTYLHOP~ (22R)-17~(H), 21 ~(H)-30-n-PEN~YLHOPANE BIOMARKER IDENTIFICATION - STERANES BP CODE TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 217) 10 11 13 14 15 16 18 19 20A 20B 2lA 2lB 22 27 29 33A 33B 34 36 39 40 41 (24S+R)-(20S)-13=(H) (24S+R)-(20R)-S=(H), (24S+R)-(20R)-13=(H) (24S+R)-(20S)-5~(H), (24S+R)-(20R)-5~(H), (24S+R)-(20S)-5~(a), (24S+R)-(20S)-5~(~), (24S+R)-(20R)-5~(H), ,17 ~(H)-24-ETHYLDIACHOLESTANE 146(B), 17 ~(H)-24-METHYLI SOC~OLESTANE ,17 6(H)-24-ET~YLDIACltOLESTANE 14 ~(~), 17 6(a)-24-~HYLISOC~OLESTANE 14~(H), 17 ~(B)-24-METHYLCHOLESTANE 14=(H), 17 =(H)-24-ETHYLCHOLESTANE 14~(H), 17 ~(H) -24-ETHYLI SOCHOLESTANE 14~(H) , 17 ~(H)-24-ETHYLI SOCHOLESTANE 1 A,~( R ~. 17 ~( R % -9_&-F. TRYLCHOLE STANE BIOMARKER IDENTIFICATION - AROHATIC STEROIDAL HYDROCARBONS (AROHATIC STERANES) BP CODE TENTATIVE ASSIGNHENT BASED ON HASS SPECTROMETRY (m/e 253 mass frag~entogram) F22 C21DIMETHYL MONOAROMATIC STERANE F23 Czz DIMETHYL MONOAROHATIC STERANE F1 C2~(20S)5~(H)DIMET~YL MONOAROMATIC STERANE F3 C2~(20R)5~(H)DIMETHYL MONOAROHATIC STERANE FA C~(20S)5~(H)DIMETHYL MONOAROHATIC STERANE F5 C2a(20S)5~(H)DIMETHYL MONOAROHATIC STERANE F6 Cz?(20R)5~(H)DIMETHYL MONOAROHATIC STERANE F7 Cza(20S)5~(H)DIMETHYL MONOAROHATIC STERANE F8 C2s(20R)5~(H)DIMETHYL MONOAROHATIC STERANE F9 C29(20S)5~(H)DIMETHYL HONOAROHATIC STERANE Fl0 C29(20S)5~(H)DIHETHYL HONOAROHATIC STERANE Fll C2a(20R)Sa(H)DINETHYL HONOARO~ATIC STERANE Fl2 C2~(20R)5~(H)DIHETHTL HONOAROHATIC STERANE F13 C2~(20R)Sa(H)DIHETHYL HONOAROHATIC STERANE ~ C20Hl2 POLYAROHATIC HYDROCARBONS Fl4 F15 Fl6 Fl7 Fl8 Fl9 F20 F21 (m/e 231 mass iragmentogram) C20HETHYL TRIAROMATIC STERANE C21HETHYL TP, IAROMATIC STERANE C26(20S)HETHYLTRIAROMATIC STERANE C26(20R)METHYL TRIAROMATIC STERANE C27(20S)HETHYLTRIAROMATIC STRRANg C28(20S)HETHYLTRIAROMATIC STERANE C27(20R)HETHYL TRIAROMATIC STERANg C28(20R)MgTHYL TR~ARO~ATIC STERANE BIOMARKER IDENTIFICATION - NORHOPANES BP CODE Y D C1 C2 C3 C5 C6 C7 C9 C10 TENTATIVE ASSIGNMENT BASED ON MASS SPECTROME~Y (m/e 177) 17a(H)-25,30-BISNORHOPANg 17~(H)-25-NOKHOPANE 17~(H),21~(H)-30-NORHOPANg (22S)-lTa(H)-25-NOR-30-METHYLHOPANg 17e(a),21~(H)aOPANS (22R)-17~(H)-25-NOR-30-METHYLHOPANE (22S)-lT=(H)-25-NOR-30-ETHYLHOPANE (22R)-lT=(H)-25-NOR-30-ETBYI, HOPANE (22S)-17~(H)-25-NOR-30-n-PROPYLHOPANE (22R)-lT~(H)-25-NOR-30-n-PROPYIItOPA~ (22S)-lTa(H)-25-NOR-30-n-BUTYLHOPAI~ ~ (22R)-lTa(H)-25-NOR-30-n-BUTYI, HOPANE (22S)-17a(H)-25-NOR-30-n-PENTYI~OPANE (22R)-17~(H)-25-NOR-30-n-PENTYLHOPANE Gl~C Data Report 116 Page 4/44 ~270 1444.75 , i , 474( i141 LITHOLOGY AND STRATIGRAPHY (m) 886.97 896.11 905.26 914.40 932.69 932.69 941.83 941.83 960.12 969.26 978.41 987.55 996.70 1005.84 1014.98 1024.13 1033.27 1042.42 1051.56 1060.70 1069.85 1088.14 1115.57 1179.58 1225.30 877.82-886.97 886.97-896.11 896.11-905.26 905.26-914.40 923.54-932.69 923.54-932.69 ,69-941.83 98-960.12 12-969.26 ;6! 26-978.41 I~ 41-987.55 1( 98-1024.13 1(,2, 13-1033.27 1051.56-1060.70 1060.70-1069.85 1078.99-1088.14 1106.42-1115.57 1170.43-1179.58 1216.15-1225.30 MtDSTCNE-~90%:~10% SILTS~~UFF 100% SIL~KA~ 100% 85%:Q~RTZ-PICKEDCUT SILTS~-CALC~ 5%:~B~ 95%:~~ SIL~~ 5%:~B~ 95%:~~ ~~ 100%:~~ ~~100%:~~ ~~100% ~B~70%:{~30% PI~~ ~B~70%:{~30% PI~~ ~~70%:{~30% PI~~ ~B~70%:(~30% PI~~ ~~50%:{~50% PI~~ ~~ 40%:{~0% PI~~ ~B~ 40%:{~0% PI~~ ~20%:Q~0% PI~~ ~20%:Q~0% PI~~ ~0~:~ 70%:~ ~0~:~ LITHOLOGY AND STRATIGRAPHY (m) 1234.44 1243.58 1252.73 1271.02 1298.45 1316.74 1344.17 1380.74 1417.32 1444.75 1472.18 1517.90 1527.05 1554.48 1572.77 1591.06 1609.34 1618.49 1 1225.30-1234.44 1234.44-1243.58 1243.58-1252.73 1261.87-1271.02 1289.30-1298.45 1307.59-1316.74 1335.02-1344.17 1371.60-1380.74 1408.18-1417.32 1435.61-1444.75 1463.04-1472.18 1508.76-1517.90 1517.90-1527.05 1545.34-1554.48 1563.62-1572.77 1581.91-1591.06 1600.20-1609.34 1609.34-1618.49 30%:~ . 30%. 100%:MU~WI~-~;~PI~~ ~100%:~i~.-GY ~30%:~ ~30%:~ 70%:QUARTZ-PICKED(/~ LITHOLOGY AND STRATIGRAPHY (m) j, , 1627.63 1618.49-1627.63 1636.78 1627.63-1636.78 1664.21 1673.35 1700.78 1728.22 1755.65 1792.22 1801.37 1810.51 1874.52 1892.81 1901.95 2039.11 2066.54 2139.70 1655.06-1664.21 1664.21-1673.35 1691.64-1700.78 1719.07-1728.22 1746.50-1755.65 1783.08-1792.'22 1792.22-1801.37 1801.37-1810.51 1865.38-1874.52 2029 {~8~96'11 2057~ .54 2130.55-2139.70 (m) 2148 2258.57 2414.02 2249.42-2258.57 2313.43-2414.02 LITHOLOGY AND STRATIGRAPHY ~100% (MDST-BLK) TR:~ 85% GY 80% :~Z~Z-PICKED COT 122 SOURCE ROCK QUALITY INDICATORS I · Il I ·lll, I , l ~~ PICKED ~ .P1 P1 P2 ( ) (m~'gC) 0.5 1.8 36.3 0.2 28.8 ~ 43.9 0.7 22.? 7 i°'1 i 1'61 4.4I .... Sample ~ype. C3TI~C~ unless marked: *~SIDE ~%LL CCRE,~ '0.44 0.32 0.65 (%) 134 7O (%) (%) I 95 20.2 16.8 8.1 31.3 13.5 1.7 13.0 23.7 1.6 14.7 15.3 3.5 11.2 13.8 3.4 3.4 20.9 2.3 62.5~2 17.2 I *¢~* 1344.17 ~s8o.7. 1417.32 1417.32 1444.75 '1472.18 :'~ 1472.18 ~':.' 1517.90 ~'.. 1527.05 1554.48 1572.77 1572.77 1591.06 1609.34 1636.78 17 . 1728.22 1792.22 1801.37 1810.51 1874.52 1874.52 1947.67 1956.82 1956.82 2039.11 1993.39 214 . 4 SOURCE ROCK QUALITY INDICATORS P1 P1 P2 GOGI HI (k~V~) (m~'gC) (kg/t) '!il .~ 4.7 8:1 ~:~  .! 6.8 1.2 82 8:1 8:~ 1.2' 1.6 10~.4 0.22 0.6 9.2 1.8 0.78 25.1 10.6 2.1 1.5 8.2 2.3 1.1 2.0 10.0 (%) 46.9 45.S 19.0 25.5 26.3 32.5 27.2 28.2 18.3 27.6 28.1 $ (%) 0.8 1.1 3.6 3.3 1.9 1.7 2.4 1.7 2.0 3.9 3.5 D '4- i. ,/ ,. ... ,::~ ,,. PYROLYS I S-GC i i ii i i 941.83 1014.98 1243.58 1527.05 2148.84 C1-C5 i I 18 · 11 11 11 11 14 DATA C:IO-CL3 (%) 23 14 13 I CI.4-C22 (%) 23 23 25 I C23-C36 (%) (%) GOGI . 44 ~0007 94i.85m (CUT) GOG! J tOi4.gSm (CUT) -. KEROGEN PYROLYSATE (P2) DISTRIBUTIONS WELL_NAME · HAMMERHEAD-~I GMC Data Report 116 Page 13/44 GOG~ .G5 ~0026 t243.58m (CUT) GOG! .24 t527.05m (CUT) KEROGEN PYROLYSATE (P2) DISTRIBUTIONS WELL_NAME ' HAMMERHEAD- GMC Data Report 116 Page 14/44 h/~LL._NAME.. GMC Data Report 116 DISTRIBUTIONS Page 15744 SOLUBLE EXTRACT DATA-1 __ il i i i ii (m) -- ii I il i i .. .:2.::.! il i (%) I ' '1 I 23.8 18.4 19.4 22.8 32.6 24.8 20.1 22.8 38.5 42.3 (%) 51.5 61.5 (%) I' I CARBON ISOTOPE RATIOS ISOIOPE I~0 (per mil) 1014.98 1014.98 ' 1243.58 1243.58 :NBS-22 AT ,-29.8 per ml o .r.. STANDARD 94~. 83m' (CUT) SAC FRACTION .CHROMATOGRAMS WELL. NAME ' HAMMERHEAD- GMC Data Report 116 Page 18/44 GCB ref. 88f. 2SEDO07 f · ! 1 I I dO ~4.98m i i iii i i ii (CUT) 800i4 :J. 243.58m (CUT) _ SAC FRACTION CHROMATOGRAMS WELL._~AME ' HAMMERHEAD- GMC Data Report 116 Page 19/44 ~_-;: ........ ,..~ ~, :.;-~?-fi?:.-:. ..... . GCB Pef, 88t2SED007 ~6~7.63m (CUTJ 1673.35m (cu~ SAC FRACTZON CHRONATOGRANs NELL._NANE . HAHHERHEAD_~ Data Report 116 Page 20/44 GC~~B pe f. BB~.~SEDO07 STANDARD 80007 · g4~.83m (CUT) SAC FRACTION CHROMATOGRAMS WELL._NAME ' HAMMERHEAD- GMC Data Report 116 Page 21/44 GCB ref. 88J2SEDO07 800],4 ~0~4.98m (CUT) ~243.58m (CUT) SAC FRACTTON CHROMATOGRANS klELL._HAME ' HAMHERHEAD-~ GMC. Data Report 116 .~.- ~. Pa~je.22/44 !~ __, o~,~,^^~ i ~627.63m (CUT) .// '673.35m (CUTJ SAC FRACTION CHRONATOGRAMS ~ELL~NAHE . HAHHERHEAD_~ GNC Data Report 116 Page 23/44 43.1 217 i i i ii i ii i i i i i i i BP G£OCHE~IIS'TRY BRANCH ~ AHALY~I$ i ii ii ii ! il i i SAMPLE: SATS EX I-IAHM£RHEAO-I 1673.4:~;8012S£0007~00479 OATA FII.~ A~?8 i ! Ill I illl I i i MY2 191. I 'i I ' ' I I ..... '"'i ' ' I I , .......... 24:36 , 32:48 , 41:00 49:12 57:25 65:37 73:49 TIME , , ,,1, .... , 111 "1, , ' ' i i iiii , i ,i i ii ii i ii i i i iiiiiii iii iii i iiii i i ii i ii 217 ,, I. ,thJ I ?,,,, , " I'' i'' 'i ' "' 'J '""i '"l '"i J ! ! J' ,, IO N 191. 217. .... ' ..... "' I , .... , .... ,' i"' I ' ' ,.' 'I J ' ' ' I 49:12 57:25 65:37 73:49 TI.Ih'_ '"'5 ,.,' __ _ iiiiii iiii ii ii · BP GEOCHENI~'TRYBRANCH GCYM$ ANALYSIS; i i · m i i i iiiiii i i i $'AMPL~; SILTS E~ HAMMERHEAO-1 1243.6; S8812SEDOO7SO025S DATA FILE~ ·. . m, , · .i ! ,, lmm i .. iiil! I I I I ~m miI I I ! mi I mm I i i m I I I II iii i ii i m 0 - I I I ' , 9 ' I fO 2.,5 2=~ 33 M/Z 217. 24: 36; 32:48 49:12 57:25 65:37 73: 4~ TIME .............. Bp 'GE~CHEH~STRy DRAHCH -OC?~' 'AHALYSiS .............. i ii i i i i ii i i i ....... SA'~IP~'E: SAT$ I~ HAHH~I.~AD-1 !814' !~8' $88~'25h"D887~Oe14S 191 m DATA FILE: AC079 · - - - ' ii ii i il i mul III i iii iiimlll iii i iii i ii i ii · i i iii i i mill I I mill lllll I i i 8,7- 217 I'I/Z 191. I'I/Z 217. 21 ~ 3~ ' IO :z~ .~ 24:36 32:48 41:88 49:12 ~:25 65:37 73:49 TI~E ,b u..,~ ~ ~ ~ ~ ~ ~, ~ - , . ,,,, ,, , , .,,. , ii ii i ii II II i i ii iiii ! i i i BP GEOCHEI'IISTRY BRANCH G~I'IS AHALY$I$ ..... s'AMPLE: $AT$ EX HAMIqERHEAO"I 941.1) $88t~EO007500075 DATA FILE: fl0)74 ii m i I i ii I II m II iI i .... Ii -,"1,' ' ' ' " ii, ,,", 191 Tm i i i i i i i i mm i ii 1:91. 32:48 '. 41:08 M/Z 217. 65:37 73:4:9 TIME HIDHASS CHROHATOb~AH.~ DATA: AC074 01 SCANS 2888 TO S588 01Y31/(U:J 9:52:08 CALI: ACO?4 02 SAHPLE: SATS E~ HA~AD-1 941.8 %~I~87S8887% CONDS.: RANGE: 6; 1,45;80 LABEL: N 8,10.8 QUAN: A 2, 2..8 J 0 BASLE: U 15, 3 13.4- 217 38.1- ~-: ~ , ,~ ~ m ...................... I ii I i I iii ,1111 IIII i i i,1 ,11' i ' I " I ' ' 191.~b'7 ± 8.588 i ' I ,111 I III ~ 22784. 217.865 + 8.588 218 · ~ ,,mm 2888 32:48 I ' I I i 2288 2488 , 2688 2888 36:85 39:22 42:39 45:56 :3888 3288 ~)488 49:12 52: 2~) 55:46 218.86~ :1: 8.508 TIME 1~1 o 8.7" 217 MIDMASS CHROMATOGRAMS DATA: AC875 #1 SCANS 2888 TO 3588 81y31~ 11:17'.88 CALl: AC~75 #2 SAI'IPLE: SATS EX HA~I 1814. g8 CONk. = RANGE: G 1,45t~t LABEL: N 0,18.0 QUAN: A 2, 2.8 J 8. BASE: U 15, 3 " I ' '"1 .... ' ' I' 13.7- 218 ;.~ .~... ~ln~l~..~ "~ i~l,-- -- , , ,~1~"' Ill Il Il I I I Il I IIll I Illll I I II Il I I I Il I I Illll Il Il I I Il I ' ' " ' I I I I' 2888 2288 32:48 3~: 85 ~- i , , , ................ - ~~ , I ' I ' I I I 2488 2688 2889 3888 3288 39:22 42:39 45:56 49:12 52:29 3400 55:46 521216. 455F~. , 217.06;5 :t 8.500 71296. 218.865 , 0.5t~ SCAN TIME 100.0- 191 aa,, °1 · 217 ~ MIDMASS Cl-IROMATO~RAIS; DATA: AC978 itl 01/31Y89 12:42:80 CALI: AC978 #2 SAMPLE: ~;ATS EX HAMMERHEAD-I 1243.6' ~;88128E080750028~ COHOS.: RANGE: G 1,4588 LABEL: H 8,10.8 QUAH: A 2, 2.0 J 0 BASE: U 15, 3 SCANS 2080 TO 3500 ' ' ' ' ' i ' I 15.4- 218 b"T E ,R Ftl::) IEN E.,~ ? I ' ' I ' I' ' I ' I I 1 i 2808 2~9 2480 2808 2888 3088 3288 3488 32:48 36:05 39:22 ' 42:39 45:58 49:12 52:29 ~: 46 2.97472. = 191.~57 8.588 ,-' 11744. 217.085 + 8.58~ 218.865 ± 8.58~ SCAN TII'IE -,j 16.1- mm, 217 ,m 79.8- 2888 TO 3588 BASE: U 15, 3 I I ' I .Il ~11 Il Il] I Ill I I Il IIl~lll I Illl, Il il I I Il [ 218 32:48 2288 36:85 I ' I ' ' I I ' I 2498 2698 2888 39:22 42:39 45:56 ' i ' ]'~- 3089 3288 3498 49:12 52:29 55:46 78144. 191.857 + 8.599 217.865 :1:8.588 218.865 + 9.589 SCAN TIME 188'8I~,_~ 177_ m 191 19.5- m MIOMA~$ CHROMATOGRAM~ DATA: AC978 81/31y~ 15:17:06 CALl: AC678 SAMPLE: SATS EX HAM~ER~AD-1 lb'73.4 $88125ED88750847~ CON05.: RANO£: G 1~4588 LABEL: N 8,18.0 QUAN: A 2, 2.8 J SCANS 2200 TO 4588 0 BA~E: U 15, 3 i i[111m i I i I iiiiiiiI iii i m iiii ii i i ,lllllll ,i I ii i~11 i m i ii iii i m i i i i i HI n ii I II I i i ~ " ' I' ~" " ' m I "' ' ' ] i ill i ~ .... I ........ m i ~11 i ~ .... m .... & i ..... i. . m m m i m I m m I .... i ......... m ..... i , 2586 3888 41:98 49:12 3588 4888 4588 82848. 8.596 5~326. 191.857 8.586 15984. ~S.~l 8.596 57:25 65:37 SCAN 73:49 TIME 188. O- 191 o · .,j .. 43.1- 217 88.8- 218 MIOI'IAS~ CHROMATOGRAMS DATA: AC078 ttl OIY31Y89 15~17:88 CALl: AC075 #2 SAMPLE." SATS EX HA~O-I 1673.4 $8812SE000750847~ RANGE: G 1,4588 LABEL: N 0,10.0 QUAIl: A 2, 2.0 d · SCANS 2888 TO 3588 0 BASE: U 15, 3 i ii iii i i i ii I ' I ! 56328. 191 .Bb'? :1: 0.500 24256. J __ ~ $'TEI~RDIEN E ~ 77 _ __ - --.-~ %.. ..... . ...... .., ....... 2000 22e0" 2400 2600 2see 3eee 3~e 34ee 32:48 36: es 39:22 42:39 45:56 49:12 52:29 55:46 17344. :1:8.588 ~ SCAH TIME , ,1,,, 1,111, Bpi,GEOC~I~mlr~l iiii B~I i i iii iiiiiiii i ~1 , i ANALYSIS' i i i iii i , 11 ...... s~'~£: '~o.~ ~ .~~~u-~ ~. ~ ~~s£o~?~75 ...... DATA FILE: AL'Bm ........ , iiii i i i i ii i i i I I I 32:50 I I ' I I I i I'I/Z 231. I I I 41:02 I , , ' ' -1 49:15 57:27 I i i I 253. 65:40 TI{'E 1~:25 ~ 19.'42 22~59 25:16 ..................... Ill I I I I I II I I I I I II IIIII III II I I II II II I I I I I I I I 29:33 192. 32:56 TI~£ BP GEOC1-E~ISTR¥ BRANCH GC/M~ ANALY$ SAMPLE: AROI'LS EX HAMMERHEAO-.1 1814.98 ~;8812SE0087S80145 DATA FILE: AC086 32:50 I i I I I I 41~62 i I ' ! i l 57:27 F:~5:40 TildE ' i ' i ..... 16:25 ' I ' ' I 19~42 ' 22:5:9 i i i i i ii H/Z 178. ' I ' I ' I 29:33 M/Z l~. 2;;: 16 1[11 i i i Ill Illll I I I ~:$0 TI~ ,1111 1111,1,1,! iiii i i iiiiiiiii i i ii ! ii i i i ii , , .~cd~PLE'~' AROI'L~; EX .AMMERHEAD-I 1243.6 ~08'i2~ED807~OO2G$ D~qTA FIkE: AC081 ii ii iiiiii i i i i ~ i i ii i i iiii i i ii i ii i ii illll i i i ii ii I i I I i I I ! i i I I I 3:2:50 41: 8:2 49:15 [ I I 57:27 M/Z 231. M/Z 253. -___D I TIME BP GEOCXEHIS'TRY BRAXCH OCx~I$ ANALYSIS $¢IPIPLE: AROI~ EX FlCl~flO-1 I $ 1 D~TI% I~ILIZ: IQC881 I I I III I ! I I I llm -- i I II II I II i II I I II I I I i i i i I I ii .. l"l/Z~ I~. ......' .... * ..................... I ....... ~ I- '' I' I 1G:2§ 19:42 22:59 2~: 1~ 2~:33 32:58 TI~ ................... ......... ....... ~, , , , , , mm m m illin II mm mil i iL i m mm mi mil Immm m I m mmml m mmm . m m mm mi m mil m mil m I mil m i Il Illl I I I Il I I III I I I I IIII II II I II I I I I II BP GEOCHEMISTRY BR~N~ Gf~l~ ANALYSIS j i i I II II I IIII II I I I i ii i I III II II $~: AROM.s EX' HAMMERHEAD-1 1E;27. E; S'0812S'E0007599445 OflTfl FILE: flC982 i i ii ii I II I I Ill i ii ii i i ii i iii ii i i i iii ii i ii ' FI~. I i I ! J ...... :1 I I 32:50 41:02 I I ' I ...... I .......... ~'1' J 49:15 M/'Z 231. M/Z 253. I 57:27 ~5:48 TIME i i i$1 ii j I~11 , ii i i i iiii ii ! i i iiiii i ! i i i i i i i iI i 89.2 16:2§ I i 19:42 22:59 26:15 2:9:33 N/Z 178. I'l/Z 192, 32:58 TI~ I ~,?.,.n~,. ~? ........................ I ~,,~'."~' .... '" ' ' ' ......................... I' I !~ I 2:31 . 1~2 281. ~ ~. ~ I .... ~ ..... , .... , I I I , I ....... , I , i .......... iI I ~ ' .... , ........'II .... , I I , , ............ ~ I ~ :--;~ I.__ BP EO IST BRAN HS ANALYSIS I Il I I I I I I I I I I I I I I II I I ~AHPI.E:AROMS EX H~I Ib'?'3.4 ~88125E0807588475 , OATA FILE: AC883 i iiii I i i ii ii i ii iiii i Ill .. III I I ~88~0 178 178. ........ ~ I I ~ I ......... ~ i " 192. 16::25 19:4:2 2:2:59 2~: 1G 2.9:33 32:50 TIME ....................... , , , , _ i i , . , 'lllll, Illl 111 I , I IIIII IIIII II L II I Ill II I III I I ii IIII I III I Geochemical data of cuttings and sidewall cores from the Union Oil Company OCS Y-0849-1 (Hammerhead No. 1) well Supplement A to the Geologic Materials Center Data Report No. 116 This material is from the U. S. Minerals Management Service Total of 4 pages in report (A-1 through A-4) Craig K. White District Exploration Goologlst - No,lb Alaska District December 3, 1985 Uno~l Co;'~ration RD. Box 190247 A~orage. Alaska 99519~247 Telephone (907) 276-76~ 1 8 1985 Mr. Brian F. School United States Department of Interior Minerals Management Service Alaska OCS Region R.O. Box 101159 Anchorgge, AK 99510 Dear Mr. School: Attached are the final results of geochemical work on samples from Union, OCS Y-0849#1. Table I includes data from cuttings samples. Table 2 includes sidewall core data. The contents of these two tables are described as follows- Depth TOC S1 S2 S3 Tmax VR Measured depth, in fee~ Total organic carbon, in percent S1Rockeval yields in mg/g S2 Rockeval yields in mg/g q3 Rockeval yields in mg/g Femperature at S2 maximum, in degrees C Vitrinite reflectance, measured on whole rock (%) These comprise all the geochemical logging data Union has concerning Zhe rock samples from this well. We would be willing to answer questions concerning these data at anytime. CKW: rms {2013e) Attachment Sinc[rely, ~__~ ~White GMC Data Report 116 Page A-1/4 FILE GMC Data Report 116 ,_ ,_,:-~, P.a§e..A-2/4 (. T~gLE 1 OCS-Y-~4Q-1 'WELL,, CUTTINGS OEPTH TOC S1 S2 S3 THA X VR f. 360 1.67 . . 420 1.41 . . 480 0.68 . . 540 2.35 0.17 1.51 720 0.57 . ' . 870 0.82 . . 930 0.11 . . 990 0.39 . . 2010 0.34 . . 2070 0.54 . . 2130 0.50 . . 2190 0.60 . 2250 0.57 . . 2310 0.71 . . 2370 0.57 . . 2460 0.45 . . 2520 0.78 . . 2580 0.70 . . 26 40 O. 85 . . 2700 0.53 . . 2760 0.69 . . 3060 I 5.82 I .00 19.15 3180 0.61 . . 3240 29.53 2.37 25.41 3300 1 0.09 0.7'1 8.4.9 3360 6.93 0.34 6.10 3&20 5.49 0.23 4.71 34. 80 1.44 . 3600 0.97 . . 3720 0.86 . . 3840 1.76 . . 3900 1.47 . . 3060 0.60 ,.o o 41 40 5.30 0.27 3.78 42C0 1Z.Q4 0.76 12.62 4201 3.41 0.11 1.75 4202 4.37 0.20 2.24 4320 3.95 0.19 2.6~. 4~50 1.45 . . 45G0 0.67 . . 4560 1.3o . . 4620 2.0,a 0.24 1. 4680 0.86 . . 4~.90 1 SO?O I .55 . . 5130 7.37 0.1'9 5.1~ 5190 3.17 0.11 1.97 5250 4.98 0.2~; 2..~7 5.~10 2.4.~ 0.12 1.61 5370 4.20 C. 35 2.71 5430 B.85 1.1~ 9.45 5490 R.Q5 1.27 4.63 437 . . . 0.35 . . . ' ' -- . -- . . . . 0.45 . . . . . . . . 0.!7 m m m m . -- m . . 9.37 . . . . . 0.40 11.04 426 . . . I 9. :'37 376 O. E.59 415 . 5.15 423 . 4.7.~ A2~ . . 0.36 . . 0.~2 . . 0.34 . . . . . 0.35 -- 11 02 412 . 1 3.96. 43 7 -'3. 4.49 ~.11 . 8.0C 391 . .T. 3C ~15 . 5.22 412 0.36 5.2C ~.24 . - . 0.33 . · . . · . . . 0.37 ' ~ ° 4.11 12 . 2.~4 426 . 5.3q 4Z1 2.93 423 . 5.5C . 5.45 ~,22 . 59~0 600,3 6060 67.10 6390 5730 7~30 7470 76~0 7~00 6..9~ 5'?0 ~25 5.07 0.59 ~-~0 5.26 0.56 1.9~ 0.~.~ 2.16 4~ 0.91 -' ' ~ 429 ' O. 78 ' . 1.07 - . . - ,.- . I.~0 . . 0.97 . ' · 7 - - . - 1.5~ . . . . 0.~ J u PUBLIC FILE MAY ~. 6 1988 Page A-3/4 - . . .~- T &~LE 2 0CS-Y-949-1 WELL, SIOEW&LL D~PTH TOC 51 S2 CORES S3 TM&X VR 3231 1.5 3 3.10 '0.76 4.94 ~26 0.23 3334 0.95 0.05 0.45 8.9? 430 0.35 351:~ 1.26 C.13 0.81 1.14 425" O. ZZ 3666 1.79 0.11 1.27 8.1~ 427 0.25 3732 1.70 0.15 1.25 8.28 420 0.-28 3780 1.6~, 0.11 1.11 6.42 428 0.34 ~890 2.31 0.11 1.1-~ 7.62 423 0.29 30.02 1.65 0.09 0.87 5.70 424 0.25 3978 1.36 0.05 0.69 4.46 426 0.25 4120 1.51 0.10 0.97 6.09 425 0.24 4~43 1.1 ~, 2.02 O. 37 5.55 425 0.39 4426 1.77 0.10 1.43 11.88 426 0.29 4445 2.7q :3.13 2.07 8.34 427 0.29 4495 I .52 0.05 0.63 5.97 424 0.31 4576 1.85 0.08 0.89 5.3~ 425 0.30 4620 2.24 0.10 1.50 10.95 425 0.31 4688 1.46 0.03 0.40 11.63 426 0.33 4764 1.58 0.07 0.80 6.72 425 0.30 4S4,", 1.24 0.06 0.60 1.58 428 0.32 0910 1.05 0.07 0.~9 7.05 427 0.36 4q70 1.1 0 0.06 0.43 4.29 428 0.25 5004 1.55 C.O~ 1.1~ 5.47 427 0.26 5063 1.34 0.07 0.96 5.61 427 0.30 510~ ~..03 0.08 1.33 3. $3 426 0.24 5290 0.91 0.0~ O.&~ 2.97 432 0.37 5335 O. 8~ 0.09 0.56 4.68 426 0.38 54C1 1.64 0.13 1.14 11.41 428 0.39 5662 1.25 0.04 0.71 6.67 425 0.38 5765 0.94 O.C'~ 0.35 1.21 426 0.33 60?2 1.2~ (].O& 0.57 5.11 ~32 0.~ 6074 1.6~ ~.14 ~.96 ~.27 425 ~.&l 0212 10.06 0-~z* 4-~-~ 10.59 419 0.35 6380 1.2a. 0.04 0.68 4.08 /,29 0.38 6500 0.74 0.0~ 0.15 1.03 421 0.40 6600 2.6~ 0.07 1.53 5.11 427 :3.37 ~700 2.0~ .~.04 0.49 1.42 422 0.37 oQC3 O. 9 6 0.07 0.57 3.39 428 0.36 7000 1.34 '~.25 1.~,0 2. S6 /.,27 O.$& 720~ 1.0a 0.13 1.23 5.44 427 0.~,2 7300 1.0.~ C,.07 0.92 5.95 426 0.40 7450 1.0~ 0.03 0.60 6.$5 430 0.43 765:} 0.96 0.03 0,77 2. ?2 430 0.40 7750 1.04 3.07 O.a-3 4.<~1 ~,26 0.~,4 MAY' I 6 lg~8 GMC Data Re port 116 Received OCS District Office DEC 1 7 Minerats Management Service Anchorage, Alaska Page A-4/4