Department of Commerce, Community, and Economic Development
Alaska Oil and Gas Conservation
Commission
HOME
EVENTS
DATA
Data List
Drilling
Production
Orders
Data Miner
Document Search
REPORTS
Reports and Charts
Pool Statistics
FORMS
LINKS
Links
Test Notification
Data Requests
Regulations
Industry Guidance Bulletins
How to Apply
ABOUT US
History
Staff
HELP
Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
GMC Data Report No. 159
Geochemical characterization by. thermal desorption,.liqu.id chromatography, gas chromatography, isotope-mass-spec and gas chromatography mass-spectrometry of extracts from the following North Slope wells- Mobil Oil Corp. Beli Unit No. I (5590'-5680' of cuttings, 8400'-8670' of cuttings, 9010'-9180' of cuttings, 10,810'-10840' of cuttings, and 10900'-10940' of cuttings) Humble Oil E. Mikkelsen Bay State No. I (11500'-11600' of cuttings) . BP Alaska Inc. Kuparuk Unit No. I (5900'-5950' of unwashed cuttings) . Mobil Oil Co. Mikkelsen Bay-State'13-09-19 (10564'-10650' of core, and 11650'-11701' of core) Arco Alaska Ravik State No. I (2560'-2650' of cuttings) Exxon Corp. Pt. Thomson Unit No. 2 (5790'-6240' of cuttings, and 10158'- 10210' of core) Mobil O'il Co.'WeSt'staines"state 18-09'23 (10594' of core, 11672'-11710' of core, 12545'-12560' of core, and 12653'-12660' of core). There are also 'some additional geochemical data on'the following North Slope wells- Mobil Oil Co. Kadler State 1-5-"09-16 '~ Atlantic Richfield Susie Unit No. I (4610'-4660' of core and cuttings) AtlantiC Richfield Itkillik Ri"ver'Unit~No I (7200'-7340' of cuttingS) Received at'the GMC 15 June 1990 Total -of 226 pages-in report Alaska'. Geologic Materials ce~ter-.Data..RepOrt_No'. 159 GEOCHEMICAL CH^R^CTERIS^TION OF EXTRACTS FROM R^VIK-1, BELl UNIT-i, PT THOMSON-2, MIKKELSEN BAY-i, E. MIKKELSEN BAY-I, WEST STAINES-1, SUSIE UNI.T ! KUPARUKUNIT-I AND ITKILLIK'R! V~R- 1 BY THERMAL DESORPTiON, LIQUID CHROMATOGRAPHY,GAS CHROMATOGRAPHY, ISOTOPE-MASS-SPEC AND GAS CHROMATOGRAPHY MASS-SPECTROMETRY GMC Data Report No. 159 Page 1/226 WELL BELl UNIT #1 .. BELl UNIT #1 ITTKiLLIK RIVER #1 RAVIK STATE #1 RAVIK STATE #1 KUPARUK UNIT.#1 MIKKELSEN BAY M1KKELSEN BAY PT. THOMPSON #2 P.T. THOMPSON #2 PT. THOMPSON#2 WEST STAINES #1 WEST STAINES #1 WEST STAINES #1 WEST STAINES #1 WEST STAINES #1 E MIKKELSONBAY E'MIKKELSON BAY E MIKKELSON BAY E MIKKELSON BAY E MIKKELSON BAY SUSIE UNIT #1 BELl UNIT #1 BELl UNIT #1 BELl UNIT #1 KUPARUK UNIT #1 DEPTH IDENT 8670 4234 9:180 4235 7~40 4236 ~650 4237 ~240 4238 2761 4239 10650 4240 11701 4241 6'24O 4242 10210 4243 11823 4244 6060 4245 10594 4246 1.1710 4247 12560 4248 12660 4249 7950 4250 8600 4251 9780 4252 10280 4253 11600 4254 4660 4255 5680 4272 1'0840 4273 10940 4274 5950 4275 S1 0.99 3.61 0.24 2.52 0.26 0.11 1.57 1.16 2.5O 5.64 0.62 0.06 11.55 8.25 1.55 3.77 0.26 0.19 0.34 0.36 0.49 0.13 1.53 9.73 5.32 2.77 S2 S3 4.54 1.27 19.40 1.05 0.62 0.46 5.95 3.42 0.54 1.36 0.13 0.21 2.59 0.74 1.72 0.21 5.36 0.79 5.17 1.56 1.36 1.01 0.31 0.27 9.12 0.49 12.05 0.81 7.37 0.44 3.79 0.47 0.69 1.75 0.31 2.32 0.47 2.47 0.86 i .61 0.92 1.80 0.04 0.19 8.41 0.92 108.34 1.05 27.05 1.54 0.44 1.40 TOC 1.42 2.93 O.72 3.68 0.81 0.23 1.24 O83 1 3O 2O7 1 05 030 200 3 47 2.35 0.81 0.89 0.64 0.06 0.99 0.87 0.24 1.50 13.42 5.31 0.26 HI OI Tmax ROK CHROM 319 89 419 A 662 35 428 A 86 63 441 161 92 430 A 66 167 423 56 91 381 208 59 434 A 2O7 25 438 A 412 60 430 A 249 75 423 A 129 96 439 103 90 431 456 24 426 A 347 23 431 A 313 18 428 A 467 58 438 IS 77 196 436 48 362 432 .... 435 86 162 428 105 206 423 IS * * 79 * * 560 61 423 A 807 7 439 A 509 29 431 A 169 538 431 IS ** Values of S2, S3, or TOC below 0.1 did not permit accurate calculation of this parameter. * IS=- INSUFFICIENT SAMPLE FOR ANALYSIS A- SEE ATTACHED DATA SHEET (~13C DEPTH LAB EXTRACT TSE SARA SAT GC SAT WELL ( f t) IDENTIFIER YIELD ("/~,) BIOMARK BELl UNIT#1 8670!WF 4234 6.57 --27.98 A A A BELl UNIT #1 9180 4235 26.20 -28.1 6 A A A .I RAVIK STATE #1 2650 4237 7.01 -28.75 A A A MIKKELSEN BAY 10650; 4240 3.62 -29.15i A A A MIKKELSEN BAY 11701 4241 2.20 -28.751 A A A PT. THOMPSON #2 6240 4242 7.55 -29.57 A IS A PT. THOMPSON #2 10210 4243 9.70i -29.29 A A A WEST STAINEs #1 '10594 4246 -26.21 -29.57 A A A ~WEST STAINES #1 11710 4247 12.50 -28.90 A A A WEST STAINES #1 12560 4248 2.90 -30.50 A A A WEST STAINES #1 12660 42491 - 8.10 -28.97 A IS A E MIKKELSON BAY 11600 4254 1.83 -28.95 A A A BELl UNIT #1 5680 4272 15.50 -28.13 A A A BELl UNIT #1 10840 4273 120.63 -27.61 A A A BELl UNIT #1 10940 4274 43.11 -28.02 A A A KUPARUK UNIT #1 5950 4275 2.60 -29.47 A A A * IS= INSUFFICIENT SAMPLE-FOR-ANALYSIS- A = SEE Aq-FACHED DATA SHEET EXTRACT YIELD=KG/TON SARA=HPLC SAT GC= SATURATE CHROMATOGRAM SAT BIOMARK=SAT GC/MS GMC Data Report No. 159 Page 3/226 .:.,-,., 1P-E NAME ! NSTRUMEI-,IT ~,.i f- ~ I,,.]ECI TI,1- ,n .......· USED SEC.!UEt,I::E C,' RE_.U,_T F !LE REPORT TIME SARA Ai'4ALYS.! S : BELT UNIT ~'i ~'~'¢0- : HPLC F !D : Tue .]un i'2 i':.--'? o ':': 26: o5 .~,-,; : /METHOD/HPLC_F![30. MTH : .,"DATA×LOOP/SEOUEI-?E,'HP 1 .q_; "-'-' 0_¢4U", .T,-,,- ....... C-. '-%E~I_ _ : /RESULT/t, JF4222A_SAP. RES . . lggA : ?:51 A'M TUE ; !3 3UNE¢ _. . Saturates Aromatics ! Aromat ics 2 Po tars RESPOI'.iSE AREA T I ME FACTOR 569z 5 29 127sF-0= 3181 . ?. 42 . 5470E-04 · 'K -', 0 . . 26_--,,_,. 14.36 ':::;4?OE- 04 38841. 19.92 .4!60E-04 Sa.turates "Ar0ma t ics Po 1ars AMOUNT (rog) °'.~ RES I DUE .75 18.3 " 1.62' " 40.8' 1.62 40.8 Saturates Aromatics Po la,'s Aspha ! tenes OIL 14.2 51.6 31.7 22.5 GMC Data Report No. 159 Page 4/226 0 ,'-'~ i.4i RESULT: .7~_ .......... , I ......, .! ...... ' I ~ .... I t . I. ~ . .I , . I ...... , m~.nu-a'OO'tes ~s.37 7.~ to.ia ia.~ i4..7 i7.~ SAMPL~ BELI UNIT ~t ~->-~'- ~-~s~ ~ ,ANALYZe: Tue dun ~2. ~990, 9: 26:05 am /RESULT/~F4272A SAP.RES METHOD: HPLC FIDO 22.00 PETRrjLEUM GEOCHEMISTRY SATURATE GC SAMPLE NAHE INSTRUMENT INJECT TIHE METHO0 USED RESULT FILE REPORT TIME 8ELI UHIT-1 55'?0-5680 HP 5890 2 Wed Hay 9~ i990 3:17:49 /HETHOD/SATSBg0E.HTH /RESULT/~F42~2 SAT.RES i 4:08 PM ~ED. ~ 9 MAY ~ CPI UALUE : PRISTANE / PHYTANE : PRISTANE ,' Ci? : PHYTANE / C18 : .86 C15/C25 .47 CiT/Pr .47 C18/Ph AREA %AREA NALI< N-C10 N-Cll N-C12 N-C13 N-C14 N-C15 N-C16 N-C17 N-C18 N-Ci? N-C2t] N-C21 N-C22 N-C23 N-C24 N-C25 · . N-C26 N-C22 N-C28 N-C29 N-C30 N-C~I N-C32 N-C33 N-C34 N-C35 N- C36 O. 0.0 O. 0.0 O. O.O O. 0.0 O. 0.0 O. 0.0 182. 1.4 263. 2.0 292. 2.2 312. 2.3 222. 2.1 362. 2.8 465. 3.5 300. 2.3 369. 2.8 454. ~.4 i84. i.'4" 234. 1.8 240. 1.8 390. 2.9 279' 2.1 280. 2.1 899. 6.8 1~01 12 4985. 57.4 283. 2.1 551. 4.1 AREA ~ARE~''' 'I Sp'~ pm 1990 T I ME 0.00 0.00 0.00 0.00 0.00 0.00 17.29 19.45 21.02 22.52 23.95 25.32 26.63 27.89- 29.09 50.29 31;37 ' 32.45 33.49 34.49 35.47 36.41 32.32 38.26 39.31 40.48 41.85 -T I Farnesane 0. 0.0 0.00 Acyclic C16 0. .0.O _._0.00 Acyclic C18 ' O. O.O O.O0 Pr istane 123. 46.4 19.61 Phytane 143. ~.x 6 '-'1 99 0.00 2.14 '~ 04 NORM C!5 GMC Data Report No. 159 Page 6/226 0 N r'~ o ZDZ 2.48 2.39 2.90 2.22 2.13 2,04 .... ~, ., i . ,, I 5,00 :tO.O0 minutes I , , ,, I ...... , ,,,I , I ,,,, I , ,, i ,, , 15,00 20.00 25.00 30.00 35.00 40,00 45,00 SAMPLE: BELT UNTT-1 5590-5680 ANALYZED' Ned May 9, t990 3' :t7' 49 pm RESULT: /ARCHTVE/WF4272 SAT. RES METHOD' SAT5890E PETROLEUM GEOCHEMISTRY × GNH ROCK EUAL *** SAMPLE' : WELL: BELI UNIT ~D1 DEPTH: 5680 INOECTED AT : Fri May ii, i990 4:02:25 am INSTRUMENT : GROCK METHOD USED : /METHOO/PYROS.MTH RESULT FILE : /RESULT/~F42728_GRO.RES 8LANI< FILE : /RESULT/8LA~<I~_GRO.RES AREA SLICE INTEGRATION AREA YIELD (mg/g) FRACTION 28106848. 262600260. !. ~..7 $1 - o 26 S2 · ,_.,Inl ii I-.~... o o . Tm.az : 415 C GMC Data Report No. 159 .; Page 8/226 N '7 4;.22 5.37 ,4.52 f? J--...~ ....... 1 ........... ~ ........L ....... ~ .......... L ....... ~- ....-..I 1~.05. 23.i$ 31.28 39,40 47.52 55,(;4 (;3,76 71.88 80.00 ~llntites SAMPLE: WELL: BELl UNIT #l DEPTH: 5680 "ANALYZED: Wed Mar 21, 1990 8: 50: 2! am RESULT: /RESULT/WF4272 GTX.RES METHOD: GTXGC! 0 +*? ~ F'ETF:OLEU.~! GEOCHEM I c_.- -,r p ...., .._;,.., :; G1'-4!-4 PGC AUTO :+-'-+:~, :Mi ,Fur_ : . ._!_ ~._ !':_;:.L; :J',': i T ';..:i ~..r~EpTH.:. ..680 · ~'I'43EE'TE£: .'~,"'" ' F.'''' '~. i!.~.':' i'l. _.. 1°c'':'',. , ...., 4: f','-:': 2-4,. ,.. an": ,, ,-.,'-"T¢, ,".',¢', 'T : GPGU_L-' ., _ ..on.c-, ,, "r ,ijc' -42 72 "" GPG RES ~ESIiLT F',.._E : "" .... /RESULT ;~" ""~-"-"15 E,.._~l.d. F ] LE : ... o,__~.,-,,-. _GPG. RES AREA AREA,c'~"~"-'¢'""r,_, ..,....,...: ,, · FR.qCT ! 0l'4 128~ 1248. 3 . _, ~ METHANE 82103852. 20.9 GASES 120°60938. 30.7 GASOLINE 99= ~ ~' x?'''' 2"5 2 KEROSENE 65858144. 16.7 GAS-OIL 12483568 . 3.2 WAX-D!ST ILLATE TOTAL AREA : 393585470. SAMPLE WT. : 97.70 rags AREA ~ .0: 100.0 SAMPLE GOGI = .32 THIS IS OIL + GAS PRONE METHANE + GASES = 24.i GASOLINE+KEROSINE+GAS OIL+WAX DISTILLATE BY FACTOR ANALYSIS OF KEROGEN PYROLYSATE THIS READING DOES NOT CONFORM TO KNOWN P~RAMETERS INUESTIGATE PRODUCT DISTRIBUTION THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT ITS " PRESENT"MATURITY. TH'IS "IS 'NOT''~ A':'KE~OGEN ~TYPE "ANALYSIS- SAMPLE K2 : 8.16 rog/gm "GMC:' Oa~'a'Re-Port No. 159'- ' '' ..... '" " : -"' -page 1-'o/226 :--- X ON 0 73.83 59.08 44.34 29.60 14.85 O. O0 . t0. O0 L:~O. O0 30. O0 40. O0 ~. O0 ~. O0 minutes SAMPLE: HELL: BELI UNIT #t DEPTH: 5680 ANALYZED; Fri May tt, t990 4:02:24 am RESULT: '/RESULT/NF42728 GP$.RES METHOD: GPGC2 0 70.00 80.00 Sequence: /chem/msd/042790.$ · Vial: 25 Injection: Normalized Percent Report Information from Curre~t Data File Header: File: /chem/msd/WF4272_SAT.d Operator: Date Acquired: Sat Apr 28 90 05:34:53 AM Sam~le~: WF4:272_SAT Misc Info: Sequence Index: 1 Bottle Number: 25 Repetition Number: SATURATE BI(D~gKER~ CalibratiomTable Last Updated:Sun Jun 10 17:4:9:53 1990 Reference Peak Wix~dow: 0.250 Absolute Minutes. No~-refere~ce Peak Wi~dow: 0.250'AbsoluteMinutes Default Sample Amount: 0 U~calib. Peak Response Factor: 0 Default Multiplier: 1 Ret. Signal Time Descrip~fo~ Amount 1 2' 3 4: . 5 6' 7 8 9 10 11 12 13 14: 15 16 17 18.. 19 20 21 22 23. 24: 25 26 39.728 191.00 amu C27 18A HOPANE TS 4:0.389 191.00 amu C27 17A HOPANE TM 4:1.819 191.00 amu C28 BISNORHOPANE X 4:2.74:2 191.00 amu C29 HOPANE D 4:2.852 191..00 amu C29 NORHOPANE D2 4:3-255 191~00 amu-..-C30-PENTACYCLANEPI 4:3.873 191.00 amu C30 18A OLEANANE B 44:-132 191.00 amu C30 HOPANE G 44~734:191.00 amu C30 MORETANE K 4:5.760 191.00 amu C31S HOPANE N 45.945'191.00 'amu' C31R HOPANE O 46.051 191.00 amu O & GAMMACERANE 4:6.34:3 191.00 amu GAMMACERANE 4:6.482 191.00 amu. P ' _ 46.621-191.00-a mu R 4:7.058 191[00 amu C32S HOPANE U* 4:7.314:191.00 amu C32R HOPANE V 48.. 530.:. 191.. 00..~ _~ C$~S..~OPAN.z ~.ALPHA 4:8.915 191.00 amu C33R HOPANE BETA 50.200 191.00 amu ~34:S HOPANE GAMMA 50.764:.191.00. a mu C34:R HOPANE DELTA 52.1'82 191.00 amu C35S HOPANE EPSILON 52.999 191.00 amu C3~R'HoP~NE'*ZETA 27.14:3 217.00 amu C21 STERANE y 36.085 217.00 amu C27S ba DIASTERANE10 36.'744 217.00 amu C27R ba DIASTERANEll 19679 58633 725 52755 20091 360 .. 3857 732O1 15O77 36884: 234:63 16231 556 1606 1324: -21385 9758 37620. . . 3.081 % 4.624: % 0.1170 % 8.519 % 3.244 % ~0..05818 % 0.6228 %* 11.82 % 2.4:35 % 5.956- 3~'789 % 2.621 % 0.08979 % 0.2593 % 0.2137 % 3.453 % 1.576 % 6.075 % " '112i3'" "-~1~811 30287 4891 14:606 14:79 74:4:3 8294 7031 4.891 % 0.7898 % 2. 359 % 0 :'2388-" % 1.202- % 1.339 % 1.135 % Run: 13 GMC 0ara Report No. 159 June 10, 1990 Page: ! Page 12/226 Sequence: /chera/msd/O42790.s Vial: 25 Injection: Peak ~t. Ret. Signal NumType Type Time~s~i~i~ Compound Name Amount 27 28 VV 29 W 30 W' 31 VV 32 PV 33 VV 34 W 35 VV 36 VV 37 VV 38 VV 39 VB 40 VV VV VV VV VV - 217.00 amu 13 37.649 217.00 amu 14 37.767 217.00 amu 15 37.901 2i7.00 amu 16 38.432 217.00 amu 18 38. 596 217.00 amu 19 38. 802 217.00 amu 20 39. 054 217.00 arau 21 39.285 217.00 arau 22 39.527 217.00 amu C27R aaa STERANE 25 39.803 217.00 amu 27 41.368 217.00 amu C28R aaa STERANE 36 41.'878 217.00 ainu C29S aaa STERANE 39 42.886 217.00..iarau C29R aaa STERANE 42 39.012 2t8.00 amu C27R abb STERANE 21B 39.180 218.00 amu C27S abb STERANE 22 40.763 218.00 amu C28R abb STERANE 33A 40.931 218.00 amu C28S abb STERANE 34 42.206 218.00 arau C29R abb STERANE 40 42.336 218.00 amu C29S abb STERANE 41 -Not Found- 5243 0.8466 % 5617 0.9070 % 1876 0.3029 % 5109 0.8250 % 170 0.02738 % 12083 1.951 % 7352 1.187 % 2177 0.3515 % 11386 1.839 % 14375 2.321 % 9159 1.479 % 9923 1.602 % 13188 2.130 % 10930 1.765 % 10685 °1.725 % 10988 1.774 % 10976 1.772 % 14411 2.327 % 15772 2.547 % *** ~ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not Ail Calibrated Peaks Found *** Run: 13 GMC Data Report No. 159 June 10, 1990 Page: 2 Page 13/226 Abundance Ion 77. O0 amu. from WF4272_SAT, d 900 - 800 '700 600 500 4OO 40' ' 42 44 46 48 50 ,52 54 ': Time (min.) ,, Abu'ndance Ion lgl.o0 amu, from WF4272_SAT. d , 2400 ~.oo :',~- " ' ,~oo,;,,,i , ' , A , ~oo ':.. II t~, )//~' :~oo"...~ , '.' ~ '/,, A..~v '~ ' .._., . , ' 'i ........ i ....... ' '' ' ......i::: i ........... 1 - - ' I .... ' '-- I 40 42 44 48 46 Time (min .) 5O 52 54 Abundance .. 2400 - 2000 ~600 ~200 ~ E300 36 38 40 Ion i91.O0 amu. from WF4272_SAT.d 42 44 46 48 Time (min.) 5O 52 54 Abundance · _ 2400 ' ' 2000 ' ~600 Ion 191.00 amu. from WF4272_SAT.d 80O .-]. . .. 400,.:"',. ~ ~~*' , ' 30 40 ,.. . T',me Ion ~i7.00 amu. from WF4272._SAT.d ,; , Abundance 400 'I 360:1 320 280 200 ' J. 60 I ~ 30 40 '. T:i. me (m~.n.) Ion 217'00 amu. from WF4272_SAT.d ',, Abundance 400 ,360 3~0 240 36 38 4O T'~me (m:~n.) 42 44 PETROLEUM GEOCHEMISTRY *~*- SARA ANALYSIS SAMPLE NAME I~ c 1' N._,TR~,'IENT II'IOECT T IliE METHOD USED SEQUENCE RESULT FILE REPORT TIME BELLI UNIT~kl 8400-8670 HPLC_FID Thu Apr 19~ 1990 4:25:42 pm /METHOD/HPLC_FID0.MTH /OATA/LOOP/SEOUENCE/HP1090_AUTOBY.SEO /RESULT/WF4234_SAP.RES 4:51 PM THU. ~ 19 APR. ~ 1990 Seturate~ Aromat ic~ 1 Aromatics 2 Po lars RESPONSE AREA TIME FACTOR )1080. 5.29 .1275E-0) 5952. 9.42 .5470E-04 18291. 14.)6 .5470E-04 60821. 19.96 .4160E-04 Saturate~ Aroma t ic~ Po lar~ AMOUNT (rog) % RESIDUE ).96 50.7 1.3) 17.0 2.53 32.4 Saturates Aromatic~ Polars Asphaltenes OIL 42.6 14.) 22'.2 16 'O GMC Data Report No. 159 Page 18/~26 .7:[ U U i SA~L.E: 6ELLI I~iIT~l 8400-8670 AItALYZED: Thu Apr 19. 1990 4: 25:42 p. /RE~i!~LT/WF4234 SAP.RES ~ETHOD: HPLC FIDO PETROLEUM GEOCHEMISTRY SATURATE GC SRI'IPLE NAME ! NcTRUMENT l N,]ECT T ! I'IE METHOD USED RESULT F!LE REPORT TIIIE : BELl UNIT 4ri 8400-86.--2'0 : HP 5890 2 : Tue I'1.=,,, 8 lg90 6:3~,:42 om : /I1ETHOD/SAT58.90E.. MT.H __ HT RES : /RESULT/WF4234 ?," . _, ._, lOgO : -:2/ Pi1 TUE.. 8 .-'dAN' : .. CPI UALUE : 1.01 PRISTANE / PHYTANE : PRISTANE / CI? : PHYTANE / C18 : 1.95 C15/C25 : .69 C12/Pn : 1.45 .50 C18/Ph : 2.01 AREA %AREA I'-IALI< T !IIE NORM C!5 N-CIO N-Cll N-C12 N-C13 N-C14 N-C15 N-C16 N-C17 N-C18 N-C19 N-C2 O 1'4- C21 N-C22 N-C23 N-C24 N-C25 N- C26 - N-C22 N-C28 N-C29 N-C30 N-C31 N- C3 2 N-C33 N-C34 l-l- C}5 N-C 36 O. 0.0 0.00 O. 0.0 0.00 145. .3 !0.11 665. 1.5 12.22 1688. 3.8 14.19 3519. 8.0 16.04 4493. 10- 2 17.79 4478. 10. 1 19 .'45 3188. 7.2 21.02 2744. 6.2 22.52 1997. 4.5 23.95 2336. 5.3 25.32 2217. 6.1 26.63 2169. 4.9 27.89 1.210 = ,~ -)o 09 1477. _5.3 _50.26 I213.' -2 '7- 31.'-3-7 1099. 2.5 32.45 1071. 2.4 33.49 988. 2.2 34.50 737.- 1.7 35.47 722 1 6 36 4~ 981 2 '-' 37 32 9.52. 2. ! 38.27 1518. 3.4 '~9.3! 802. 1.8 40.49 819. 1.9 41.85 0.00 0.00 .04 .19 .48 !.00 1.27 .91 .78 .57 .66 .49 .42 . .5'1 .30 .28 .21 .21 .26 .2~ Ac~c I lc. C1.6 Ac~c ! ic 618 Pristine Ph,Jtane .. AREA %AREA -!SPR TIME -~I! 4 "-' 13 78 90~ 1'2 1 15 40 · .. . _. · 1580. 21.2 18.67 308-~ 41 ~ I 9 61 1586. 21.2 21.2'2 GMc Data RePort No. 159 Page20'/226 2 7~ 2 57 2 43 cz) N % E LL] r._ Eib 0 ~Z 2 29 2 15 2 01 , t ,,, , , I ,,, ~ ,, I ,, ,, I , I , I, 10. O0 15.00 20.00 25.00 30.00 35. O0 5.00 mznutes SAMPLE: BELI UNIT #t 8400-8670 ANALYZED' Tue May 8, t990 6'35'42 pB RESULT: /ARCHIVE/WF4234 SAT.RES METHOD: SAT5890E 40.0O 45.00 PETROLEUM GEOCHEMISTRY ./ GI4H ROCK E'JAL '-*-~* /.,~:',, o,"' ".... 13620 ,..:,_L I UH I T SA!'IPLE : .... ~: .1 OEP i '.J-' ' 1940 4' Fi3: '] I pm IN._'IECTEO AT : Tue Feb 20; . _ INSTRUMEI'4T : GROCK IIETHOD USED : /IIE'THOD/PYROS.IITH ,.,_°cc' ..... rL.T F I LE : /RESULT/WF4234 GRO. P-.',_~ 8LANI< F I LE : /I:;'ESULT/BLANI<13_GRC;. RES AREA SLICE INTEGRAT!ON **~** AREA Y!ELD (mg/g) FRACTION 15992160. 111~3o2~0 1.68 4.50 SI Si.--." SAMPLE WT. : 18.7'-'0 mos Tmax : 435 C . . G~qC Data R'epoft'N"°'~'"i59'' ' '' ..... '" 'l~a'ge 22i'226 r, 5~ SAMPLE: NELL: BELI UNIT ~! DEPTH: 8670 ANALYZED: Tue Feb 20, ~990 4: 03: ~ pm RESULT: /RESULT/NF4234 6TX.RES METHOD: GTX$C! 0 80.00 PETROLEUM GEOCHEMISTRY / GNH PGC AUTO · :.3:.qMPLE : WELL: BELl UNIT ~1 DEPTH: 8620 lO90 4:0.3:11 om INOECTED AT : Tue Feb '2-_0, .. , IhISTRUMENT : GPGC_2 METHOD USED : /METHOD/GPGC2_O.MTH RESULT FILE : /RESULT/tdF4234 GPG.RES BLANK F!LE : ,,'RESULT/8LAI'~<14 GPG.RES AREA SLICE INTEGRRTION ***** AREA AREA PERCEHT FRACTION TOTAL AREA : --,,.,-" ::: 2144.2 . ? . ?__ METHANE .. 13918842. ?O. 7 17.345224. 25.9 GASOL I NE 18281164. 22..3 !<EROSENE 8151146. i2.2 GAS-O I L 4569234. 6.8 t. JA;K- D I ST I LLATE c-~:,~o~F' kiT : 18 70 rags AREA ~;: 100 0 ¢~.,, =~ GOGI = .39 THiS IS GAS + OIL PRONE METHANE + GASES = 22.9 GASOLINE+KEROSINE+GAS OiL+WAX DISTILLATE = 72.1 BY FACTOR ANALYSIS OF,.~,.~,~_,'/~°n'-~*'. PYRQLYSATE THiS IS A ~AS+OIL SOURCE THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT !TS PRE:SENT f'IAI'URITY. THIS IS NOT A KEROGEN TYPE ANALYSIS. 'GMC 'Dat'a-'Re~5ort' N'O" 159" Z. uJ CD C:~ N UJ r.,. i7. i~" ii. ii. ii .09. 8.07 5.05 L __ E.O~ ,,,~,,."'°'°"°"t. esto.oo ~.oo:,o.oo ,,o.oo SAMPLE: WELL: BELl UNIT ~! ANALYZED: Tue Feb 20, i990 RESULT: '/RESULT/WF4234 GP$.RES METHOD: 50.00 B0.00 DEPTH: 8670 4: 0:3: t! pm GPSC2 0 70.00 80.00 . Sequence: /chem/msd/0R2790.s Vial: 22 Injection: Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF4234_SAT.d Operator: Date Acquired: Sat Apr 28 90 02:06:38 AM Sample Name: WF4234_SAT , Misc Info: Sequence Index: 1 Bottle Number: 22 Repetition Number: 1 SATURATE Calibratio~ Table Last Updated: Sun Jun 10 17: 02: 03 1990 Reference Peak.. Window: 0. 250 Absolute Minutes Non-reference Peak Window: 0. 250 Absolute Minutes Default Sample Amount: 0 Uncalib. Peak Response Factor: 0 Default Multiplier: 1 Ret. Signal T%me_ ~- Description Amount I W '2 W 3 VV 4: W 5 W 6 7 VV 8 VV 9 W 10 W 11 W 12 W 13 14 W 15 W 16 VV 17 W 18 W 19 W 2O VV 21 VV 22. W 23 VV 25 W 26 VV Run: 10 39. 741 191.00 amu C27 18A HOPANE TS 40. 396 191.00 amu C27 17A HOPANE TM 41. 784 191.00 amu C28 BISNORHOPANE X 42.750 191.'00 amu C29 HOPANE D 42.861 191.00 amu C29 NORHOPANE D2 43 ,.270 19.1, pO ainu . C. 3o,_ pENTA.CYC:~..LANE .PI 43.881 191.00 amu 44.142 191.00 amu 44%876 191.00 amu 45.769 191.00 amu 45.961 191.00 amu 46.273 191.00 amu - 191.00 amu 46.485 191.00 amu 46.620 191.00 amu 47.059 191.00 amu 47,329 191.00 amu 48,530 191,00 amu 48,913 191,00 amu 50,207 191,00 amu C30 18A OLEANANE B C30 HOPANE G C30 MORETANE K C31S HOPANE N C31R-' HOPANE O- O & GAMMACERANE GAMMACERANE R C32S HOPANE U C32R HOPANE V C33S HOPANE ALPHA C33R HOPANE BETA C34S HOPANE GAMMA -. 50.775 191.00 amu. C34R HOPANE DELTA 52.192 191.00 amu C35S HOPANE EPSILON 53.023'191.00 amu- ~C35R HOPANE ZETA' 27.164 217.00 amu C21 STERANE Y 36.092 217.00 amu C27S ba DIASTERANE10 36.740 217.00 amu C27R ba DIASTERANEll June 10, 1990 58695 2.593 % 94671 4.182 % 3576 0.1580 % 140202 6.194 ,% 58693 2.593 % 607 0.02682 % 5355 '0.2366':%* 208575 9.214 % 7728 0,3414 % 125214 5.531'. % -77595 3.428 -% 52591 2.323 % -Not Found- 49288 2.177. 21902 0,9675',% 159118 7.029 % _ _ . ' 71615 3.164-~ 125042 5,524 % 53997 2.385 % 91269 4.032 % 40068 1.770 * % 85778 3.789 % 39841 -1~760 54808 -' 21421 - % -36919 1.631 % 29923 1.322 % - Page: Data Report No. 159 Page 26/226 Sequence: /chem/msd/0~2790.s Vial: 22 Injection: 1 Peak Int. Ret. Signal Compound Nu~~ Type Time Description Name 27 PV 37.332 217.00 amu 13 28 W 37.648 217.00 amu 29 VV 37.770 .2'17.00 amu 15 30 W 37.914 217.00 amu 16 31 W 38.433 217.00 amu 18 32 - 217.00 amu 19 33 PV 38.812 217.00 amu 20 34 W 39.093 217.00 amu 21 35 W 39.297 217.00 amu 22 36 VV 39.529 217.00 amu C27R aaa STERANE 25 37 W 39.196 217.00 amu 27 38 VV 41.363 217.00 amu C28R aaa STERANE 36 39 VB 41.904 217.00 amu C29S aaa STERANE 39 40 W &2.891 217.00 amu C29R aaa STERANE ~1 VV 39.026 218.00 amu C27R abb STERANE 21B ~2 VV 39.19& 218.00 amu C27S abb STERANE 22 ~3 VV 40.767 218.00 amu C28R abb STERANE 33A ~ VV 40.938 218.00 amu C28S abb STERANE 3~ ~5 VV 42.217 218.00 amu C29R abb STERANE ~0 46 W 42.348 218.00 amu C29S abb STERANE 621 0.0274¢ % 209¢2 0.9251 % 24914 1.101 % 6219 0.2748 % 19867 0.8777 % -Not Found- 434~9 1.919 % 50500 2.23~ % 8579 0.3790 % 32113 1.419 % 27232 1.203 % 32391 1.431 % 29753 1.31~ % 43902 ~.939 % 39809 ~.759 % 30159 °1.332 % 34148 ~.509 % 33553 1.482 %' 45018 1.989 % 47445 2.096 % *** REPO~ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not Ail Calibrated Peaks Found *** Run: 10 aM~ I~t~ Rpnnrt Nh_ 159 June 10, 1990 · .. Page: 2 Pame 27/226 Abut3. dance 50O0 'i 4000 3000" 2000 ":' ~.000 Zon i9i,O0 emu, from WF4834._SAT,d 30 40 Time (mtn.) Abundance ,. i400.. ~.200 ~000 800 600 "- ,.~ 4OO 200 "~ ~ ! Ion 2i7..,00 amu, from WF4234_SAT,d ' I ' ' 30 40 ,. Time (min,) 5O ' i '1 50 Abundance , ., Z .,' ~ 5000 4000 3000 2000 lOO0 36 38 40 Ion ~g~',O0 nmu, fpom WF4234_SAT.d 42 44 46 T~me (m~n.) 48 50 52 54 ~tO0 ~000 ,. Abundance . 900 ' 800 .: 700 '" ',. ~00 5OO 400 '~ , ,-,,.,,.,300 ',',' ¢ Zon 2~17.00 ~mu. fr',om 14F4E34_SAT.d 38 ' 40 42 Tftme (m:Ln.) ,,' Abundance Ion ~77.00 amu. from WF4234_SAT. d 1800 1600 - ,. 1400 ~200 1000.'~~800 600:.. ............ ~ ~ , '~ .... 40 42 44 46 48 50 52 54 Time (min.) Ion i91.O0 amu. from WF4234_SAT.d AbU:ndance 5000' ,,' 4000 3000.. 2000.' loo0" I .... I ' I ' [ , ,, 46 48 50 52 54 Time (min.) Sequence: /chem/msd/042790. $ Vial: 22 Injection Ion 177.00 amu. from WF4234_SAT.d WF4234_SAT Peak# Ret Time Type Width Area Start Time End Time 1 42.750 BV 0.052 30704 42.576 42.815 2 43.544 BB 0,.061 36557 ~3.R~6 43.657 ~ Ion 191.00 amu. from WF4234_SAT.d WF4234_£AT Peak# Ret Time Type Width Area 1 22.290 BB 0.064 33533 2 22.964 BY 0.066 95433 3 25.017 BV 0.062 52897 4 26.325 BB 0.066 51124 5 29.100 BB 0.065 83013 6 30.259 BB 0.063 55176 7 32.580 BB 0.106 59310 8 33.807 BB 0.065 57372 9 39.740 BB 0.076 50577 10 40.395 BB 0.065 -. 93333 11 42.750 W 0.073 142247 12 42.860 VB 0.062 50291 13 ~.142 BV 0.064 181222 14 44.768 VB 0.062 51903 15 ~5.769 BV 0.077 111649 16 45.972 PV 0.066 47484 17 46.085 W 0.079 49082 18 47.058 BB 0.078 105615 19 ~8.531 BV. . 0..066 63568 ...... 20 52.207 BV 0.089 60082 Start Time 22.194 22.853 24.932 26.219 29.018 30.131 32.295 33.720 39.550 42.561. 42.817 44.036 44.687 45.580 45.874 46.019 46.774 48.441 52~073 End Time 22.387 23.072 25.%13 26.453 29.222 30.393 32.711 33.928 39.866 40.520.' 42.817 42.992 44.2~9 44.902 45.874 46.019 46.204 47.160 48.618 _ . 52.331 Ion 2~7.00 amu. from WF4234_SAT.d WF4234_SAT Peak# 1 2 3 5 6 7' 8 9 Ret Time Type 22.~36 BV 25.585 PV 25.996 BV 26.164 W 26.508 VV 27.164 BV 27.36'9 W'' 29.483 BV 36.092 PV Width Area Start Time 0.060 9937 22.056 0.067 33640 25.429 0.094 -'' 23021 25.'857 0.065 ~3689 26.078 0.060 10231 26.442 0.063 52902 27.077 0~074 '' ' 24474 "27.'255- 0.104 29652 29.338 0.065 31698 36.01~ End Time 22.225 25.753 26.078 26.253 26.607 27.255 27.443 29.611 36.173 Run: May 2, i9. o .. Page' GNC Data Report No. 159 Page 32/226 sequence: /chem/msd/O42790.s' Vial': 22 Injec'tion: 10 36.740 BV 0.059 28538 36.612 11 37.510 W 0.069 10118 37.462 12 37.648 W 0.056 18614 37.585 13 37.770 VV 0.066 22394 37.705 14 38.032 VB 0.082 16393 37.971 15 38.377 BV 0.060 12140 38.283 16 38.433 VV 0.080 19349 38.395 17 38.812 PV 0.099 44084 38.595 18 39.093 W 0.098 51408 38.951 19 39.196 W 0.094 35708 39.149 20 39.528 VV 0.081 32473 39.373 21 39.810 W 0.120 51104 39.605 22 40.115 W 0.083 14298 39.927 23 40.473 VV 0.113 27598 40.321 24 40.758 W 0.078 36643 40.632 25 40.937 W 0.084 25501 40.851 26 41.138 W 0.121 24656 41.020 27 41.363 W 0.089 32858 41.267 28 41.905 W 0.107 36379 41".745 29 42.218 PV 0.074 35622 42.099 30 42.348 VV 0.065 26057 42.286 31 42.891 BV 0.069 38084 42.800 36.877 37.585 37.705 37.856 38.210 38.395 38.595 38.951 39.149 39.373 39.605 39.927 40.185 40.632 40.851 41.020 41.267 41.591 42.099 42.Z86 42.449 42.999 Ion 218.00 amu. WF4234_SAT from WF4234_SAT.d Peak# Ret Time I 36.097 2 39.026 3 39.194 4 39.S~1 5 '39.731 6 40.478 7 40.767 8 40.938 9- 41.138- 10 41.368 11 42.217 12 42.348 13 42.888 Type Width Area VV 0.058 8224 PV 0.071 34713 VB 0.060 22843 BV 0.070 12635 PV 0.093 5454 BV 0.090 16636 PV 0.072 31062 W 0.067 29923 W 0.083 22347 PV 0.066 7406 BV 0.069 42721 VV 0.064 41725 BB 0.072 24413 Start Time 36.025 38.936 39.135 39.385 39.'60~' 40.347 40.651 40.855 41.028 41.275 42.110 42.279 42.726 End Time 36.175 39.135 39.266 39.604 39.781' 40.651 40.855 41.028 41.27-5 .. 41.436 42.279 42.468 43.114 'gUn:.. 10 GMC Data Report No. 159 - -page-: Page 33/226 . PETROLEUM GEOCHEMISTRY *** SARA ANALYS SAMPLE NA?IE I I'-~.S TRU!IEIqT ! NOEPT T l METHOD USED SEE:UE NCE RESULT FILE : BELl UNIT 4~1 9010-9180 : HPLC_F I D : l'hu lla? 1O. 1990 2:!~:5_=, pm : /METHOD/HPLC_FIDO. MTH /DATA/LOOP/SEOUEI','CE/HP i [',? u_AUTOCF', cE_,~U- : /RESULT/tdF42=¢-.,~, SAP. RES : '~_.:;.=9 PM THU. ., 'tO MAY : 1 ~;'~. ;_'- Satur-ate$ Aromatics i R~oaatics 2 Polars RESPONSE AREA TIME FACTOR 128456 . 5 . 29 . !275E- 03 24951. 9.42 . 54.?0E-04 66303. 14.36 . 5428E-04 !~2032. 19.96 . 4!60E-0-4 Saturates Aroma t i cs Po la~s AMOUNT (mgl. .o°~ RESIDUE 16 38 58 -~ 4.99 12.9 6.53 23.4 Saturates Aromatics Po!ars Aspha!tenes OIL 41.2 12.6 16.5 29.7 GMC Dat~ Report. Nb. 1~9"" " ..... ' -'" .... :" .... '" "":-':" -PAge '34/226 -- 0 N ~ ~) 14J ¢.. @.59 6.89 5.20 3.50 i .80 .lO__ , [ 0,00 mlnu%es 3.1P- (u 4J 4.J RESULT: /RESULT/I~F4235 SAP.RES 'X ._4_ ......-L .... ~----J , ! .... _~_____ 6.25 9.38 12.50 i5.63 18.76 SAHPLE: BELI UNIT iii 90~0-9180 ANALYZED: Thu Hay lO, i990 2: 13' 53 pm HETHOD: HPLC FIDO 25.0~ PETROLEUM GEOCHEMISTRY SAI'URmTE GC SAMPLE I-IArlE INSTRUMENT !NOECT TIME METHOD USED RESULT FlmE REPORT T!ME 8ELI UNIT '~1 9010- ,, . 9180 HP_5890 _2 · -'- . '~ ? 1990 6: 16: :1 /l-4cmur, r'~ /C~TmOO, OE MTH /RESULT/WF42 ~ ~_S~T. RES ?:07 PM S~T.. I2 MAY. pm 1990 CPI UALUE : 1.02 PRISTANE / PHYTANE : PRISTANE / Cl? : PHYTANE / C18 : 1.47 C15/C25 : .:,. .65 C17/Pr : 1.54 .49 C18/Ph : 2.04 AREA ~AREA NALI< TIME NORM N-CiO N-Cll N-C12 N-CiD N-C14 N-C15 N-C16 N-C17 N-C18 N-C19 N-C2O N-C21 N-C22 N-C23 N'- C24 Iq-C25 N-C26 N-C27 N-C28 N-C29 N-CDO N-C31 N-C32 Iq-C33 N-C34 l',l- C35 N-C36 O. 0.0 O. 0.0 O. 0.0 126. .5 525. 1.4 1276. 3 ._.4 2040. 5.4 2565. 6.8 2317. 6.1 2255. 6.0 1914. 5.1 1872. 4.9 2285. 6.0 2189. 5.8 2036 .-. 5 .-4 - 2-330. 6.2 1867. 4.9 1535. 4.1 1592.. 4.2 -. 1398. 3.7 921. 2.6 930. 2.5 917. 2.4 1155. 3.0 1404. 3.7 1016. 2.7 1310. 3.5 0.00 0.00 0.00 0.00 0.00 0.00 12.21 .14 14.18 .41 16.0D !. O0 17 ~.o ..-~, 1.60 19.44 2. O1 21. O1 1.82 22.51 1.77 23.94 !.50 25.31 !. 47 26.6: 1.79 27.88 1.72 _29..08 1.60 30 04 1 o-~ 31.36 1.46 32.44 1.20 33.48 1.29 34.48 .... i. iO 3,5.46 . ?6 36.40 .73 37.31 .72 38.25 39.29 1.10 40 47 ~'0 41.83 1. 03 AREA %AREA ;SPR TIME F&.rne=_.-~ne Acyc!ic C16 Ac,Jclic CIE'. F'r i ~, tane Phk,t ar-,e ~,- ..'., .. '.... :. .. , ',. .. : 0 '0 ...... '0 00 4 15 3° 19:~ ~8 ' ' .:.-', ,.a 1 o "0 "-r-' . u --.' 2..°.. 1 21.21 ~ ' -: "., .,.'.C'_:~ . ..-.-.. ,- - . -- .-._ GFiC Data Report No. 159 Page 36/226 2 ;::' 40 o,-.~ ca LLI r..._ r-1 CD I--.. 2 22 2 03 , i , .I , .. I. ~ I .., I 5,00 lO, O0 15.00 20.00 25.00 30. O0 35.00 minutes SAMPLE: BELI UNIT #1 9010-9180 ANALYZED: Sat May t2, t990 6: 16:2i pm RESULT: /ABCHIVE/WF4235 SAT.RES METHOD: SAT5890E i , 40.00 45.00 PETROLEUM GEOCHEMISTRY / GNH ROCK EUAL SAMPLE .: 9010-9180 FT. INJECTED AT : Mon Mar 19, 1990 2:02:17 pm INSTRUMENT : GROCt< METHOD USED : /METHOD/PYROS.MTH RESULT FILE : /RESULT/WF4235 i GRO.RES 8LANI< FlEE : /RESULT/8LA~<13 GRO.RES AREA SLICE INTEGRATION .. -. AREA Y I ELD (mg/g ) FRACT I Obi 22852124. 2.22 Si 141428770 17 7o co SAMPLE bJT. : 24.70 mgs Tmax : 421C :~ ':GMC 'Da't~ 'Re'po'rt'-No.- 159 ......... .'---- - .: ...... -- ~-- '---'--Page 38/22-6. "- .... -. - 6.4g 5.07 ;~3. l; ~l. 28 39.40 47.5t 55. $~J 6~J. 75 SAHPI. E: I~ELI,: BEt.! UNIT ti DEPTH: ANAI,YZED: Hon*Nar 19. ~990 2: 02:]7 pm RESULT: /RESULT/HFa235 ! ;TX.RES HETHOD: ;TX$C! 0 ?i .85 PETROLEUM GEOCHEMISTRY z GNH PGC AUTO SAMPLE : NELL: BELI UNIT ~1 DEPTH: 9180 IN3ECTED AT : lion Mar 19, 1990 2:02:12 pm INSTRUMENT : GPGC_2 METHOD USED : /METHOD/GPGC2_0.MTH RESULT FILE : /RESULT/WF42~5 i GPG.RES 8LANK FILE : /RESULT/SLA~<iS_GPG.RES AREA SLICE INTEGRATION AREA AREA PERCENT FRACTION 4i~765i. 6.i METHANE 8614926. 12.2 GASES 20010012. 29.6 GASOLINE 12046044. 25.2 KEROSENE 144522~2. 21.3 GAS-OIL 3422110. 5.1 WAX-DISTILLATE TOTAL AREA : 67662984. SAMPLE WT. : 24.20 mg5 AREA %: 100.0 SAMPLE GOGI = .23 THIS IS OIL PRONE . METHANE + GASES = 18.8 GASOLINE+KEROSINE+GAS OIL+~AX DISTILLATE = 81.2 BY FACTOR ANALYSIS OF KEROGEN PYROLYSATE THIS IS AN OIL+GAS SOURCE THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT !TS PRESENT MATURITY. THIS IS NOT A KEROGEN TYPE ANALYSIS. SAMPLE_ K2 = 16..~?/ mg/gm "'"" GMC Dat~a'Rep-o'rt N'O. 159-- :'.--: PAge: 40/226" - -' - t2.06 X ~ gs~ o r~ 707 r~ 0 2.0~ ~t~tes 9.~9 sg.gg as.ge ~.~ SAMPLE: WELL: BELI UNIT fL ANALYZED: Mon MaP ~9, t990 2:02:~7 pm RESULT: /RESULT/WF4235 ! GPG,RES METHOD: GPGC2 0 49.98 5g. 98 69.98 79.98 DEPTH: 9L80 · Sequence: /chem/n;sd/o~L,~'~$90.s Vial: 1 Injection: 1 Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF4235_SAT. d Operator: Date Acquired: Fri May 25 90 07:25:00 PM Sa-?le Name: WF4235_SAT Misc Info: Sequence Index: 1 Bottle Number: 1 Repetition Number: 1 SATURATE BIOMARKERS .. Calibration Table Last Updated: Mon J[~ 11 12:37:36 1990 Referemce Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 0.250 AbSolute Minutes Default Sample Am~u~t: 0 Uncalib. Peak Response Factor: 0 Default Pklltiplier: 1 Peak I~t. Ret. Signal Time Description compound Area Amount 1 VV 2 W 3 W { W 5 VV 6 W . 7 W 8 .. W 9 VV 10 VV 11 W 12 W 13 VV 15 W 16 W 17 VV 18 VV 19 VV 2O W 21 W 22 W 23 "~ PV ' 24 VV 25 lr~ 26 VV 39.759 191.00 ainu ~0.~t17 191.00 amu {1.792 191.00 amu ~2.762 191.00 amu {2.86{ 191.00 amu ~3.179 191,..0° ainu {3.'792 191.00 ainu 44.152 191.00 amu 44.771 191.00 amu ~5.773 191.00 amu 45.973 191.00 amu 46. 099 191.00 amu 46.256 191.00 amu {6.~93 191.00 amu ~6.806 191.00 amu 47. 052 191.00 amu {7.327 191.00 ainu 48. 526 191.00 amu 48.909 191.00 amu 50,198 191.00 amu 50.76{ 191.00 amu 52.184 191.00 amu C27 18A HOPANE TS C27 17A HOPANE TM C28 BISNORHOPANE X C29 HOPANE D C29 NORHOPANE D2 C30 PENTACYCLANE PI C30 18A ~Or;EANANE' B C30 HOPANE G C30 MORETANE K C31S HOPANE N -C31R HOPANE-O O & GAMMACERANE GAMMACERANE P R C32S HOPANE U C32R HOPANE V C33S HOPANE ALPHA C33R HOPANE BETA C3{S HOPANE GAMMA C3~R HOPANE DELTA C35S HOPANE EPSILON 53.009 191.00 ainu ---C35R HOPANE- ZETA 27. 201 217'. 00 amu C21 STERANE Y .36. 111 217.00 ainu .C27S ba DIASTEP~aNE10 36.760 217.00 amu C27R ba DIASTERANEll June 11, 1990 65999G 1.51~ % 3978398 9.127 % 102130 0.2343 % 2956125 6.782 % 780374 1.790 % 296603 0.6805 % 72708 0.'1668 '%, 3999642 9.176 % 5118358 11.7% % 1668~83 3.828 % 860~24 1.97~ % 5513382 12.65 % ~50562 1.03~ % 588~54 1.350 % 157817 0.3621 % 1~1i~9 3.2~5 % 863008 1.980 % 8103~5 1.859 % 451738 1.036 % 607281 1.393 % 260611 0.5979 % 6~5092 1.~80 % 301716 0.6922 % 670624 1.539 % 666037 1.528 % 54376~ 1.2~8 % Pace _- .............. ~ ~'^ ~ Paee 42/226 Sequence: /chem/msd/O52590.s Vial: I Injection: I Peak Int. Ret. Signal Compound NumType Type Time Description Name Area Amount 27 W 37,197 217.00 amu 13 28 W 37,670 217.00 amu 14 29 W 37,787 217.00 amu 15 30 W 37,925 217.00 amu 16 31 W 38,448 217.00 amu 18 32 PV 38,635 217,00 amu 19 33 VV 38,831 217.00 amu 20 34 VV 39,216 217.00 amu 21 35 VB 39,308 217.00 amu 22 36 BV 39,550 217.00 amu C27R aaa STERANE 25 37 VB 39,821 217,00 amu 27 38 VB 41,378 217.00 amu C28R aaa STERANE 36 39 W 41,904 217,00 amu C29S aaa STERANE 39 40 W 42.901 217.00 amu C29R aaa STERANE ~2 41 BV 39,0~0 218,00 amu C27R abb STERANE 2lB 42 VB 39,210 218.00 amu C27S abb STERANE 22 43 VV ~0,789 218,00 amu C28R abb STERANE 33A 44 VV ~0,952 218.00 amu C28S abb STERANE 3~ 45 PV 42.22~ 218,00 amu C29R abb STERANE &0 46 W ~2.357 218.00 amu C29S abb STERANE RI 235792 0.5~10 332519 0.7629 386659 0.8871 108872 0.2~98 303696 0.6968 1271 0.002916 7555~1 1.733 370984 0.8511 72140 0.1655 ~87606 1,119 692190 1.588 752851 1.727 53R~7 1.226 596292 1.368 55968~ 1.28~ 418135 ~ 9593 593957. 1,363 653502 1.~99 633310 1.{53 659743 1,514 *** REPORT ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 1 June 11, 1990 Page: 2 GMC Data Report No. 159 .PaQe 43/226 Abundance .. i6000 i40"00 t~olOo ,' lO000 ,', ', 80'00 ., ,,, 6000 ,,1000 ~_o,0o , ,! Ion 217.00 emu. fr"om WF4235_SAT.d 40 42 Time (min.) FI) 0 ..~ Abundance o lO0000 800OO 0'0oo 40000 . 20000 Ion ~9~.00 amu. from WF4235_SAT.d 36 38 40 i' "! ........ j '"'"! ' ii 44 Time (min.) i ! i j i 50 52 lO0000 sOOOO 60'000 ,, Abundance ,~Oooo 20ooo ,, Ion 191.O0 amu. from HF4235_SAT.d 30 40 Time (min.) Ion 217.00 amu. from HF4235_SAT.d Abundance 16000 1 ~O'oo ~ 12000 ~,, lO000 - 8000 000 4600 2000 ' ,,, ' I I , 3O 40 T,.me (min.) 160000 1400:'00 1200..00 iO00,O0 .. 80000 60'000 · 4O0OO .Abundance , ' I Ion i77.00 amu. from NF4235_SAT.d Abundance lO0000 = ., 80000 60,000 , 40000 20000 , ' 40 42 44 i 46 48 Time (m-in.) 50 52 ,. i PETROLEUM GEOCHEMISTRY SARA ANALYSIS SAMPLE NAME : I I-4STRUME!-4T - II-IJECT TINE : METHOD USED : SEOUENCE : RESULT FILE : REPORT T!ME : 8ELI UIqIT 4~1 10810-10840 HPLC_FID Thu ile,, !0. 199n '2:s4:~ pm /IIETHOD/HPLC_FID0.HTH /DATA/LOOP/SEQUENCE/HPIOgO_AUTOCF.SEO /RESULT/WF4273 SAP.RES %:20 PM THU., lO , ...... ..urat~e. (~r'oma t ~ C~. 1 .Aromat ~cs 2 Po!ars AREA T I !'IE FACTOR Saturates Aroma t i cs Po lars AMOUNT (mg) ~ RESIDUE 9 85 z-~ 7 "-' 60 16 ~- = g2 gO 8 "' OIL Saturates '62.~ Aromatics 16.5 Polars 20.8 Asphaltenes 0.0 GMC 'Data .Report No.'-1.59- - · . .... .':- ' -- -- ....... --. - :--..-.: - - -:- .-:Page -48/226 3.80 ANALYZED' Thu Nay _I0, 1990 2: 54:46 pm RESULT: /RESULT/~F4273 SAP.RES NETHOD: HPLC FIDO · 0 ¢: ' L .I .... ._~.. /_...b~~ _ .33 .- .... _.__L. ~ ._.__l · _ I _ _ , ...... 1 . ___..l______ 0.00 3.22 6.25 9.38 i2.50 ~5.63 18.76 21.e8 25.0~ $znuSes SAMPLE: BELl UNIT ¢~ ~0810-~0840 PETROLEUM GEOCHEMISTRY SATURATE GC SAMPLE NAME ] t~STRUiqENT IN.]ECT T!I1E METHOD USED RESULT FILE REPORT TildE : 8ELI UNIT ~1 10810-10840 ' HP qo- ~ c-_ 12 1990 7:11:48 : ~ t l'lay ~ : /METHOD/SAT5890E.MTH /RESULT/WF4273_SAT.RES : 8:02 PM SAT.. 12 MAY : pm 1o90 CPI UAL!JE : .... PRISTANE / PHYTANE : PRISTANE / C12 : PHYTANE / ¢'1 8 : 1.09 C15/C25 : .49 C17/Pr : .46 C18/Ph : 2.05 o 1o ~.. .- N-CI I N-Ci2 N-C13 N-C14 N-C15 N-C!6 N-Ci? N-CI8 N-C19 N-C20 N-C21 N-C22 N-C23 .N-C24 N-C25 N-C26 N-C22 N-C28 N-C29 N-C~0 N-C}i N-C32 N-C33 N-C34 N-C35 AREA O. O. 166. 285. 464. 553. 604. 592. 768. 1065. 576. 674. 576. 6i8~ 840. ~72. 525. · 452 ~51. 1152. 1~?0. 1292. 641. ~AREA NALK TIME NORM 0.O 0.00 0.00 0.0 0.00 0.00 0.0 0.00 0.00 1.0 12.21 .36 1.7 14.18 .62 2.8 16.04 1.00 ~ 3 17 ~o . ..~ 1.19 3.7 19.44 1.50 ~.6 21.02 1.28 4.7 22.51 1.66 6.4 25.94 2.~0 3.5 25.51 1.24 4.1 26.62 1.45 5.5 27.88 1.24 '5.7 29 .-08 1.3;.5 5.1 3;0.25 1.81 :5.4 51..56 1.21 2..5 52.44 .81 .5.2 '5'5.48 1.13; 2.7 34- 48 " .97 2.1 35.46 .26 2.2 56.50 .78 7.0 37.'51 -2.48 8.'5 '58.07 2.95 7.8 39.29 2.79 '5.9 40.62 1.38 lO. O 41 . 83 3,. 57 AREA ~AREA ISPR TIME Fa r neS"ane Ac,..,c 1 ic C16 · Acyc I i c P,'ister, e 'g. ~ F: ,-....'. ~ n e . .... . , . .., ... O' 0.0 0.00 153. 16.7 15.39 ~01 91 o 18 60 /... z.. i -; .~0 · -,-~r, 2° 4 al 21 '. . - . . -.. Data Report No. 159 Paoe 50/226 o z o 2. 461 2.37 2.2~ CD N w r_ ~z 2.20 2.t2 2.03 , I ' I , I , iii I ~ I I I lO.O0 ~5.00 20.00 25.00 30.00 35.00 5 O0 minutes SAMPLE: BELI UNIT #1 10810-10840 ANALYZED: Sat May 12, i990 7' 11' 48 pm RESULT: /AF~CHIVE/WF4273 SAT, RES METHOD: SAT58gOE I 40.00 45.00 . - ..... c- , 6NH ROCK *+**.' PETmfiLcUI'I GEOCHEMI._.TR¢ .-' SRMPLE : WELL: BEL! UNIT 4~1 D£PTM: 10S40 . INJECTED AT : Fei Apr 27~ !990 !2:53:26 pm [NS'fRUriEHT :' METHOD USED : /METHOD?PYROS.MTH RESULT FILE : ×RESULT/NF4273ii_GRO.RES BLANK FILE : ?RESULT/BLA~<13 GRO.RES AREA SLICE INTEGRATION AREA YIELD (mg/g) FRA£TION 3824965. i0.23 Si i4464380. 98.39 S2 SAMPLE ~T. : 6.80 Tma× : 452 C. - - GMC' Data"'Re'port' No': 't59 .:'- ..... - 9.7~ ;~3, ],(; 3]. ;~11 39.40 47.5t 55.63 53.75 7 ~. 86 79. ~)~ ~5,. 05. minutes SAMPLE: NELL: BELI UNIT #1 DEPTH: 10840 ANALYZED: Fri Mar 16. 1990 2: 5~' ~6 pm RESULT: /RESULT/NF4273 GTX.RES METHOD: GTX~C1 0 PETROLEUM GEOCHEIqISTRY / GNH PGC AU'FO SAMPLE : WELL: BELI UNIT ~1 DEPTH: 10840 INJECTED AT : Fri Apr 27, 19°0, 12:53:26 pm INSTRUMENT : GPGC_2 METHOD USED : /METHOD/GPGC2_O.MTH RESULT FILE : /RESULT/WF427311_GPG.RES BLANK FILE : /RESIJLT/BLA~<15_GPG.RES AREA SLICE INTEGRATION AREA TOTAL AREA : 1420206. 6484635. 5141986. 1945422. 631713. 13~'661 SAMPLE I¢!T. : 6.80 mg5 ':,q?~PL¢ GO:Si = 1 0 THIS IS GAS PRONE AREA PERCENT FRACTION ?. 0 METHAf'IE 41 1 .: .6 gASOLINE 12.3 V. EROSENE 4. O GRS-O [ L . 9 LIAX-D ! ST: LLATE AREA %: 100.0 METHANE + GASES = 50.1 GmSOLINE+I<EROSINE*GAS OIL+i,JAX DISTILLATE = 49.9 .o'( FACTOR ANALYSIS OF '.-<EROGEN PYROLYSA'¥E THIS IS :SAS PRONE t-..: = ~'z 6= mq..-"qm -. --- -',:' ':' "- -' -'-~' P-age-,54/226 ----": - "- .... 6HC"Dbt'a'Report"No 159- ""' -'-"-,' .... . -- .' . . -. Z. 9.5! 5~ 3.1! ~i~?ut es to.oo ~o.oo so.oo 40.00 ~o.oo ~o.oo SAMPLE: WELL: DELI UNIT ~! DEPTH: 10840 ANALYZED: FPt Apr 27, ~990 t2: 53:26 pm RESULT: /RESULT/WF4E7311 GPG,RES METHOD: GPGC2 0 70.00 80.00 Sequence: /chem/msd/O 52590. s Vial: 2 Injection: . Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF4273_SAT.d Operator: Date Acquired: Fri May 25 90 08:36:20 PM Sample Name: WF4273_SAT Misc Info: Sequence Index: i Bottle Number: 2 Repetition Number: 1 SATURATE BIOflARKERS Calibratio~Table Last UPdated: Mon Jun 11 13:22:55 1990 Reference Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 0.250 Absolute Minutes Default Sample~t: 0 Uncalib. Peak Response Factor: 0 Default ~ltiplier: 1 Peak Int. Ret. Signal Time Description Amount 1 W 2 W 3 VV 5 W 6 W 7 Vv 8 W 9 W 10 W 11 VV 12 W 13 W 15 W 16 W 17 W 18 W 19 W 2O W 21 W 22 W 24- PV 25 W 26 W 39.725 191.00 amu 40.374 191.00 amu 41.756 191.00 amu 42.727 191.00 amu 42.834 191.00 amu 43.155 191.00 amu 43.867 l'91'~00:aIllu 44.116 191.00 a.mu 44.739 191.00 amu 45.745 191.00 au 45.946 191.00 amu 46.238 191.00 amu 46.064 191.00 au 46.'493 191.00 amu 46.853 191.00 a~n.u 47.032 191.00 amu 47.301 191.00 a!llu 48.508 191.00 amu C27 18A HOPANE TS C27 17A HOPANE TM C28 BISNORHOPANE X C29 HOPANE D C29 NORHOPANE D2 C30 PENTACYCLANE PI C30 18A OLEANA~E C30 HOPANE G C30 MORETANE K C315 HOPANE N C31R HOPANE O O & GAMMACERANE GAMMACERANE P R C325 HOPANE U C32R HOPANE V C335 HOPANE ALPHA 48.883 191.00 amu . C33R HOPANE BETA 50.172 191.00 amu 50.748 191.00 amu 52.163 191.00 amu 52.982 191.'00 amu 27.138 217.00 amu 36.073 217.00 amu 36.729 217.00 amu C345 HOPANEGAMMA C3&R HOPANE DELTA C355 HOPANE EPSILON C35RHOPANE ZETA C2i STERANE Y C275 ba DIASTERANEi0 C27R"ba DIASTERANEll 13~&17 271782 21107 3~1298 161093 61369 " 61617 ~8.3509 228907 295713 127218 94~55 2670&9 118220 11338 3201&6 158915 206083 93208 1~18~ 56737 137158 81749 105594 96517 2.27{ % 4.599 0.3572 % 5.775 % 2.726 % 1.038 % 1.0{3 %* 8.181 % 3.873 % 5.00& % 2.153 % 1.598 % &.519 % 2.000 % 0.1919 % 5.417 2.689 % 3.~87 % 1.577 % 2.400 % 0.9601 % 2.321 % 0.6908 % 1.383 1.787 % 1.633 % Run: 2 June 11, 1990 Page ' I Paoe 56/226 Sequence: /chem/msd/052590.s Vial: 2 Injection: i Peak Iht. Ret. Signal Compound Num Type Type Time Description Name Area Amount 27 VV 37. 319 217.00 ainu 13 28 W 37.741 217.00 ainu 29 VV 37.887 217.00 amu 15 30 W 38.011 217.00 amu 31 W 38.421 217.00 amu 18 32 PV 38.702 217.00 ainu 19 33 VE 39.789 217.00 ainu 20 34 W 39. 173 217.00 amu 21 35 VE 39.264 217.00 amu 22 36 BV 39.514 217.00 amu C27R aaa STERANE 25 37 - 217.00 amu 27 38 VB 41.346 217.00 amu C28R aaa STERANE 36 39 VV 41.869' 217.00 ainu C29S aaa STERANE 39 40 W 42.868 217.00 amu C29R aaa STERANE 41 BV 39.005 218.00 amu C27R abb STERANE 21B 42 VV 39.168 218.00 ainu C27S abb STERANE 22 43 W 40.746 218.00 arau C28R abb STERANE 33A 44 VV 40.917 218.00 amu C28S abb STERANE 45 VV 42.190 218.00 ainu C29R abb STERANE 46 W 42.323 218.00 amu C29S abb STERANE 1738 0.02941% 74340 1.258 % 25607 0.4333 % 71790 1.215 % 64113 1.085 % 22332 0.3779 % 144665 2.448 % 92035 1.557 % 19667 0.3328 % 112459 1.903 % -Not Found- 108267 1.832 % 92934 1.573 % 98932 1.674 % 142~69 2.411 % 134754 ~.280 % 135350 2.290 % ~33036 2.251 % 149950 2.537 % 167489 2.834 % *** REPORT-ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 2 .. June 11, 1990 Page: 2 GMC Data..Report No. 159 Pa_qe 57/226 Al~'undance Ion 19t.00 amu. from WF4273_SAT.d ~ooo0 9000 ~o00 7000 ~oo,0 5OO0 4000 3oo,o ~_oo:0 lo00 ,,, Abundance ,. 2800' 2400. , 200~': ~6oo, 1200. ~o~ 400' 30 40 Time (min.) :[on 2_17.00 amu. fr"om WF4a73_$AT.d , V i i , , 3O i 40 Time (min.) i , I ' 50 Abundance ~ooo'.- 5000' 4000 3000" 2000'. lO00'.' Ion ~77,00 amu, from .WF4273_SAT,d 40,' 42 44 46 48 50 Time (min.) Ion ~9t,00 amu, from WF4273_SAT,d 52 54 ~bundance 1000:0 90~0 80~0 7000 6000 o0o o°"o 30~0 2o 'o lO'O0 40 42 44, 46 48 50 52 54 Time (min.) ,, .Abundance 00'00 .. 9000 8000 70,00 ~O,OO · 5d'oo ,, 40':00 - 3d'O0 - '. 20'00 - Ion 19~.00 amu. from WF4273_SAT.d ' I. ' ' ' i ', , I ' ' ~ I "' ' ' I , ' , i "i ' i , I ' ' 'I " ' '"1 '" ' " 1 36 38 40 42 44 46 48 50 52 54 Time (min.) ~ AbL~ndance ~ asoo, , , ., , ,., 2400 ,,: 2000 ,. ~200". 800 ,' 400 Ion 2i7.00 amu. from WF4273_SAT.d ~-' t ' i ......... I ..... ~ i "' ~ 38 40 T:tme (re:in.) *:+-'~ PETROLEUM GEOCHEMISTRY SARA ANALYSIS SAMPLE NAME I NSTRUIfENT INJECT TII1E METHOD USED SEOUENCE RESULT FILE REPORT TIME : BELl UIq!T ~1 10900-10940 : HPLC_FID logO z:55:40 pm : TNu May 10~ .. . /IIETHOD/HPL£_FIDO.MTH : /DATA/LOOP/SEQUENCE/HPt09O AUTOCF.SEO /RESULT/WF4274_SAP.RES 3:52 PM FRI.: ii MAY , i990 Saturates Aromatics 1 Aromatics 2 RESPONSE AREA TIME FACTOR 94715. 5.29 .1275E-0} 14908. 9.42 .5470E-04 44195. 14.~6 .5470E-04 112401. 19.96 .4160E-04 Saturates Aroma t ics POlars AMOUNT (mg) % RESIDUE 12.08 60.4 3.23 16.2 4.68-- 23.-4 Saturate5 Aromatics Polars Aspheltenes OIL 42.1 11.3 16.3 30.3 GMC Data .Report No.-159 .. .... . -.-_...-: ..:.Page.62/226 -. ~. i8i 4. 43t. ", '"' "~, .25 0,00 3.12 6.25 minutes 2.62 9,38 12,50 15,63 18,76 2i.88 SAMPLE: BELl UNIT #! 10900-I0940 25.01 ANALYZED: Thu Hay lO, 1990 3' 35:40 pm RESULT: /RESULT/WF4274 SAP.RES t4ETHOD: HPLO FIDO :+:*.-'* PETROLEUM GEOCHEM ! STRY SATURATE GC SAMPLE NAME I NSTRUMEIqT !NDECT TIME METHOD USED RESULT F!LE REPORT TIME : 8ELI UNIT,,"3~ 10900-3. _0940 : HP_5890_2 '--- 12 1990 8: 07:1 : -~t l-lay, ~ . : /METHOD/SATS890E. MTH : /RESULT/WF42Y4_SAT. RES : S:~° PM SRT 12 ' CPI UALIJE : .96 PRISTANE / PHYTANE : PRISTANE / C12 PHYTANE / C18 : 1 '~6 CIs 'CnS : .41 CI?/Pr : .5zi Cla/Ph : .24 '}. 45 N-Ci0 N-Ci1 N-C12 N-C13 N-C14 N-C15 N-C16 N-C17 N-Cia N-C19 Iq- C2 O N-C21 N-C22 N-C23 N-'C24' .... N-C25 N-C26 N-C27 N-C28 N-C29 N-C30 N-C31 N-C52 N- C 3 ~ N- C34 t4- C35 H- C ]'f., 6 AREA %AREA I'I~LI,. T I'" O. 0.0 0.00 O. 0.0 0.00 104. .5 t0.11 28~. 1.4 12.21 593. 3.0 14.18, 893. 4.5 16.04 °60 4. ~, 17 79 858. 4.3 19.44 764. 3.8 21.02 815. 4.1 22 · 657. ~. 3 23.95 564. 2.8 794. 4.0 26.62 950. 4.2 27.a8 1021 - .. 5..3- . 2.9-.0.9.... '~ 00~ 6 0 30 1191. 5.9 31.36 1096. 5.5 -32.44 1030. 5 '~ J3 ,:o 902. 4.5 34.49 283. 5.9 35.46 604. 3.0 36.40 967. 4.~, -,, - 49s 2 ¢, 3a ~5. 1407. 7.0 39. 573 . 2 . 9 40.47 595 3 O 41 .,c NORM C~.-~- ~ 0.00 0.00 .12 .}2 .66 1.00 .96 .96 .86 .91 .74 .89 1.06 1.20 1.35 1.35 1.23 1.15 !. '01 .88 LJu 1.58 .67 AREA %AREA I°°P_,,., rIME, . 109. 925 205. 17.9 221.. 3. '"' :j 7-9.7 ,_~ f.l ~ ... :3 . 2 '2. ~_. .. :... . . Y-. -.. '_ _ GMC Data Report No. 159 Page 64/226 2.45J 2.37 2.29 q~ 0 N 0 .r-'l 0~-~ r"'a cD ZDZ 2.20 2.~2 2.03 I .... , . .I J I ...... , .I , I , I 5.00 :~0.00 :~5.00 20. O0 25.00 30.00 35.00 minutes SAMPLE: BELI UNIT #:[10900-10940 ANALYZED: Sat May ~2, :[990 8: 07:13 pm RESULT: /ARCHIVE/NF4274 SAT.RES METHOD: SAT5890E 40.00 45.00 PETROLEUM GEOCHEMISTRY / GNH ROCK EUAL **~ SAMPLE : ~dELL: 8ELI UHIT ~1 DEPTH: 10940 ]:~.]ECTED AT : Fri Apr 27, i990 2:-59:02 pm INSTRUMENT : GROCI< METHOD USED : /METHOO/PYROS.MTH RESULT FILE : ?RESULT/NF4274il GRO.RES I BLANK FILE : ×RESULT/BLA~<i-5_GRO.RES AREA SLICE INTEGRATION AREA YIELD (mg/g) FRACTION '1616122. 2.~3 Si 37284296 . 2.5.19 S'2 'GMO'Data'RepOrt NO. '159" -' Page- 66/226 -- J, 3, (;7i 9,52 7, 23, ~16 3:1.28 :39,40 47. ~2 ~5.64 6:3.76 15.05. mlfluces SAHPLE: NELL.: ~EL~ UH~T tl DEPTH: 109~0 ANALYZED: Hon Ha~ 19, 1990 ~0: a9:~8 am RESULT: /RESULT/~Fa27a GTX.RES HETHOD: GTXGC~ 0 ._.J eo.oo PETROLEUM GEOCHEMISTRY / GNH PGC AUTO SAMPLE : NELL: BELl UNIT ~1 DEPTH: 10940 INOECTEO AT : Fri Apr 27) i990 2:39:02 pm INSTRUMENT : GPGC 2 METHOD USEO : /METHOD/GPGC2_O.MTH RESULT FILE : /RESULT/WF42741!_GPG.RES BLANK FILE : /RESULT/BLA~<15_GPG.RES AREA SLICE INTEGRATION AREA 4625853. 10140442. 10422142. 5401934. 1255691. 115624. TOTAL AREA : 32011692. SAMPLE WT. : 13.90 mg5 AREA PERCENT FRACTION 14.6 METHANE Dl.7 GASES 52.6 GASOLINE 16.9 KEROSENE ~.9 GAS-OIL .4 ~ .... WAX-DISTILLATE AREA ~: i0o. 0 SAMPLE GOGI = THIS IS GAS PRONE METHANE + GASES = 46.3 GASOLINE+KEROSINE+GAS OIL+WAX DISTILLATE = 53.7 BY FACTOR ANALYSIS OF KEROGEN TH Ic I'~ GAS PRI]NE THIS ANALYSIS DETERII!NES KEROGEN POTENTIAL AT ITS PRESENT MATURITY THIS 15 ~.,nT A ~/~'~'~' TVO~ ANALYSio SAMPLE K2 = 22.31 mg/gm ,.. · "GMC -Oa'.ta Report NO ":1'59:: -: --:'-:"" '-- ' .' -- :- - ' '- - "-~ - .... -Page: 68/226 - - t4.0! ii. 5.0t 0.00 . 10.00 L~O.O0 ~).00 40.00 50.00 60.00 minutes SAHPLE:HELL: "BELl UNIT 1t DEPTH: 10940 ANALYZED: Fr'i Apr, 27, 1990 2: 39:02 pm RESULT: /RESULT'/HF4274tl GPG.RES HETHOD: GP$C2 0 70.00 ~).00 Sequence: /chein/m~.d/052590. $ :. Vial: 3 Injection: 1 NOrmalized Percent Report Information from Current Data File Header: File: /chem/msd/WF427~_SAT,d Operator: Date Acquired: Fri May 25 90 09~7:1{ PM Sample Name: WFq274_SAT Misc Info: Sequence Index: 1 Bottle Number: 3 Repetition Number: 1 SAIIIRATE BIO~ARKERS Calibration Table Last Updated: Mon Jun 11 13:07:13 1990 Reference Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 01250 Absolute Minutes Default SampleAmount: 0 Uncalib. Peak Response Factor: 0 Default Multiplier: 1 Peak Num Type Int. Ret. Signal CompoUnd Type Time Description Name Area Amount 1 2 3 5 6 7 8 9 10 11 12 13 15 16 17 18 20 21 2-2 23 25 26 W W W W W W' W W W W. W W W W W W W W W PV PV .W W 39.727 191.00 amu 40.382 191.00 amu 41.76~ 191.00 amu 42.737 191.00 amu 42.841 191.00 a/nu 43.154 191.00 amu C27 1SA HOPANE TS C27 17A HOPANE TM C28 BISNORHOPANE X C29 HOPANE D C29 NORHOPANE D2 C30 PENTACYCLANE PI 43.880 191.0Oamu-" C30 18A-OLEANANE B 44.124 191.00 amu 44.746 191.00 amu 45.750 191.00 amu 45.949 191.00 amu 46.241 191.00 amu 46.481 191.00 amu 46.589 191.00 amu 46.851 191.00 amu 47.033 191.00 amu 47.310 191.00 amu 48.569 191.00 amu 48.890 191.00 amu 50.183 191.00 amu 50.743 191.00 amu 52.169 191.00 amu 52.984 191.00 amu 27.148 .217.00 amu 36.080 217.00 amu 36.735 2i7.00 amu C30 HOPANE G C30 MORETANE K C31S HOPANE N C31R HOPANE O o & E GAMMACERANE P 'R C32S HOPANE U C32R HOPANE V C33S HOPANEALPHA C33R HOPANE BETA C34S HOPANE GAMMA C34R HOPANE DELTA C355 HOPANE EPSILON C35R HOPANE ZETA C21 $TERANE Y C27S ba DIASTERANE10 C27R ba DIASTERANEll 354247 2.425 % 539297 3.692 % 51342 0.3514 % 9~7821 6.&88 % R29816 2.942 % 148773 1.0~8 % -186019 1:273-, %* 1343331' 9.195 % 297226 2.035 % 771031 5.278 % 394390 2.700 % 251711 1.723 % 209617 1.~35 % 108297 0.7~13 % 7446 0.05097 % 745294 5.102 % 395175 2.705 % 437064 2.992 % 244078 1.671 % 311345 2.131 % 133299 0.9125 % 343581 2.352 % 156913 1.074 % 264071 1.808 % 287306 1.967 % 275768 1.888 % ~{U~l: 3 Jtu~e 11, 1990 Page: i GMC Data Report No. 159 Page 70/226 Sequence: /chem/msd/052590.s Vial: 3 Injection: 1 Peak Int. Ret. Signal Compound NumType Type Time Description Name Area Amount 27 W 37.157 217.00 amu 13 28 VV 37.756 217.00 amu 14 29 ~J 37.893 217.00 amu 15 30 W 38.016 217.00 amu 16 31 W 38.426 217.00 amu 18 32 PV 38.708 217.00 amu 19 33 VE 39.794 217.00 amu 20 34 W 39.178 217.00 amu 21 35 VE 39.274 217.00 amu 22 36 BV 39.518 217.00 amu C27R aaa STERANE 25 37 W 39.673 217.00 amu 27 38 VB 41.356 217.00 amu C28R aaa STERANE 36 39 VV 41.875 217.00 amu C29S aaa STERANE 39 40 VV 42.876 217.00 amu C29R aaa STERANE 42 41 BV 39.009 218.00 amu C27R abb STERANE 2lB 42 VB 39.176 218.00 amu C27S abb STERANE 22 ~3 VV 40.757 218.00 amu C28R abb STERANE 33A ~ VV 40.924 218.00 amu C285 abb STERANE 34 45 PV 42.200 218.00 amu C29R abb STERANE 40 ~6 W 42.333 218.00 amu C29S abb STERANE 41 123028 0.8422 % 210768 1.~43 % 70387 0.R818 % 230833 1.580 % 184323 1.262 % 56052 0.3837 % 317208 2.171 % 2R4445 1.673 % 52019 0.3561 % 341431 2.337 % 96539 0.6608 % 336915 2.306 % 270364 1.851 % 271170 1.856 % 370648 2.537 % 283922 1o944 % 388182 2.657 % 371599 2.544 % 364452 2.&95 % 390193 2.671 % *** REPORT ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 3 June 11, 1990 Page: 2 GMC Data Report No. 159 Page 71/226 AbU ndance Ion ~77.00 amu. from WF4274_SAT. d 9000.., 8000~' 7000 6000': 5O00. 4000:': 3ooo";' 2000'" ,., looOi:,;, 40'. 42 kbundance 28000 - 2400',0 20000 . , t 600"0 ~2ooo : 40 , 42 ,', 44 46 48 50 52 Time (m. in .) Ion i9~,00 amu, fPom'WF4274_SAT,d 46 48 50 52 T&me (min.) Abunda'nce Ion i9~..00 amu. from WF4274_SAT.d 28000 24000 20000 16000 ~oOo soOo - 4O'0O 36 38 40 42 44 T'~me (min.) ' I ' ' i i ' ' ' I ' i 48 50 52 Abundance 9OO0 ., 8000' 70001 ,. 6oo~ - 5000' . . 4O00 ' 3oo0" - 2000: tOO' . 1 Ion 2&'.?.O0 amu. from WF4274_SAT.d 38 40 Time (min. ,. ~ Abundance o 2[300 z 2400'0 '0 - ,,, ~ 2000'0 i6000 ~.2000 - 8o0:o - ...... i Ion 19~.00 amu. from WF4274__SAT.d Ab'Undance i , ,,. , , ~ I i , I ' ' " 30 40 50 T~me (m&n.) Ion 2't'7.00 amu. fr"om WF4274_SAT.d 8OOQ:,'1 7000": ooo 5000, 4000 3oo0' lO0~ 30 40 T~me (min.) T i I j' 5O S.x~' res Aroma t Ar'omar ics :2 -Y' Po lar's RESPONSE :",.~2 ".: ,~f- ~ ~ T l ME F ACTOR !7317. 5.29 .!275E-03 6995. 9.42 .5470E-04 oox ~4 36 5470E-04 ~0649. 19.92 .4160E-04 Saturates ~roma t i cs Po lars AMOUNT (m9 ) RESIDUE 2.21 53.4 .65 _15.2 1.22' 30.9 Saturates Aromatics Polars Asphaltenes OIL 52.9 1~.6 30.6 .9 "GMC Darta'"Report No'." '15.9. '-' - ...... '-- ::- :Page 76/226 ON ~Z I---t (3,) , .... I _~ : I_ , ..... I ,, _! ,, I I ..... I,, SA~L~ E. ~I~8~ BAY ST. ~ALYZ~: Tue 'dun 12, t990 /RESULT/~F4254A S~.RES ME. OD: es ~ 11500-11600 8:; 04:~.8 am RESULT: HPLC FIDO PETROLEUM GEOCHEM [STR¥ SATURATE GC S~I-IPLE t4A~IE ! I,ISTRU[1ENT 11-.13E£T T ! I'IE IdETHOD USED RESULT FILE REF'0RT T !ME : E.id!I<;:.EL'$EN BAY STATE~I 11500-11600 : HP_5890_2 1990 1: 26. ' s-:, om : t4ed May 9~ ._ , : ,'I"IETHOD,/SAl'589gE. MTH : --"RESULT.-'WF4254_SAT. RES : 2:18 PI1 WED ; 9 MRY ., .,. CP! UALUE : .8~ PR ISTANE / PHYTANE : PRIc'T'~'~'-'c..~.n,,,_ / C12 : PHYTANE / C18 : 1.29 C1D/C25 : .~2 CI?/Pr : 1.60 =o C18/Ph : AREA %AREA NALt< T !IIE NORM N-Ct 0 N-Cll N-CI2 N-C15 H-Cf4 N-C15 N-C16 N-C12 N-ti8 N-C19 N-C20 N-C21 N-C24 N-C25 N-C26 N- C22 N-C28 N-C29 N-C30 N-C31 N-C32 N- C33 N-C34 N-C~ N-C~6 0. 0.0 0. 0.0 0. 0.0 319. 4933. 4.1 4279. 3.6 4520. 3.6 4916. 4.1 6022. ~. 0 36~6. 3. i 4008. 3240. 3.1 8604. 2.2 8221. 6.9 8242.. 6. 5704. 4.8 6209. ~ .2 5556. 4.5 4021. 5.4 ~552. ~. O 5084. 2.6 2952. 2.5 4019. 5.4 ~15~. 2.6 2280. 1 0.00 0.00 O.O0 0.00 0.00 0.00 12.20 . 14.12 1.15 16.03 1.00 12.28 1. O1 19.44 1.15 21.01 1.41 22.51 .86 ' 94 94 25.31 26.62 27 o? 1 9x 29.08 ? 11 30.25 1.95 31.37 2.14' 32.45 1.33 33.49 1.45 34.49 1.25 35.46 .94 36.41 .83 37.32 .22 38.26 .69 39.30 .94 40.29 .74 41.84 AREA %AREA ISPR TIME Fa,'nesane Ac;,:c'! ic C16 Acyc ! ic P,' istane Phs, tane 205. 2.4 13.76 1070.' ,t-2 o 15 38 1621. 19.9 18.65 3071. 36.6 19.60 ~'3~ 28.3 °i °l GMC Data Report No. 159 ''"' :-" ' '""' .... Page 78/226 3.44 3.i4 2.84 2.55 2.25 .95 5,00 iO .00 minu~es ,. I. ,. .I , I ,,, I ...... ~ ......... I l .... 15.00 20.00 25.00 30.00 35.00 RESULT' /ARCHIVE/NF4254 SAT. RES SAMPLE: E.HIKKELSEN BAY STATE#1 ilSO0-il600 ANALYZED: Ned May 9, 1990 1'26:52 pm METHOD: SAT5890E 40.00 45.00 PETROLEUM ~EOCHEMISTR¥ *** SATURATE GC SRI'IPLE t.4fq~ 1E ! NSTRUMENT !N3ECT TiME METHOD USED RESULT FILE REPORT TIME E.IIli<'.i.".ELSEI-4 BAY STATE4~i 11500-11600 HP_589 0_2 t,.~ed May c,., 19oo. 0 1:26:q';'-_ .°m /IJETHOD/SAl'589 0E . IITH /RESULT/I_,,IF4254 SAT. RES -- - . -i 9'-~0 g MA]: 2:1b: PM WEO ; , _ CP! UALI_IE : .._.°5 PR]STANE / PHYTANE : PR!STAi',;E ./ C:17 : PHYTAI'.-IE / C18 : N-CIO N-C11 N-C12 N-C13 II ~'" · N-C15 Iq-C] 6 Iq-C17 N-C18 N-CI? I,I- C2 0 N-C21 I-'4 - C i' 2 ~.-:-C23.. ;-4-6:24 Iq-C25 N-z C26 I',!-'- '" -' N-C28 N-C29 I-,l- C3 L1 I'4- C51 t,.i-C}2 N-C33 N-C34 Iq-C35 N-C36 '~_. '2q, C 1 $/C25, : . 5'-'-- z o C17/Pr : i 60 ~o ClO/ph : o AREA %AREA NALK T i!iE O. O.O 0.00 0 0 d ..] 0. :':. 0 0. [': 0 319. .3 12.20 4933. 4.1 14. 17 4275. 3.6 16.03 4320. 3.6 17.78 49 16. 4,1 19.44 6022. 5. O 21. O1 3656. 3. t 22.51 4008 =' "' ::;} Y.~ 3740. --, 1 25. ':; ~ ,. 8604 2 ~' o6 c, 2 8221. 6.~. ~217.- 82 9012. .7.5 29.08 8247. 6..9 30.25 9159. 7.6 -31:37 5704. 4.8 32.45 6209. 5.2 33.~9 5336. 4.5 34.49 4021. 3.4 35.46 3992. 3 . 0 36 . 41 3084. 2.6 32.32 2952. 2.5 38.26 4019. 3.4 39.30 3153. 2.6 40.29 228O. i .9 41.84 NORIj C O. (:0 0.00 0.00 .OY 1.15 1.O0 1.01 1.1~ 1.41 8TM . 2.01 1.93 1.93 1.33 1.45 1.25 .94 .83 .72 .69 .94 .74 AREA ~AREA ISPR TIME 205. 2.4 13.76 10.70. 12.8 !5.38 i67i. i9.9' 'i's'.~.~ 3071. 36.6 i9.~o 23.73. 28.3 21.21 'G/4C 'Data Report' No : 159;" -Page 80/226- - Sequence: /chem/msd/0&2790. s : Vial: 2R Injection: 1 Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF&25R_SAT.d Operator:. Date Acquired: Sat Apr 28 90 0R:25:39 AM Sample Name: WF~25R_SAT Misc Info: Sequence Index: 1 Bottle Number: 2~ Repetition Number: SATURATE BIOMARKERS Calibration Table Last Updated: Sun Jun 10 15:39:~7 1990 Reference Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 0.250 Absolute Minutes Default Sample Amount: 0 Uncalib. Peak Response Factor: 0 Default Multiplier: I met. signal Time Description Compound Name Amount 1 3 4 5 ..6 7 8 9 io 12 13 15 16 17 18- 20 · 21 22 23 24 25 26 VV VV VV VV VV VV VV VV VV VV VV VV VV VV W VV VV VV VV VV VV VV PV' PV PV VV 39,763 191.00 amu 40.419 191.00 amu 41,366 191.00 amu 42,771 191.00 amu 42.876 191.00 arau 4.3,187_191,.00 amu 43.851 191.00 amu 44.158 191.00 amu 441776 191.00 amu 45.781 191.00 amu 45.976 191.00 amu 46.139 191.00 amu 46.274 191.00 amu 46.502 191.00 amu 46.631 191.00 amu 47.063 191.00 amu 47.335 191.00 amu 48.536 191.00 amu 48.916 19i.00 amu 50.205 191.00 arau 50.767 191.00..amu 52.192 191.00 amu 53.019"191-~00 amu 27.180 217.00 amu 36.116 217.00 arau 36.765 217.00 amu Run: 12 C27 18A HOPANE TS C27 17A HOPANE TM C28 BISNORHOPANE X C29 HOPANE D C29 NORHOPANE D2 C30~.P.ENT. ACYCLANE PI C30 18A OLEANANE B ' C30 HOPANE G C30 MORETANEK C31S HOPANE N C31R HOPANEO O & GAMMACERANE GAMMACERANE P _ R C32S HOPANE U C32R HOPANE V C33S HOPANE ALPHA C33R HOPANE BETA C34S HOPANE GAMMA C34R HOPANE DELTA C35S HOPANE EPSILON C35R HOPANE ZETA C21 STERANE Y C27S ba DIASTERANE10 C27R ba DIASTERANEY1 June 10, 1990 168317 1,557 % 301738 2,791 % 89784 0,8305 % 472140 4.368 % 187761 1.737 % 60727 0.5617 % 2254' -0.02085 %* 873287 8.078 % 161403 1.493 % .. 475474 4,398 % 317733 2.939 % 28129 0.2602 % 59725 0.5525 % 101738 0.9411 % 17584 0.1627 % 364683 3.373 % 187203 1.732 % 257149 2.379 % 107457 0.9940 % 146214 1.353 % 59300 0.5486 % 171834 1.590 % 8-5331 0.7893 -% 166365 1.539 % 351305 3.250 % 2~8736 2.301 % Page: 1 GMC Data Report No. 159 Page 81/226 Sequence: /chem/msd/042790.s Vial: 24 Injection: Peak Int. Ret. Signal Compound NumType Type Time Description Name Amount 27 - 217.00 amu 13 28 W 37.674 217.00 amu 29 W 37.795 217.00 amu 15 30 W 37.938 217.00 amu 16 31 BV 38.388 217.00 amu 18 32 W 38.460 217.00 amu 19 33 PV 38.836 217.00'amu 20 34 W 39.108 217.00 amu 21 35 W 39.311 217.00 amu 22 36 W 39.555 217.00 amu C27R aaa STERANE 25 37 W 39.827 217.00 amu 27 38 W 41.394 217.00 amu C28R aaa STERANE 36 39 VB 41.913 217.00 amu C29S aaa STERANE 39 40 W 42.911 217.00 amu C29R aaa STERANE 42 41 W 39.049 218.00 amu C27R abb STERANE 21B 42 W 39.217 218.00 amu C27S abb STERANE 22 43 W 40.79~ 218.00 amu C28R abb STERANE 33A 44 W 40.957 218.00 amu C28S abb STERANE 34 45 W 42.236 218.00 amu C29R abb STERANE 40 46 W 42.368 218.00 amu C29S abb STERANE 41 -Not Found- 229673 2.125 239958 2.220 51822 0.4794 129052 1.194 185973 1.720 457059 4.228 409632 3.789 84340 0.7802 317534 2.937 430639 3.984 341433 3.158 259727 2.403 299177 2.768 324883 3.005 255667 ~.365 365387 3.380 336634 293070 2.711 335255 3.101 *** REPORT ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 12 Data Report No. 159 June 10, 1990 Page: 2 Page 82/226 ,, AbUndance ~ 20O00' ~000 ~6000 ~4000'- I~oo0 - ~ooo0 - 8000 . 6oo0: 400'~' 2000 Ion ~9~.00 amu. from WF4254_SAT.d 30 40 ., Time (min.) Ion 2~7.00 amu. from WF4254_SAT.d Abundance I 8000 7000 6000'- 50O0' 4000 2000 3000'1000 4O Time (min.) i Abundance · 5000 - 4000 ' · 3000 - ,- 2000 ",.~ ~000 "~ Ion 177:.00 amu. from wF4254_SAT.d "! .... I ' ' ' ' :1 40 ' Abundance ,, 20000: . ~600(~ ! 4000' !2000 ~ o000 8000 6000 4O00 2000 I I ' I ' I i I t ~ I 44, 46 48 50 52 54 Time (m&n.) Ton '19'1.00 emu. fpom NF4~54_SAT.d 40 42 44 46 48 50 52 54 ' Time (min.) ',, Ion 191.00 amu. fr'om WF;~4288__SAT.d Abundance iO00,O 8000 soO'o 4000 2000 36 38 40 42 44 46 48 50 52 TAme (m~.n.) AbUndance 8000'. , 7000' 600© 5000' ~ooO, 300~ 200© 36 ]:on 2~?.00 amu. fr'om NF4254._SAT.d 38 ' 40 T 5me (m~.n 44 46 Ab 20000 ~8000 l~O00 I4000 ~0000 undance 000 000 000' ' ',0 ..... i' '1 Abdndance Ion ~9~_,00 amu. from WF4254_SAT,d 8000' 7000 6000 5000~ 4000.'~ 3000':~ 30 .. Ion 217,00 amu. .,, . , ] , t 3O 40 Time (min.) from WF4254_SAT. d I ' ' 40 Time (rain,) i 5O PETROLEUM GEOCHEMISTRY SARA ANALYSIS SAMPLE NAME : t<UPARUK4~i >-Y~¢' - ~"~;¢'¢ INSTRUMENT : HPLC_FID INJECT TIME : l'lon Apr 16... 1990 3'46'56 pm METHOD USED '- /METHOD/HPLC_FIDO. MTH SEOUENCE : /DATA/LOOP/SEOUENCE/HP109 O_AUTOBU SEE! RESULT F!LE : /RESULT/t:JF4275_SAP. RES . . 19gO REPCIRT TIME : -4:12 PM MOI-4 ~ 16 APR ; . Saturates Aromatics 1 Aromatic$ 2 Po lar5 RESPONSE AREA T I ME FACTOR 17064. 5.29 .1225E-03 11026 . 9.42 .5420E- 04 °0546 14 36 5420E-04 30412. 19.96 .4160E-04 Saturates Aromat Po lars AMOUNT (mg) % RESIDUE 2.18 42.1 1.7.5 33.4 1.22 24 5 OIL Saturates 41.8 Aromatics 33.2 Polars 24.3 Aspha 1 t ene5 .8 GMC:Data RepOrt-NO." 159 ..... :'.".':--';--_- - -: -- .... :...- '---- - -~--Page-'88/226.-- LLJ F-- .77 .54 .. ,. i .30F 1.07!. .83L. ~ , . i t I ', f ~ ,,~. / ~.~ ._..' '~'~ '~'~- '.... ............................/ ', ....... / '- ....) ....... ._. O,O0 3.12 6.25 9.37 1~.50 i5.62 18.75 ~IRLJ~eS SAHPLE: KUPARUK~ ~ ~' - ~-¢ ANALYZED: Hon App i6, ~990 3: 4G:5~ pm RESULT: /RESULT/WF4275 SAP,RES METHOD: HPLC FIDO i .87 ;~5,00 PETROLEUil C-EOCHEI'I ! STRY '-*-'-*'--'-*- SATURATE GC .... '.: 'f"LE '- ~ i-.-~: i :.~STRUMEN'T ; N.]ECT T ! I'IE METH00 USED RESULT F!LE REPORT T!ME : HP_5890_2 : bled Ila,.., 9, 1990 4: l'Z: 1 /METHOD/SAT5890E.MTH /RESULT/t, JF4225 SAT. RES 5: 05 PM [.,.IE0.. 9 MAY pn] 1990 CPI UALUE : 1.08 PR!STAI'IE / PHYTANE PR]STANE /- PHYTANE / : '2.62 C15/C25 : : . 8=_, C17/Pr : : .40 C18/Ph : AREA .%AREA NALK TIME 109.54 1 o c:-0 NORM CiD ~xl-- ~.., 1 0 N-Cll N-C!2 N-C13 N-C14 N-C15 N-C16 N'C17 N-CI8 N-ci9 N-C20 N-C21 I',1-C24 N-C25 N-C26 N-C2? N-C28 N-C29 N-C30 N-C31 N-C52 N-C33 N-C34 N- C35 N-C3& 218. .0 5.62 15~7 1 7 oo 8925. .7 10.10 106345- 8.2 12.22 271145- 20-8 14.22 259814- 18.4 16- 07 168747. 13 - 0 1~. 82 15'0653. !1.6 19.47 119889- 9.°-- "1: . 04 88946 6.8 22.54 65236. 5.0 23.92 36309- 2.8 25.33 19732. 1.5 26.64 8606. .7 27.89 3512. .3 29.10 2i93. .2 _.50.26 "1384. . i '1222. .1 32.45 1272. .1 33.49 i364. .i 34.50 822. .1 35.47 824. .1 36.41 892. .1 57.32 675. 1 38 1276 . . 1 39.31 501. . O 40.63 415. .0 41.85 .00 .01 .04 .44 1.13 1.00 .63 .50 .27 .15 .08 .04 .01 .01 .01 .01 .01 .01 .00 .00 .00 .00 .01 .00 .00 F6 rr, e ~.ane Acyc I'i c Ac.,>.,c 1 i c C18 F'r istar, e P h,.., t e r, e AREA ~AREA ISPR TIME 63439. 15 5 13 -;',o ii6.50.1. ~ .28.5; _ i.5.....~i 5520?. 13.5 18.68 1,-,¢,,~x. 30 7 ~g 6'~ 4?92,°. 11 '7 "-,'~ '~ · . . .' 'GMC Da'ta:RePort-No '159. ' .. "-- ' '- --' - - '-.'-- :- - Page'-90/226 ..... - 0 N CZ) .ri ~ 0 ~Z 34.48 _ 27.63_ 20. '78 13. g3 minutes SAMPLE: KUPABUK-:I 5900-5950 I I ..... ~ , I ~ i .... ~ .... I , ~ ...... I 20. O0 25. O0 30, O0 35. O0 40. O0 ANALYZED: Ned May 9, 1990 4' .t3' 15 pm RESULT: /ARCH]:vE/t/'/F4275 SAT.RES METHOD: SAT5890E 45.00 Sequence: /chem/msd/0q2?90.s Vial: 19 Injection: 1 Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF4275_SAT.d Operator: Date Acquired: Fri Apr 27 90 10:38:44 PM Sample Name: WF4275_SAT Misc Info: Sequence Index: I Bottle Number: 19 RepetitionNumber: 1 SATURATE BIO~fARKERS Calibration Table Last Updated: Tue Jun 12 15:32:53 1990 Reference Peak Window: 0.250 Absolute Minutes No~-refere~ce Peak Wi~dow: 0.250 Absolute Minutes Default Sample /%mou~t: 0 U~calib. Peak Response Factor: 0 Default Multiplier: 1 Peak Int. Ret. Signal ~ Type' Type Time Description Name Area Amount 1 2 3 5 6 7 8 9 10 11 12 13 15 16 17 18 19 2O 21 22 23--- 24' 25 26 39.765 191.00 amu C27 1SA HOPANE TS 40.424 191.00 amu C27 17A HOPANE TM 41.024 191.00 emu C28 BISNORHOPANE X 42.772 191.00 emu C29 HOPANE D 42.878 191.00 amu C29 NORHOPANE D2 43.390 191.00 emu C30 PENTACYCLANE PI W"'" "'43.975'' I9'1.00 amu 'C30 '18A OLEANANE B W W W W W W W W W W W W W W VV W W VV w 44.159 191.00 amu C30 HOPANE G 44.778 191.00 emu C30 MORETANE K 45.787 191.00 amu C31S HOPANE N 45.983 191.00 amu C31R HOPANE O 46.269 191.00 amu O & GAMMACERANE 46.339 191.00 emu GAMMACERANE 46.509 191.00 amu P 46.623 191.00 amu R 47.064 191.00 emu C32S HOPANE U 47.342 191.00 emu- C32R HOPANE V 48.543 191.00 amu C33S HOPANE ALPHA 48.923 191.00 amu C33R.HOPANE BETA 50.213 191.00 amu C34S HOPANE GAMMA 50.784 191.00 emu C34R HOPANE DELTA 52.205 191.00 amu C35S HOPANE EPSILON 53.028 191.00 amu C35R HOPANE ZETA- 27.'334'' 217.00 emu - 'C21-STERANE Y 36.123 217.00 emu C27S ba DIASTERANE10 36.772 217.00 emu C27R ba DIASTERANEll 108364 254302 166878 361781 165882 20285 16407 478171 139817 26689~ 241053 48327 89~2 100079 46043 183724 124295 118174 9538~ 83725 50471 39142 1.2736. 23-5815 79225 65993 2. 140 % 5.022 % 3.296 % 7.144 % 3. 276 % 0. 4006 % 0. 3240 %, 9.443 % 2.761 % 5. 271 % 4:.760 % O. 9544 % 0. 1760 % 1. 976 % 0. 9093 % 3.628 % 2.4:55 % 2.334: % 1.884 % 1.653 % 0. 9967 % 0.7730 % 0. 2515_ % 4:. 657 % 1.565 % 1.303 % Run: 7 AMC. Ilaf~ R~nart No. 159 June 12, 1990 Page: i Page 92/226 Sequence: /chem/msd/042790.s Vial: 19 Injection: i Peak Int. Ret. Signal NumType Type Time Description Compound Name Amount 27 VV 28 VV 29 VV 30 VV 31 VV 32 33 PV 34 VV 35 36 EV 37 VB 38 W 39 BB 40 PB 41 BV 42 VV 43 PV 44 PB 45 W 46 BV 37.203 217.00 amu 13 37.675 217.00 amu 14 37.802 217.00 amu 15 37.942 217.00 amu 16 38.464 217.00 amu 18 - 217.00 amu 19 38.841 217.00 amu 20 39.113 217.00 amu 21 - 217.00 amu 22 39.559 217.00 amu C27R aaa STERANE 25 39.829 217.00 amu 27 41.386 217.00 amu C28R aaa STERANE 36 41.910 217.'00 amu C29S aaa STERANE 39 42.911 217.00 amu C29R aaa STERANE 42 39.049 218.00 'amu C27R abb STERANE 2lB 39.217 218.00 amu C27S abb STERANE 22 40.791 218.00 amu C28R abb STERANE 33A 40.961 218.00 amu C28S abb STERANE 34 42.368 218.00 amu C29R abb STERANE 40 42.236 218.00 amu C29S abb STERANE 41 30443 53488 55711 18147 48264 -Not Found- 111205 155483 -Not Found- 96013 133554 93778 69309 133040 111402 84047 90073 74823 9~123 99020 0.6012 % 1.056 % 1.100 % 0.3584 % 0.9531% 2.196 % 3.070 % 1.896 % 2.637 % 1.852 % 1.369 % 2.627 % 2.200 % ~.660 % 1.779 % 1.478 % 1.859 % 1.955 % *** REPORT ERRORS *** Calibration. Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 7 GMC Data Report No. 159 June 12, 1990 .. Page: 2 Page 93/226 ., Abundance ~91.00 amu. from WF4275_SAT. d 12000 ~0000 8000 60~),0 ,4000 ,, 2000 ~ ~ ' ' I t ""1' ~''' I I I 42 44 46 T-~me (min.) 48 5O 52 0 ~bundance Ion ~9~.00 amu. from WF4275_SAT. d 10000 80~0 6000 4000 .. 2000 0 ' ' ' I ' ' ~ i ' . . SO Abundance 5000 ooo 3000 20 O0 1ooo 0 ' Ion 2~7. O0 40 Time .(min,) amu, from WF4275_SAT,d ~ ' I ' ' ' I ' ' 30 40 Time (m-in.) ' I ' 4000 · Ion ~77.00 amu. from WF4275_SAT.d Abundance 300.0 2000 ~ lOgO ,: ' ' ' ' I i ' ', ' ''1" ':' 40 42 44' :',Abundance :1OOOO - , 80oo - 6000 , 4000 2000 ' 46 48 50 52 Time (min.) Ion ~9~.00 amu, fnom WF4275_SAT.d 40 42 44 46 48 50 52 Time. (min.) ~ Ab,Dndance ~ 3000'- 2oo0 7 ~°°0 Ion 2!7.00 amu. from WF4275_SAT.d ., 36 38 40 42 Time (min.) PETROLEUM GEOCHEMISTRY SARA AtqALYS !S SAIdPLE NAME INSTRIJIIEIqT IN3ECI' TIME IdETHOD USED SEQUENCE RESULT FILE REPORT TIME Saturates Aromatics Aromatics Polars : IIIKKELSEN BAY STATE 4~1 10564-10650 : HPLC_F ID : 14ed Ida;,: 9; !9'~0 !0:56:04 am : /METHOO/HPLC_F IOO. MTH : /OATA/LOOP/SEOUENCE/HPI090 AUTOCR.SEO -- : ,-RESULT/14F4240 SAP. RE:_=; : ll:O1 AIl WED. , o !1A¥ ... 19Y:J · . ~.. AREA TiME 23696. 5.29 33257. 9.42 56275. 14.36 12~021. 19.96 RESPONSp- FACT:OR · 1275E- 03 · E470E-n/-,~ .5470E-04 .4_~ 60E- O~ Arom~ t ice. Po lar5 AMOUNT 4.98 5 OIL ~-'- RES I n~ ~.~ 48.0 25.0 27.0 Sa t u re t es 46.=, · -l~t~ Aromatics - Po lars 26.3 ph o 4 As a ! t enes ~. GMC. Data' ·Report No~ -.1-59'- .-'. ..... . '-,' . --'-. --'- '----- -. -. ...... -.:, -- -- --Page--98/.22.6:. 6.65~ 5.37 4.09 2.8i .52 .24 0,00 m~nu~es 3.i2 6.25 9.38 !2.50 i5.63 i8.76 2i.88 25.0i SAMPLE: MIKKELSEN BAY STATE #I 10564-10650 ANALYZED: Wed May 9, 1990 t0: 36:04 am RESULT: /RESULT/WF4240 SAP.RES METHOD: HPLC FIDO *~* PETROLEUId GEOCHEMISTRY S~TURATE gC SAMPLE NAME INSTRUMENT INJECT TildE METHOD USED RESULT FILE REPORT TIME : MIKI<ELSEN 8AY STATE ~1 10564-10650 : HP_5890_2 : Sun May 6 ,, 1990 8: 49: 16 am : /METHOD/SAT5890E.IdTH : /ARCHIUE/bJF4240 SAT. RES : 4:08 PM TUE. , 12 JUNE, 1990 CPI UALUE : .92 PRISTANE / PHYTANE : PRISTANE / CI? : PHYTANE / Ci8 : .86 C15/C25 : .53 .58 C17/Pr : 1.22 .57 C18/Ph : 1.76 N-Ci0 N-Cll N-C12 N-C15 N-C14 N-C15 N-C16 N-C17 N-C18 N-C19 N-C2O N-C2i N-C22 N-C25 N-C24 N-C25 N-C26 N-C2? N-C28 N-C29 N-CS0 N-CS1 N-C52 N-C55 N-C54 N-C55 N-C56 AREA ~AREA NALK TIME 0. O.0 0.00 146. .0 7 82 694. .2 10.10 2252. .6 12.21 5657. 1.5 14.18 11602. 5.0 16.04 17177. 4.5 17.79 25645. 6.1 19.45 279~8. 7:5 21-. 02 .. 27958. 7.2 22.52 29181. 7.6. 25.95 25896. 6.7 25.52 27617-. 7-.2 26.65 25125. 6.5 27.89 26166. 6.8 29.09 22045. 5.7 50.25 25841, 6,2 51.57 . 14514. ~.?" 32.45 14556. 5.7- 55.49 12768. 5.5 54.49 9757. 2.5 55.46 7826. 2.0 '56.41 6667. 1.7 57.52 6124. 1.6 58.26 . 7759' '2'. 0 59.50 4818. 1.2 40.48 4171. 1.1 41.84 NORM C15 0.00 .01 .06 .19 .49 1.OO 1.48 2.04 2.41 2.41 2.52 2.25 2.58 2.17 2.26 1.90 2.05 1.23 1.24 1.lO .62 .57 .42 AREA ~AREA ISPR TIME Farnesane Acyclic C16 'Acyclic C18' Pr-istane Phytane 708. 1.8 15.27 2505. 6.5 15.59 5916,' --- 15.5-' - 18-. 66 15715. 55,4 19.60 15860. 41. O 21.22 GMC 'Data" Report 'No. '159 '7 :-'--': · .: -'-' '-': -'. Page 100/226 O~ ~Z 5 96 5 i3 4 30 3 48 2 65 82 .... 5 O0 minutes ~0.00 i5.00 20.00 25.00 30.00 35.00 RESULT: /ARCH]:VE/HF4240 SAT. RES SAMPLE: MIKKELSEN BAY STATE #1 10564-].0650' ANALYZED' Sun May 5, ].990 8' 49' :1.6 am METHOD: SAT5890E J 40.00 45.00 , .r_:P.U_.E_I,, C, EOCHEI'I]STF.'Y / Gl-iH ROE!( FU.~L .~:*.~: ..... ~._ - ,(l-.'~', c-:st_, B.~Y C:l-1 DEPTH: 1065'! .. ] :'~.3EC:TEE: -~.T : .."1on Mat:; .';'.. !9'~0 2: 38: 54 arn .... -f .... ,~ !'lETHE:E) USEr: : /1'1[: THUb:,-P ~ Ru 5 ..MTH - ~,:., ,T -: ~=-~o.';08 r'r:.l-I RES F:'ESI ILT F ! LE : · ,- ....,_,--..' ~,, , --,. -- --, _ ~_'~1 \ _~. -- ~'* ~>-',~:" ¢- ! LF ' /F.'ESIJLT 'P.~ '"'~'q;~ -~ ¢-' "-; .... : ,,_.~,, -..~ _,_-.F.' -_, ~.!.- '.:: ~-' . ~ FRACT I OI--,' AREA YI,_.,_O rr.,-~g.-'S . ":704182 I. 16 Si -' '~'-' S2 S.~IqF'LE biT. :8q-,. .5'-',~ mo=_..~ Trna>: : .444 C GMC. Data .Repo..r.t' No..,,1.59 .... . . :..PAge_.10g/'.226. ...... **~:-.~ PETRFILEUM. _ C.;E,-,,-'u~-,-' l STR]',_,,__., ,=,, -.' LT!qH PFqC_ AUTO APEA ARER PERCENT '-'79 15144 12 4 358793 12. 16.3 5oo¢.0800 2-¢ 8 59674024. 22.1 2?5.94004.. 12 . 5 1P262392. 7.9 TNT,",- AREA : 919875710 SAMPLE WT. : 89.53 mgs -AREA ~: 100.0 . SAMPLE GOGI = .40 THIS IS GAS + OIL PRONE METHANE + GASES = 28.7 GASOLINE+KEROSINE+GAS OIL+WAX DISTILLATE = 71.3 FRACTION METHANE GASES GASOLINE KEROSENE GAS-OIL WAX-DISTILLATE DY FACTOR ANALYSIS OF KEROGEN PYROLYSATE THIS IS A GAS+OIL SOURCE - THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT ITS PRESENT MATURITY. THIS IS NOT A KEROGEN TYPE ANALYSIS. SAMPLE i<2 = 3.2! rog/gm .... , .... . GNC Data Re:port. No..-159 --- -;-- -. -- ~- . - :'- ,- .-.. Page-1.037226 - II 0.00 . ~lnutes RESULT: ~o.oo ao.oo ~o.oo · SAMPLE: 10651 ' . ANALYZED: ')ion May /RESULT/WF42408 GPG.RES , 40. O0 SO. O0 GO. O0 ?0. O0 80. O0 7, 1990 2:38:54 am METHOD:' GPGC2 0 ~quence: /chem/msd/OS[390.s . .. Vial: 86 Injection: Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF4240_SAT.d Operator: Date Acquired: Sun May 13 90 01:18:03 PM Sample Name: WF4240_SAT Misc Info: Sequence Index: 1 Bottle Number: 86 Repetition Number: 1 SATURATE BIOMARKERS Calibration Table Last Updated: Tue Jun 05 07:56:00 1990 Reference Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 0.250 Absolute Minutes Default Sample Amount: 0 Uncalib. Peak Response Factor: 0 Default Multiplier: i Peak Int. Ret. Signal Time De$criptio~ Amount I VV 2 VV 3 VV 4 VV 5 VV 6 W- 7 W 8 VV 9 VV 10 VV 11 VV 12 VV , 13 VV 15 16 VV 17 W 18 VV 19 VV 20 VV 21 PV 22 W 23- VV 24 W 25 PB 26 W RtLn: 1 39.785 191.00 amu 40.440 191.00 amu 40.744 191.00 amu 42.779 191.00 amu 42.877 191.00 arau 43-:193-191vOO-amu 43.808 191.00 amu 44.155 191.00 amu 44.771 191.00 amu 45.771 191.00 a_mu 45.964 191.00 amu 46.095 191.00 amu 46.255 191.00 amu 461484 191.00 a_mu - 191.00 amu 47.046 191.00 amu 47.318 191.00 amu 48.518 191.00 amu 48.892 191.00 amu 50.177 191.00 amu 50.739 191.00 amu 52...163 191..00 amu 52.985 191.00 amu 27.228 217.00 amu 36.144 21.7.00 amu 36.788 217.00 amu C27 18A HOPANE TS C27 17A HOPANE TM C28 BISNORHOPANE X C29 HOPANE D C29 NORHOPANE D2 C30-PENTAC¥CLANE Pi C30 18A OLEANANE B C30 HOPANE G C30 MORETANE K C31S HOPANE N C31R HOPANE O O & GAMMACERANE GAMMACERANE P R C32S HOPANE U C32R HOPANE V C33S HOPANEALPHA C33R HOPANE BETA C34S HOPANE GAMMA C34R HOPANE DELTA C35S HOPANE EPSILON C35R HOPANE ZETA C21 STERANE Y C27S ba DIASTERANE10 C27R ba DIASTERANEll JLule 5, 1990 451079 1.501 % 1028221 3.422 % 105649 0.3516 % 1507821 5.019 % 494744 1.647 % 138028 0.4594 % 28086 0.09348 %* 2212684 7.365 % 1515412 5.044 % 1022838 3.404 % 552441 1~839 % 1491041 4.963 % 189188 0.6297 % 262529 0.8738 % -Not Found- 724165 2.410 % 352405 1.173 % 433329 1.442 % 151962 0.5058 % 230496 0.7672 % 75209 0.2503 % 269829 0.8981 % 114061 0.3796 % 840517 2.798 % 1015418 3.380 % 811215 2.700 % Page: 1 Sequence: /chem/msd/051390.s Vial: 86 -. Injection: 1 Peak Iht. Num Type Type Ret. Signal Time Description Compound Name Area Amount 27 W 28 VV 29 W 30 W 31 w 32 33 W 34 W 35 W 36 W 37 W 38 W 39 W ~0 W 42 W 43 VV 45 PV 46 W 37.222 217.00 amu 37.694 217.00 amu 37.818 217.00 amu 37.957 217.00 amu 38.475 217.00 amu - 217.00 amu 39.076 217.00 arau 39.121 217.00 amu 39.326 217.00 amu 39.571 217.00 amu 39.848 217.00 amu 41.393 217.00 amu 41.920 217.00 amu 42.913 217.00 amu 39.063 218.00 amu 39.237 218.00 amu 40.807 218.00 amu 40.967 218.00 amu 42.242 218.00 amu 42.372 218.00 amu 13 14 15 16 18 19 20 21 22 C27R aaa STERANE 25 27 C28R aaa STERANE 36 C295 aaa STERANE 39 C29R aaa STERANE 42 C27R abb STERANE C275 abb STERANE 22 C28R abb STERANE 33A C285 abb STERANE 34 C29R abb STERANE 40 C29S abb STERANE ~l 408541 774278 802436 209791 620592 -Not Found- 516024 1.718 783777 2.609 253537 0.8439 746074 2.483 1217367 4.052 715033 2.380 596722 1.986 645886 2.150 110647.4 3.683 913855 °3.042 1030700 3.431 955882 3.182 803298 2.674 925427 3.080 1.360 2.577 2.671 0.6983 2.066 -. *** REPORT ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 1 June 5, 1990 Page: 2 C~M~ Data Report No. 159 Paae 106;226 Abundance Ion 77. O0 amu. from NF4240_$AT. d 20000 ~6000 J2000 8000 400'0, t ..... ~ 40 42 44 46 48 50 52 ,, Abundance 5000'0 - 40000 30000 ~ ;.~ 00 00 ~000.'0 ~ 40 Time (min.) Ion ~9t.O0 ainu. from WF4240__SAT, d 42 44 46 48 50 T:tme (m~n.) _A ,-.____ 58 54 Abundance 500010 - , . 4OO0O .,,' 3OO0O - ,,,, ., 20000 ... ,. ~0000 Ion ~9~.00 amu, 36 38 40 42 fpom WF4240_SAT. d '" I ' ' 'i ' ~', ' I 44 46 Time (min.) ! ""'1'" ' , ' j 48 50 52 28000 " ,. 24000 ,j' 2O000 ~6000 .. 2oOo 8 0~0 0 ,. 4000 ' Abundance Ion 217,00 amu, from WF4240__SAT,d 38 40 T_"tme (m~n.) 44 Abundance 5oooO 1 4O000 soooo - 2ooo.0 lO000 Abundance 28ooo 1 , EO000 1 16oO'o . ~200'0 800,0 4O0'O 0 Ion ~.9~..00 amu. fr"om WF4240._SAT.d I i' 4O Time (min.) [on 2~7.00 amu. fPo~ NF4240_SAT,d i i ' i , i ' 30 40 ' Time (min.) i 1 j J .... 5O SAMPLE NAI'IE I ~._,, RUI ,EI.T l N.] EC T T 1 !-1E METHOD USEI] SEOUENCE RESULT FILE REPORT TIIIE PETROLEUM GEOCHEMISTRY SARA ANALYSIS / : MII<I<ELSEN 8AY STATE t~?m/ : HPLC_FIO : l'lon Apr ].6. 1990 ii:)3:ii am : /METHOD/HPLC_FIDO.llTH : /DATA×LOOP/SEOtJENCE/HPi090_AUTOBU.SEQ : /RESULT/WF424i SAP.RES : ii:se Am ~loN.. 16 APR.~ 1990 AREA TIME Sa t u rat es 49088. 5.29 Aromat ic-=. 1 24525. 9.42 Aromatics 2 50.°-49. O~ F'o lars ~o686. i9.96 RESPONSE FACTOR .1275E-03 .5470E-04 .5470E-04 .4160E-04 Saturates Aroma t ~ cs Po tars AMOUNT (mg) % RESIDUE 6.26 44.7 4.1~ 29.5 ~.61 25.8 Saturates Aroma t i cs Po lars Aspha I tenes OIL 42.1 22.8 24._~ " ..... ' GMc""Data R~p0'rt ' NS' 159"" "':-: "P'age iil/2'26-' Z 0 k--. 4.5J. 3.70 2.89 2.07 '0 ! 1.26 , ,o ., . , ....... ~ ............. ~ ( ..... l ~ ............ - m5 res SAHPLE: NIKKELSEN ~AY STATE /5 ~ ~ /5~¢/' ANALYZED: Mon Apr 16, 1990 1~:33: tl am ~ESULT: /~ESULT/WF4241 S~P.flES METHOd: HPLC FIDO PETROLEUM GEOCHEIq!STRY **-~ SATURATE GC SAMPLE blAME I NSTRUMEI-,IT IN.]ECT T!ME METHOD USED RESULT FILE REPORT TIME : MII{KELSEN 8AY STATE ~! 11650-11701 : HP 5890 2 : bJed !'18,y 9; 1990 ?:35'35 am : /METHOO/SAT5890E. MTH : /RESULT/LdF4241 SAT. RES . . 19°0 : 8:22 AM L. IEO 9 MAY ; ,. CPI UALUE : PRISTANE / PHYTANE : PRISTAi','E / Ci? : PHYTAIqE,' Ci°,_. : .89 C15/C25 : .40 .55 C17/Pr : 1.8_5. .63 C18/Ph : !. 59 AREA %AREA NALK TIME N-CiO 118. N-Cll 0. N-C12 102. N-C13 274. N-C14 363. N-C15 705. N-C.16 1176. N-C17 1485. N-C18 1450. N-C19 1427. N-C20 13988. N-C21 1230. N-C22 1979. N-C23 1814. N-C24 1410. N-C2D 1747. N-C26 1735. N-C27 1342. N-C28 3203. N-C29 2322. N-C30 2381. N-C31 2150. N-C32 3125. N-C33 1662. N-C34 1896. N-C35 2591. N-C36 104!. NORM C15 .2 5.98 .17 0.0 0.00 0.00 .2 10.09 .14 .5 12.20 .39 . ? 14.18 .52 !. 3 16.04 1.00 2.2 17.79 1.67 2.8 1'9.45 2.11 2.8 21.02 2.06 2.7 22.92 2.02 26.5 23.95 19.84 2.3 25.32 1.74 3.8 26.63 2.81 3.4 27.89 2.57 2.2 29.10 2.00 3.3 30.26 2.48 3.3 31- '38 2.46 2.6 32.46 1.91 6.1 33.49 4.54 4.4 34.50 3.29 4.5 35.48 3.38 4.1 36.52 3.05 ~. 9 37.41 4.43 3.2 38.27 2.36 3.6 39.32 2.69 4.9 40.31 3.62 z. 0 4~ . 86 1.48 AREA ~AREA ISPR TIME F~rnesane 0. r .... '~ 19 - Ac'Jc 1 ia ~io _ - Acs, clic C!8 741. Pr' i 5 i ar,.e 813. Ph: ,+ e,-,e 9 14 0.0 0.00 -8 !- 15.39 · 22. E, i8.66 30.3 19.60 34. O 21.22 ....... GMc O~'ta RePo'rt NO. 159'"" ' 'Page' 1137226' '- 2.931' 2.74 2.56 o N 0 .r'-I 0 ~ 2.37 2.19 2.00 ........ ~ I , I . I I . , . I , I ., ..I .., ....... I 5, O0 tO. O0 tS. O0 20.00 25.00 30. O0 35.00 40.00 m~nutes SAMPLE: M]:KKELSEN BAY STATE #1 :[1650-11701 ANALYZED: Ned Hay 9, 1990 7: 35:35 am RESULT: /ARCHTVE/NF4241 SAT.RES METHOD: SAT5890E 45.00 · *-~-*-* PETROLEUM I~EOCHEMIC'TRY / -"' ' · I_-:,l-: F,:L-IC:i:'. ~--~ '~L + '~ + SiqI'IPLE : t,.IELL:Iq~'I ..... ELESEI'.-! F__:RY STi DEPTH: 11650 - ,o90 3.:'):3: 3~ I H.]ECTEO AT : t:led I'ia:-- i4; -- ,. - _ pi'..': I NSTRUMEI'4T : GROCK IqETHOD I ISE©_ : ./['IFTurir'', , ,_,:...../P""I;'['I~:. . , ..u ;, . !1] H t-- ~--" '~ .... RESULT F ! LE : .,.-'F..'. .... u,_T.--'I.,.IF4'24 ~ _¢;F..'FI. R'E'--...; BL.,qN.t( F I LE : /RESULT/BLP. I'.IF.'i3_GF;:Q. RES AREA SLICE INTEGRATION AREA YIELD (rog,'9 ) FRRCTIOI-,i 10663102. .90 S1 17604020. 1.48 S2 SAMPLE '~T. : 14.9'0 mgs Tmax : 441C . '-' '"" ' 6MC""D~t'a' Re DOrt'NO'-"1-59 :'" -- -- ' -'-" ' "-- --' '" Page' --1'1-5/226'" - _.J o. N 4.g7 minutes RESULT: 3t. 28 39.40 47.5~ SANPLE: tt650-!t70t FT. 'ANALYZED: Hed Hat' J. 4. !990 /RESULT/HF424! GTX.RES NETHOD: 55.64 63.76 7i.8~ 80.00 3: ~8: 3t pm GTXGC! 0 S~I'IPLE : b]ELL:MII<I,'.ELESEN B~'~' ST i DEPTH:Il?01 [N;1ECTED AT : bled Mar 14. 1°'-~0,. 3:'--'°:31:,_-. _ c, rr, I NSTRIJ,~iENT : GPGC 2 '¢~ "P- '"-'-"-' _ I'ITH METHOD USED : /i'IETHO-., ~Fo~ O. RESULT FlEE : /RESUL?/U~':'~;:i,. ,~,=_~ GPG ~ E',L~NI,. FILE : ./RESULT./BL~I'i!( 4 GPG RES AREA SLICE INTEGRATION AREA AREA PERCENT FRACTION 2242929. 9.1 METHANE 2112594. 8.6 GASES 4555792. 18.5 GASOLINE 2448619. 9.9 KEROSENE -4283725. 17.4 GAS-OIL 8962218. 36.4 ~AX-DISTILLATE TOTAL AREA : 24609384. AREA ~: lO0.O SAMPLE WT. : 14.90 mgs -. SAMPLE GOGI = .22 THIS IS OIL PRONE METHANE + GASES = !7.7 GASOLINE+KEROSINE+GAS OIL+WAX DISTILLATE = 82.3 13Y FACTOR ANALYSIS OF I<EROGEN PYROLYSATE THIS IS AN OIL+GAS SOURCE THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT ITS PRESENT MATURITY. TH!S IS NOT A t<EROGEN TYPE ANALYSIS. CAI,1PLE._,....l.,"n = I . '=8 mo./om GMC',Data'. Repor't No" 159 ..... ...... .-:---'. - ..... : -. ,-: -:: . Page, 117/226- 6.00 4.64 , RESULT: ~o.oo 2.00 sm.oo 4o.oo r>o.oo ~.oo SAMPLE: HELL: MIKKELESEN BAY ST ! DEPT~. ~70! ANALYZED: Wed Mar !4. ~990 3: 28: 3! pm /RESULT/WF424! 6PS.RES METHOD:. GPSC2 0 70.00 80.00 Sequence: /chem/msd/042790.s Vial: 16 Injection: Normalized Perce~t Report Informatio~ from Curre~t Data File Header: File: /chem/msd/WF~2~l_SAT.d Operator: Date Acquired: Fri Apr 27 90 07:08:51 PM Sample Name: WF4241_SAT Misc Info: Sequence Index: I Bottle Number: 16 Repetition Number: 1 SATURA/~ BIOt4ARKEB~ Calibratio~ Table Last Updated: Sun Jun 10 13: 29: ~ ~ 1990 Reference Peak Window: 0.250 Absolute Minutes Nom-refere~ Peak Window: 0. 250 Absolute Minutes Default Sample Amoumt: 0 U~calib. Peak R~e Factor: 0 Default F~tltiplier: 1 Ret. Sig~l Amount I W --2 W 3 VV ~ W 5 W 6 W 7 W 8 VV 9 W 10 W 11 W 12 VV 13' VV 14: W 15 W 16 VV 17 VV 18 W 19 W 2O W 21 W 22 W 23 25 26 39.873 191.00 amu C27 18A HOPANE TS 40.529 191.00 amu C27 17A HOPANETM 40.839 191.00 amu C28 BISNORHOPANE X 42.876 191.00 amu C29 HOPANE D 42.970 191.00 amu C29 NORHOPANE D2 43.286 191.00 amu C30 PENTACYCLANE PI 43.904 191.00 amu C30'18A OLEANANE B 44.25~ 191.00 amu C30 HOPANE G 4{..862 191.00 amu C30 MORETANEK 45.864 191.00 amu C31S HOPANE N G6.059 191.00 amu C31R HOPANE O 46.203 191.00 amu O & GAMMACERANE 46.3~9 191.00 amu GAMMACERANE 46.583 191.00 amu P 46.689 191.00 amu R 47.138 191.00 amu C32S ~OPANE U 47.407 191.00 amu C32R HOPANE V 48.601 191.00 amu C33S HOPANE ALPHA- 48.981 191.00 amu C33R HOPANE BETA 50.280 191.00 amu C34S HOPANE GAMMA 50.840 191.00 amu C34R HOPANE DELTA 52.283 191.00 amu C35S HOPANE EPSILON W .... 53,107 191-,-00 amu C35R HOPANE ZETA-.. PV 27.309 217.00 arau C21STERANE Y VV 36.223 217..00 amu C27S ba DIASTERANE10 VV 36.868 217.00 amu C27R ba DIASTERANEll 1230306 4.262 % 1211994 4.198 % 138622 0.4802 % 2340028 8.106 % 1195233 4.140 % 260172 0.9012 % : 52~25 0:1816 %* ' 3255565 11.28 % 315608 1.093 % 1715658 5%943 % 1266776 4.388 % 178112 0.6170 % 365362 1.266 % 2G2671 0.8~06 % 109755 0.3802 % 1288667 4.464 % 807688 2.798 % 711523 2.465 % 464381 1,609 % 4G5196 1.5~2 % 249878 0.8655 % 481385 1.667 · 270590_ 0.9.373 % 1014032 3.512 -% 736564* 2.551 % 523537 1.81-3 % Run: 4 June 10, 1990 Page .... ~,_,.. n .... * ~,^ ~co Pan~ .t19/226 Sequence: /chem/msd/042790.s Vial: 16 Injection: Peak Imt. Ret. Signal NumType Type Time Description Compound Amount 27 VV 28 PV 29 VV 30 W 31 BV 32 PV 33 34 VV 35 VV 36 W 37 VV 38 W 39 VV 40 VV VV W BV VV 37.305 217.00 amu 13 37.641 217.00 amu 14 37.777 217.00 amu 15 37.900 217.00-a mu 16 38.487 217.00 amu 18 38.763 217.00 amu 19 - 217.00 arau 20 39.162 217.00 amu 21 39.329 217.00 amu 22 39.659 217.00 amu C27R aaa STERANE 25 39.812 217.00 amu 27 41.480 217.00 amu C28R aaa STERANE 36 42.005 217.00 amu C29S aaa STERANE 39 42.996 217.00 amu C29R aaa STERANE 42 39.152 218.00 amu C27R abb STERANE 2lB 39.324 218.00 amu C27S abb STERANE 22 40.889 218.00 amu C28R abb STERANE 33A 41.054 218.00 amu C28S abb STERANE 34 42.329 218.00 amu C29R abb STERANE 40 42.462 218,00 amu C29S abb STERANE 41 240640 0.8335 % 291315 1.009 % 385622 1.336 % 391764 1.357 % 195168 0.6760 % 4321 0.01497 % -Not Found- 411078 1.424 % 486893 1.687 % 316528 1.096 % 143566 0.4973 % 259618 0.8993 % 446895 1.548 % 349794 1.212 % 795468 2.755 % 627755 o2.174 % 634866 2.199 % 598863 2.074 % 669532 2.319 % 748038 2.591 % *** REPORT ERRORS *** . Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** Run: 4 GMC Data Report No. 159 June 10, 1990 Page: 2 Page ~20/226 7ooo0 ooo0 : 50000 4000'0 soooo EO00.O :0000 Abundance ,. Abundance ,,. E4000 - ooo0 :600'0 ~200'0 ,: 800.0 O00 ,,, ,0 ,.' Ion 191.00 amu. from WF4241_SAT.d ' ' I 3O i ' i '1 j i 4O Time (min.) Ion 217.00 ~mu. from ~F4-,241~AT.d ' I ' i I ' ' 3O 40 50 Time (min.) Abundance ,, 70000'.. ,. . '., 6ooo0..' 50000 40000 . ,, 30000' 20000 ~ ~0000 ; 36 38 Ion ~9~.00 amu. from HF4241_SAT.d 40 ,42 44 46 48 50 Time (min.) ",' s I " , - t -i 52 54 Abundance · .. · . 18000 14000 aooO ,1_ 000,0 ,. 8000 ,. ,,, oo0 , 400'0 ,, 2000 Ion 217.00 amu. from WF424i_SAT.d 38 40 42 T::i. me (m:in.) ,$ '1 II Ii I III II ~l I ~ 44 Abundance 24000 - ' . 20000 6000 ~2000 8000' 4000 Ion 177.00 amu. from WF4241_SAT.d 7OOO0 40 42 44 46 48 50 Time (min.) Ion ~9~.00 amu. from WF4241_SAT.d Abundance 60000 5000.0 4000'0 , ~ooo0 20000 ~0000 52 54 40 42 44 46 48 50 52 54 Time (min.) So..quence: /c[lent/m~d/OR 2790 Vial: 16 Injection: 1 : Ion 177.00 amu. from WFR241_SAT.d WF4241_SAT Peak# Ret Time Type Width 1 39.096 BV 0.056 2 39.215 W 0.084 3 39.885 W 0.129 4 40.142 W 0.061 5 40.220 W 0.067 6 40.505 W 0.090 7 40.853 VI/ 0.064 8 41.032 W 0.107 9 41.382 W 0.071 10 41.796 BV 0.064 1I 42.321 PV 0.074 12 42.436 W 0.077 13 42.875 W 0.071 14 42.971 W 0.067 15 43.166 W 0.066 16 43.653 W 0.080 17 44.096 BV 0.067 18 44.254 W 0.072 19 45.862 PV 0.064 20 46~058 W 0.065 21 ~7.138 ' 'BB 0.'055 22 47.407 BV 0.060 23 ~8.599 BV 0.065 Area 83363 220819 513711 57982 9~583 236420 79855 324838 55738 45279 99238 1551~2 938769 748390 78991 261164 39501 269336 137999 77~89 9952~- 6~689 57567 Start Time 39.013 39.128 39.689 40.068 40.182 40.414 40.780 40.933 41.303 41.734 42.215 42.371 42.764 42.926 ~3.102 43.559 4~.011 44.157 ~5.979 ~7.018 ~7.296 ~8.500 End Time 39.128 39.290 40.068 40.182 40.299 40.616 40.933 41.193 ~1.499 41.881 42.371 42.526 42.926 ~3.102 43.236 43.876 44.157 ~4.351 ~5.979 46.169 ~7.220 47.497 48.683 Ion 191.00 amu. from WF4241_SAT.d WF4241jAT · Peak# Ret Time Type Width 1 22.091 BV 0.073 2 22.604 VB 0.066 3 22.890 W 0.066 4 23.084 W 0.069 5 23.321 W 0.075 6 23.482 W 0.067 7 2~.~86 BV 0.06~ 8 25.156 W 0.070 9 25.870 W 0.068 10 26.092 W 0.075 11 26.241 W 0.079 12 26.455 W 0.067 13 27.071 PV 0.068 14 27.201 W 0.060 15 27.304,. W 0j069 16 27.682 PV 0.057 17 28.004 PV 0.064 Area 79958 39099 105338 71302~ 1098~1 78371 88381 1050905 105816 69237 86770 53ool ~98670 46887 6'5315' 31505 328665 Start Time 22.013 22.464 22.805 22.967 23.203 23.~09 2~.3~9 25.029 25.779 26.010 '26.168 26.361 26.965 27.157 27.253 27. 565 27.903 End Time 22.249 22.697 22.967 23.203 23.~09 23.563 24.581 25. 376 25. 971 26.168 26.361 26.585 27.157 27.253 27. 383 27.727 28.095. GMC Data Report No. 159 May 2, 1990 Page- Page !2.5/226 Sequence: /chem/msd/O42790.s Vial: 16 Injection: 18 28.727 19 29.123 20 29.253 21 29.538 22 29.925 23 30.409 24 30.894 25 30.981 26 31.045 27 31.220 28 31.402 29 31.667 30 32.507 31 32.728 32 33.172 33 33.314 34 33.551 35 33.947 36 34.391 37 34.522 38 35.099 39 35.459 40 36.241 41 36.440 42 36.560 43 36.869 44 37.316 45 37.695 46 37.762 47 38.106 48 38.356 49 38.452 50 38.914 51 39.157 52. .39.455 ~ 53 39.873 54 40.052 55 40.220 56 40.528 57 40.839 58 41.126 59 41.463 60 41.803 61 42.140 62 42.424 63 42.604 64 42.700 65 42.876 66 42.970 67 43.286 68 43.473 6'9 43.65'2 70 44.254 71 44.412 BV BV W W VV W W BV W W W PV BV W W VB BV VV W VV W BV BV W W VV W W VV VV W W VV W VV W VV W VV W W VV W W W VV VV 0.062 0.064 0.071 0.073 0.058 0. 068 0.061 0.051 0.079 0.070 0.072 0. 072 0.079 0.111 0.063 O. 074 0.084 0.068 0.067 0.065 0.096 0.086 0. 067 0.061 0.074 0.060 0.O67 0.070 0.065 0.071 0.068 O. 057 0.073 0.087 0..077 . 0.083 0.085 0.092 0.077 0.131 0.106 0.085 0.105 0. 077 0.119 0.087 0.065 0.072 0.068 0.084 0.071 0.097 0.072 0.079 156~88 54744 2974534 77103 ~20757 ~924067 72597 57252 135510 50334 248862 87834 86942 1815827 120504 61055 191579 798658 603169 617074 54021 107215 253372 135039 75283 63659 90625 157103 170623 511785 534246 70490 175911 970990 756.665 1370899 121807' 201256 1306258 246946 821031 485062 278509 148688 320403 295457 131946 2347573 1201128 264045 113495 328119 3246431 312286 28.623 29.037 29.145 29.449 29.841 30.268 30.805 30.931 30.994 31.151 31.295 31.545 32.418 32.590 33.087 33.249 33.409 33.839 34.279 34.454 35.021 35.233 36.152 36.353 36.511 36.723 37.229 37. 573 37.728 37.966 38. 251 38.432 38.824 38.994 39.364 39.625 39.996 40.115 40.302 40.655 40.945 41.380 41.626 42.070 42.22O 42.515 42.669 42.770 42.932 43.202 43.389 4-3.530 44.060 44.349 28.813 29.145 29.~49 29.648 30.003 30.615 30.931 30.994 31.151 31.295 31.545 31.766 32.590 32.945 33.249 33.409 33.644 34.058 34.454 34.689 35.225 35.550 36.353 36.511 36.723 36.963 37.449 37.728 37.836 38.205 38.432 38.528 38.994 39.364 39.625 . . 39.996 40.115 40.302 40.655 40.945 41.279 41.626 41.882. 42.220 42.515 42.669 42.770 42.932 43.102 43.389 43.530 43.-762 44.349 44.488 IRu/~: 4 May 2, 1990 GMC Data Report No. 159 Page 126/226 Sequence: /chem/msd/042790<s 72 44.566 VV 0.073 73 44.715 VV 0.065 74 44.862 W 0.081 75 45.162 VV 0.069 76 45.494 W 0.095 77 45.864 VV 0.076 78 46.059 W 0.094 79 46.350 W 0.103 80 46.583 W 0.086 81 46.689 W 0.068 82 47.138 VV 0.079 83 47.407 W 0.079 84 47.687 W 0.068 85 47.835 W 0.082 86 47.988 W 0.097 87 48.373 W 0.110 88 48.601 W 0.071 89 48.752 W 0.082 90 48.981 VB 0.078 91 49.400 PV 0.067 92 50.280 VV 0.084 93 50.841 BV 0.094 94 52.283 BB 0.105 95 53.107 BB 0.108 96 54.729 BB 0.111 Vial: 16 303038 100765 302921 67888 95547 1677298 1396854 336490 215411 84231 1224538 747O53 57334 131088 120471 109420 657215 86681 390812 71O54 384903 222692 491471 237383 62885 44.488 44.'652 44.783 45.094 45.410 45.639 45.962 46.281 46.496 46.663 46.966 47.295 47.583 47.746 47.921 48.267 48.507 48.700 48.866 49.310 50.173 50.692 51.989 52.908 54.553 Injection: 1 4~.652 44.783 44.967 45.229 45.639 45.962 46.281 46.496 46.663 46.807 47.295 47.583 47.746 47.921 48.148 48.507 48.700 48.866 49.217 49. ~95 50.443 50.981 52.557 53.294 54.889 Ion 217.00 amu. from WF4241_SAT.d WF4241_SAT Peak# 1 2 3 5 6 7 8 9 10 11 12 13 15 16 17 18 19 2O Ret Time Type Width 22.243 W ..... 0...066 22.535 PV 0.099 23.267 W 0.069 24.224 W 0.082 24.785 PV 0.082 25.161 W 0.064 25.270 W 0.068 25.446 W 0.063 25.715 PV 0.067 26.107 W 0.113 26.302 W 0.068 26.387 W 0.057 26.527 W 0.060 26.647 W 0.085 26.879 W 0.078 27.031 W 0.068 27.309 PV 0.071 27.505 'W .... 0.080 ':' 27.660 W 0.064 27.807 W 0.091 Area 126460 '~' 83600 41941 51418 99791 40686 69338 55875 460051 388985 181593 58673 34834 166588 40144 36345 1012214 -408549 ..... 22744' 51836 Start Time 22.172 22.438 23.132 24.148 24.652 25.092 25.211 25.370 25.6O4 25.978 26.226 26.365 26.473 26.566 26.801 26.961 27.167 -- '27~390 27.615 27.720 End Time 22.373 22.685' 23.369 24.358 24.889 25.211 25.370 25.534 25.882 26.226 26.365 26.473 26.566 26.801 26.961 27.167 27.390 27.593 27.720 27.924 Run 4 C-HC Data Report No. 159 Page 127/226 -abed 'Z86'L~ ~OL'L~ O~'L~ O00'Le 9££'9£ LIg'9e 900'9£ 9Lg'S£ L0£'~£'- ISZ'S£ 00£'~£ S96'e~ S0£'~ 96S'£~- SS~'Z~ S06'0£ S£L'0£ S9S '0£ 96£ 'OC 600'0~ £8S'6Z £S~'$Z 980'6Z ZgL'SZ Lzg'sz :uo~oa~ui £0L'£~ S6~'£~ 0Ig'L[ 9~Z'Le 000'L£ 9LL'9£ SZS'9£ LI9'9~ 6Z0'9~ 9LL'S£ S~9'S~ 9L9'S£ £66'9~ 00£'~£ S96'~ SOL'~ ££0'~ 009'Z~ 009'I~ SS~'l~ 890'I~ I9L'0C 96£'0~ EEZ'0~ 99L'6E £8S'6E LS~'6Z S~'6~ 68L'SZ 066T . . . IESS6S 008£0~ '-81969~: SI906£ I909S ~S916 SE090I EL9019 9~£68L LII6S I9890I SOOSII 9~£0~ . 6~09~I 0L6LS 96~SII 9I~£S IL066 gLI0~ 86SE. S 8L000Z £08E0~ OSE9E S9S9Z I~90~ AE90£ ~t9 S6£~II 60~f8~ 9~S£~ £68STE SZS08 098E~ OSIOEI ~£T'0 AA 8~I'8E SL0'0 AA 6~0'8£ ~L Z80'0 AA 006'££ .EL ~gO"O -'AA LLL"L£ IL 860'0 AA 099'LE 0L 890'0 AA TSP'L£ 69 S80'0 AA S0~'L~ 89 990'0 AA I£I'££ L9 ££0'0 AA 690'L~ 99 080'0 AA 898'9£ S9 ~ZT'0 AA 9Z9'9£ 99 0£0'0 AA Z99'9~ ~9 S90'0 AA Zg£'9E Z9 690'0 AA £~Z'9£ I9 E£0'0 AA ~EI'9£ 09 S80'0 AA 616'S£ 6S t90'0 AA 6~8'S£ 8S 9L0'0 AA £0L'S£ £S 080'0 AA- 6£S'S£ 9S S.S0~0 - AA. 89Z.~.S£ . SS £60'0 AA EgT'S~ ~S £80'0 AA ZTL'~£ ~S S£0'0 AA £9£'9£ ZS 9£0'0 AA S6~'9£ IS ~90'0 AA I90'9~ OS EL0'0 AA 098'££ 69 £S0'0 AA 99&'£~ I90~0 AA S99'££ 860'0 AA E~S'££ 99 660'0 AA SEZ'££ S~ I80'0 AA 8EA'Z£ ~60'0 AA S6I'Z£ Z60'0 AA ~00'~£ 6S0'0 AA 698'I~ I90'0 AA £99'I£ 09 090'0 AA Z8S'I£ 6£ I80'0 AA S~'T~ S90'0 AA 6LI'I£ E90'0 AA I90'~£ 9£ IL0'0 AA ~Z0'I~ IL0'0 AA g~8'0~ LLO'O AA 6~9'0£ ~g0'0 AA ~'0£ ~g0'0 AA .~L£'0~ 9£0'0 AA 9~g'6g 0~ 880'0 AA 8~9'6~ 6E 6S0'0 AA 0£S'6~ S80'0 AA 9~'6~ gII'O ~ I88'8~ 9~ 0g0'0 ~ 669'8E SE IOT'0 ~ 89~'8~ I80'0 ~ 9g~'~Z g90'0 ~ ESI'SE IL0'0 ~ 990'8E 9I :Ie!A s'06LZ~O/psm/u]aq3/ :oouanba$ .- Vial: 16 Sequegce: /chem/lnsd/042790.s 75 38.487 W 76 38.555 W 77 38.762 W 78 38.941 W 79 39.162 W 80 39.217 W 81 39.329 W 82 39.549 W 83 39.659 W 84 39.812 W 85 39.934 W 86 40.112 W 87 40.234 W 88 ~0.383 W 89 40.594 W 90 40.669 VV 91 40.879 W 92 41.055 W 93 41.150 VV 94 41.171 W 95 41.253 W 96 41.480 VV 97 41.819 VV 98 42.005 VV 99 42.328 W 100 42"459 W 101 42.740 W 102 42.869 W 103 42.996 W 104 43.138 ~ 105 43.288 W 106 43.529 W 107 43.636 W 108 44.254 PV 0.078 0.094 0.048 0.126 0.058 0.067 0.078 0.066 0.081 0.080 0.116 0.080 0.080 0.092 0.098 0.064 0.O89 0.O86 0.023 0.023 0.100 0.111 0.079 0.125 0.086 0.085 0.077 0.072 0.091 0.076 0.083 0.063 0.088 0.072 322128 465348 47432 850740 500725 633586 599499 170925 461133 239091 881029 124420 265822 327536 419781 202796 780388 546013 48894 48906 466393 434809 173077 615298 641482 54831 72064 383239 123480 72234 148355 216853 85904 . . 38.387 38.522 38.723 38.775 39.078 39.182 39.277 39.484 39.579 39.731 39.827 40.065 40.I68 40.300 40.463 40.647 40.753 40.978 41.140 41.163 41.186 41.380 41.739 41.881 42.2:05 42.397 42.694 42.796 42.907 43.093 43.224 43.426 43.574 44.108 Injection: 1 38.522 38.723 38.775 39.078 39.182 39.277 39.402 39.579 39.731 39.827 40.065 40.168 40.300 40.463 40.647 40.753 40.978 41.140 41.186 41.380 41.623 41.881 42.205 42.397 42.577 42.796 42.907 43.093 43.224 43.426 43.574 43.765 44.350 . _ Ion 218.00 amu. from WF4241_SAT.d WF4241_SAT Peak# Ret Time Type Width 1 35.184 W 0.055 2 35.574 W 0.068 3 35.701 W 0.062 ~ 35.919 W 0.083 5 36.108 W 0.070 6 36.227 W 0.072 7 36.343 W 0.053 8 36.397 W . . 0,074 .... 9 36.619 W 0.130 10 36.865 W 0.083 11 37.065 W 0.079 Area 20589 34359 25963 100419 73741 216779 30747 .. 475.71 12788'6 199505 85311 Start Time 35.082 35.475 35.6~0 35.779 36.018 36.157 36.303 3.6.374 ~ . 36.522. 36.776 36.995 'End Time 35.273 35.640 35.779 36.018 36.157 36.303 36.374. 36.522 36.776 36.958 37.136 Run: GMC Data Report No. 159 May 2, 1990 Page: Page i29/226 Sequence: /chem/msd/O42790.s Vial: 16 Injection: 1 , 12 13 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 4O 42 43 45 48 49 50 51 52 53 54 55 37.155 W 0.049 24026 37.136 37.277 W 0.096 131123 37.198 37.487 W 0.082 34190 37.396 37.558 W 0.065 70462 37.497 37.644' W 0.074 97255 37.597 37.776 W 0.088 215281 37.697 37.899 W 0.066 144600 37.844 38.033 W 0.092 302224 37.941 38.148 W 0.104 463497 38.089 38.492 W 0.078 99423 38.391 38.601 VV 0.109 279742 38.507 38.844 W 0.091 205246 38.708 38.944 VV 0.098 277182 38.887 39.152 W 0.080 861447 39.065 39.324 W 0.073 676020 39.257 39.429 W 0.060 129070 39.401 39.551 W 0.055 87983 39.497 39.662 W 0.083 270185 39.579 39.806 W 0.062 212718 39.730 39.874 W 0.052 191760 39.828 39.934 W 0.079 306181 39.897 40.138 VV 0.063 64987 40.073 40.229 VV 0.081 137083 40.167 40.357 W 0.084 130389 40.298 40.597 W 0.104 298240 40.441 40-668 W- 0.070- 9.1694- 40..658 40.889 VV 0.082 691462 40.756 41.054 W 0.076 641311 40.973 41.252 W 0.097 565191 41.141 41.476 W 0.088 165600 41.381 41.564 W 0.088 137826 41.525 41.822 W 0.087 146294 41.703 41.909 W 0.049 61538 41.880 42.056 W 0.116 314326 41.940 .42,329 .=V3; ...0.0-75 705655 .... ,. 42.198 42.462 W 0.080 777956 42.394 42.720 W 0,077 47654 ' 42.677 42.870 W 0,073 41328 42.801 42.997 VV 0.093 200645 42.916 43.125 VV 0.074 56638 43.099 43.293 W 0.074 49870 43.225 43.534 PV 0.069 148721 43.420 43.631 VV 0~077. 171421 43.578 44.257 PV 0.076 135626 44.045 37.198 37.396 37.497 37.597 37.697 37.844 37.941 38.089 38.391 38.507 38.708 38.887 39.065 39.257 39.401 39.497 39. 579 39.730 39.828 40.073 40.167 40.298 40.441 40.658 40.756 40.973 41.141 41.381 41.525 41.703 41.880 41.940 42.198 42.394 42,582 42.801 42.916 43.099 43.225 43.420 43.578 43.739 44.369 Run: 1'990 -.. Page: "6 GMC Data Report No. 159 Page ]30/226 SAMF'LE Iq~ME i NSTRUI-1ENT !Iq.]ECT T!fl[ METHOD USED SEOUENCE RESULT F!LE REPORT TIME Saturates Aroma t ~ cs Aroma t i cs Po lars **".+- PETROLEUM GEOCHEMISTRY SARA AIqALYS ICd RAU I,~1,'-' x : HPLC_F ID I'lon Apr 16; 1990 10:52:17 am /I'IETHE:D/HPLC_F ! DO. MTH /DATA/LOOP/SEO. UENCE/HPi090 AUTOBU. /RESULT/L, JF4232_SAP. RES : 11:12 AM MOI,I.,. 16 APR. ~ 1790 AREA TIME 23065. 5.29 2612. 9.42 15896. 14.36 49191. 19.96 RESPONSE FACTOR .1275E-03 .5470E-04 .5470E-04 .4160E-04 Saturates ~romat~cs Polars AMOUNT (mg) % RESIDUE 2.94 46.9 1.29 20.5 2.05 32.6 Saturates Aromatics Polars Asphaltenes OIL 39.2 17.4 15.3 GMC..Data Repo.r.t No....!59 Page - !3.:1/2.26 2.85 2.98 .92 ~.46 t .00 .53 0,00 mlnu[es RESULT: · ......... .-.u ....1 .... , .... ! ......~ ........ !_-.---~ ! .__~.._ I _ .--~__~L-.-...-__~----! ...... ~.----- 3.12 6.25 9.38 i2.50 15.63 i8.76 21.88 SAMPLE: RAVICK z~,-~o'-z~,-,~" ANALYZED: Iqon Apr' 16, ~.990 ~.0: 52:17 am /RESULT/~/F4237 SAP.RES METHOD: HPLC FIDO 25,01 PETROLEUM GEOCHEMISTRY SATURATE GC SAIIPLE NAI'IE INSTRUMENT I N.]ECT TIME METHOD USED RESULT FILE REPORT TIME : ,q.:R'JIK STATE 4.*-1 2t~60-2650 : HP 589 O 2 : Tue il,au 8 1990 7:~1:09 orr, : /METHOO/SAT5890E.MTH : ..-'RESIJLT/LdF4237_SAT. RES : 8:2~,_ PM TUF_. ,.. 8 MAY .: lg.~O I.CPI UALUE : .73 PRISTANE / PHYTANE : PRISTANE / C17 : PHYTANE / C]8 : .71 C15/C25 : .6_=., C!7/Pr : .28 C18/Ph : Ol 1.60 N-CiO N- C11 N-C12 N-Cl.3 N-C14 N-C15 N-C16 N-C17 N-C18 N-Cl9 N-C20 N-C21 N-C22 N-C23 N-C24 N .-C25 . N-C26 N-C2? N-C28 N-C29 N-C~0 N-CS1 N-C52 N-C55 N-C54 N-C55 Iq-C}6 AREA %AREA I-IALK TIME 174. . ! 550. .1 2080. .8 4985. 1.9 .7725. 5.0 10852. 4.2 15558. -- 5.5 1590i. 6'2 i;'819. 7. o :' 17570. 6.° 19055. 7.4 16 048. 6.5 16505. 6.4 15477. 6.0 15055. 5.9 .15545 .... 5.....2.. ...... · 12649. 4.9'- 8856. 5.5 9629. 5.8 7558. 2.9 5684. 2.2 4081. 1.6 5845. 1.5 4555. 1.7 6294. 2.5 5284. 1.~ 5566. 1.5 5.85 -~ 88 ; . 10.11 12.21 14.19 16.04 17.79 19.45 21.05 22 .'53 25 25.52 26.64 22.89 29.10 30.26 ._ '51'i ~ 8 52.45 35.49 54.50 55.47 56.41 ./.35 38.27 59.51 40.50 41.85 NORM .02 .19 .46 .22 1.00 1.25 1.47 1.64 1.62 !. 26 1.48 1.52 1.4:5 1.59 1.23 1.17' .82 -89 .68 .52 .38 .35 .58 .30 .31 AREA %AREA ISPR TIME Farnesane ~cyc I lC' Ct'~ Ac.wc I ic C18 Pt- istane Ph?t ane 3236. 8-.8 -'4256-. ..... 11.9 5401. 14.2 9955. 27.1 1~0o %7.0 15.78 1-5.-. ~.9 18.67 ~o 61 o1 GHC Data Report No. 159 page--~D:3/226: ~z 4.69 4.i3 3.58 3.02 2.46 ~.. 90 , ,, ! , 5,00 ~0.00 m~nutes 15.00 20.00 RESULT: /ARCHIVE/WF4237 SAT. RES I I ,I ~ I ,~,,, I 25.00 30.00 35.00 40.00 SAHPLE: RAVIK STATE #t 2560-2650 ANALYZED' Tue Hay 8, ~990 7'3t'09 pm ~4ETHOD: SAT5890E 45.00 PETROLEUM GEOCHEMISTRY / GHH ROCK EVAL *** SAMPLE : WF4237 INOECTEO AT : Mon Apr 16~ 1990 i1:51:18 pm INSTRUMENT : GROCI< METHOD USED : /METHOD/PYROS.MTH RESULT FILE : /RESULT/WF42371O_GRO.RES 8LANK FILE : /RESULT/BLA~<i3_GRO.RES AREA SLICE INTEGRATION AREA YIELD (mg/g) FRACTION 9~455312. 528722990. 4.09 S1 5.46 S2 SAMPLE WT. : 44.80 mgs Tmax : 441C' GMC Data Report No. 159 Page 135/226 _ N 7.31 6.67 5.84 4.36 tS.OS. 23.t$ '~ 3:t.28 3:9.40 47.52 55.64 63.76; 7t.88 minutes SAI4PLEi HELL: RAV;[K STATE DEPTH: 2650 ANALYZED: lion liar' 19, 1990 3: 38:28pa RESULT: /RESULT/HF4237 I sTX,RES 14ETHOD: $TX6Cl 0 PETROLEUM GEOCHEMISTRY ? GNH PGC AUTO SAMPLE : WELL: RAUIt< ST ~1 DEPTH: 2650 INOECTED AT : Mon Apr 16, 1990 11:51:12 pm INSTRUMENT : GPGC_2 METHOD USED : /METHOD×CGPG2_0.MTH RESULT FILE : ?RESULT/WK4257i0 GPG.RES BLANK FILE : /RESULT/BLANKiS_GPG.RES AREA SLICE !NTEGRATION ***** AREA AREA PERCENT FRACTION 4082455. i6.6 METHANE 6?05502. 22.5 GASES ??28040. 51.5 GASOLINE 475~055. i9.4 KEROSENE 1255421. 5.i GAS-OIL 0. 0.0 WAX-DISTILLATE TOTAL AREA : '245'2>426.- AREA ~:~' ~00.0 THIS IS -'.SAS PRONE METHANE + GASES = 44.0 GASOLINE+KEROSINE+GAS OIL+MAX DISTILLATE = 56.0 TH I'.'~ ,- ..... , .,IS r,C'ETER;'!,' INES ""'-'-"-"~'-"' PK~TEI'-'.TM ,-.r_r.,._-m~'_,'-~ . _- : :AL .z,.i !TS · - .=' ,.,,-,T --. ~--'.'..E?O~-.?.:i-.N TYPE '- .... ",! :-"~-' PRESENT "':" ~ '~ i T ~ . T" '-' '_--; ?., ,-,-~. ~ 2'-Ii '~n__ t ~, S ~ ;P~, : ._;r~.. , , . ~ - -- -'-~ -:: '- - :~-- Page- t3//226- , :GMC 'Data Repo'rt-.No~'-159.' -. ".... .... ." ' _ , ~6.t6 X ~ iO ?.7~~ 30.00 0.00 . t0.00 20.00 , SAMPLE.' WELL: RAVIK ST ~! DEPTH: 2650 ..ANALYZED: Non Apr i6, 1990 ~: 5~: ~7 pm RESULT: /RESULT/NF4237tO GPG,RES METHOD: CGPG2 0 I * I I * ...... 1 ........ I i il i l1 * -~ 40.00 ~0.00 60.00 70.00 80.00 .Seq,.tertce: /chem/m.3d/042790. $ Vial: 15 Injection: . . Normalized Percemt Report Informatio~ from Curre~t Data File Header: File: /chem/msd/WF4237_$AT.d OPerator: Date Aoqu~ed: Fri Apr 27 90 05:58:24 PM Sample Name: WF4237_SAT Misc Info: Sequence Index: 1 Bottle N[tmbe_r: 15 Repetiti°~Number: SATURATE BIOMARKERS CalibratiomTable Last Updated: Sun Jun 10 13:14:59 1990 Reference Peak Window: 0.250 Absolute Minutes No~-refere~ce Peak Wind0w: 0.250'Absolute Minutes Default ~___-~,_le Amount: 0 ~calib. Peak Respomse Factor: 0 Default Multiplier: I Peak Iht" Ret. Signal Time Description 1 ~Z 3 5 6 7 8 9 10 11 12 1.3 14: 15 .16 17 18 19 20 21 22 -23' .. 25 26 . - W W W · · . W UV W 39.821 191.00 amu 40.481 191.00 amu 4:0.805 191.00 amu 42.829 191,00 amu 4:2.930 191.00 amu 43.245 191.00 amu C27 18A HOPANE TS C27 17A HOPANE TM C28 BISNORHOPANE X C29 HOPANE D C29 NORHOPANE D2 C30 PENTACYCLANE PI 43. 853 191.0'0 ainU' C30 '18~ OLEANANE 'B' 44.211 191.00 amu 44:~826' 191.00 amu 45.831 191.00 atm,t 46.025 191.00 amu 46.327 191.00 amu 46.414: 191.00 amu 4:6.548 191.00 a.mu C30 HOPANE G C30MORETANEK C315 HOPANEN C31R HOPANEO O & GAMMACERANE GAMMACERANE P - 191.00 a~u- R - 4:7.110 191.00 amu C325 HOPANE U 47.385 191.00 amu-- C32R HOPANE V 48.585 191.00 amu C335 HOPANE ALPHA 48.966 191.00 amu C33R HO~ANE BETA 50.263 191.00 amu C34:S HOPANEGAMMA 50.823 191.00 amu 'C34:R HOPANE DELTA 52.266 191.00 amu C355 HOPANE EPSILON W.- 53.-074 .191..00-a mu C35R.-HOPANE ZETA. PV 27.224 217.00 amu - C21STERANE Y . W 36.168 217.00 amu C275 ba DIASTERANE10 W 36.817 217.00 amu C27Rba DIASTERANEll 4:36997 3.334: 500812 3.821 98004 0.7477 529787 4.04:2 4:85321 3.703 180528 1.377 :'35165 0.2683'%* 860006 6.561 209273 1.597 341675 2.607 4:59379 3.505 73263 0.5589 984:32 0.7509 199225 1.520 -Not Found- 332316 2.535 184:780 1.4:10 209889 1.601 161172 1.230 137825 1.051 77181 0.5888 113097 0.8628 49600 0.3784 290956 .. 2.220 % 498291 3.801 % 383983 2.929 % :. Run: 3 June 10, 1990 Page: cN~r n~-~ I;',~nnY-f Nh_ 159 Page ]39/226 Sequence: /chem/msd/042790.s Vial: 15 Injection: 1 Peak Int. Ret. Signal NumType Type Time Descriptiom Compound 27 28 W 29 W 30 W 31 32 33 PV 34 W 35 W 36 VV 37 W 38 VV 39 VV 40 VV 42 W 43 VV 45 BV 46 37.251 217.00 amu 13 37.595 217.00 amu 37.726 217.00 amu 15 37.851 217.00 amu 16 38.438 217.00 amu 18 - 217.00 amu 19 38.889 217.00 amu 20 39.112 217.00 amu 21 39.273 217.00 amu 22 39.612 217.00 amu C27R aaa STERANE 25 39.889 217.00 amu 27 41.443 217.00 amu C28R aaa STERANE 36 41.972 217.00'amu C29S aaa STERANE 39 42.965 217.00 amu C29R aaa STERANE 42 39.100 218.00 amu C27R abb STERANE 39.271 218.00 amu C27S abb STERANE 22 40.846 218.00 amu C28R abb STERANE 33A 41.016 218.00 amu C28S abb STERANE 34 42.287 218.00 amu C29R abb STERANE VV 42.417 218.00 amu C29S abb STERANE 41 170857 1.303 % 195003 1.488 % 271305 2.070 % 326853 2.494 % 152571 1.164 % -Not Found- 459485 3.505 % 216221 1.650 % 294489 2.247 % 297485 2.270 % 551536 4.208 % 256883 1.960 % 281423 2.147 % 251845 1.921 % 470405 3.589 % 362466 . 2.765 % 402194 3.068 % 395301 3.016 %- 376884 2.875 % 427679 3.263 % *** REPORT~ *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not Ail Calibrated Peaks Found *** .. Run: 3 GMC Data Report No. 159 _ June 10, 1990 Page: 2 Page i40/226 Abundance ~oooo. ~ . ~oo0' i ~oo0 :]:on 19~.00 amu. fr'om WF4237_SAT.d ~oo0 4000' · , .,, Abundance ." ,. ~2000 '. ~oooO :, 800~ , 6000 .. 400'0 ',~ 30 ~, 40 T~Lme (min.) ., ]:on ~.7.00 emu. fr'om NF4~_37_.SAT.d ,. 30 i 40 T::tme (min.) ~ ~8ooO..' ~6000' ~4000. , t2OOQ , . ~,0000 ,. 8000 6000 4000 , 2000 .,, Ion 191.O0 amu. from WF4237_SAT.d Abundance , 36, 38 40 42 .,. ,', Time (min.) 46 48 50 52 Ion 217..00 amu. from WF4P37_SAT,d Abundance .. 12000:' - , ~oo00. 8000.: ~00'0 ,: 4000 2000 36 38 40 42 44 Time (min.) AbundanCe 8000:. 6000, 4000 ~oo6 0000'.. 8000 6000 400~'. 2000 40 42 ,, Ab'u ,, 1800~ 16000, :400© 12000 ~000~ aooo 600'0' 4000 2000 0 ~dance 40 42 Ion _~77,,'.00 amu. from WF4237_.SAT.d 44 46 48 Time (min.) Ion 191.00 amu. from WF4237_SAT.d 50 52 44 46 48 50 52 Time (min.) Sequence: /chem/msd/042790.$ Vial: 15 Injection: 1 · Ion 177.00 emu. from WF4237_SAT.d WF4237_SAT Peak# Ret Time Type Width Area 1 39.156 BV 0.088 122224 2 39.868 W 0.128 278588 3 40.180 pv 0.070 293453 4 40.466 BV 0.066 76961 5 40.810 W 0.064 56460 6 40.982 W 0.087 957794 7 41.751 PV '0.096 161255 8 42.393 W 0.071 462360 9 42.824 W 0.067 206132 10 42.928 W 0.078 192132 11 43.612 W 0.078 172141 12 44.058 PV 0.075 196718 13 44.240 W 0.074 174442 14 44.708 BV 0.093 126381 15 45.384 BB 0.063 98330 16 45.652 BV 0.060 57017 17 46.891 BB 0.072 63230 · . Ion 191.00 amu. from WF4237_SAT.d WF4237_SAT Start Time End Time 39.012 39.232 39.668 40.016 40.016 40.278 40.367 40.593 40.731 40.883 40.883 41.157 41.594 41.911 42.298 42.498 42.739 42.881 42.881 43.075 43.512 43.727 43.829 44.140 44.140 44.354 45.299 45.4~6 45.562 45.720 46.762 47.017 Peak# 1 2 3 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 2O .... . . 21 22 23 Ret Time Type Width 22.333 BB 0.061 23.004 PV 0.067 25.070 BV 0.064 26..380 -..PV 0-.059- 26.990 BV 0.066 27.933 BV 0.063 28.657 BV 0.054 29.171 W 0.071 29.852 BH 0.071 30.331 BV 0.064 30.981 W 0.089 31.331 BV 0.073 32.651 BV 0.091 33.487 PV 0.085 33.881 PV 0.068 34.325 BV 0.063 34.459 W 0.065' 36.182 BV 0.072 36.391 VV 0.075 37.274 W 0.083 37.641 W 0~060" ' 37.718 W 0.069 38.052 PV 0.062 Area Start Time End Time 265200 22.214 22.438 162480 22.886 23.121 190199 24.943 25.168 .--59778- 26.287 26.481 98466 26.893. 27.076 98011 27.831 28.004 51203 28.538 28.758 881102 28.953 29.376 37796 29.773 29.935 607147 30.209 30.588 62209 30.868 31.059 80800 31,24~- 31.518 602359 32.541 32.885 54178 33.327 33.552 248626 33.781 34.005 229128 34.209 34.393 226671 34.393 34.630 136979 35.981 36.305 52044 36.305 36.461 74494 37.143 37.363 · '6~1'65 '3 ....... 37.501' : ''37266T 100792 37.661 37.784 238337 37.942 38.148 Run: 3 May 2, 1990 _ .. Page GMC Data Report No. 159 Page t45/226 Sequence: /chem/msd/042790.s Vial: 15 Injection: 24 38.299 PV 0.064 204469 38.148 25 38.868 W 0.078 109524 38.792 26 39.~08 W 0.085 387598 38.962 27 39.406 W 0.067 313558 39.329 28 39.822 PV 0.084 460331 39.579 29 40.177 VB 0.083 79530 40.081 30 40.478 BV 0.075 456536 40..344 31 40.801 PV 0.095 71428 40.610 32 41.082 W 0.093 468758 40.900 33 41.423 W 0.070 209651 41.325 34 41.760 VV 0.070 ~00766 41.660 35 41.847 VV 0.059 48271 41.818 36 42.097 W 0.074 119785 42.013 37 42.392 BV 0.072 516473 42.267 38 42.568 VV 0.075 132477 42.487 39 42.682 W 0.071 74220 42.626 40 42.828 W 0.069 483995 42.741 41 42.930 W 0.084 453411 42.882 42 43.245 VV 0.078 146685 43.155 43 43.441 PV 0.075 61342 43.342 44 43.614 VV 0.079 140121 43.499 45 43.970 BV 0.068 56426 43.911 46 44.039 W 0.060 40864 44.022 47 44.211 W 0.075 788596 44.100 48 44.527 W 0.079 99909 44.445 49 44..689 PV 0.075 68589 ..... 44.622 50 44.826 W 0.070 167417 44.753 51 45,831 BV 0.076 325186 45.614 52 46.026 PV 0.098 397257 45.938 53 46.327 W 0.062 55083 46.262 54 46.398 W 0.077 74080 46.354 55 46.549 VV 0.115 134435 46.477 56 47,110 W 0.086 268787 46.942 57 47.384 W 0.078 145901 47.282 58 .. .48.348. W 0.:...0.91.. .10~61.4 ...... 48.22~ 59 48.585 W 0.068 160996 48.494 60 48.966 W 0.077 92158 48.841 61 50.263 BB 0.076 85147 50.177 62 50.823 BV 0.077 48192 50.702 63 52.266' BB 0 098 103751' 52.015 38.375 38.962 39.255 39.579 39.954 40.282 40.610 40.900 41.247 41.595 41.818 41.923 42.181 42.487 42.626 42.741 42.882 43.155 43.342 43.~99 43.726 44.022 44.~00 44.328 44.622 44.753 44.934 45.938 46.262 46.354 46.477 46.799 47.251 47.552 48.494 48.664' 49.072 50.502 50.936 52.471 Ion 217.00 amu. from WF4237_SAT.d WF4237_SAT Peak# Ret Time Type i 22.175 PV 2 24.154 BV 3- : .... 24.739 PV '"' 4 25.090 W 5 25.194 W . Width o.055 0.055 0-. I02 '0.054 0. 067 Area 25911 13259 "30855 11943 28592 Start Time 22.090 24..082 .... -~ '- 24:589 25.013 25.127 End Time 22.256 24.248 -24.838' 25.127 25.299 GtqC Data Report No. 159 1990 Pa?e: Page i46/226 Sequence: /chem/msd/042790.s Vial: 1S Injection: 1 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 35 36 37 38 39 50 51 52 53 55 56 57 58 59 25.373 PV 0.061 25.636 BV 0.067 26.037 VV 0.100 26.220 W 0.077 26.311 W 0.057 26.450 W 0.062 26.569 W 0.072 26.822 W 0.067 26.944 W 0.068 27.224 PV 0.067 27.429 W 0.077 27.735 VV 0.079 27.988 PV 0.070 28.102 W 0.060 28.235 W 0.080 28.401 W 0.081 28.805 BV 0.099 28.937 W 0.064 29.252 BV 0.073 29.573 PV 0.100 29.747 W '0.064 30.294 W 0.050 30.352 VV 0.084 30.561 W 0.072 30.763 W 0.067 30.947 'W 0.057 31.276 W 0.093 31.507 W 0.055 31.583 W 0.065 31.936 W- 0.092 32.142 W 0.100 32.649 W 0.065 33.157 W 0.092 33.463 W 0.093 33.598 W.. ..... 0.061.-... 33.688 W 0.063 33.799 VV 0.077 33.973 PV 0.053 34.136 PV 0.064 34.655 BV 0.066 35.123 VV 0.097 35.274 W 0.080 35.524 W 0.075 35.657 W 0.093 35.781 W 0.066 35.869 W 0.076 36.058 VV 0.054 36.168 W' 0.079 36.365 W 0.031 36.414 W 0.062 36.554 W 0.119 36.8i7 ' 'vV ........0.078' 37.019 W 0.070 37.134 W 0.070 ~7076 lq4598 119186 62149 14677 18347 61332 19092 17790 289776 157300 18161 47088 10891 27918 41282 551i6 12664 24233 240970 '45034 15620 32782 15006 15445 13351 44703 12156 29287 70021 73678 12079 46777 20680 13789 39813 17167 46216 17588 76272 20687 62-567 62181 26759 57407 22738 577699 14076 34932 124959 63042 72550 25.299 25.526 25.905 26.146 26.294 26. 387 26.497 26.727 26.880 27.093 27.310 27.655 27.845 28.061 28.159 28.318 28.711 28.913 29.171 29.383 29.669 30.220 30.309 .30.495 30.652 30.872 31.174 31.418 31.520 31.846 32.057 32.588 32.940 33.324 33.53.0 33.648 33.738 33.896 34.059 34:588 34.838 35.196 35.402 35.587 35.734 35.811 35.999 36.075 36.345 36.382 36.464 '-36~696 36.948 37.071 25.661 25.769 26.146 26.296 26.387 26.497 26.727 26.880 27.093 27.310 27.522 27.845 28.061 28.159 28.318 28.551 28.913 29.024 29.383 29. ~69 29.858 30.309 30.495 30.652 30.839 30.976. 31.418 31.520 31.688 32.057 32.274 32.761 33.290 33.530 33.648 33.738 33.896 34.059 34.263 '34.784 35.196 35.318 35.587 35.734 35.811 35.976 36.075 -36.365 36.382 36.46~ 36.696 ~'36'968 -" -' 37.071 37.i69 Run: GMC Data Report No. 159 'May 2, 1990 '- " ~"' Page: Page !47/226 Sequence: /chem/msd/O42790.s Vial: 15 Injection: i 60 37.251 W 0.095 228976 37.169 37.363 61 37.418 W 0.062 40794 37.363 37.456 62 37.595 VV 0.095 266614 37.456 37.656 63 37.726 W 0.067 323192 37.656 37.781 64 37.851 W 0.088 398888 37.781 37.939 65 37.985 W 0.076 129441 37.939 38.037 66 38.105 W 0.130 387894 38.037 38.335 67 38.438 W 0.068 232122 38.335 38.468 68 38.508 W 0.093 372585 38.468 38.669 69 38.889 W 0.133 682665 38.669 39.027 70 39.112 W 0.064 279312 39.027 39.125 71 39.164 W 0.067 442938 39.125 39.232 72 39.273 W 0.073 365425 39.232 39.347 73 39.371 W 0.057 153703 39.347 39.437 74 39.613 W 0.104 469889 39.437 39.684 75 39.889 W 0.145 784971 39.684 40.008 76 40.077 W 0.075 94436 40.008 40.115 77 40.189 W 0.090 211129 40.115 40.259 78 40.329 W 0.093 232232 40.259 40.417 79 40.545 W 0.097 302638 40.417 40.~03 80 40.621 VV 0.064 145453 40.603 40.709 81 40.828 W 0.103 528180 40.709 40.925 82 41.015 VV 0.076 399120 40.925 41.091 83 41.110 W 0.056 93209 41.091 41.149 84 41.208 W 0.101 292472 41.149 41.331 -85 41,443 VV 0..-134 .439255 41.331 41.665 86 41.785 VV 0.087 128214 41.693 41.830 87 41.858 W 0.035 40926 41.830 41.873 88 41.972 VV 0.124 404092 41.873 42.162 89 42.289 W 0.093 406206 42.162 42.357 90 42.414 VV 0.080 342512 42.357 42.521 91 42.703 W 0.070 49503 42.645 42.749 92 42.965 W 0.089 289601 42.863 43.052 93 43.094 W 0.076 100043 43.052 43.186 94 ~3.252 .VV . 0~0.89 62500 43.186 43.374 95 43.494 VV 0.079 95916 43.374 43.544 96 43.605 VV 0.091 137631 43.544 43.734 97 44.227 VV 0.083 94173. 44.121 44.432 Ion 218.00 amu. from WF4237_SAT.d WF4237_SAT Peak# 1 2 3 4 6 7 Ret Time Type Width 35.514 'PV 0.065 35.641 VV 0.058 35.861 W 0.077 36.057 PV 0.049 361171 VV ....... '0~069' 36.281 W 0.046 36.594 BV 0.084 Area 15361 10862 41196 22871 130239 7807 20901 Start Time End Time 35.422 35.589 35.589 35.720 35.720 35.972 35.972 36.096 -36.'096- " 36:253' 36.253 36.333 36.470 36.605 MaY 2, 1990 Page: GMC Data Report No. 159 Page 148/226 Sequence: /chem/msd/042790.S 8 36.617 W 0.050 9 36.820 W 0.073 10 37.014 W 0.066 11 37.133 W 0.046 12 37.240 W 0.087 13 37.532 W 0.057 14 37.593 W 0.061 15 37.733 UV 0.081 16 37.845 W 0.086 17 37.984 VV 0.077 18 38.098 W 0.106 19 38.444 W 0.061 20 38.541 W 0.099 21 38.794 W 0.081 22 38.892 W 0.098 23 39.100 W 0.084 24 39.271 W 0.071 25 39.372 W 0.055 26 39.613 W 0.109 27 39.815 W 0.102 28 39.880 W 0.074 29 40.083 W 0.057 30 40.179 W 0.075 31 40.312 W 0.087 32 40.547 V'V 0.121 -33 40.847 ',W 0.0'81 34 41.016 W 0.069 35 41.207 W 0.107 36 41.444 W 0.089 37 41.524 W 0.075 38 41.790 W 0.096 39 41.887 W 0.055 40 42.025 W 0.113 41 42.287 W 0.075 42 42.417 W 0.083 .. 43 42.687 W 0.079 44 42.965 W 0.083 45 43.093 W 0.074 46 43.258 W 0.078 47 43.498 PV 0.071 48 43.598 VV 0.075 49 44.223 W 0.075 Vial: 15 16519 130522 35924 12488 66521 43290 51059 137469 130686 150516 255014 71613 190072 135155 196427 504485 387594 72444 246150 267408 211492 36689 106872 89508 275243 432413- 418830 332221 153459 86518 99570 38645 212306 396600 ~89383 45101 35420 84037 1O9282 54521 36.605 36.725 36.942 37.077 37. 149 37.437 37. 551 37.643 37.793 37.919 38.040 38.342 38.465 38.662 38.839 39.019 39.209 39.352 39.445 39.688 39.850 ~0.021 40.109 40.254 40.4O5 40.718 40.931 41.101 41.340 41.502 41.648 41.840 41.899 42.166 _42,353 42.635 42.860 43.053 43.180 43.389 43.547 44.122 InjeCfiion:'' : 36.725 36.942 37.077 37.149 37.347 37.551 37.613 37.793 37.919 38.040 38.342 38.465 38.662 38.839 39.019 39.209 39.352 39.445 39.688 40.021 40.109 40.254 40.405 40.718 40.931. 41.101 41.340 41.502 41.648 41.840 41.899 42.166 42.353 42.635 42.'771 43.053 43.180 43.389 43.547 43.890 44.312 Data Report No. !59 Hay 2, 1990 Page !49/226 PETROLEUM GEO£HEI'IISTRY -~ C ,,'- .~AR~ ANALYS!S SAItPLE NAME : PT. THOMSON !I-.ISTRIJllENT : HPLC F ] O I N3EET T [ ME : hied tla.., o 1990 11 ' 16 ' METHOD USED : /IdETHOD/HPLE_FIDO.I'ITH z~AT5 zl FIleD ~c'~131/~]r'F/UP-1 Ao 0 ~UTOC~ SEIki SEQUENCE : .............. ~ ~ ......... _ . - RE_,U~T' e , r-tEE. : .-'RESULT/WF"~4°~ ~_S~P.RES REPORT TTIqE ' '!'1- z" AM I,JEO o MAY 1°QO RESPONSE AREA T ! !nE FACTOR - '~9849. 5 ':' '-~ !225E-03 S~tur-ates --' _ '-, . _.- Aromatics i 16818. 9.42 .5470E-04 Aromatics 2 34192. 14.36 .5470E-04 Po ! ar_=, 1153770. 19.92 .4160E-04 AMOUNT (mg) ,"'. RES ! DUE Saturates 2.91 277..7 Aromatics 2.29 26.6 Po lars 4.80 45.77 ~' OIL Saturates 21 2 Aroma tics 20.5 Po lars _z_4.9 Aspha 1 tenes 2~. 2 '.GMC Data Report No..-159 - . ..._Page 150/226 0 'o 0 r--! 5. @0i. 4 ~ .53L I .4( _ .2i ___.~ ........ 0 · ':3.25 9.38 i2.50 !5.63 ~.8.76 21.88 SAMPLE: PT. 'FHOMSON ¢2 5790-,.,=,,.,0='"" - ANAL'(ZED. Wed May 9, :S. 990 ~.:t' ~.6:57 am METHOD: HPLC FIDO RESULT: /RESUL. T/WF4242 SAP,RES 25.0~ PETROLEUM GEOCHEMISTRY / GNH ROCK EUAL *~* SAMPLE : WELL: PT. THOMSON ]~2 DEPTH: 6240 INOECTEO AT : Tue Apr 12~ 1990 1:37:46 am INSTRUMENT : GROCK METHOD USED : /METHOO/PYROS.MTH RESULT FILE : /RESULT/WF4242iO_GRO.RES 8LANI< FILE : /RESULT/SLA~<!~_GRO.RES AREA SLICE INTEGRATION AREA YIELD (ma/o) FRACTION 389850.-76. 191448930. ~. 12 S1 4.23 S2 ,,-_-.-'-..~..,,o~'.._,,_.,, ,, ,-,_ b.-".T . : 15 . 50 mos Trna:< : 414 C GMC. Data. Report No. 159 P~ge 152/2.26 -. ~.-~ _:_ .- s . . , 4.49 [ ~..0~. llrlute~ RESULT: SAMPLE: WELL: PT. THOMSON DEPTH: G~40 ANALYZED: Tue MaP 20. ~990 8:0~: 45 am /RESULT/WF4~42 ~ GTX.RES METHOD: GTXGC~ 0 ; s 71.88 80. O0 PETROLEUM GEOCHEMISTRY / GNH PgC AUTO SAMPLE : WELL: PT. THOMSON ~2 DEPTH: 6240 INOECTEO AT : Tue Apr i7, 1990 i:32:46 am INSTRUMENT : gPGC_2 METHOD USED : /METHOO?GPgC2_O.MTH RESULT FILE : /RESULT/WF424210_gPg. RES 8LANI< FILE : ×RESULT×SLANt<iS_gPG.RES AREA SLICE INTEGRATION AREA AREA PERCENT FRACTION 452015. 1462989. 31546~5. 1868971. 590649. O. TOTAL AREA : 6.1 METHANE 19.5 gASES 41.8 GASOLINE 24.8 !<EROSENE o GAS-O[' 7 ~ 0.0 WAX-DISTILLATE AREA ~: ~00.0 CAS PRONE ~ .,~ 25.~ M=,HAI,~ + GASES = ~ GASOLINE+KEROSINE+GAS 01, +,1~'~ ... ~ ~-, DISTILLATE = 24 ~ FACTOR *-' ""-' AH~,_,o IS OF !(EROGEN PYROLYSATE THI'-~ REAOII','G "'"-'cF; ':'-'"' '-"- "="- .... - .... ,..,Ut.!. .... R,, TO CNOt~,N F'ANA~E 1 F ~,q INUEST I~ATE PRODUCT GMC 'DatA-:' RePort.. No'" 159 """ " ..... ' ..... - - - '"" ---' -.-' - ' Page"l-54~226: X "--"1:3 CD N O'"~ ~ fO ¢::30 4.47 ~.07 RESULT: O0 m~9,~es.,,,,~ ,. 9.99 x9.99 a~.99 SAHPLE: HELL: PT. ANALYZED: Tue ..App /RESULT/HF4242tO GPO. RES ,, I ...... , .... I , !. 39.99 49.98 59.98 THOHSON ~2 DEPTH: 17, t990 t: 37:46 am NETHOD: GPGC2 0 6240 69.98 7~ Sequence: /chem/msd/05119 O_SAT. Vial: 47 Injectio6.: 1 Normalized Percent Report Inforn~tion from Current Data File Header: File: /chem/msd/WF42i2_SAT.d Operator: Date Acquired: Fri May 11 90 08:18:38 PM Sample Name: WF~242_SAT Misc Info: Sequence Index: 1 Bottle Number: 47 Repetition Number: 1 SATURATE BIOMARKERS CalibratienTable Last Updated: Sun Jun 10 21:28:04 1990 Referemce Peak Window: 0.250 AbsOlute Minutes Non-reference Peak Window: 0. 250 Absolute Minutes Default Sample Amount: 0 Uzlcalib. Peak Respoz~e Factor: 0 Default Multiplier: 1 Peak Int. Ret. Signal Num Type Type Tin~ Description Area Ammmt 1 2' 3 4 5 -6 7 8 9 10 11 12 13. 15 16 17 18 19 20 21 .2.2 23* 24 25 26 Run: 7 VV 39.817 191.00 amu C27 18A HOPANE TS VV {0.~69 191.00 .amu C27 17A HOPANE TM W ~1.84~ 191.00 amu C28 BISNORHOPANE X W 42.814 191.00 amu C29 HOPANE D VV 42.918 191.00 amu C29 NORHOPANE D2 W .... 43.232 .191.00 amu .C30~.PENTACYCLANE PI.. W 43.828 191.00 amu C30 18A OLEANANE B W 44.192 191.00 amu C30 HOPANE G W 44~805 191.00 amu C30 MORETANEK W 45.801 191.00 amu * C31S HOPANE N W 46.000 191.00 amu C31R HOPANE"O- VV 46.167 191.00 amu O & GAMMACERANE W 46.291 191.00 amu GAMMACERANE W 46.521 19'1.00 a~u P - W 46.832 191.00 amu R VV 47.084 191.00 amu C32S HOPANE U W 47.352 191.00 amu C32R HOPANE V W 48.547 191.00 amu C33S HOPANE ALPHA W 48 924 191.00 amu C33R HOPANEBETA * W 50.212 191.00 a mu C3GS HOPANE GAMMA W 50.773 191.00 amu C34R HOPANE DELTA .VV .... 52.199 191.00 amu C35S HOPANE EPSILON · w 53' 023."**~91,*06"am~'. **C3SR**HoPaNE<*ZETA PV 27.228 217.00 amu C21 STERANE Y W 36.164 217.00 arau C27S ba DIASTERANE10 VV 36.811 217.00 a_mu C27R ba DIASTERANEll June 10, 1990 1636572 2.338 % 1902861 ~.292 % 446682 1.007 % 2711485 6.115 % 1660984 3.7G6 % 74~915 ..1.687 % . 239831 0.5409 %, 3250223 7.330 % 711361 1.604 1548855 3.493 % 1165031 2.628 % 393252 0.8869 % 616551 1.391 % 462215 1.042 % 126473 0.2852 % 1026092 2.314 % 712205 1.606 % 634225 1.430 % 418061 0.9429 325929 0.7351% 190424 0.~295 % 422429 0.9527 % '263132' -0,'5935-% '- 2037039- ~.594 %' 1231382 2.777 % 113588~ 2.562 % Page: 1 ................. ~cn Paae J56/226 Sequence: /chem/msd/051190_SAT. s Vial: 47 Injection: 1 Peak Int. Ret. Signal Compound NumType Type Time Description Name Area Amount 27 W 37.248 217.00 amu 13 28 W 37.720 217.00 amu 14 29 W 37.840 217.00 amu 15 30 W 37.969 217.00 amu 16 31 VI; 38.500 217.00 amu 18 32 - 217.00 amu 19 33 PV 38.880 217.00 amu 20 34 W 39.152 217.00 amu 21 35 VB 39.369 217.00 amu 22 36 BV 39.607 217.00 amu C27R aaa STERANE 25 37 VV 39.796 217.00 amu 27 38 VV 41.426 217.00 amu C28R aaa STERANE 36 39 VV 41.963 217.00 amu C29S aaa STERANE 39 40 VV 42.947 217.00 amu C29R aaa STERANE 42 41 BV 39.095 218.00 amu C27R abb STERANE 2lB 42 VV 39.262 218.00 amu C27S abb STERANE 22 43 VV 40.838 218.00 amu C28R abb STERANE 33A 44 VV 41.003 218.00 amu C28S abb STERANE 34 45 VV 42.280 218.00 amu C29R abb STERANE 40 46 VV 42.404 218.00 amu C29S abb STERANE 41 495724 1.118 % 932874 2.104 % 1162199 2.621 % 209930 0.4735 % 982833 2.217 % -Not Found- 1271892 2.869 % 1371037 3.092 % 230027 0.5188 % 783798 1.768 % 1465259 3.305 % 945571 2.133 % 935~03 2.109 % 848219 1.913 % 1092414 2.464 % 941890 ° 2.124 % 1342014 3.027 % 1320595 2.978 % 1294974 2.921 % 1295171 2.921 % *** REPORT ERRORS *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not All Calibrated Peaks Found *** .--. Run: 7 GMC Data Report No. 159 June 10, 1990 Page: 2 Page t57/226 Abundance ~.20,000 ., 100,000 soOoo 60000 ., .' 40000 20'000 Abundance ,, 70000 r~oO, oo 50000 :., 40000 , 30 0~0 0 ~oo"0o 100'00 Ion i77.00 amu. from" WF424P-_SAT.d 42 44 46 48 ,, Time (min,) 50 52 5~ .40 42 ,. Ion :i'9C.O0 ainu. from WF4242_SAT.d 44 46 48 Time, (min.) 50 52 54 70000 ., zoo'oo , ,, .. oooo 4O00O Abundance Ion 19~.00 amu. from WF4242_SAT.d 30000 , z:oo'oo 36 38 40 42 44 46 48 50 52 54 T:~me (min.) "(::3 0 · 30000 Abundance 200'00 , , Ion 2~7,00 amu. from: WF4242_.SAT.d ,, 36 38 dO 42 " Time '(min.) Abundance '. ~20000 - ~oo0:'o0 ,' 80000 sooOo 400.00 20000 ,. · 0 ... , . Ion tgi.o0 amu. from NF4242_SAT.d ,'. ', 30 40 T~me ,(min.) Ion ~,7.00 amu. from NF4248_.SAT.d :, Abundance ',, 4000:0 3oo00 ~ ~oo0o ~ ~oo0o T~me I ~ ' ~ i 40 50 (rain .) PETROLEUM GEOCHEMISTRY SARA ANALYSIS SAIIPLE NAME : INSTRUMEIqT : INJECT TIME : METHOD USED : SEQUENCE : RESULT FILE : REPORT TIME : PT. THOI'IPSON~2 10158-10210 HPLC_FIO Thu Apr 1~ ~ l?g0 ~: 06: ~6 pm /METHOD/HPLC_F I DO. I1TH /OATA/LOOP/SEOUENCE/HPiOgO_AUTOBY.SEO /RESULT/~F424~_SAP.RES .... ~g APR ~ lgg0 s:~g PM THU ~ Saturates Aromat Aromatics Polars RESPONSE AREA TIME FACTOR lii518. 5.29 .1275E-03 23922. 9.42 .5470E-04 63448. 14.36 .5470E-04 136069. 19.96 .4160E-04 Sa t,J rat es Aroma t i cs Po lars AMOUNT (mg) ~ RESIDUE 14 oo 57 7 4.28 19.4 5.66 23.0 Saturates Aroma t i cs Po lars Aspha Itenes OIL 52.0 19.2 22.2 1.1 GMC.. Da ta.' Repo.,r.:t ..No.,. ! 59.. · · Page 162/226 o o 7.41 5.96 4,5! 3.06 .i6 0,00 m~nutes 3.12 6.25 9.38 i2.50 15.63 18.76 RESULT: SAMPLE: PT. THOMPSON#2 i0158-10210 ANALYZED: Thu ApP i9, 1990 5: 06:36 pm /RESULT/WF4243 SAP.RES METHOD: HPLC FIDO 2I .88 25.0i ; I. ~,~ Tr-,I t-. - I' :. .... r.. d, 1Et'., r i~.,'.]EET T ! rli:-: T.~a_-~D USEO PE'~L.:LT FILE F.'EPOf-?T T ! ME · ..':' T .... l'-~i!"'"~ 1F''''--''' I''J- ...... --:" ';- ] ,:"' J ::'8 -- 1 (12. ] Fi_ · HF' ~.F:q'-' ':-' · b,'. e d I'1,~ '.., '~ l o ,.-~ 0 :5: ~'- '~: ;] 9 a m · "r',£THODxSATDSgOE.MTH ' ..'RESIJLT/blF424~ SAT. RES , - .- I1~. ~ ., , : a: 29 ~i'1 hiED. , a --',, lYvU CPI. UALIJE : .92 PRISTANE / PHYTAIqE : PRIST'ANE .-' C:l? : PH'::TRNE ,- ,_..~ : 9° C15/C25 : . 16 58 r:l 7,-'P r : '~ ?'-' .40 C!8/Ph : 2.51 · APP-A.._ ,%AREA NALK T I MF~ NAF:M_ .. El~.. N-C ! 0 N-C ! 1 N-C12 N-C13 N-C14 N-C15 N-C16 N-C17 N-C18 N-C19 N-C20 N-C21 N-C22 N-C23 N-C24 N-C25 · N-C26 Iq-C27 N-C28 N-C29 N-C30 I-,I- C~ 1 N-C32 N-C33 N-C~4 N-C35 N-C36 100. .0 5.62 .02 241 1 7.°° 06 572. . i lO. 11 .14 1237 '~ - . .-, 12.22 ~0 2166. .5 14.19 .52' 4157. 1.0 16.05 1- O0 9287. 2.2 17.80 2.23 20664. 4.9 19.46 4..97 30353. 7.3 21.03 7.3(:, 33328. 8. o 22.53 8.02 36062. 8.6 23.96 8.68 31502. 7.5 2'5.33 2.58 31682. 7.6 26.64 ?. 62 30189. 7.2 27.90 2.26 27887. 6.7 -29.11 6.71 25226. 6.1 30.27 6.19 2'5542. 5.6 = ' 31:58 5-;6-1 16486. 3.9 32.46 3.9.2 16813. 4.0 33.50 4.04 14655. 3.5 34.51 3.53 10841. 2.6 35.48 2.61 8855. 2.1 36.42 2.13 8272. 2.0 37.33 1.99 8353. 2. O 38.27 2.01 14711. 3.5 39.32 3.54 5666. 1.4 40.50 1.36 5267. 1.3 41.86 1.27 Farrlesane · Ac~,c 1 i c. ,Cid. Ac~.:c 1 ic 'C18 .. Pr- i ,s tar, e ..,- ~ AREA ~AREA I SPR T I ME 00 ~ 0 -~ x 78 ,_.lu o ~ . ~j . -~-' 826 2 8 15 40 .~ _ -., _ . °-. . . . :. ~ '"14 ' ' ' 4147. . i 18.67' 12022. 40.9 19.61 I '~I]'~7 ;:~ ,m, Ol o~ GMc' Data' Re~0rt'N° '.:159' -' ' ....... ' ' '" '" : -: ----' .... - .....-Page-- ]-64/-226' 99_ 95_ 8; . 78,, , 5,00 minu~es 9 81~ I lO ,00 I .... I I i , i i I .... , i i 15.00 20.00 25.00 SAMPLE: PT. THOMPSON #2 10158-i02~0 ANALYZED' Ned' May 9, i990 8' 31' 02 am RESULT: /ARCHIVE/WF4243 SAT.RES METHOD' SAT5890E I , I , .., ....I ~ 30. O0 35.00 40. O0 45.00 PETROLEUM GEOCHEMISTRY / GNH ROCK EUAL SAMPLE : YELL: PT. THOMSON ~2 DEPTH: 10210 INOECTED AT : Fri Mar 16, 1990 10:53:13 am INSTRUMENT : GROCK METHOD USED : /METHOD/PYROS.MTH RESULT FILE : /RESULT/WF4243 1GRO.RES BLANK FILE : /RESULT/BLANK13_GRO.RES AREA SLICE INTEGRATION AREA YIELD (mg/g) FRACTION 40632784. 2.66 SI 92994144. 4.99 S2 SAMPLE WT. : 23.80 Tma× : 425 C . G..MC Data. R.eport .No .... 159 . . _Page 16 6/226_ 17' 95i .92 15.. 05 23. t6 3t. 26 39.40 iIIlnuf, es SAMPLE: NELL: PT. ANALYZED: 'FP~L Mar' RESULT: /RESULT'/WF4243 ! (:;TX.RES 47.9t ,,qg. 63 63.79 7t. 66 79.96 THOHSOhl f2 DEPTH: 10210 16. 1990 10: 53:t3 am METHOD: GTXGC! 0 '-:' -~-OC:HEMTSTRY ' GNH PGC AUTO '*' :*- -~. :+. · ,,--..- DEPTH: 0 -_. 'i 0 ~!i.'.u-:Z~'E!.''' ?*-',:' : :t-ri Mar- !6... 1990 10'-53:1_-5.. ar,; 1 '.": sc,: :'"~'~'.'T ' i'~F'G'-' 2 fIETHOD USED : ../METHOO,"GPGC2_O. !1TH RESULT FILE : /P..ESL~LT/t,!F4243 1 GPC~.RES E:L.R!','I...'. F i L£ : "F:ESULT:-'BLANl<lS_GPG. RES SLICE !NTEGRATIOM ***~** AREA AREA PERCENT FRACTION 21887~1. 15.2 METHAlqE 262423~.. i8.= ~ GASES 5788811. 40.2 GASOLINE ~122872. 21.2 KEROSENE 660229. 4.6 GAS-OIL O. O.0 ~AX-DISTILLATE TOTAL AREA : 14384942. AREA ~: 1OO.0 SAMPLE WT. : 25.80 rags SAMPLE GOGI = THIS IS GAS PRONE -.. METHANE + GASES = 33.5 GASOLINE+KEROSINE+GAS OIL+WAX DISTILLATE = 66.5 BY FACTOR ANALYSIS OF KEROGEN PYROL¥SATE THIS IS A GAS+CONDENSATE SOURCE THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT ITS PRESENT MATURITY. THIS IS NOT A KEROSEN TYPE ANALYSIS. SAMPLE I<2 = 4.86 rog/gm "'GMC Data 'Repo'rt'No:-'.159- -' --'- -", ..... i - -.::-:: - _ _- Page I 1_68.-/.226~ I -- 6.02 3.63 0 0 9.99 mfn~tes RESULT: /RESULT/IdF4243 i GPG.RES SAMPLE: HELL: PT. THOMSON #2 DEPTH: 10210 ANALYZED: Frt Mar ~6, ~990 t0:53:~3 am METHOD: GPGC2 0 Sequence: /chem/msd/O q 2 7 90. $ . Vial Injection: 1 Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF42{3_SAT.d Operator: Date Acquired: Sat Apr 28 90 03:15:25 AM Sample Name: WF~2~3_SAT Misc Info: Sequence Index: I Bottle Number: 23 Repetition Number: 1 SATURATE BIO~K%RKERS Calibration Table Last Updated: Sun Jun i0 16:46:57 1990 Reference Peak Window: 0.250 Absolute Minutes Nom-reference Peak Wi~dow: 0.250 Absolute Minutes Default Sample ~t: 0 Umcalib. Peak Response Factor: 0 Default Multiplier: 1 Peak Int. Ret. Sigr~l Compound Time De$criptio~ Name 1 3 5 6 7 8 9 10 11 12 13 15 16 17 18 20 21 22 25 26 ¢ Rim: 1! W W W W W W W W W 40.020 191.00 amu C27 18A HOPANE TS 40.675 191-.00 amu C27 17A HOPANE TM 41.820 191.00 amu C28 BISNORHOPANE X 43.004 191.00 amu C29 HOPANE D 43.093 191.00 amu C29 NORHOPANE D2 1363409 1621133 73385 2643803 1502684 43.-.2.77 .!91-.Q0 amu C30 PENTACYCLANE PI 180740 43.889 191.00 amu d~0'lSA oLEANhNE B ........ 129951 44.373 191.00 amu C30 HOPANE G 44.969 191.00 amu C30 MORETANE K 45.957 191.00 amu C31S HOPANE N 46.153 191..00 amu C31R HOPANE O 46.295 191.00 amu O & GAMMACERANE - 191.00 amu GAMMACERANE 46..442 191.00 amu - 46.671 191.00 amu R 47.219 191.00 amu C32S HOPANE U 47.484 191.00 amu C32R HOPANE V 48.665 191.00 amu C33S HOPANE ALPHA 49.044 191.00 amu C33R HOPANE.BETA 50.334 191.00 amu C34S HOPANE GAMMA 50.899 191.00 amu C34R HOPANE DELTA 52.324 191.00 amu C35S HOPANE EPSILON 3.244 % 3.857 % 0.1746 % 6.291 % 3.576 % 0.4301 % 0-.3092 %* 4602979 10.95 % 724011 1.723 % 1846469 ~.39~ % 1536858 3.657 % 26{928 0.6304 % -Not Found- 469334 1.117 % 733656 1.7~6 % 1232357 2.932 % 911188 2..168 % 792649 1.886 % 537319 1.279 - 4{0067 1~047 % 254980 0.6067 % 410243 0.9761 26.5913 -~ O.6327-- -%* 1378416 3.280 % 1339092 3.186 % 981487 2.335 % · . W 5'3'150 191'00"amu-C35R'HOPANE-:ZETA PV 27.441 217.00 amu C21 STERANE Y PV. 36.368 217.00 amu C27S ba DIASTERANE10 W 37.00¢ 217.00 amu C27R ba DIASTERANE11 'June 10, 1990 Page: 1 Sequence: /chem/msd/O42790.s Vial: 23 Injection: 1 Peak Int. Ret. Signal NumType Type Time Description Compound Na~e i~ea Amount 27 VV 28 PV 29 VV 30 W 31 32 PV 33 VV 34 VV 35 VV 36 W 37 W 38 W 39 VB 40 VV 41 VV 42 W 43 W 45 VV 46 W 37.310 217.00 amu 13 37.617 217.00 amu 14 37.781 217.00 amu 15 37.913 217.00 amu 16 - 217.00 amu 18 38.627 217.00 amu 19 38.698 217.00 amu 20 39.082 217.00 amu 21 39.350 217.00 amu 22 39.803 217.00 amu C27R aaa STERANE 25 40.067 217.00 amu 27 41.621 217.00 amu C28R aaa STERANE 36 42.145 217.00 amu C29S aaa STERANE 39 43.122 217.00 amu C29R aaa STERANE 42 39.291 218.00 amu C27R abb STERANE 2lB 39.466 218.00 amu C27S abb STERANE 22 41.033 218.00 amu C28R abb STERANE 33A 41.192 218.00 amu C28S abb STERANE 34 42.452 218.00 amu C29R abb STERANE 40 42.589 218.00 amu C29S abb STERANE 41 129484 0.3081 % 12133 0.02887 % 371182 0.8832 % 663037 1.578 % -Not Found- 404413 0.9623 % 676768 1.610 % 1141942 2.717 % 1507252 3.586 % 817462 1.945 % 1380915 3.286 % 692275 1.647 % 763782 1.817 % 830824 1.977 % 1134182 2.699 % 923661 ~.198 % 1064103 2.532 % 1060665 2.524 % 1003027 2.387 % 1212560 2.885 % *** REPORT~ *** Calibration Peak #7's Qualifiers Were Not Satisfied. *** Not Ail Calibrated Peaks Found *** June 10, 1990 Page: 2 GMC Data Report NQ. t59 . Page ]71/226 Abundance Ion ~91.00 amu. from NF4243_SAT.d ; 90000 - 800.00 70000 60000 5oo o oo0o ' 200:~0 lO0:O0 : ,. i" :, ',, ,. '.'Abundance. ,, ' 40 Time (min.) Ion ~7,00 amu. from ~F4~43_$AT.d 30000 200'00 lO0'O0 . i i j i 5O 40 50 (min.) 40000 - Abundance 0 30000 - 200'~0 I 00'00 Ion :[77.00 amu. from NF4243_SAT.d f I f ' ' I. ' ' ~ I ' '" ' I ' ~ i I' ' 40 42 44 46 48 Time (min.) Zon 19~.00 amu. from WF4243_SAT.d 50 52 54 Abundance 900,00 80000 70000 60000 500'00 , 40000 30000 200 0 ~o00o 140 42 44 46 48 Time (m-in.) 50 52 54 ~bundance Ion 19~.00 amu. from NF4243_SAT.d ' 9ob'oo 80000 70000 · 60000 , 5oo:0o ,', 40000 · ,, 30000 , 20 0 0 i ' , ', .... ~ "'i .... ,' 36 38 40 42 44 46 48 50 52 54 T&me (min.) Abundance asoo'o ,, , , 24000 20000 ~600'0 :2oOo 80OO 4000 Ion 2~.'7.00 amu. from.'WF4243_SAT.d 38 40 42 44 T~me (m~n.) PETROLEUM GEOCHEMISTRY SARA ANALYSIS SAI'IPLE NAME ! NSTRUMENT If.I.]ECT T!ME METHOE: USED SEOIJENCE RESULT FILE REPORT T!ME ! : UEST STA!t-IES~I · HPL£_F I D : lion Apr 1S. lyYu 2: 25: 0S pm : /METHOD/HPLC_FIDO. MTH : /DATA/LOOP/SEOUENCE/HP109 0_AUTOBU. SEO - /RESUI_T..-'I.JF4246 SAP. REc. : '2:50 Pi1 IION.. 16 APR.. 1990 Saturates Aromat ics 1 Aromat ics 2 Polars RESPONSE AREA TIME FACTOR 19808 s ')g ~n~ 03 946D. 9.42 .5470E-04 15325. 14.36 .5470E-04 46416. 19.92 .4i60E-04 Saturates Aromat ics Po tars AMOUNT (mg) % RESIDUE 2.5~ 1.36 2~.3 S~turates Aroma t i cs Po lars Aspha 1 tenes OIL 29.0 '12.? · GMC Data "Report No.'-'-I59' "" --'-- '-~'~-'/'' '' '~ - ..... :- -~ -Page 176/226· '-' - : O' o o o 3.65 3,02 2..39 i .76 4J 15.63 , SA~4PLE: ~EST STAINES#_~ /2~77 / !8.76 RESULT' ANALYZED: Non Apr' 16, 1990 2: 25:08 pm /RESULT/~F4246 SAP.RES HETHOD: HPLC FIDO 2~.88 25.01 PETROLEUM GEOCHEMISTRY SATURATE GC SAMPLE I-4AI'IE INSTRUMENT INOECT TII'IE METHO0. USEO RESULT F!LE REPORT T!ME : I,.IEST STAll,lES,r~l 10594 : HP_5890_2 : /METHOD/SAT589OE. MTH : /RESULT/WF4246_SAT. RES : 1!:47 AM WED.. 9 MAY 1990 CPi UALUE : .90 PRISTANE / PHYTANE : PRISTANE / CI? ' PHYTANE / C18 : .50 C15/C25 : .68 C17/Pr : 1.!0 C18/Ph : .06 1.47 .91 N-CI0 N-C11 N-C12 N-C13 N-C14 N-C!5 N-C16 N-Cl7 N-C18 N-C19 N- C20 N-C21 N-C22 N-C23 N-C24 N- C25 N=C26 .... N-C2? N-C28 N-C29 N-C30 N-C31 N-C32 N-C33 N-C34 N-C35 N-C36 ARER . %AREA NALI( T IIqE . O. 0.0 0.00 O. 0.0 0.00 O. 0.0 0.00 O. 0.0 0.00 O. 0.0 0.00 187. .5 16.03 344. .9 17.79 610. 1.6 19 . 44 762. 2.0 21.02 1032. 2.7 22.5:2 1780. 4 7 23.95 1669. 4.4 25.32 2376. 6.2 26.63 2840. 7.5 27.88 3140. 8.3 29.09 3355. 8.8 .. 30.25 :3389." 8.--7 . 31.-37. 2136. 5-. 6 32.45 2667. 7.0 33.49 2137. 5.6 34.49 1741. 4.6 35.47 1444. 3.8 36.51 1530. 4. O 37.32 1207. 3.2 38.26 1960. 5.2 39.31 ,_,6,..,. 2 '-¢ 40 49 941 2 NORM 0.00 0.00 0.00 0.00 0.00 1.00 1.84 3.2'7 4.08 5.52 9.53 8.93 12.72 15.20 16.80 17.95 17.71.. 11.43 14.27 11.44 9.32 7.73 8.19 6.46 10.49- 4.65 5.04 AREA %AREA ISPR TIME O. 0.0 O. 0.0 "1'19" ' -' 8 -4'- 416. 50.4 8/..6. 61. ! 0.00 0.00 :'18" 6~. 19.60 21.2! · - GMC Data Repo.rt.No-.'15.9 - Page -1_78/226- P 70 2 56 24i 2 27 2 13 99 ..... I , .... I , ,I 5 ~ lO.O0 15.00 20.00 25.00 30.00 35.00 mi res SAMPLE: WEST STAINES #t 10594 ANALYZED: Wed May 9, 1990 10'55:57 am RESULT: /ARCHIVE/WF4246 SAT.RES METHOD: SAT5890E 40.00 45.00 ..... L,,._-,J~: Gr-'OCHEMISTR¥ / GI-4H ROCt< EUAL :*.** . ::-'.:A.f'iF'I_£ : .......~_ : ME'qT ..... ST.A !,'{~S d~l ~,~,F'C-C'T~ :,,, lrtmo4_ .... ],,.1E-CT~-,', - ~' 07 ~oo~1 o:.)K i iqE.''r"', ,...,~,~'lEiqT : GROCt< ,,~'~C-THCP'~. .~ USED : ./I~ETHC:O.-"PYR05 . Iq'TH RESULT F!I..E : ./RESULT/b.IF424611_GRO. RES ~'~,~,"'-"-',,...FILE : ,-REC;I ILT/BLAI-iK 1=__ . . . ~ GPFm.__. RES AREA SLICE INTEGRATION AREA YIELD (mg/9) FRACTION 5061.4. . O1 SI · 26998522 . 7.32 S2 . SAMPLE biT. : 14.50 mos Trna>: : --.,. o C '~M'C"'Data' R~l~Ort :NO' 15'9' · ' - ..... '-': "-"- 'Page 180/2'26- : - _ F L-.::_ AUTO ~+~-:+- PETRALEUM GEOCHEI'IIS]'RY .--" GI'~H '-"- SAMPLE : tdEST STAINES ~t~! C:EPTH: 10594 INJECTEO AT : Fr-i Apr 27: i,°-?0 9:25:0:? am I-~.~TRu, ,L:--iT : bnoU '2 METHOD USED : ,.'P1ETHOE:;,;GPGC2_0. !qTH ~E'~ULT FILE : :-'REE;ULT/b]F42-~611 GPG. RES 8LANK F!LE : /RESULT..,'BLANKiD_GPG.RES AREA SL1CE INTEGRATION ****~ , F'-c'i. T - _ . AREA AREA PER ...... 4. FF:~'¥.ZT I F~i'-~ ..................... ,~. 'i '~ ?~.~,~'-,'-.' 8 8 HETHANE 29009)8 ~ ~ ,--.. c-- .... ~_,UL I NE 21392748. 16. O t<EROSENE 4~i15144. 52.2 C4AS-O~L 4~~3~0 34 1 L4fi~-DISTILLflTE TOTRL AREA : 133728940. AREA %: iO0.O SAMPLE LdT. : i4.9rJ rngs ... SAMPLE GOGI = .i3 THIS IS OIL PRONE METHANE + GASES = li.8 GASOLINE+KEROSINE*GAS OIL+DAN DISTILLATE = 88.2 BY FACTOR ANALYSIS OF KEROGEN PYROLYSATE THIS IS OIL PRONE · , THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT ITS PRESENT MATURITY. THIS IS NOT A KEROGEN TYPE ANALYSIS. /'-) ~'] rna/om SAMPLE [~.-- = 7..- _~ ~ .: ':~ "' GMC-Data: Report 'No:.-159' .. Page 181/226 -. X 2t.24 ~,3.84 ~t~tes RESULT: to,oo ~o.oo 3o,o0 40.00 ~o.oo SANPLE: WEST STAINES ff. ANALYZED: Fri. Apr 27, ~@90 /RESULT/WF4246t ! ~PG. RES NETHO~ 60.00 DEPT~ ~0594 · . 25: OP- am sPeCa o 70.00 80.00 Sequence: /chem/msd/042790. s : Vial: 17 Injection: 1 Normalized Percent Report Information from Curre~t Data File Header: File: /chem/msd/WF42~6_SAT.d Operator: Date Aoq~ed: Fri Apr 27 90 08:19:20 PM Sample Name: WF42~6_SAT ~isc Info: Sequence Index: 1 Bottle Number: 17 Repetition Number: 1 $ATURATE BI~ Calibration Table Last Updated: Sun Jun 10 13:21:31 1990 Refere~ce.Peak W~: 0.250 Absolute Minutes Non-referetlce Peak Wi~: 0.250 Absolute Minutes Default Sample Amou~t: 0 Uncalib. Peak Resp~m~e Factor: 0 Default Multiplier: I Peak Int. Ret. Sig=a~ ~um Type Type Time Description Compound Area Amount 1 3 5 6 . 7 8 10 11 12 13 15 16 17 18- 2O 21 22 23 25 26 -Run: 5 W W W VV W VV W W 39.827 191.00 amu C27 18A HOPANE TS 40. 682 191.00 amu C27 17A HOPANE TM 40.820 191.00 amu C28 BISNORHOPANE X 42. 829 191.00 amu C29 HOPANE D 42. 935 191.00 amu C29 NORHOPANE D2 43.249 191.00 amu C30 PENTACYCLANE PI 43.857"'-;,i-9~".o-o-"amu." 'C'30-iSA~"OLEANANE B" '-- 44. 216 191.00 amu C30 HOPANE G 44';831 191.00 amu C30 MORETANE K 45.828 191. Ob amu C31S HOPANE N 66.026 191.00 amu C31R.HOPANE O. 46. 321 191. O0 amu O & GAMMACERANE - 191. O0 amu GAMMACERANE .46. 551 191.00 amu P - 191.00 ainu." R &7.108 191.00 ~mnu C32S HOPANE U .., 47. 382 191.00 amu C32R HOPANE V 48. 578 191.00 amu C33S HOPANE ALPHA 48.-956 -19I:.00,-.amu- C33R'HOPANE BETA 50. 252 191.00 amu C36S HOPANE GAMMA 50.812 191.00 amu C36R HOPANE DELTA 52.244 191.00 amu C35S HOPANE EPSILON ~26858 2.639 % 633427 3.916 % 41050 0.2538 % 856612 5.294 % 495384 3.062 % 187790 1.161 % "50318 0.3110'%', 1375268 8.501 % 273008 1.688 705104 6.359 % 592763 3.666 160025 0.9892 % -Not Found- 257659 1.593 % -Not Found- 567397 3.507 % 336815 2.082 % 369076 2.281 % 223027 1.'379 % 228829 1.615 % 114091 0.7053 % 212148 i.311 '% -W .5'3-.'075-1-9-1.00 antu ,-C35R HOPANE.ZETA -.. . 117422:. ...... 0.,7259 .% :VV 27.226 217.00 amu C21 STERANE Y 267024 1.651 % - VV 36.175 217.00 amu C27S ba DIASTERANE10 674330 2.932 % W 36.822 217.00 amu C27R ba DIASTERANEll 354498 2.191 % GMC Data Report No. 159 June 10, 1990 Page: 1 Page 183/226 .. Sequence: /chem/msd/042790.s .- . . . :. Vial: 17 Injection . Peak Int. Ret. Signal Num Type Type Ti~e Description Compound Name Area Amount. 27 VI; 28 PV 29 VV 3O VV 31 BV 32 33 PV 34 W 35 W 36 W 37 W 38 W 39 W 4O VV 41 VV 42 VV 43 VV 44 VV 45 BV 46 W 37.261 217.00 amu 13 37.597 217.00 amu 14 . 37.735 217.00 amu 15 37.8'57 217.00 amu' 16 38.450 217.00 amu 18 - 217.00 amu 19 38.897 217.00 amu 20 39.172 217.00 amu 21 39.281 217.00 amu 22 39.616 217.00 amu C27R aaa STERANE 25 39.898 217.00 amu 27 41.447 217.00 amu C28R aaa STERANE 36 41.979 217.00 amu C29S aaa STERANE 39 42.967 217.00 amu- C29R aaa STERANE 42 39.109 218.00 amu C27R abb STERANE 2lB 39.276 218.00 amu C27S abb STERANE 22 40.851 218.00 amu C28R abb STERANE 33A 41.013 218.00 amu C28S abb STERANE 34 42.293 218.00 amu C29R abb STERANE 40 42.424 218.00 amu C29S abb STERANE 41 169454 1.048 % 195015 1.206 % 274369 1.696 % 3183'35 1.968 % 136838 0.8459 % -Not Found- 485~92 31001 555219 3.432 380597 2.353 343309 2.122 582575 3.601 359397 2.222 342593 2.118 366945 2.268 426027 2.634 339961 o 2.102 % 407236 2.517 % 391509 2.420 % 360922 2.231 % 421418 2.605 % ***'REPORT-~ *** . Calibration Peak #7's Qualifiers-Were Not Satisfic~l. *** Not All Calibrated Peaks Found *** June 10, 1990 Page: 2 Paoe 184/226 ~12000 AbUndance ,", lO000 8000',' 6000': ,,, 4000'::i 200'0,".' ,, ., AbOndance soooo' , 20000,', lO000' 40.~ 42 Ion 177,00 amu, from WE4246_SAT,d ' ,,. , 42 44 46 48 50 52 54 Time (min.) Ion _'19~',00 amu, from WF4246_SAT,d ' 1 ' I 1 ~ ' I ' I I 46 48 50 52 54 T~me (m~n.) ~aoob ,:, 24000 2000,0 ,, ' eooO , , ~200'.0 · . 8000 . , , 400'0 ii, Ion ~g~,,O0 amu. ' I ' ' "; I 40 "42 , from WF4246_SAT, d 44 46 48 Time (min.) ' ' 50 52 5,4 Abundance :~000;0 ,,' ;, 8oOo ,. ;, ,, .,; 600'0 . 4O0.0 ., ,.' .;. ,; 200'0 .. ... Ion 217,.00 amu. fnom '.WF4246_SAT.d .. 36 38 T~me ' I s , 'i ..... 44 AbU'ndance 30000, · ~0000'" , .' , lO000 ,, Abundance !2000 ' . , tO000" oo0 - ', 6000 ~oo0 , ooO,'.' Ion lgl.o0 amu, ~ ' from wF4246_SAT, d · 40 Time (min.) ,, Ion 2t?:..O0 amu. from WF4246_SAT.d ,, i i I ' 50 . ..,. i,' 30 . 40 ,, ' ', ~, T&me (min.)' ; ,. o . PETROLEUM GEOCHEMISTRY SARA ANALYSIS SAMPLE NAME : UEST STAINES~i 1~TZ'-/~7/~ INSTRUMENT : HPLC_FIO - INJECT TIME : Mon Apr 16~ 1990 3:06:01 pm METHOD USED : /METHOD×HPLC_FIDO.MTH SEQUENCE : /OATA/LOOP/SEQUENCE?HP1090_AUTOBU.SEQ RESULT FILE : /RESULT?~F4247_SAP.RES . 1990 REPORT TIME : 3:31 PM MON ¢ 16 APR., . RESPONSE AREA TIME FACTOR --.- tur- tes 64552 $ -79 1275E-03 Aromat ics 1 19274. 9.42 .5420E-04 Aromat ics 2 36069. 14.56 .5420E-04 Po ! ars 75934. 19.96 .416 OE-04 Saturates Aromatics Po lars AI1OUNT (rog) 8.23 5.05 RESIDUE. 21.~ 21.4 Saturates Aromatics Polars Asphaltene's ., OIL " 56.0 20.8 20.9 .. _ 0 N 4,28 3,5t' 2,75i.' 1,99 i.22,. .46 0~. mi~°utes RESULT: 6.25 9.38 !2.50 15.63 is.?6 21.88 25.0t SAMPLE: WEST STAINES#i /O,¢zz'-. /¢ z/,¢ ' ' ANALYZED: M0n .ApP ~.6, ~.990 3: 06:01 pm /RESULT/~tF4247 SAP.RES METHOD: HPLC FIDO :+.*:-~ PETROLEI_II1 GEO6HEM ! STAY *--~-~- SATURAI'E 6C SAMPLE NAIiE I NSTRUMEI,IT IN3ECT TIME METHOD USED. RESULT FILE REPORT TIME WEST SI'AINES ~1 11672-11;-'"10 HP_5890_ 2 bled May 9 ? 1990 !1: 5-1 ' 24 am /IIETHOD/SA!'589 0E'~ ldTH /RESIJLT/WF4242_SAT. RES . . 1'290 12:43 PM WED 9 ;1AY ; CPI UALUE : .98 pPlCl'ANE ? PHYTRNE : P R ! '.S'F A;',l E / "' i 2 : PHYTAItE / C!8 : .26 1.59 2.08 AREA .oAR~_A NALK TIME NORM N-CI0 N-Cll N-C12 N-C15 N-C14 N-C15 N-C16 N-Ct'2' '. N-C18 N-C19 N-C20 N-C21~ -: N-C22 N-C25 N-C24 · N-C25 -NzC26- N-C2? N-C28 N-C29 N-CS0 N-CS1 N-C52 N-C35 N-C54 N-C35 N-C36 983. 128. 439. 1168. 1902. 2240. 5196, · .: '5'725 .-' 4551. 5456. 6586. '"6979. 9144. 10562. 11154. 10665. "'" ....... 1048'I. " 7698. 7433.. 6968. 5324. 4484. 3976. -. 41.06. 2610. Farnesane ._.: ...... A.c.~a I ~.c, .C16 · -Acycl ia C18 P~istane Phytene .7 .I .8 1.3 1.9 2 ~' 2.-6 5.0 5.8 4.5 4.9 . 6.4 7.4 7.8 7.5 7.5 5.4 5.2 4.9 5.7- 5.1 2.8 2.9 5.8 5.7 1.8 = 85 '" 10.11 12.21 14.18 16. O~ 17.79 -19.45. 21.02 22.52 25.95 25.52 26.65 2?.89 29.09 .30._ 25 -31':-'57 32.45 33.49 54.49 55.47. 56.41 37.40 58.26 59.51 40.50 41.84 .36 .05 .16 .45 .69 1.OO 1.17 1.38 1.59 1.99 2.33 2.55 5.85 4.07 5.89 -5~85 ..... 2.81 2.71 2.54 1.94 1.64 1.45 1.50 1.96 1.91 .95 AREA %ARE¢~ IsPR' '"TIME ........ ..... 261. 4.5 13.78 ..524.. 8 6 15 -¢9 -- .- .... . .-. .t .... . -: ~. - - . .... ' "--- ----- .~ ~- · ..... - . -.. - . ..~.. :--'- ~; - : -~ - - 870. · .14.2 18.66 2567. 58.7 19.60 2094. "34'.2 ' 21.22 3.77 3.40 3.04 2.67 5,oo ~o.oo ~5.oo 2o.oo 25.oo 3o.oo mzhb res SAHPLE: WEST S"TAZNES #1 11672-11710 ANALYZED: Wed Hay 9, 1990 1~'51'24 am , RESULT: /AROHZVE/WF4247 SAT,RES HETHOD: SAT5890E 35.00 40.00 45.OO PETROLEUM GEOCHEMISTRY ? GNH ROCK EUAL *** SAMPLE : WELL: WEST STAINES ~1 DEPTH: 11710 INJECTED AT : Tue Apr i7, 1990 7:25:30 am INSTRUMENT : GROCK ' METHOD USED : /METHOD/PYROS~'MTH RESULT-FILE : /RESULT/WF42471O_GRO.RES 8LANK FILE : /RESULT/SLA~<13_GRO.RES. . . :*.-*-:*.-*-.*- AREA SL ! CE I NI'EGRAT I ON '-*-*.'-*-'+:-*- AREA YIELD (mg/g) 46426688. 5. O0 ~2212220 11 19 FRACTION Si S2 SAMPLE WT. : 23.80 'mgs Truax. : -438 C '~ - · .... 'GMC' .Data-. Report. No-...159 o .t.tJ g I--. "~g~ s~.g$ 9.76 S.37 minutes RESULT: 23. ~6 3:i. 28 39.40 47.52 5:5.64 $3.76 7:1.88 80. O0 · SAMPLE: WELL: ,,,'WEST STAINES ~! DEPTH: '1~710 ANALYZED: Fri,,.Mar t6, ~990 ~: t0: 5B pm /RESUL~/WF4~47 GTX.RES METHOD: 'GTXGC~ 0 ' PETROLEUM GEOCHEMISTRY /.GNH PGC AUTO SAMPLE : NELL: tdEST STAINES ~! DEPTH: 11710 II-IJECTEO AT : Tue Apr 17~ 1990 ?:25:29 am INSTRUMENT : GPGC_2 METHOD USED : /METHOD/GPGC2_O. MTH _ RESULT FILE : /RESULT/t, JF4247iO GPG.RES I BLANK F!LE : /RESULT/BLANt<iS_GPG. RES AREA SLICE INTEGRATION TOTAL AREA AREA AREA PERCENT 2282390. 8.3 2964128. 8.8 8911876. 26.6 ?3?4954. 22.0 9838402. 29.3 1688621. 5.0 FRACTION METHANE o GASES GASOLINE KEROSENE GAS-OIL NAX-DISTILLATE SAMPLE ~IT~ : 23.88 rags .. SAMPLE GOGI = .21 THiS IS-OIL PRONE .. -. METHANE + GASES = GASOLINE+KEROSINE+GAS OIL+~AX DISTILLATE = 82.9 BY FACTOR ANALYSIS OF I<EROGEFI..,-.u~.Ov°'~' vc4'rc,._,,., ,_ THiS !S AN OIL+GAS SOURCE - , - . : - ..... : ..... _ .~ ,: ......... ~ ~_ ...... THiS ANALYSIS DETERMINES KEROGE;',' POTENTIAL AT '-iTS PR£SENT M~TURITY. TH!S IS NOT A KEROGEN TYPE ANALYSIS. . ....-: :---..' -'.GMG,. Da.ta...Repo.r.t .No... !5.9.... -- . .... _ .... ..... .-:--...-. ~..-...-,.:, ,...:. _ :. - .-:..:.. . Page_ 1.95/22.6- C:3 (:3 iO.Ot 8.60 7.i8 5.78 0 0 iO.O0 minutes RESULT: ~ .I i ......... I. . , I , I , ,I,, , I .... I ,, I ...... :' L~.O0 30.00 40.00 ~:~). O0 6~). O0 70.00 ii7iO ':, SAMPLE: NELL: .'.NEST STAINES ~i DEPTH: ,. ' ANALYZED:' Tue Apr i7, 1990' 7: 25:29 am /RESULT'/NF4247~O GPG,RES METHOD: GP$C2 0 .00 's.' .e~ue. nce :' ./Chem/msd/042790. s . . Normalized-perCent Report . Information from Current .Data File Header: File: /chent/msd/WF4247_SAT. d '..Operator :. Date Acquired: Fri Apr 27 90 09:29:04 PM Sample Name: WF4247_SAT Misc Sequence Index: 1 "Bottle Number: 18 aepetit on Number: .. SATURA~ BIOMARKERS Calibration Table Last Updated: Sun Jun 10 14: 34: 58 1990 .. . Reference Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 0. 250 Absolute Minutes Default Sample'~t: 0 Un~. Peak Response Facbor: 0 Default 14ultipli~: 1 1 3 5 6 8 9 10 13 15 16 17 18 20 21 22. 25 . 26 Run: 6 W W W W W W VV W W W W W W W W W W W W W · W- W W 39.823 40.498 40.805 42.828 42.948 43.270 -'--'43,.878-- 44:.232 44%845 45,845 46,036 46,329 46.408 46. 574: .. 47.122 47.390 48.585 ..--3: 48.968.-. 50.260 .' 50.823 52.253 · ',-- 53,085., 27.231 36.193 ., 36.840 191.00 amu C27 _18A HOPANE.TS 191.00' ainu C27 i7A: HOPANE TM ':': ' . 191.00 ainu .~C28 BISNORHOPANE X . 191.00 amu -C29 HOPANE'D' "- 191.00 amu C29 NORHOPANE D2 191.00 amu C30 PENTACYCLANE PI i91.~Oo"am~':'c30 'ISA-OLEANANE-B-~-" 191.00 amu C30 HOPANEG 191.00 amu 191.00 amu 191,00 amu 191.00 amu' 191.00 amu 191.00 amu 191.00 amff 191.00 amu 191.00 amu 191.00 amu 191~00:amu--.- 191.00 amu 191.00 amu 191.00 amu C30 MORETANE K. C315 HOPANE N C31R HOPANE O O & GAMMACERANE GAMMACERANE P C32S 'HOPANE U: C32R HOPANE- V ~29511 :'552851 '~' 86537 '852444 535087 255478 ~52541'- 1510866 234562_ 703522 608720 120257 52792 261895 3.414 ::'3,564- - '-0,5579 5,496 3.4:50 1.64:7 0;3387' 9.741 1.512 4.536 3.924 0.7753 0.3G03 -1.688 % % % % .%, % % % % % % % :. 544:888 >: -3,513 - %:?..~ : . 33064:6 !:" - 2.132 . C33S HOPANB ALPHA - 315788, ': 2. 036 C33R HO. PANE.:BETA -.,- _ ,: ,-.. ....219239_:i.~:.:~ 1:.-~!3 .-, C34s aOPaNE:GaMMA C3'4a HOPANE DEr. a C355 HOPANE' EPSILON - ' 188458. :~::-' 1. 215" ~04:175 ·0.6716 162056 1.045 191-.00,.amu.- ..... C35R...,HOP~NE'~:'Z~: .... -.:z....:..-97~01::~_0.62~9'..% ' '- * '- ' ' - i ' ' ' ° ' ' ; '" 217.00 amu C21 STERANE- Y .. 316118~-:,2 038. 217.00 amu. C275 ba DIAsTERANE10.-, 431750 2.783. 217.0'o'~mu C27R ba' DIASTERANEll : 336978" 2,172 June 10, 1990 GMC Data Report No. 159 . Page: 1 Page 197/_226 ._ Sequence: /chem/msd/0¢2790.s Vial: 18 Injection: 1 Peak Int. Ret. Signal Num -Type Type Time Description Compound Name Area Amount 27 28 29 3O 31 32 33 35 36 37 38 39 40 41 42 43 45 46 W W W VV BV W W 'W W VV W W VV W VV W VV W BV W 37.277 217.00 amu 13 37.618 '217.'00 amu 1¢ 37.751 '217.00 amu 15 37.871 217.00 amU 16 38.465 217.00 amu 18 38.529 217.00 amu 19 38.913 217.00 amu 20 39.193 217.00 amu 21 39.302 217.00 amu 22 39.632 217.00 amu C27R aaa STERANE 25 39.907 217.00 amu 27 ¢1.458 217.00 amu C28R aaa STERANE 36 41.990 217.00 amu C29S aaa STERANE 39 ¢2.978 217.00 amu C29R aaa STERANE 42 39.126 218.00 amu C27R abb STERANE 2lB 39.296 218.00 amu C27S abb STERANE 22 40.869 218.00 amu C28R abb STERANE 33A 41.030 218.00 amu C28S abb STERANE 34 42.308 218.00 amu C29R abb STERANE 40 42.440 218.00 amu C29S abb STERANE 41 156153 1.007 167301 1.079 259254 1.671 314006 ~2.024- 150792 '" 0.9722 235040 399824 2.578 521963 273517 1.763 267961 1.728 4572¢8 2.948 223066 1.{38 267415 1.72¢ 247339 1.595 388844 2.507 302455 o 1.950 365258 2.355 371276 2.394 341539 2.202 396330 2.555 *** REPORT ERRORS *** m Calibration Peak #7's Qualifiers= Were Not Satisfied. *** Not All Calibrated Peaks FOund *** . - ... -.. . . -. .. Run: 6 June 10, 1990 GMC Data Report No. 159 Page: 2 Page 198/226 14000 .. ; ooo' ' :. ~000 6000 400~.' 2000... .. AbUndance Abundance ,' . . · '. Ion 17~ O0 amu ;, · · o, · from WF4247_SAT. d ,, 40 42 ' '44 46 "~ ' 48 T~.me (m~,n.) Ion 191.O0 amu. from WF4247_SAT.d 3000~'.. ooo0' 4Q. 42. 44' 46 "' 48 50 '., ': , ,, Time (min.) , ,52 54 AIsunda 30000 ,, · ,, ~ooo.o - ~ 000"0 ~on 36, 38 40 ',, .' ~ ~9~..00 ainu. from ~4F4247._SAT. d ,'42 44 ' 46 Time (min.) · · 30000 · ~0000~ - .. Ab',undance ',, ,, :,ooo0', 800~, 600~ 400~ Ion 191.00 emu. fr'om WF4247_SAT.d ,;. rXme (m:l'n.) Ion ~t7,00 amu. fPom WF4~4?._$AT.d ' Tf~me (mf~n.) 50 5O A~undance: , ,. i~ ~oooO - 6000 - 400,0 - Ion 2~7,.0"0 amu, fr'om XF4247_SAT.d ,. ,, ! I ' I "'" 40 T~me (min.) . I ' I 44 .' ] _ PETROLEUM -GEOCHEM I STRY SARA ANALYS!S SAIIPLE NAME. : .WEST STAINES INSTRUMENT : !NOECT TIllE : METHOD USED : · . SEQUENCE : REcU' T FILE : REPORT TIME : 12545-12560 HPLC_F I D Wed llav o 1°°0 ll'5?:st am /METHOD/HPLC-.FI D0 ~ MTH /D~T~/LOOP/SEOUEI4CE/HP i 09 0 _~IJTOC~. SEO /o~e,.~/i,t~-x~zo S~P RES ~o:/_~q PM. WED ~ 9 MAY ~ 19o0 - RESPONSE AREA T I ME FACTOR Saturates 11463. Aromat ics 1 4862. Aromat {cs 2 i0322. Polar~ 24788. 5.29 .1275E-03 9.42 .5470E-04 14.36 .5470E-04 19.96 .4160E-04 Saturates '~romatics Poler~ Saturate~ Aromatics Po.lar~ Asphaltenes . AMOUNT (mg) 1.46 1.03 OIL 41.} 23.4 29.1 . 6.2 RES I DUE 44.0 26~0 31.0 1.35 .93' O. O0 minutes .'7 ; i., f RESULT' 3. !2 6,25 9.38 t2.50 .. · 'SAMPLE: ~fEST STAINES #1 12545-12560 'ANALYZED: h'ed !'May 9, !990 11: 57:51 am /RESULT/%~F4248 SAP.RES HETHOD: HPLC FIDO ,, L ...... ,. __._.L_.~' ....... ! .... __~ ..... J 15.63 iS. 76 21. es a5 .ol ~'~ PE'i-ROLEUI"i GEOCHEMISTRY SATURATE'GC SAMPLE NAI'IE ! NSTRUMENT INJECT TIME METHOD USED RESULT FILE REPORT TIME : [dEST STRIiqES ~1 12545-12560 : HP_5890_2 : Sun May 6¢ 1990 10:40:14 am_ : /IqETHOD/SRT5890E.MTH : .,,ARCHIUE/WFq248_SAT.RES : 4:06 PM TUE.~ 12 3UNE~ 1990 CPI UALUE : .88 PRISTANE / PHYTANE : PRISTANE / C12 : PHYTANE / C18 : 1.18 C15/C25 : .91 C17/Pr : .76 C18/Ph : AREA %AREA NALK TIME NORM-C15 N-C10 N-Cll N-C12 N-C13 N-C14 N-C15 N-C16 N-C17 N-C18 N-C19 N-C20 N-C21 N-C22 N-C23 N-C24 N-C25 ' :'-N-C26 N-C2? N-C28 N-C29 N-C30 N-C31 N-C32 .l>l. ~-C33 N-C34 N-C35 N-C36 o O. 0. 0. 548. 1870. 3475. 4621. 4726. 4298. 4337. 5555. .3963. 3194. 3566. 2993. - - '328.9, 1775. 2098. 1872. 1210. 939. 847. 852. 1465. 917. 733. 0.0 0.0 0.0 0.0 1.0 3.3 6.1 8.1 8..3- 7.5 7.6 6.2 6.9 5.6 6.2' 5.2 5.1 2.1 1.6 1.5 1.5 1.6 1.3 0.00 O.O0 0.00 0.00 0.00 0.00 0.00 0.00 14.19 .29 16.04 1.00 17.29 1.'86 '22.52 25.95 · . . 25.31 26.62 27.88 29.09 30.25 '5-i. 37 32.44 33.48 34.49 3~. 46 36.40 37.32 58.26 _ 40 . 41 19.44 2.47 2i. 02 ' '" .... '"'2-] ~-~ ....... -- -' '2'30 2.32 1.90 2.12 1.71 1.91 1.60 ..... ~.- --.-! .,-76 .~ - - 1.12 1.01] .65 .50 .45 .46 50 .... 78 -. .47 .49 . .83 .39 'AREA -%-AREA ISPR '-' :.: T-I-frlE .-:.. !:; -.: ....... . Farnesane O. O. 0 O. O0 Acvc I ic' C16 365. 3.7 15.39 :: ..:~ ..-......, ~ ,....~- . . .. Acy'c 1 i ~ i-ci8 ..... '" Ii52';4 -' ';'"' '"':":' '1'6'76:' -' ......... 18'.:'&-6":'--:--"': .... ' ........ .- '- - -'- .... :- .... - ..... -"--- -- --. .... - -- -.-~ - Pristane 4215. "' ' 43;'1 19.60 " Phsstene -3579~-- 36.6 - .. 21.22 ._ 2 53 2 40' 2 26 98 , I ,, ,,,, 5. oo ~o. oo ~5. oo 20. oo 25. oo 30. oo 35. oo m~nutes , SAHPLE: WEST STAINES #i 12545-12560 ANALYZED: Sud Hay 6, 1990 J0'40' 14 am RESULT: /ARCHIVE/WF4248 SAT.RES METHOD: SAT5890E 40.00 45,00 :,,, -.'..~-~...*- PETROLEUM GEOCHEMISTRY x GNH ROCK EUAL SA:"-~PLE : idELL: ',,.,'EST STAINES ~I DEPTH: 12560 " 49 · ] ,.~-lr,-'T:r', A'..r Thu lla',,: -" ., oD 0 i: 12: prc~ i 1~..I..-~-,/ ~..[I '" .... ~ '~ GROCK ! I~S~ :~.d, ,£I-.T .,~ -r ilc. r.n : /METHOD,'PYRO5 !"11H ! .... THUD :,cc-:. :, = F'!LE : /RESULT/I~JF42487 GRO RES P, LA!'?.-<' F I LE : /RESULT/BLANKI"'.._GRO. RES AREA SLICE INTEGRATION AREA YIELD ~976064. 117998100. FRACTION 1.39 S1 6.51 S2 SAMPLE tJT. : 32.10 mgs TAa× ':"' 4'4'!'C ,,, GMc -Data., R~p.oi~t.-.N(~ -..159 .... -Pa:ge 2'0)7/226- --:-'! '- - --: PETROLEUM GEOCHEMISTRY ./ GNH PL]C AUTO ~'.*.'.*.*. SAMPLE ' : L, JELL: WEST STAINES ~l DEPTH:. It-4JEC'TED AT : Thu Mas: *; 1990 11:t2:48 pr;, ] . c c.~ 'I' t 4,..,T, ,:~. 1ElxT : GPGC_2 METHOD USED : /METHOD/GPGC2_0.MTH ...... U~T 'F!'LE : /RESUL'T/L, JF42487_GPG. RES BLANK FILE : /RESULT,'BLAI',IK15 GPG.RES AREA SLICE INTEGRATION AREA AREA PERCENT FRACTION TOTAL AREA : 5959549. ~5178656. 45559888. ~8589808. 2~6~2864. 1868~09. - ' - : ~- ~ c - _ - . _ . . .... ;_ . 148969090. SAMPLE wT. : ~2.10 mgs 4.0 METHANE 23.7 GASES 29.3 GASOLINE 25.8 KEROSENE 15.9 GAS-OIL 1.3 WAX-DISTILLATE . AREA ~: 100.0 SAMPLE GOGI = THIS IS GAS + OIL PRONE METHANE + GASES = 27.7 GASOLINE+KEROSINE+GAS OIL+WAX DISTILLATE = 22.3 BY FACTOR ANALYSIS OF KEROGEN PYROLYSATE '-. THIS-IS A GAS+OIL SOURCE THIS ANALYSIS DETERMINES KEROGEN POTENTIAL AT ITS PRESENT MATURITY. THIS IS NOT A KEROGEN TYPE ANALYSIS. .......... '~--~-T~ ....... -,. ........ . .......... . - . - . ....Page 2.08./226 26.9! 2~.94 t6.97 t2.00 7.04 ~t~dtes RESULT: . i ii i iii i! i i iii L i i l ,. . 9.37 /RESUL?/NF4E487 GPG.RES i ml i i · i i i i , ;1 , t8.75 28. t2 37, r)O 48.87 E~6.25 65.62 ~ SAHPLE: NELL:" NEST STAINES fi DEPTH: iES§O. - . ANALYZED:Thu' Hay 3, t990tt: t~: 48 pm , METHOD: 'GP~CE 0 . 75.00 Sequence: ./chem/msd/051190 .SAT. s viai: {s' . ...... Injection: Normalized Percent Report Information from Current Data File Header: File: /chem/msd/WF424:8_SAT.d Operator: Date Acquired: Fri May 11 90 09:27:39 PM Sample Name: WF42R8_SAT Misc Info: Sequence Index: 1 Bottle Number: 48 Repetition Number: SATURATE BIOMARKERS Calibration Table Last Updated: Thu Jun 07 14:02:48 1990 Reference Peak Window: 0.250 Absolute Minutes Non-reference Peak Window: 0.250 Absolute Minutes Default Sam~leAmount: 0 Uncalib. Peak Response Factor: Default Multiplier: I Peak , Int. ~-'Ret. Time Description .-. -Name Amount 1 2 3 6 7 8 9 10 11 12 15 16 17 18 . 19 20 21 23 25 26 vv W VV W VV , 39.750 :191. W 40.406-191. W 40.844 191. W 42.753' 191. .W.... 42..860. 1.9.i.. W 43.165 191. W 43.896 191. W 44.141 191. VV '44.762 191. VV 45.764 191' VV 45.964 191. W 46.197 191. · W 46.252 191. VV 46.490 ~ 191. W 46.621 19t. W 4:7.053 191. 47.319 191. ~'-""--48.'5'21'--'i91-~ 48.9O3 191. 50.~89 191. 50.759 1'91. W 53~002 ' - -W .-. 27.177 pv 36.107 ~Y 36.752 00 amu "C27 18A HOPANE TS - 297023 00 amu .C27 17A HOPANE TM 542047 00 amu. 'C28 BISNORHOPANE' X 6179 00 amu C29 HOPANE D ~: . :: - : ' 560836 0O.amu 00 amu O0 amu O0 amu O0 amu O0 amu 00 amu 00 amu 00-a mu O0 amu C29.,NORHOP.ANE .,_. 0,2. .... -_ _ . 2~93163 C30 PENTACYCLANE PI C30 18A OLEANANE B C30 HOPANE G C30 MORETANE K C315 HOPANE N - C31R HOPANE O O & GAMMACERANE 00 amu <' R :'-' O0 amu :-: C325 HOPANE U O0 amu C32R HOPANE V O0 -amti - ' ' C~'3S' HOPANE:'ALPHA' · 00 ainu C33R HOPANE BETA 00 amu C345 HOPANE GAMMA 00 amu' C34:R HOPANE DELTA . 94299 19266 1053625 264290 546727 379653 6402 -GAMMACERANE 65218 P ..........::~ ..... : .... :-~-~?~ : .... ~163944 14581 422902 198727 ..... 346460 116732 190678 6'2082 i 9'1 ?'00: ~."; -" !'C35S "HOP/~NE"EPSIIX)N ": '":' ~1'93:172 191.00 amu ' C35R HOPANE ZETA 74867 217.00 .amu . .C21 STERANE-' Y · 613929 217.00 amu C275 ba DIASTERANE10 12a_4978 217.00 amu C27R ba DIASTERANE1~. 893329 ' ' ·: ' ' "" '- ' ' 'f' ' : : - - :i - * . . . I. 182 2.156 0.02458 2.231 1.166... 0. 3751 % 0.07664 %. 4.192 % 1.051 % 2. 175 % 1.510 % 0. 02547 % 0. 259.4 . % 0.6522 % 0.05801 1.682 % 0.7906 % 17378-"- '~-.%" 0.4644 % 0.7586 % 0. 247O % '0""~ 7685:"'.' %'~' - - 0 '2978 .2.44:2 - %. 4.953 % 3.55~ % Jcute 7, 1990 Page: i P~np. 2t 0/226 .. Sequence: /chem/,-r~d/051190_SAT.s' Vial: 48 Injecti°n': 1 Peak I~t. Ret. Signal Num Type Type Time Description Compound . Name 27 W 28 W 29 W 30 W 31 W 32 VV 33 PV 34 VV 35 W 36 VV 37 VV 38 W 39 W 40 PV W W 45 PV 46 W 37.319 217.00 amu 13 37.192 217.00 amu 37.658 217.00 amu 15 37.790 217.00 amu 16 37.926 217.00 amu 18 38.443 217~00 amu 19 38.823 217.00 amu 20 39.101 217.00 amu 21 39.302 217.00 amu 22 39.544 217.00 amu C27R aaa STERANE 25 39.821 217.00 amu 27 41.377 217.00 'amu C28R aaa STEPJINE 36 41.893 217.00 amu C29S aaa STERANE 39 42.893 217.00 amu C29R aaa STERANE 42 39.036 218.00 amu C27R abb STERANE 21B- 39.203 218.00 amu C275 abb STERANE 22 4372 0.01739 % 466036 1.854 1065540 4.239' 1088085 4.329 161314 0.6417 824682 3.281 1727131 6.871 1177278 4.683 388246 1.545 1133721 4.510 722061 2.872 1459079 5'.804 708816 2.820 720625 2.867 878816 ~..496 654155 2.602 40.777 218.00 amu C28R abb STERANE 33A 1060007 4.217 % 40.945 218.00 amu C28S abb STERANE 34 916982 3.648 % 42.220 218.00 amu C29R abb STERANE 40 627477 2.496 % 42.350 218.00 amu C29S abb STERANE 41 687628 2.736 % *** REPORT ERRORS *** Calibration Peak #7's Qualifiers' Were Not satisfied. *** Not Ail Calibrated Peaks Found *** · . June 7, 1990 '~ 6000" ~oo0' ,4o0o: 300'0' 200,~ ., .to00' ,. Ion i77, O0 amu, · ,' from.' HF424B_.SAT, d ,, ,, ,. 44' 46 48 50 52 Time imin .) Ion 5gl.O0 amu. from..~F4~48._SAT.d .. ° ':000 2O000 .16000 Abundanc'e. , _I 2, 0 o o 800o 4000 46 48 50 52 54 Time '(min.) Abundance't: ,. · .. sO0'O0 ,, .. ,, !6000 ,. · · . ,, ,, 8000 .'. ,.,, Ion lgl.o0 amu. ,. from. WF4248_SAT .d 4'0 42 44 " 46 48 50 5.'2. T~me ::.'(min.) Z Abundance 280,00 24000 ,, ,',. 20000 ., 16000 ,, .. o"bo 8000 O'oo Ion 2.~7.00 amu. ,, .. ,'. from' 'WF4248_SAT. d 3'6 38 40 :' 42 A~undance ~'. 2400.'0 2000'0 . ~ 600.,0 ~.2000 800',.0 '"'" 4000 - Ion &9~.O0 amu. -, from Abunda,nce ",, WF4248_SAT. d .":, " 30 40 ' ~,' " T-~me (m~.n.) ' Ion 2t7.00 amu. from WF4248_SAT'.d .,~ 4O (min.) . 28000 - .', ;:,.~o0'o '''~.". 20000 '~ (-~000. ~ ' , o0'o 400'0 ' Time 3O PETROLEUM GEOCHEMISTRY *** SARA ANALYSIS SAMPLE NAI1E INSTRUMENT IH.]ECT TIME IqETHOD USED SEOUENCE RESULT FILE REPORT TIME : ~JEST STAllq£S ~1 12653-'12660 : HPLC'F!D - Wed May ?; 1990 '12:D8:45 pm .. : /METHOD/HPLC_FIDO-I1TH : /DATA./LOOP?SEOUENCE/HPZ090_AUTOCA-SEQ : /RESULT'/WF4249_SAP.RES . ~ I1AY , 1990 : 1:04 Pm WED , . RESPONSE AREA ' '' '~IME FACTOR Saturates 23405. . 5.29 Aromatics i 9811' '9.42 ~ 17~06 14 36 Aromatics ~ - ' Polars 50041. 19.92 .1275E-03 .5470E~04 .5470E-04'- .4160E-04 AMOUNT (mg) Saturates Aromatics- Polars 2.98 1.48 2.08 RESIDUE 45.6 ' 22.6 ~1.8 Saturates Aromatics Po lars ' P ispha I t~nes ~ OIL ~m ' 34.5 17.2 24.1 ...... 24.'2 .... -: _ -. ,, · . . "GMC' Da"ta"R'6p~':rf"No. 159-' ' ': ' ": 'Pa~e 2i'6/2'26`. 2.84 ., 2.36,_ 1.88 t' I .40 ' .92 _ ' .44 ,', ' t_ · 4-I .ri ro ,, , t~ to i 0,00 mznutes RESULT' 3.12 6.25 9,38 12.50 15.63 18.76 SAMPLE: t~EST 'STAINES #~ ~2653-~2660 ANALYZED: ~ed"May 9, ~990 !2:38:45 pm /RESULT/NF4249 SAP.RES 14ETHOD: HPLC FIDO 21 ,,88 25.01 PETROLEUM GEOCHEMISTRY SATURATE GC sAMPLE NAIdE INSTRUI1ENT INJECT TIME METHOD USED RESULT FILE REPORT TIME WEST STAINES 4~1 i2653-12660 HP_5890_2 Sun May 6, 1990 ii:35:43 am /METHOD/SAT5890E.MTH /RESULT/WF4349_SAT.RES 4:05 PM TUE.~ 12 3UNE~ 1990 CPI UALUE : .88 PRISTANE / PHYTANE : PRISTANE / C17 PHYTANE / C18 : .63 C15/C25 : .13 .66 C17/Pr : 1.50 .85 C18/Ph : 1.17 AREA -~AREA HALF .' TIME --NORM C15. N-CI0 N-Cll N-C12 N-Ci3 N-Ci4 N-C15 N-C16 -N~Ci7, ~...-.- . .... .~.. N-C18 N-C19 N-C20 N-C21 N-C22. N-C23 ' N-C24 N-C25 N-C26 :- ,..' · N-C2? N-C28 N-C29 N-C30. N-C31 N-C52 I4-C3 2,- N-C34 N-C36 O. 0.0.. 0.00 · 0.. 0.0 ... 0,00. O. 0.0 0,00 O. 0.0 0.00 . 259. .3 14.19 942. 1.0 16.04 1637. 1.7 17.79 :3966, 4.2 22.52 5~67, 5 7 23,95 6266. 6.6 25 '32 8227.' 8.7 - 26.63 784~." 8,~ 27,88 9042. 9.6 29,09 7~17. 7.9 30.25 - -' .... 868~-, ...... 9.2 ..... ., ...~ 1..~32 4772. 5.0 32,45 5105. 6.4 33..48 4134. 4.4 -=-4.49 . 3238. 3.4 35 46 2625. 2,8 ~6.40 2272. 2.4 37.32 i~3i. 2.0 38.26 ':28i7." ~.'o -.'- ~9..3o 1626. 1.7 40.48 1351. 1.4 41.83 0.00 0,00 . 0.00 0,00 .28 1.00 1.74 2.58 ' ~'79~- ..... 4,21 -- 5.70 6.65 8.73 8.33 9.60 7.98 .9__.-22 ..... '5 ."42 4.39 3.44 2 79 2.41 2.05 2.9-9- -' 1.73 1.43 Farnesane O. 0.0 .Acuclic C16 251. 5.! ' '"n~ ¥':'i'J'; ci'e.' :-:' ~' ':'"'..:..'" .' .,- fT*' -- '" ---? :is :-9- Pristane 1490. 30.'~ Phs, tene' '- ' .- 2380. - ' 48.6 GMC Data Report No. 159 Page 218/226 3.35 .. 3.06) 2.78 2.50 22 2. 5,00 ~0.00 mznutes ' RESULT: /RESULT:/WF4349 SAT.RES I II ~ ' I I ..... I II I Ii I I Ii ' I ~.5.00 20.00 25.00 SAMPLE: WEST STATNES #_1 .t.2653'-~2660 ANALYZED: Sun;;:.Hay6, 1990 _tl. 35' 43 am FtETHOB: SAT5890E m I , m I ..... ~ 30 O0 35. O0 40.00 zl~. ,00 NormaliZed Percent Report Informatio~ from Current. Data File Header: File: /chem/msd/WF4249_SAT. d Operator: Date Acquired: Fri May 11 90 10:36:34 PM Sample Name: WF42~9_SAT Misc Info: Sequence Index: 1 Bottle Number: 49 RepetitionNumber: · SATURATE BIOM~RKEP~ ...Calibrati(m T.able.La...st Updat~:..s. un Jun 10 13:58.:.56 1990 ._ Refereflce Peak Window: 0 250 Absolute Minutes Non-referen~ Peak Window: 0.250' Absolute Minutes ' Default Sa_?le Amount: 0 Uncalib. Peak Response Factor:_ 0 . Default l~ultiplier: 1 Ret. Signal _.:-~ . : :~.'~'~d ,.: , Time Descriptiou -" N~___-:~__- Area . Amount · . 1 7 8 9 10 11 12 13 14 15 16 17 18 · -- "19" 2O 21 22 "-'.. - 237* 24 ...25' .. 26 W W W VV W W W W W W W W W 47.058 amu W 47.329 amu W 48..529 amu '-:" ' 'W'"""~8'.-906- w so.189 W 50.748 39.770 191.00 40.421 191.00 · 40.853 191.00 amu 42.769 191.00 anm/ 42.874 191.00 amu 43.189 191.00 amu 43.9i3'i91'.:00:'am~' 44.155 191.00 amu 44%770 191.00-amu 45.773 191.00 amu 45.970 .1-91.00 amu - 191.O0'amu 46.266 191.00 amu 46.486 191.~0 191.00 191.00 191.00 191.00 19~;00/amu 191.00'a mu 191.00 amu VV 52.175 191.00' ainu "'"i .... ".--~v.¥:. ~-~---5~.::e~O.-.~.~o'O' ainu- · PV 27.179 217.00'a mu PV 36,122.217.00 amu W 36.766 217.00 amu amu .:~ C27 18A HOPANE-TS > · - _ - amu C27.- 17A .HOpANE TM ..': C28..BISNORHOPANE ' X., :.11279 C29 HOPANE D ' 1038384 C29 NORHOPANE D2 394313 C30 P .ENTACYC~ PI 153589 'C3b ~'SA'0L~E'B': ....... "98673 C30 HOPANE G 1698412 C30 MORETANE K 302784 C31S HOPANE N 1032227 C31R HOPANE O o & ~CERaNE GAMMACERANE .380541 1.192 .. % 747503 2.342 ...... % 0.03534 3.254 1.236 % 0.4812 % ' '0'~30'92'::"%~ 5.322 % 0.9487 % 3.234 -701292 ..2..197 %. -Not Found- 131922 0.4134 % p. . ' .. = 264938 '0..8301 ' %'" R -Not Found- 2:. 53Z % C32S HOPANE-U 807965 C32R HOPANE V 376383 1.179 C33S HOPANEALPHA 571937 .1.792 :~:--C33~-HOPANE-B~A,-'' '-~-'-.--1847.22 .... 'G.~788-::-%..~:~.. C34S HOPANEGAMMA 297065. 0.9308 C34R HOPANEDELTA 86470 0..2709 C35S'.HOPANE EPSILON 373987 1.172 · '. '-C35~"'HOPANE:~ET-A,.:-~-:~-:' ~'.¥.-:. 1&0884-. · -C21 S~E Y 495637 - 1' 5'53 C27$-.ba DIASTERANE10 . . 1421559 4.454. * . 'C27R ba DIASTERANEll' 990263 3.103 Run: 9 June 10, 1990 Page: 1 Paqe 22 0/226 .Sequence: /chem/msd/051190_SAT.$ Vial: 49 Injection: Peak Iht. Ret. Signal Compound Num Type Type Ti_-~__~ Description Name Area Amount 27 VV 28 W 29 VV 30 VV 31 BV 32 VV 33 PV 34 VV 35 W 36 W 37 W 38 VV 39 VV 40 VV 42 W 43 W 44 VV 45 BV 46 VV 37.204 217.00 amu 37. 676 217.00 amu 37.800 217.00 amu 37. 935 217.00 amu' 38. 390 217.00 amu 38. 459 217.00 amu 38. 837 217.00 ainu 39. 059 217f00 amu 39.307 217.00 amu 39. 555 217.00 amu 39.825 217.00 amu 41.391 217.00 amu 41.913 217~00 amu 42.908 217.00 ainu 39.048 218.00 amu 13 14 15 16 18 19 20 21 22 C27R aaa STERANE 25 27 ' C28R aaa STERANE 36 ;C29S aaa STERANE 39 " C29R aaa STERANE 42 C27R abb STERANE 21B 39.217 218.00 'amu 'C27S abb STERANE 22 40.792 218.00 amu C28R abb STERANE 33A 40.957 218.00 amu C28S abb STERANE 34 42.231 218.00 amu C29R abb'STERANE'40 42.365 218.00 amu C29S abb STERANE 41 500380 1.568 970694 3.041-',k' 997900 3.127 220866 0.6920 498577 1.562 772424 2.~420 1584390 4.964 793699 2.487 353768 1.108 933271 2.924 1533754 4.806 914511 2.865 775999 ~2.431 650631 2.039 1361325 4.265 1333638 .~1.179 1429509 4.479 ~351513 4.235 1002283 3.140 ~2333~8 3.864 . *** REPORT ERRORS *** : ~ .. . _ Calibration Peak #7's ~J. alifiers Were NOt Satisfiod. *** Not All Calibrated :'Peaks Found *** Run: 9 June 10, 1990 · . Page GMC Data Report No. !59 Page 221/226 Abundance' ~.0000 .2 8000 ,;. 600.0 4000 ~00'0 ,: A. bundan¢¢ ..' ,,,'; 0:300 - Ion-J. 77.00 amu. from .WF4249_SAT.d 3','.)000 20000 ~.0000 44 ... 46 ': 48 50 52 · Time '(m in. ) ]:on -~g&.O0 amu. fnom NF4P. 49_SAT.d 40 42 44' i i i i 46 4~8 50 . 52 54 T~.me (m~n.) ; ~bundance" IoN 19i.O0 amu, from WF424g_SAT. d 30000 ,. 20000 ~(}000 3.6 38 40 42 44 46 T~me (min.) 48 50 52 Ion 217.00 amu, ~nom;.WF~2~9_~AT,~ Abundance EO000 :OOO0 :' 36 ' 38 . , , 40 Til'ne (m:l,n.) 42 44. 30000 20000 Abundance iO000 0 Ion ~91.00 amu. from:, WF4249_SAT. d Abundance Ion 2'17.00 amu. Time i '(min.) from. WF4249_SAT. d 30O00 20000 ~0000 . ' 30 4O ', ,, : Time (min.) 5O 4.5t e ~'~tes ge.se ~s.~s ~.4o 47.~ ~.e~ e~.?e SAMPLE: ~ELL:KADLER ST ~i DEPTH: 5850 ANALYZEB: Sun May 6, t990 4:t7:54 pm RESULT: /RESULT/NF43038 GTX,RES METHO0: GTXGCt 0 7t 80.00
