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GMC Data Report No. 275
Geochemical analysis of cuttings from the following North Slope oil/gas exploratory wells: ARca Alaska Inc. Bergschrund No. 1 (6,520' - 6,600') ARca Alaska Inc. Fiord No. 1 (6,560' - 6,720') ARCa Alaska Inc. Fiord No.2 (7,520' - 7,620'). ~~ GE~Ozo :¡; ~ ~ ~. 0 $?¡ALS Received 27 October 1997 Total of 85 pages in report Alaska Geologic Materials Center Data Report No. 275 GEOCHEMISTRY Geochemical Analysis of Cuttings Samples from Bergschrund-l; Fiord-] and Fiord-2, Alaska by :SR Andrews' LGC (Teddington) Ltd. Ref.: LFX/228/40 Prepared for: Neil Piggott BPX Sunbury CheI1sey Road Sunbury on Thames Ref.: 1001576 . Authorised by: NS Goodwin Date: 6th October-1997 GMC Data Report 275 Page 1 of 85 ···.··.··w ".,.._,..,.,..""._,....,."...,'~,......_, ...~_'_.. ..',"",. Cl ~ n t:I $:I:> ~ $:I:> id CD Iocj o ;:1. N -..J VI COUNTRY: Ala5ka WELL: -Fiord-I DEPTH DEPTIIRANGE 1\ ft 6560-6720 I¡j $:I:> {JQ CD N o H-¡ 00 VI TABLE 1.2 LImOLOGY AND STRATIGRAPHY FORMATION HRZ AGE TABLE LITHOLOGY PICKED SAMPLE TYPE LITIIOLOGY MOST-die BY shale 9O%:SSt It gylbr 10% Mudstone CUT a ~ n,;' tJ p:¡ -- p:¡ ~ CD "'d o ::¡ N -..) VI COUNfRY: WELL: DEPTH DEPTIIRANGE ft ft 1520-7550 7550-7580 7580-7620 Iï::I $:I:> fIG (!) w o I-t) 00 VI Ala5ka . Fiord-2 TABLEt.3 LITHOLOGY AND STRATIGRAPHY FORMATION IIRZ HRZ HRZ AGE LllHOLOGY PICKED SAMPLE TYPE LIlllOLOGY MDST-dk 8Y shale 9O%:SSt It gylbr 10% MOST -die 8Y shale 9O%:SSt It gylbr 10% MDST-dk gy shale 9O%:SStltgy 10% Mudstone Mudstone Mudstone Clff t:lff CUT .- - Q'. ~.. (') 0, $:I:> ~ $:I:> ~ CD "d o ::¡ N -..) VI I¡j $:I:> (JC¡ CD .þ.. 0; H-¡ 00 VI DEPTH (ft) 6530 6540 6550 6560 657G 6580 6590 6600 TABLE 2.1 SOURCE ROCK QUALITY INDICATORS COUNTRY: Alaska ' WELL: Bergschmnd-l DEPTHRANGE FORMATION PICKED LImOLOGY PI PI P2 TOC TMAX HI GOGI CARBT S (ft) (kglt) (mglgC) (kglt) (%) degC (%) (%) HRZ Mudstone 1.1 16.7 22.7 6.6 443 344 7.1 1.9 HRZ Mudstone 1.1 22.4 13.5 4.9 427 276 8.9 3.8 HRZ Mudstone 1.1 24.4 13.5 4.5 426 300 9.8 2.1 HRZ Mudstone 1 19.6 14.7. 5.1 428 288 8.2' 3.3 HRZ Mudstone 1 22.2 17.3 4.5 424 384, 8~7 3 HRZ Mudstone 1.3 21.7 18.9 6 423 315 7.4 2.5 HRZ Mudstone 1.1 15.9 18.4 6.9 - 428' 267 7 2.6 HRZ Mudstone 1 19.6" 15.1 5.1 433 296 8.2 2.5 CJ ~ (1 o $:I:> ~ p:¡ þd CD '"d o ::4- N -..J VI ~I ;t;t:~-1 TABLE 2.2 SOURCE ROCK QUALITY INDICATORS COUNTRY: AJaska WELL: ' Fiord-l DEPTII DEPTH RANGE FORMA nON PICKED LITIIOLOGY PI . Pi P2 Toe TMAX H[ GOGI CARBT S (ft) (ft) (kg/t) (mg/gC) (kg/t) (%) degC (%) (0/..) 6560-6720 HRZ Mudstone 1.01 16.6 15.14 6.1 430 248 8.72 3.44 I¡j $:I:> {JQ (t) V\ o H-¡ 00 VI ....:.~;: í o ~ (J o $:I:> ~ $:I:> id CD "d o ;:1. N -..) VI TABLE 2.3 SOURCE ROCK QUALITY INDICATORS ~ PJ {JQ CD 0\ o H-¡ 00 VI COUNTRY: Alaska· WELL: Fiord-2 DEPTH DE PTHRANGE FORMATION PICKED LIffiOLOGY PI PI P2 TOC TMAX HI GOGI CARBT S (ft) (ft) (legit) (mg/gC) (Ieg/t) (%) degC (%) (%) 7520~ 7550 . HRZ Mudstone 0.86 27.1 7.27 3.1 426 234 8.61 2.19 7550~ 7580 HRZ Mudstone _' L13 16.6 20.21 6.82 421 296 6.47 3.61 7580-7620 HRZ ' Mudstone 1.06 16.2 19.68 '6.57 429 300 7.86 2.93 ¡ i I \ I i ., a ~ n d p:t .-+ '$:I:>, ~ CD ~ o :4- N --.] Vt " I-jj p) (JQ CD ..:...) o H-¡ 00 VI ~ " i: :~ , DEPTII ft 6560 TABLE 3.1 OPTICAL SOURCE ROCK MATURITY INDICA TORS COUNTRY:· Alaska WELL: Bergschrund-1 FORMA nON VITRINITE NO. of CONFIDENCE (%Ro) READINGS HRZ 20 0.5 Confidence A=Excellent .B=Good C~Average D COMMENTS MOD PHY;IPARIOO% VPAR TR; MOD BS. MODJRI BW;L ALG Y/O.TR HYD SPE Y/O. TR SP LT 0 D=Poor E=Dubíous E=Dubious D=Poor MOD-RI PHY;IPAR 10%, VW+VW PAR 30%;MOD-STR BS. MOD-RI BW, TR ALG Y/O-LO, TR Sf LT 0 COMMENTS A=ExceUent ~=<ìood C=Average Confidence CO~TRY: ' Alaska WELL: Fiord-I , DEPTU FORMATION VITRINITE NO. of CONFIDENCE ft (%Ro) READINGS 6720 HRZ 0.54 20 C OPTICAL SOURCE ROCK MATURITY INDICATORS TABLE 3.2 ! '. 'Þ¡: ~ (JQ (1) 00 ,0 J H-¡ '00 , VI :C> . ';s;:: /1 ':1::) :;$:1:> .-+ ':~ ':10 ;CD ~ :0 ::+ N -..) VI 0, ~ () tj $:I:> ..-+-. $:1:>' ~ ro- '0: o ::¡ N -..) VI TABLE 3.3 OPTICAL SOURCE ROCK MATURITY INDICATORS COUNTRY: ' Alaska WELL: Fiord-2 DEPTH FORMATION VITRINITE NO. of CONFIDENCE ft ("IoRo) READINGS 1550 HRZ 0.57 20 D ~' ~ Q'Q (D \0 o I--t) 00 V\ Confidence A=Excellent B=Good C=A verage ÇOMMENTS MOD-RI PHY;IPAR 100%.TR VW PAR+PAR; MOD/STR BS, MOD-RI BW+BL; TRALG LT 0, TR SP LT-M 0 D=Poor E=Dubious VITRINITE ABBREVIATIONS ANS · Anisotropic B · Bitumen BAR · . Virtually Barren BL · Blebs BS · Bitumen Staining BW · Bitumen Wisps CARB· Carbargi1ite CAV · Caved COR · Corroded CTGS· Cuttings DO · Differentiation Difficu~ DEC · Decomposed, DMA . Drilling Mud Add~ive DOM .. Dominant F · Few FL - Fluorescence FR · Fragments GN · Gnarled G · Good HAE - Haematite HI .. High I - Inertinite IGN · Igneous Traces INST · Interstitial IRON .. Iron Oxides L .. Low LGN .. Lignite LOW .. Low RefJectances LT .. Light MAT .. Maturity M .. Mostly MOD .. Moderate NDP .. No Determination Possible NTV · No True Vitrinite aBS .. Overall Bitumen Staining acc · Occasional ax .. Indications of Oxidation P · Poor PAR .. Particles PHY .. Phytoclast content PL - ,Plentiful or Plenty POS - Possibly PY - Pyrite R - Reworked RES - Resin RI - Rich RM - Reworked Material RO · Reflectance Measurement S - Some SC - Scruffy SH - Shale SLT - Siltstone SML - Smail SPE - Specks STC - Structure STR - Strongly SUB .. Subordinate T8 - Turbo-drilled TEL .. Telinitic TR - Trace V - Vitrinite VAR - Variable RO VL - Very Low Organic Content VLT .. Very Light VST - Vitrinite Stringers VW - Vitrinite Wisps W - Wisps 0 r Wispy WH .. Wholly .. Allocthonous = I - Equal Proportions ? .. Questionable SPORE FLUORESCENCE COLOURS UNDER ULTRAVIOLET LIGHT G - Green Y - Yellow 0 .. Orange R - Red LT - Light M - Mid D - Deep P · Pale ALG - Algae CAR - Carbonate HYD · Hydrocarbon RES - Resin RH - Rhombs SP .. Spores GMC Data Report 275 Page 10 of85 Date Signature In!!~( """,II :0(1':;'" ):11: !.~ E~~rr."rDff~·,f: f :~;\ If' " JHISOI1 1~1( U~tr¡;¡1 [~.:. ¡;.: , :liJI1Hlno:o:: - Jor:nU/T;I;Ur!;jIH r,¡r:.:-:' :!....: GEOLA8 ~ UK WAVELENGTH R.I. OF IMMERSION OIL 546nm / 1·516/ ()'67 TOTAL No. OF O·6() PARTICLES MEASURED .<0 0·5/ No. OF O·6C) REFLECTIVITY (010) PARTICLES' O'S'2 R:/ 0-5"4 20 I¡¡¡¡;( R ~ver. COMMENTS C ~0 - 0 45 Ij 50 ".: .-J",' t.,.. ........ . . . .. . .. .. . .. I . ....... . ",".. f.' I "" '''' ...... "',,' ............ ...,.. . ........... t,..".. .0?~ç\q ¡.O . . . . .. ,'. . . ;?;;'*4". . . I...... . . . .#c.f~.. _... .. .. ..p-:~?:....... ..,'..... ,.... I $,*,,&- Colour Content Character FLUORESCENCE " .., I... I I., I.. I.. I......... .... I...... . ...... ... . ""'" I . . I I'" "" I I...'..... I............ . .... ... .. Condition . . I . I , I . . . , , .. . , . . . . . . . . . . I , I . . I , . , . . I . . .. " ...... Form /~/2. "7Í'CC<:3 ¡;¡;;;' ; ¡¡~; 4~;~~~:: : :: I' .. ., .. .. 1_' I., , . . . ..,. Character ,1«f::~??,(I(~~~ . . !!/?:?/."Y(. ~~ . . . 0/0 7~... I. .., 30 PHYTOCLASTS Content JIIo!).ê:I2197¿£ -;?ø . I I'.. . . f' . . ""'" . """ '~O, $"61,J 15:J../'7 , II!) 75) " SAMPLE Our Ref: Your Ref: I IVI \,,1- I VoJV\J '-' I -..... ,. f .... "" .. . It'..... I ... Content .~~/~~ . ~.t.?ß?("(~ ( 'G~C Data Report 27) ~W ~ I 90 2 ¡JO ' 2 30, PREPARATION Isopropyl Alcohol I ~r CJ·4' 0·57 (/·60 Ci ~ fI o· s"O OS} 0·5"/ 0·5' 05* 0·5'"4 O'$'o 0.5"0 O-s;, O· Sï 0·5(. "" .... I.. .. I. I" II' ., .,......." I I., I.... BITUMEN Form ß:¡/N//V4 .. """ ,...... 1'"", ...µ/~F............ ... .,...... '" '" I I .. I..... I I..... ....,., I.. '" It.,..,',. ". . . I' '"'" ...1 "" .. ",..,... ...,. . I, SPECIAL MINERALOGY ß7.h'~~ /?i</'TI( .,... I.', ,.,.... I'" . I . I .. " ....... . . .. ...,. t I . " . .... .. .,.. .... I' .. '" .. .... .. .. . . . ". t.' I. I.........". , . ., . ., , . , . ., , , I., . . . ~ . . , . . , . " . , , . . . . . . . . . . , . . . " . . . t "'" 100 ....,. . ., "' ,. .. .... .. .. ., .. . I.... . " . 0/0 LITHOLOGY ßpj,E , j. c. c:. ORIGIN Date Signåture .. : )"-11: ~.: Et'tcr(.JfJse CCM'1 ~¡;Ison IrìClIS[(I;:\1 E~:,l:i: I,::ijlrlilnqton ,\]Or1nUfT1tJE:r!i3r1C NE:::; A.': . Jr~I:"(J K!r:'l!Jo1n , - / GEOLA8 ~ UK COMMENTS -J) :2.0 0·5"0 Rffiæ( / ' / Raver. No. OF PARTICLES REFLECTIVITY (°/0) R.L OF IMMERSION OIL 1·516/ TOTAL No. OF ~ PARTICLES MEASURED zo Character Content Colour A,ç.;1,,€ ~t/4,) ..i~ ". M:ß~;~::::: ..... ,.... t ..-.- .. ;19 .. , !?~~~ , ..~~~~"",.., --- ..~~.:;ç~. L,O I"", \,' ,..... . t "' t. I I ... .. I.., "".... .. I. . .". FLUORESCENCE Condition . .f~l(. ,~A,!~~~~~~~~~..~",· ",.. Úr/<~ 1/\// ;>¡:. . ." . I.'........ ., , ..... I ........ ......,. .. It. .,. .. I. "'............ ...... 1'" . ". I I I I . .... " ...... .., r.... I" I ........ ..,. I . I . . .. I' ... . ,(~.Q. .. --- ,<-9.~(!. . .Form , (if~?"(,t:;~f.~. , ,arf.,~~<~~, . , . Character . h.);~??~~~~,. . ..if !?¿,t'~~ '!.~, . . % /tIo j)k-.:l?J.::J 72! . . , ", , I I '"' . ,... . . Content SAMPLE Our Ref: . Your Ref: PHYTOCLASTS '606 s6i¡7s';;'TG7 Ii]) 7r¡ ¡"'¡I;I~~\JIIIUIIU- I V<oJwV - .......""'....... /¡ ~~ \ 40 ' C &0 ~ j ! '\ ç a~ ': G~;': Data Report 275' <0; 110 100 0 9S ,0 9Page 12 of 85 . , '. , 90 ? SO 2 00 O'~9 tJ,~s" (/'#9 o.tt; 0-43 PREPARATION Isopropyl ,Alcohol / WsMr ð·Sï 0·5*, (J'it} 0·5"4 0·" c/·4¿ O·~3 0·37 o,~J 0'5'$' ,0.5"/ ()·ft.Z 0·(,0 0.42 0"7 WAVELENGTH 546nm / ..... ...... " . - ""....... . ... -" .. ..&~~... 11.~'? /4~. ' ,6r.~~).. ... ..,. I "'" '"'' l' I " Content BITUMEN Form .f5..~/N/~ : ~ :ïJ;; : : : : : : : : : " : : .., I.".... ,.., I.'" I " ..." I .' "1'" " ..'... t I 1 '" .,. II.... .. '" "" , I . .. I ... ,.,. I. . .. I" I , """",,, I...... .. .. .. " . t .,. I , ., , ,. ". " I . . SPECIAL MINERALOGY . "1." ., .. I I' f"" ,... ., ... .. " . , . , ,. , .. .. . .., ..... _., ..... ... . . I .. , . . > .. . .. , . ......,..,.. ,. ,I" .. ., I I . " . , 100 .... I . I" LITHOLOGY ßh;¡'~ .......... ...... .. . . . ., . . I 0/0 i: C. c: ORIGIN ,.. .. "..... . ~ . . . , . , .. . , ..'. '. q., , ~ ·¡l/.fO ",..,.. .-,', Colour·. Date Signature ; Jnll ,~ E: :ror¡')rlSG c./ur~ ~J~lson Inau¡;¡r/(11 E~r;j:':· ;,~r ìJrnllnglQn ,"¡ortMurT10orlann NE2: ',iL...: : -'nlred Kif Iqaorn GEOLA8 ~ UK COMMENTS ]) 2.0 0·fi7 R~ /. / Raver. No. OF PARTICLES REFLECTIVITY (0/0) R.I. OF IMMERSION OIL 1'516/ TOTAL No. OF PARTICLES MEASURED 20 .....,....,.. . .. . . . . . .. .. I . .. . I ~ I I I .. .. ,.. I...... '" I.. - ... I I................. ~Cê . .. . .. ~ . .. .. . '" . Character #M);.¡f : ::r:~~~::: ~ ~::: .. _ .. f , . ~ . .. .. .. ~ Content t.. " ....... ..... I.....'...........,...... ....... . .. I. I. ... FLUORESCENCE . ............ "" ........ I"" '," I" ........,.. '" I..... ., ... ,.. ...... I . I . . I I , I .. I . . . .. . .. . , . . . . . . .. I . . .. , , . . I I I . . . .. , . Condition 0/0' /ðO I' ,I. I , '" .&~... ""''''''M_.'' ._,........ Character Form h..;;f' 77#/ 7~ 4.;c",~ '~~~~~;;' . .. M;~;' ~;~;;;; :::: :....:: ::::: ::: ~.'~~~~~~:::: . PHYTOCLASTS Content .#Æj)~ì?~7£ - R~ . . I'.... '.. . . I I' ,." .". , SA~'~~E'-"Õür R~T-r- ÞOG~G~/ S-VG7 Your Ref: )I]) 80 . ."-'1.... .... ""......., r 'W""twlU" ':J \ 5 I 90 o ~o 2 00 045 2 ~o 0,6/ ()·6:.r O·/,t~- O·GS' CJ·# c. PREPARATION· Isopropyl Alcohol / \#;;M ()'60 ¿:J·t? CJ'S"Z 0·;2 0':/7 0·5·/ {)·42 0.62. O·S"' o ·7/ c),6?? O·5!> 0·41 OG7 O·/,IJ WAVELENGTH 546nm / "'" .... .,. ., 1"'" I"" - I I "'...... .... ...., ., . '" .".. .., I. .., I'.... I, I, Content .~p/~~<; . (1:'",?/A1~. BITUMEN Form 4 ..ß"f~~~...,..., #r;~, .~ 4~.r:. . . . . .,.. ,.....,.,. .."... I....' . , I.. . . I . '" I I .. I . I I'" I,. .. I I .,. ,"." . ,., ..... .". ...... , ..., ... SPECIAL MINERALOGY B ~¢~ )4,,¿/7-'c, .. , .. , .. " . I . . .. , . I . I . . . . . . . I . . . .. . I . . . . I , . . , , . ~ .. . . . . . . . .... " , I.., . I I .. I I... ....... I I .. . . . , , .. . . I I I I" "" ... .. I'''' '" I ..... ., . . . . . . . . . . . .... . .,.. .. . " .... " .,..,.... /00 ... <I" . I I . LJTHOLO'GY ß4~£ , I" I.. . , ., . I .. '" . .... . . I' . 0/0 'J.c.r:: ORIGIN Sheet1 Table 4 Kerogen Source Rock Isotope Values Well Sample Depth (ft) del C13 per mil Bergschrund-1 6520--6530 -27.8 6530-6540 -27.5 6540-6550 -27.5 6550-6560 -27.7 6560-6570 -27.9 6570-6580 -28, 6580-6590 -28.2 6590-6600 -27.8 Flord-1 6560-6720 -27.8 Fiord-2 7520-7550 -27.6 7550-7580 -28.3 7580-7620 -28 . GMC Data Report 275 ' Page 14 of 85 1 Page . .-.-~._. .~, ..-.... ò ~ () t:j p.ì ~ ~ ~ ro "'0 ~ N -.J V\ Sediment/Extract Analysis Well Dame: Suite Dame: COUDtry Of Origin: Depth (m) : Sample name: Bergschrund-I Bergschrund-I Source Rock Study Alaska 6590 HRZ unit Inspection Properties API: Density@ IS deg C: \Vax Content %wt: Wax Melling Point deg C: Pour Point dcg C :' Viscocily cSt @ 20 dcg C : TOlal Acidity mg KOII/g : Asphaltenes %wt (II' Metbod) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm: NickdNanadium : Extraction TSE %wt: 0.240 HPLC Saturates %wt: Aromatics %wt : Residues % \VI : AsphaUCDCS (Micro Method) %wt : I¡j ~ {JQ (þ ~ VI 0 H-¡ 00 VI ~\ ~ t\\ ,~ ) III: 0.39 112 : 0.45 113 : 0.73 114: 0 liS: 100:105:41:31:18:13 116: . 0.19 111 : 0.43 118: 119 : 1110 : 1111: 1112 : 1113: 1114 : IllS: 11I6 : 1111: 1118 : Biomarker Ratios 51 : 0.22 MZ: 0-66 52 : 0.32 At3: 0.58 S3 : 36:28:34 M4: 35.08 54,: 32:34:32 I\1S : SS: 45.03 AI: 0.11 A2: 0.15 86 : A3: 0.28 81 : 51.28 0.07 A4: 88 : 28.17 AS: 0.68 59 : A6: 2.31 SIO: MDR: 0.54 MOP: 4.86 8.12 3.51 4.18 9.03 0.00 0,00 42.70 0.00 :,. -; '. " Saturates GC PristaneIPhytanc : Pristaoe/oCI1 : Pbytane/nCt8 : crl: ALKlND : al2 : Light Hydrocarbons Mcn % : IIER IIXR Stable Carbon Isotopes Saturates : T oral Oil : Aromatics : Residue: AspbaUcncs : Kerogen: -28.2 STANDARD: NBS22 -29.8 Inspection Properties API: Density @ IS deg C : Wax Content %wt : Wax Melling Point deg C : Pour Point dtg C : Viscodty cSt @ 20 deg C : Total Acidity mg KOWg : AspbliUenes %wt (IP Method) : Nilrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickeWanadium : o ~ f) Ö s¡I) .-.+ ,~ .~ (t) ~ ,0 :::4- N ......) Vi .' 1-0 þ (JQ .CD ~ :0\ ,0 I--t) 00 VI ~. A:' ~ ~ <.'t\ ~ III: 112 : 113: 114 : 115 : 1(6: 111 : 118: 119: 1110 : 1111: 1112: JIB: 1114 : 1115 : 1116 : 1117 : 1118 : î ',. ; .:~ " '. ~ -:7. ;~ ~ , f Well name: Suite name: COUDtry OfO.-igin : Depth (m) : Sample name: 0.41 0.48 0.72 o 100;99:39:28;18:12 0.18 OAO 6.51 2.64 5.24 11.98 0.00 0.39 40.33 0,00 fiord-2 Fiord-2 Source Rock Study Alaska 7620 HRZ unit SedimentlExtract Analysis Extraction, TSE -Iowt: 0.200 HPLC Saturates %wt: Aromatics %wt : Residues %wt: AspbaUenes (Micro Method) %wt : Saturates GC rristaneJPhytaDe : P.-istancJnCl1 : PhytancJnC18 : CPI: ALKlNO : R22 : Biomarker Ratios Light Hydrocarbons SI : 020 M2: 0.63 1\1CH % : 81: 0.26 I\U: 0.58 IIER S3 : 35:28:35 M4: 37.78 HXR 84,: 32:35:32 MS: S5 : 44.73 AI: 0.22 A2 : 0.20 86 : Stable Carbon Isotopes A3; 0.25 57.: 49.99 0.06 A4: 58 : 21.51 0.81 Saturates: AS: 89 : Total Oil : ~29A AD; 2.25 Aromatics: SIO: MDR: 0.46 Residue: MOP: 4.54 AsphalteDtS : Kerogen: -28 STANDARD: NÐS22 -29.8 - CJ - 3: =- , () 260~ ~O :~ ~ i~ ~ : id, 24û~ ·CD '0 ,0 ': ~ 220~' N - : -..) ¡VI 9705SEDO 13S007, - - 200-= - - 180-=. - '~ - : ~ -, . (JQ 160--= :(1) '=- ~ ...-. : -..) - : 0 - : H") 140-= ,(x) - ~Ut = " - 120-::= - - 100-= ')} ~ " '- - \. <1' 80~ - - . ; - 60-=- :] - '. - 4°1 ~ . IJjIJ~ J 20-= l.!li M ,S f~l ~ JJAµJJAI tl il,'I" I . > ,~ _;:i ~ .~ -~ i ,.~ Bergschrund-1, 6570-6590ft (mudstone, HRZ unit) Total Soluble Extract GC I ,. . . ~\ l~{ t,~ '~~ I' ~ J,i, ~~ ,,~. ~ \\If\\~,.AI\I!I.''''~\<j~,¡,J , ~~ .J...~" ~."C\........ --..v'-'"'--------.,.~___ t tl 1 - o--=- -1m 1'III I' r IITTTITrTlTTrn 'III r 1111 f I f 1'1 rTfITl'IIIIIIIIII III' IIII r 111 lllllT11Tf11UrrnTfTTDlT11 rpTfTIITTTTTTnrrrnTfn rpTTTTTTrry !TTTfTnTrTTTJTlrrrrrnp rITfnrrfnn I I I / I 1/ ,/ '1/ 1/'1' 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 ) - ~20~, . - () ~ t) 9705SED017S003 ~ .. .-t- - ;t0o~ CD Iocj .. 0 '~ :4- _ '; ~80--= V'I - -, 160, ' ~ ~40-= ~ - {JQ CD Fiord-2, 7550-7620ft (mudstone, HRZ unit) ~ 00 ~ ~20-:·· H) - 00 VI Total Soluble Extract GC 100=< 80"= 60-= '1) ~. ~}.J 40-" :¡.. ,I .. . I .' 4; ~ l1 J ~~I4,J ~: I! ". ' . ..:' I .I, W\v I ~,~, ,~./f\~w.~~' ,J..¡ w'~~ == ' J, i.~k I: t·t~' ,~ ~ . "~.J. 20,'=' . ~ 'ill ~ ' ~-"'-'---'~-----", = ,nï~ ~ '~___Jß~V,~ . 0"= » - TrTTfTTI r \ 1111 FT11 111 \ \ I n IIII11 ¡ III1 ~ 111\ ( IIIIIIII { r 111 llTTpTIl IIIIIIIIIIIIII 1111111111111111 r fill' ) 111111111111'11111 i J IIIIIIIIIIIIIIIIIIIII}'IIIIIIIIIII TTPTll 11111111 r 11111 r I rTTfITTl 6 8 . 10 12 14 16 18 20 22 24' 26 28 30 32 34 36 3A iln A'" " " ~! . j 'j ..:c ~ ~!I .:! :1 C)' ~~ n: 0: ~: -- p) ~::r CD ' , "d '. 0' ::¡ N' -..) VI I ~ $:1:>; (JQ. (l) Þ-" \0 o Þ-f) 00 V:1) ~~ 1 .¡ ~ < ~It ~.~ ~j ~ :1 " File:MPDMI00066? #1-3081 Acg:11-JON-1991 14:10:26 GC EI+ Voltage SIR ?OSE Sample.2 Text:BERSCHRUND-l 6590ft $9705SED013S007$ File Text:GCM8 6000RP 191.1799 5:2 F:2 10~ - 90-= - 80-= - 70~ - 60": - 50~ - 40~ 30-= '20-= .J ~ 10": O-=" 30': 00 217.1956 10~ 90-=; 80~ 8:2 F:2 ...... - 70-= 60": 50-':- - 40-':: I ., 30"': - 20-= - 10~. 1M O:~~ -. I . I 30:00 Exp: GCMS_HRSIR (f v {oJ 1> -ís ú .{s A «. " -iP" .1 ~ . ,11' IX ~~ l \. \J'~ J.... /.t "'- j'b....J.1AILili..AA_~_,____. - 1:0ð:OÒ l:lÓ:OO I I I 40:00 I r · 50:00 1< q.1- (0 ' \\ 1'0. 11 -5b ..,;, I I I 40:00 h}' J }\\:I ~,l,----. __.._ _ _ . I I I r I b r I b I . 50:00 1:0 :00 1:1 :00 ~ .~, _.~.......... ~ .,.-~..-,,",:-,,-;-- .-. - _3.4&7 ~3.1E7 - ~2.7E7 - =-2.4&7 - ~2.1E7 - =-1.7E7 .... =-1.4E7 ~1.0E7 - :'6.9B6 =-3_4E~ - _~ 0 . OEO Time _2.1&7 - ~1.9E7 - ~1.7E7 - :"1.5E7 - :'1.3&7 ...; :"1.1E7 - :"8.4&6 - :"6.3E6 - :"4.2E6 - :"2.1&6 - .= 0 . OEO Time Q- ~ o ti1 ~ -- ~ ~ '"d o ~ tY" ;...,J q. - 1 ~ pJ (JQ CD tv o Ó ~ Qo CI'I ¡~ File:MPDMI0006õ1 #1-3081 Acq:l1-JUN-199~ 14:10:26 GC EI+ Voltage SIR ~~SE Sample#2 Text:BERSCHROND-1 6590ft $9105SED013S001$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 177.1643 5:2 F:2 10œ.: _6.9£6 80~ ~5.5£6 40~ 60~ ~4.1E6 ~2.8E6 ~ 20---= . .IJ,I~J f \M 1" I. . .1.1 f" ...I¡/-'II......~ 0- 30:00 '40~OO' 191.1199 8:2 F:2 , 1000~ 80-= 60.0: 40-=: 20-= o : ¡^----Á -, ' L..J 30-: 00 'I ' I 4 0 ~ 00 I '.'"\ \N 205 . 195 6 S: 2 F; 2 \ lOO'!£ ~ : ~ -¡ ,¡ 'I ; ! \ .~ ~ BO~ 60~ 40~ 20-= -~...... O-=:I -,......-"..- , I I I 30:00 ....+-.. ~-""'--- I I I 40:00 '. '50~00r- l:-òÓ;OÓ i:lh:oo I ,- 1 ^-J~ '.,..- ~~LÅ\~IJJ 'i:óò:oo I "I I I' 50:00 --~ i : 16 : 0 0 - I ~~l~ ,~_ 6. - _ _ i:ob:oò 1:10:00 I I I 50:00 - - " ,., I 1 I 1:20:00 ~ ~1.4E6 .,- o. OEO Time _3.4£1 :..2.7E7 ~2.1E7 ~1.4E7 ,:..6.9£6 - - ~ - . n. t_".- 0 . OEO 1:26:00 Time 1 I 1 1:20:00 _8.6£6 =-6.8£6 =-5.1£6 :..3.4E6 :..1.7£6 - 0 . OEO Time C). . ~ n t:1 $:1:>: <""'t- $:1:>; ~ CD' Iocj 0: ~ N. -..J VI ~. $:I:> (JQ CD 10 ........ Q r-;t) do v-. :! ! ,-, - j , ~ ; 0( ~ . :j J ~ ·1 1 , --; Fìle:MPDMI00066~ #1-308"/ Acq:l1-JUN-199? 14:10:26 GC EI+ Voltage SIR ?OSB Samp1ei2 Text:BERSCHRUND-l 6590ft $9705SED013S007$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 218.2033 S:2 F:2 10~ _8.1E6 80~ ~6.5E6 60~ ~4.9E6 40~ ~3.2E6 - - 20~. I . ... j; \ ~ III v' ~ t iA. w . .1 . ~1. 6E6 O-~M\vÅ.~_'" ,..__~'\JV __ 't..YU~-o OEO 30:00 ' I '35~O'O' '1 40~OO' I 1 4S~OÒ .- , 50~0-O' I' , "55~'OO' -, 111:011:010 I 'I I , . Time 217.1956 8:2 F:2 , 1 0 ~ _2 . 1E7 80.-:: 60..:: 40.-:: 20.-:: -þ~ 1 o-=~ I - 1) 30:00 ~, 231~2111 1 0 O'!f l", ~ . - w 80..:. 1 I 1 35:00 S:2 F:2 60...:: 40-= 20~ ~AJ o-~ - I I I 1 I I I I 30:00 35:00 , :...1 . 7£7 ~1. 3£7 :.8.4£6 40 ~ 00' 45 ~ 00' w~JÞVJvAïNAÅ ~",-, &~ 's 0 ~ 0 Ò I '55 roo' 1 11: 0 b : 0' 0' Ì- , 'I ?O.OEO Time ,:.4'.2E6 _7.0£6 -- ~5.6E6 =-.4.2E6 ~vJJ'~ 4~J~ J ~~::::: I I I . (I . I I 1 I I - 0 .OBO 50:00 55:00 1:00:00 Time I I I 40:00 I I 1 45:00 : 0 .OBO Time :"6.8E6 :"4.5E6 =-2.3£6 =-1.1E7 :"9.0E6 -:"'1.6B7 =-1.4£7 :"2.0B7 :"1.8B7 _2.387 ::-3.6£6 ,; O. OBO Time :"7.3B6 :"1.1£7 :"1.5E7 :"1.8E7 _3.6E7 :"3.3E7 :"2.9E7 L :"2.5E7 =-2.2E7 , I I 1:10:00 , . J It, ~ ~'------ 1.:06:00 ,- - . - - .. ~<1' ~ '\'l' ....~~.~- -~~#""'~'~":':"'."--'.-~ . ~·fiF.""'~"'-"'·liif'''''~''Sf''.·~,-, ~-- -.. .\' I I 1 50:00 , 40~OO I 10": o ~.~Jww 30:00 J '- I Å~~I .I Ð 'J~ 90":- 80-= 70": 60-= 50-= .... 40": 30": 2 0": '\ -z.,f'\ 't> 1-~ 40-= 30~ 20": 10": o~~ ."~___A"'W~ 30:00 I J' ,- I 40~0() , 217.1956 B:3 F:2 ' 10O?i ~ ({ \ ù p /Íi. 1f tX t .^-'Å"_ .~ ~ [" ~ IIv. \",""Jl~1i~_~. - ,- I' I 50~O'O" ,- I í~()Ó:OÓ--' I 1:10:00 " I ~ "1> rJo 1-- 80": 70-= 6 0": 5 0": 9 0": File:HPDMI00066'l #1-308'l Acq:l1-JUN-1991 1~:~1:40 GC EI+ Voltage SIR 'lOSE Samp¡ei3 Text:FIORD-2 7620ft $9705SSED017S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 191.1799 8:3 F:2 10~ v :. ,~ ; -... *' I-c: P' (JQ (1) N N ~o ~~ v. ~') . .... ", ø 3: n Ò ~ ...,.. ~ it' (1) "0 ..0 ::4 ,N ':.:w Vl , , ex ~ Q Ö p)~ ~' $:1:>' ~ CD:: "0': Oi ::¡: N -.....1 ~ ,- ; Þ-Ø ~ (JQ o tv W o ~ 00 ~~ ~ , ,~ J " File:MPDM100066'l #1-3087 Acq:l1-JUN-1997 1~:~1:40 GC E1+ Voltage SIR 70SE Sample#3 Text:F10RD-2 7620ft $970S88ED017S003$ File Text:GCMS 6000RP Exp:GCMS_HRS1R 177.1643 8:3 F:2 10~ 80-.: 60-.: 40-.: 20-.: 0- 30:00 '40~00' 191.1799 8:3 1":2 1000; 80--= 60--= 40--= 20--= o ~ ..... ~.. r - J ~'a _ . I · 30:00 40:00 205.1956 8:3 1":2 10 œ-- 80--= 60-.: 4 0--= 20-= - o-=-.r- .. " '."" 30:00 . ....,--. ,,- . --,A-- ,. ~ .._. . I ' 40:00 'V~.i~J·~·~ ~~~~__. i:1Ó:OO I 50;00 i:oo:oo · 1 1 1:20:00 . . A _. . _ '..J. ........-.uJ...~ J.N,,,,- r '50:00" · -, í:06:0.ó ì :-10 -:O() . i; 2 ¿ ~ O'Ò .,.,. ~~ "'~.#-_A.._" __ "__ · J' · 1 r 'l' 50:00 1:00:00 1:10:00 I 1 I 1:20:00 _7.7E6 :"6.2E6 :'4.6E6 :"3.1£6 :'1.5E6 - O. OEO Time _3.6E7 :..2.9E7 :'2.2E7 :.1.5E7 :'7.3£6 1-- - O. OBO Time _9.5E6 :'7.6E6 :'5.7E6 :'3.8E6 :'1.9£6 - 0 . OEO Time p ,S: n b þ) -- p:¡ þd CD >¡::j o ;:t. N '-..J ;VI I¡j $:I:> {JQ CD 'N ~ '0 ~ 00 VI ~ ~. -, -- File:MPDMI000667 #1-3081 Acq:ll-JUN-1997 1~:~1:40 GC BI+ Voltage BIR 'lOSE Samp¡e#3 Text:FIORD-2 7620ft $97058BED017S003$ File Text:GCM8 6000RP Exp:GCMS_HR8IR 218.2033 8:3 F:2 10m _9.0E6 80...:: :..7.2E6 60...:: - :..5.4E6 40...:: =..3.6E6 20..: o~~ " - -- ~L I . . . I I 1 I I 30:00 35:00 40:00 217.1956 8:3 F:2 10œt . .Utl L~: \ ÌU^v I~ ..1' . J _ . ~1. BE6 ~'vJJI'VVV V ,lVl "rJ ...JI\J~- 0 .OEO · I · · I 1 I I · · I I I I 1 I 1 I I, I I 45:00 50:00 55:00 1:00:00 Time _2.3E1 80...:: =-1.BE1 ~ 60-=: =-1.4E1 40...:: 20: =-9.0B6 w "'" P\k'''/~ WI JVL~ '50~00' I --I 'S5~00' -. · l';ob:ö'o ' :..4.5B6 O-~'''-I- 30:00 35100 231.2111 8:3 F:2 -C' 10~ . IN 80...:: - 0 .OBO Time . 40 ~ 00' .- I I' .- 45:00 _6.9£6 - =-5.5E6 :..4.1B6 - 60...:: 40...:: L =-.2. 8E6 20~ .1 '. ' . . I. JJ,f~ ~ IAJJ J ~!.I . . .~1.4E6 o_~~~~v..~~\.J\ \JII~O.OEO I I I ~ I"" I"" I I 1 I I I' 1 I I I I I" l' I I I 30:00 35:00 40:00 45:00 50:00 55:00 1:00:00 'Time , ~ a ~ () tj $:1:>' ~ $:I:> ~ CD, '"0, 0' :4. N -..) VI ~ $:I:> (Jq CD N VI o ~ óo u. J ~ File:MPDMI000667 #1-3087 Acq:ll-JuN-1997 14:10:26 GC EI+ Voltage SIR 70SB Sample#2 Text:BBRSCHRUND_l 6590ft $9705SEDOI3S007$ File Text:GCMS 6000RP 231.1113 8:2 F:2 1 0 CY!£ - 90-': - 80-': 70-': 60-': - 50-=: 40-=: 30-': - . 20": - 10-= " 't o : t , , , r I ' 3~:00 35:00 253.1955 8:2 F:2 10 OO:íi f , , I ' , 40:00 r 'r r ' , 45:00 ~ 90-= ~ 80-': 70-': - 60-': 50-': - 40": 30-': - 20": - 10-= L, l \ l~ - '0 : , 30:00 --~""~""~rt;o'~;: _- ""-,. __._:-.' :"-t _ . ,., ..... .a I... , , I ' I . 50:00 flrl (-f ,".1 (-~ ,t fn""I<6 BXP:GCMS_HRSIR f26 ili> f1~ .J.---,,,,,,,1 Wi --J..û.r- ~ r '5 5 ~ 0,) , '1; 0 Ó:Ò O· -¡ i; 0 A : ,) 0' f 1'11"'1 f\o t\3 :~.~.~ ~~ I" 50:00 55:00 1:00:00 , fl' I 1:05:00 _5.9E1 - :"5.4E1 - =-4.BE7 - =-4.2E1 - =-3.6E7 - =-3.0£7 - :"2.4£7 - =-1.8B7 :"1.2B1 - =-5.9£6 : 0 . OEO Time _1.6£8 - :"1.5£8 - =--1.3E8 :"1.1E8 - ~9.7E7 :"8.1E7 - :"6.5£7 :"4.9E7 - :"3.2B7 - =-1.6E7 - .= 0 . 0 E 0 Time =0.0£0 Time -:"2.9&7 :"1.5B7 :"5.8&7 ::"4.4&7 :"7.3B7 =-1.3E8 ... ~1.2E8 ~1.0E8 :"8.7E7 _1.SE8 [1.6B7 :"8.1B6 , : 0 . OEO Time ~3.3B7 :"2.4E7 -:"5.7£7 ¿4.9B7 :"4.1E7 ~8.1E7 3-7.3E7 :"6.5E7 .,-+ ....-'-- .., :'~"'''''~'-"'.:-~''-''''''' f -11' f-l-"?> _ ~' ~I~ lIvt'tW'ia.. -~ '~.. I I,. I I " T r I I 1 I I . I 1 I 1 1 . I . I 1 1 . I 35:00 40:00 45:00 50:00 55:00. 1:00:00 (¡~O~:ÒO' I I ç.3 ftoÎ /\l-t' ~ f!o ~~ I I ø _~"- "'" Iu ~ ~~ 1 I I I I I I I I I 1 1 I I I, I 1 I I 50:00 55:00 1:00:001:05:00 fit) ¡t"i fib Ý1-O f1. 1 . I 45:00 I I I I 40:00 -..,.---,- I . , 35:00 8:3 F:2 20-= 10-= o : _" 1 1 30:00 30": 3 0": 2 0": 103 o :_ , ¡ 30:00 253.1955 1000¡ 90": 80": 70": 6 0": 5 0": 4 0": 40-= 80": 70": 60-= 50": 90":, File:MPDMI00066ï #1-3081 Acq:ll-JUN-199'l 1~:~1:40 GC EI+Voltage SIR 'lOBE Sample#3 Text:FIORD-2 7620ft $9705SSED017S003$File Text:GCMS 6000RP Exp:GCMS_HRSIR 231.1173 8:3 F:2 1 0 ()?¡j fl1.....'~ , I (Æ) f\4 "> -J ~ ~ ~ í ·1 :~ " ~ \ ~ \ \~ -.1. ~ ~ ~ {JQ ~ N Q\ d H-¡ 00 v-. d ~ () d $:I:> " ~ $:I:>~ ::d CD, ~ Þ--cj": , 0' =:¡: tv -..J VI '. 0- ~ n t:1 p:¡ .-+- W Id CD- "0: 0, ~ N- -..J VJ ~. p:¡ {JQ (t) N -.:J o ~ 00 VI File:~PDMI00066·1 #1-1291 Acq:11-JUN-199"¡ 14:10:26 GC EI+ Voltage SIR ~/OSE Sampleü2 Text:BER5CHRUND-l 6590ft $9705SED0138007$ File Text:GCMS 6000RP 178.0782 8:2 10~ .~ ~ - 90--= 80~ - 70--= 60-': - 50": 0, 40-': - 30": - °20-': - 10-= - O:~~~.....r-~[', '"' 1'1" I ['1" I 18':00 19:00 20:00 21:00 22:00 23:00 24:00 192.0938 5:2 1000í - 90-: - 80-: - 70-: - 60~ - 50-: - 40-= 30-= - 20-': - 10": - 0: I I 18:00 I I , -I I I I I I I I I 19:00 20:00 Exp:GCMS_HRSIR _1.5E8 - :"1.4E8 - :"1.2E8 - :"1.1&8 ~9.1E7 - :"7.5&7 :"6.0B7 - :"4.5E7 - ::"3.0&7 - :"1.5&7 : 0 . OEO 30: 00 Time I I I" I 1'1" I I'll I I" I' 1.1 I II I I 25:00 26:00 27:00 28:00 29:00 I' 'T 1 Î"'. ( , -I I fïì I , I I I I I I 1 II I I I I I I I 21:00 22:00 23:00 24:00 25:00 ~ I I I I I I r I I I I I II I I I I 26:00 27:00 26:00 ~ 7 . BE7 - :"7.0E7 - ¿6.3E7 - :"5.5&7 - :"4.7E? - :"3.9&7 :"3.1&7 - :"2.3&7 - :"1.6&7 - :"7.8&6 : 0 OEO I I I I , I ..- . 29: 00 30: 00 Time CJ s: í n : C1 J i $:I:> ~ $:I:> It1 -' CD '0 0 ::4- N -..J VI -. '. -; r -j :} ... ,-. -. 'j .> File:MPDMI00056ï #1-1291 Acq:11-JPN·1991 1~:~1:40 GC EI+ VOltage SIR ïOSE Sample#3 Text:FIORD-2 7620ft $9705SSED017S003$ Fiie Text:GCMS 6000RP Exp:GCMS_HRSIR 178.0782 S:3 1000~ - 40~ 30~ 20~ 10':: o : --^ --^^ --"^-_^ ^ _ _, , i , 9-" r· ~,- , ..- ~ r, ¡ 'r. - ,- ï"~' , , , I ' , , ,-, I . . . . , I . . , , , I . . . , , I ' . . "I " . , , I . , , 18:00 19:00 20.00 21:00 22.00 23.00 24.00 25:00 26:00 27.00 28.00 29:00 192.0938 8:3 1000; 90~ 80-': - 90-': 80-= .J 70-': - 60-= - 50-= 'ïj $:I:> (Jq CD N 00 o H) 00 VI ..~ ; - 70-= ..~ - 60-': 50-= - tQ. 40": 30-= - 20~ 10':: - 0= 18:00 I I I I I I I I - I I I I I 19:00 20:00 · 'I ,l}..- I I I I r-J I I .- I I I 21:00 22:00 23:00 -I 1~11~'111 24:00 25:00 26:00 27:00 I I I I I II I I I I I I 28:00 29:00 _1.2E8 :"1.0E8 - :"9.3E7 - :"8.1£7 - ~7.0&7 :"5.8&7 - :"4.7E7 - :"3.5E7 :"2.3E7 - ~1.2E7 I I ' '0 . 0 B 0 30: 00 Time _6.9&7 - :'6.2E7 - :"5.5E7 - :'4.8&7 - :"4.1E7 :"3.4E7 - :"2.8&7 - ::'2.1£7 - :"1.4£7 - :"6.9E6 - O. OBO I I 30: 00 Til4e 'Q ~ (1 b $:I) Þ ,þj ,CD Iocj b P. oN :-J :v-. File:HPDMI00066~ #1-1291 Acq:11-JUN-199'l 14:10:26 GC EI+ Voltage SIR 'lOSE Sampl~#2 Text:BERSCHRUND-l 6590ft $97058RD0138007$ File Text:GCMS 6000RP 168.0939 8:2 100%: ~ $:I) (JQ CD "N .\0 o : H-¡ ; 00 ~ VI '~ '. -- J' '\0 -~ j -. . ~ <1 :I ... 90':" --;; 80-': - '70-': - 60~ ~ 50': 40': - 30-': '20-': - 10~ o : ~ I r ( I \ IL r l' I 10':00 12:00 198.0503 8:2 10a!f - 90': - 80~ - 70': - 60": - 50": - 40-=: 30-=: - 20": - 10-': - O~ I r 10:00 r I r I r' r 1 12:00 Exp:GCMS_HRSIR _s.aR? - ¿5 .2£7 '- :"4.6E7 - :"4.IE?' :"'3.5E7 :"2.9E7 - :"2.3£7 :"1.7£7 :"1.2E7 \ . - ....... 1'{-r'~."J~r ,-.-. -. . I " , , . T'-''''T I ,H, , 14:00 16:00 18:00 2,0:00 22:00 24:00 26:00' - :"5.8E6 1 1 J - 0 .OEO 30: 00 Time , 'I I , I 14:00 I'1III1'1''''11'''1'11'' 16:00 18:00 20:00 22:00 I r I ° I '" 28:00 _4.0E7 :"3.6B? - :"3.2E7 - =-2.8E7 - :"2.4E7 ..: :"2.0E7 - ::"1.6E7 - :"1.2E7 - :"8.0E6 ) 1 .::'4. OE6 1 I I I ~ ~ I '-,-=ì~., (" (~~ O. OEO 24 : 00 26 : 00 28 : 00 30 : 00 Time :Q ~. n t; $:I:> ~ ~ p) :: 10 \g ~o' , ;: =:¡ ;N -..) . VI '. F :I¡j !$:I:> .(JQ :CD VJ ~o ~o , ' H-¡ 00 VI ...... . \ '. \ .. \ '1 ,~ \... ,() '~ -' , , -! -' '1 " .Ÿ f 'í 'i -~ i , .~ ; File:MPDMI0006&7 #1-1291 Acq:l1-JUN-199ï 1~:~1:40 GC BI+ voltage SIR ïOSE Samp~e#3 Text:FIORD-2 7620ft $9705SSED017S003$ Fi1e Text:GCMS 6000RP Exp:GCHS_HRSIR 168.0939 8:3 1000~ - 90'-: 80'-: - 70":" 60~ 50": 40~ - 30~ 20-= - 10": 0: . . ...1'1.1. 10:00 12:00 198.0503 8:3 10O?é - 90~ , 80-': - 70-': - 60~ SO": 40-= - 30": 20": - 10": 0= . . 10:00 L '"v~,J~ ."" I ' I . · . I · I I I I I I , I . I I . . I 14:00 16:00 18:00 20:00 _3.8E7 ~3.4B7 - ~3.0E7 :"2.6£7 - :"2.3B7 - :"1.9B7 - "" :"1.5E7 - :"1.1£7 - :"7.5£6 I I I I I 22:00 - :"3.8B6 :.. O.OBO . . 30: 00 Time I I I I I I . I I I " . . I I I I . 24:00 26:00. 28:00 . . . I " I I I I I . I I I I I I I I 12: 00 14: 00 16: 00 t I -. It. I I . I . . . t \ . t . 18:00 20:00 22:00 . . I I ) ~l "":' 1'-' "f 24:00 26:00 _3.4B7 :"3.1£1 - :"2.8B1 :"2.4£7 - :"2.1£7 - :'1.7£7 :"1.4£7 - ':..1.0B7 - :"6.9B6 :"3.4&6 I r (~~:: O. OEO 28 : 00 30 : 00 Time Inspection Properties API: Density @ IS deg C : Wax Content %wt: Wu Melting Point deg C: Pour Point deg C : Viscocily cSt @ 20 deg C : Total Acidity mg KOHlg : AsphaltcQcs %wt (IP Mdbod) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickellV anadium : aj, ~ (); tJ; p:¡i --. P:¡: :;0: (þ: '"d " 0; ~:: N: -..): VI: I¡j, $:I:> (JQ, CD VJ >--' 0' H) 00 V\ ~ <;~, '~":, ;~ 'j ~ ) ) ¿~ " :' ., -4 ~ '-- Well DaUlt: Suite namc : Country Of Origin: Depth (m; : Samplc Damc: 111 : 111: II] : 114: liS: 116; 117: 118: 119: 1110 : 1111 : 1111 : 1113: 1114 : IllS: 1116 : HI7 : 1118 : 0.57 0.52 0.86 o 100:72:50:31 :23: 15 0.45 0.57 6.57 3.18 0.00 9.74 0.00 0.00 39.54 0.00 Sediment/Extract Analysis Bergschrund-I ßergschrund-l Extract Study Alaska ó9óû Alpine unit, Bulked Extraction, TSE ~Dwt: 0.150 HPLC Saturates %wt: Aromatics %wt : Residues %wt: Aspbaltenes (Ptficro Method) -Iowt : Biomarker Ratios SI: 0.51 Ml: 0.68 S2 : 0.50 M3: 0.68 S3 : 38:29:32 M4: 65.48 54: 32:27:40 MS: SS: 30.92 AI: 0.59 A1: 0.59 S6: AJ: 0.25 S7 : 54.19 A4: 0.13 S8 : 31.62 AS: 0.44 89: A6: 0.75 SID: MDR: 2.15 MBP: 10.71 Saturates GC PristllneIPhytane : PristanunCI7 : Phytane/nCI8 : CPI: ALKIND : R22 : Light Hydrocarbons MC" % : HER IIXR Stable Carbon Isotopes Saturates: Total Oil : -30.6 Aromaûcs : Residue: AspbaUcncs : Kerogen: STANDARD: NBS22 -29.8 o ~ ,(1 b ~ ~ þj CD "'d b ~ N N VI Wen name: Suite name: Country Of Origin: Deptb (m) : Sample name: Bergscbrund-l Bergschrund-l Extract Study Alaska 7100 Nuiqsut unit Inspection Properties API: Den5ity @ 15 deg C : Wax Content %wt: Wax Meltiog Point deg C: Pour Point deg C : Viscocity cSt @.20 deg C : Total Acidity mg KOlllg : Aspbaltents %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickeWanadium: }¡j PJ OQ CD 0.J ~ o 'H) .:00 ':v. ,J III : 112: 113 : ~ 114: liS: ~ 116: 117 : 1 ~) 118 : 119: .~ ~ 1110 : : ¡ .' f'J 1111: - . . , 1112 : ;~ 1113: ~ ," 1114: ~1 ~~ illS : ~ ·~I In6 : ",i ;J --3 1117 : .-! ?- 1118 : SedimentlExtract Analysis Extraction TSE "fewt: 0.080 HPLC Saturates %wt: Aromatics %wt : Residues %wt: Asphaltcnes (Micro Method) % wt : Biomarker Ratios SI: 0.28 M2: 0.74 S2 : 0.42 MJ: 0.57 SJ: 33:26:39 M4: 68.1S 84-: 28:30:40 MS: SS: 38.39 AI: 0.21 A2: 0.22 S6: AJ: 0.21 51: 45.40 . 0.07 A4: sa: 22.98 AS: 0.58 S9: A6: 1.43 SIO: MDR: 0.96 MBP: 9.71 0.48 0.48 0.75 20 100: 100:46:26: 11:11 0.18 0.50 3.41 2.91 0.00 7.62 0.00 0.00 39.09 0.00 Saturates GC PristaneJPbytanc : Pristane/oCl7 : PhytanelnCI8 : CPI: ALKlND : R22: Light Hydrocarbons MCH % : IIER HXR Stable Carbon Isotopes Saturates : Total Oil : Aromatics: Residuc : Aspbaltcnes : Kerogen: -23.5 STANDARD: NBS22 -29.8 ,d) ~ ø ..t) PJ ~ p:¡ '~ CD Iocj " ::4- N -..) VI Well name: Suite name: Country Of Origin: Depth (m) : Sample DaUle : 'SedimentlExtract Analysis Bergschrund-l Bergschrund-I Extract Study Alaska 7350 Nechelik unit Inspection Properties API: Density @ IS deg C : Wax Content %wt : Wax Melting Point deg C : Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOlllg : AspbaUenes %w. (IP Metbod) : Nitrogen ppm : Sulpbur %wt : Nickel ppm : Vanadium ppm: NickellVanadium : '~ $:I:> GQ CD l;J VJ o H-¡ 00 VI }\ J'\. ~\ III : IU: 113 : 114: 115: 116: 117: 118 : 119: 1110 : 1111: 1112: liB: 1114 : 1115 : 1116 : 1111 : 1118 : ~ ~ , :j Extraction TSE %wt: 0.050 HPLC Saturates %wt: Aromatics %wt: Residues %wt: Aspbaltenes (Micro Metbod) ~owt : Biomarker Ratios SI : 82 : 83 : -- S4': .- S5 : S6 : S7 : 88 : 89: SIO: M1: MJ: 1\14 : MS: AI: A2: A3: A4 : AS: A6: MDR: MBP: Saturates GC PdstanUPhytane : PristanelnC17 : PbylanelnCI8 : crl: ALKlND ': R22 : Light Hydrocarbons Mcn % : HER IIXR Stable Carbon Isotopes Saturates: Total Oil : -282 Aromalics : Residue: AspbaUeoes : Kerogen: STANDARD: NBS22 -29.8 CJ ~ n' o p:¡ .-t> p:¡ id CD' '"0: o· ::¡ N -..J VI Wdr name: Suite name: Country Of Origin: Depth (m) : Sample Dame: Fiord- J Fiord-J Extract Study Alaska 6920 Kuparuk C unit Inspection Properties API: Density @ IS deg C : Wax Content %wt: Wax Melting Point deg C: Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOllIg : Asphaltene5 %wt (IP Method): Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm: NickeUVanadium : I¡j ¡:S) f1Q CD V-) .¡::.. o ~ 00 v-. ~ ~ t' C\\, III : 112: If]: 114: liS: 116: 117 : 118: 119: 1110 : Hl!: 1111 : 1113: 1114 : 1115 : 1116 : 11I7 : 1118 : \t) '-- ..; J " '. '-" Biomarker Ratios SI: S2 : SJ: .. S4: .. S5 : S6 : S7 : 88: 89 : SIO: SedimentlExtract Analysis Extraction TSE %wt: 0.060 HPLC Saturates Vowt: Aromafics %wt : Residues %wt : Asphaltenes ( l.ficro Metbod) %wt : M2: M3: M4: 1\15: A~: A2: A3: A4: AS: A6: MDR: MBP: Saturates GC PristaneIPbytane : Prisfane/nCI7 : PbytanefnC18 : CPI: ALKlND : R2l: Light Hydrocarbons MClI % : IIER HXR Stable Carbon Isotopes Saturates: Total Oil: -2&.7 Aromatics : Residue: Aspbaltenes : Kerogen: Sf ANDARD: NßS22 -29.8 Q ~ '0 t:J $:I:> --- ~ ~ '"d o ~ W -..J ,~ , SedimentlExtr;¡ct Analysis Well Dame: Suite Dame: CouDiry Oi Origin: Depth (m) : Sample DaJIIC : Fiord-I fiord-I ExtIact Study Áiaska 7200 Nuiqsut unit Inspection Properties API: Density @ IS deg C : Wax Content %wt: Wax Mdting Point deg C : Pour Point deg C : Viscocity eSt @ 20 deg C : Total Acidity mg KOlIIg : Asphallenes 'Yawt (If Method) : Nilrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickellVanadium: ~ ~ (JQ CD W VI o H-¡ 00 Vt &\ ,~""" ~ ~'\ .' \~) pJ III : 112: 113 : 114: 115: 116: 117: 118: 119: 1110 : 1111: 1112: 1113: 1114 : HI5 : 1116 : 1117: 1118 : 0.52 052 0.73 o 100:105:49:26:18: 12 0.11 056 4.02 3.42 0.00 5.20 0.00 0.00 40.16 0.00 Extraction TSE %\\'Î: û.OïO HPLC Saturates %wt: Aromatics %wt : Residues %wt : Aspbaltenes (Micro Method) %wt : Biomarker Ratios 51 : ,0.27 M2: 0.71 82 : 0.30 M3: 0.60 53 : 31:27:41 1\-14 : 77.65 54: 30:30:38 M5: 55 : 31.44 AI; 0.38 A2: 0.38 , 56: AJ; 0.18 87: 42.76 A4: ,0.06 88 : 27.74 AS: 0.67 89 : A6 : 138 SIO: MDR: 1.66 MBP: 9.16 Saturates GC p,.istaneIPbytane : PristanclnCI7 : Phytane/nC18 : CN: ALKlND : R22 : Light Hydrocarbons MCH % : HER IIXR Stable Carbon Isotopes Saturates: Total Oil: -28.6 Aroma tics: Residue: Asphaltenes : Kerogen: 5T ANDARD: NBS22 -29.8 Cl s;:: n tJ $:I:> ~ $:I:> id CD >0 o ::¡ to -..J VI Well name: Suite name: Country Of Origin: Depth (m) : Sample na,me : Sedhnel1tlExtract An~lysis Fiord-2 Fíord-2 Extract study Alaska 7780 Kuparuk C unit Inspection Properties API: Density @ 15 deg C : Wax Content %wt : Wax Melting Point deg C: Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOllIg : Asphaltenes ~.wt (lP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm: Vanadium ppm : NickelNanadium : ~ ~ {JQ ( ) W 0'\ o !-tJ 00 VI ~ 'Ä ~ ~ " III : - 0.58 112: 0.51 113 : 0.81 114 : 0 US : 100:90:62:40:32:35 116: 035 117 : 0.52 118: 119 : 1110 : 1111: ¡1I2 : 1113: 1114 : 1115 : H(6 : HI1 : 1118 : ,; , .~ 5.88 2.16 0.00 7.34 0.00 0.00 51.84 6.19 .< Extraction TSE %wt: 0,010 HPLC Saturates %wt: Aromatics %wt : Residues "Iowt : Asphaltenes (Micro Method) %wt : Biomarker Ratios SI: 0.48 M2: 0.72 S2 : 0.41 M3: 0.59 S3 : 35:31:33 M4: 64.06 84,: '21:30:42 M5: SS: 17.14 AI: 0.60 A2: 0.63 S6: AJ: 0.13 S1 : 51.57 . 0.06 A4 : S8 : 31.12 AS: 0.45 S9 : A6: 1 . A ...... SIO: l\1DR: 2.27 MBP: 11.99 Saturates GC Pristane1Phytane : PristanelnC11 : Phytane/nC18 : CPI: ALKIND : R22 : Light Hydrocarbons MCU % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -29.3 Aromatics: Residue: Aspbaltenes : Kerogen: STANDARD: NDS22 -29,8 ~, (j t:2 P'~ ~ P:¡' Id (þ' þoO' o· ~ N -..) Vi I¡j P' CJQ CD W -..) o HJ 00 VI Well name: Suite name: Country Of Origin: Depth (m) : Sample name: SedimentlExtract Analysis Fiord-2 Fiord-l Extract study Alaska 793ô Alpine unit Inspection Properties API: Density @ IS deg C: Wax Content %wt : Wax Melting Point deg C: Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOll/g : AsphaUeoe5 %wt (IF Method): Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm: NickellVanadium : Extraction, T5E %wt: 0.060 HPLC Saturates %wt: Aromatics °/ewt : Residues %wt : Aspbaltenes (Micro Method) %wt: Biomarker Ratios HI: 0.55 SI: 034 M2: 0.67 112: 0-42 S2 : 0-40 MJ: 0.54 ~\ 113: 0.19 53 : 31:30:38 M4: 6132 114: 17 MS: liS: 100: I 01:52:32:21 :15 84,: 26:32:40 ~ 116: 0.28 SS: 32.95 AI: 0.24 ~ 117: 0.58 A2: 0.24 86 : 118: A3: 0.30 ~ 119 : 81: 45.45 . 0.10 A4: ('J 1110 : S8: 30.42 AS: 0.50 nil: 10.74 S9 : A6: 1.54 1112: 5.33 SIO: IIIJ: 16.96 MOR: 2.36 11I4 : 7.01 MBP: 12.18 illS: 0.00 - 11I6 : 0.00 .. ~ 1111 : 42.50 ~ 1118 : 0.00 '.~ ,. -~ Saturates GC PristaneIPbytane : P.istaneloCl7 : Pbytaoe/nCI8 : CPI: ALKlNO : R22: Light Hydrocarbons Mcn % : IIER IIXR Stable Carbon Isotopes Saturates : Total Oil : -28.6 Aromatics : Residue: AspbaUenes : Kerogen: STANDARD: NBS22 -29.8 Q g:: (") b $:I:> ~ p:¡ id CD '"d o Þ- N :....} ~ SedimentlExtract Analysi~ Well name: Suite name: Country Of Origin: Depth (m) : Sample name: Fiord-l Fiord-l Extract study Alaska 8100 Nuiqsut unit Io'Ij $:I:> {JQ CD u.> 00 o ,~ 00 :VI Inspection Properties API: Density@ IS deg C: \Vn Content %wt: Wax Melling Point drg C : Pour Point dcg C : Viscocity cSt @ 20 deg C : TolBI Acidity 109 KOWg : AspbaUenes %wt (IP Metbod) : Nitrogen ppm : Sulphur 'Yewt : Nickel ppm : Vanadium ppm : NickclNanadium: Extraction TSE %wt: 0.060 HPLC Saturates %wt: Aromatics %wt: Residues %wt: AsphaUenes (Micro I\fethod) %wt: Biomarker Ratios III : 0.52 81 : 0.40 M1: 0.68 112: 0.44 S1 : 0.47 M]: 0.54 113 : 0.83 S3 : 33:30:35 1\-14: 60.66 114: 10 MS: liS: 100:88:52:28:19:14 84': 26:33:39 ~\ 031 55 : 27.59 AI: 029 116.: 87: 0.53 A2 : 031 t 56 : 118: A3: 031 119: 87 : 49.02, A4: 0.14 ~ 1110 : S8 : 34.91 AS: 0.47 1111 : 8.53 S9 : A6: 1.12 ~ 1112 : 3.65 SIO: MDR: 2.54 1113: 15.33 i W 1114: 7.07 MBP: 9.93 HIS: 0.00 Hl6 : 0.00 1111: 41.59 .~ 1118 : 0,00 ,~ ~ Saturates GC Pristaneœhytane : PristanelnCJ7 : Phytane/nC18 : CPI: ALKIND : Rl1: Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil: -28.7 Aromatics: Residue : AsphaUenes : Kerogen : STANDARD: NBS22 -29.8 a _ ~oo- 97050lL014S001 n t1 p:¡ ~50~ CD "d o ::¡ - ~OO-- -..) VI Bergschrund-1. 6840-6960ft (sands, Alpine unit) Total Solube Extract GC 450- - 400- I¡j PJ {JQ - ~50- w \D o H-¡ ~O--= 250- ~= Cf' 200--~ :~ ¡ '- 150- 100- - 0-' -nITI'111111111 (1111 J IIIIIII1IIIII1I t II IIIII ~ 1II1III1I11 rill rTfTTTITTffil!II'I'IIIIIIIIIIITlflTTTfI rr rrnTf1l1T rrrrrnTTJTITITfnT.JlTIT fTT1TfmrrrnTJ rrrqTTTTflHqT Dl rnfTTTrqTTíqnrrpnT 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 . If ,11 ~ ~ h iii .I,l. ,l~JÅ.µ'~L., . 1, ' ,tJ1J\1 ~ m~ Al4' ,v l~' rJV~ ~ 'M'f YrJ rw \lI.!J.LF,-o", 'I I ' J W . ~ ¡j ~llr, "',~\......J'. ~ ~. ""'~ """"",,)_ I "",-. II \ ~ J~ ~~ ' , ~"-~'------_A__~__A------^- ~L.--~iAc--"".JJJ ~ 50-- -10 -= Î ¡IIJt IIIIIII l111 1111 l11111111 l111(11" I1III (l111 11'1 I" II III 'III' 'I"" III" I"" I'" 'I" 'lllTIpTnFlllTrnTplrrpnrpTJTI. TffirmrrrnrTTrpn'lnnp JHTTnTrrTrJffTTllTJTJTlTnrnlT 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 36 40 42 .d.ð. - o~ I ~ ¡ tìl .., ,I,: I I ,I I I J ,I I ~ 1'1'~. W lJJll»!LtJ~W'"LLJLJ.,llW~~,- IL~ ' ¡ , , ~' ' 10-; - 20--= ~ !-.) -- ,~;... 30~ ,>, - ~ \r" 40~ . . - .... ;\j," ~ ~ " 50~ - 60~ ~ 70~ - Total Soluble Extract GC ï60~ (JQ =- CD ,:.: ~O~ o = I-f-) -= fio~ - Bergschrund-1, 7050-7100ft (sands Nuiqsut unit) 110~ - 120,~ - a _ ~=: rno~ tJ == 97050lL014S002 ~ --= .-.- = Sf50-=- ~ = CD -=- 'ì:j =: !{1°1 N-=- -..J ::- WO-= ~·IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII n 11I111I1IIIII1111111111111111111111 qTmTnlTfll1TfTllTlTITITrn I}!TfT}TITTfnnrrllTTTfnl rrnpTITrrrn TllT lTIlTI flTrrrl flIIIT}1 II !I' rnJTTTfrlTTTl rnrplr 6 8 10 12 14 16 16 20 22 24 26 28 30 32 34 36 38 40 42 44 , I ,. '~ 'b . ~ ..I I) I µ~WII.~JI ~,¡ l '~I.II~ N ~,'t\i.rI~i.¡W'~"!f<,.w..~,j.".,.ft ~ .___^---~~_~____ -, 20~ J ~ VI __ ,Ii 0-= ~-j, . " ~J 11 ,t ) ~ 40-= ;J1 -'," y - -' 60-= 80-= 100-= o H-¡ Ei20--= T atal Soluble Extract GC 160--=. "ï:1 p:¡ CTQ ~40-= ~ - ...-. - Fiord-1. 7100-7200ft (sands, Nuiqsut unit) 180-=: 97050lL016S002 a ~40~ t:1 $:I:> r-t- $:I:> ~20-= CD - "'d o ::¡ ~OO~ VI - ¡J}Nþ, .J;"I.r.u\.. l I . .}"'V v~~~.}¡ ¿d' \-J' II .~ II W . JA¡. µ.)..,¡..II-¡I!JI 10--= . J .. ~ J,,¡ # ,~h~.Alll\\ . . = I )Ü·. I ({,II. - LJJ" 5-~ . ~5~ . g = 97050lL018S001 $:I:> - 6fio- id - ( ) - "'d o ~5~ -..J - VI - 40- 35- ~ - ~ - {JQ - CD ~--= o - H-¡- 00- VI 25- ~~20~ \f\ '- "'" 15- "- '. -~ , - í ~~ -1 0- J '~~ Fiord-2, 7760-7780ft (sand. Kaparuk 'C' unit) Total Soluble Extract GC 1: -ITTTTIII I IIII I 111111111111 I 1111 I IIIII IIIII III I 11111111111111' I' 1111111111111111111111'llllllllllllllm~rITTTmpTnfTTITrr 111 11111ITTTfTTn TTTTJITTTITfTTTI11'IIIIII1TfT'TI llllfllllllll'frlrr 6 8 10 12 14 16 16 20 22 24 26 28 30, 32 34 36 38 4042 44 Q - ~ =' n 80--= t:' p:¡ S-- 75~ :;;0 ~ CD - -g 70~ ::¡ - N ~65~ , ~ 50~ p:¡ - (JQ (i) .þ. - t;.) 45--=: o H-¡ ~ 40-=: ... 25--= ': \.'f'\ - - ,} \; 20-= '" =: ~ 15--= f -"1 :. :' ~ O-=- J ~! 97050ll018S002 60-=: Fiord-2. 7910-7930ft (sand, Alpine unit) 55--= Total Soluble Extract GC 35--= , 30-= , A _ fv/okv ~ · J I Ii' .. ,*,J.¥~.~/vMI ,).).,¡i~v ~""-- . . ~'l'W~ìlri,¡\J.,.J\Wl ~LJ~~______, . JJ,¿J\~. J 5--= ~~J~vvJ 10--= :, " " -5-=-1TTTfT I J I l111( II 11\ II1I P III1I1I 1111111111 III I \III J II [ I l1111111 II III 'I J 1111111111111 \III '1"11 II IfTTTfTp "11"111' I rrrrrfTI1Il11"IIITHT¡TITTfTTTTfTTTlTfTTTlTfTflTTfTTTH rpTITfTlI1 I I I Ir 6 8 10 12 14 16 16 20 22 24 26 28 ' 30 3~ ' 34 36 38 40 42 44 ..... .; :' °cYJO-= ~ 97050lL018S003 n e-=: o ~ - S-80~ ~ CD "'d o ::4- !:!J30-= VI 140-= d2o-=:' {JQ - CD _ .þ. - .þ. - o M>O--=: Ut - Fiord-2, B080-B100ft (sand, Nuiqsut unit) Total Soluble Extract GC 80-= .60--= . j -í ~.~ -~ ~~ .~.. : .~--&: . ~. 40-= -; ~ 20~ ~.I t~f¡ ~;q~'\l ,~l-~.IM f~~\~~~~¡qi\;~µ'AN~tl~,l~~ ~ 'A~I, ---~- =~~~ 0-= ~i :}I '~ ìTlljllll 11111111111111111111111111111111111111111111111111111111111111111111111111111111 111I1 J J 11111111111111111 t Ilq 111.11 11111'1 J 111 " I III J I " I I" " I " I'I'I " I rJTTfll1I II " I II( I III rptTIJTITT 6 8 10 12. 14 16 18 20 22 24 26 28 30 32 34 36 ,38 40 42 44 :"3.3E6 :"2.2E6 :"1.1E6 . -: O. OEO Time I 1 I 1:10:00 . . I 1 I 1:00:00 ~,. \ ~ ~~"..~-,.~...~.~~,,~ .~~~, ~ 20-= 1:j~~1~~ip. I I I 30: 00 . I 40 I I I I : 00 I I I 50:00 :"5.4E6 :"4.326 :"7.6E6 :"6.5E6 :"8.ïE6 _1.1E7 :"9.8E6 :"3.ïE7 :"2.5E7 :"1.2E7 ::- O. OEO Time }'l 11 ~ q\ ~ -\1- '}1 'l~ ' \, ~> 10 1-.Ä t;( . . - A~ £. - U ,,- I I I I I 40:00 5:2 F:2 ' I\~ 'Í~ k V tK I " . , I-itA i I ç L \- ~~ JL.~~ Alv~~U~ __.- I 'I 'I I I ' · 1 I . · I I' 1 I 50:00 1:00:00 1:10:0~ :"7.5E7 :"6.2E7 :"5.0E7 :"9.9E7 :"8.7E7 _1.2E8 :"'1.1E8 Exp:GCMS_HRSIR Voltage SIR 10SE Text:GCMS 6000RP i LM .A \} o ,J ~ 0-= ,.J- 30:00 217.1956 10 O?J¡ 90-= 80-= 70-= 60-= 50-= 40-= 30-= 80-= 70": 6 0": 50-= 40-= 30-= 2 0": 10": IFi~e:MPDMI000666 #1-3081 Acq:10-JQN-1991 09:24:21 GC EI+ Samplei2Text:BERGSCHRUND-1 6960ft $97050IL014S001$ File 191.1799 8:2 F:2 10005 90": {f , j :. -, '" ,~ '1 J ~i ~ --.. ~ ~ ,~ þoU p:¡ {JQ (D .þ.. ·:.VI '0 I+t) 00 Y' a ~ (:J t:1 SlJ -- PJ 10 (t) ~ Q ::4- N -...) V. cb ~ (1 t:1 w ·ar ;.0 CD "C <P :;;¡ ~ "":"':¡ "0 ~ p:¡ {JQ rt> ''¡:::'' 0\ o ~ 00 V\ ..\f File:MPDMI000666 #1-30B'l Acq:l0-JUN-199'l 09:24:21 GC EI+ voltage SIR 'lOSE Sample#2 Text:BERGSCHROND-l 6960ft $97050IL014S001$ File Text:GCMS 6000RP Exp:GCHS_HRSIR 177.1643 S:2 F:2 10~ _2.2E7 80~ ~1.BE7 60~ ~1.3E7 - 40~ ~8.9E6 20~ . "'-', .'~""'-"."'."""''''''J'~''''''''~_'''. . .'" .L .. 0-=-(' . I · 30:00 40:00 191.1799 8:2 F:2 1000¡ i:oo:oò , 1 ' 1:10:0Ò , I ' 50;00 80~ 60~ 40~ 20~ _.~Þ~J.L~I~ . , I I '1' I 1 I 50:00 1:00:00 1:10:00 '- ~ IV 0- ,Å .. - _ J I 30:00 "40~00" 205.1956 8:2 F:2 10~ 80~ 11.--1 .. I I 60~ 40...:: 20--= ~i .._. .',. . ~ ... .".. . .. ..._".... .._ . 1..1..... ..JJ....~_..... ~.. ._.. ,. '40~00 I "50~00 I i:oo:oo i:10:00 0=,"'..··,· 30:00 - ~4.5E6 - '- -, -- .~ --'-:-,0. OEO i:2Ó:OO Time _1.2E8 ::..9.9E7 - ~7.5E7 ~5.0E7 ~2 . 5E7 I 1 I 1:20:00 - O. OEO Time ,-1.5E7 ::..1.2E7 - ~8.9E6 ::..5.9E6 ::..3.0E6 I 1 I 1:20:00 -O.OEO Time d ~. n d $:I:> .-+- P:¡' ~ CD· 'ï::S: O· ;f, tv -..) VI '. ~ p.J (JQ: CD-. ~ ~ 0' ~ 00 ~ .~ ~ . ' ~~ ] .i ~ ~ File:MPDMI000666 #1-3081 Acq:l0-JUN-1997 09:24:27 GC EI+ Voltage SIR ~OSE Sample#2 Text:BERGSCHRUND-1 6960ft $97050IL014S001$ File Text:GCMS 6000RP 218.2033 8:2 F:2 100% - 80-=: 60-=: 40-.:: - 20-=: III o - r--&Þ "",,,. . . 30:00 217.1956 8:2 1000; . .. ~/MIhJ¡ ~~~,"_...IO-_~ I I' . I r I I I I I' I I I 35:00 40:00 45:00 50:00 55:00 F:2 80-=: ~ 60-.:: 40-=: ~ \Ñ 20-=: : __ & ..f... ...J..,~ o - ,--... _n_ 30:00' · · 35~Oo' 231.2111 8:2 F:2 1 0 O'!t¡ 80...: JJ8~) V\J~ \)¡. -h~t:~::: - 0 .OEO Time 60-=: 40-=: 2:i~~L . . I ,. I . I . 30:00 35:00 . I 1 40:00 1 I 1 45:00 I I 1 50:00 40 ~ 00' r I I 45:00 . I · 50:00 '55·~ 00' Exp:GCMS_HRSIR _8.4E6 - :..6.7E6 - :"S.OE6 :..3.3E6 I.f :..1.7E6 ~I't\JJ~ O.OEO 1 1 1 1 1 . I I 1:00:00 Time _1.1E7 , =-8. 7E6 - :..6.SE6 1 11:00:010 I _4.9E6 =-3.9E6 ... J V V !hi I vi t \ ""V ~ ~ L II ~2. OE6 'J''trW~9 _ DES I I 1 55:00 =-2.9E6 I I I 1 I 1:00:00 - 0 . OEO Time Q --~ o 'to '_: ß) -- ~ \_~ '--~ o ,;¡ tv -;...J Y1 ;-0 -~ OQ [D ::.þ. :00 -0 .~ 00 ;VI \.fr' \£- ........ , ~ .i I ; ~ " " ,'¡ --' -~ 1 -~ File:MPDMI00066ô #1-3081 Acq:l0-JUN-1991 11:0~:31 GC EI+ Voltage SIR 70SB Sample#3 Text:BERGSCHRUND-l 7100ft $97050IL0148002$ File Text:GCMS 6000RP 191.1799 8:3 F:2 10O?é 90": 80~ 70": - 60": - 50": 40-= 30-= - 20~ - 10~ - o : r^- _ 1 - . ..- . I 30:00 217.1956 8:3 F:2 100% - 90-= - 80~ - 70-= 60~ - 50": 40-= - 3 0": - 20": - 10~ al.l oi~~ I I I 30:00 ,,< a 1 I I I 40:00 1>- ---.J: tJ" '- O<þ ~~ -t1' L ~~ I ~.\- ~~J..\.J~~.Å,,-w~ ~ I I I I 1 I I 1 I 50:00 1:00:00 1:10:~O .... ,. I ,0 \\ I ~ !J> \. I I I 40:00 I I I 50:00 Exp : GCMS_BRSIR is _6.8E7 :"6.2£7 :"5.5E7 ~4.8E7 - :"4.1E7 ~ 'Y l> - ::'3.4B7 ~2.7E7 1'" \C r- ~2.1E7 ~1.4E7 :"6.8E6 : 0 . OEO Time p ~"t- _8.9E6 ~8.0E6 =-7.1£6 -¡.S - 1-'''' ....., ~~ - =-6.2£6 ).... - ~5.4£6 :"4.5E6 ¡f '4-\ I _ ~~ ~ ¡ , HI, ~ 4 - :"3.6E6 ::'2.7£6 :"1.8E6 - :"8.9£5 I] V~"''''.lv.a.. ....___"', .'-,^__, ',.'~ - - O. OEO Time I 1 I 1:00:00 I 1 I 1:10:00 d ~' n d $:1:>, ...... $:1:>- ?ð CD '"d- e' ::¡; ~ -.3 Vi :. I Þ-ò $:I:>: (JQ CD: ~ \Ó o ~ 00 u:- -? ~ 1 {~ . ~ ~.~ ,; .; Fi1e:MPDMI000666 #1-3081 Acq:10-JUN-199~ 11:0~:3~ GC EI+ Vo~tage SIR ~OSE Sample#3 Text:BERGSCHRUND-1 7100ft $97050IL014S002$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 177.1643 8:3 F:2 10~ _1.3E7 80~ ~1.0E7 40~ 60~ ~7.7E6 20~ o = r -- · . , ," 30:00 191.1799 8:3 10~ 80~ 60...:: 40..:: ," -~-_v"'_~~" _____~~JJ.....~~J'__w___,,, ,,___ __ u. _ _ _ _ . -"-"'" ,,- .. .. IT' I I "1' '1' '1 ' . 40:00 50:00 1:00:00 1:10:00 1:20:00 F:2 20...:: 0-........ -' .1 30:00 '40~00' 205.1956 B:3 F:2 100?£ __ _ .....--Lw\.........Þ .J.,J........ ~_ I I I I I I 1 I I I " 1 . 50:00 1:00:00 1:10:00 i:2ð: 00 --.J. -, ~ I I 80-= . ~ 60...:: 40...:: 20...:: o - ,..... 30:00 .~AL J\..u..N.~1' . _ I 1 I 1:00:00 , 1 I 1:20:00 -, ,,-- -~- I I ' 40:00 I I I 50:00 I 1 . 1:10:00 ~5.1E6 =-.2.6E6 " .- 0 .OEO Time _6.8E7 ~5.5E7 ~4.1E7 ~2.7E7 ~1.4E7 - 0 .OEO Time _1.3E7 ~1.1E7 __7.9E6 ~5.3B6 ~2.6B6 - 0 .OBO Time Q ~' o d ~ M- s::o ~ ~ ,~ Ñ ....:.J Q-. ~ $:I:> JIQ .(D VI b o ~ po V\ ~ ~ ~ " ~ j File:MPDMI000666 #1-3081 Acq:10-JUN-1991 11:0~:31 GC EI+ Voltage SIR 10SE Sample#3 Text:BERGSCHRUND-1 7100ft $97050IL014S002$ File Text:GCMS 6000RP Exp:GCMS_HR8IR 218.2033 S:3 F:2 10~ _3.9£6 - 80~ ~3.1E6 - 60~ ~2.4E6 40~ 20~ o -, . - ..., ........JL 30:00 35~OO 217.1956 8:3 F:2 1000: , I 1 40:00 1 I . 45:00 - 80~ - 60~ 40~ - 20~ - o -_f -..- ,"" , I ' 30:00 35:00 231.2111 8:3 F:2 100% , I · 40:00 , I ' 45:00 80~ - 60~ 40..=- 20~ d . _ I . . .~....... o - ~~\,O.J\rJI . 1 , .1 I ' , , , I . I 30:00 35:00 40:00 I I I 0 I 45:00 ~1.6E6 \Iv» ~ { V r ~ ',. W V\.J ~ 7 . 9E5 ~O.OEO J I' J' 111 -.- I I 55:00 1:00:00 Time 50 ~ 00' _8.9E6 - =-7.1E6 - =-.5.4£6 =-3.6£6 vJ.... ' t I ~ ~ "". -h. II . ~1. 8E6 \.Iv",,\/, 'v\....;o~ o. OEO I I I · I I I I , 1 .- I I I 50:00 55:00 1:00:00 Time _4.2E6 - =-.3.3£6 I 1=-2. 5E6 . . . I " _ .¡ V\'¡!,oI ¡føJ~ II I ~1. 7E6 V , -"~~~8.4E5 - 0 . OBO Time I I I 50:00 . I 55:00 '1':00:0'0 I ~' o tJ p:¡' rot' ~ ~ (t); "t:1 o ::f 1'4 --.:J Lit ~ cffl CD ~ t-'-' o '"':t') cio U\ ~ ~ . ~ ¡ '. --1 .; -; " .., :t i ) ,~ " J ]~ 1 File:MPDMIOOOõ66 #1-308~ Acq:l0-JUN-199ï 12:46:41 GC EI+ V91tage SIR Samp¡e#4 Text:FIORD-1 7200ft $97050IL016S002$ Fi1e Text:GCMS 6000RP 191.1799 S:4 F:2 lOOO¡ 90-= - BO~ - 70~ 60-= 50~ -< 40~ 30": 20": 10~ ~~ 1 '. ~ . . I...J. I , I I ' 40:00 ';'1 - 0=.-' 30:00 217.1956 10~ 90~ eo~ 8:4' F:2 - 70~ 60-': 50": 40-': 30-': 20": 10-': o ~ ~JlL. I I I 30:00 '/0 BE Exp:GCMS_HRSIR C$ 'Þ rl o 'Í.... t<. .. " fl- v o<.~ ' ~ ~$ 1"1 I '( t I¿, \- & .. L _ . ~~ J..~Jv;M..- )t.~.L..A.All~ _ ,- -, 50~00 I 1:00:00 1:10:00 A -t1- '1-~ '1,Ç\ ~\o 10 \l t..1 -;3 1"\ ~.. II J~~~I~d ¡J".... \ · "'" \. h._ - ~'-""""-_--JI I 1 I 'I I 1:00:00 1:10:00 I 40 ~ 00 ' I 50~OO I _l.SEa :"l.4Ea - :"1.2E8 - :"1.IE8 - :"9.2E7 - :"7.7E7 :"6.1E7 - :"4.6E7 :"3.1E7 :"1.5E7 : O. OEO Time _1.8E7 - :"1.6E7 - :"1.4E7 - :"1.3E7 - :"1.lE7 - :"9.0E6 - :"7.2E6 - -=-5.4E6 - :"3.6E6 - :"1.8B6 - ;:. 0 . OEO Time .~. (j t:! ~ ~ ~ en; ~ 'd ~ ~ o - 'j t-d ~ CD v-. W Ó ~ do \..!1 File:MPDMI000666 #1-3081 Acq:l0-JUN-199'l 12:46:4'l GC EI+ Voltage SIR 108B Sample#4 Text:FIORD-1 7200ft $970S0IL0168002$ File Text:GCMS 6000RP Bxp:GCMS_HRSIR 177.1643 8:4 F:2 1 0 001! 80...: 60.: -~ 40: 20: O~ / ~ - . ¿" .. 30:00 '40~00' 191.1799 8:4 F:2 1000¡ j~"'V~~ .. '50~OO' i:oo:oo i:10:00 i:26:oo - _~-A . ,-. 80...: 60...: ~ 40..: 20...: V\ O-=-~ ~I-" r 1 J. . ' 30:00 40~OO ~ 20S~1956 8:4 F:2 1000f 80..:: - 60...: · 1 · 1:20:00 . ~~l~_l~ f'T · · · · 1 · · .- · 1 · 50:00 . 1:00:00 1:10:00 Ai "" - '. -iÔ...: j ; 20..: ~~t'J·~_.. · l' I I I 1:00:00 1:10:00 I I · 1:20:00 j , ¿ .IJ . , I 50:00 0...:. 30:00 I I I 40:00 ª ) .- ~3_7E7 =-2 _ 9£7 =-2 _ 2E7 =-1_ 5&7 - =- 7 _ 3E6 ~ 0 _ OEO Time _1.5E8 =-1.2E8 =-9.2&7 :.6.1&7 :..3.1E7 - 0 . OEO Time _3.3&7 :..2.7E7 =-2.0&7 =-1.3&7 :..6.6E6 - 0 . OBO Time .. Q ~ n tJ ;¡); S '~ ':C:f ~ N -.¡] U1 ~ Jþ ('!) ,&. ~ o If"t) 00 VI )) ,~ , ,\j) ":\ ~ . . -, , ; " " ':1 j .~: ~~ '1 ~ " .~ , " File:MPDMI000666 #1-308~ Acq:1Ò-JUN-199~ 12:46:4~ GC EI+ Voltage SIR ~OSB Samplei4 Text:FIORD-l 7200ft $97050iL016S002$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 218.2033 S:4 F:2 . lOO?i _8.0E6 80..:: =-6.4B6 60..:: =...4.8B6 40..:: :..3.2R6 - 20..:: O-~-- .~~,- 30:00 35~OO 40~00 211.1956 S:4 F:2 10003 ~ ~. I, 'J Ii 'J =-1.6E6 V·~ ~~~~IU : --oW!- J',~ ' ~O.OEO 45~OO r "'50'~OO' I '55~OÓ .1 1':00:0'0' " Time 80..:: ,-1.8&7 :..1.4&7 - 60..:: -- :..1.1&7 40..:: :..7.2&6 20...:: .. wl J¡ 11i"JV\Jr\V"fu~ ---.........,..,,~ - -'-'''' 4ofoo" '4S~OÓ' 1'-'s0~00'55'~OO' · -, l'~OO:OO ' - =-3.6E6 "'--- 0 .ORO Time ~ o - r ; , I' I' 1 ' r - I"' 1 30:00 35:00 231.2111 8:4 F:2 10003 _7.4&6 80..:: - =...5.9E6 '- - 60..:: - :..4.4E6 40..:: l ~ N~.NMil ~~::::: - O. OEO Time - - 20 - I. i . . . " O~~~~·~~~ '" J I I " r 1"" I I 30:00 35:00 40:00 45:00 I I ' 50:00 I I 1 55:00 I , 1 I I 1:00:00 : 0 . OEO Time :"8.1E6 :"5.4E6 =-2.7B6 :"1.9E7 :"1.6E7 =-1.4E7 :"1.1E7 :"2.2E7 _2.7B7 :"2.4E7 - 0 . OBO Time :"6.8B7 :"4.6E7 :"2.3E7 :"9.1E7 =-1.1E8 =-l.6B8 :"l.4E8 :"l.8E8 =-2.1E8 _2.3E8 ~ I I I 1:10:00 I I I 1:00:00 I I I 50:00 I I J 40:00 ~~~ I ¡II ~jJ II to 11 """'\ JIf" o.4D .,\ v~~ ~~ ~ 'i d" ~ r}( «- "'iI" - - ~ \- ", . ,-(A L ~ juJ) ó.L ~""'" ~ l~,,""'" I I I I I · I I I I I 1 I 50:00 1:00:00 1:10:00 - LJ -- , I ' 40:00 ~ 1l.........uL.U - . . oSÞ " ,.t l' 10-': olr--- ~ I . I 30:00 40-': 30-': 20-': 60-': 50-': O=µ.- 1, - . . . , I 30:00 217.1956 8:2 F:2 1 0 O?l; 90-': 80": 70~ ~ 10-': 80-': 70": 60": 50-': 40": 30-': 20": File:M~DMI00066~ #1-3086 Acq: 9-JUN-199-1 14:34:4-' GC E:t+ Voltage SIR -'OSB Samp~e#2 Text:FIORD-2 7780ft $97050IL018S001$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 191.1799 S:2 F:2 1000: 90": u ~ .! --! " - ,... '-.....;, ' \ ¡ \.{} , '''- ~ '1 !-o ~ {JQ CD V. j:>. o ~ 00 VI - ,I ò ~ :<p ~ S- ~ ß> 1 N .;.:¡ va , . c, ~ () d p:¡, ...-t-i p:¡- ~ CD: '"di 0: ~. tv -..) Vi - :~ ~ ~ ~ Ut Ctt Ö t-t> 00 VI .~ - ! --' ~ :i ~ j , .~ -., J ..: .~ -~ ~ File:MPDMI00066~ #1-3086 Acq: 9-JUN-199~ 14:34:47 GC EI+ Voltage SIR 'lOSE Samp~e#2 Text:FIORD-2 7780ft $97050IL018S001$ File Text:GCMS 6000RP Exp:GCM8_HRSIR 117.1643 B:2 F:2 100?£ 80..: 60..: 40..: 20...: o - , - ~ ---;-- f ~p-" --- 30:00 '40~00' 191.1799 8:2 P:2 10 OC!£ 80..: -.... q....... 60..: 40...: 20..: 0--" i . f~ rv 30:00 40:00 205.1956 S:2 F:2 100?£ N - 80..: 60..: 40..: 20..: O-=-r~ 30:00 . '" - - I I I 40:00 ,,_ .~J,~~~"",v_ · "50~00' · -, 1:00:00 1 I i:16:00 ,. ...& A-. 1 ~ _ _~~L~L~, ~-, 50 ~ 001' '- 1 ' _.~ i: Ò 0 . 0 Ò T 1 i : 1 b : 00 I' ~'L.~. · I I · I · 1 I I I '11 50:00 1:00:00 1:10:00 -y · 1 I 1:20:00 ..... I 1 I 1:20:00 V I I I 1:20:00 _5.7E7 ::.4.6E7 ::.3.4E7 ::.2.3E7 ::.1.1E7 -- 0 . OEO Time _2.3B8 ::.1.8£8 ~ =-1.4B8 ::..9.187 =--4.6£7 - , ~O.OBO 1 - . Time _3.5B7 ::..2.8B7 :..2.1E7 :..1.4E7 :..7.0£6 - 0 . OEO Time 40-= 20-= - 0- t I 30:00 35 ~ 00' ,; 231.2111 8:2 F:2 - \:" 0\ 10001 "- é\o - 80-= <¡-- 60-= \¡-1 - f 40-= ~ 1 ~ 20-= 0- I I I I ~ 30:00 35:00 " o ~ n t::I PJ ..,-1- $:I:> ~ CD "'d o ::+ N ""-J VI r-c PJ ~ VI ,0\ o H-¡ -00 ,~ File:MPDMI00066~ #1-3086 Acq:9-JUN-199'l 14:34:41 GC EI+ Voltage SIR 108& Sample#2 Text:FIORD-2 7780ft $97050IL0188001$ File Text:GCM8 6000RP Exp:GCM8_HRSIR 218.2033 B:2 F:2 10005 _2 .2&7 80-= =-1.8&7 60-= =-1.3&7 40-= =-8.9B6 20-= 0-_ . ~-__----">- 30:00 '35~00' I I 40~OO' I 217.1956 8:2 P:2 100% ,- ' JU_ 45~Oo' ~ ~ "I'll). ~ lJ ~4.5E6 V \IN' . ^J- ~_ .. - 0 .OBO .. I" I. I'" 11' I.. 50:00 55:00 1:00:00 Time _2.7&7 - 80-= =-2 . 2&7 - 60-= =-1.6E7 - I \ :..1.1B7 ~l""ivfM dì.wVl~5.4B6 . -O.OBO I I r · I' · 11" 50:00 55:00 1:00:00 Time I I . 40:00 45~Oo' _1.387 =-1.1&7 - . _ ~ V# ~ ~~ J~_:~;:: __~_~I - :2.7B6 · I · · I I I · I I I I I I I . I I I I 1 I I - O. OEO 40:00 45:00 50:00 55:00 1:00:00 Time 0, ~ () t1 $:1:>- ...-t> $:1:>' ~ CD '0 o· ~ N --.) VI ~ PJ: (JQ' CD VI -..) 0, H-¡ 00 VI ------' , ,~ " Q ~.-- . ''-V , .' ':) '-- , , ~ .' File:MPDMX00066~ #1-3086 Acq: 9-JÐN-199? 16:1~:~6 GC EI+ Voltage SIR 'lOSE SampleD3 Text:FIORD-2 7930ft $97050XL018S002$ File Text:GCMS 6000RP Exp:GCMS_HR8XR 191.1799 8:3 F:2 10œ-, 90": - 80"': 70"': - 60": 50-= - 40-= - 30-=: 20": - 10--= o :: rA------l-~.. l-.- A I . 30:00 217.1956 8:3 F:2 10 O?t: 90": · 40~OO I · 50 ~ 00 · - 80-=: - 70": 60-= 50"': 40-= 30'-: ~:] flL.L~~)~ O"':~ '0 It 30:00 . I ' 40:00 , I · 50:00 tJ~ (s '9 o " ¡f,.. ~1 t( b1 " .. , )lJ" 'l~ 'i ~, vol-Uo J..J' i ...... ¡ · .. ..J.,,,~ 1':00:00' · . 1:10:00' ~ ",s ~ ,1. 1.1 tp .., ¡" !~ I~ 'I \ ~ W J V ~......._,."..-,~~ , 1 · 1:00:00 1:10:00' _1.0E8 :"'9.4E7 - :"8.4E7 - :"7.3E7 :"6.3E7 - .:"5.2B7 - :"4.2E7 - :"'3.1B7 :"'2.1E7 :"1.0E7 - .: 0 . OEO Time _2.1E7 - , :"1. 9E7 - :"'1.7E7 - :"1.5E7 :"1.3E7 - :"1.0E7 - :"8.4E6 - :"6.3E6 :...~.2E6 - :"2.1E6 - .,: 0 . OBO Time "'ð;J ~ o t:ï ~ ~ ~ CD '"d o :¡ N -..) VI I¡j $:I:> (JQ CD v-. 00 o H) , 00 1JI " ~ ~ ·1 ,,} 1 h 1 :i ~ ~ i ì ~ ~ ~ File:MPDMI00066~ #1-3086 Acq: 9-JUN-1991 16:1~:~6 GC BI+ Voltage SIR ~OSE Samp~e#3 Text:FIORD-2 7930ft $97050IL0188002$ File Text:GCM8 6000RP Exp:GCMS_HRSIR 177.1643 8:3 F:2 10~ 80..:: 60..:: 40..:: 20..:: 0..:: 30:00 r40~00' 191.1799 8:3 F:2 10~ 80-: , I I 50:00 ~ 60..:: 40..:: ~.-._~ - 20..: o : rA - . ~-, U_& r ,- r I r 30:00 40:00 205.1956 8:3 F:,2 100% 1L-.J¥ - ~liJ~~_lL.~_". . r 50~OÒ I i:oo:oò' '-I i:-10:OÒ 'I í:20:00 -~ :\--.... U\ 80..:: 60..: 40..:: 20.: ~ ~~~.. 11 . I ' ~ >J, ...._~... ._ p....__ 'þ'_ _ _ ...... .. &a. _...... ..... i:oo:oô i:l0:00 i:2b:oò 0...::.( 30:00 ~~""~~ I I I r 1 I I 1 I 50:00 1:00:00 1:10:00 I I I 40:00 i:20:00 _2.6£7 :..2.1£7 :..1.5£7 :..1.0£7 :..5.1£6 r O. OEO Time _1.0B8 :..8.4E7 =-6.387 :..4.2£7 =-2.1E7 I ,-- 0 . OEO Time _4.287 :..3.4E7 :..2.5E7 ~1.1E7 :..6.4E6 - 0 . OEO Time C:r ~. () t1 P'è .-+-' $:1:>: ?ð CD' "tj; O~ :41 N ---:i V1 .- ; I¡j p:¡ (JQ' CD: VI \0 o H-¡ 00 UI ~ It-~ :~.. ~ ~ ~ --- c;r-r- File:MPDMI00066~ #1-3086 Acq: 9-JUN-199ï 16:1~:~6 GC EI+ VOltage SIR ïOSE Samp~e#3 Text:FIORD-2 7930ft $97050IL0188002$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 218.2033 8:3 F:2 10O?i 80-= _1.IE7 =-8.6E6 60-= =-6.5E6 40-= - =-4.3E6 ~ 20..:: .. .. ~J! ,/ ~ 111-\ .....J.J . ~2.2E6 0-,- -. ~~~__.~,Jw.-._-..~. ~O.OEO II I II 1 J III 1 1 ~ 1 II . 1" 1 1 3 0 : 0 0 3 5 : 0 0 4 0 : Ò O' 45 : 00 50 : 00 55 : 00 1 : 00 : 00 Time 217.1956 8:3 F:2 1GOO¡ _2.1E7 80-= - 60..:: =-1.7E7 =-1.3E7 40..:: =-8.4E6 20..:: ~. , '. o ~ J 30:0~ ~i:o~ 231.2111 8:3 F:2 10001 "5 ~O O' ~) V ~ .M f\,.fi ~. Ù ' ~4. 2E6 w,./tV' , ..;'\...v.~ I' , I' · ,',,", 1 - I' I' " 0 . OEO 50:00 55:00 1:00:00 Time ~ , 1 I '" 1 40:00 _8.5E6 80..:: =-6.8E6 <F"" 60..:: 40..:: =-5.1E6 IAJ V~!J NJ· J~~3.4E6 ~~". . '~1.7E6 - 20~. . ~. _ J.A"'L,. o _ ~~-..v-'V.. 1 1 1 .' I ' 1 1 1 I 1 30:00 35:00 40:00 1 I 1 45:00 , 1 1 1 1 1:00:00 - O. OEO Time 1 I 1 50:00 , I 1 55:00 =-2.2B6 :"'1.1B6 -. - O. OEO Time :"4.4E6 =-3.3E6 :"6.7E6 :"5.6E6 :"7.8E6 :"1.0E7 :"S.9E6 _1.1E7 :"S.5E6 ;: 0 . OEO Time :"1.7E7 :"2.6E7 :"'5.1B7 :"4.3E7 =-3.4E7 :"6.8E7 :"6.0E7 _8.5E7 =- 7 .7E7 \\1 ~'N" " .....,.. ... -... u"" .. ~_ I 1 I I J I 1 I 1:00:00 1:10:00 30-= 20-= 10: ~ 0]~Jt..Llw.... . .1\ 30:00 . .. . ~lA~. ' 4 I I 0: 00 I I I 5 I I 0:00 , , 40-= l\O 1-1 ~ q\ 1t I 1'1 50-= 40-= 30-= 20-= 10-= O:~ I 30:00 217.1956 F:2 lOa!: 90-= 80-= 70-= 60-': 50-= " '1\Þ- l() ó ~ 'tv 1", ~" - v ......:: )l p. f db, " ~ r ~I _~-.L.)L ~_ kl.~~~ I I · · I · I I I 1'1 · · 1'1 I 40:00 50:00 1:00:00 1:10:00 ,,", . - I . I ,L-j tí{ riD 'J 70-= 60-': 90-= 80-= File:MPDMI000666 #1-3081 Acq:l0-JUN-1991 07:43:11 GC EI+ Voltage SIR 'lOSE Sample#1 Text:FIORD-2 8100ft $97050IL018S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 191.1799 F:2 10~ C$ " .~ i - ) ~~ ~ ',:- : ~\-\ i , - ,Þ¡: ;$:1:> (Jq CD ,0\ <=> o H-¡ 00 v-. CJ ~' .(') ö .p) ..-+- -~ ~ .g o ;:1. tv ,-..J :VI C'f ~~ o Ö p:¡~ pj"! ::d CD- '1:::S~ o¡ ::t¡ I'-i, --.); VI' ~ p.)' (JQ, CD, 0'\ - o Þ-+) 00 VI " -"(, : :,{\ ........ ~ ~ File:MPDMI000666 #1-3087 Acq:l0-JUN-l991 Oï:43:17 GC EI+ Voltage SIR 10SE Samp~e#l Text:FIORD-2 8100ft $97050ILOl8S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 177.1643 F:2 10 0'!6 80..:: 60..:: 40..:: 20..:: o : r- .. '--- Þ" - 1 30:00 191.1799 F:2 10œ: a 0..:: 60..:: 40..:: 20..:: o - .-'-----i ,.- 1 1 30:00 205.1956 F:2 10O?f 80..:: 60..:: 40..:: 20..:: 0-, 30:00 . ~~~.,¡~~. II> -u,..,.......·.Á'....... ,~,.. ... ,...........~.._,. ~ ....~.... _", ..,. i:ob:o~ i:1b:o~ 1 I I 40:00 ._~ .. . - - . I · 50:00 1 1 . 1:20:00 La-- 1 4'O~00 1 þ - -~~~~~ ÁL '50:00' 'i~oA:o~ IL..J.. - 1:"10: o~ --I i:;b:oó I. 1 I I 40:00 _ . -'-,.....~~_ .,~ÁA-. A...~~~ I 1 1 1 1 1 1 I 50:00 1:00:00 1:10:00 I 1 1 1:20:00 _2.0E7 =-1.6E7 =-l.2E7 =-7.9E6 =-3.9E6 - 0 .OEO Time _8.5E7 =-6.8E7 =-S.lE7 =-3.4E7 =-1.7E7 - 0 .OEO Time _2.5E7 =-2.0E7 =-l.SE7 =-1.0E7 =-S.1E6 -O.OEO Time :..2.1E6 '<J \\... ~1. OE6 =O.OEO Time I 1 · I 1:00:00 :..3.1E6 :"4.1E6 _5.2E6 :..4.4E6 ~~2.2E6 - 0 . OEO I I 1 . . . I 1:00:00, Time :..8.9E6 :..6.7E6 _1.1E7 . I I 55:00 I I I 50:00 I I I 45:00 I 40:00 40~ 20~ . j A I I ~ o-~~~ I I . I I I . 30:00 35:00 'V~v,,/~ 60...:: 80...: I I I 55:00 0-1 30:00 231.2111 F:2 10005 150 ~ 001 I I I 45:00 I I I 40:00 . I I 35:00 ¡JM'~ /.¡ ..N)J '\J J :~.~ 20~ 40...:: 80...:: 60~ . I · 55:00 20...:: 0=, - - .--A1LL~ I I . I I I I I I I I, I 30:00 35:00 40:00 217.1956 F:2 10005 =-2.9E6 ",,~~1.5E6 I .. . I I I 0 . OEO 1:06:00 ' Time :"4.4E6 :"5.8E6 _7.3E6 5 0 ~ 001 45 ~ 00· , ] ,vW J'~ ~i~\ '40~ 80~ 60~ File:MPDMI000666 #1-308'l Acq:l0-JUN-199'l 01:43:1'l GC EI+ Voltage SIR 'lOSE Sample#1 Text:FIORD-2 8100ft $97050IL018S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 218.2033 F:2 10~ ,"1 :'0:- " 'Q ,j ....... j ~ j~ ' i ~1 .~ ~i --~  ',i ~ Þ-ç ,$:I:> (JQ 'CD 0\ N :0 H-¡ ,00 VI ··ò '~ ê1 t:1 ~ ~ ~ lit) "'0 o µ. N -!..J U. :"5.8E6 ~4.4E6 ~2.9E6 ~1.5E6 ....~O.OEO I I Time :"1.2E7 :"1.OE7 :"8.7B6 =-7.3B6 _1.5B7 :"1.3B7 , :"3. 7E6 - 0 . OBO Time :"1.1B7 :"7.4B6 :"2.6B7 =-2.2B7 :"1.9B7 :"1.5B7 '- :"3.0B7 :"3.4B7 ~3.7B7 I I 1 I I 1:05:00 I I b I I 1: 0 : 00 I I I I , , I I I 50:00 55:00 " . -."" . ^ }~ ~,.---_.-. ".~ L~.J ~~~,_ I II I It 11 1.11' I 55:00 1:00:00 .1:05:00 f1-° f\'\ ft' 20-': - ~ 10~. I o:~~·,,_·- ~~ II III I I I I II I I I I I t I 30:00 35:00 40:00 45:00 1 ~y 30-= 90-': 80'-: 70'-: 60'-: 50-= 40-': 30-= 20-': 10-= o ~ r- I 30:00 253.1955 1 0 a!t¡ 40-= 60'-: 50": 80-': 70-= 90-= Exp:GCMS_HRSIR File:MPDMI000666 #1-308'l Acq:l0-JUN-199'l 09:24:2'l GC EI+ Voltage SIR 'lOSE Sample#2 Text:BERGSCHRUND-l 6960ft $97050IL014S001$ File Text:GCMS 6000RP 231.1173 8:2 F:2 1000i f\-'\.o(\V ~:L, fAD fL~ t{fI('1 (/1. 't- f\\J¡'I'1- ø f) I I r 50:00 ~IJ ~ 1'1 I I 11-' 40:00 45:00 I I I I 35:00 8:2 F:2 . , f-\~ {-\4 ~I'" ---., ~ ......J .& ._--{\ \, - "":'0 -..~ -.' Þ-Ø $:1:>, (JQ: CD; 0\ V;) o ~ 06 VI Q '~, C) d $:1:>' ~ ~ ro~ ~: o¡ ~ N -i tA ,'0. E:: :n ~b ~p:¡ ~r-+ ¡:l) "?d ,CD ~ .:0 ~::¡ IN , "-..) :VI '. ;I¡j :$:1:> ;{JQ .CD :0\ .þ. '0 - H-¡ 00 :VI ,-. '. ~\..-.~'" ..- ,;, ,~ .~ .¿ ~ j ',1 -~ File:MPDMI000666 *1-308~ Acq:l0-JUN-199~ 11:0~:3~ GC EI+ Voltage SIR ~OSE Sample#3 Text:BERGSCHRUND-1 7100ft $97050IL0148002$ File Text:GCMS 6000RP 231.1173 8:3 F:2 10~ - 10-= o : y· r-'---'('- I - t I 30:00 35:00 253.1955 8:3 F:2 1000: 90-': 80": 7 0": 60": 50-': 40":: - 90-= - 8 0": 7 0": - 60-= SO": 4 0": - 30": 20": ........" \"\ " ~ i? - 30": 20": 10": 0: _ - I I 30:00 Exp:GCMS_HRSIR ",&-t'\S' fZ· øt f''' ft'\ f'~ "'-~ _,,__Þ---...JvJ~· ~~ . I 4 0 ~ 00 I I 4 5 ~ 00 I ' I 5 0 ~ 0 Ó I I 55 fo 0 I I 1 ~ 00 : Ò 0 I' I, 1 ; 0 S : <> 0 I ,Y<'\ "s {f-A1 f1\.\-\'J- f~ po . ~} f1. V"1.t.. p.~ _~,J.J;AU ~ Jt\N~ , -'1 , I I I I I I I I I I I I r , I 1 I , \'., 1 I ,- 45:00 . 50:00 55:00 1:00:00 1:05:00 ~ -__ A.. £. I ',I I I , , 1 " I 35:00 40:00 _3.2E7 - :"2 _ 9E7 - ~2.6E7 - ¿2 _ 2E7 ~1.9E7 ~1.6E7 =-1.3E7 - :"9.6B6 :"6.4B6 - :"3.2B6 : O. OEO Time _6.2B7 =-5.5E7 - =-4.9E7 =-4.3&7 - :"3.7&7 - :"3.1&7 - :'2.5&7 ~ - :"1.8E7 :"1.2E7 =-6.2B6 =O.OEO Time ò '~' o t:1 ~ ~~ '~ (D' u o ~ t'b '...:..:J U. J Þ-O pj (JQ ~ d\ VI o -. 00 u-. J .~ 'I ( ~ \ \ '<,i~ , - '. File:MPDMI000666 #1-308? Acq:l0-JUN-199? 12:46:47 GC EI+ Voltage SIR 708E Samp~e#4 Text:FIORD-1 7200ft $97050IL016S002$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 231.1173 S:4 F:2 10005 f\'lt'~ - 90"-: 80"-: - 70':: 60"': - 50": 40':: 30':: - 20':: - 10':: f,\ø fzÞ f~ f''\ t''t - 0:; t' F -I -·f . I 30:00 35:00 253.1955 8:4 F:2 10005 90": 80": 70": 60": 50':: 40-= '- ~ - 30-= 20"-: 10"-: - 0: ~ I 30:00 I I I I I 40:00 ~ I I, I I I I I I I I 35:00 40:00 a. ~~~JU~~ I I I I I I I 1 I I I I 1 I I 55:00 1:00:00 .1:05:00 a. _A .... I I I I I 45:00 I I I I I 50:00 f''JC~ f-~ p "" -( 1 ,,\'1- f"" ,,1- .l^0 L p,) L ~_~,_j.~J i~ h,J~ I I II 111I111 I 11111111 45:00 50:00 55:00 1:00:00 I I 1 I I 1:05:00 _7.5E7 - :"6.8E7 - :"6.0E7 - :"5.3E7 - :"4.5E7 - :"3.8E7 - :"3.0E7 - :"2.3E7 :"1.5E7 - =-7.5E6 : 0 .OEO Time _5.9E7 - :"5.3E7 - :"4.7E7 :"4.1E7 - :"3.5E7 - :"3.0E7 - :"2.4E7 - :"1.'8£7 :"1.2£7 - :"5.9£6 - }---.: 0 . OBO Time Q ~ n 'tJ p;¡ .-t- -$:I? ::t1 (þ '"'d <:> ::¡ w ..:...J Vt ~ ~ (JQ CD 0'\ 0\ o I;-i') tx> VI , '~\ .~ ; .-- , ..~ t - j --{ ~ , . -, File:MPDMI00066~ #1-3086 Acq: 9-JUN-199'l 14:34:4'l GC EI+ Voltage SIR 'lOSE Samp~e#2 Text:FIORD-2 7780ft $97050IL0188001$ File Text:GCM8 6000RP Exp:GCM8_HRSIR 231.1173 8:2 F:2 10 O'!f fl","", ¥ 90': 80': - 70': - 60-= 50": 40": 30-=' 20": 10-= o : - --..r -,. , , , , I 1 , 30:00 35:00 253.1955 8:2 F:2 10 00i, 90': 80": 70": 60": sol 40":: - 30":: - 2 0": flit' ".~ feo ft'\ F'Z-t _9.0E7 :'8.1E7 - :. 7 . 2E7 :"6.3E7 - :"5.4B7 :"4. SB7 :'3 . 6B7 :"2. ?B7 :'1.8E7 - :"9.0B6 , - -O.OEO Time _2 . 9E7 :'2.6E7 - :'2.3E7 - :'2.0E7 :"1.?E7 - :'1.4E7 - :"1.2E7 :"8.6B6 :"S.8E6 fL f~ fJ.ð· ' ..LJ. _~.J.,J,Ju ~ Iw~, _ . u. . ,_.. .-,- , '. I ' , I , I ' I I , I ' , , 1 I 1 I 1 1 I ,I I, 1 1 1 ' , , I 1 ' , 35:00 40:00 45:00 50:00 55:00 1:00:00 1:05:00 - 10-= - 0=,--' I 30:00 ~- &- il ....& - , I I ' , I , I I , 40:00 45:00 fll. ~~~J 4---.~ 'I"" I" I '1'" '11' 50:00 55:00 1:00:001:05:00 ~, ~ ~~ f'c~ f'\~\2- fl" "''!) - :"2.9E6 4..-..\: , - 0 . OEO Time :"1.9E7 :"1.327 :"6.4E6 =O.OEO Time :"3.2E7 :"2.5E7 :"5.1E7 =-4.4E7 :"3.8E7 _6.4E7 :"5.7E7 :"4.0E6 ,.- O. 0 EO " -- Time :"8.0E6 :"1.2E7 :"1.6E7 :"2.4E7 :'2.0E7 :"3.2E7 :"2.8E7 _4.0E7 :"3.627 , , 1 I I 1:05:00 _~,~,JÂ... \\,. ~~ 1'1" "I' I I I II1I'I1 I 45:00 50:00 55:00 1:00:00 -~- I I I I 40:00 f1- f''O f'>.3 f~ ,,\<\"\1 f"~1 é Ji~~N,~ .~_ I I 1 I' f I I 1 I , 1:00:00 ,1:05:00 Lv-~ I I I I I I I I I I I I ' 40:00 45:00 50:00 (-1í-t1 , JI 55:00 J< ..M' ~* ,~~ 11." fie. fd. &r.. ,.".1.- JLJ I I. I I , 35:00 I -, , I I I 35:00 S:3 F:2 30": 2 0": 10': 0=.. . 30:00 60": 50": 40": 3 0": 2 0": 1 0": 0:' . 30:00 253.1955 1000¡ 90": 80": 70": 6 0": 50": 40": File:MPDMI00066~ #1-3086 Acq: 9-JUN-199? 16:1~:~6 GC BI+ Voltage SIR 'lOSE Sample#3 Text:FIORD-2 7930ft $97050IL018S002$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 231.1173 8:3 F:2 1 0 ()?¡¡ 90-= 80-= 70": f'"1JC'~ í , ~ , ~ . ~ '. ~ " -- -~.~ -';"l."~. -.~ - '" \ ~ , ~ , - "'d $:I:> {JQ CD (J\ -.J o I--t) 00 y-. Ò :t' .~ tj) ~ ~ ~ i ~ ~ -<J Vi " Q ~ () tj $:I:>~ r-t-- PJ~ ~ ~; 0; ~ r-J -:.t ~ .< ..: ~ ~ aq (1)' 0'. ex> 0. ~ VI -·~i , c ...;~\ ;:: 'I ] '~~~ ;~ . ~ -j - :> - ~ ... -< ',~ ! .~-.i File:MPDMI000666 #1-308'l Acq:l0-JUN~199? O'l:43:1? GC EI+ Voltage SIR lOSE Sample#l Text:FIORD-2 8100ft $97050IL018S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 231.1173 F:2 1 0 0'ltJ 90-': - 80-': 70--=: 60-= - 50-': 40-= 30-': 20-= - 10-= A1"(\~ It#¡ f'2- Þ "2-\ f''- 4=>1- {-\~ L~~0~J~~ , 4 0 ~ 00 ' , 4. 5 ~ 0 Ò " 5 0 ~ 00 'I , 5 5 ~ 0 Ó ' '1 ~ 00 : 00' , - 0:., I 30:00 253.1955 1000: 90-': I , I' I' , 35:00 F:2 - 80-= - 70-= - 60-= - 50-= ....-:..,. .~"~ \.--~ - 40-= 30-= 20-= 10-= I 1 o:~~'\. 30:00 ' , 35~00 ' ",,1/ f{ f-,,%1 ~.o¡1 «.\-\-\"1.- ç.~ fib [\3 ~ù ÇI1.- _,~.JJ JU ~ ~~. "1"1 I II" '1"'11'111111 40:00 45:00 50:00 55:00 1:00:00 ..' I 1 I I ,1:05:00 I I 1 I I 1:05:00 _1.9E7 :"1.7E7 - =-1.5E7 - ::'1.3E7 - ::'1.1B7 - =-9.5E6 - ~7.6E6 - =-5.7E6 =-3.8E6 - ~1.9E6 ~ O. ORO Time _2.4E7 - =-2.1&7 - =-1.9E7 - =-1.7B7 ¿1.4E7 =-1.2E7 - =-9.4E6 - =-7.1&6 - =-4. 7:86 ' - =-2.4B6 - ~:O.OEO Time ~ Î --- - ~ - - - '--^-.. I........ - ~ ~ 0 OBO I I 1 I - I "T 'I I I I I I . I 1 I I I I I I 1 1 1 I -I -I --r I 1 I I I I r I -, r I 1 I 1 I . 23:00 24:00 25:00 26:00 27:00 28:00 29:00 30:00 Time :"7.7R6 :"2.3B7 :"1.5B7 :"3.1B7 :"'3.9B7 :"4.6B7 :"5.4B7 :':6.2B7 :"7.0B7 _7.7E7 - O. OEO I I I 30: 00 Time I I I I I 29:00 , - :"1.9E7 =-9.7B6 :"2.9B7 :"4.8E7 :"3.9B7 :"5.8B7 :"7.7B7 :"6.8B7 :"8.7B7 _9.7E7 Bxp:GCMS_HRSIR I I I I I I I I I I 1 I I I -I I I I I I r 1 I I I 19:00 20:00 21:00 22:00 I I I J 1 I I 28:00 ^ ~_ _ --.J "-..-_ _ ~. _ - r, II . I I I " I I 1 1 I I 1 I I r I' I 1 I I I I I I I I I I 1 I I I I I I 1 1 I I I 1 I I I 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 30-= 20-= 10-= 0: . . 18:00 70~ 60~ 50~ 40-= 90~ 80"': 30-= 20": 10-= 0= I } I I I 1 ' I'" 18:00 19:00 192.0938 S:2 10 O?l¡ 50-': 40-= 70-': 60~ 80-= Fi1e:MPDMI000666 #1-1291 Acq:10-JUN-199? 09:24:2'l GC BI+ Vo1tage SIR ?OSB Sample#2 Text:BBRGSCHRUND-1 6960ft $97050IL014S001$ Fi1e Text:GCMS 6000RP 178.0782 S:2 10~ 90-= - j ': , 1 ,;~, ..r. e\ '''J ."\. ,t \) '-. '- \\ :' ... \.), Þ¡J ~: (JQ (D' 0\ \Q 0: ~ OÓ V) d ~. (j d $:I:>j ~ P:¡i ~ CD:: '0'; 0- ~; tv ~ ~ lP ~ n tJ ,p:¡ -- ~ ~ ft) '"'tj o ~ 'N t-.) "r '~ ~p) rJCI -,CD '-..J ;0 ,0 'H) 00 VI :~ -. "\\ - ~ ~ ,j '\ .. -i ~ '~ (} , J ...J .,i '-.1 ',) '1 ;~ 1- -'1 "¡ ~; ,1 c't '1 .'~ :~ ,;) ; File:MPDMI000666 #1-1291 Acq:10-JUN-199? 11:0~:31 GC EI+ Voltage SIR 'lOSE Sample#3 Text:BERGSCHRUND-l 7100ft $97050IL014S002$ File Text:GCMS 6000RP 178.0782 8:3 100% 90-= 80~ 70~ - 60~ 50~ 40-= - 30-= 20": 10": I 0= '^--^^~~ ~ ~ .. 1 J I , I I 1 (1 ,,-. ~I -. , , , , I ' . .,. , I ' . . . , I I , , , I . 18:00 19:00 20:00 21:00 22:00 23:00 24:00 192.0938 8:3 1000; Exp:GCMS_HR8IR "1'11"'."""1"1"1'" I "'1"'1 25:00 26:00 27:00 28~00 29:00 (\,J - 90": '80": 70": 60": 50": 4 0": 30-= 2 0": ~ 10": 0: ^ ^ -^--,-.,...., ~ ~ ~ I , I , , I 1" I , I , I I I I ( .' I (" I Î J I 1 ,- 't I I ., ~ f ..... . ,_ I r 1 . . . r , I ' , y , , I . , 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00 26:00 L ..... , , . I ' · · , , I ' , 21:00 26:00 _1.4E8 :"1.3E8 - :"1.lE8 :"9.8E7 - :"8.4E7 =- 7 .OE7 - :"5.6E7 - :"4.2E7 :"2.8E7 :"1.4E1 -=O.OEO I . 30: 00 Time _5.6E7 :"5.0E7 - :"4 . SE7 =-3.9E7 - :"3.4E7 - :"2.8E7 =-2.2B1 - :"1.7E7 :"1.lB7 - :"5.6E6 - ~ ~ O.OEO I , . I · I I I , 29 : 00 30 : 00 Time Q ~ n t:1 ~ P:¡ ~ CD, Iocj . o ::4.' N -..) VI ~ P:¡' (Jq' (t) -.j ¡--.o o I-+) 00 VI ..l'J '\. - ~r...") ~. :-:.) ., 08E Exp:GCMS_HRSIR File:MPDMI000666 #1-1291 Acq:l0-JUN-1997 12:46:4~ GC EI+ Voltage SIR Sample#4 'l'ext:FIORD-l 7200ft $91050IL016S002$ File Text:GCMS 6000RP 178.0782 8:4 10001 90'-: - 80": - 70'-: 60": - 50": - 40": 3 0": - 20'-: - 1 0": o ~ f. . J . I . t r'1 {"f. I·~ 1 I . 1-.1', ~ .. I { I I J Î t"î, I . , . .. 1 J . .11 I Î' I~ f 1'1 ~I J . I 11 I 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 192.0938 8:4 10006 90": 80'-: - 70'-: 6 0": 50": 4 0": - 3 0": - 20'-: 1 0": 0= I I I . I, , J I, . I I , I . I 18:00 19:00 20:00 J. - ... I I I I . I I I 1 . I I 21:00 22:00 _4.3£8 :"'3.9E8 - :"'3.4£8 - :"3.0£8 :"2.6E8 - :"2.2£8 :"1.7E8 :"1.3E8 - :"8.6E7 =-4.3B7 - ~ 0 .OEO I . 30: 00 Time _1.7H8 :"1.5E8 - =-1.4E8 :"'1.2B8 =-1.0E8 :"8.6£7 -:"'6.9E7 - :"5.2£7 :"3.4B7 - :"1.7B7 I ("-I . )'-11 "-. I? I I ". II 1'1 I ~I I ~ I I I I '1 I I I (. I "Ì. r;' I "i I I ë o. OEO 23:00 24:00 25:00 26:00 27:00 28:00 29:00 30:00 Time a ~ (J o ~ ....... ~ ~ (;D >a o ~ N ..;...J V'I ~ Po', (JQ CD -..J N o H-¡ ,00 .VI <~'-..." '.~' "'" - ~ ,",';;" ');, ~ ~ -' File:MPDMI00066~ #1-1291 Acq: 9-JUN~1997 14:34:47 GC EX+ Voltage SIR 'lOSE Sample#2 Text:FIORD-2 7780ft $97050IL018S001$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 178.0782 5:2 10 (Y!: 90"': 80-= 70-= - 60": 50"': 40-= 30-= 20": 10": o ~ I . , , '~I . , 1'T'f " ,...rJ\ ) 1', . AI .~ , o;¡-, , ;" I ' f , ,... I ' , . (', I ' 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00 26:00 192.0938 B:2 10~, 90"': 80": - 70': - 6 0": 50"': 40"': - 3 0": 2 0": h, - 10": - 0= , , I ,- , I ' '.' 18:00 19:00 J -, I ' , , 20:00 ) I' I ' , I' f I ' 1"'1, T' ' -r-1" , I ,.,..-- I , 1:1 ' ( I .. I ~I 21:00 22:00 23:00 24:00 25:00 26:00 , J I ' , 29:00 _1.6&8 ~1.4E8 - :"1.3E8 :"1.1&8 :"9.6&7 -:"8. OE7 :"6.4E7 :"4.8E7 :"3.2E7 -=-1.6E7 - O.OEO J J , 30: 00 Time _8.3B7 ~7.5B7 - =-6.6E7 - =-5.8E7 :"5.0E7 :"4.2E7 :"3.3E7 - :"2.5&7 -=-1.7B7 :"8.3B6 - , ~ J I" 1----;-- 1 I I ' , ,- 'Î I (7ï-<iI 1 i O. OBO 27:00 28:00 29:00 30:00 Time o s::' o tj PJ r1- $:I:> ïO CD '1:S o ~ N -..J U\ ~ $:I:> (JQ CD -..J W o H-¡ 00 VI .'-" \) . \' "_.: --=""'-'':; File:MPDMI00066~ #1-1291 Acq: 9-JUN-199ï 16:1~:~6 GC EI+ Voltage SIR 1088 8ample#3 Text:FIORD-2 7930ft $97050IL018S002$ File Text:GCM8 6000RP Exp:GCM8_HR8IR 178.0782 8:3 10 O?D 90-': 80-': 70-': - 60-': - 50": - 40": - 30": - 20": - 10'-: 0= 18:00 ' 19~OO 192.0938 8:3 100% 90": - 80": - 70": ~ ~ - 60-= 50": 40": 30": 20": - 10-= 0= , , , , , 1 ' , , 18:00 19:00 _3.4E8 :'3.0E8 - :"2.7E8 - :"2.4E8 - :"2.028 :"1.7E8 :"1.4E8 :'1.0E8 .- :'6.8E7 =-3.4E7 r,-~, ~^t-, ,ì f '-I', ';-r-¡ I 'ì ' I ~ I ,"r...-' , ' , ".f I" ""''-"1 ' "~, , 1-" , ", ~ O.OEO 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 30:00 Time _1.5E8 :"1.4E8 - :"1.228 - :'1.1E8 - :"9.227 - =-7.627 :"6.1E7 :"4.6B7 - :"3.1£7 - ~1.5E7 ^ ........~. ~...... r~ ,,---^- ~- ~ . <"'- ----. ..r- 0 OEO I I ( , ,,"\ .J' I" I , , I 1 I II I I I I I , , . 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OE7 '-:"6.1E7 :"5.3&7 :"4 . 4&7 :"3 . 5E7 _8.8E7 :"7.9E7 . 1 I""" I....... ,'." 1 J' 11'~IÎ. -r) .{'-.î,., 1--;--. f,..'I....Tl'l.~, 19:00 20:00 21:00 22:00 23:00 24:00 25:00 26:00 ~ 0- , , 18:00 30-= 20-=- 10-= 80-= 70-= 60~ 50-= 40-= "1·····1'· 25:00 26:00 0: , . , . . r . , (l-f1", ~ '~I . îî"í"'r", ~, ~-. 18:00 19:00 20:00 21:00 22:00 23:00 24:00 192.0938 10~ 90-= -____________ ;: 0 . 0 BO , , , I' · . · 1.1 . . , . . 1 · · · , · 27:00 28:00 29:00 30:00 Time :"5.6E7 :"3.8B7 t..1.9E7 :"9.4B7 :"7 . 527 :"1.3B8 :"1.1B8 :"1.5B8 :"1.7E8 _1.9B8 10~ 20-= 30~ 60~ 50-= 40~ 90-= 80-= 70~ File:MPDMI000666 #1-1291 Acq:l0-JUN-199~ O~:43:11 GC EI+ Voltage SIR 10SE Sample#1 Text:FIORD-2 8100ft $97050IL018S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 178.0782 100?£ ):q, ~ i ~ -, ..""{". ; '~-.}.' . r-c ~ CD ".....J ~ o M 00 Vt ·6 ~ <f) tJ ~ $:I:> ~ CD '"d o ~ N ~ çr. d;J ~ o t:1 g.> S- .~ CD "t::j o 4 N -..J v-. ,; . f.t; $:I:> aq CD -..) VI o H-¡ 00 VI " ; ~ 1 4 .'! -.. ~ ~ "'. ~. }v ,w Fi~e:MPDMI000666 #1-1291 Acq:10-JUN-199~ 09:24:27 GC EI+ Voltage SIR 70SE Samp1e#2 Text:BERGSCHRUND-1 6960ft $97050IL014S001$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 168.0939 S:2 10~ _2.0E7 90~ ~1.8E7 - 80~ 70~ 60-= ....... - 50~ 40~ 30~ 20~ 1:~ ! I I I , I I I 11\, 10:00 12:00 198.0503 8:2 10~ 90'-: 80'-: 70'-: 60-= 50~ 40~ 30-= 20~ - 10~ - :"1.6&7 :"1.4&7 :"1.2B7 :"1.0B7 - ~8.1E6 ,~ Ilt~I}.<I~. I I" 14:00 16:00 18:00 20:00 - :"6.1B6 :"4.1E6 :"2.0B6 r ;: 0 . OEO 1 I 30: 00 Time I 1 I I . I 22:00 . 1 1 I . I 1 1 . I 1,1 , 1 I I I . I 24:00 26:00 28:00 _2 . OB7 :"'1.8E7 - :"1.6E7 - :"1.4B7 - :"1.2B7 - :"1.0B7 :"8.2B6 - :"6.1E6 - :"4.1B6 - 0= I 1 1 1 , I .1 I 1 1 I I I 1 . . I I I 1 I 10:00 12:00 14:00 16:00 I 1 I I 1 1 18:00 1 I' I I 1 1 . 1 I 1 . . 20:00 22:00 - I :"2.0B6 · I I 1'1- I~I'-I I 1 11)"-h ,,^,? .'; O.OEO 24 : 00 26 : 00 28 : 00 30 : 00 Time -0 ,g: (1 -~ ,r+ p:¡ -j;;o -f[) "'d o ';4- _N ~ ÍJ\ : '""0 :$:1:> {TQ ;CD ; -..J :0\ -0 H-¡ :00 ;'VI / "=-. :, '\. \.. .... ~~ .~ File:MPDMI000666 #1-1291 Acq:10-JUN-199~ 11:0~:3'l GC EX+ Voltage SIR 'lOSE Sample#3 Text:BERGSCHRUND-1 7100ft $97050IL014S002$ File Text:GCMS 6000RP 168.0939 8:3 10005 90-': - 80-': 70-': - 60-': - 50-': - 40-':; 30": 20"-:- - 10: 01 .,.. .!I' n, \lt~JJ~. I" 10:00 12:00 14:00 16:00 18:00 20:00 198.0503 8:3 10m: Exp:GCMS_HRSIR c3.5E7 :"3.1E7 - :"2.8E7 :"2.4E7 - :"2.1£7 - =-1.7E7 - =-1.4E7 - :"1.0E7 =-7.0E6 - =-3.5E6 """""'"1"""'"""1'" 22:00 24:00 26:00 28:00 - >- 0 . OEO , I 30: 00 Time ~ , ~ - 90-': 80": 70-': - 6 0-': ,50": 4 0-': 30-= 20-': - 1 0-': - 0=' I I I I I {.,' ~ , I , , I I . I I I . I . . I , " . .-. -r I Y (", 10:00 12:00 14:00 16:00 18:00 20:00 I . I ' I ) 22:00 ~1.0E7 - =-9.3B6 - =-8.3E6 =-7 .3E6 =-6.2E6 =-5.2E6 =-4.2E6 - =-3.1£6 =-2.1E6 1L ,=-1. OB6 Iv.. '---^-' - ^ ~ ^-^" ~........-^-- - _: 0 . 0 E 0 , , I 'I I I , . I I . r-r. ,- rï -'-'-~~-, 24 : 00 26 : 00 28 : 00 30 : 00 Time =-9.9£6 =-4.9£6 I Jf 1 ^("ì ,-^y q I : 0 . OEO 28:00 30:00 Time =-1.5E7 ,: =-3.5E7 =-3 .' OE7 =-2.5E7 =-2.0E7 =-4 . 5E7 =-4.0E7 _4.9E7 =-2.8E7 =-1.4E7 _ -= 0 . OEO I I 30: 00 Time =-4.2B7 =-5.6B7 -:"8.5E7 =-7.1E7 =-9.9E7 =-1.1E8 =-1.3E8 _1.4E8 L ..A_ ~ , . , , , 1 I , I I I I . 24: 00 26: 00 . I I I , 18:00 . I . I I . I I I I I I I 14:00 16:00 I I . I ,( I 12:00 30~ 20-= 10~ 0= I I 10:00 I . I I ' I 22:00 111'11. 20:00 80'-: 70~ 60~ 50": 40": , '. . I I I I I . 28:00 I I I (,\A~tM~~ r--;-~r- ì I 14:00 16:00 18:00 20:00 22:00 24:00 30-= 20": 10-': I o ~ ' ^ ! 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I 22:00 1 , 1 I ,I ( 1 I , I J I 1 I 1 I J 1 I I I I I I 12:00 14:00 16:00 18:00 80": 7 0": 6 0": 50": 40": 3 0": 2 0": 1 0": 0= I I 10:00 II'IIII 20:00 , II,,"^,A~("'~f Yl'r~~I' 14:00 16:00 18:00 20:00 22:00 20": 10~ 'I 0- J\ Tl . , , , , , I I I 10:00 12:00 198.0503 8:2 10 O?t¡ 90": 30": a 0": 7 0": 6 0": 50": 40-= 90": File:MPDMI00066~ #1-1291 Acq: 9-JUN-1997 14:34:47 GC EI+ Voltage SIR 'lOSE Samp¡e#2 Text:FIORD-2 7780ft $970S0IL018S001$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 168.0939 8:2 10~ i "' .j ·i -j '. " ....... \~ ,,,.:\ ~ ~ $:I:> {JQ :CD : -..J ': 00 o : H-¡ . 00 , VI -.0 ".~ ;'{(') , 'tJ 1~ :$:1:> 1~ ~CD '"d o ~:¡ "'N ;-..) ¡VI I , -Å_ A.^ L t'"-:- ^ ",---/'-a ---..~. t : O.OEO I I I I I 1- -ì" I I ,I I I . I I,' I 1 I 24:00 26:00 28:00 30:00 Time :'9.5£6 :"4.7B6 :"1.4£7 :"3.387 :"2.887 :"2 .487 :'1.987 :"3.887 _4.7B7 :"4.3E7 ' :'1.987 ~9.486 ·0.0£0 30:00 Time :"2.887 :"4.7£7 :"3.8&7 :"5.7E7 :.. 1 . 5&7 :"6.687 :"8.5E7 _9.4E7 30": 20": 10~ 0= I I 10:00 I I I I, I I I I I I I I I I I I I rill I · I I I I 1 I I I I, I I I I I 12:00 14:00 16:00 18:00 20:00 22:00 I I . I I I I . . I I I I I . I 1,1 I 1'1 I I . 22:00 24:00 26:00 28:00 ~ ". 1-' I 1~~l"'I)'-~-1 I" 14:00 16:00 18:00 20:00 40": 50": 70": 60": 10'-: o ~ ' A A 11"'11. 10:00 12:00 198.0503 S:3 100% 90": 80": 5 0": 4 0": 30"= 20": File:MPDMI00066~ #1-1291 Acq: 9-JUN-199'l 16:1~:~6 GC BI+ Voltage SIR 'lOBE SampleD3 Text:FIORD-2 7930ft $97050IL018S002$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 168.0939 8:3 1000£ 90": 8 0": 70"= 60-': 1 .-~ '" \~\ .J\ I'J v - \ rJ '~ .$:1:> aq (1) -..) ,\0 o H-¡ :00 "VI a· :~ :n :t) :$:1:> ~ :$:1:> .~~ :(1) ';d -0 , i;:1. 'N . !-..J :VI -1 ~ CJ· ~~.~ jn \~ ~~ - ~ .......... ~~ .j ~ -:~. '0 ;:4- ~N --.) .¡ V1 -. t¡j -~ (JQ (D 00 C> o H") 00 V1 ~ ~ ~, W File:MPDMI000666 #1-1291 Acq:10-JUN-199? O'l:43:1? GC EI+ Voltage SIR 10SE Sample#l Text:FIORD-2 8100ft $97050IL018S003$ File Text:GCMS 6000RP Exp:GCMS_HRSIR 168.0939 10~ 90": - ao-=. 70": - 6 0": 50~ 40": 30-=- 20": 10": 0= I I I 10:00 198.0503 100% 90-': 80": 70-': - 60-':' 5 0": 4 0": - 3 0": 20": - 1 0": 0: 10:00 I 1\ It 12:00 I I I " ,I ... I 12:00 _6.9E7 :"6.2&7 - =-5.5E7 :"4.8&7 - ~4.1E7 - =-3.5E7 - =-2.8E7 - :"2.1E7 :"1.4E7 :"6.9E6 - - . . - 0 . OEO 30: 00 Time I" ^__"-__A &. . . ;'JrVI IL.~ _..... _ AI ~ - u I ~ I ,·'(-r'r-õ,:,"1'.wr.. I '--1~-,--'-'''''''''''í~J I . I . . . I . I I I , I . I I I "1 I -I I I I I -I I I 14:00 16:00 18:00 20:00 22:00 24:00 26:0~ 28:00 1111111"11111,11. 14:00 16:00 18:00 I I I I I - I 20:00 1- I I I. I "I 22:00 - ~J~~ I If' I I I I l---?I 24:00 26:00 _2.2&7 =-2.0&7 - :"1.8&7 :"1.6&7 =-1.3&7 :'1.1&7 - ~8.9E6 =-6.7E6 =-4 .4E6 ~2.2E6 , 1-')~tr I ^t <r I : 0 .OBO 28: 00 30: 00 Ti.me MOLFÇ!,JLAR PARAMFTFR LIST 8P CODe PARAMETFR USE/NOTF . H1 C32 HOPANE 22S/(22S+22R) M H2 C31 HOPANE 22S/(22S+22R) M 1 H3 C30 HOPANE/(C30 HOPANE+C30MORETANE) MS H4 ßß HOPANES PRESENT/ABSENT M H5 C30;C31 :C32:C33:C34:C35 HOPANE DISTRIBUTION S He C27 HOPANES Ts/(Ts+Tm) MS H7 C33 HOPANE 22S/(2.2S+22.R) M H8 C34 HOPANE 22S/(2.2S+22R) M H9 C35 HOPANE 22S/(22S+2.2R) M H10 RESIN DITERPANES % RELATIVE TO C30 HOPANE (PEAK G) S H11 C23 EXT TRICYCLIC TERPANE % RELATIVE TO C30 HOPANE (PEAK G) S H12 C24 TETRAOYCLlO TERPANE % RELATIVE TO C30 HOPANE (PEAK G) S H13 28,30 BISNORHOPANE (PEAK X) % RELATIVE TO C30 HOPANE (PEAK G) S H14 17a(H),15a(Me)-27-NORHOPANE (PEAK PI)% TO C30 HOPANE (PEAK G) S H15 OLEANANE % RELATIVE TO C30 HOPANE (PEAK G) S' H16 GAMMACERANE % RELATIVE TO (PEAK G) S H17 HOPANES 035/(C34+035) % S S1 C29 a,cw; STERANES 20S/(20S+20R) M S2 C29 STERANES a,ßß/(a,ßß+a,a,a,) M 2 S3 8TERANES a,a,a C27:C28:C29 S S4 STERANES a,ßß 027:C28:029 8 S5 ßa OIASTERANES/(SAME+aaa,+a,ßß STERANES) % 8M 3 86 LOW MOLECULAR WEIGHT STERANES RELATIVE TO C29 8TERANES 8 S7 STERANE INDEX C27/(C27+C29) % (FROM S3) S S8 4-ME C30 8TERANE % RELATIVE TO C29 20R a,a.a STERANE (PEAK, 42) 84 S9 4-ME STERANES INDEX C28/(028+C30) % S 5 S10 81CADINANES PRESENT/ABSENT S A1 C28 20R TRIAROM. STERANE/(SAME+C29 20R MONOAROM. STERANE) M 6 A2 SUM TRIAROM. STERANE8/(8AME+SUM MONOAROM. 8TERANES) M A3 C20 TRIAROM. STERANE/(SAME+C28 20R TRIAROM. 8TERANE) M A4 C20+C21 TRIAROM. 8TERANE/(SAME+SUM C26-C28 TRIAROM. STERANES) M AS C26 208 TRIAROM. STERANE/C28 20S TRIAROM. STERANE S A6 C27 20R TRIAROM. STERANE/C28 20R TRIAROM. STERANE S M2 PHENANTHRENES (3ME+2ME)/(9ME+1 ME) M 7 M3 MPI [(3ME+2ME)/(PHENANTHRENE+9ME+ 1 ME)] · 1.5 M 7 MBP 3-METHYL S/PHENYLJ2-METHYL BIPHENYL M MDR 4-METHYLDIBENZOTHIOPHENE/1-METHYLDIBENZOTHIOPHENE M M4 SUM C2rC35 HOPANES/(SAME+ SUM C27-C29 STERANES) % S 8 ALKIND ALKANE INDEX n-C17/(n-C17+n-C27) % S R22 R22 INDEX (2 · n-C22)/(n-C21 +n-C23) SM GMC Data Report 275 Page·810f85 NOTES: 1 2 3 4 5 6 ·7 8 m/z 205 aßß m/z218, aaa m/z217 C2?'s backcalculated using S1, 52 and 53 m/z217 m/z 231 Corrected as in Mackenzie, 1980 PhD. Corrected for response factores, Le. equivalent to GC measurement From m/z 191 and m/z 217 S=SOURCE PARAMETER, M=MATURITY PARAMETER. TRIAROM. STERANE=MONOMETHYL TRIAROMATIC 5TERANES MONOAROM. STERANE=DIMETHYL MONOAROMATIC STERANES. (25/04/94) GMC Data Report 275 Page 82 of 85 810MARK~R IDENTIFICATION· PENTACYCLIC HYDROCARBONS BPCOO~ TENTATIVE ASSIGNMENT BASED ON MASS SpeCTROMETRY (m/e 191) I 9-DODECYLPERHYDROANTHRACENE [INTERNAL STANDARD] T s 18a.(H)-22,29,30-TRISNORNEOHOPANE . T m 17a(H)-2.2.29,30-TRISNORHOPANE .Q 17ß(H)-2.2.29.30-TRISNORHOPANE W 17a(H)-25,30-BISNORHOPANE X 17a(H),18a:(H),21 ß(H)-28,30-BISNORHOPANE . Y 17a(H)-25-NORHOPANE D 17a(H)/21 ß(H)-30-NORHOPANE D2 18a(H)-30-NORNEOHOPANE 7t . 17a(H),15a(Me)-27-NORHOPANE ("DIAHOPANE") A 17ß(H),21a(H)-30-NORMORETANE 8 18a(H)-OLEANANE G 17a(H),21ß(H)-HOPANE H 17ß(H),21ß(H)-30-NORHOPANE K 17ß(H),21 a(H)-MORETANE N (22S)-17a(H),21 ß(H)-30-METHYLHOPANE o (22R)-17a(H)/21 ß(H)-30-METHYLHOPANE S GAMMACERANE P 17ß(H),21ß(H)-HOPANE R 17ß(H),21 a(H)-30-METHYLMORETANE U (22S)-17a(H),21 ß(H)-30-ETHYLHOPANE V (22R)-17a(H),21 ß(H)-30-ETHYLHOPANE J 17ß(H),21 ß(H)·METHYLHOPANE a (22S)-17a(H),21 ß(H)-30-n-PROPYLHOPANE ß (22R)-17a(H),21 ß(H)-30-n-PROPYLHOPANE L 17ß(H),21 ß(H)-ETHYLHOPANE 'Y (22S)-17a.(H),21 ß(H)-30-n-BUTYLHOPANE 8 (22R)-17a(H),21 ß(H)-30-n-BUTYLHOPANE E . (22S)-17a(H),21 ß(H)-30-n-PENTYLHOPANE ç (22R)-17a.(H),21 ß(H)-30-n-PENTYLHOPANE GMC Data Report 275 Page 83 of 85 BIOMARKER IDENTIFICATION - STERANES BP CODE TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 217) 10 (20S)-13ß(H),17cx(H)-DIACHOLESTANE 11 (20R)-13ß(H), 17cx(H)-DIACHOLEST ANE 13 (20S)-13a(H), 17ß(H)-DIACHOLEST AN E 14 (20R)-13a(H),17ß(H)-OIACHOLESTANE 15 (24S/R)-(20S)-13ß(H), 17cx(H)-24-METHYLDIACHOLEST ANE 16 (24S/R)-(20S)-13ß(H), 17a(H)-24-M ETHYLDIACHOLEST ANE 18 (24S/R)-(20R)-13ß(H), 17a(H)-24-M ETHYLDIACHOLEST ANE 19 (24RIS)-(20R)-13ß(H),17cx(H)-24-METHYLDIACHOLESTANE 20A (24S/R)-(20S)-13a.(H), 17ß(H)-24-M ETHYLDIACHOLEST ANE 208 (20S)-Sa(H), 14a(H), 17a(H)-CHOLESTANE 21 A (24R+S)-(20S)-13ß(H),17a(H)-24-ETHYLDIACHOLESTANE 218 (20R)-Sa.(H), 14~(H),17ß(H)-ISOCHOLEST AN E 22 (20S)-5a.(H), 14ß(H), 17~(H)- sac HOLEST AN E 25 . (20R)-Sa(H), 14a.(H), 17a.(H)-CHOLESTANE 27 (24S+R)-(20R)-13ß(H),17a(H)-24-ETHYLDIACHOLESTANE 29 (24S+R)-(20S)-13a(H), 17ß(H)-24-ETHYLDIACHOLEST ANE 33A .(24S+R)-(20R)-Sa(H),14ß(H)17P(H)-24-METHYLlSOCHOLESTANE . 338 (24S+R)-(20R)-13a.(H),17ß(H)-24-ETHYLDIACHOLESTANE 34 (24S+R)-(20S)-Sa.(H), 14ß(H), 17ß(H)-24-M ETHYLlSOCHOLEST ANE 36 (24S+R)-(20R)-Sa.(H), 14a(H), 17a(H)-24-M ETHYLCHOLEST ANE 39 (24S+R)-(20S)-Sa(H), 14a.(H), 17 a(H)-24-ETHYLCHOLEST AN E 40 (24S+R)-(20S)-Sa(H), 14ß(H), 17ß(H)-24-ETHYLlSOCHOLEST ANE 41 (24S+R)-(20R)-Sa(H),14ß(H), 17ß(H)-24-ETHYLlSOCHOLESTANE 42 (24S+R)-(20R)-5a(H),14a(H), 17a(H)-24-ETHYLCHOLEST ANE 4ô (24S+R)-(20R)C:3Q STERAN E . GMC Data Report 275 Page 8.4 of 85 810MARKER IDENTIFICATION - AROMATIC STEROIDAL HYDROCARBONS (AROMATIC STERANES) BP CODE TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 2S3 mass tragmentogram) F22 C21 DIMETHYL MONOAROMATIC STEROID F23 C22 DIMETHYL MONOAROMATIC STEROID F2 C27(20S)5ß(H)DIMETHYL MONOAAOMA TIC STEROID F3 C27(20R)5ß(H)DIMETHYL MONOAROMATIC STEROID F4 . C27(20S)Sa.(H)DIMETHYL MONOAROMATIC STEROID F5 C2s(20S)Sß(H)DIMETHYL MONOAROMATIC STEROID F6 C27(20R)5a(H)DIMETHYL MONOAROMATIC STEROID F7 C28(20S)Sa(H)DIMETHYL MONOAROMATIC STEROID FS C28(20R)5ß(H)DIMETHYL MONOAROMATIC STEROID F9 C29(20S)5ß(H)DIMETHYL MONOAROMA TIC STEROID F10 C29(20S)5a(H)DIMETHYL MONOAROMATIC STEROID F11 C28(20R)5a(H)DIMETHYL. MONOAROMATIC STEROID F12 C29(20R)Sß(H)DIMETHYL MONOAROMATIC STEROID F13 C29(20R)Sa,(H)DIMETHYL MONOAROMATIC STEROID (m/e 231· mass fragmentog ram) F14 C2QMETHYL TRIAROMATIC STEROID F15 C21 METHYL TRIAROMA TIC STEROID F16 C26(20S)METHYL TRIAROMATIC STEROID F17 C26(20R)METHYL TRIAROMATIC STEROID F18 C27(20S)METHYL TRIAROMATIC STEROID F19 Cza(20S)METHYL TRIAROMATIC STEROID F20 Cz7(20R)METHYL TRIAROMATIC STEROID F21 Cza(20R)METHYL TRIAROMATIC STEROID BIOMARKER IDENTIFICATION - NORHOPANES BP CODe TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 177) W 17a.(H)-2S,30-SISNORHOP ANE Y 17a(H)-25-NORHOPANE D 17a(H),21 ß(H)-30-NORHOPANE C1 (22S)-17a(H)-2S-NOR-30-M ETHYLHOPANE G 17a.(H),21 ß(H)HOPANE C2 (22R)-17a.(H)-2S-NOR-30-METHYLHOPANE C3 (22S)-17a(H)-2S-NOR-30-ETHYLHOPANE C4 (22R)-17a,(H)-25-NOR-30-ETHYLHOPANE C5 (22S)-17a.(H)-2S-NOR-30-n-PROPYLHOP ANE C6 (22R)-17a(H)-25-NOR-30-n-PROPYLHOPANE C7 (22S)-17a.(H)-2S-NOR-30-n-BUTYLHOPANE C8 (22R)-17a(H)-25-NOR-30-n-BUTYLHOPANE C9 (22S)-17a,(H)-2S-NOR-30-n-PENTYLHOP ANE C 1 0 (22R)-17a.(H)-2S-NOR-30-n-PENTYLHOPANE GMC Data Report 275 Page 85 of 85 Geochemical analysis of cuttings from the following North Slope oil/gas exploratory wells: ARca Alaska Inc. Bergschrund No. 1 (6,520' - 6,600') ARca Alaska Inc. Fiord No.1 (6,560' - 6,720') ARca Alaska Inc. Fiord No~ 2 (7,520' - 7,620'). . ~ GEO¿ ¡r~' Received 27 October 1997 Total of 85 pages in report Alaska Geologic Materials Center Data Report No. 275
