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GMC Data Report No. 183
Geochemical data for an oil show project that included the following 10 North Slope well materials' Exxon Corp. Alaska State C No.l, washed cuttings (8,040'-8,250'); Home Oil Co. Bush Federal No. 1, washed, cuttings (5,500',5,610'; 6,800'-6,8.80'; and 9,220'- 9,300'); Mobil Oil Corp. Echooka Unit No. 1, x~ashed cuttings (12,740'-12,870'; and 12,870'-12,930'); McCulloch Oil Co. Fin Creek Unit No. 1, washed cuffings (7,100'-7,230'); Union Oil Co. of California E. De K. LeffingWell ~ No. 1, washed cuffings (13,790'-13,880'); Atlantic Richfield Co. Nora Federal No. 1, washed cuttings (5,590'-5,620'; 11,150'-11,190'; 11,550'- 11,650'; and 11,670'-11,730'); Atlantic Richfield Co. Toolik Federal No. 1, washed cuttings (8,300'-8,380'); Arco Alaska Inc. West Mikkelsen State No. 1, washed, cuttings (9,970'-10,030'; 10,030'-10,070'; and 11,210'-11,260'); Atlantic Richfield Co. West Sak 25618 No.20, core (6,691'; and 6,701'); and Mobil Oil Corp. West Staines State blo.2, washed cuttings (13,070'-13,110'). Received 13 May 1991 Total of 113 pages in report Alaska Geologic Materials Center Data Report No. 183 WELL Toolik Federal #1 Toolik Federal #1 Ech0oka Unit #1 Echooka Unit #1 Leffingwell #1 Leffingwell #1 Fin Creek Unit #1 West Staines #2 Alaska State C1 W. Mikkelson Bay #1 W. Mikkelson Bay #1 W. Mikkelson Bay #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Bush Federal #1 Bush Federal #1 Bush Federal #1 West Sak 20 West Sak 20 TABLE la Brookian II Samples and Extraction Data Sorted by Lab Identifier LAB IDENTIFIER DEPTH TSE TSE (ft) (rog) (kg/tn) WF4804 830O - 8330 WF4805 83.3O - 8380 WF4806 12740 - 12870 WF4807 12870 - 12930 WF4808 13790 - 13820 WF4809 13820 - 13880 WF4810 710O - 7230 WF4811 13070 - 13110 WF4812 8040 - 8250 WF4813 9970 - 10030 WF4814 10030 - 10070 WF4815 11210 - 11260 WF4816 5590 - 5620 WF4817 11150 - 11190 WF4818 11550 - 11650 WF4819 11670 - 11730 WF4820 5500 - 5610 WF4821 6800 - 6880 WF4822 922O - 9300 WF4823 6691 WF4824 6701 10.0 1.37 19.4 2.07 256 3.88 80 1.63 4.7 0.48 12.6 0.97 18.4 1.09.. 17.2 0.99 5.1 0.51 ~ 86 4.21 14.5 1.42 186 4.00 50 0.11 25.6 10.57 12.9 0.24 17.4 0.38 28.3 0.50 17.1 0.57 12.1 1.41 41 0.83 27.6 0.50 COMMENTS Combined into WF4805 Combined into WF4809 GMC Data Report No. 183 TABLE lb Brookian Ii Samples and Extraction Data Sorted By Well WELL LAB IDENTIFIER DEPTH TSE TSE (ft) (mg) (kg/tn) COMMENTS Alaska State C 1 Bush Federal #1 Bush Federal #1 Bush Federal #1 Echooka Unit #1 Echooka Unit #1 Fin Creek Unit #1 Leffingwell #1 Leffingwell #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Toolik Federal #1 Toolik Federal #1 W. Mikkelson Bay #1 W. Mikkelson Bay #1 W. Mikkelson Bay #1 West Sak 20 West Sak 20 West Staines fl~2 WF4812 8040 - 8250 5.1 0.51 WF4820 5500 - 5610 28.3 0.50 WF4821 6800 - 6880 17.1 0.57 WF4822 9220 - 9300 12.1 1.41 WF4806 12740 - 12870 256 3.88 WF4807 12870 - 12930 80 1.63 WF4810 7100 - 7230 18.4 1.09 WF4808 13790- 13820 4.7 0.48 WF4809 13820- 13880 12.6 0.97 WF4816 5590 - 5620 50 0.11 WF4817 11150 - 11190 25.6 0.57 WF4818 11550- 11650 12.9 0.24 WF4819 11670 - 11730 17.4 0.38 WF4804 8300 - 8330 10.0 1.37 WF4805 8330 - 8380 19.4 2.07 WF4813 9970- 10030 86 4.21 WF4814 10030 - 10070 14.5 1.42 WF4815 11210- 11260 186 4.00 WF4823 6691 41 0.83 WF4824 6701 27.6 0.50 WF4811 13070 13110 17.2 0.99 Combined into WF4809 Combined into WF4805 GMC Data Report No. 183 Page 2/113 WELL ~laska ,Stale G1 Bush Federal #1 Bush Federal #1 Bush Federal #1 I--chooka Unit #1 Echooka Unit #1 Fin Creek Unit #1 Letlingwell//1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Toolik Federal #1 W. Mikkelson Bay #1 W, Mikkelson Bay #1 W, Mikkelson Bay #1 West Sak 20 West Sak 20 West Staines #2 TABLE 2 Brooklan II SARA, Isotopes and Saturate Fraction Chromatography LAB DEP._....._..~_~ _ IDENTIFIER (FT) COMPOSITION (%) ~313C ~313C ~13C SAT AROM POLAR ,, ASPH _ _TSE SAT AROM 8250 .WF4812 32.2 20.5 35 12.3 -27.17 5610 WF4820 32.7 33 29.9 '4.5 -28.97 -28.87 -27.47 6880 WF4821 33.3 24.1 37.3 5.4 -28.24 -27.08 9300 WF4822 37.3 27.2 23.3 12.1 -28.65 -27.32 12870 WF4806 25.5 13.9 25.1 35.5 -29.60 -29.62 -28.93 12930 WF4807 29.5 13.8 25.2 31.5 -29.35 -29.01 -28,34 7230 WF4810 50,8 16.6 27.2 5.4 -29,45 -27.85 13880 WF4809 19.5 41.4 18 21.1 -28.94 -28.14 5620 WF4816 * -27.35 11190 WF4817 46.3 31.3 15.5 6.9 -28.76 -27.33 11650 WF4818 23.3 39.2 27.7 9.8 -26.81 11730 WF4819 27.3 25.2 37.7 9.7 -27.81 8380 WF4805 19.3 19.2 50.5 11 -27.71 10030 WF4813 55.9 15.5 24.5 4.1 -29.27 -28.73 10070 WF4814 45.3 35.9 10.6 8.1 -27.42 -27.55 11260 WF4815 33.9 18.1 19.4 28.6 -29.48 -29.94 -29.01 6691 WF4823 60.2 25.8 10.3 3.7 -29.14 -29.79 -27.86 6701 WF4824 66.9 .'2.6 25.3 5.3 -29.02 -29.50 -27.51 13110 WF4811 33.2 15.7 34.9 16.2 -28.44 -28.98 -27.71 Pr/ Pr/ Pr/ ....... CPI , Ph .,C!7. _C18 1.52 2.36 0.61 0.48 0.95 1.7 0.52 0.49 1.3 1.63 0.57 0.49 0.83 1.63 0.44 0,39 1.05 1.54 0,59 0.31 1,05 * No SARA data was obtained for samples WF4816 because the detector malfunctioned during the run. No additional material was available for a repeat analysis. s Sample size very small; results have less precision than for other samples. WELL Alaska State Cl Bush Federal #1 Bush Federal #1 Bush Federal #1 Echooka Unit #1 Echooka Unit #1 Fin Crook Unit t11 Leffingwell #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Nora Federal #1 Toolik Federal #1 w. Mikkelson Bay #1 W, Mikkelson Bay #1 W. Mikkelson Bay #1 West Sak 20 West Sak 20 West Staines #2 DEPTH (ft) 8250 5610 6880 9300 12870 12930 7230 13880 5620 11190 11650 11730 8380 10030 10070 11260 6691 6701 13110 NR = Not repodable, TABLE 3 Brooklan II Saturate Biomarker Parameters LAB IDENTIFIER S,1, ..... S2 -, ,,, S3 ............. S,4 (%) (%) S5 M4 (%) (%) WF4812 0.33 0.81 24.7/36.1/39.2 WF4820 0.27 0.46 23.1/15.5/61.4 WF4821 0.39 0.27 61.3/14.4/24.2 WF4822 0.55 0.63 39.1/27.1/33.8 WF4806 0.52 0.54 36.6/21.5/41.9 WF4807 0.52 0.45 39,7/31,3/29,0 WF4810 0.54 0.60 30.4/23.8/45.9 WF4809 0.47 0.46 25.3/33.5/41.1 WF4816 0.56 0.54 30.4/24.8/44.8 WF4817 0.53 0.51 33.3/28.0/38.7 WF4818 0.39 0.46 25.9/29.0/45.1 WF4819 0.45 0.58 32.9/34.3/32.8 WF4805 0.17 0.50 8.2/13.8/78.0 WF4813 0.52 0.48 23.8/40.3/35.9 WF4814 0.48 0.52 23.8/34.6/41.6 WF4815 0.62 0.57 37.6/26.7/35.8 WF4823 0.56 0.58 22.3/29.5/48.2 WF4824 0.57 0.59 23.5/29.0/47.5 WF4811 0.54 0.56 27.1/29.2/43.7 11 5/17, 21 9/33. 64 1/17. 37 6/29, 32 0/30. 38 7/35, 30 3/29. 29 0/33. 34 4/24. 31 9/31. 21 8/34. 37.3/29. 13.6/19. 23.5/39. 29.5/31. 36.5/27. 20.0/31. 21.9/25. 30.1/30. H1 5/71.0 54.7 71.8 0,65 3/44.8 71.4 75.3 0.42 8/18.1 81.7 62.9 0.68 3/33.1 60,8 66.6 0.63 5/37.5 59.1 78.4 0.62 9/25,4 63,6 67.0 0.68 2/40.5 53.7 59.6 0,65 7/37.3 54.7 64.5 0.62 2/41.4 49.9 84.8 0.65 3/36.8 66.4 60.6 0.69 1/44.1 78.8 57.4 0.56 7/33.0 65,9 59.9 0.54 8/66.6 47.0 78.0 0.45 9/36.6 60.3 56.7 0.64 8/38.8 50.2 65.9 0.62 1/36.4 53.1 74.5 0.63 6/48.4 72.1 72.8 0.67 5/52.7 61.6 75.4 0.64 7/39.2 61.9 69.6 0.63 ratio could not be calculated because one or more peaks could not be identified. H2 0.48 0.28 0.27 0.62 0.47 0,59 0,63 0.60 0.60 0.67 0.50 ,0.60 0.43 0.61 0.61 0.61 0.66 0.67 0.62 H3 . 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. H6 77 0 50 73 0 44 75 0 58 85 0 5O 85 0 47 84 0 48 87 0 53 84 0 47 81 0 33 83 0 48 98 0.50 79 0.41 67 0.16 86 0,44 87 0,49 91 0.46 84 0.46 82 0.42 90 0.58 ,. GC-MS BIOMARKER PARAMETERS TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF4812_SAT STERANE DISTRIBUTION Alaska State C-1 8040 - 8250 ft .RATIO COMPOUNDS VALUE si) s2) C29S/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB 0.33 0.81 S3) RATIO AAA 20R STERANES ABB 20S&20R STERANES COMPOUNDS C27 C28 C29 2&.7% 36.1% 39.2% 11.5% 17.5% 71.0% VALUE ss) M{) RATIO DIA BA/(DIA+ NON-DIAS~ES) (CALCULATED) C27-35 HOPANES/(HOPA~.S+STERANES C27-29) HOPANE DISTRIBUTION . . COMP~S 54.7% 71.8% VALUE H1) HZ) H3) H6) C32S/C32S+R. HOPANE · · C31S/C31S+R HOPANE C30 'HOPANE/HOPANE+MORETANE 18A/18A+17A HOPANE 0.65 0.48 0.77 0.50 GMC Data Report No. 183 Page 5/113 Ion ~9~.00 amu. from WF4Bt2,_SAT,d' Abundance t800 - 1600 1400 1200 1000 s~oo~z~ OZL. sHO~S 2 Alaska State 0-1 8040. 8250 ft Abundance t 400 - 300 20 30 Time (min.) 40 " 50 Abundance o ~ 1600 - o · Ion igi,o0 amu. from WF48i2_SAT.d ' i400 - 1200 - :tO00 800 600 400 e~OOKZA~ OZL SHO~S 2 Alssks Stste C-1 8040 - 8250 It 32 36 40 44 48 " Time (min.) Ion 2i7.00 amu. from WF4812_SAT.d · Abundance 440 4OO 360 · · 32O 280 2,4O 28 30 BROOKZAN OZL SHOWS Alaska State 0-1 8040 - 8250 ft 32 34 36 38" Time (min.) ~ 5000 · - 4000 Abundance 3000 2000 lO00 Ion i77.00 amu. from NF48i2_SAT.d BROOKIAN OIL SHOWS 2 32 34 Alaska State C-1 8040 - 8250 ft 36 38 40 42 44 46 48 50 Time (min.) Ion ~9i.00 amu, frOm WF4812._SAT.d Abundance 1600 - i400 - 1200 - lO00 - 800 600 400 32 34 i I I I I I I , I 36 38 40 42 44 46 48 ' 50 Time (min.) PETROLEUM SEOCHEMISTRY ~e SATURATE SC SAMPLE NAME : INSTRUMENT : IN3ECT TIME : METHOD USED : RESULT FILE : REPORT TIME : BUSH FED 41 5500-5610 FT. HP_5880 Mon Oct 22, 1990 9:40:09 am /METHOD/SAT_5880.MTH /RESULT/WF4820_SAT.RES 10:31 AM MON., 22 OCT., 1990 Bush Federal #1 5500 - 5610 ft CPI UALUE : 1.52 PRISTANE / PHYTANE PRISTANE / Ci? PHYTANE / C18 2.36 C15/C25 : .61 C17/Pr : .48 C18/Ph : 4.92 1.65 2.07 AREA H-CIO O. N-Cll O. N-C12 66. N-C13 245. N-C14 766. N-C15 1022. N-CId 776. N-C17 619. N-C18 529. N-Ci9 ' 209. H-C20 120. N-C21 125. N-C22 125. N-C23 197. N-C24 106. N-C25 208. N-C26 92. N-C2? 172. N-C28 70 .'- N-C29 147. N-CSO -. O. H-CSi 91. N-C52 175. N-C54 0. N-C55 O. N-C36 0. NAREA NALK TIME 0.0 0.00 0.0 0.00 1.1 10.05 4.0 12.14 12.8 14.10 17.0 15.94 12.9 17.68 10.5 19.52 5.5 20.89 3.5 22.57 2.0 23.79 2.0 25.15 2.1 26.4.5 3.5 27.69 1.8 28.89 3.5 50.05 1.5 51.16 2.9 52.25 1.2 33.27 2.4 54.27 O.0 O.00 1.5 36.18 2.9 57.09 5.8 58.01 0.0 0.00 o..o o.oo 0.0 0.00 NORM C15 0.00 0.00 .06 1.00 .61 .52 .20 .12 .12 .12 .19 .10 .20 .09 .17 .07 .14 0.00 0.00 0.00 0.00 AREA Farne~ane Jig. Acyclic C16 351. Ac~clic C18 254. Ph~tane 159. ~AREA ISPR TIME 9.5 13.70 27.9 15.3 0 20.2 18.55 29.8 19.48 Z2.6 21. 08 GMC Data Report No. 183 Page 10/113 c~ Bush Federal #1 55O0 - 5610 ft 2.07 .' u.j e_ c:r e 2.0:t 5.00 . tO.O0 :tS. O0 ~0.00 L~3.O0 30.00 35.00 mznu~:es SANPLE:BUSH FED #! 5500-56!0 FT. ANALYZED: Non Oct 22. ~990 9: 40:09 am RESULT: /RESULT/I~F4820 SAT.RES HETHOD: SAT 5880 40.00 45. O0 c~l I,"~I ~zd c~§I 'oN nodo%{ ~mQ DIAID GC-MS BIOMARKER PARA3~-?ERS -. TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF4820__SAT Bush Federal #1 5500 - 5610 ft STERANE DISTRIBUTION RATIO COMPOUNDS VALUE s~) s2) C29S/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB 0.27 0.~6 s3) S4) AAA 20R STERANES ABB 20S&20R STERANES C27 C28 C29 23.1% 15.5% 61.~% 21.9% 33.3% 44.8% RATIO COMPOUNDS VALUE ss) H4) - DIA BA/(DIA+ NON-DIASTERANES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) 71.4% 75.3% HOPANE DISTRIBUTION RATIO COMPOUNDS VALUE H2) H3) H6) C32S/C32S+R HOPANE -. C31S/C31S+R HOPANE C30 HOPANE/HOPANE+MORETANE 18A/18A+17A HOPANE 0.~:2 O. 28 0.73 0.~4 I Adundance 4000 3OO0 2000 lO00 Ion ~g~.o0 amu. from WF4820_SAT.d Abundance 1600 1 1400 i200 - i000 8OO 600 4OO BROOKIAN OIL. SHOWS Bush Federal //1 5500. 5610 ft 20 30 Time (min.) Ion 2i7.00 amu. from WF4820_SAT.d 40 5O 30 · 40 50 20 T:i. me (m:ln.) Ab'dndance 4000 3000 2000 - lO00 Ion ~gJ,o0 amu. from WF4820_SAT,d ' I i ii BROOKIAN OIL SHOWS 23 Bush Federal #1 55O0 - 5610 ft 40 T~me (min.) , '' ' i ' ' ' I ' 44 48 c~ L~ Abundance Ion 217,00 amu. from WF4820_SAT.d i400 iO00 8OO 600 4O0 ' ' ' i ' ' ' I ' ' ' i 30 3E 34 : Time (min.) BROOKZAN O]::L GHONS ;~ Bush Federal #1 5500. 5610 ft Abundance 2200 - . 2000 · i800 . 1600 . i400 . i200 Ion ~77.00 ainu. from WF4820..SAT.d BROOKIAN OIL SHOWS 2 Bush Federal #1 5500 - 5610 ft ' 34 36 38 40 42 44 46 48 50 Time (min,) Ion 191,00 amu. fPom WF4820._SAT. d Abundance 4000 ' . 3000 - 2000 ~ ~000 34 36 r~ Z 40 42 44 46 48 50 ~ Time (min,) ~ PETROLEUM GEOCHEMISTRY SATURATE GC SAMPLE NAME : INSTRUMENT : .~!NJECT TIME : METHOD USED : RESULT FILE : REPORT TIME : 8USH FED $i 6800-6880 FT. HP_5880 Mon Oct 22, i990 i0:38:23 am /METHOD/SAT_5880.MTH /RESULT/WF4821_SAT.RES 11:29 AM MON., 22 OCT., 1990 CPI UALUE : .95 PRISTANE / PHYTANE : PRISTANE / C12 : PHYTANE / C18 : N-CiO N-Cll N-C12 N-C13 N-C14 N-C15 N-CiO N-C12 N-Ci8 N-C19 N-C20 H-C21 N-C22 N-C23 N-C24 N-C25 N-C26 N-C2? N-C28 N-C29 N-C30 N-C31 N-C32 N-C33 N-C34 N-C35 N-C36 AREA 0. 0. 0. 186. 282. 254. 152. 100. 141. 240. 256. 253. 228. 280. 226. 216 ' 198. 166. 299. - O. O. 1.70 C15/C25 : .52 C17/Pr : .49 C18/Ph : ! - ~AREA NALK TIME 0.0 0.0 0.0 1.5 4.3 7.8 6.5 5.9 3.6 2.3 1.2 3.3 5.6 5.9 5.9 6.4 6.5 6.4 5.0 4.6 4.1 1.9 3.9 6.9 0.0 O.p 0.0 0.00 0.00 0.00 12.14 14.11 15.94 12.68 19.32 20.88 22.32 23.29 25.15 26.45 22.69 28.89 30.04 31.15 32.23 33.26 34.26 36.17 32.08 38.01 0.00 0.00 0.00 1.21 1.93 2.03 NORM C15 O.O0 0.00 0.00' 1.00 .84 .4;7 .22 .42 .83 .82 .24 .49 .8~ 0.00 0.00 0.00 Farne~ane Acyclic C16 Acycli¢ C18 Phytane AREA 0. 100. 132. ~AREA ISPR 0.0 22.5 25.0 jj.O L9.5 TIME 0.00 15.30 18.59 19.48 21.08 Bush Federal #1 6800 - 6880 ft GMC Data Report No. !83 Page 17/1 2.~0 · Bush Federal #1 6800 - 6880 ft 0 N 4 s.o_ so.oo ~5.oo ao.oo as.oo ~o.oo ~.oo Ill~. n u T. es SAHPLE: BUSH FED ~. 6800-6880 FT. ANALYZED: Non Oc~: EE, ~990 lO: 38:E3 am RESULT: /RESULT/I~F482! SAT.RES HETHOD: SAT 5880 40.00 45,00 GC-MS BIOYJtRKER PARAMETERS TITLE': BROOKIAN OIL SHOWS 2 ANALYSIS: WF~821_SAT STERANE DISTRIBUTION RATIO COMPOUNDS si) S2) C29S/C29S+C29R STERANE C29R&S ABB/C29S&R AAA+ C29R&S ABB Bush Federal #1 6800 - 6880 'ft VALUE 0.39 0.27 $3) s~) AAA 20R STERANES ABB 20S&20R STERANES C27 C28 C29 61.31 1~.~% 24.2% 64.11 17.81 18.11 RATIO COMPOUNDS VALUE ss) DIA BA/(DIA+ NON-DIASTSiRANES ) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) 81.71 62.9% HOPANE DISTRIBUTION RATIO COMPOUNDS VALUE HI) H2} H3) C32S/C32S+R-.HOP~E -. C31S/C31S+R HOPANE C30 HOPANE/HOPAN~+FDRETANE 18A/18A+lTA HOPkNE 0.68 0.27 0.75 O. 58 GMC Data Report No. 183 Page '.,9/113 Abundance 2000 - 1800 1600 ': 1400 i200 ooo W 800 _t 600 · 400 , Ion ~9~,00 amu. from WF4821_SAT.d s~oo~t~s o2c SHOWS Bush Federal #1 6800 - 6880 ft Ct Abundance 1200 1 iO00 - 8OO 600 400 200 2O 3O Time (min.) Ion 2t7.00 amu. from WF482i_SAT.d 4O 'i I ' ' ~ I ' ' " 30 40 Time (min.) Abundance lO00 9O0 800 - 700 6OO 5OO 400 - ,- Ion t91.00 amu. from WF4B2.i_SAT. d BROOK3:AN O3:1_ SHONS a Bush Federal #1 68OO - 6880 ft i 34 36 38 40 42 44 46 48 Time (min.) Abundance ~000 Ion 217.00 amu. from WF482i_SAT.d . 9OO 80O 7OO 600 500 300 't ' BROOKIAN O"['L SHOWS Bush Federal #1 6800 - 6880 ft 32 34 36 38 ' Time (min.) 600 - 500 ,100 Abundance Ion ~77.00 amu. from WF482~_SAT.d' Bush Federal #1 6800 - 6880 ft 34 36 38 40 42 Time (min.) 44 46 48 Ion igi.o0 amu. from HF482i_SAT.d fig I,.,) Abundance iiO0 lO00 900 80O 700 500 ' 400-, , .... ,' , 34 36 38 40 42 Time (mtn.) 44 46 48 PETROLEUM GEOCHEMISTRY SATURATE GC SAMPLE NAME INSTRUMENT IN3ECT TIME METHOD USED RESULT FILE REPORT TIME 8USH FED ~1 9220-9300 FT. HP_5880 Man Oct 22, 1990 11:36:41 em /METHOO/SAT_5880.MTH /RESULT/WF4822_SAT.RES 12:27 PM MON., 22 OCT., 1990 Bush Federal #1 9220 - 9300 ft CPI UALUE : 1.30 PRISTANE / PHYTANE : PRISTANE / C12 : PHYTANE / C18 : 1.G3 C15/C25 : 1.00 .57 CI?/Pr : 1.76 .49 C18/Ph : 2.06 AREA ~AREA NALK TIME NORM C15 N-Cia N-Cll N-C12 N-C13 N-CI4 N-C15 N-CiG N-C17 N-C18 N-C19 N-C2 0 N-C21 N-C22 N-C23 N-C24 N-C25 N-C2G N-C27 N-C28 N-C29 N-C30 . N-C31 N-C32 N-C55 N-C34 N-C55 N-C36 O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 58. 3.3 14.11 .52 112. 6.4 15.94 1. OO 131. 7.4 17.68 169. 9.6 19.52 1.50 121. 6.8 20.88 1.07 104. 5.9 22.57 78. 4.4 25.79 .70 174. 9.9 25.14 1.55 275. 15.6 26.44 2.45 199 . 11 . 3 27.69 1 . 77 125. 7.1 28.89 1.12 112. 6.4 50.04 1. OO O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 0'; 0.0 0.00 13.00 O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 102. 5.8 56.17 .91 O. O.O O.OO O.O0 O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 O. 0.0 0.00 0.00 O. 0.'0 O. O0 O. O0 Farnesane Ac~clic C16 Ac~clic C18 Pristane Phytene GMC Data Report No. 183 AREA ~AREA ISPR TIME O. 0.0 O.OO O. 0.0 0.00 23. ~2.2 18.54 96. 42.1 19.48 99. 29.8 21.08 Pa_,.'~-~ 24/i 13 2.~,0 , 2.07 e 2.0~ Bush Federal #1 9220. 9300 ft 5.00 . t0.00 t5.00 20.00 25.00 30.00 35.00 mznutes SAHPLE:BUSH FED ~. 9280-9300 FT. ANALYZED: Mort Oct 22, J990 ii: 36: 4i am RESULT: /RESULT/WF4822 SAT.RES METHOD: SAT 5880 40.00 45.00 " d z GC-M$ BICh'(ARKER PARAMETERS TITLE: BRC~KI~M OIL SHOWS 2 ANALYSIS: WF4822_SAT Bush Federal #1 9220 - 9300-ft STERANE DISTRIBUTION CC~MPOUNDS VALUE C295/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB 0.55 0.63 s3) s~) AAA 20R STERANES ABB 20S&20R STERANES C27 C28 C29 39.1% 27.1% 33.8% 37.6% 29.3% 33.1% RATIO COMPOUNDS VALUE ss) · DIA BA/(DIA+ NON-DIAST~--RANES ) (CALCULATED) C27-35 HOPANES/{ HOPAN~.S+STERANES C27-29) 60.8% 66.6% HOPANE DISTRIBUTION RATIO COHPOIJNDS VALUE H-~) H6) C32S/C32S+R HOPANE .. C31S/C31S+R HOPANE C3.0 P~0PAN E/H, OPANE+MOP~WTANE 18gJ18A+17A HOP.~E 0.63 0,6.2 0.85 0.50 GMC Data Report No. 183 Page 26/1 ] 3 t~jJ Abundance 800 1 1600 1400 1200 lO00 @00 soo ~ 400 ': Abundance Ion i9i,00 amu, from WF4822..SAT,d · IBROOK]:AN OIL SHONS 2 Bush Federal //1 9220 - 9300 ft i '~ i ' ' ' I ' ' ' I I 20 30 40 50 Time (min.) 3:on 2~7.00 amu. from HF4822_SAT.d iiO0 lO00 9OO · 800 700 600 5OO 400 SO0 ~0 '1 ....... i' , , I ' i , I 30 40 " 50 Time (min.) ~ Abundance 0 o 900 - 800 - 7OO 6OO Ion 191.00 amu. from NF4822_SAT.d ' IBROOKIAN OIL ~BHON~ ~ Bush Federal //1 9220 - 9300 ft 500 ,400 ..... , .... -,"~ ....... ,~ 32 36 40 44 48 ' ~ T:t, me (mtn.) ,--- Abundance Ion 2i7.00 amu. from WF4822_SAT.d ~ :: ..... ...... , ....... , i ...... I ..........' .... ' ......... "" I i ~" ~ I i ', " ..... i - ' ' , ' (IQ .... : ' I ~ ~ 28 30 32 34 36 38 ~ TSme (m&n.) . BROOKI'AN O~C SHOWS a Bush Federal #1 700 -' 9220 - 9300 ft · 600 - , 5OO ,, 300 ~ 560 Abundance 520 480 440 4OO ~ 360 32O " '" 32 Ion i77.00 amu. from WF4822_SAT.d ' BROOKIAN OIL ~HOWS ~ Bush Federal ttl 9220 - 9300 ft i ' ' ' i ' ' ' I .... i ' ' ' i ' ' ' i ~ ' t ~ ' I 34 36 38 40 42 44 46 48 50 Time (min.) Ion ~9i,00 amu, from WF4822_SAT,d Abundance 9O0 8OO 700 6o0 500 400 Ii 34 36 38 40 42 44 46 48 50 Time (min.) GC-~ BIOMAFd(ER P2~U~ETE~S TITLE: BOOKIAN OIL SHOWS ANALYSIS: WF4806_SAT STERANE DISTRIBUTION Echooka unit #1 12740 - 12870 ft RATIO si) s2) COMPOUNDS C295/C295+C29R STERANE C29R&S ABB/C295&RAAA+ C29R&S ABB VALUE 0.52 0.5& s3) S4) RATIO AAA 20R STERANES ABB 20S&20R STERANES "COMPOUNDS C27 C28 C29 36.6% 21.5% 32.0% 30.5% 37.5% VALUE , SS) M4: ) · . RATIO H2 ) H3) H6) DIA BA/(DIA+ NON-DtASTERANES) (CALCULATED) C27-35 HOPANES/(HOPD~S+STERANES C27-29) ..HOPANE DISTRIBUTION C32S/C32S+R HOPANE .. C31S/C31S+R HOPANE C30 HOPD~E/HOPANE+MORETANE 18A/18A+!7A HOPANE 59.1% 78.4:% VALUE 0.62 O. 4:7 0.8~ 0.4:7 GMC Data Report No. 183 Page 3 t !1_% Abundance 3000 - (b 2OOO 1000 Ion t9~.00 amu. from WF4806_SAT.d BOOK1:AN O;I:L SHOWS 2 Echooka Unit #1 12740 - 12870 ft 20 30 40 Tt. me (m~.n.) Ion 2t7.00 amu. from WF4B06_SAT.d Abundance 900 ! 8OO 7OO 500 , 400 300 -' ""' t"tw,~lv,.. /.,~.~-.;~.~All,~iAA~-~.~ltu~' ' 200 , ..... ~ ....... ~ ...... j , ' ; i ~ ~ ~ ' ; ~ ..... ; .......... ~0 30 40 " Time (min.) ~ 3~00 · Abundsnce 2800 - 2400 2000 1600 200 400 .... 32 Ion ~9~.00 amu. from WF4806_SAT.d BOOKIAN OIL SHOWS Echooka Unit #1 12740 - 12870 ft 36 40 44 ,48 ' Time (mtn.) Ion 2~?.00 amu. from WF4806_SAT.d Abundance .. 800 70O 600 500 400 300 /' 28 30 32 Time BOOKIAN Oil. SHOWS Echooka Unit #1 12740 - 12870 ft 34 36 i " ' W ' i o o lO00 900 Ion 177.00 amu. from WF4806_SAT.d" Abundance' BROOK]:AN OIL SHOWS Echooka Unit #1 800 12740 - 12870 ft 700 .. 5OO - · ..... .'. ............ ~ ....' --i ...... ' i -; ....... i-'-"~"-i' ~ "-i ~ -'' ~ ' i ..... · ''---~-- i--" ~ .... ' ' i ~---~- --~ .... ' ' ' i ' ' I 34 36 38 40 42_ 44 46 48 Time (min,) Ion i9i.O0 amu. from WF4806_SAT.d Abundance 3200 2800 2400 2000 i600 1200 8OO 34 36 38 40 42 44 46 ' 48 " Time (mir,) GC-MS BIOMARKER PARAMETERS TITLE: BOOKIANOIL SHOWS 2 ANALYSIS: WF4807._SAT Echooka Unit #1 12870 - 12930 ft STERANE DISTRIBUTION COMPOUNDS VALUE sz) S2) S3) RATIO ss) M~ ) C295/C295+C29R STERANE C29R&S ABB/C295&R Ag3k+ C29R&S ABB C27 AAA 20R STERANES 39.7% ABB 20S&20R STERANES 38.7% COMPOUNDS C28 31.3% 35.9% DIABA/(DIA+ NON-DIA3TERANES) (CALCULATED) C27-35 HOPANES/(HOPA~ES+STEP, ANES C27-29) · 0.52 0 .~5 C29 29.0% 25.4% VALUE 63.6% 67.0% RATIO H1) H3) H6) ~NDS HOPANE DISTRIBUTION C32S/C32S+R HOPANE -. C3iS/C3IS+R HOPANE C30 HOP~E/HOPANE+MORETANE 18A/18A+lTA HOPANE VALUE 0.68 0.59 0.84 0.48 GMC Data Report No. 18_; Page 36/113 Ion' i91.00 amu. fr, om HF4807._SAT.d Abundance 2200 ; 2000 ~ ~800 ~ i600 ~ 1400 ~ ~200 ~ lO00 - 80O 6OO 400 ': EIROOKZAN OZL SHOWS Echooka Unit #1 12870 . 12930 ft PO ., 30 40 50 T~me (min.) ]:on 2i7.00 amu.' from HF4807_SAT.d Abundance t000 l 900 · 8O0 , 700 . ~ 600 : 500 ~00 300 ~ ' 20 30 40 5O Time (min.) Abundance 2.000 Ion' ~9~.00 amu. · from WF4807_SAT, d 1800 1RO0 1400 ~200 ~000 800 6OO snooKZAN OZL sHOWS Echooka Unit //1 12870 . 12930 ft 38 36 40 44 48 T~,me (min.) .~oo0 Abundance Ion' 2i7,00 amu. from WF4807_SAT,d Br~OOKXAN OXL s~ows ~ ~ Echooka Unit #1 gOO -~ 12870 . 12930 ft 80o · 7O0 SOO 3O0 28 30 32 34 36 38 T~me (m~n.) 800 7OO 600 500 Abundance 900 I " 400 32 34 36 Abundance Ion t77.00 amu. from WF4807....SAT.d BROOKZAN OIL SHOWS £chooka Unl~ #~ 12870 - 12930 ft 38 40 42 44 46 48 Time (min.) Ion ~9~.00 amu. from WF4807...SAT.d 2OO0 :~800 1600 l~O0 ~200 lO00 800 i 600 - _~ 34 36 38 40 42 44 46 48 T~me (m~.n.) GC-MS BIO~.ARKER PARAMETERS ,...-- .... .. TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF48 X0_SAT Fin Creek Unit #1 7100 - 7230 ft STERANE DISTRIBUTION RATIO COMPOUNDS VALUE S1) S2) S3) RATIO ss) C29S/C29S+C29R STERANE C29R&S ABB/C29S&R AAA+ C29R&S ABB ~.. C%7 AAA 20R STERANES 30.4% ABB 20S&20R STERANES 30.3% COMPOUNDS C28 23.8% 29.2% DIA BA/(DIA+ NON-DIAS~ES) (CALCULATED) C27-35 HOPANES/(HOPA~rES+STERANES C27-29) 0.54 0.60 C29 45.9% 4~0.5% VALUE 53.7% 59.6% HOPANEDISTRIBUTION RATIO -. COMPOUNDS VALUE Hi) HZ) H3) H6) C32S/C32S+R'HOPANE -. C31S/C31S+R HOPANE C30 HOPANE/HOPANE+MORE?ANE 18A/18A+lTA HOPANE 0.65 0.63 0.87 0.$3 GMC Data Ret)on No. 183 Page 41/113 30000 ' Abundance Ion igt.o0 amu. from HF48iO_SAT.d 20000 - iO000 20 30 Time (mtn,) Ion 2t7,00 amu, from NF4810_.SAT,d Abundance 2000 1 lO000 8000 . 6000 4000 2000 BROOI<IAN OIL SHOWS Fin Creek Unit #1 7100- 7230 ft ,~ i I d , d i ' i i I ' 20 30 40 Time h ,. , ii i f ~ ¢~ Abundance 30000 20000 tO000 28 92 Ion .~9~.00 amu. · · from WF48~0_$AT. d BFIOOKZ:AN OIL SHOWS 2 Fin Oreek Unit #1 7100- 7230 ft 36 40 Time (mtn.) .. 44 48 Ion 2~7.00 amu. from HF48JO_SAT.d ~2000 Abundance 10000 - 8000 6000 - 4000 - 28 30 32 34 T:lme (m:tn.) BIqOOK:I:AN OZL SHOWS 2 Fin Creek Unit #1 7100 - 7230 ft 38 Ion t77.00 amu. from WF48~O_SAT.d Abundance 800O 7000 6000 5000 ~ 4000 3000 ' 2000 iO00 - 0 ' ' ' i ' ' ' i :" "' "' ..... 34 36 BROOK2AN OXL SHONS 2 Fin Creek Unit #1 7100. 7230 ft 38 40 42 44 46 48 Time (min.) Ion ~g~.o0 amu. from WF48~.O....SAT.d Abundance 30000 20000 iO000 ,, 0 ~ '~ , ,'" i ,- .... ~ ' 'i "'~ '" '~ I ' ' ' i ~ ' ' I ' ' ' I ' ' ' , ' ' ' I · ' ' I 34 36 38 40 42 44 46 48 Time (mtn.) GC-M$ BIOMARKER PARAMETERS TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF4809_SAT STERANE DISTRIBUTION Leffingwell #1 13790 - 13880 ft (WF4808 and WF4809 Combined) RATIO COMPOUNDS VALUE si) s2) s3) s4) RATIO ss) M~ ) C29S/C29S+C29R STERANE C29R&S ABB/C29S&R AAA+ C29R&S ABB AAA 20R STERANES ABB 20S&20R STERANES C27 ' C28 25.3% 33.5% 29.0% 33.7% COMPOUNDS DIA BA/(DIA+ NON-DIAS~ES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) 0.47 0.46 C29 41.1% 37.3% VALUE 54.7% 64.5% HOPANE DISTRIBUTION RATIO -. COMI~S VALUE H2) H3) H6) C32S/C32S+R'HOPANE -. C31S/C31S+R HOPANE C30 HOPANE/HOPANE+MORETANE 18A/18A+17A HOPANE 0.62 0.60 0.84 0.47 GMC Data Report No. 183 Page 46/113 Abundance 40000 Ion J9].O0 amu. from NF4809_SAT.d ' 30000 20000 toooo 30 T:i. me (mtn.) Ion 2i7.00 amu. from WF4809_SAT.d IBROOK]:AN OIL SHOWS Leffingwell #1 13790 . 13880 ft (WF4808 and WF4809 Combined) i i ..... i '' j 10 50 Abundance 16000 1 14000 12000 ~ lO000 1 8000 8000 4000 , 2000 0 ' ' ' .... i ..... ' ..... ' ....... ' " 'i ........... 20 30 Time (m :t.n .) 40 " 50 Abundance Ion ~9~.00 amu. from ~/F4B09_SAT.d ~0000 30000 20000 lO000 BROOKIAN OIL SHOWS 2 Lefflngwell //1 13790 . 13880 ft (WF4808 and WP4809 Comblned) I i" , ' I ' ' ' i ' 22 36 40 Time (min.) 44 48 ' AbU ~ 16000 · :t4000 ~2000 lO000 80OO 6000 4O0O 2000 ¢10 0 ,.,,.,, Ion 2t7.00 amu. from NF4BOg_SAT.d ndance I ' t BROOK~AN O~L 8HOW8 ~ ~ fl" " Lefflngwell #1 : ~ ~ (WF480~3~"gdO ~F%~Oc~Lblned) 28 30 32 34 36 38 T~me (m~n.) Abundance lO000 @000 6000 4000 2000 32 34 Abundance Ion .177.00 amu. from WF4809_SAT.d ' 8F:IOOKIAN OIL SHOWS Leffingwell #1 13790 - 13880 ft (WF4808 and WF4809 Comblnod) ' I ' '~ ' i ' ' ' i ' ' ' ""1 ' ' ' i ' i " ........ 38 40 42 44 46 48 50 Time (min.) Ion ~9~.00 amu. from WF4809_SAT.d CD ,...._, 40000 30000 20000 iO000 32 34 36 40 42 44 46 48 Time (m~n.) GC-MS BIOMARKER PARAMETERS TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF&SX6._SAT No. ra Federal #1 5590 - 5620 ft .STERANE DISTRIBUTION RATIO · s1) S2) COMPOUNDS C295/C295+C29R STERA~ C29R&S ABB/C295&RAAA+ C29R&S ABB VALUE 0.56 0.5& s3) s~) AAA 20R STERANES ABB 20S&20R STERANES C27 C28 30.~% 2G.8% 3~.~% 2~.2% C29 4G.8% 41.4% RATIO ss) M~) RATIO . COMPOUNDS DIA BA/(DLA+ NON-DIASTERANES) (CALCULATED) C27-35 HOPANES/(HOPD_NES+STERANES C27-29 ) HOPANE DISTRIBUTION o COM~S 49.9% ~. .... 8~_. 8% VALUE H2) H6) C325/C325+R HOPANE C315/C31S+R HOPANE C30 HOPANE/HOPANE +MORETANE 18A/18A+!7A HOPANE 0.65 0.60 0.81 0.33 GMC Data Report No. 183 P~_-o~,. 51 / 1 ! _3 200 Ion ~g~.o0 amu. from NF4816_SAT.d Nora Federal #1 5590 - 5620 ft 40 5O i ' 'I , I 40 " 50 Abundance .. 7000 I eROOKIAN OIL SHOWS 6000 5000 ~ ' 4000 3000 2000 lO00 20 30 Time (min,) Ion 2~7.00 amu. from WF48~6_SAT.d Abundance 900 1' 800 . 700 ~. 500 ' ,4oo i 3O0 .' · , i I ' ""j ..... ~ i ' ' 20 I 30 T:ime (min.) Abundance 7000 - 3:on ~,9~.00 amu. fr'om NF4B~.'6_,SAT.d .' 6000 5000 4000 3000 2000 iO00 32 BROOK3:AN 03:1. SHOWS Nora Federal #1 5590. 5620 ft Time (min,) 44 48 ~ Abundance ~ 900 0 8O0 7OO 6OO 500 400 300 Ion 2~7.00 amu. fr, om HF48t6_SAT.d BROOKIAN OIL SHOHS ~ Nora Federal #1 5590 - 5620 ft J 32 34 Time (m~.n.) 36 38" Abundance 2400 - 2000 1600 1200 800 ~ 4O0 32 Abundance ' ' ' i ' ~ i I 34 36 · Ion ]77.00 amu, fr'om HF48~,6_SAT.d ' tBROOK:ZAN O:i:L SHONS p- Nora Federal #1 SSg0. $620 ft ' I ' ' ' I ' 38 40 42 44 46 48 50 Time (min,) Ion 7000 6000 - 5000 - 4000 - ] ,~- , .--~-~-.,-,, , -I -, ...,. lO00 3~ 34 36 ' ' ......... ' ............... IF-;': i':" ; '~' ,'" ] z14 46 48 ' 5O Time (min,) -. TITLE: ANALYSIS: GC-MS BiOMARKER PARAMETERS BROOKIAN OIL SHOWS 2 WF~817_SAT STERANE DISTRIBUTION Nora Federal'.#1 11150 - 11190 ft RATIO .. si) s2) s3) s4) RATIO ss) M{ ) COMPOUNDS C29S/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB AAA 20R STERANES ABB 20S&20R STERANES VALUE COMPOUNDS 0.53 0.51 C27 C28 C29 33.3% 28.0% 38.7% 31.9% 31.3% 36.8% DIA BA/(DIA+ NON-DIASTERANES) (CALCIU_~TED) C27-35 HOPANES/(HOPANES+STERANES C27-29) VALUE 66.4% 60.6% RATIO -. HOPANE DISTRIBUTION VALUE H1) H2) H3) H6) -. C32S/C32S+R HOPANE % C31S/C31S+R HOPANE C30 HOPANE/HOPANE+MORETANE 18A/18A+17A HOPANE 0.69 0.67 0.83 0.48 GMC Data Report No. 183 Paee 56/1 t 3 Abundance 14000 1 12000 ~0000 Ion t9~.00 amu. from WF48t7_SAT.d 8000 6000 4000 2000 0 Ion 2i7.00 amu. Time (min.) from WF48i7._SAT. d BROOKZAN OZL SHOWS Nora Federal #1 11150- 11190 ft , i , i 40 Abundance go00 - 8OO0 7000 8000 5000 4000 3000 . 2000 iO00 0 20 30 Time ........ i .... I i ' i i j ' I .... iml,., i ...... i ' - .,, i 4O (rain .) Abundance 14000 - ~2000 iO000 - 8000 ' 6000 4000 2000 Ion ~_9~,00 amuo 28 32 36 from WF4817_SAT. d BROOK]:AN Oil. SHOWS Nora Federal #1 11180- 11190 ft Time (min.) 44 48 Ion 2~7.00 amu. from HF48~7~AT.d Abundance g000 BROOKIAN OIL SHONS ~ ~ Nora Federal #1 @000 11150:- 11190 ft 7000 : 6000 5000 ooo 28 30 32 34 36 38 Time(min.) Ion ~77.00 amu. from WF48~7_SAT.d 6000 5O00 4000 3000 2000 lO00 Abundance . . A ~. BROOKTAN OIL SHOWS ., A'A, .11. i~ . .o,.,, ,.o,:,o,.,,,, #., , ' 0 ..... i .... ' : ' :I I' I -- ~- I i i 'i i" I i 'i I 'i I ' ' ' ' i ' ' ' i--- ' I , i ' I i I 34 36 38 40 42 44 46 48 Time (min.) Ion '~9~.00 amu. from WF48~7_SAT.d · i Abundance 14000 - i2000 iO000 - 8O00 - 8000 ~000 2000 - 0 34 36 38 40 42 44 46 48 Time (min.) SAMPLE NAME : INSTRUMENT : IN3ECT TIME : METHOD USED : RESULT FILE : REPORT TIME : PETROLEUM GEOCHEMISTRY SATURATE GC NORA FED ~1 11550-11650 FY. HP_5880 Fri Oct 19, 1990 4:40:06 pm /METHOD/SAT_SB80.MTH /RESULT/WF4818X_SAT.RES 5:31 PM FRI.~ 19 OCT.~ 1990 Nora Federal #1 11550 - 11650 ft CPI VALUE : eeee*~ PRISTANE / PHYTAHE : PRISTANE / C12 : PHYTANE / C18 : 0.00 C15/C25 0.00 C12/Pr 0.00 C18/Ph : 114641 N-CiO N-Cll N-C12 N-C13 N-C14 N-Cl~ N-C16 N-Cl7 N-Ci8 H-C19 N-C20 N-C21 N-C22 N-C23 H-C24 H-C25 N-C26 H-C22 H-C28 H-C29 N-C30 -H-C31 N-C32 H-C33 N-C34 H-C3~ N-C36 AREA 0. 0. 65. 123. 130. 115. 88. 89. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. ~AREA HALK lB.O 19.0 16.8 12.8 13.0 11.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 TIME O.O0 0.00 10.05 12.14 14.10 15.94 17.68 19.32 20.88 O.O0 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NORM C15 0.00 0.00 1.02 1.13 1.0.0 .. °65 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Farnesane Ac~clic C16 Ac~clic C18 Pristane Phytane GMC Data Repo~ No. i83 AREA ~ O. O. O. O. ~AREA ISPR TIME 0.00 0.00 0.00 0.00 0-00 Nora Federal //1 11550 - 11650 ft "in~ ~o.oo is.oo ~o.oo ~.oo ~o.oo ~s.oo m tes SAMPLE: NORA FED ti 1i550-it650 FT. ANALYZED: Fpi Oct t9, t990 4: 40:06 pm RESULT: /RESULT/WF48tSX SAT.RES METHOD: SAT 5880 40.00 45.00 GC-M$ BiC~WARKER PARAMETERS TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF4818_SAT STERANE DISTRIBUTION Nora Federal. #1 11550 - 11650 ft RATIO COMPOUNDS VALUE si) C29S/C29S+C29R STERANE C29R&S ABB/CZgS&RAAA+ C29R&S ABB 0.39 0.46 53) AAA 20R STERANES ABB 205&20R STERANES C27 C28 C29 25.9% 29.0% 45.1% 21.8% 34.1% 4~.1% RATIO COMPOUNDS VALUE ss) M{ ) DIA BA/(DIA+ NON-DIAST-~gANES) (CALCULATED) C27-35 HOP~_NES/(HOPANES+STERANES C27-29) HOPANE DISTRIBUTION 78.8% .57.{% RATIO COMPOUNDS VALUE H2) H3) H6) C32S/C32S+R HOPANE C31S/C31S+R HOPANE C30 HOPANE/HOPANE+MORET~E 18A/18A+lTA HOPANE GMC Data Report No. 183 0.56 0.50 O. 98 O.50 Page 63/113 Ion .~9~.00 amu. from HF4B~B_SAT.d Abundance :0000 @000 8000 7000 ~000 5000 4000 3000 2000 ~000 BROOKIAN OIL SHOWS 2 Nora Federal #1 11550 - 11650 ft 20 30 40 Time (min.) Ion 2i7.00 amu. from HF48~.B...SAT.d Abundance 7000 ~000 5000 4000 3000 2000 iO00 ~i ............ E l- . E ........ j ....... EI 20 30 40 " Time (m:tn.) Abundance Ion t9t.00 amu. fr'om WF48tS_SAT.d 4000 3000 - 2000 BROOKXAN O3:1_ SHOHS P_ Nora Federal #1 11550 - 11650 ft 28 32 36 40 Time (min.) 44 48 " Abundance ,40O0 3000 2000 - iO00 ' Ion 217,00 amu. Crom WF4B~B_SAT.d ' I ' ' ~' I 28 30 Nora Federal #1 11550 - 116S0 ft ~ .....' 'I [ I I ' ' ...... ' -- I I .... i ........ ' ....... ill I ' .... ' .....' -- ' ~ i .... i i -- 32 34 36 38 Time (min.) Ion t77.00 amu. from WF4BiB_SAT.d Abundance 2800 ' 2400 2000 i600 i200 ' 800 :34 BROOKIAN OZL SHOWB 2 Nora Federal #1 · 36 38 40 42 44 46 48 Time (min.) Ion t9t.00 amu. from WF4818..SAT.d Abundance 4OO0 30O0 2000 ~000 34 36 38 40 42 44 46 48 Time (min.) SAMPLE NAME : INSTRUMENT : IN3ECT TIME : METHOD USED : RESULT FILE : REPORT TIME : PETROLEUM GEOCHEMISTRY SATURATE GC NORA FED ~1 11670-117)0 FT. HP_5880 Mon Oct 22, 1990 8:41:52 am /METHOD/SAT_5880.MTH /RESULT/WF4819_SAT.RES 9:52 AM MON.~ 22 0CT.~ 1990 Nora Federal #1 11670 - 11730 ft CPI UALUE : .8:5 PRI'STANE / PHYTANE : PRISTANE / C17 : PHYTANE / C18 : 1.6:5 C15/C25 : .44 CI?/Pr : · :59 C18/Ph : 4.28 2.28 2.54 N-CiO N-Cll N-C12 N-CI:5 N-C14 N-C15 N-C16 N-C17 N-C18 H-C19 N-C21 N-C22 N-C25: N-C24 N-C25 N-C26 N-C22 H-C28 H-C29 H-C:50 · .N-C:51 N-C~4 H-C~5 N-C~6 AREA ~AREA NALK TIME O. 0.0 0.00 20:5. :5.8 7.82 5:5:5. 6.6 10.0:5 43::5. 8.1 12.12 5:81. 7.1 14.09 5:3:5. 6.2 275. 5.1 17.62 5:09 . 5: . 8 19 . 32 211· :5.9 20.88 232. 4.5: 22.:37 174. :5 . 2 2:5 . 79 45:5. 8.5 25.14 15: O. 2.4 26.44 152. 2.8 27.69 92. 1.7 28.89 78. 1.5 5:0.04 129. 2.4 5:1.04 75 .. 1.4 5:2.23 348: 6.5 3;3.09 120. 2.2 3:4.21 80. 1.5 35.24 O. 0.0 0.00 613;. 11.4 157.20 187. O. O.O 0.00 0. 0 .-.0 O. O0 O. 0.0 0,00 NORM 0.00 .61 1.05 1.29 1.14 1.00 .B2 1.04 .24 0.00 0.00 0.00 0.00 Farne~ane Acycl ic 016 Ac~,c I ic C18 Pristane Ph~tane GMC Data Report No. 183 AREA ~AREA ISPR TIME 104. 17.8 13.68 150. 22.4 15.29 129. 22.2 18.54 136. 23.3 19.47 8~. 14.~ 21.08 P~_.~o~ 68/113 ON e Nora Federal #1 11670 - 11730 ft n~t~tes ~o.oo ~s.oo zo.oo ~.oo ao.oo ss.oo SAMPLE: NORA FED ~i it670-ti730 FT. ANALYZED: Mon Oct 22, t990 8: 4t: 52 am RESULT: /RESULT/NF48t9 SAT.RES METHOD: SAT 5880 40,00 45,00 GC-MS BIOMARKER PARAMETERS TITLE: ANALYSIS: BROOKIAN OIL SHOWS 2 wF4819_SAT Nora Federal #1 11670 - 11730 ft STERANE DISTRIBUTION RATIO COMPOUNDS VALUE S2) C29S/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB 0.{5 O.58 s3) AAA 20R ~ERANES ABB 20S&20R STERANES C27 32.9% 37.3% C28 3{.3% 29.7% C29 32.8% 33.0% RATIO COMPOONDS VALUE s5) DIA BA/(DIA+ NON-D~ES) '(CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29 ) 65.9% 59.9% HOPANE DISTRIBUTION RATIO · ~S VALUE Hi) H2) H3) H6) C32S/C32S+R ' HOPANE C3iS/C31S+R HOPANE C30 'HOPANE~OPANE+MORETANE 18A/18A+17A HOPANE 0.54 0.60 0.79 0.41 GMC Data Report No. 183 · Pao-~ 70/113 Abundance 600 560 52O 480 440 4OO 360 320 Ion i77.00 amu. from WF48i9_SAT.d BROOKIAN OIL SHOWS Nora Federal #1 ' 11670 - 11730 ft · -- ' ' ' ~ ' ' '" 'i i ' '' '" ' i '' "" ' I '~ ~ " I' ~ ' ' ..... i ' ' ~ ' .... I " "' " I ' ' 32 34 36 38 40 42 44 46 Time (min,) Ion i9i.00 amu. from HF48i9._SAT,d 48 50 Abundance 000 ~ - , , goo I~. ~,~_.Fl~d~l, ~ ~" 800 ' ~ 7OO 6OO 5OO 400 ' , 32 34 36 38 40 42 44 46 48 50 Time (min.) Abundance 900 ~00 7OO 8OO 500 400 32 Ion ~9~.00 amu. from NF4819_SAT.d IBn0OKZAN OIL SHOW~B ~ Norn Federnl //1 670 - 11730 fl: 36 4o T~.me (m~n.) 44 48 ~ Abundance 0 ? 480 UJ 440 4OO 360 320 280 Ion 2i7.00 amu. from WF4819_SAT.d IBROOKZ:AN Oil. ~HONS ¢~ Nora Federal #1 11670 - 11730 ft 28 30 32 34 36 38 T~,me (min.) lO00 900 go0 7OO 6OO 500 400 Ion lg~.o0 amu. from WF4Btg_~AT.d ' Abundance Nora Federal #1 . ' ' '-Il" ",'1='=)-, II 'lll~ i ' ; ......... ' ...... I , 'I ~ I ' ' I' I ' ' ' i ~0 30 40 50 Time (min.) Ion 2i7.00 amu. from WF48~g_SAT.d Abundance 700 600 5OO 4O0 300 i lli i Ii ...... , l i II II .......... I I I I I I i [ I 20 30 40 50 Time (min.) GC-MS BIOMARKER PARAMETERS TITLE: BROOKIAN OIL SHOWS ANALYSIS: WF&805_SAT STERANE DISTRIBUTION T°olik Federal #1 8300 - 8380 ft (WF4804 and WF4805 Combined) RATIO COHP(X/NDS VALUE si) s2) s3) RATIO C29S/C29S+C29R STERANE C29R&S ABB/C29S&R A~_~+ C29R&S ABB AAA 20R STERANES ABB 20S&20R STERANES 0.17 0.50 C27 C28 C29 8.2% 13.8% 78.0% 13.6% 19.8% 66.6% VALUE ss) DIA BA/(DIA+ NON-DIb3TERANES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) 78.0% HOPANE DISTRIBUTION RATIO COMPOUNDS VALUE HI) H2) H3) H6) C32S/C32S+R HOPANE · · C31S/C31S+R ROPANE C30 HOPANE/HOPANE+PDRETANE 18A/18A+17A HOPANE 0.45 0.43 6 67 0.16 GMC Data Report No. 183 Page 75/113 Abundance 200000 ' Ion ~9~.00 amu. from ~4F4805JAT.d 160000 :t20000 8O00O 40000 20 i 30 Time (min.) Ion 217.00 amu. from HF4805_SAT. d Abundance BROOKIAN OIL SHOWS 2 Toollk Federal #1 8300- 8380 ft (WF4804 and WF4805 Combined) ftr~ Ct, 40000 30000 - 20000 - lO000 I I 20 30 Time (min.)' ,40 ~ · ..... '' l;il -I ' rz .... , iil i I 50 Abundance Ion ~g:~.O0 amu. fr'om WF4805_SAT.d · ~80000 i60000 140000 ~20000 lO0000 SO000 60000 40000 20000 ! ! ! j i i ....; i ' 28 32 BROOklAN OIL SHOWS 2 Toolik Federal //1 8300- 8380 ft (WF4804 and WF4805 Combined) 36 40 Time (min.) 44 48 (IQ Abundance Ion' 2~7.00 amu. from WF4805_SAT.d 40000 30000 20000 ~0000 BROOKIAN OIL SHONS 2 Toolik Federal #1 8300 - 8380 ft (WF4804 and WF4805 Combined) 28 30 32 34 T~me (min.) ........... Abundance Ion 77.00 amu. · from WF.4805_SAT. d 60000 50000 40000 30000 20000 lO000 0 32 34 36 38 ]~on BROOKIAN OIL SHOWS Toollk Federal //1 8300. 8380 ft (WF4804 and WF4805 Combined) 40 42 44 Time (min.) ~9~.00 amu. from HF4805_SAT.d 46 48 50 Abundance i80000 i 160000 140000 120000 lO0000 80000 60000 40000 20000 0 32 ' I ' ' I ' ' ' i I I ' ' ' I ' 34 36 38 40 42 44 Time (min.) 1 46 48 50 GC-MS BIOHARKER PARAMETERS TITLE: ANALYSIS: BROOKIANOIL SHOWS 2 WF4813_SAT STERANE DISTRIBUTION West Mikkelson' Bay #1 9970- 10030 ft RATIO COMPOUNDS VALUE S2) s3) s~) RATIO C29S/C29S+C29R STERANE C29R~S ABB/C29S&RAAA+ C29R&S ABB AAA 20R S~S ABB 20S&20R STERANES 0.52 0.48 COMPOLYNDS C27 C28 C29 23.8% 40.3% 35.9% 23.5% 39.9% 36.6% VALUE ss) M4 ) DIA BA/(DIA+ NON-DIASTERANES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29 ) 60.3% 56.7% 'RATIO H1) H2) H3) H6) HOPANEDISTRIBUTION -. C32S/C32S+R HOPANE C31S~C31S+R HOPANE C30 HOPANE/HOPANE+HORETANE 18A/18A+17A HOPANE VALUE 0.64 0.61 0.86 0.GG GMC Data Report No. 183 Page 80/113 ~80000 °'160000 ~0000 120000 iO0000 80000 60000 40000 20000 Abundance Ion i9~.00 amu. from WF4B~3_SAT.d B~OOKZAN OIL SHOWS e West Mikkelson Bay #1 9970- 10030 ft , , . · ' [ ..--. ~.,.- -...- , _ ........ , ...... - ,, , "' ' '; ......... i - ' i i , ' i ' ' ' i ' 20 30 ~lO Time (min.) Ion 2~7.00 amu. from HF48~3._SAT.d Abundance 70000 60000 50000 40000 30000 20000 iO000 0 20 30 40 T~me (min.) Abundance · ~80000 Ion .lgi.o0 amu. 160000 140000 120000 ~00000 80000 60000 40000 20000 ,' ,o 28 from HF48~3_SAT. d BROOK:i:AN OTL SHOWS West Mlkkelson Bay 9970- 10030 ft Time 40 44 48 (min.) 70000 60000 50000 40000 30000 20000 lO000 0 Ion 2~7.00 amu. Abundance 28 30 from WF48~.3_SAT. d 32 34 Time (m~n.) BROOKZAN O:i:L SHOWS West Mlkkelson Bay 9970 - 10030 ft 36 38 50000 40000 30000 20000 10000 Ion t77.00 amu. from WF48~3_SAT.d Abundance . BROOKIAN OIL SHOHS 2 West Mikkelson Bay t/1 9970 . 10030 ft 34 36 38 40 42 Time (min.) Ion 19i.00 amu. from WF48i3_SAT.d Abundance flC~ Cb 180000 160000 140000 i20000 - lO0000 80000 80000 40000 20000 0 34 36 ~ , , ' i , ~ i ' ~ ' ' ' i .... ~"-=r--*: .... ?' ~--~'~-' 38 40 42 44 46 48 Time (min.) GC-HS BIOPLARKER PARAMETERS TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF4814_.SAT West Mikkelson Bay #1 10030 - 10070 ft STERANE DISTRIBUTION RATIO COMPOUNDS VALUE C29S/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB 0.48 0.52 s3) s~) RATIO AAA 20R STERANES ABB 20S&20R STERANES . · .. COMPOUNDS C27 C28 C29 23.8% 34.6% &1.6% 29.5% 31.8% 38.8% ss) M~) DIA BA/(DIA+ NON-DIASTERANES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) HOPANEDISTRIBUTION RATIO .. H1) H2) H3) H6) C32S/C32S+R'HOPANE -. C31S/C31S+R HOPANE C30 HOPANE/HOPANE+MOR!~f'ANE 18A/18A+17A HOPANE VALUE 50.2% 65.9% VALUE 0.62 0.61 0.87 0.&9 GMC Data Report No. 183 Pao_e 85/113 Ion ~9~ O0 amu fpom WF48~4_SAT d Abundance ° 70000 60000 . 50000 ~ , 40000 30000 2O0OO lO000 0 - 20 30 40 Time (min.) Ion 2i7.00 amu. from HF4B~4_SAT.d BROOKZAN OTL SHOWS 2 West Mikkelson Bay #1 10030 - 10070 ft 'j i i Abundance (b O0 20000 :faO00 i2000 8OOO 4000 20 i 30 Time (min.) 4O Abundance Ion ~.9i.00 amu. from WF48~t4_SAT.d 70000 60000 50000 40000 30000 20000 iO000 32 36 Time (min.) BROOKZAN 03:L SHOWS ;3 West Mlkkelson Bay #1 10030 - 10070 ft tt 44 48 Abundance 20000 16000 i2000 8000 4000 Ion 2i7,00 amu. fr, om WF48t4..SAT,d BROOK~AN OZL SHOWS Wes! Mikkelson 8sy 10030 - 10070 ~t 30 32 34 Time (min.) 36 38, ' Abundance i6000 14000 ~2000 iO000 8000 6000 4000 2000 - Ion ~77.00 amu. from WF48i4_SAT.d BROOKIAN O3:L BHOWB 2 West Mikkelson Bay #1 10030 - 10070 ft 34 36 38 40 42 44 46 48 Time (min.) Ion i9i.O0 amu. from HF48i4-SAT.d Abundance 7OOOO 60000 - 50000 - 40000 30000 20000 1 ~0000 0~, , , , , , . , 34 36 38 I ' ' ' i ~ I ' ' I ' ' I ' 40 42 44 46 48 ,, Time (min.) GC-MS BIOMARK~ PARAPIETER$ ~_ _ TITLE: BROOKIAN OIL SHOWS ANALYSIS: WF~815_.SAT West Mikkelson Bay //1 11210- 11260 ft STERANEDISTRIBUTION RATIO COMPOUNDS VALUE s1) s2) S3) $4) RATIO C29S/C29S+C29R STERANE C29R&S ABB/C29S&RAAA+ C29R&S ABB AAA 20R STERANES ABB 20S&20RSTERANES 0.62 0.57 COMPOUNDS C27 C28 C29 37.6% 26.7% 35.8% 36.5% 27.1% 36.4% VALUE ss) DIA BA/(DIA+ NON-DIASTERANES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29 ) 53.1% 74.5% 'RATIO H1) H2) H3) H6) HOPANE DISTRIBUTION ° .. - '. ' C32S/C32S+R HOPANE C31S~C31S+R HOPANE C30 HOPANE/HOPANE+MORETANE 18A/18A+17A HOPA~E VALUE 0.63 0.61 0.91 0.4=6 GMC Data Report No. 183 Pale 90/113 Ion .t9i.00 amu. from HF48iS_SAT.d ' i80000 i60000 i~O000 i20000 Abundance · IBROOKIAN OIL. SHOHS West Mlkkelson Bay #1 11210- 11260 ft 'iO0000 - 80000 60000 40000 20000 . 0 ~ I 20 30 40 50 Time (min.) Ion 2i7.00 amu. from WF48iS_SAT.d 'Abundance 40000 30000 20000 iO000 30 40 " 50 Time (min.) o 180000 ~ ~GO000 Abundance 140000 120000 - lO0000 - Ion ,19t.00 amu. fPom WF4BtS_.SAT.d ' 80000 BROOK1~AN OIL SHOWS West Mlkkelson Bay #1 11210 - 11260 ft 60000 - ''~' 40000 i · 20000 0 40 44 48 " 28 32 36 Time (min.) Ion 2~7.00 amu. from WF48~5_SAT.d' Abundance ~0000 30000 ' 20000 iO000 BROOKXAN O]:L, SHOWS West Mlkkelson Bay #1 11210- 11260 It 28 30 32 3~, 36 38 , Time (min.) Abundance 50000 ' 40000 30000 20000 iO000 Ion t??.00 amu. from WF4815_,SAT.d 32 34 36 Ion BROOK'tAN O?L SHOWS West Mikkelson 8ay #1 11210- 11260 ft 38 40 42 44 46 Time (min.) ~91.00 ainu, from HF48~_SAT,d Abundance i80000 - 160000 140000 120000 ~00000 80000 60000 40000 20000 0 I ' ' ' I ' ' ' I ' -[ ' ' ' ] ' ' ' i ' ' ' i ' ~' ' 'i 32 34 36 38 40 42 44 46 Time (min.) 48 50 48 ,, 50 PETROLEUM GEOCHEMISTRY SATURATE GC SAMPLE NAME : WEST SAK 20 6691 FT. INSTRUMENT : HP_5880 IN3ECT TIME : Mort Oct 22, 1990 12:34:55 pm METHOD USED : /METHOD/SAT_5880.MTH RESULT FILE :' /RESULT/WF4825_SAT.RES REPORT TIME : 1:26 PM HON., 22 OCT., 1996 West Sak 20 ~6691 ft CPI UALUE : 1.05 PRI'STANE / PHYTANE : 1.54 C15/C25 : PRISTANE / C12 : .59 Ci7YPr : PHYTANE / C18 : .51 CIS/Ph : .19 3.2? AREA ~AREA HALK TIME N-C10 O. 0.0 0.00 N-ClI O. 0.0 0.00 N-C12 O. 0.0 0.00 H-C13 O. 0.0 0.00 N-C14 53. 1.1 14.11 N-C15 25. 1.6 15.95 N-Cid 105. 2.2 12.68 H-ClY 172. 5.2 19.52 N-C18 216. 4.6 20.88 N-C19 ' 271. 5.8 22.57 N-C20 502. d.5 23.79 H-C21 321. 6.9 25.14 N-C22 550. 2.5 26.44 H-C23 594. 8.5 22.69 H-C24 583. 8.2 28.89 N-C25 599. 8.6 50.04 N-C26 374. 8.0 51.15 H-C27 ~29. 7.1 52.23 N-C28 259.' 5.6 33.26 H-C29 227. 4.9 54.26 H-C30 '- 157. ~.4 55.25 · N-C31 11~. 2.4 56.17 N-C~2 6~. 1.5 57208 N-C3~ 89. 1.9 58.00 H-C34 '-O. 0.0 0.00 H-C35 O. 0..~ O.O0 N-C36 O. 0.0 0.00 NORM 0.00 0.00 0.00 '0~ O0 .?0 1.00 1.38 ' 2.~1 2.88 4.04 4.28 4.68 5.22 5.12 5.54 5.00 4.40 5.46 2.10 1.51 .84 1.19 0.00 0.00 0.00 AREA ~AREA ISPR .TIME Farnesene O. 0.0 0.00 Acyclic C16 O. 0.0 0.00 Acyclic C18 O. 0.0 0.00 Pristane 102. 60.2 19.48 Phytane 66. 59.3 21.08 GMC Data R~o~ No. 183 Page 95/113 2. West Sak 20 6691 ft , 2.03 2.0! iO.O0 ~§.00 20.00 25. O0 30. O0 35.00 SAM)LE: WEST SAK ~0 SS@~ FT. ANALYZED: Mon Oct 28, i990 i2: 34:55 pm RESULT: /RESULT/WF4823 SAT.RES METHOD: SAT 5880 40.00 45,00 GC-MS BIO~4ARKER PARAMETERS TITLE: ANALYSIS: BROOKIANOIL SHOWS 2 WF4823_.SAT West Sak 20' 6691 ft STERANE DISTRIBUTION RATIO COMPOUNDS VALUE S2) C29S/C29S+C29R STERA~E C29R&S ABB/C29S&R AAA+ C29R&S ABB- 0.56 0.58 s3) RATIO , ss) M4 ) AAA 20R ST~ANES ABB 20S&20R STERANES C27 C28 C29 22.3% 29.5% 48.2% 20.0% 31.61 48.4% COMPOUNDS DIA BA/(DIA+ NON-DIAS~ES) (CALCULATED) C27-35 HOPANES/(HOPA~S+STERA~S C27-29) VALUE 72.11 72.8% HOPANE DISTRIBUTION .RATIO VALUE H1) H2) H3) H6) -. C32S/C32S+R HOPANE C31S/C31S+R HOPANE C30 HOPANE/HOPAh~E + ~REq'. A_NE 18A/18A+17A HOPkNE 0.67 0.66 0.84 0.46 GMC Data Report No. 183 Page 97.113 8000 - 7000 6000 5000 · ,4000 Abundance Ion .19~.00 amu. from WF4823_SAT.d EIROOK):AN OIL 9HO~S 2 West Sak 20 66§1 ft 3000" I I , 2000 lO00 20 30 40 50 Time (min.) Ion 217.00 amu. from WF4823._SAT.d Abundance 2400 2000 1200 80O 400 20 3O Time (min.) 40 50 ~o Abundance ~ 8000- · 7000 - 6000 5000 4000 3000 2000 lO00 ' o, ., Ion .19~,00 amu, from HF4823_SAT,d . 36 40 Time (min.) BROOK3:AN OIL SHOWS 2 ', West Sak 20 6691 ft " i ' I I' ' 44 48 Abundance 2400 2000 1600 - ~200 800 - 400 I ' ,,, Ion 2i7.00 amu. from WF4823_.SAT.d BROOKIAN OIL SHOWS West Sak 20 6691 ft 30 32 34 36 38 Time (min.) Abundance 2000 i800 ~600 ~400 :200 lO00 800 600 400 Ion 'i77.00 amu. fr, om WF4823._SAT.d BROOK]:AN O2L SHOWS e ,, West Sak 20 6691 ft ' , _,l,~,a., o l~, ...... ..,.,uI ~. Abundance 8000 ' 7000 ' I~000 ' · 5000 4000 · 3000 2000 :tO00 ,o 84 36 38 40 4P- 44 46 48 Time (min.) Ion lgl.00 amu. fr'om WF4823_SAT.d 32 ' i ' ' i ' 34 36 38 40 42 44 46 48 Time (m~,n.) PETROLEUM GEOCHEMISTRY SATURATE GC SAMPLE NAME : INSTRUMENT : INJECT TIME : METHOD USED : RESULT FILE : REPORT TIME : ~EST SAK 20 6201 FT. HP_5880 Mon Oct 22, 1990 1:33:08 pm ~'IETHOD/SAT_5880.MTH /RESULT/WF4824_SAT.RES 2:24 PM MON., 22 OCT., 1990 CPI UALUE : 1.05 PRISTANE / PHYTANE : PRISTAHE / C12 : PHYTAHE / C18 : 653.75 C15/C25 .60 Ci?/Pr 0.00 C18/Ph : .33 : 1.68 West Sak 20 6701 ft N-CiO N-Cli N-C12 N-C13 N-C14 N-C15 N-C16 N-CI? N-C18 N-CI9 N-C20 N-C21 N-C22. N-C23 H-C25 N-C26 H-C22 H-C28 H-C29 N-C30 -H-C31 N-C32 H-C33 N-C34 H-C35 H-C36 AREA ~AREA NALK T IME O. 0.0 0.00 O. 0.0 O.O0 O. 0.0 0.00 O. 0.0 0.00 68. 2.4 80. 2.8 22. 2.2 12.68 110. 3.9 19.32 95. 3.4 20.88 104. 3.2 22.32 102. 3.6 23.29 126. 4.5 25.14 161. 5.2 26.44 206. 2.3 22.69 210. 7.4 28.89 239. 8.4 30.04 249 . 8 . 8 250. 8.8 32.22 206:" 2.3 33.26 183. 6.5 34.26 138. 4.9 35.23 97. 3.4 24. 2.6 32.08 56. 2.0 38.00 O. O.O 0.00 O. 0.0 0.00 O. 0.0 0.00 NORM C15 0.00 0.00 0.00 0.00 .86 1.00 1.38 1.19 1.31' 1.28 1.59 2.05 2.59 2.63 3.00 3.13 3.15 2.59 2.30 1.24 .?0 O.O0 0.00 0.00 AREA ~AREA ISPR Farnesnne O. O. 0 0 Acyclic C16 O. 0.0 0 Acyclic C18 O. 0.0 0 Pristane 69. SO0.O 19 Phs)tone O. O. 0 O GMC Data Report No. 183 IME .00 .00 .oo .48 .00 Page 102/113 N C. LI., .2.07 2.0~ _ West Sak 20 6701 ft 2.0! 5o 00 , ~,0.00 ~,5.00 20.00 25.00 30.00 35.00 mznutes SAMPLE: NEST SAK 20 670i FT. ANALYZED: Eon Oct. 22, 1990 1: 33:08 pm RESULT: /RESULT/~F4824 SAT,RES IvtETHOD: SAT 5880 40.00 1 45,00 GC-MS BIC~"IARK£R PARAMETERS TITLE: BROOKIAN OIL SHOWS 2 ANALYSIS: WF~824_SAT STERANE DISTRIBUTION West Sak 20 6701 ft RATIO COMPOUNDS VALUE s~) s2) S3) s~) .RATIO C29S/C29S+C29R STERANE C29R&S ABB/C29S&R AAA+ C29R&S ABB AAA 20R STERANES ABB 20S&20R STERAN~S 0.57 ~0MPOL~T)S 0.59 C27 C28 C29 23.5% 29.0% 47.5% 21.9% 25.5% 52.7% VALUE ss) M~) DIA BA/(DIA+ NON-DIASTERANES) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) 61.6% 75.4% RATIO H2) H3) H6) H.O. PANE DISTRIBUTION - . COMPOUNDS - . C32S/C32S+R HOPANE - . C31S/C3IS+R HOPANE C30 HOPANE/HOPANE+MORETANE 18A/18A+!7A HOPANE VALUE 0.64 0.67 0.82 0 .~2 GMC Data Report No. 183 Page 104/113 (IQ Ion '19i.00 amu. from WF4824_SAT.d Abundance 6000 5000 4000 3000 2000 ~000 2O 30 Time (mtn.) 217.00 amu. from WF4824_SAT.d BROOKIAN OIL SHOWS West Sak 20 6701 ft 4O Abundance ,J. 1400 lO00 800 600 400 20 30 T~me ! (mtn .) 40 ~ 6000 Abundance 5OOO 4000 3000 2000 lO00 Ion 'i9~.00 amu. from WF4824_SAT,d BROOK:tAN OTL SHOWS West Sak 20 6701 ft ~ I ' ' 'I ' 36 40 Time (min.) 44 48 Abundance Ion 2i7.00 ainu. · · from WF4824_SAT. d t400 ~200 looo 800 600 400 2OO 34 Time (mtn.) BROOKZAN O]:1. SHONS 2 West Sak 20 6701 ft 36 38 Abundance Ion '~77,00 amu. from WF4824_SAT.d 2000 · ~ ~600 ~200 800 ~,~,~ 400 - ." 34 36 38 40 42 Time (min.) SROOKTAN OIL SHOWS West Sak 20 6701 ft 44 46 48 Ion 19~,00 amu, from WF4824_SAT.d Abundance 6000 5000 4000 3000 2000 ~000 . . ~' ............ i ...... i ! i' i 34 36 38 40 42 44 46 48 Time (min.) iii I ' ' ' GC-MS BIOMARKER PARAMEq'ERS TITLE: BROOKIANOIL SHOWS 2 ANALYSIS: WF&811_SAT STERANE DISTRIBUTI°N West Staines #2 13070- 13110 ft RATIO COMPOUNDS VALUE S1) S2) C29S/C29S+C29R STERANE C29R&S ABB/C29S&R AAA+ C29R&S ABB 0.54 0.56 s3) s&) RATIO AAA 20R STERANES · ABB 20S&20R STERANES COMPOUNDS C27 C28 C29 27.1% 29.2% 43.7% 30.1% 30.7% 39.2% VALUE ss) M{ ) DIA BA/(DIA+ NON-DIAS~S) (CALCULATED) C27-35 HOPANES/(HOPANES+STERANES C27-29) 61.9% 69 ..6~% HOPANE DISTRIBUTION RATIO · · co m6u os VALUE H1) H2) H3) H6) C32S/C32S+R'HOPANE -. C31S/C31S+R HOPANE C30 HOPANE/HOPANE+FDRETANE 18A/18A+17A HOPANE GMC Data Report No. l S3 0.63 0.62 0.90 0.58 Page' 109/ 113 Ion ,~9J.O0 amu. from WF4811_SAT. d Abundance 5OO00 ~0000 ,' 30000 . 20000 lO000 0 '" ' ...... " - ' ' -- - I ' ' ..... ' - I ' ' ........... 20 30 Time (min,) Ion 2i7,00 amu, from WF48ii_.SAT,d undance Ab ~8000 i8000 i4000 12000 iO000 8O0O 6000 4000 2000 0 , i i ' , i I ' 20 30 Time (min,) BROOKIAN OIL SHOWS West Staines #2 13070- 13110 ft i '' , ........... i ..... ]- ' ......... I 40 50 I II I Il i - - 40 5O Abundance - 50000 - /40000 ' Ion ~gJ.o0 amu. 30000 20000 iO000 32 36 Time from HF48~_SAT,d BROOKZAN O3:1. SHOWS West Stalnes #2 13070- 13110 ft 40 44 48 (min .) Abundance · i8000 t6000 14000 12000 t0000 8000 6000 · 4000 2000 28 Ion 2t7.00 amu. fr'om WF48~.i _SAT. d Time (min.) West Stalnes #2 13070- 13110 ft 38 Ion .~77.00 amu. fr'om ttF4B~._SAT.d' Abundance i0000 BROOKltAN O1tL SHOWS 2 West Stalnes #2 6o00 '] -13070 - 13110 ft 6000 ,1000 2000 0 ~' " i ,---, i"' i 'i" 'i ' ;i" ' I , ,,, 'I .... i' ,"' i ..... ,~ "i' , .... ' .... '~"'l ........ ~' .... ' ,' 'J , '"" ' ' .... i"- ~- -~ ~- ; .... ~ 32 34 36 38 40 4~ 44 46 48 50 Time (min,) Ion igi,00 amu. fr, om WF48ii_SAT.d Abundance 50000 40000 30000 20000 t0000 32 3,4 :36 38 40 42 44 Time (min,) 46 48 " 50
