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GMC Data Report No. 279
Geochemistry of oil show intervals from ARca Alaska Inc. Fiord No.3 ARca Alaska Inc. Fiord No. 3A. r~ GE~O'¿Q '~ ~ ~ / ÇI::) () ~lALS Received 10 February 1998 Total of 154 pages in report Alaska Geologic Materials Center Data Report No. 279 ~ . t. ;:I" .. LGC GEOCHEMISTRY Geochemistry of oil show intervals from Fiord-3 and 3A, Alaska by SR Andrews LGC (Teddington) Ltd. · ~.! · a' · .. ,.. Ref.: LFXJ228/76 Prepared for: Neil Piggott, BP Exploration Sunbury on Thames Ref.: 01111455 Authorised by: NS Goodwin Date:January 1998 GMC a Report No. 279 1/154 r I t' I I I I ~ t Summary List of Tables List of Figures Tables Figures Appendices Appendix A Molecular Parameter List Appendix B Biomarker Identification Appendix C Whole Oil GC Peak Areas GMC )ata Rep~~ No. 279 Contents 2/154 ¡ f ~ ~ , f t I . t I I ~ I I . I t t LFXl22 8/7 6 Table No. 1 2.1 - 2.8 -3.1-3.8 Figure No. 1.1-1.8 2.1-2.8 3.1 - 3.24 4.1 - 4.24 5.1 - 5.8 6.1 - 6.8 7.1 - 7.8 8.1 - 8.8. 9.1 - 9.8 10.1 - 10.8 January 1998 GM pata Report No. 279 CONFIDENTIAL List afTables & Figures List of Tables Lithology and Stratigraphy Oil Analysis - Fiord-3 Oil Analysis - Fiord-3 A List of Figures Whole Oil GC Chromatograms '- Fiord-3 Whole Oil GC Chromatograms - Fiord-3A Sterane and Triterpane Ion Chromatograms - Fiord-3 Sterane and Triterpane Ion Chromatograms - Fiord-3A Aromatic Sterane Ion Chromatograms - Fiord-3 Aromatic Sterane Ion Chromatograms - Fiord-3A Phenanthrene and Methyl Phenanthrene Ion Chromatograms - Fiord-3 Phenanthrene and Methyl Phenanthrene Ion Chromatograms - Fiord-3A Biphenyl and Dibenzothiophene Ion Chromatograms -Fiord-3 Biphenyl and Dibenzothiophene Ion Chromatograms -Fiord-3A .......--.-.-......... 3/154 r r" II, , LFXl228/76 CONFIDENTIAL Summary Summary Log evaluation had indicated that there were possible oil shows present in sand and silty sand intervals in the wells Fiord-3 and Fiord-3A, Alaska. Eight such intervals from each of these wells, encompassing the LBK 80, Kuparuk, Alpine and Nuiqsut sedimentary units, have been carefully picked, avoiding significant amounts of caved shale and the samples extracted with dichloromethane. The extracts have been characterised by whole oil GC, GC-MS and Total Soluble Extract isotope analysis. The whole oil GC profiles show a general distribution over the range C!2 to C36, but with co-elution with the lighter hydrocarbons of interfering components in some of the samples. Determined peak areas are reported in Appendix C The data presented in this report augments that from other shows in Bergschrund-I, Fiord-! and Fiord-2, characterised previously and reported in LGC report LFX/228/40. r II r I' I I r . "..." January 1998 GMC Data Report No. 279 4/154 ._...,,--~... .". C) ~ ... - - - - - - .. - . . . . ~ . . . . ., ,. . . . . - - _-.---.-.~~. tJ ~ f:\) ~ ~ o ~ Z o N -J \0 TABLE 1 LITHOLOGY AND STRATIGRAPHY COUNTRY: Alaska WELL: Fiord-3 and Fiord-3A DEPTH DEPTH RANGE WELL UNIT LITHOLOGY PICKED SAMPLE TYPE ..m--- 7(; ct: ..ß'(" LITHOLOGY :H 4020 3960 Fiord-3 LBK 80 Silty sand 90%:SH -dk gy 10% Silty sands Cut 4140 4020 Fiord-3 LBK 80 Silty sand 90%:SH -dk gy 10% Silty sands Cut 4740 4620 Fiord-3 LBK 80 Silty sand 100% Silty sands Cut 6240 6120 Fiord-3 LBK 80 Turb Sand, It-med bm 90%: SH- dk gy 10%: Sands Cut 6600 6570 Fiord-3 Kupamk C Sand, It-med bm 80%:Sand - It gy 10%: SH 10% Sands Cut 6750 6720 Fiord-3 Alpine Silty sand, md-dk bm 60% sands It bm 30%; SH 10% Silty sands Cut 6770 6750 Fiord-3 Alpine Silty sand, md-dk bm 6O%:sands, It brn 30%:SH 10% Silty sands Cut 7020 6930 Fiord-3 Nuiqsut Silty sand, It-med bm 80%:SLST, dk gy 10% SH 10% Silty sands - Cut 4800 4680 Fiord-3A LBK 80 Sands, It grey 90%: Silty sands, It bm 10% Bulked Cut 8010 7980 Fiord-3A LBK 80 Turb Silty sands, med gy 6O%:sands, It gy 40% Bulked Cut 8100 8070 Fiord-3A LBK 80 Turb Silty sands, med gy 80%:sands, It gy 20% Bulked Cut 8130 8100 Fiord-3A LBK 80 Tu'rb Silty sands, med gy 60%: sands It gy 40% Bulked Cut 8610 8580 Fiord-3A Kuparuk C '. Sands, med br 30%: SILTST. med gy 70% Sands Cut 8800 8770 Fiord-3A Alpine Sands, It gy 60%: sands It gy 10%: SH med gy 30% Sands Cut 8840 8800 Fiord-3A Alpine Sands, med bm 70%: sands It gy 20%:SH dkgy 10% Sands Cut 9120 9030 Fiord~3A Nuiqsut Sands, med bm 80%: Sands It gy 20% Sands Cut Ut - ....... Ut ~ r - Q ~ (') tj ~ f""t '~ :::0 ~ o ::¡ Z o N -.J \0 Well name Suite name Country or Origin Depth (ft) : Sample name Fiord-3 Fiordc3 and Fiord-3A extract study Alaska 4020 Inspection Properties API: I>ensity @ 15 deg C Wax Content %wt Wu Melling Point deg C Pour Point deg C Viscod!)' cSt @ 20 deg C Tolal Acidity mg KOIllg Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium ..., tIJ cr' (þ t.J III : 112: 113: 114 : 115: 116 : 117: 118: 119: 11I0 : 11I1: 11I2 : 1113: 11I4 : 11I5 : 11I6 : 11I7 : 1118 : 0.55 0.43 0.85 25 100:81 :45:25: 15: 14 0.36 0.56 114.07 12.49 16.01 3.73 0.00 6.00 47.98 3.94 SedimentlExtract Analysis Extraction TSE %wt 0.075 HPLC .,' Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios SI: 0.26 M2: 0.66 S2 : 0.39 M3: 0.59 S3 : 31 :35:33 1\14 : 51.56 S4 : 27:34:38 M5: S5 : 31.99 AI: 0.12 S6 : A2: 0.18 A3 : 0.55 S1: 48.23 A4 : 0.29 S8: 0.00 AS: 0.63 S9 : A6: 0.99 810 : MDR: 2.84 l\fßP: 15.11 L..........-.....-.-.-.-------- 0'\ - - VI .þ. Saturates GC PristanelPhytane Pristane/nCI7 Phytane/nCI8 CPI: ALKIND : 1U2 : Lightllydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : 28.4 Aromatics: Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 Q - -~ - . ö ~ ~ ~ ~ ~ 0 ::1- Z 0 N -....) \0 - . - . . . . ........ Sediment/Extract Analysis Well name Suite name Country Of Origin Depth (ft) : Sample name . Fiord-3 Fiord-3 and Fiord-3A extract study Alaska 4140 Inspection Properties API: Density @ IS deg C Wax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 10 deg C Total Acidity mg KOnIg Asphallenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium ......:¡ ~ (i' N tv -....) - ~ U\ ~ HI: 112 : 113: 114: 115 : 116: 117 : 118: 119: 1110 : 1111: 1112: 1113: 1114 : 1115 : 11I6 : 11I7 : 11I8 : 0.54 0.46 0.87 19 100:83:54:30: 19: 18 0.33 0.56 84.90 9.91 12.27 4.70 0.00 6.61 48.27 4.52 . . . . 1I--r1I '* .'._"-IIT Extraction TSE %wt 0.041 HPLC Saturates %wt Aromatics %wt Residues %wt AsphaUenes (Micro Method) %wt Biomarker Ratios SI: 0.33 M2: 0.67 S2 : 0041 M3: 0.61 S3 : 33:34:34 M4: 55.48 S4 : 29:33:38 MS: S5 : 32.64 AI: 0.20 A2 : 0.27 S6 : A3: 0.55 57 : 49.44 A4: 0.30 58 : AS: 0.61 S9 : A6: 0.86 510 : MDR: 2.79 MBP: 13.14 Saturates GC PristaneIPhytane Pristane/nCI7 PhytanelnCI8 CPI: ALKJND : R22 : Light Hydrocarbons MCH%: HER HXR Stable Carbon Isotopes Saturates: Total Oil : -28.7 Aromatics: Residue: AsphaUenes Kerogen: STANDARD: NBS22 -29.8 Sediment/Extract Analysis Q ~ n t1 ~ ~ :::0 .g o ::¡ Z o N -J \0 Wtll name Suite name Country Of Origin Depth (ft) : Sample name Fíord-3 Fíord-3 and Fiord-3A extract study Alaska 4740 Inspection Properties API: Density @ 15 deg C Wax Content %wt Wax !\Ielting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOII/g Asphallenes "Iowt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium Extraction TSE %wt 0.319 HPLC Saturates %wt Aromatics %wt Residues %wt AsphaItenes (Micro Method) %wt Biomarker Ratios III : 0.57 SI: 0.44 M2: 0.74 112 : 0.50 82 : 0.51 M3: 0.71 113: 0.89 S3: 32:25:42 M4 : 72.93 114: 0 M5: liS: 100:85:53:30:19:21 84 : 31 :26:41 116: 0.31 85 : 35.29 AI: 0.57 117 : 0.58 A2: 0.65 86 : 118: A3: 0.55 S7 : 4321 119 : A4: 0.31 1110 : 88 : 0.00 AS: 0.71 1111: 72.54 89 : A6: 0.86 11I2 : 12.55 S10 : 1113: 9.25 MDR: 2.62 11I4 : 4.73 MBP: 13.63 ~ illS: 0.00 p) 11I6 : 5.55 cr' (Ð 11I7 : 52.40 N HI8 : 4.71 W ¡ I ¡U."Þr.~·~1'I. .-~~\ . - .,_......-.'- ~..., !\A-, L- 00 - ~ VI ~ Saturates GC PristanelPhytane PristanelnC17 Phytane/nC18 CPI: ALKIND : R22 : Light Hydrocarbons MCR % : HER HXR Stable Carbon Isotopes Saturates : Total Oil: -29.4 Aromatics: Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 Ç) .x. t:1 ~ r-;- ~ ~ (t) "0 o ~ Z o tv -.1 \0 -1 ~ (þ ~ 10 U; ~ ~ . . . . . . . . . . . . - . - . . . . Sediment/Extract Analysis Well name Suite name Country Of Origin Depth (ft) : Sample name Fiord-3 Fiord-3 and Fiord-3A extract study Alaska 6240 Inspection Properties API: Density @ IS deg C Wax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOHlg Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium 111 : 112: 113: 114: 115: 116: 117: 118: )19 : 1110 : 11I1 : 1112 : 1113: 1114 : 1115 : 11I6 : 1117 : 1118 : 0.54 0.50 0.86 o 100:80:51 :31:22:16 0.38 0.55 63.25 7.87 5.34 7047 0.00 2.64 41.83 6.72 . . . . . Extraction TSE %wt 0.094 HPLC Saturates %wt Aromatics %wt Residues %wt Aspbaltenes (Micro Method) %wt Biomarker Ratios SI : 0.38 M2: 0.61 S2 : 0.47 M3: 0.57 S3 : 38:24:37 M4 : 63.03 84 : 33:28:38 MS: 85 : 45.60 AI: 0.41 A2: 0040 S6 : A3 : 0.25 S7 : 50.17 A4 : 0.12 88 : 0.00 AS: 0.47 S9 : A6: 0.83 SIO: MDR: 2.63 MBP: lLl7 Saturates GC PristanelPhytane Pristane/nC17 Phytane/nC18 CPI: ALKlND : R22 : Light Hydrocarbons MCR%: HER HXR Stable Carbon Isotopes Saturates: Total Oil: -29.1 Aromatics: Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 . . II -·-:........--wi ' II . . .. 1 C) ~ () tJ ~ ~ ~ ~ o :4 Z o N -.) \0 ~ ~ (Ð' tv v.. , '~·..!".k '.j' "',,",,'1¡O. c; ",.... ..... - o - - U'I ~ Sediment/Extract Analysis Well name Suite name Country Of Origin Depth (ft) : Sample name Fiord-3 Fiord-3 and Fiord-3A extract study Alaska 6600 Inspection Properties API: I>ensity @ 15 deg C Wax Content %wt Wax Melling Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOlIIg Asphaltenes %\\'t (If Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium III : 112 : 113: 114 : 115 : 116: 117: 118: 119: 11I0 : 1111: J112 : 1113: J114 : 11I5 : 11I6 : 11I7 : 11I8 : 0.50 0.52 0.70 o 100:113:42:19:10:5 0.10 0.51 1.68 3.67 0.00 5.19 0.00 0.00 33.39 0.00 Extraction TSE %wt 0.083 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios SI: 0.23 M2 : 0.74 S2 : 0.29 M3: 0.60 S3 : 29:26:44 M4 : 77.11 S4 : 30:30:38 M5 : S5 : 40.61 AI: 0.28 A2: 0.29 S6 : A3: 0.21 S7 : 40.05 A4: 0.06 S8 : 0.00 A5: 0.61 89 : A6: 1.36 SIO: 1\fDR: 131 MBP: 8.45 Saturates GC PristaneJPhytane PristanelnCI7 Phytane/nCI8 CPI: ALKIND : ' R22,: Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -28.1 Aromatics : Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 ~ P> cr ëÐ ~ 0\ o s:: *t ~ ,.;- ~ ~ (t) "0 o :4 Z o N -.J !..O - I--" - I--" Vt ~ .. Inspection Properties API: Density @ 15 deg C Wax Content %wt Wu Melling Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOIIIg Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickdNanadlum ill .. II .. . . II . ...~. SemmenttE"xtrã'ct AnåTysis - 1- '.---, lit _,,81" .vw..~ .. . . . . . Well name Suite name Country Of Origin Depth (ft) : Sample name Extraction Fiord-3 Fiord- 3 and Fiord-3A extract study Alaska 6750 TSE -/..wl 0.165 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Saturates GC PristanelPhytane Pristane/nCI7 PhytanelnCI8 CPI: ALKIND : R22 : Ill: 112 : 113 : 114: 115 : 116: 117 : 118 : 119: 11I0 : 11I1 : 11I2 : 1113: 1114 : 1115 : 1116 : 1117 : 11I8 : Biomarker Ratios SI : 0.39 M2 : 0.67 S2 : 0.47 M3: 0.63 S3 : 36:24:38 M4 : 63.74 S4 : 34:29:36 M5: 55 : 38.40 AI: 0.42 56 : A2: 0.43 A3: 0.22 S7 : 48.97 A4: 0.10 S8 : 0.00 A5: 0.53 S9 : A6: 1.00 SIO: MDR: 1.66 MBP: 8.54 Saturates: Total Oil: -30.3 Aromatics : Residue: AsphaUenes - Kerogen: Light Hydrocarbons 0.55 0.52 0.84 o 100:79:46:27: 17: I 0 0.37 0.55 Mcn % : HER HXR Stable Carbon Isotopes 5.21 3.08 0.00 8.53 0.00 0.00 36.44 0.00 STANDARD: NBS22 -29_8 Sediment/Extract Analysis Q ~ (j tj ~ ~ ~ ~ o ::¡. Z o N -.J \0 Well name Suite name Country or Origin Depth (fI) : Sample name Fiord·) Fiord·) and Fiord-3A extract study Alaska 6770 Inspection Properties API: Density @ 15 deg C '''ax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOll/g Asphallenes %wt <IP Method) Nitrogen ppm Sulphur "Iowt Nickel ppm Vanadium ppm NickdNanadium Extraction TSE %wt 0.086 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios III : 0.57 SI: 0.48 1\12 : 0.70 112: 0.52 S2 : 0.44 1\13 : 0.68 113 : 0.84 S3 : 36:30:32 M4: 59.49 114: 0 MS: 115 : 100:79:44:27: 17: II S4 : 33:28:37 116: 0.34 S5 : 31.54 AI: 0.50 117 : 0.55 A2: 0.51 S6 : 118: A3: 0.26 119: 87 : 52.57 A4: 0.12 11I0 : S8 : 0.00 AS: 0.53 1111 : 9.16 89 : A6: 0.91 11I2 : 3.87 SID: 1113: 0.00 MDR: 2.08 1114 : 7.82 l\-mp: 8.30 ~ 11I5 : 0.00 ~ 1116 : 0.00 rJ ,~ 11I7 : 39.67 N 11I8 : 0.00 "-..I ~f_"""""'_~"""""'4.'_""""'--""""'__ '-0-.~ ...,..... __.._ ,_ - N - - Ut ~ Saturates GC PristanelPhytane Pristane/nCI7 Phytane/nCI8 CPI: ALKlND : R22 : Light Hydrocarbons Mcn % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -30.2 Aromatics : Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 L Q ~. I I I I I U I ~ U U i ~ ~ ~ ~ K~~-n-1rU ~ Sedlment/rxtract An:l'ysis ~ :;d ~ o ::4 Z o Well name Suite name Country Of Origin Depth (ft) : Sample name Fiord-3 Fiord-3 and Fiord-3A extract study Alaska 7020 N -.) \0 Inspection Properties API: Density @ IS deg C Wax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOll/g Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium Biomarker Ratios III : 0.57 SI: 0.44 M2 : 0.71 112: 0.53 S2 : 0.42 M3 : 0.62 113 : 0.78 114 : 0 S3 : 30:25:43 M4 : 71-59 115: 100:94:51 :35:23: 13 S4 : 30:27:41 MS: 116: 0.18 SS: 34.99 AI: 0.50 117 : 0.55 A2: 0.52 118: S6 : 119: S7: 41.50 A3: 0.13 11I0 : S8 : A4: 0.05 0.00 1111: 2.82 AS: 0.48 S9 : 1112: 2.74 A6: 0.86 1113: 3.59 SIO: MDR: 1.30 1114 : 6.37 MBP: 5.92 ~ 1115 : g. 0.00 Õ 11I6 : 0.00 !v ....... 1117 : 36.17 W 00 - 1118 : 0.00 ....... tit ~ ,. Extraction TSE %wt 0.061 HPLC Saturates %wt Aromatics %wt Residues %wt Aspbalteoes (Micro Metbod) %wt Saturates GC PristaneIPbytane Pristane/nCI7 Phytane/nC18 CPI: ALKIND : R22 : Light Hydrocarbons MCII % : HER IIXR Stable Carbon Isotopes Saturates: Total Oil : -29.5 Aromatics: Residue: Aspbalteoes Kerogen: STANDARD: NBS22 -29.8 I SedimentlExtract Analysis C') ~ () tJ ~ ..... ~ ~ ~ o :4- Z o N .......) \0 Well name Suile name Coun'ry Of Origin I>epth (ft) : Sample name Fiord-3A Fiord-3 and Fiord-3A extract study Alaska 4800 Extraction TSE %wt 0.075 HPLC Saturates %wt Aromatics %\Vt Residues %wt Inspection Properties API: Density @ 15 deg C Wax Content %wt Wax MelCing Point deg C Pour Point deg C . Visroeit}' cSt @ 20 dcg C Total Aeidlty mg KOlIIg Asphallenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelfVanadium Asphaltenes (Micro Method) %wt Saturates GC Pristaneæhytane Pristane/nC17 Pbytane/nC18 CPI: ALKlND : R22 : Biomarker Ratios III : 0.56 SI : 0.28 M2: 0.67 112: 0.40 S2 : 038 M3: 0.62 113: 0.84 S3 : 33:35:31 M4 : 53.72 114: 27 M5: 115: 100:99:56:34:20:21 S4 : 27:34:38 116: 0.36 S5 : 27.06 AI: 0.10 117: 0.54 A2: 0.15 S6 : 118: A3: 0.51 119: S7 : 51.79 A4: 0.27 11I0 : S8 : 0.00 A5 : 0.56 1111: 89.38 S9 : A6: 0.92 1112 : 11.60 SIO: 1113 : 12.58 MDR: 2.75 11I4 : 3.91 MBP: 8.97 I >-J 11I5 : 0.00 p:¡ 1116 : 0.00 cr' Õ 11I7 : 50.64 V-} 11I8 : 4.09 Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -28.3 Aromatics: Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 ~'~.'4fI'F."'.~.~.~._.___._._.____. - . - - __- _- - · · · - - - - - _. ~ - I-" U. ~ Q ~ () tJ -::;.- ~ ~ .g o :¡ Z o N -.J \0 - - - - - . ..... .. i1i .. .. iI 1M .. ~ - Sediment/Extract AnalysIs Well name Suite name Country Of Origin Depth (ft) : Sample name Fiord-3A Fiord-J and Fiord-3A extract study Alaska 8010 Inspection Properties API: Density @ IS deg C Wax Content %wt Wax Melting Point deg C . Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOII/g Asphalrenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium II ¡¡ ¡a ill a 1& II 1& jf-U ~-I-nd \ \ Extraction TSE %wt 0.089 HPLC -- Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios III : 0.45 SI: 0.26 M2 : 0.71 112 : 0.42 S2 : 113: 0.37 M3 : 0.56 0.81 114: 0 S3 : 32:26:40 1\-14: 47.59 liS: 100:83:43: 19: 13:10 S4: 33:31 :35 1\15: 116: 0.33 SS: 48.26 At: 0.13 117 : 0.48 A2: 0.15 118 : S6 : 119: S7 : 44.76 A3: 0.40 11I0 : S8 : A4: 0.13 0.00 11I1 : 53.52 AS: 0.56 S9 : 1112: 12.20 A6: 1.69 11I3 : 8.87 SIO: MDR: 2.63 11I4 : 7.09 MBP: 11.42 illS: 0.00 ~ - 11I6 : P-1 Vt 0.00 cr - (b - IIl7 : 42.24 Vt l...) .þ. 11I8 : 12.82 N Saturates GC PristanelPhytane Pristane/nCt7 Phytane/nCI8 CPI: ALKIND : R22 : Light Hydrocarbons Mcn % : HER IIXR Stable Carbon Isotopes Saturates: Total Oil: -27.8 Aromatics: Residue: Asphaltenes Kerogen : STANDARD: NBS22 -29.8 C) ~ (') t:1 ~ ~ ~ (t) "0 o ::t. Z o N -.) \0 Sediment/Extract Analysis Well name Suite name Connlry Of Origin Deplh (ft) : Sample name Fiord-3A Fiord-3 and Fiord-3A extract study Alaska 8100 Inspection Properties API: ()ensily @ J5 deg C Wax Conlent %'r\'t Wu !\Ielting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Tolal Acidity mg KOlllg Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wl Nickel ppm Vanadium ppm NickelIVanadium I-J ~ (þ ~.) ~.) III : 112: 113: 114: 115: 116: 117: 118: 119: 1110 : 1111: 1112 : 1113: 11I4 : 1115 : 1116 : 11I7 : 11I8 : 0.44 0.44 0.80 o 100:78:37:17:11:7 0.29 0.46 47.02 11.99 6.30 7.39 0.00 3.45 41.11 9.90 ,"-.-----"-"'--.......----..---- - - 0\ - - VI ~ Biomarker Ratios SI: 0.25 1\-12: 0.75 S2 : 0.35 M3: 0.58 S3 : 31:26:41 M4: 49.68 S4 : 33:31:35 M5: S5 : 49.21 AI: 0.14 A2 : 0.16 S6 : A3: 0.41 S7 : 43.24 A4: 0.15 S8 : 0.00 AS: 0.62 S9 : A6: 1.54 SID: MDR: 2.48 MOP: 9.78 Extraction TSE %wt 0.108 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Saturates GC PristanelPhytane Pristane/nC17 Phytane/nC18 CPI: ALKlND : R22 : Light Hydrocarbons Mcn % : IIER HXR Stable Carbon Isotopes Saturates: Total Oil: -28.3 Aromatics: Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 -"" -. t-1 ~ (D' w ~ C) ~ () p ~ ~ (þ '"0 o ~ Z o N -J \0 - -J - - Ut ~ . . . . . . Well DaOle Suite DaOle Country Of Origin Depth (ft) : Sample Dame . . . . . .. .-..... Sediment/Extract Anniysís Fiord-3A Fiord-3 and Fiord-3A extract study Alaska 8130 Inspection Properties API: Density @ 15 deg C Wax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C- Total Acidity mg KOlIIg Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium. III : 112: 113: 114: 115: 116: 117: 118: 119: 11I0 : 1111: 11I2 : 1113: 11I4 : 11I5 : 11I6 : 1117 : 11I8 : 0.46 0.44 0.81 o 100:77:35:16:11:7 0.29 0.47 65.79 12.11 6.89 8.33 0.00 0.37 40.56 8.19 II M···.j rrT1("" .II~ Extraction TSE %wt 0.11 I HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios --- 81 : 0.23 M2: 0.74 82 : 0.36 M3: 0.43 83 : 35:24:40 M4 : 45.97 84 : 35:32:32 MS: 85 : 51.20 AI: 0.15 A2: .0.16 86 : A3: 0.50 87 : 4650 A4: 0.19 88 : 0.00 AS: 0.63 89: A6: 1.54 810 : MDR: 2.34 MBP: 10.82 Saturates GC PristanelPbytane Pristane/nCl7 Phytane/nCl8 CPI: ALKIND : Rl2 : Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -28.5 Aromatics: Residue: Aspbaltenes Kerogen: 8T ANDARD: NBS22 -29.8 C) ~ n tJ ~ .... ~ ~ .g o ::1- Z o N -.) \0 .....J t\) cr" (õ w VI , . .Þ_ÿ~~.~~J...~A4""'~~"""" "\......... , - 00 - - Ut .þ. Well name Suite name Country Of Origin Depth (ft) : Sample name Fiord-3A Fiord-3 and Fiord-3A extract study Alaska 8610 Inspection Properties API: Density @ 15 deg C Wax Content "Iowt Wax Melling Point deg C I'our Point deg C "iscodty cSt @ 20 deg C Total Addity mg KOn/g Asphallenes "Iowt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium III : 112 : 113: 114: 115: 116: 117 : 118 : 119: 11I0 : 1111: 11I2 : 11I3 : 11I4 : 1115 : 11I6 : 11I7 : 11I8 : 0.41 0.50 0.72 o 100:98:40:24: 13:8 0.17 0.43 13.59 3.66 0.00 7.45 0.00 0.00 39.26 0.00 ...... - -.- -=-.......-.... ....- ~.-.,.. Sediment/Extract Analysis Extraction TSE "Iowl 0.197 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios SI : 0.20 M2: 0.77 S2 : 0.22 M3: 0.63 S3 : 33:31:35 M4 : 35.19 S4 : 32:35:31 1\15 : S5 : 41.62 AI: 0.28 A2: 0.22 S6 : A3: 0.20 S7 : 48.30 A4: 0.04 S8 : 0.00 AS: 1.04 S9 : A6: 2.81 S10 : I\IDR : 0.49 MBP: 6.21 Saturates GC PrislanelPhytane Pristane/nCl7 Phytane/nCtS CPI: ALKlND : 1U2 : Lightllydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -28.8 Aromatics : Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 .....J C) ~ .. f"'\_ Ö PJ ..... PJ ~ (þ þoO o ;¡ Z o N -..) \0 Jo-i p) cr' ëÞ w ~ - ~ - u. ~ ... - - - - - - - - - - - - - - - - - - Sediment/Extract Anatysis Well name Suite name Country Of Origin Depth (ft) : Sample name Fiord-3A Fiord-3 and Fiord-3A extract study Alaska 8800 Inspection Properties API: Density @ IS deg C Wax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOH/g Asphaltenes %wt (lP Melhod) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadium III : 112 : 113: 114: 115 : 116 : 117 : 118: 119 : 11I0 : lilt : 1112 : 1113: 11I4 : 1115 : 11I6 : 11I7 : 11I8 : 0.51 0.52 0.71 o 100: 108:34: 16:8:2 0.13 0.50 40.32 1.45 0.00 5.65 0.00 0.00 21.24 0.00 - - - ---- Extraction TSE %wt 0.112 HPLC Saturates %wt Aromatics %wt Residues %wt Aspbaltenes (Micro Method) %wt Biomarker Ratios SI : 0.25 M2: 0.75 S2 : 0.29 M3: 0.63 S3 : 36:21:36 M4: 62.19 54 : 36:31:31 MS: S5 : 50.06 AI: 0.26 A2: 0.26 S6 : A3: 0.31 S7 : 49.75 A4: 0.09 S8: 0.00 AS: 0.75 59 : A6: 1.68 810 : MDR: 1.27 MBP: 7.41 Saturates GC PristanelPhytane Pristane/nCI7 Phytane/nCI8 CPI: ALKIND : R22 : Lightllydrocarbons MCH%: HER HXR Stable Carbon Isotopes Saturates: TotalOil: -28.7 Aromatics: Residue: Asphaltenes Kerogen: 8T ANDARD: NBS22 -29.8 - - . - . ...... C) s:: (') t1 ~ ~ ~ ~ ~ o ::1- Z o N ......,J \0 Well name Suite name Country or Origin Depth (ft) : Sample name SedimentlExtract Analysis Fiord-3A Fiord-3 and Fiord-3A extract study Alaska 8840 Inspection Properties API: Density @ 15 deg C Wax Content %wt Wax Melling Point deg C Pour Point deg C Viscocit)' cSt @ 20 deg C Total Acidity mg KOII/g Asphallt'nes %wt (IP l\It'lhod) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm Nickt'INanadium i I~ IIlJ cr' (b W -1 , ~~r.IjilllIoI',: II\~'-_,.. ',A..~,~"_ .__ ,,_____. _ N o - 1-'0 Ut ~ III : 112: 113: 114: 115: 116: 117: 118: 119: 11I0 : 11I1 : 11I2 : 1113: 11I4 : 11I5 : Hl6 : 11I7 : 1118 : 0.55 0.52 0.76 o 100:91 :35:17:10:3 0.25 0.53 41.75 9.04 0.00 7.02 0.00 0.00 25,63 0.00 Extraction TSE %wt 0.208 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios SI : 0.34 M2: 0.74 S2 : OAO M3: 0.71 S3 : 38:26:35 1\14: 59A8 S4 : 37:30:32 MS: SS: 46.83 AI: 0.32 A2 : 0.34 86 : A3: OAl S7 : 52.41 A4: 0.15 S8 : 0.00 AS: 0.67 S9 : A6: 1.38 SIO: MDR: 2.10 MBP: 9.41 Saturates GC PristanelPhytane Pristane/nCl7 Phytane/nCIS CPI: ALKlND : " R22 : Lightllydrocarbons Mcn % : HER JIXR Stable Carbon Isotopes Saturates: Total Oil : -19.7 Aromatics: Residue: Asphaltenes Kerogen: STANDARD: NBS22 -29.8 Q ~ n -l.i~'- ~ ~ :;;tJ ~ o ::¡. Z o N -] \D .~ t} (ñ W 00 N ¡......o. - ¡......o. Vt -J:>. Well name Suite name Country or Origin Depth (ft) : Sample name Sediment/Extract Analysis Fiord- 3A Fiord-3 and Fiord-3A extract study Alaska 9120 Inspection Properties API: Density @ IS deg C Wax Content %wt Wax Melting Point deg C Pour Point deg C Viscocity cSt @ 20 deg C Total Acidity mg KOlllg Asphaltenes %wt (IP Method) Nitrogen ppm Sulphur %wt Nickel ppm Vanadium ppm NickelNanadiulU III : 112: 113: 114: liS: 116: 117 : 118 : 119: 1110 : 1111 : 11I2 : 1113: 11I4 : filS: 11I6 : 11I7 : 1118 : 0.52 0.52 0.75 o 100:98:46:25: 16:8 0.16 0.53 13.94 4.30 0,00 6.87 0.00 0.00 33.81 0.00 -.... ..í<ii'¡¡'_."__,.-"'~ Extraction TSE %wt 0.098 HPLC Saturates %wt Aromatics %wt Residues %wt Asphaltenes (Micro Method) %wt Biomarker Ratios SI: 0.32 M2: 0.76 S2 : 0.34 M3: 0.63 S3 : 32:26:40 1\14: 68.44 S4 : 32:30:37 M5: SS: 40.73 AI: 0.35 A2: 0.36 S6 : A3: 0.22 S7 : 44.56 A4 : 0.07 S8 : 0.00 AS: 0.60 S9 : A6: 1.21 SIO: MDR: 1.26 MBP: 7.10 Saturates GC PristanelPbytane Pristane/nC17 Phytane/nCI8 CPI: ALKlND : R22 : LightIIydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -28.5 Aromatics: Residue: Asphaltenes Kerogen : STANDARD: NBS22 -29.8 Q ~ n d ~ 400~ ~ ~ 97110lL001S001 -~ - 0 _ ::1 _ Z o Whole Oil GC Fiord-3, 4020ft (LBK unit) 350- N _ ....J \0 300- 250- 200-- 150- 100- 50~ 31 9 =1 11 N N .------ O~ ..,..;. 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Jv Jilt, l.\JJ /JI>..¡J<.J.-;c -,¡-,,""'....;L -LLL_~__ ÞOyj ,jQ' ~ O-=- ---- (þ !'J ~"'-I..!X!.!l!.!.!lI.!l!.I.l111 ~l~~ lí(ll_r~l¡!I Tff1nc!rrrTl~.l!:ITT]TIT11111 ~I ~ IlIrrr~l~rrTfTT~1111111 :I~ III III :I~ 1111111:1 ~ IIIIIII~I~"I III :I~IIIII f I ~I~"I III ~I! 1111'111.1 ~ 11/ III ~ ~ II '1111 ~E III II'~E "'11 f I ~I~ II I f1 I ~ II /'11 ~E 111// 1/ 1 "!l w VI - I--' VI .þ. o 3:: () t1 r-1 - ~ - ~ ( ) - -g 97110lL001S015 gOO-=- ;¡ -- Z - 0 N =_ -...J -- \0 800~ Whole Oil GC Fiord-3A, 8840ft (Alpine unit) \ I I 700~ BOO-=- 500~ 400~ 300~ 1 DO-=- , JI I ~ J II ) \ AI I \~, t \t . r,¡~ I\I¡ i~ ~/w... j Jw ,^'^ , '~~~--- --- 2DO-=-- Þ-r1 -=- ~ óQ' -- E; 0=:; ( ) --=-~ N -.} ~L J 1mrmqnlTjlTnllTrrp 1IIIIIIIJIITlJl1TlllTllJ II11IIII1111111111111111111111111111111111111111111111II11II111III11111111111111' 1I1I11IIIIIII 1111111111 lllllllllìTTlI 1 II1IIIIIIII 1II1II'II III rmrmrrllll IIII IIII 1IIIIII1I11I rill IIIIIIT 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 56 58 '-' ---_.~-----'-'-_._- .'"--.""'--~, - -~.-~---_.. _..-----.,-....-_.-~ ._------~---~_. - .. 700- 97110lLOO1S016 Q 650- ~ () ,Ö 600- i~ Øo) ~ ~ 550,-- 0 ,:4 Z ? 500-· I'-> -.1 \0 450- 400- 350--- 300-- 250- 200·-- 150-- 100-- Whole Oil GC Fiord-3A, 9120ft (Nuiqsut unit) ÞT1 ~. ~ N 00 ._..." !<¡¡.¡W.\\!W¡¡¡~¡Y¡¡lj,lIij!!!;qJlll.lJllfW,Im!IIImlt"lj .ij¡'¡ IMw.UmmIJ J¡¡ ,lli!.WJw.I!.ll\WÞf'!I "I!IJ.!,IJ./IM~!IJillI ¡11.W' B"" , , ,¡Uô,~" B " ,.., , ... ~. u. ." u co.' ,u,u' .. ....... ~.., , . 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Q ~ () tJ ~ ~ .~ (1) ~ o ;:¡ Z o N -J \0 "T1 oëï E; (j) w VJ 00 - - U\ ~ J.t·1~e :M1"lJFI~UUU7 J.~ #1-::fD8b Acq: lll-=-DE'C-199"' 1~: 41: 11 GC EI+ Voltage SIR 70SE Sample#3 Text:FIORD-3 4020' $97110IL001S001$ File Text:6000RP GCMS Exp:GCM8_HR8IR 191.1799 8:3 F:2 10 O'!; "Í) 90-= 80-= if - 70-= ~ IV J 0- 60-= ~ .v- I ~î/ I -¡; ~ - 50--= - 40-= ~ ~ ~ o < o 1'0 t¡) ~ n ~ i - 30": - ~ 20": Æ p v l:~~~~lAL~~1L"ll.l"~ a( 30~00 I I I I 40~00 I 50~00 1:00:00' 217.1956 8:3 F:2 1 0 0015 I 1 I 1:10:00 90": l' - - ",z.- 80--= - -.."" - 70-= - - 60-= 1° ~"J - - 50": - \\ - 1Jc<>4\ 40": 1+ 3 0-= ' h . ::J~J ,j jij~'~~~NÅ) rJ\\~I~~~___~_m - I I I I I I I I I I I I I I 1 I I I I 1 I 30:00 40:00 50:00 1:00:00 1:10:00 - - ----- -- -- ---- _1.2E8 :"1.lE8 :"9.4E7 - :"8.3E7 :"'7.1E7 - :"5.9E7 - :"4.7E7 - :.. 3 . 5E7 / _ - :"2.4E7 - :"1.2E7 O.OEO Time _3.4E7 :"3.1E7 - :"2.7E7 :"2.4E7 - :"'2.1E7 :"1.7E7 - :"1.4E7 - :"1.OE7 - ~6.9E6 ~3.4E6 - ;. 0 . OED Time C) ~ () tJ ~ ~ :::0 ~ o ::¡ Z o N -J \0 Þ-rj åQ" 'E; In ~~,,,r¡=_-. .._..~_._, .. W \0 - ~ Ut ~ File:MPDMI000112 #1-30ê6 Acq:l0-DEC-1997 1~:41:11 GC EI+ Voltage SIR 70SE Sample#3 Text:FIORD-3 4020' $97110IL001S001$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 8:3 F:2 1000: 80...:: 60...:: 40...:: 20...:: 0..:, I I ' 30:00 40:00 191.1799 8:3 F:2 1000~ 80...:: 60..:: 40...:. "~~~.~.ÞJ~ .1 20..: =J~~~ O-~ - I , , I I ' I 30:00 40:00 205.1956 8:3 F:2 10~ 80...:: 60_~ 40_~ 20: 0..:: 30:00 I 40:00 ". I I. , I I SO:OO i:oo:oo i:10:00 , 1 ' 1:20:00 '50~00' wLf~,~,._ i:oo:oo i:1Ó:OO , 1 I 1:20:00 I 50:00 ",,-,(L~ I 1 I '1 I 1:00:00 1:10:00 i:26:00 _2.5E7 =-2.0E7 =-1.5E7 =-1.OE7 =-S.OE6 - 0 . OEO Time / _1.2EB =-9.4E7 =- 7 . IE7- =-4.7E7 =-2.4E7 - 0 . OEO Time _3.2E7 =-2.6E7 =-1.9E7 =-1.3E7 =-6.5E~ - 0 .OEO Time I ~ Q ~ () o ~ ...,. ~ ~ ~ o ::¡ Z o tv ......,J \0 'TJ OQ' ~ ~ o 0 w;::: w~ File:MPDMI000712 #1-3086 Acq:10-DEC-1997 15:41:11 GC EI+ Voltage SIR 70SE Sample#3 Text:FIORD-3 4020' $97110IL001S001$ File Text:6000RP GCMS Exp:GCMS_HRSIR 218.2033 S:3 F:2 10OO~ 80...:: 60...:: 40...:: 20...:: O-~ ~~~ " I I . ' . 30:00 35:00 40:00 217.1956 S:3 F:2 10ms 80...:: 60...:: 40...:: 2 o~ . jlJJj.JMJLJ O-_~ · · I I . I . J I . 30:00 35:00 40:00 231.2111 S:3 F:2 10~ 80-.:: 60...:: - 40~ t ~ 20~ _~jJ..M,~ ~ ~ o -1- . . . . . . I I I I . I I 30:00 35:00 40:00 ..0/V~ k~ Jv1 ~ .~. ~~: ~ ::: - O. OEO Time I f 45:00 -l~.J\¡ A ....~~ 55 roo' r · 1':'06; 0'0 · I . ' . - I 50:00 . I I 45:00 - ( w JJ .Jv. · tv I J"!\ ,I'y ""'\ ~ ~ ~ · I I · I I · I 1 . I 50:00 55:00 1:00:00 45 ~ 00' . I I 50:00 . I I 55:00 · · 1 · I 1:00:00 _3.6E7 ~ :"2.9E7 :"2.1E7 :..1.4E7 :"7.1E6 .N."--:.-O.OEO Time / _3.4E7 :.2.7E7 :.2.1E7 :.1.4E7 :.6.9E6 O.OEO Time _1.3E7 - :.1.0E7 :..7.5E6 =-7.9£6 :"5.3E6 :"2.6E6 -O.OEO Time :"2.4E7 :'2.1E7 :'1.9E7 -:"1.6&7 ~1. 3£7 :"1.1£7 _2.6£7 :'1.0&7 - 0 . 0&0 Time :'2.0&7 :'3.1&7 / :"4.1&7 =-5.1E7 =-6.1&7 _1.0E8 :"9.2E7 :"8.2E7 :"7.1E7 1:10:00' 1:00:00 ~ rJ (~;~~~,- It or <l' ~ "l '" 1\ ~ .¡:.. ~ - - Ut .¡:.. .!-~4;;t)1;~~TrJ."'·"~ln~""~"4':~""..."".r ._". ~ r~·~~--.. '.. _\l"'~fv. _.~- 80": 70": 60"': 50':' 40: 30~ t · ~:} .1. _ L~,I,)!l.J4...JJ~ ~N. ~, o-~~· - I I I I I ' , , , I ' , 30:00 40:00 50:00 ;'T ~. ~ lû ~ \\ ,0 -Þ 90"': 20--=' ~ ~ ,,¡ 0( : Þ ~ ~ \', - f' fJ lO-j ~--.L~~ 1111.1.1.11, -l. II ~~~I~ . o-=.~~ ~r.A.~A"WW JJL u~ JlVN'tv~ 30:00 1 I , , 40~00' , , '50~00' , , 1:00:00 I I 1:10:00' , ,-~ 217.1956 8:4 F:2 100% File:MPDMI000712 #1-3086 Acq:l0-DEC-1997 17:22:26 GC EI+ Voltage SIR 70SE Sarnple#4 Text:FIORD-3 4140' $97110IL001S002$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 S:4 F:2 1 0 <Y!f ù ,,"J 3 i ~ , ~ ~ 41 ~ 1 ~ ~ ~ y !:.' t1 f> q! f ({ 1("" 30": 70--= 60--= 50-': 40"': Q 3:: () ö .~ ...... ~ :;d (l) "0 o ::+ ..-z o tv -..J \0 80--= 90--= /¡S' - 0 .OEO Time ::...5.0E6 ::...1.0E7 ::...1.5E7 ::"'2.0E7 _2.5E7 - O.OEO Time ::...2.0&7 ::...4.1E7 -=-6.1E7 ::...8.2E7 ~1~OE8 - 0 . OEO Time ::...5.6E6 ::...1.lE7 ::...1.7E7 ::...2.3&7 _2.8E7 .---f 1 1 1 1:20:00 I 1 I 1:20:00 i:2b:oò I , l.. I ~ -A..- \..).J...)JoJ ~ . _...._.. _ I 1 1 1 ' i:ob:oó 1:10:00 , 1 1 50:00 1 40:00 0..: 30:00 20..: 40..: 60..: 80..: 40..: 2:L~~~~~JuJL~l~ 30·00 4010 1 I I 1 I 1 , 1 , . : 0 50.00 1 I 1 1 1 I I 205.1956 S:4 F:2 . 1:00:00 1:10:00 1000~ 60...:: 80...:: i:10:0Ó 0.:_ 30:001 1 I 140~OO' 191.1799 S:4 F:2 1000~ i:oo:oó 150~001 - I ~J.~. 20...:: 40..: 80..: 60...:: File:MPDMI000712 #1-3086 Acq:10-DEC-1997 17:22:26 GC EI+ Voltage SIR 708E Sample#4 Text:FIORD-3 4140' $97110IL0018002$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 8:4 F:2 10003 Iï1 ~. (p ~ ~ ~ Vl - UI ~ / C) a: n tJ ~ ~ :;d ~ o :4 Z o N ....... \0 C) ~ n tJ ~ rt' ~ .~ (þ "0 o ::¡ Z o ·.-N -.J \0 ~ ôQ" ¡~ '(t) IJJ 0\ -. - ~-,~,~-~_",,-,-,-_~_~- - -. ......~_._"'-.~.-"._.o....__¡,.. - _~_~_._ __._-=~'-'-'-~,,"-__~_--"_""_ .. Fìle:MPDMIOOOï12 #1-3086 Acq:10-DEC-1997 17:22:26 GC EI+ Voltage SIR 70SE Sample#4 Text:FIORD-3 4140' $97110IL001S002$ File Text:6000RP GCMS Exp:GCMS_HRSIR 218.2033 S:4 F:2 10~ 80-= 60-= 40-= 20-= O·~ ~JJ~ 'I " I '" 30:00 35:00 40:00 217.1956 8:4 F:2. 10m; 80-= 60-= 40...:: 2 o~ )JJ.J JMJwJ O=~ - I , , I I I , , , I ' 30:00 35:00 40:00 231.2111 S:4 F:2 1 0 CY!f 80-= 60~ - 40~ JJ~ ~ 20~~)J.J.\. 0-= I . I , , I I I , , I I ' 30:00 35:00 40:00 ,):-.I';.-."AI1'......, ----..-;rr.-~:-....Ð,.'... " .-~.... . __r --, ~ w - - Ut ~ _2.7E7 :..2.1E7 :"1.6E7 :"1.1E7 I I ' 45:00 - ~ ~:"5.4E6 ,) ~.. ^ - "It r \..J\.a.}\\ , J V ~ : 0 E 0 I I ' , , , 1 r , " O. 55:00 1:00:00 Time - / . 5 0 ~ 0 0' _2.6E7 :..2.1E7 :..1.6E7 45 ~ 00' I \ ~1.1E7 W JJ tJ /< 'I¡ \ .M ,/\1 """. "'^ ~ ~ 5 . 3E6 ~ O.OEO ' I ' .' , I ' J , , 1 ' , I , 50:00 55:00 1:00:00 Time _9.5E6 :"7.6E6 ::"S.7E6 ~~ ~ jIJ¡J ~. , ~3.8E6 ~:"1. 9E6 - 0 . OEO Time 45 ~ 00' , I ' 50:00 , I ' 55:00 , 1': 011 : 0'0 ' C) ~ n u ~ ~ ~ ~ o :¡ Z o tv -.J \0 Þyj oQ' ~ CD ~ W ~ -.J u; ~ File:MPDMI000112 #1-3086 Acq:10-DEC-1997 19:03:38 GC EI+ Voltage SIR 70SE Sample#S Text:FIORD-3 4740' $97110IL001S003$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 8:S F:2 100% & - 90~ 80-= /Í( -:J - 70-= 60-= - SO-= 40-= cJ ';1'\ o - 30-= () - r-;;" 0< 2 0...:: ,.. t. ( :: "1 A ~.,. 'ð~).. 1:~ ~~-",,-....Lvw- ~ J.A.L..Av'J_J1U J.Å.J LI~ ,~..~~ I I I I I I I I I I I I I I 1 I I I I 1 I I I 30:00 40:00 50:00 1:00:00 1:10:00 217.1956 S:5 F:2 100% 90-= - 80-= - 70-= - 60"': 50-= 40-= -\-'1- 10 'þJi'. 1.~ ~1 ~~ 1íoi'... 3'1 ,!>b \\ - 30: ~:1~JtL~~^,)~J\M ~ . I . . I I I . I I I I I . 30:00 40:00 50:00 .~J~__. 1:06:00' I 1 I 1:10:00 -~-- ----""':-,,_...-,,*,-...-j .i:.'_'\Ii ':>""'~-'~::::1 , ì ! _l.SE8 :"'1.4E8 :"1.2E8 - :"1.lE8 - =-9.1E7 :"'7.6E7 :"'6.1E7 - :"4 .6E7 / ~ :"3.0E7 - =-1.5E7 - ;. 0 . OEO Time _3.0E7 :"'2.7E7 - :"2.4E7 :"'2.1E? =-1.8E7 :"'1.5E? :"'1.·2E7 - :"'9.1E6 - :"'6.1E6 :"'3.OE6 :: 0 .OEO Time o ~ (1 ,tj ~ ..... ~ ,c .('Ð "0 o ;¡ Z o N -J \0 ÞOyj ¡ rjQ" ,.~ (1) W 00 File:MPDMI000112 #1-3086 Acq:10-DEC-199ï 19:03:38 GC EZ+ Voltage SIR 70SE Sample#5 Text:FIORD-3 4740; $97110IL001S003$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 8:5 F:2 10005 80...:: 60...:: 40...:: 20...:: ~~, 0-· 30:00 '40~00' 191.1799 8:5 F:2 10m- 80...:: 60...:: 40~ 20...:: o = ~~~..J-., - I , I I I ' 30:00 40:00 205.1956 8:5 F:2 1 0 0015 80...:: 60...:: 40...:: 20~~ o -I - I I I I I 30:00 40:00 J .'¥"'J") P;~"'~ :.ll~A -. \ '" "-WA< -'" '_', _VI _ '. ;J!!o.;.~, ~.'. ~ VI - ~ VI ~ . ......~.. .~.., ~-...,,;........~, . .~ I I I 50:00 I I I 50:00 I { , 1:00:00 1:10:00 ~~~f~~~ 1:00:00 i:10:00 L \L lJJJ..~ I I I 50:00 1:06:00 I 1 I 1:10:00 I f I 1:20:00 i:20:00 I 1 ' 1:20:00 _ 5.. OE7 =-4.0E7 =-3.0E7 =-2.0E7 :..1.0E7 - 0 .OEO Time / _1.SE8 :..1.2E8 :..9.1E7· :..6.1E7 :..3.0E7 - 0 . OED Time _2.3E7 :..1.9E7 :..1.4E7 =-9.4E6 =-4.7E6 - 0 . OEO Time C) ~ (j u ~ ..... ~ ~ ~ o ::¡ Z o N -..J \D ~ ûQ' Ei (!) w .þ. \0 ~ ~ Ut .þ. ___nn~,~~~··~! "'V~-"~~"--,,"-Y':''"v ....L"::~V'lI.;..~:UYc1'<i¡.?'~; File:MPDMIOOO'l12 #1-3086 Acq:10-DEC-1991 19:03:38 GC E1+ Voltage SIR 70SE Sample#5 Text:FIORD-3 4740' $97110IL001S003$ File Text:6000RP GCMS Exp:GCMS_HRS1R 218.2033 8:5 F:2 1000~ 80..: 60..: 40..: 20..: O-~ ..~~~ " 'I' I I ' 30:00 35:00 40:00 217.1956 8:5 F:2 1 0 OO~ 80..: 60..: 40..: 20~ _ M L. .. . ~_.Ak JuJ,~ o - r·_L.r~_PP~ , , , I I ' I I I I ' 30:00 35:00 40:00 231.2111 8:5 F:2 10005 80..: 60..: 40~ ~M ~.h/t~ 20..: 0- I 30:00 . I ' 35:00 40 ~ 00' ~ _3.2&7 :..2.6&7 ~ :..1.9E7 =-.1.3&7 , I · 45:00 'L lvvl~ · I' 'I 1 I I 55:00 1:00:00 :..6.4E6 ---;---O.OEO Time / . I I 50:00 _3.0E7 =-2.4E7 =-.1.8E7 45~Oo' =-1.2E7 "",,;M I ",.'MIAl, ,J.~~6.1E6 - 0 . OED I I I 1 I , I · , , I 1 ' ¡ I I 50:00 55:00 1:00:00 Time _8.2E6 =-6.6E6 - J~~ ~ ~~J~~}:~::: :..1.6E6 45 ~ 00' - o. OEO Time I I I 50:00 , I I 55:00 I I 1 I ¡ 1:00:00 --..: O.OEO Time :"'7.0E6 :"'5.3E6 :"3.5E6 :"1.8E6 :"1.6E7 :"1.4E7 :"1.2E7 :"1.1E7 :"8.8E6 _1.BE7 :"8.6E6 - - 0 . OEO Time :"1.7E7 :"5.2E7 :"'4.3E7 ':"3.5E7 :"'2.6E7 :"6.9E7 :"'6.1E7 _8.6E7 :"'7.8E7 .¡:.. ......... - - Ut .¡:.. --.....--.<-..."'-'~ -.~--- .- -ÞJt..:&~L4I>o._. " ; ',>(4:-:: -""!I"~~I'"."-:-_",",7_" .I.'I!:......L..-«.~ - .jO,l\f'\I! .. __ _ . ,-. ~:,.;..~. _t.~?l\1I\ '1', .1.\___ __J<..._ o 1:10:00' Þ-r1 ~. (1) w I 1 I 1:00:00 t( 60-': ZIA : rl~ 50~ ~ : 1fÞ.µ 40...: ~ _ J'f. ,.. : }~ 30": 20-' I II A" I \ ~~, ~ 1:1~.,.wl. ,^,~WJ.w\\MMI-Al~ A~, ,. .'.A, ~A~"... - I I I I I I I I I I I 30:00 40:00 50:00 '1"2. 70": 80": ,0 90": 30~ ~ : ~ v 20": r.; '" 0<, :: 1 1fA - lrt·'."L~ 1~1~~·~..M....,~~JwM lL".j J."vv-w..~ I I I I I I I I I I I , I I 1 I I I I 1 I I I 30:00 40:00 50:00 1:00:00 1:10:00 217.1956 S:6 F:2 1000: o rJ 50": 40-= Q 3:: () tJ ~ ~ ~ :::0 ~ o ::¡ Z o N ......... 1.0 \) 60-= ;($' 80": 70": 90": Fíle:MPDMI000712 #1-3087 Acq:10-DEC-1997 20:44:50 GC EI+ Voltage SIR 70SE Sarnple#6 Text:FIORD-3 6240' $97110IL001S004$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 S:6 F:2 10~ ~ ~ O. OEO Time =-.2.4E6 ~4.9E6 =-.7.3E6 ~9.8E6 _1.2E7 - 0 .OEO Time ~1.7E7 ~3.5E7 ~5.2E7 ~6.9E7 _8.6E7 O.OEO Time ~4.0E6 ~8.0E6 =-.1.2E7 =-.1.6E7 _2.0E7 40-= 20-= O=~~-L; I I I I I I 30:00 40:00 205.1956 S:6 F:2 10 O?c i:20:00 1:10:00 1:00:00 I 50:00 I 40:00 ~~ ~--- -LL~J~ I 1 I I I I 1 I I I I 1 I 1:00:00 1:10:00 1:20:00 I 50:00 0- 30:00 "rj úQ' ~ (I) w ~;..... oo~ - - V\ ~ 20-= 40-= 60-= 80-= 60-= 80-= i:20:00 150~00" 0- I I I I I I 30:00 40:00 191.1799 8:6 F:2 10005 1:10:00 I 1 ' 1:00:00 - J. 20-= 40-= 60-= C) ~ I~ , .... ~ :;d ~ o ::4- Z ~ tv -.) \D 80-= File:MPDMI000712 #1-3087 Acq:10-DEC-1997 20:44:50 GC EI+ Voltage SIR 70SE Sample#6 Text:FIORD-3 6240' $97110IL001S004$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 S:6 F:2 1 0 O?ií __-___-__-_-_1' -- File:MPDMI000712 #1-3087 Acq:l0-DEC-1997 20:44:50 GC EI+ voltage SIR 70SE Sample#6 Text:FIORD-3 6240' $97110IL001S004$ File Text:6000RP GCMS EXp:GCMS_HRSIR 218.2033 S:6 F:2 1000~ o s: () t:1 ~ .... ~ :;:0 ~ o ::¡ Z o N .......) \0 80-= 60-= 40-= 20-= ~ Jj GJLAAJ o -=.. .----^-, .,. , I' I I I 30:00 35:00 40:00 217.1956 S:6 F:2 1000~ 80-= 60-= 40-= - 20~ .. I. L ~...W ~ o - ,''--'~~ . , , , , I I I , I I I 30:00 35:00 40:00 231.2111 S:6 F:2 10~ 80-= 60-= Þ-r1 åQ' ~ (' ) w 40~ J}.~ ~ 20~. ~)Jv.M.¡ o-r-- I I , I I I I I I I I 30:00 35:00 40:00 ~ N ¡~~......~ ...,..~I.......~.~ .... __-.........,_ ................._.__.-~...Jt., _...._p_ ~ \0 - - tit ~ _l.BE? - :...1.4E7 - :...1.1E7 :...7.2E6 - :...3.6E6 'L.1\ù ~ , I' ,., 1 I , 55:00 1:00:00 - ;~-O.OEO Time I r ' 45:00 , I ' 50:00 W N"~ , I I 45:00 , I I 50:00 _1.SE7 - =-1.4E7 =-1.1E7 =-7.0E6 rVJ\I.M,~\ .¡,~3.5E6 O.OEO I IS S ~ 00' I 1 1': 0 b : 0' 0 I I I Time , I I 45:00 J I I SO:OO - -- _. -- _.-.A~ I I 1 55:00 _6.6E6 :...S.3E6 - =-4.0E6 M~' ~2.6E6 ~1.3E6 '1':00:0'0 ' - 0 . OEO Time C) ~ Q t1 ~ ~ ~ ::0 ~ o ~ Z o N -J \0 ÞTj ciQ' Ei (þ w V\ 0-< e W ...- V\ ~ ~~-----r-"'-. ~'f.ii---------' -~- ~~'W7 -----~~_...=-----~----~---.......:1J_,-~~ ~~~~- --..-..--........ ~"-/lllT~ .~..-----=-:-..~--~.J'"'7,.....~:i--i....~_~~~~ File:MPDMIOOO'l12 #1-308'l Acq:l0-DEC-199"' 22:2~:~8 GC EI+ Voltage SIR 10SE Sample#7 Text:FIORD-3 6600' $97110IL001S005$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 S:7 F:2 1000: 90": 8 0": 7 0": - 6 0-': 5 0": 4 0": 3 0": 20": - 10": O:_~ 30:00 217.1956 10~ S,:7 F:2 90": 80": 70':: 60": - 50": 40": 3 0": - 2 0": 10": o~~ -.." I I 30:00 A. _ . I - ~ I I I 40:00 tt:' ~ ..1 /(l'\ () J ( ~¿c.""f~ 'I. ,. R -.>" 0< h ,.. 0:. . I t ~ \ J _~.. . ~~J.l"Jv,~ -h~J.J..Jt.lM. ~ I I I I I I I 1 I I I I 1 I I I 50:00 1:00:00 1:10:00 :it- \f2.- tS '11" 10 ,¡\ø 1.1 11 II 1Î J Vv-lJ ~/,\ J \ ~¡\IJA,~_ 50~00 l:Oð:OO 1:1ð:OO I r I 40:00 _2.5E8 - :"2.2E8 :"2.0E8 ::'1.7B8 - ::'1.5E8 :"1.2E8 - :"9.8E7 - ~7.4E7 i ::'4.9E7 - :"2.5E7 : 0 . OEO Time _2.8E7 :"2.5E7 :"2.2E7 - :"1.9E7 ::'1.1E7 - :"1.4E7 ::'1.lE7 - ::'8.3E6 - ::'5.5E6 :"2.8E6 - : 0 . OEO Time Q ~ () tJ ~ ~ ':::0 CD . ."0 '0 ::\. Z o ...~ \0 'Tj ¡ ~. (J) w ..þ. File:MPDMI000712 '#1-30e", Acq:l0-DEC-1991 22:25:58 GC EI+ Voltage SIR 70SE 5arnple#7 Text:FIORD-3 6600' $97110IL0018005$ File Text:6000RP GCMS EXp:GCMS_HRSIR 177.1643 8:7 F:2 100'& eo: 60: 40: 20: 0...::., I . I . I I 30:00 40:00 191.1799 5:7 F:2 10~ 80: 60-= 40-= 20~ o ~ ..o--~ ",- ( I' r . 30:00 40:00 205.1956 8:7 F:2 100% 80.':: 60-.:: 40: 20-= 0...::.. 30:00 I 40:00 ~~J¡~2!"'t\· "~~".>.......)~",-. ~. ..~.""".~_.",.;..._.._~"",,-__, . . U\ - - - U\ ~ . . ' 50:00 "'- ~~&.._. i : 00': 00 I . i : 10 : 0 o' - i : 20 : 0 Ò .... f .- - 0 . 0 :~me / . .,---L;-- - _~~"'-'--A.""--""'~_ '50~00' I I i:ob:oò I I i:1b:oò I b I 1: 2 : 00 _____ '__ _ ~tL ù ~_._ _ I ' b I I b I 50:00 1:0 :00 1:1 :00 i:20:00 _G.GE? - :..S.3E7 :..4.0E7 :..2.6E7 :..1.3E7 _2.5E8 :..2.0E8 - :..1.5E8 :..9.8E7 :..4..9E7 - o. OEO Time _6.8E7 - :..5.4E7 :..4.1E7 :..2.7E7 :..1.4E7 - 0 .OEO Time C) 3: () ~ ~ þ) ~ ~ o ::¡ Z o N -1 \C) t-r1 åQ' E; VI fi) tv w - ....... ..-. VI V\ .J:o. V""- - - ~~a~~ ~='¡-"""""""'-'-¡/1-~~~~~~ File:MPDMI000712 #1-3087 Acq:10-DEC-1997 22:25:58 GC EI+ Voltage SIR 70S& Sample#7 Text:FIORD-3 6600' $97110IL001S005$ File Text:6000RP GCMS Exp:GCMS_HRSIR 218.2033 8:7 F:2 10 00:£ _1.2E7 80...:: 60...:: =-9.4E6 =-7.0&6 40...:: =-4.7E6 I .II..! hi ~ I J J ~ 2 . 3 E 6 ~W,~·~ "I. ~~ , O.OEO 150'~00'- .. T 55~ oö" 1 r 11: 06: 0'0 r r' Time 20...:: O-~ ,,, ~ 1 . , 'I I·' " I . r I J . 1 30:00 35:00 40:00 217.1956 8:7 F:2 1 0 001] . - "' I' J - , 45:00 _2.8&7 80...:: =-2.2E7 60...:: =-1.7E7 40...:: =-1.1E7 JJ J....~ \~~~j J~5.5E6 ~ O.OEO I l' I 1 I , I 1 , I I b I I' 1 1 50:00 55:00 1:0 :00 Time 20...:: O:~ - 1 I I I ' 30:00 35:00 231.2111 8:7 F:2 10~ I J ' 40:00 I I I 45:00 _8.9E6 80...:: =-7.2E6 60...:: =-5.4E6 40...:: \ ~ IA) ~ J!I/ ~. ~ A. t: :::: 1V\.....v ~ V. ~ - 0 . OEO Time 20...:: 0- I 30:00 I I ' 55:00 I I ' 45:00 I I 1 50:00 I , b 1 , 1: 0 : 00 1 I I 35:00 I I 1 40:00 File:MPDMIOOO",12 #1-308', Acc,¡:11-DEC-199ï 00:0",:06 GC EI+ Voltage SIR "lOSE Sample#S Text:FIORD-3 6750' $97110IL015S006$ File Text:6000RP GCMS EXp:GCMS_HRSIR 191.1799 8:8 F:2 1 0 O'!f if C) ~ n tj ~ ~ ~ .(t) "'0 .0 ;¡ Z o N -J -'"\0 - 90"': 80"': - 70"': - 60"': 50"': - 40"': 30"': 20"': - 10"': - O~J - .A. 30:00 217.1956 5:8 F:2 10001í . - 90"': - 80_: 7 0_= 60"': - 50-= 4 0"': 30"': 20"': y tJ o ~ "i~ z."'Df~ cJ ¡({ .U I I I 40:00 /,1'\ K ~ ~ ~ 4" Pt , . (2. þ ~' ~. . ~~~ llJ..w·~.",-lLuJ~~ I I I I 1 I I 1 ,I 50:00 1:00:00 1:10:00 ,.. '2-' f\ .~ \\ 4-'2- '\.1 ~') flPt¡1 l' '~11b V I I', A t ^NJ 'v~,.,. --, --- , ,~ :åQ' E; (\) w - 10~ ~ o:~ - , I I I I I 30:00 40:00 0\ ~.~~~~- ..--..-.-'..- . .....-- w - - Ut +:>- 150~00' 1.:06:00 1:16:00 _1.9E8 :"1.7E8 :"1.5E8 :"'1.4E8 :"'1.2E8 :"'9.7E7 - :"'7.7E7 - :"'5.8E7 ¡_ - ~3.9E7 :"1.9E7 - ;. 0 .OEO Time _2.6E7 - :"'2.3E7 :"'2.0E7 :"1.8E7 :"'1.5E7 :"'1.3E7 :"'1.0E7 - :"7.7E6 :"5.1E6 :"'2.6E6 - .: 0 .OEO Time v ~ ~ ~ ~ o :4 Z o N -J \0 '"rj ciQ' F::i Ut (t) +:0- W;:::; I--' Ut -.:¡+:O- C) ~ () File:MPDMI000712 #1-3087 Acq:11-DEC-1997 00:07:06 GC EI+ voltage SIR 70SE Sample#8 Text:FIORD-3 6750' $97110IL001S006$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 5:8 F:2 10 OO::é 80...:: 60...:: 40...:: 20...:: o _,L.I" _ þ _L._' . ". - I 30:00 191.1799 8:8 F:2 10~ 80~ 60...:: 40~ 20...:: I 40:00 0-. ~ L.J "I " 1 I I I 30:00 40:00 205.1956 5:8 F:2 1 0 OO::é 80~ 60~ 40...:: 20...:: o --=- f 30:00 I 40:00 ~>.,.,¡~.... '-J. L_ I 50:00 I 1 I 1:00:00 I b I 1: 1 : 00 '-'. . ~J.L.L.,.L~, 50~00 I" i:ob:o¿ i:lb:06 ~l~__. I I I 50:00 1 1 1 1:00:00 i:1b:o¿ I b I 1: 2 : 00 " - I 1 b· I 1: 2 : 00 I b I 1: 2 : 00 --.- "if- ---' -.. .-:----~-'""~r-~'f _3~9E7 :...3.1E7 :...2.3E7 :...1.6E7 :...7.8E6 I - 0 .OEO Time _1.9E8 :::...1.5E8 :::...1.2E8 :::...7.7E7 :::...3.9E7 - 0 . OEO Time _2.8E7 =..2.2E7 :...1.7E7- =..1.1E7 :...5.5Et) - 0 .OEO Time - 0 . OEO Time 1":ob:o'o · I I I 55:00 . I · 50:00 1 I · 45:00 I I I 40:00 I I I 35:00 o - - I 30:00 \ I 'W I Ih ~5.6E6 ~ w,J · ~ / 'I.¡ J'V' '" 'AI. I. -:. . ~3 . BE6 v 1J1I1."J~1. 9E6 20--= =-7.5E6 _9.4E6 ~.. J :..1.OE7 \ JIfI ~/\ .,¡t~~5.1E6 - 0 . OEO ' I 1 1 I . I . 1:00:00 Time . I I 55:00 I I I 50:00 I I I 45:00 I I I 40:00 2 O_~ ~ ~.tI'.I rv.J¡ :..1.5E7 :..2.0E7 _2.6E7 40-.:. 60-.:. 80--= o - --- , I I I I I 30:00 35:00 231.2111 S:8 F:2 100~ 40--= 60--= 80-.:. =-5.8E6 ! : -2.9E6 J~, "^~J~O.OEO · · · I Time · I 1 0 / . 1:00:0 20-=: o-~ - - A I 30:00' · I I ~~ 217.1956 35:00"" I 100"-. S:8 F:2 40:00 '55 ~ 00' I I I 50:00 I I · 45:00 vJ~h v'»I :..8.7E6 :...1.2E7 _1.4E7 40--= 60--= 80--= File:MPDMI000712 #1-3087 Acq:l1-DEC-1997 00:07:06 GC EI+ Voltage SIR ïOSE Sample#8 Text:FIORD-3 6750' $97110ILOOlS006$ File Text:6000RP GCMS EXp:GCMS_HRSIR 218.2033 S:8 F:2 1000; u-. u-. - 1--'0 u-. ~ ..: ~-A').A-:.'~_..~V.r"".'I" .~_, .-.. 00 Þ-r1 Qq' ~ w o ~ n tj ~ þJ Id (Ð "0. o .::¡ Z o N -J \0 _3.7E8 - - :"3.3E8 - - :"2.9E8 - - :"2.6E8 - - :"2.2E8 - - :"1.8E8 - - :"1.5E8 - - :"1.1E8 / - - :"7.4E7 - - ~3.7E7 - - L : 0 . OED Time _4.8E7 - - :"4.3E7 - - :"3.9E7 - - :"3.4E7 - - :"2.9E7 - - :"2.4E7 - - :"1.9E7 - - :"1.4E7 - - :"9.7E6 - - :"4.8E6 - - - 0 . OEO Time l I 1 I 1:10:00 I 1 I 1:00:00 I~·I 1" j ~ ' . "'\~~ q°ut J'I J'ý 1b I(.J..- '}~ 2-1 )~ 30~ 1 20~ _ _ ~ ~ l~i~JLLL~l/Jf' I I I I I I I I I I I 30:00 40:00 50:00 40-= Il 80-= 70-= 60~ 50--= þf'. 90--= \0 10-= O_=- J--.--Á I 30:00 217.1956 S:9 F:2 1000: "Í <'\ t.> <... \<" 0< P -(It - IZ ~ ç _ 1> ;i· ,¡ I ~ï~;y-7: 1., - ~~~ ~J.t.1J.v..I ~\J~~ I I I I I I 1 I I I I 1 I I I 50:00 1:00:00 1:10:00 o ~ ð~~'v.°f~~"" cJ 'Y ~~ ~ . .LJ I I I 40:00 1 .." I 40":: 3 0": 2 0": 5 0--= 70-= 60-= 9 0--= 80-= File:MPDMI000712 #1-3086 Acq:11-DEC-1997 09:05:10 GC EI+ Voltage SIR 70SE Sample#9 Text:FIORD-3 6770' $97110IL001S007$ File Text:6000RP GCMS EXp:GCMS_HRSIR 191.1799 S:9 F:2 10~~ ~ ÞOyj åQ" ~ V1 (1) 0'\ w ;::: :-. V1 \0 ~ o ~ n Ö ~ ~ :::0 ~ o :¡ Z o N .......) \0 - 0 .OEO Time :...1.2E7 :...2.3E7 :...3.SE7 :...4.7E7 _S.8E7 - - 0 . OEO Time :"'7.4E7 :...1.5EB :...2.2EB :..2.9E8 _3.7EB - 0 .OEO Time / :...1.8E7 :...3 .7E7 :...S.5E7 :...7.4E7 _9.2E7 Ut -..J - - Ut ~ ~ - J"- -\:111'-- -~" "J.1:I¡o.'t!!'II...",..,~_~.,,_._,,_~""'_"__"___..A .,.J¡ .--1. , 1 ' 1:20:00 i b t 1:16:00 1 I 1:00:00 '50~00' '40~00' O~J 30:00 _,,~lL ~~.. _ ..L--...- 20..: 40--= 60--= 80--= , 1 I 1:20:00 o --=--1 - - A 1 - - . . L1 1 I , 1 I 1 30:00 40:00 205.1956 8:9 F:2 10~ ~~JlL,vL~ 1 1 - I I ,.. I' - -, 1 1 I · , 1· . , 50:00 1:00:00 1:10:00 20--= 40--= 60_= 80--= 1:26:00 o - - , 1 , 1 I ' 30:00 40:00 191.1799 8:9 F:2 10~ C) ~ n Ö '~ r-+ ~ :þO ~ o ::¡ Z o tv -..J \0 · 1 I 1:10:00 I 1 ' 1:00:00 I 50:00 4.~ . _ 20--= 40--= File:MPDMI000712 #1-3086 Acq:11-DEC-1997 09:05:10 GC EI+ Voltage SIR 70SE Sample#9 Text:FIORD-3 6770' $97110IL0018007$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 8:9 F:2 1 0 O'!t 80...:: 60--= 40~ 20-.:. 0-= , r I , I I 30:00 35:00 231.2111 S:9 F:2 1 0 0":1í 80-.:. 60-= 40~ 20~ ~ ~. o - I (I) Ut 30:00 '35 ~ 00' 00 VJ _ . I--" NUt i-".þ. Q ~ () U ~ ~ ~ ~ o :4 Z o tv .....J \0 File:MPDMI000112 #1-3086 Acq:11-DEC-1997 09:05:10 GC EI+ Voltage SIR 70SE Sample#9 Text:FIORD-3 6770' $97110IL001S007$ File Text:6000RP GCMS Exp:GCMS_HRSIR 218.2033 8:9 F:2 10 OO:1í _2.9E7 ::..2.3E7 80~ ::..1.7E7 60~ ::..1.2E7 40~ t ~\r~ , J ,,~ "^--'Ij ~ ~5. 8E6 ~ O.OEO I I 1 I I I I 1:00:00 Time I 20-.:: o-~ ~-~~ I' I I I 'I' 30:00 35:00 40:00 217.1956 5:9 F:2 10~ I I I 55:00 , I ' ·45: 00 I I I 50:00 _4.8E7 ::..3.9E7 80~ ::..2.9E7 60-.:: VvA"v·~J~\.M t~, .þ~~::::: - O. OEO Time 1 I ' 40:00 , I ' 45:00 , I 1 50:00 I I ' 55:00 , 11:06:00 I _1.7E7 J...v./ -=-.1.4E7 J ~ ::..1.OE7 '.' '1/ W, .- I I 6 tV ùV "\I ~ ~ 7 .OE k3.5E6 , I I 40:00 I I ' 45:00 1 I I 50:00 I I 1 55:00 , 11:00:0'0 1 - 0 .OEO Time :"6.7E6 :"4.5£6 :"2.2E6 .: 0 .OEO Time :"9.0E6 :"1.3E7 :"1.1£7 :"1.8E7 :"1.6£7 _2.2£7 :"2.0£7 :"2.2£7 ~: o. OEO Time :"4.3E7 =- 6 . 5E7 / :"1.5E8 :"1.3E8 :"1.1E8 :"8.6E7 :"1.7E8 _2.2E8 :"1.9E8 1:10:00 1:00:00 .J'J~, , ,,; W'}b t ~ -h "LÎ~!> 11 "2-\~ 4J.. V. \0 - - v. ~ ,.;~~....».. _,. ,.. ._P..... .. __ . )t,. _." _. ., J,. ~ I I I 50:00 ~ ùQ' :~ \fÐ W N N 10": All o~~.J~J - I I I I I I 30:00 40:00 \ ,}JiJ . 30": 20": 40": 50": 1\ 9 0": 80": 7 0": 60": \0 o ~t---A---J. A . L-.J. I I I I I I 30:00 40:00 217.1956 S:10 F:2 10~ A ~ 0<. ~ ieX' t\'~ ~ ~ ~ f., . ~~ ~'--v^"M.- ¡J.."",.Jl,..__Jk,",~ I I 50~00 f.. 1:00:00' I I 1:10:0'0' · I v .J .-{ { tJ (!e.v-- '-6 ~. f ~ ~ "'" -v 30--= 2 0-': 10": 90": 8 0": 7 0": 60-= 50": 40": Q s:: n tj ~ .~ ..~ '(1) :~ o ::4- Z o N -J \0 File:MPDMIOOOï12 #1-30à7 Acq:11-DEC-1997 10:46:21 GC EI+ Voltage SIR ·70SE Sample#10 Text:FIORD-3 7020' $97110IL001S008$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 8:10 F:2 100% ~ "Tj òQ' e¡ ~ (1) - ....... w Ut N ~ w Q a:: () t1 Þ-' .... Þ-' ~ ~ o ::¡ Z o N ......) \0 File:MPDMIOOO"/12 #1-3087 Acq:11-DEC-199'" 10:46:2", GC EI+ Voltage SIR 70S2 Sample#10 Text:FIORD-3 7020' $97110IL001S008$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 8:10 F:2 10 a!tí 80..:: 60..:: 40..:: 20..:: O"::r ..J...._._ . .-~ .- - - - I J I 30:00 40:00 191.1799 8:10 F:2 10~ 80..:: 60..:: 40..:: 20..:: 0..:: , _ '-----" I I I 30:00 40:00 205.1956 8:10 F:2 10 001i 80..:: 60..:: 40..:: 20..:: O"::r 30:00 . - ... .. -. I ,J I 40:00 I I I 50:00 I..I..~-, i:06:00 i:10:00 -J _ - ~~~...~.l~ I I J I I I I 1 - I I I I" 1 I I I 50:00 1:00:00 1:10:00 _.~J.L~~__ i:06:00 1:10:00 J 50:00 I 1 I 1:20:00 I b I 1: 2 : 00 i:20:00 - .- " -~T" .--....-...."'r----------y ---~ ~4.7E7 :..3.827 - :..2.8E7 :..1.927 - :..9.5E6 - .- O.OEO Time / - _2.2E8 :..1.7E8 - :..1.3E8 =-8.6E7 - :..4-.3E7 - - O. OEO Time _3 .7E7 - :..3.0E7 :..2.2E7 :..1.5E7 =-7.4E~ - O. OEO Time o ~ (j 'tJ ~ ~ þd ~ o ::4- Z o .N , -.J \0 ~ ~. (tþ w N .þ. \ 0'\ ....... - ....... Vt ~ File:MPDMI000712 #1-3087 Acq:11-DEC-1997 10:46:27 GC EI+ Voltage SIR 70SE Sample#10 Text:FIORD-3 7020' $97110ILOOIS008$ File Text:6000RP GCMS Exp:GCMS_HRSIR "218.2033 5:10 F:2 1000x 80..:: 60..:: 40..:: 20..:: o-~- ~ " I I' 'I' 30:00 35:00 40:00 217.1956 8:10 F:2 10ms I I ' 45:00 80..:: 60..:: 40..:: 20..:: o=~, ,'. , I ' 30:00 35:00 231.2111 5:10 F:2 10001':. _1.4E7 - :..1.1E7 - :..8.3E6 :"S.SE6 I Jlrt. AI. ¡ v! Pu 'J)Î l"\'Ju. ~2 .BE6 ~IIJ'VVV ~ o. OEO , I I I I' "1 I . . . 50:00 55:00 1:00:00 Time / " _2.2E7 :..1.8E7 - :..1.3E7 :..9.0E6 '\IV Jl'V '50 ~ 00' 1\)) ~ I. ~ ~,A J.Vl ;4.SE6 ~:O.OEO · 1': 00: 0'0' 'I Time . I ' 45:00 . I I 55:00 40 ~ 00' 80..:: 60..:: 40..:: 20..:: 0..:: I 30:00 . I · 35:00 . I · 40:00 45~Oo' _1.0E7 - :..8.2£6 ^ ~ ~\ ~ \t\¡~~~ "..v~~ - :..6.1£6 :..4.1£6 ~~~~2.0E6 - O. OEO Time , I · 50:00 , I · 55:00 I 1':00:0'0 I ;:. O. OEO Time =-8.3E6 =-5.5E6 =-2.8E6 =-1.7E7 ':-1.4E7 =-1.1E7 =-2.5E7 =-2.2E7 =-1.9E7 _2.8E7 =-1.6E7 =-8.1E6 - 0 .OEO Time :"2.4E7 ¡ . =-5.7E7 =-4.9E7 =-4.1E7 .- =-3.2E7 :"6.5E7 :"7.3E7 _8.1E7 -TI ..-~- 'i-~-_··"_'-A\i.''f--'''~'' : ~ ~¡J~JA¡JAk~~ÁW' ~r\ ¡J.~ n\J~~~. I I I · I I I I I I I I I · 1 I · I I 1 I 30:00 40:00 50:00 1:00:00 1:10:00 I 1 I 1:10:00 K: f y. ~~ II ) ~ ; I l I IA ,JJel.. .\ JIv.J I 1 '\)V... v,^, '0 ~ I ~ .;: 0 , ~ µ þ ù ~'fl \I 50'-: 40~ or:; \() 60~ ~ 80":: 70'-: Ita.. 90'-: 20": \ l:]~~~~~Jl~.<uJ1 I · I I I I I · · I I · · · 1 . 30:00 40:00 50:00 1:00:00 217.1956 8:11 F:2 100% ....s .... .... t ~ "< ~ 1,... .{) 30": ~ . 60~ 50-': 40~ ¡ ~ 70": 80~ File:MPDMIOOOï12 #1-3086 Acq:11-DEC-1997 14:07:14 GC EI+ Voltage SIR "JOSE Sample#!1 Text:FIORD-3A 4800' $97110IL001S009$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 8:11 F:2 10œa: 90~ if 4 ~ åQ' E; 0'\ (J) tv +::-~ ;""'<t. C) ~ n ~ þ) iJ ::0 ~ o :4- Z o tv -1 \C) o ~ n tj ~ ..... ~ ~ .~ o .::4- Z o ·tv .......) \0 Þ-r1 òQ' ~ (t ...þ.. tv File:MPDMI000712 #1-3Ò86 Acq:11-DEC-1997 14:07:14 GC EI+ Voltage SIR 70SE Sample#11 Text:FIORD-3A 4800' $97110IL001S009$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 S:11 F:2 100%5 80...:: 60...:: 40...:: 20...:: 0...::. I I J 30:00 40:00 191.1799 S:11 F:2 10<r~ I I I 50:00 80...:: 60...:: 40...:: JJ~~J~~. i:ob:oo i:1b:oo i:2b:oo 2:~~~~~~.1JJJJtJ.~:l~ - I J I J I I I I I I I I I I 1 I I I I 1 I I I 30:00 40:00 50:00 1:00:00·· 1:10:00 205.1956 8:11 F:2 100~ 80...:: 60...:: 40...:: 20...:: 0...:: 30:00 I I I 40:00 I I I 50:00 ,!"ß'4\-',I!:· ,_~.s,;~._y,. .,..' .w ~__,..__ 0'\ W - - Ut ...þ.. '^'-....I...~~ - .___ I 1 I I 1 I 1:00:00 1:10:00 I 1 I 1:20:00 I 1 I 1:20:00 _2.4E1 ::..1.9E7 =-1.5E1 ::..9.7E6 - ::..4.8E6 -: 0 .OEO Time / _8.1E7 ::..6.5E7 ::..4.9E7 ::..3.2E7 ::..1.6E7 - 0 . OEO Time _2.8E7 ::..2.2E7 ::..1.7E7 ::..1.1E1 - ::..5.5E6 - O. OEO Time C) ~ () u ~ ~ ~ ~ ~ o ~ Z o N -J \0 "Tj åQ' ~ o ;Þ- l.H ~ - I--" Ut .¡:.. ~ ~--_.~ -,.r-r- --...-~ File:MPDMI000712 #1-3086 Acq:l1-DEC-1997 14:07:14 GC EI+ Voltage SIR 70SB Sample#11 Text:FIORD-3A 4800' $97110IL001S009$ File Text:6000RP GCMS Exp:GCMS_HR8IR 218.2033 8:11 F:2 10~ 80..:: 60..:: 40..:: 20..:: O=r---^- ~Jj~ " 'I' I I ' 30:00 35:00 40:00 217.1956 8:11 F:2 10~ 80..:: 60...:: 40..:: 20..:: n II I 1..A. r o = ~J~ 'W\J'lWVW , I , I I ' I I , I . 30:00 35:00 40:00 231.2111 8:11 F:2 1 0 00:11 80...:: 60..:: 40..:: 20~ ~~.^^ oi~ , , , , I ' I , , I ' 30:00 35:00 40:00 _2.5E7 - =-2.0E7 =-1.5E7 =-9.9B6 , I ' 45:00 AI =-5. OE6 I'V~ JuA M~V~= O.OEO , I ' I , , 1 '.' · · 55:00 1:00:00 Time / - , I · 50:00 _2.8E7 =-2.2E7 =-1.7E7 I =-1.1E7 f 1 : wJJlÂ;' 'It W i\1j J.~ ~5.5E6 ~ O.OEO , I 1 ' , 1:00:00 Time '45 ~ 00' '50 ~ 00' , I ' 55:00 _1.3E7 - =-1.1E7 - =-8.0E6 =-5.3E6 W2.7E6 - o. OEO Time ~ ~~JtvJ I\J~- 45 ~ 00' '50 ~ 00' , I ' 55:00 , I 1 I , 1:00:00 _3.8E7 =-3.4£7 :"3.1E7 =-2.7E7 :"2.3E7 :"1.9E7 :"1.5E7 :"1.1£7 :"7.6E6 :"3.8£6 : 0 . OEO Time :"9.3E7 :"8.1E7 :"7.0£7 :"5.8£7 :"'4.6E7 :"'3.5E7 :"2.3E7 :"1.2£7 : o. OED Time _1.2E8 :"1.0E8 ....- - ..~ , ~~ II I .0} ^" ~. , 1 I , , I 1 I 1:00:00 1:10:00 60-': 50-': 40-': 30-': ~:I..1. . i,AJ L'Jw~^~."ì o _ r·...,."'------- . , , , , J ' , , , J ' 30:00 40:00 50:00 Tt' tf~1 ">1 .,~ '~1 "':t1 10 70-': " 80"': ,J 90-': ~1.- 80-': 70':' 60-= 50':' 40-': 30"': 201 ~ ~b PI" t(. .J" : .J 1111 · 1.1{.n 1~ tX~ 1:1 ~~~,....y\.......~...j)lurt¡) J,.J"..j 1Jl,~, ~ I I I I I I I , , I I I 1 ' J I I 1 I I 30:00 40:00 50:00 1:0'0:00 1:10:00 217.1956 8:12 F:2 1 0 (Y'~ ID /,'M ~ .....,~ fT1 f,( 2$ NO("'of~· o ,.J J) If"~ File:MPDMIOOO'/12 #1-30ê6 Acg:11-DEC-199ï 1~:48:31 GC EI+ Voltage SIR 10SB Sample#12 Text:FIORD-3A 8010' $97110IL001S0I0$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 8:12 F:2 1 0 O'!f if 90':' ---, 0\ Ut - - Ut ~ "Tj òQ' Ei (1 ~ ~ / --, Q ~ () tJ ~ .... ~ ~ ~ o ::¡ Z o N -J \0 - 0 .OEO Time :..3.5E6 :..7.1E6 :..1.1E7 :..1.4E7 _1.8E7 .- 0 .OEO Time :..2.3E7 :..4.6E7 =-7.0E7 :..9.3E7 _1.2E8 - 0 .OEO Time :=-6.2E6 :..1.2E7 :..1.9E7 :..2.5E7 _3.1E7 ~, -, I 1 I 1:20:00 I 1 I 1:20:00 I b I 1:2 :00 -l ~1Jo\}.,~ -.'H _ I 1 I I I i:10:0Ò l;Ou;OO I 1 I 1:10:00 1:10:00 150~00" I J I 40:00 0-= 30:00 20~ 40-= 60~ 80~ ~vl~ I 1 I 1:00:00 40-= 20~~ - """"- 0...:.. . I I I J I I 30:00 40:00 205.1956 8:12 F:2 10005 I I I 50:00 I 1 I 1:00:00 I f I 50:00 ~.. - I I Y. r J '~,,"JÅJv.J '\t~ '"V~ 80-= 60-= 20-= o - I I I I f I 30:00 40:00 191.1799 8:12 F:2 10005 40-= 80-= 60-= File:MPDMI000712 #1-3086 Acq:11-DEC-1997 15:48:31 GC E1+ Voltage SIR 70SE Sample#12 Text:FIORD-3A 8010' $97110IL001SOIO$ File Text:6000RP GCMS - Exp:GCMS_HRSIR 177.1643 8:12 F:2 10~ -¡. .. l' .. _'1 ¡>;. t,) ÞOrj ~. !-"CD Vt..J::>. ~. V\ / CJ ~ n H ~ ..... ~ ,c ~ :0 '::¡' Z o N .....,J \0 ~..,~À-~·_~r...,~"l. :...;...l'~"~_"'~-=-=7"" .~tlJM -..J - - Ut ~ ..;" l :.7.6E6 M - 5. 1E6 J ~JI~ "'" \ 10. ~L .5E6 - 0 .OEO , 1': 00 : 0'0' " Time I I ' 55:00 50 ~ DO' I I I 45:00 , I I 40:00 , I I 35:00 o - - I 30:00 40...: 20~~~J,J~ 60...: :.1.0E7 80...: _1.3E7 20~ ' ~\~ O:~ , , I , I I , , I I ' 30:00 35:00 40:00 231.2111 S:12 F:2 10ms I J' :.1.5E7 I - v.. ,¡i) /îJ} \ ~ ~ ~. "^ ~ 7 · 6E6 O.OEO I ' , , I I I I I , 1 I , , , 50:00 55:00 1:00:00 Time 45 ~ 00' 40...: :.3.1E7 :.2.3E7 60...: 80...: _3.8E7 20- o~~ --,.~~.~ 30: 00' , , '35 I ' , , , .00 I ' 217.1956 S:12 F.2 40:00 10m: . :..9.2E6 ~~ J~ A~l~, d A ~4.6E6 ~U~_ O.OEO , I I I I I I I , , , 1 I , I , 50:00 55:00 ,1:00:00 Time I I I 45:00 60...: 40...: :..1.4E7 :..1.8E7 80...: _2.3E7 File:MPDMI000712 #1-3086 Acq:l1-DEC-1997 1~:48:31 GC EI+ Voltage SIR 70SE Sample#12 Text:FIORD-3A 8010' $97110IL001S010$ File Text:6000RP'GCMS' Exp:GCMS_HRSIR 218.2033 8:12 F:2 10mti ;Þ-rj iåQ' ~ t1I ..þ.. 0\ / Q ~ n t:J ~ Ø,) þd .g o ::¡ Z o tv -..J \0 : 0 .OEO Time =-1.2E7 =-9.2E6 =-6.9E6 =-4.6E6 - =-2 . 3E6 .- =-1.4E7 =-1.6E7 =-1.8E7 _2.3E7 =-2.127 =-7.9E6 : 0 .OEO Time =-1.6E7 =-2.427 / _ :"3.227 =-3.927 =-5.527 =-4.727 =-6.327 =-7.127 _7.9E7 .._''OP-.-,,_,...-.....~ 30": 2 0 :: /Í~ A- - ~ J" :: I I '{ n I QIZ- o(P - 10~ ~~..J.....~~~I'I-l~ J,.~w\ ¡ -11 j~~1 £-..'L 0= ~..~ - I I I I I I I I I I I I I I 1 I I J I I I I I 30:00 40:00' 50:00 1:00:00 1:10:00 217.1956 8:13 F:2 1 0 00:: I 6 J 1:1 :00 ~ .....Ië lîj roc- '.25 rJÞr,^oe~- "' 0 SE Exp:GCMS_HRSIR l t .;\ ~'^-~ l:OO:OÒ 30"-: 20~ II I. . d I. , 1~~~,~ .JMw~A~, I I I I I I I I I I I 30:00 40:00 50:00 t }f- .p \4\ 1\ 90": - - 80": '" - - 70-':' - - 6 0--= - - 50"-: - - 40"-: - "!¡'\ 1~ .., ~< ¡'I~ 't'1- to )( ..-'\'" 40-':' o ,..1 ']) tfç 80": 7 0": 6 0": 5 0": File:MPDMIOOO"12 #1-3086 Acq:11-D2C-199"' 1"[:29 :4", GC EI+ Voltage SIR Sample#13 Text:FIORD-3A 8100' $97110IL001S011$ File Text:6000RP GCMS 191.1799 8:13 F:2 10005 ff 90-':' "Tj 0\ ~. 00(1) ~..¡:.. U't . ,þ.---.J Q ~ () t:1 \~ ~ ~ ~ o ::¡ Z o 'N -.J -\0 ::..4_.8E6 ::..2.4E6 - O. OEO Time ::..7.2E6 ::..9.6E6 _1.2£7 - 0 .OEO Time ::..1.6E7 ::..3.2£7 ::..4.7£7 ::..6.3£7 _7.9£7 :..3.9E6 - 0 .OEO Time / __7.8E6 ::..1.2£7 __1.6E7 _1.927 i:20:00 I 1 I 1:20:00 1:20:00 0'\ \0 - ...... VI ~ .tf'Þ.f:\~-...,q.... "._:Go\)- ~._.... -. I 50:00 o-=: 30:00 I I I 40:00 ~ l \JJv.I.~. . _ I 1 I I I 1:10:00 1:00:00 40-= 20-=: 60-= 80-= , 50:00 20~~ - L....J....., 0-= 30:00' I I '40~00' 205.1956 8:13 F:2 100~ .1 ~'-.T ~\AL"'.",--" , 1:10:00 1:00:00 4 0-= 60-= 80-= 0- - I I I I , I 30:00 40:00 191.1799 8:13 F:2 10~ ~~-J~.Jl\J~ I I I I 1 b f I I f b I 50:00 1:0 :00 1:1 :00 1- 40-= 20-=: w 60-= 80-= File:MPDMI000112 #1-30"86 Acq:11-D£C-1991 11:29:41 GC EI+ Voltage SIR 70SE 8ample#13 Text:FIORD-3A 8100' $97110IL001SOll$ File Text:6000RP GCMS - Exp:GCMS_HRSIR 177.1643 8:13 F:2 100% >-r1 äQ' E; (1) f:>- 00 ;0 ¡~ \(1 !t;1 ~ ~ ~ ~ '0 1;4 Z o tv -.) \0 Q ~ n k7 ..... ~ :::c (t) ;~ o ::¡ Z o oN .-.....) . \0 ; . t-rj' ð ~. ;:: (t) Ut ..þ. .þ. \D ----------~- \ - ------------------ File:MPDM1000712 #1-3086 Acq:11-DEC-199ï 1ï:29:47 GC &1+ voltage SIR 'lOSE Sample#13 Text:FIORD-3A 8100' $97110IL001S011$ File Text:6000RP GCMS . Exp:GCMS_HR8IR 218.2033 8:13 F:2 10œ 80...-: 60...-: 40...-: 20...-: o:~ - -,,0~~~ 30:00 35:00 40:00 217.1956 8:13 F:2 100% 80...-: 60...-: 40...-: 20...-: o : ~ ..,.../vJ"..J·w."" \~ I I I I I I I I 30:00 35:00 40:00 231.2111 5:13 F:2 100% 80...-: 60...-: 40~ ~JJ'M 20~~ ' 0- I 30:00 I I I 35:00 40 ~ 001 _1.3&7 ::...1.1&7 - ::...8.1&6 . ::...S.4E6 "~b A ,,\ ^ ,~.~~2 .7E6 V'-- wif'/VVJ1 v~ M ~ ~l "'^ -- - 0 .OEO I I I I I I I 1 I I I I 50:00 55:00 1:00:00 Time / - I I · 45:00 _2.3£7 ::...1.8£7 ::...1.4£7 ~ ::...9..2E6 Vu vl'J 150 ~ 001 l\J~' \ I ^,k . _ I -.. ~4..6E6 ~\vJtJ~- ' - 0 . OED I I 1 I I I I 1:00:00 Time 45~Oo' I -. 155 ~ 00' I I I 45:00 _7.0E6 - ::"5.6E6 - ;:..4.2E6 I I I 50:00 - l~) 'vJ1. hi - _ ~2 .8E6 4 MJ¥M~1.4E6 - 0 .OEO I I I I I 1 I I 55:00 1:00:00 Time Q ~ n ::J ~ ...... ~ to (t) þC o :4 Z o tv -J \0 Þ-tj ùQ' E; (þ ~ C> .""' -J - - - Ut ~ File:MPDMIOOO'¡13 #1-3086 Acq:16-DEC-1997 1~:36:36 GC EI+ Voltage SIR 70SE Sample#5 Text:FIORD-3A 8130' $97110IL001S012$ File Text:6000RP GCMS Exp:GCMS_HRSIR 191.1799 8:5 F:2 10ms 1:5 - 90"': - 80"': 70"': "Í5" - 60-': 50-': 'Y ~ ßV^~o ~opo~. 40"': 30"': o ~'" "" ¡.( -1~ A 20"': i ù'-l . l~~~~~~~~~~l~~_.~L~. - , , I , I ' , , , I I , , I 1 I , , I 1 ' , 30:00 40:00 50:00 1:00:00 1:10:00 217.1956 8:5 F:2 10001í . ,0 - 90"': - 80"': 70"': 1,J u ""V '}..,(\ - 60-': 50"': 1.1 "!.~ ~\, - 40"': - 30"': n ::~~J~wJ~~~,,'~,1 )~,~ .¡...A.~. -, I I , , J I , I , I ' 1 30:00 40:00 50:00 1:00:00 , 1 ' 1:10:00 _4.0E7 - :"3.6E7 - :"3.2£7 :"2.8E7 :"2.4£7 - :"2.0E7 :"1.6E7 - :"1.2E7/ :"8.0E6 - :"4.0E6 -= 0 . OEO Time _1.5E7 :"1.3E7 - :"1.2E7 :"1.0£7 :"8.9E6 :"7.4E6 :"5.9E6 :"4.4£6 :"3.0£6 :"1.5E6 - : 0 . OEO Time C) .~ (l I-f ~ ~ :;d !~ o ::¡ Z o tv -.l \0 Þ-r1 åQ' ~-.l CDN ~- . ...... ~ ......~ File:MPDMI000713 #1-3086 Acq:16-DEC-1997 15:36:36 GC EI+ Voltage SIR 70SE Sample#5 Text:FIORD-3A 8130' $97110IL001S012$ File Text:6000RP GCMS Exp:GCMS_HRSIR 177.1643 8:5 F:2 1 0 ()9j¡ 80..: 60..: - ::]~vV~.J~'J~~_ ~ 0- I I I I I I I I I I I I I I 1 I I I I 1 I 30:00 40:00 50:00 1:00:00 1:10:00 191.1799 S:S F:2 10m:· 80..: 60..: 40..: 20..: O=~~~ I I I I I I 30:00 40:00 205.1956 S:S F:2 1000~ ~~~~, I b I I I I b I I 1:0 :00 1:1 :00 I I I 50:00 80..: 60..: 0- 30:00 \l¡1\.J./v¡.~ i:ob:oo i:1b:oo I 40:00 '50~00' .;-, . ~h""""'~~,,^ -~Y:t1 _1.0E7 =-8.1E6 =-6.1E6 =-4.1E6 =-2.0E6 L . . J - 0 .OEO i:26:oo Time _4.0E7 =-3.2E7 =-2.4E7 =-1.6E7 - =-8.0E6 I b I'· T-'- 0 . 0 E 0 1:2 :00 Time -, i:2b:oo _6.2E6 =-4.9E6 =-3.7E6 =-2.5E6 =-1.2E6 - 0 .OEO Time M ~1.9E6 J'}.A, )'~ ~ AJ ~~9 .7E5 - 0 .OEO I J I · I I 1 I I . I 55:00 1:00:00 Time 5 0 ~ 0 O' 45 ~ 00' -J W - - VI .þ.. ~.MJ-- ::~ ._~~~~~ ¡J o _ rF.~. -.-- -.. ~~ ~ -- J I I I J · I · I J I 30:00 35:00 40:00 "T:I ~. (þ .þ. ........ N ~2.9E6 _4.8E6 ~3.9E6 ~8.9E6 J ~5.9E6 '^ J) rJ ~ ~ ~}rJ jJ ""," I ~3 . OE6 V\J~_ O.OEO · I I I I I J I · I I 1 I I I . 50:00 55:00 1:0u:00 Time I J . 45:00 _1.5E7 ~1.2E7 ~4.1E6 I = i hL.I, oJ ÑI A~ I ) . ~2 .lE6 ~W '-\.M JV\AL "\A~_ O. OEO r J I I I I J I · I I 1 I . I I 50:00 55:00 1:00:00 Time I 45:00 :::..6.2E6 ~8.3E6 _1.0E7 60...= 80...= 20~ u A. ... .A,,~\~ o - ~'^-'~"'" I , I I I I I I I I I 30:00 35:00 40:00 231.2111 8:5 F:2 10~ 40...= 60...= 80-.:: 40-.:: 2:~~~LW I I I I I I I I I I I 30:00 35:00 40:00 217.1956 8:5 F:2 10®¡ :;:d ~ '0 b !z :0 ·N -.) \0 60.-= :1 ~ (1 ::J ~ r""I" ~ 80.-= File:MPDMI000713 #1-3086 Acq:16-DEC-1997 15:36:36 GC EI+ Voltage SIR 705E Sample#5 Text:FIORD-3A 8130' $97110ILOOlS012$ File Text:60QORP GCMS Exp:GCMS_HRSIR 218.2033 8:5 F:2 10~ - O. OED Time =-6.9E6 :"1.4E7 :"2.1E7 :"2.8B7 :"4.1E7 :"3.4£7 :"5.5E7 :"4.8B7 _6.9E7 :"6.2E7 :"2.0E7 :"1.0B7 -=_O.OEO Time ~ 3 . 1B7 ¡ _ :"5.1E7 :"4.1E7 :"6.1£7 :"8.2£7 :"7.2£7 _1.0BB :"9.2E7 1:10:00' ~ ~ . 'N. ~ ,~J ,¡\I¡JJ...~ A<I: . . 1:00:00 I 50 ~ 00 30": 2 0": 10-= o ~~Jt.L - . I . I I 30:00 40:00 "1.1 ~) ")0 1\ ~ 10 '{-J.. 1.~ 10-= o~,~ I I I I I . 30:00 40:00 21 7 ~ 1956 S: 15 F: 2. 10~ f- " ;t1. ù 6lP :¡. !-tf S I ! I I~ N. ; . I ~ I· ~ ~ '- ~ \l \,J '^-- ~'W~ ~vJu · · 1 · · I I 1 I 1:00:00 1:10:00 I I I 50:00 /¡"~ {( 30": 2 0": ~ tA . 80": 7 0": 6 0": 50": 4 0": ~ ß~~kD'ð"".v.;.. ,..10 /\'" '1) File:MPDMI000112 #1-3086 Acq:l1-DEC-1991 20:~2:12 GC EI+ Voltage SIR ~OS£ Sample#15 Text:FIORD-3A 8610' $97110IL001S013$ File Text:6000RP GCMS -Exp:GCMS_HRSIR 191.1799 8:15 F:2 10001 (r 90": _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . _ _ _ . _ II _ _ _ .-..-.~r ~-.J _. ~ ~ ~ ( ) .þ. ~ Þ-' W 80~ 70": 60-': 5 0": 4 0": 90-= C) E=: (') t:I ~- ~ .- s» :::0 (Ð "0 0 :4 Z 0 tv -.J \0 TimeJ - 0 .OEO =-4.8E6 =-9.7E6 :..1.5E7 _2.4£7 =-1.9£7 :..4.1£7 :..2.0£7 - 0 . OEO Time =-6.1£7- =-8.2E7 _1.0E8 :"8.8E6 ::..4.4£6 - 0 . OEO Time / - :..1.3E7 _2.227 ::..1.8£7 '1 1 · 1:20:00 w~~1v~ · I · , I , 1 · · · · 1 · 50:00 1:00:00 1:10:00 _",,",-~"".1'>..._"'" . I · 4 0 : 0-0 o - r---; . ,- .- __A ; 30:00 T 20...: 40...: 60...: 80...: "'I 1 ' 1:20:00 o~~ ., I . . I I I 30:00 40:00 205.1956 8:15 F:2 10~ .1 ~..; , ..l......-. \IJ.....:---, · i, ill: 0 0 · 1:06:00 '50~OO' 20...: 40...: 60...: 80...: J . i:2Ó:OÔ 20...: oi~ 30:00' · · '40~OO' 191.1799 8:15 F:2 1 0 (Y!¡¡ I. ,^lJ\1J~k~ 'I.,~. '50~00r · · i:oó:o¿ · · i:l~:O¿ 40...: 60...: 80...: File:MPDMI000112 #1-3086' Acq:ll-DEC-1991 20:~2:12 GC EI+ Voltage SIR 10SE Sample#15 Text:FIORD-3A 8610' $97110ILOOlS013$ File Text:6000RP _GCMS -£xp:GCMS_HRSIR 177.1643 8:15 F:2 10~ -I tit - .....- tit .þ. ;- . ÞOyj ;q' E; n .~ - .þ. C) ~ () d ~ ~ ~ (t) ~ o ~ Z o N - -I \D ~7.8E6 : 3 . 9E6 __ k,iM f'JJJ! .~~ O.OEO ~ .. Time ' I 1':00:00 ' _1.9E7 =-1.6E7 :..1 .2E7 _ ~ 0 .OEO Time =-1.4E7 =-2.8E7 =-4.1E7 =-5.5E7 _6.9E7 , I ' 55:00 , I ' 50:00 .._-~~ , I ' , , , I ' , , , I I 35:00 40:00 45:00 o - r-----.,~ I I 30:00 20..:: 40..:: 60..:: 80..:: v..., ~ J ,JI'\) \.. , I I I 50:00 , I ' 40:00 o = ------L. 30:00' r , 35~00' 231.2111 S:15 F:2 1000; -þ .. -. ~ ;jq~J1k~~ r , , , 1 ' , 55~00 1:00:00 , I I 45:00 1_ 20..:: 40..:: 60..:: 80..:: :...1.1E7 .1111 j \ ~ ' ~5 . 6E6 . ~","JJ'INI,.,,,,.M At.. "^"vL~:O.OEO 1" I I" I I I I I I I I I I I 50:00 55:00 1:00:00 Time / 20..:: O-~ ~~--- , I I I I I I I I I I I I I I ' 30:00 35:00 40:00 45:00 217.1956 S:15 F:2 10~ :...1.7B7 :...2.2B7 _2.8E7 40..:: 60..:: 80..: File:MPDMI000112 #1-3086 Acq:11-DEC-1991 20:52:12 GC EI+ Voltage SIR 70SE sample#15 Text:FIORD-3A 8610' $97110IL001S013$ File Text:6000RP GCMS -Exp:GCMS_HR8IR 218.2033 8:15 F:2 10~ "Tj åQ'-.1 E;O\ 0_ -J:;:.~ . Ut ......~ V\ 1-1 ~ p:I þd ~ o ::¡ Z o N -.1 \0 CI a:: n :"2.0E7 :"1.8E7 :"1.5E7 :"1.3E7 :"1.0E7 :"7.7E6 :"5.1E6 :"2.6E6, ~ 0 . OEO Time ,....2.6E7 :"2.3E7 :"1.5E7 : 0 . OEO Time :"2.9E7 :"4.4E7 / :"1.0E8 :"8.7E7 :"7.3E7 :"5.8E7 :"1.2E8 :"1.3E8 _l.SEB 30-': : I 20~ i . ' l:jJJ.~' ~~jol-A1 ~.J..1~AW,V I , I , I I , I , I ' 30:00 40:00 50:00 ,~~ A,~-Jl ~,---- , b ' I I I 1 ' 1:0 :00 1:10:00 .. }'1 Q -j., ~ '1.%> \I *1- 1{ I" J " Q 0< p" )y :1.Á~.Aw.I.J!~~~ ¡J..~.JJL~.._~. I 1:ob:oo I I 1:1b:oo T I 50~00 I 1f- 0. R v o 1\'" ...,. ªbA.t..ðu:)I'~' ,J ? 90-': 80~ 70-': 60": 50-': 40-': 10-': o ~~~-lo... I , , 1 I I 30:00 40:00 217.1956 8:16 F:2 10~ Æ<Ç 50-': 40-': 30": 20-': 60": 80": 70-': 90": File:MPDMIOOO"¡12 #1-3086 Acq:l1-DEC-1997 22:33:22 GC EI+ Voltage SIR ~OSE Sample#16 Text:FIORD-3A 8800' $97110ILOOIS014$ File Text:6000RP GCMS '.Exp:GCMS_HRSIR 191.1799 5:16 F:2 10~ ~ -.1 -.1 - ~ Ul ~ 0\ ÞOyj òQ' ~ ('Ð .¡::... Q ~ n tJ ~ ~ ,c ~ o '::¡ Z o tv ,~ \0 - 0 .OBO Time :"7.4B6 :..1.5B7 :..2.2B7 :.3.0B7 _3 .7E7 :.2.9B7 ,- 0 .OEO Time :.5.8E7 :.8.7E7 :.1.2E8 _1.5E8 - 0 .OEO Time / :.7.9E6 :.1.6E7 :..2.4E7 :..3.2E7 ~4.0E7 · 1 · 1:20:00 J~."" -. I. I ij1l .~, .., .....~~ ~-...-. -. - - · I · · · · I · · · I 1 · I I I 1 1 1 40:00 50:00 1:00:00 1:10:00 20...:: 0-=-'- . I 30:00 40...:: 60...:: 80...:: · I I 1:20:00 20...:: O:~- .. L4I~~A,_-.1>'-''''''''''''' I J . . I 1- 30:00 40:00 205.1956 8:16 F:2 100% ~f ~lLw^,,~ I · I· .11,:00 I 1 . · 1:00:00 I I · 50:00 60...:: 40...:: 80...:: ...' I · 1:20:00 20...:: o - 30:ÒO' ~ · '40~00' 191.1799 8:16 F:2 100% l~~.4.. .~ i:oo:oo · · ì:16:oò r I I 50:00 40...:: 80...:: 60...:: F1le:MPDMIOOO'l12 #1-3086 Acq:11-DEC-1991 22:33:22 GC BI+ Voltage SIR ?OSH Sample#16 Text:FIORD-3A 8800' $97110IL001S014$ File Text:6000RP GCMSExp:GCMS_HRSIR 177.1643 5:16 F:2 1 0 0?tJ "Tj åQ' f=i -.J (D ~ ..þ. - . U¡ >-' ~ -.J (;) ~ (') ö ~ PJ :;d .g o ::¡ Z o N -.J \0 Q E;:: () t1 ~ .-t- ~ ':;:0 '~ o :4 Z o ..·N .....) \0 Þ-r1 ~' o 7>- ~ 00 .....) \0 - - u. ~ File:MPDM1000~12 #1-3086 Acq:ll-DEC-1991 22:33:22 GC E1+ Voltage SIR 10SE Sample#16 Text:FIORD-3A 8800' $97110IL001S014$ File Text:6000RP GCMS ·Exp:GCMS_HRSIR 218.2033 8:16 F:2 100% 80...:: - 60...:: 40...:: 20...:: ~JJ~ I \ j 40:00 o-~ J J '" 30:00 35:00 211.1956 8:16 F:2 10m:; 80...:: 60...:: 40...:: 20~ . .. ¡ . I JlJ ~ o· ~~'" -- I , I I , J , I , I I 30:00 35:00 40:00 231.2111 S:16 F:2 1 0 OO:1t 80...:: 60...:: 40- 20] ~,M»..; ~.~ o -I - . J I , , , ' I , , , ' 30:00 35:00 40:00 _2.6E7 - ~2.127 - :...1.627 :...1.0E7 - , \ ' 45:00 ,. -\ ' 50:00 - ~ . . ~5.2R6 ... ... .~- O.OEO , \ ' . , , 1 -, , , I 55:00 1:00:00 Time / _2.6E7 :...2.0E7 :...1.5£7 :...1.0E7 , , ' 45:00 AiIl'J rV )'\ ~.M~v"/,^^~ ~5.1E6 _- 0 .OEO · \ I I I , \ ' I , , 1 I I I , 50:00 55:00 1:00:00 Time _9.6E6 :...7.7E6 - :...5.8E6 , , I 45:00 :...3.9E6 ~ vJJ J VI'I. ~ ~1. 9E6 - O.OEO r \ ' , I , 1 ' , , , 55:00 1:00:00 Time I \ I 50:00 : O. OEO Time :"9.0£6 :"6.0E6 :"3.0E6' :"1.8E7 :"1.5E7 :"1.2E7 :"2.7E7 :"2.4£7 :"2.1£7 _3.0E7 :"2.7E7 :"1.4£7 ,.-- _: O. OEO Time :"4 .1E7 // - :"5.4E7 :"8.1£7 :"6.8E7 _1.4E8 :"1.2E8 :"1.1E8 :"9.5£7 - : ----.. 1.,...,.- 1 1 1 1:10:00 .". - _....,..__ .__... ~'=_-OO-' ~\ø }It 11~\ I.- I '¡ft'f : ~ · J i .A, J Jl............... 1- l:Oð:OO' 11 ~'!I 4'10- flV" )f' 11' o;r 1Y1~ "10\ ~~û.,-,,~~ '-h.......~~ 1 1 1 1 1 I 1 1 1 1:00:00 1:10:00 * l?,c___-z.o"'0i'~ 70S£ Exp:GCMS_HRSIR File:MPDMIOOOï12 #1-3081 Acq:12-DEC-1991 00:14:29 GC EI+ Voltage SIR Sample#17 Text:FIORD-3A 8840' $97110IL~01S015$ File Text:6000RP GCMS 191.1799 8:17 F:2 -. 10003 90-= 80-= 70-= 60-= 50-= It .-< o ¡;". t-1 ~ &' . ..~-.._~~~þIo"~,~~..;q~~~~~~.;;ç:.o_-~..---· 1 I ' 50:00 . I · 40:00 40-= , 1P 30~ I . , ~:] t v~~v·JAA·1v I\!t ~ M, \ 0": 30:00 1'~ ~~ 60-= 50-= \\ 80': 70': 10 90-= I 50~00 1 40-= 30': 20-= 10~~~M.. 0..: 1 . . 1 I 1 30:00 40:00 217.1956 S:17 F:2 10@ /¡'; ~~ Þ-rj åQ. ~ ~ ...¡::..- . - _Ut \O~ C) a;:: n ~ .... ~ :;d ~ o :4 Z o N ~ \0 File:MPDMIOOO'/12 #1-3087 Acq:12-DEC-199? 00:14:29 GC EI+ Voltage SIR ?OSE Sample#17 Text:FIORD-3A 8840' $97110IL0018015$ File Text:6000RP GCMS - Exp:GCM8_HRSIR 177.1643 8:17 F:2 10~ Q s:: n tj ~ ...,. ~ -~ !~ '0 .:4- Z o N' -J \0 80-= 60-= 40-= 20-= O-=. 30:00 '40~00' 191.1799 8:17 F:2 1 0 CY!6 '50~00' i:06:oo I 1 I 1:10:00 80-= 60-= 40-= 2 o~ I I o-~~ I I I I I I 30:00 40:00 205.1956 8:17 F:2 1000~ ~~~~~~.... , i:oo:oo I I i:l0:00 ' 111 -50:00 80-= 60-= 40..:' 20-= ~~~~.,- i:oo:oo i:10:00 Þ-r:I ~. (1) .þ. tv C> 0- 30:00 I 40:00 I I I 50:00 00 - - - U'I ~ 1:26:00 T I 1 J 1:20:00 i:26:oo _3.1E7 ::.2.5E7 - ::.1.9E7 ::.1.3E7 - ::.6.3E6 - - 0 . OEO Time / - _1.4£8 - ::.1.1E8 - ::.8.1E7 - ::.5.4E7 - ::.2.7E7 - - 0 . OEO Time _2.6£7 - ::.2.1E7 :..1.6E7 ::.1.0E7 - :..5.2E6 - - O. OEO Time )oyj ~' 00 (1) N ~ ;:::: tv Vt Þ--& ~ o ~ n t1 ~ ~ þd (I) '"0 o ::4- Z o N -.J \0 File:MPDM1000'l12 #1-3081 Acq:12-DEC-1991 00:14:29 GC £1+ Voltage SIR 'lOSE Sample#17 Text:FIORD-3A 8840' $97110IL001S015$ File Text:6000RP GCMS 'Exp:GCM5_HRSIR 218.2033 5:17 F:2 10 Q?¡¡ 80--= 60--= 40...:: 20--= o = ~~ LJwuJ , , , , I ' I , , I I 30:00 35:00 40:00 217.1956 8:17 F:2 10@" 80...:: 60..: 40...:: 20~ . M I. .. A.it· '" !LJ,~ o _ ('-"_""~'-'\,.IvnY.... ~ , , , I I ' " , , I ' 30:00 35:00 40:00 231.2111 8:17 F:2 10~ 80...:: 60--= 40~ ~~JrJJ'M 20...:: 0- , 30:00 '35 ~ 00' , I ' 40:00 _2.9E1 - :.2.3£1 :.1.7£7 :..1.1E1 :.5.7E6 , I ' 45:00 "i'lM ~ ~~ . I I " "1" 55:00 1:00:00 - 0 . OEO Time / , I I 50:00 _3.0E7 - :.2.4E7 - :.1.8E7 :.1.2E7 - "",,,'I'V f\)) It \ ~h""JLV\..1.. ~6.0E6 - ~- O.OEO , 1': 00 : Ô 0' r I Time I J ' 45:00 , I ' 50:00 , -, I ' 55:00 _1.2E7 - :.9.8E6 - :.7.4E6 :.4.9E6 WJl¡~' ~2 .SE6 ~ O.OEO 55 ~ 00' '1': 00: 0'0 ' Time I I ' 45:00 I I ' 50:00 ;:. 0 . OEO Time :"1.6E7 -' :"1.3E7 :"1.1E7 :"8.9E6 :"6.7£6 :"4.4£6 =-2.2£6 :"1.8E7 :"2.0E7 _2.2E7 : 0 .OEO Time :"'5.3E7 :"3.5£7 :"'1.8E7 :"'1.4£8 :"'1.2E8 :"'1.1E8 :"8.8£7 :"'7.0E7 _1.8E8 :"1.6£8 1:10:00' 1:00:00' ~:lr~"'I~I~~ Nil\' , , I , f ' , · · I ' 30:00 40:00 50:00 ~Ir I j j M 11 ~' '\I\.~__ l' q, 70~ 60": 5 0": 4 0": 3 0-= ,l-> 1.,.'1 ~ t\ 1i 80-= 10 90-= 6 30-= 20-= 10": o~~- 30:00 217.1956 100% 1f'1- \J It 1/ ~ - . (J(þ . ~ Q l~ . ~ ~,.. J( \ ~u,~~M.- iJ..~.~1~ I 1 I I I I 1 I I 1 1.:00:00 1:10:bo , I · 50:00 f\ ~ \( 40": ~ ~,\)"'of~· .(.. (J File:MPDMIOOOï12 #1-308"' Acq:12-DEC-1997 01:55:33 GC EI+ voltage SIR 'lOSE Sample#18 Text:FIORD-3A 9120' $97110IL0018016$ File Text:6000RP GCMS· Exp:GCMS_HRSIR 191.1799 8:18 F:2 10W~ 90-= 80-= 70": 60": 50": ,J l' IJ 00 w - - u. ~ 'ï1 QQ' ~ .(1) \.þ.. N N '·1·' C) ~ () ,Ö ¡~ :..... j~ ;:;0 ,.g o ~ Z o N -.J \0 "'rj åQ'oo ~ Ë ~lJt iv-Þ- w C) s:: () tJ ~ ~ þt1 ~ o ~ Z o N -.I \0 ------...... File:MPDMI000712 #1-3087 Acq:12-DEC-1997 01:55:33 GC EI+ Voltage SIR ?OSE Sample#18 Text:FIORP-3A 9120' $97110ILOOlS016$ File Text:6000RP GCMS· Exp:GCMS_HRSIR 177.1643 8:18 F:2 10~ ~3.8E7 60-= 80-= ~3.0E7 40-= 20-= ~~~.- 0- 1 I 1 30:00 40:00 191.1799 S:18 F:2 1000~ '50~00' i~oo:oó 1:10:00· 80-= 60-= 40-= ./ 20-.:: o - t---L-J _1 .^_ . ' - LA _ 30:00' 140~00' 1 205.1956 8:18 F:2 100% ^ . a. ~._~~~h__!~, 1 5 0 ~ 0·0 1 "i: 0 0 : 0 Ò I I - i : 1 b : 0,) · 80-= 60-= 40-= - 20-= o : r 'J'-" ~- , .,. 1 1 30:00 -". "'-.- ~ . J.... .. ~AL~·~ 1 I I I 1 I I 1 I 50:00 1:00:00 1:10:00 I I I 40:00 I I 1 1:20:00 I - 1 I 1:20:00 I 1 I 1:20:00 ~2.3E7 ~1.5E7 =-.7.6E6 .- 0 . OED Time _l.BEB =-l.4EB =--1.1E8 =-7.0E7 =-.3.5E7 - O. OEO Time _3.7E7 ~3.0E7 =--2.2E7 =-.1.5E7 =--7.5E6 - - 0 .OEO Time ~3.6E6 ¡\,.J v. Iff k ~.Jl)1. 8E6 ^ :O.OEO 1 J J Time '1':00:0'0 , J ' 45:00 40..:: 20~~~IIÀ N o - , , , 1 , J I , I I ' 30:00 35:00 40:00 , I I 55:00 I I ' 50:00 ~5.4E6 60..:: _8.9E6 =-7.2E6 80..:: 20~ II L . t ~ ~~ 0- ~~'" , 1 I I I I , I I I ' 30:00 35:00 40:00 231.2111 5:18 F:2 10 OO:ií , ~8.9E6 rI\¡ ^ V \ ~ ~ ".\. J A /1\ . ~4 · 4E6 '\J \..v~- 1 1 I J , J ( 1 I 1 , I - 0 . OEO 55:00 1:0u:00 \A, ytt J 1 , I 50:00 , .1 I ' 45:00 Time \. 40..:: =-1.3E7 60..:: =-1.8E7 80..:: _2.2E7 20..:: 0= ~ ---, .-.. J~JvA.L..JwuJ I 1 1 , I I 1 1 1 30:00 35:00 40~OÒ 217.1956 5:18 F:2 1 0 0'!1¡ =-6.2E6 j - 1.11. A I i ~ : A I l ~ 3 . lE. 6 ~W tV '\JV'\ 1\ \J\,,J ~ ~ ~ . O.OEO , I 1 , 1 I I ' 1 1 I 1 J J J J 50:00 55:00 1:00:00 Time , I · 45:00 40..:: ~9.3E6 File:MPDMI000712 #1-3087 Acq:12-DEC-199"j 01:5:>:33 GC EI+ Voltage SIR 10SE Sample#18 Text:FIORD-3A 9120' $97110IL001S016$ File Text:6000RP GCMS' Exp:GCMS_HR8IR 218.2033 8:18 F:2 10~ 80..:: 60..:: =-1.2£7 _1.6£7 00 Vt - - Vt ~ ..., ôQ' ~ (þ ~ N ~ C) ~ () tJ ~ -- ~ ~ ~ o ::4- Z o N -.....) \0 ÞOrj ~' (1) U\ Q g;:: (1 "-" ~ ~ ,c ~ o ::¡ Z o N -.....J \0 File:MPDMIOOO?12 #1-3086 Acq:10-DEC-199? 15:41:11 GC EI+ Voltage SIR 70SE Sample#3 Text:FIORD-3 4020' $97110IL001S001$ File Text:6000RP GCMS Exp:GCMS_HR8IR 231.1173 S:3 F:2 10005 f\",\-"<6 90": 80": 7 0": 6 0": 50": 4 0": 30": 2 0": ~ 10": 0: I 30:00 253.1955 10~ 90": - 80": - 70": 6 0": 50": 40": 30": - 20": - 10": 00 0'\ - I--" U1 .J::o. - o :, I 30:00 f'~ f1.< fib f'\~ fv t-l\ ~ ~\~vv..~~~~'-vJlvl'JJ.w~ I I I I I 35:00 8:3 F:2 I I I I I I I I I I I I I I I I I I - I I I I 1 I I 40:00 45:00 50:00 - 55:00 1:00:00 pr" ,~ v-l' f\ \. ~1. fP f~ (\.) H..1 ~ .& . n J __ _~wJJ -JILl ~ 4J~_ I I I I I 1 I I 55:00 1:00:00 I I I I I 35:00 Å..,. I I I 40:00 I I I I I 45:00 I I I I I 50:00 I I 1 I I 1 1:05:00 I I 1 I I 1:05:00 _2.4E7 :"2.2E7 :"2.0E7 :"1.7E7 :"1.5E7 :"1.2E7. :"9.8E6 - ~ 7 .3E6 / _ :"4.9E6 :"2.4E6 -;- no(: O. OEO Time _7.3E7 - :.. 6. 6E7 - :"5.9E7 :"5.1E7 - :"4.4E7 :"3.7E7 - :"2.9E7 ¡: :"2.2E7 - :"1.5E7 :"7.3E6 - : 0 . OEO Time G ~ () tJ ~ ~ ~ "þd ~ o :4 Z "0 N -J .\0 ÞOr:1 UQ' ~ (1) V\ tv 00 -J - - U\ ~ File :MPDMIOOO",12 #1-30'86 Acq: 10-DEC-199"' 1", :22 :26 GC E:I+ Voltage SIR "JOSE Sample#4 Text:FIORD-3 4140' $97110IL001S002$ File Text:6000RP.GCMS Exp:GCMS_HRSIR 231.1173 8:4 F:2 100% J-\"\K'\ ~ 90": 8 0": f't - 70": 60": - 50": - 40": - 30": 20": ~-{ f11 ~I A ~ \,J \,>NJ........~,~L.N vJJ,1 ~ ~~. - 10": 0: - I I I I 30:00 35:00 253.1955 S:4 F:2 1 0 0?íJ I , I ' I 40:00 , I ' 45:00 - 90": - 80": - 70": 60--= - 50": - 40": 30--= - 20": fZ' ",'),'2.- .~--L I I I I , I , I I , 35:00 40:00 . " , I I I , 45:00 - 10": 0:. , 30:00 f\'" ~ , , I I , I I I I I I I 1 ' I , I 1 I I 50:00 55:00 1:00:00' "1:05:00 ~,,1 ¡,( f~ I I I 50:00 ~ ft \,{\ 1. ~ \1j n . ,,_JLJi LAJII.J.., /Ivv ~ I 55~OO ' '1~ob:oo' I I 1 ' , 1:05:00 _2.7E7 :"2.4E7 :"2.2E7 - :"1.9E7 - :"1.6E7 - :"'1.4E7 :"1.1E7 - :"8 .1E6 / - :"S.4E6 :"2.7E6 - - 0 . OEO Time _S.2E7 - :"4.7E7 - :"'4.2E7 - :"3.7E7 :"3.1E7 - :"2.6E7 :"2.1E7 :"1.6E7 - :"1.0E7 - :"S.2E6 ;: 0 . OEO Time , .C) ~ n t:J ~ Øo:) ~ ~ o :4 Z o N -.1 \0 ÞOr1 ~. lJIoo , 00 w_ - U. ~ File:MPDMI000712 #1-3086 Acg:10-DEC-1997 19:03:38 GC EI+ Voltage SIR 70SE Sample#5 Text:FIORD-3 4740' $97110IL001S003$ File Text:6000RP GCMS EXp:GCMS_HRSIR 231.1173 S:5 F:2 10~ ~~~ 90-': 80-': 70-': 60-': 50-': h't ...~ nt "... h'\ - 40-': V].o - 30-': 20-': 10-': 0: - , 30:00 253.1955 100%5 _4.8E7 :"4.3E7 - :"3.8E7 :"3.3E7 :"2.9E7 ~2.4E7- :"'1.9E7 - :"1.4E7 / , 1 1 ' , 1:05:00 - :"9.6E6 :"4.8E6 ":.0 . OED Time AA~~~,~-L....~"'~~ . , , I 35:00 8:5 F:2 I , J ' , I I I I , 40:00 45:00 I'" r 1 J I" 11" 50:00 55:00 1:00:00 f\"''¡ ~ - 90":: ",,,1 - 80": 7 0":: 60-': 1\\1(\1. f'!, (/}.1.- - 50-': 40-': 30-': 20": 10~ Þ\l~_ .Jw, ~ 0: r" - - , , , . I ' , , , I I I I , , 1 I 30:00 35:00 40:00 45:00 "ü f\ ~ it') t'J. IJJJ,AlJ~ AN~.~. I I I I · I I I I I I I 1 I I 50:00 55:00 1:00:00 I . I _1.5E7 ~1.3E7 :"1.2E7 :"1.0E7 :"8.9E6 - =-7.4E6 =-5.9E6 :"4.5E6 :"3.0E6 :"1.5E6 "'--.. ... __1t.-_-.--. ~.....-~......-_\ 4 \. - : - . -'': 0 . 0 EO I I 1 I I 1:05:00 Time C) ~ n tJ ~ <'+ ~ :;c (t) "0 o ~ Z o tv -.) \0 "T1 òQ' G (b v-. ~ 00 \0 - - U\ .þ.. File:MPDMI000712 #1-3087 Acq:10-DEC-1997 20:44:50 GC EI+ Voltage SIR 70SE Sample#6 Text:FIORD-3 6240' $97110IL001S004$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 S:6 F:2 100015 ft1-\'1~ f'L1.. ~t,,~ ~.l~~. _~J.,JIJu·l ~~. I 35~00 I , 40~00 I I 45~00 ' , 50~00 ' I 55~00 I '1;00:00' - 90':: 80':: 70':: - 60':: 50':: 40':: - 30':: 20':: 10-': 0=__- , I I I I ' I 30:00 35:00 253.1955 S:6 F:2 10 0015 fl'f- ~s I 1 I I , 40:00 ~ I I I ' I 45:00 - 90-': 80-': 70-': 60-': 50-': 40-': 30-': 20-': 10-': - o = r-- I 30:00 ñ-' ft1 fû> ft" ~ ..J.J~ "--~, I I I ' I I I I I I I I 1 I , I , 1 I , 50 : 00 55 : 00 1 : 00 : 0 0 '1 : 05 : 00 f~ f~ ~,,'C1 f;3 f\lX\Z- vw f\3 '-1 I 1~05:00 I _2.3R? - =-2.0E7 =-1.8E7 =-1.6E7 =-1.4E7 =-1.lE7 =-9.1E6 =-6.8E6 =-4.5E6 - =-2.3E6 . - ': O. OEO Time _1.9E7 =-1.7E7 - =-1.5E7 =-1.3E7 =-1.2E7 =-9.6E6 =-7.7E6 - =-5.8E6 =-3.9E6 - =-1.9E6 - ..: O. OEO Time ~I Q ~ n t1 ~ -- ~ þC ~ o ::¡ Z o N -.) \0 ~ ~. (1) v-~ v-;::::= UI ~ File:MPDMI000112 #1-3081 Acq:10-DEC-1997 22:25:58 GC EI+ voltage SIR ?OSE Sample#7 Text:FIORD-3 6600' $97110IL001S005$ File Text:6000RP GCMS EXp:GCMS_HR8IR 231.1173 8:7 F:2 1000~ 90~ - 80": 70": 60": 50": - 40": - 30": 20": - 10": 0: I 30:00 253.1955 10~ - 90": 80": - 70": 60": - 50": 40": 30": 20": 10-': 0: . , I 30:00 I - , I I , 35:00 8:7 F:2 ~'If I , I ' I 40:00 , I I ' , 45:00 f11-t'\¡' ft'\ hÞ f'2l fl~ ,~~vJU~_ , I I I I I · I I I , I 1 I I I , 1 I I 50:00 55:00 1:00:00 1:05:00 ff\ f) {f-; ~\. (\1. ht.- &-\.-) f!!II tv hQ - ~} - , 35~OO ' - r i ~J . h) lA P ,..,,~__ · 50~OO · , 55~OO I I l~ob:oo I '1;05:ÓO' I , I ' I 40:00 I I · 45:00 _7.9£7 :"'7.2£7 :"'6.4£7 - :"'5.6E7 :"'4.8£7 :"'4.0£7 - :"'3.2E7 - :"'2.4£7/_ - :"'1.6E7 :"'7.9£6 : 0 . OEO Time _8.6£7 :"'7.7£7 - - - :"'6.8£7 :"'6.0£7 :"'5.1£7 - :"'4.3E7 :"'3.4£7 :"'2.6E7 - :"'1.7E7 :"'8.6£6 : 0 . OEO Time - 0 . OEO Time :"9.7E6 :"'4.9E6 :"2.4E7 -=-'1.9E7 ':..1.5E7 :"'3.9E7 :"'3.4E7 :"'2.9E7 _4.9E7 :"'4.4E7 :: O.OEO Time ~7.2E6 :"'1.4E7 ~2 .2E7 / _ :"'2.9E7 _7.2B7 :"6.SE7 :"S.8B7 ~S . 1E? r :"'4 .3E7 :"'3.6E7 ---..---s, __..·.___r.·~ I l~O~:OO I f>~ nJ : · At. ,~~ ~___,~'V~I ~, I I I I I I I I I I I I f I I I I I I I I I I I I I I 1 I I 35:00 40:00 45:00 50:00 55:00 1:00:00 (:11 (/1. 0° ~ ft\~t.- o f"$ ~ ~~ I ("Y" 1 I I I I I I I I I I I 35:00 40:00 45:00 5:8 F:2 ~~~~"-v~ I I 1 I I I I 1 I I 1:00:00 1:05:00 I I I 55:00 I I I I 50:00 / (Æ"J fl't f}Þ fl~ ft'1 ~J ( 30-= 20": 10'-: o :. . 30:00 40": 50:' 60": 90": 80": 7 0": o : I 30:00 253.1955 1 0 O?é 3 0": 20": 10": 4 0": 80": 70-': 60": 50": 90-': File:MPDMI000712 #1-3087 Acq:l1-DEC-1997 00:07:06 GC EI+ Voltage SIR 70SE Sample#8 Text:FIORD-3 6750' $97110IL001S006$ File Text:6000RP-GCMS EXp:GCMS_HRSIR 231.1173 S:8 F:2 10~ k'-1-f\¥ \0 - - - Ut ~ ,- --- Þ-r1 òQ' e; (þ v. 0\ Q 3: (") ö ~ ~ :;;d ~ o :4- Z o N -J \0 C) ~ () t1 ~ .... ~ ~ .g o ~ Z o tv -.) \0 ÞOyj ~. \0 (1) ~ V\ ~ .~ ~ ------- File:MPDMrOOO~12 #1-3086 Acq:11-DEC-199~ 09:05:10 GC EI+ Voltage SIR 10SE Sample#9 Text:FIORD-3 6770' $97110IL001S007$ File Text:6000RP GCMS EXp:GCMS_HRSIR 231.1173 S:9 F:2 10 O?i¡ .f1ï<l'W - 90": 80"': - 70": - 60-= 50-= K'1 fl.-( - 40": fj(.. ñÞ - 30"': 20-= "It r-~ - 10-= ~","'U L"-.. ~: I I I I I I I I I I I I 1 I I I · 1 I I 50:00 55:00 1:00:00 1:05:00 - & _ & ,. A.I ~ 0: I . ~, _~_~v-.¡"""'''^J-,""",~ I I -. I I I I . I I I I I I I I 30:00 35:00 40:00 45~00 253.1955 8:9 F:2 100% ~ - 90"': v< - 80-= 7 O_~ ' - 60-= ~ f1\-t\'1.- .' 50-= ~) - 40-= 30-= 20-= 10-= o : r I I 30:00 ,to ~I~ 0. c-1l. ~}.1 l.vJIAL J~ kv~. I I I 35:00 I I I 40:00 I I I 45:00 I I I I I I · I I I I · 1 I . .50:00 55:00 1:00:00 I I 1 I I 1:05:00 - - - - - _1.3E8 ::'1.2E8 :"'1.1E8 - :"9.3E7 :"'8.0E7 :"6.6E7 - :"5.3E7 - :"'4 .OE7 i _ - :"2.7E7 - :"'1.3E7 ~ O. OEO Time _7.1E7 :"'6.4E7 - :"'5.7E7 - :"'5.0E7 - :"'4.3E7 :"3.6E7 - :"2.9E7 - :"2.1E7 :"'1.4E7 - :"'7.1E6 - - 0 . OEO Time C) a=: () ~ ..... ~. ~ ~ o ::¡ Z o N -J \0 ÞOr1 ~' (b VI 00 \D W - ...... Ut .¡::. File:MPDMI000112 #1-3~87 Acq:11-DEC-1997 10:46:21 GC E1+ Voltage SIR 10SE Sample#10 Text:FIORD-3 7020' $97110IL001S008$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 S:10 F:2 1 0 00:£ - 90": - 80": - 7 0": 60-= 50-= 40-= - 30_= - 20": - 10": o : I 30:00 253.1955 100% 90-': 80": - 70": 60--= 50":: - 40":: - 30~ - 20":: 10-= - 0: . , 30:00 -.r - - .:\. flit " ¡--i"--¡ 35~00 5:10 F:2 , I ' I 40:00 I , I ' , 45:00 & ,J' - & , 50 ~ 00 ' I f-( f} fb11 (11-%'\'( <-;. ( (-1 '\ flL< (zÞ ..J~0JlJ~ , I ' I I , 1 ' , I , 1 ' I 55:00 1:00:00' 1:05:00 ßI< rriv f\1 ¡,{) fl.) (1V V\'''J f'J. .L1 ~,~,-~I~Vv ,Iy¡' ft ~.~ , I I I' I" I 'I' "I" I I I I I , , 1 I I I I 1 ' I 35:00 40:00 45:00 50:00 55:00 1:00:00 1:05:00 _9.6E7 :"7.8E7 :"6.9E7 :"6.0£7 :"5.2£7 :"4.3£7 :"3.5E7 - :'2.6E7 i _ - :'1.7£7 :"8.6E6 - ;: 0 . OEO Time _5.0E7 :"4.5£7 :"4.0£7 :"3.5E7 :"3.0£7 - :'2.5E7 :"2.0E7 - :'1.SE7 :"1.0E7 :"5.0E6 - - - O. OEO Time :"2.1E7 :"1.4E7 :"6.8E6. =0 . 0 E 0 Time :"5.5E7 :"4.8E7 :"4.1E7 :"3.4&7 :"2.7E7 ~6.8E7 :"6.2E7 - 0 . OEO Time :"3.6E6- :"1.8E6 :"5.4E6i :"7.3E6 :"1.3E7 :"1.1E7 :"9.1E6 :"1.5E7 _1.8E7 :"1.6E7 , \ I I 1 I I 1:05:00 ~ __~-wAJ,~ ~,~~ I I I I I I I I · I I I I I I I I 1 I I 45:00 50:00 55:001:00:00 f~ f1 f\~ Ç{!) {(..l.(\-¡' ~ ~ flJfl I · 1 I I I I 1 I I 1:00:00 1:05:00 I I I I I I I I I I I I I I I · I I I 40:00 45:00 50:00 55:00 ~ 1fi\.1V'~~G ~ -' JJ.....~ ._. (-20 c- \" ,¡\ f''\ f"( ",q ~ .~. I . I I I I I I I 35:00 40:00 À..A 10 o ~- I I 30:00 90-= 80-= 70':' 60-': 50-= 40-= 30": 20": 20": 10-= 0: I I I I I I 30:00 35:00 253.1955 S:11 F:2 10~ 40": 30':' 50-= 70": 60-': 8 0": 90-= File:MPDM1000112 #1-3086 Acq:11-DEC-1997 14:07:14 GC E1+ Voltage SIR ~OSE Sample#11 Text:FIORD-3A 4800' $971101L001S009$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 S:11 F:2 10~ f1î-\Å\ Þ-rj ~' 'f CD _ - 0\ Ut , ~ C) ~ n tJ ~ ~ þd ~ o ::+ z o N -J \0 :"1.2£7 ' : 0.0£0 Time -=-3 .6£7 :"2.4£7 :"6.0£7 :"4.8£7 :"9. 7£7 :"8.4£7 :"7.2£7 _1.2£8 :"1.1£8 :"1.2E7 :"8.2E6 :"'4.1E6 :- O. OEO Time :"2.1E7 :"1.6E7 _4.1E7 :"3.7£7 :"3.3£7 :"'2.9E7 :"'2.5E7 I 1~OS:OO I = 'Jl IiJ ~' ~~A __ _~IJwJ, ~ I I I I I I I I I I I I I I f I I Ó I f 45:00 50:00 55:00 1:0 :00 30~ 20~ 10": µ (It'\,o' ~ -- ,~-,-~. I I I I I I I I I f 35:00 40:00 o : " I 30:00 (/J- 1'1~ f'0 (;} 60": 50~ 40~ µ.' .1("\1- ~c,J) 80~ 70~ f,( 90-=- {1ft 30-': 20~ 10": 0: I 30:00 253.1955 10006 f 50~OO I I I I I 40:00 I I I 35:00 8:12 F:2 ~~~.wLLL I I I I I I 1 I I I I 1 ' I 55:00 1:00:00 '1:05:00 45~OO (A~ f''t M'\ f'" f1J 60~ 50~ 40-': (,tP File:MPDMI000112 #1-3086 Acq:11-DEC-1997 1~:48:31 GC EI+ Voltage SIR 70SE Bample#12 Text:FIORD-3A 8010' $97110IL001S010$ File Text:6000RP GCMS ' Exp:GCMS_HRSIR 231.1173 S:12 F:2 100%. ~'\~\ K 90~ 80-': 70": .J \0 U. - - u. ~ ~ òQ' ~ (D 0\ N / o ~ () t1 ~ ~ ~ ~ o ;:¡ Z o N -J \0 C) s:: () t:I Š ~ ~ o :4 Z o N -.1 \0 '"r1 åQ' \0 ~ 0\ (1) ;::: 0\ Ut W .¡:.. File:MPDMIOOO,12 #1-3086 Acq:11-DEC-1991 11:29:4, GC E1+ Voltage SIR Sample#13 Text:FIORD-3A 8100' $97110IL001S011$ File Text:6000RP GCMS 231.1173 8:13 F:2 10 CY!t: ~1J<"\"" 90~ - 80~ - 70~ 60~ 50~ 40~ 30-= - 20~ - 10": - o : I 30:00 253.1955 1000~ 90~ 80~ 70~ 60": - 50~ 40~ - 30": 20~ - 10~ 0:. I 30:00 flil- r( k I I I I I 35:00 8:13 F:2 I I I I I 40:00 I I I I I 45:00 I I I 50:00 f'~ f'1- f( ",OSE Exp:GCMS_HRSIR fw ~\o fp. h" - ~~JU-~..__ I I I I .- I I 1 I I I I 1 I I 55:00 1:00:00 1:05:00 f~ fir 11 ÇtX x\ \.- f\-O - ft) -- - I I I ~.. ','~ AtJ· l· ftv.J ~--- ~JwJ. ~ I I I I I I I I I I I I I I 35:00 40:00 45:00 I I I 50:00 I I I 55:00 I l;OO:ÒO I I - I 1 I I 1:05:00 -------..- _3.0E7 :"'2.7E7 - :"'2.4E7 - :"2.1£7 :"'1.8E7 :"'1.5£7- :"'1.2£7 :"9 .lE6 i _ - :"'6.1£6 - :"3.0£6 ; 0 .OEO Time _8.9£7 :"'8.0£7 - :"7.1E7 :"'6.2£7 - :"5.3£7 :"'4.5E7 - :"'3.6E7 :"'2.7E7 - :"1.8E7 :"8.9£6 : 0 . OEO Time Q ~ () tJ ~ ~ ~ CÐ ~ o ::¡ Z o N .....) \0 Þ-r1 åQ' ~ (1) 0\ ~ \0 .....) - ........ U\ ~ File:MPDMIOOO",13 #1-3086 Acq:16-DEC-199"' 1~:36:36 GC EI+ Voltage SIR "JOSE Sample#5 Text:FIORD-3A 8130' $97110IL001S012$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 S:5 F:2 10 O?i, ~,,4"'-' 9 0": - 80-= - 7 0": - 60-= - 50-= hÞ 4û..: ,-. Y(,l p\ø (,111- f4{ ft' - 30": 20-= 10-= o : I 30:00 253.1955 1 0 001í '~ I , I ' I 40:00 I I I ' , 45:00 ~~J~.~ , SO~OO I I S5~OO · · l~ob:oo' · i;o!:oo ' I I I 35:00 5:5 F:2 ~ 90-= 80_~ 70--= 60-= 50-= 40"': 30": f~ ~'\ f~ ~\X''' q.0 f\') - 20-= 10-= fJ. ('1-IV "v) _~ .~.JwJJAU·~~~, I I I I I I I , I I I I I I I I I I I I I I · I ' I I I b I I 35:00 40:00 45:00 50:00 55:00 1:0 :00 o : ,- I 30:00 I I ( I I 1:05:00 _1.6E7 :"1.4E7 :"1.3E7 :"1.1E7 ~9.6E6 :"'8.0E6 - :"'6.4E6 - :"'4 .8E6 i - :"'3.2E6 ::"1. 6E6 ;. 0 . OEO Time _4.4E7 :"'4.0E7 - :"'3.6E7 :"'3.1E7 - ~2.7E7 :"'2.2E7 - :"'1.8E7 - :"'1.3E7 :"'8.9E6 :"4.4E6 : 0 . OEO Time Q ~ n r! '(1) . '"CS o ::4- Z o tv -.J \0 I . ÞOyj ~. \DCÐ 000\ ;::::u-. Ut ~ File:MPDMIOOO'¡12 #1-3086 Acq:ll-DEC-199~ 20:~2:12 GC EI+ Voltage SIR 70SE Sample#15 Text:FIORD-3A 8610' $97110IL001S013$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 8:15 F:2 1 0 cr~ f'\,-n'6 - 90": - 8 0": 7 Û..: - 60": 50"': 40": - 30": 20": - 10": 0: II 30:00 253.1955 10cr~ 90"': - 80"': 70": 60": 5 0": 4 0": - 30"': 20"': 10"': o : I "I i 30:00 {.z.o ill:> ~ n\ "t\" f>S lo~,~.J~.;·~ I I I , I I 1 I I I I 1 I I 55:00 1:00:00 1:05:00 I (' I I 35:00 S:15 F:2 , ì ., I I I 40:00 I I I I I 45:00 I I I I I 50:00 f"'<:4 ~ ~1.'\ f!. f\ \-{\V ~ f1, ~ ~5If~r, J4'o~oci" '; '45~'t!~Ò~ ~55't~.·Òo'·' 1;05.ÒO .. -.~~~~. _2.2E8 :"2.0E8 :"1.8E8 :"1.6E8 - :"'1.3E8 :"'1.lE8 :"8.9E7 - :.. 6. 7E7 / - :"4.5E7 - :"2.2E7 = 0 . OEO Time _3.4E8 :"3.1E8 :"2.7E8 :"2.4E8 :"'2.1E8 :"1.7E8 - :"1.4E8 :"1.OE8 - :"6.9E7 - :"'3.4E7 =,O.OEO Time : O. OEO Time :"'1.7E7 :"8.4E6 :"'3.4E7 ':"'2.5E7 ¿ 5 . 0 E7 :"'4.2E7 _8.4E7 :"7.6E7 :"'6.7E7 :"'5.987 :"'1.387 :"'6.5E6 : 0 . OEO Time :"'1. 9E7 i _6.5E7 :"'5.8E7 :"'5.2E7 :"'4.5E7 :"3.9£7 ':"3.2E7 ':"2.6E7 I 1~OS:ÒO I IL.~ ~ tfW~. I J I I I I I I I I I 1 I I 50:00 55:00 1:00:00 I I I 45:00 I , I I I 40:00 -_L I I I 35:00 f-\~ f1J P-'" ~,o fv ",~\"L (~ (1,41 l~ o :. , 30:00 30--= 20--= 10--= 90~ 80_~ 70~ 60-':: 50-': 40-= ~~N~~. 50~OÒ I I 55~OÒ I I 1~ob:òo I 1'1;0~:ÒO I I I J I I I I I I 40:00 45:00 o -=- - - I - - (" J I I I 30:00 35:00 253.1955 5:16 F:2 100% ,~" ") ~,tt rt (2-t ~D f'l. 30-= 20-': 10-= 4û-= 60--= 50--= 80--= 70-= File:MPDMIOOOï12 #1-3086 Acq:11-DEC-1991 22:33:22 GC £I+ Voltage SIR 'lOSE Sample#16 Text:FIORD-3A 8800' $97110IL001S014$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 8:16 F:2 10m; ~X'-~ 90--= \0 \0 - - U\ .þ.. ~ ~. (þ ?" \ ~ C) a: () tj .~ !~ .~ ~ o :4 Z o N -J \0 _4.9£1 - - :"4.4£1 - - :"3.9£1 - - - :"3.4E7 - - :"2.9£1 - - :"2.5£1 - - :"2.0E1 - - :"1 . 5 E7 ii. - - :"9.8E6 - - :"4.9£6 - - . I ,: O. OEO Time _5.1£7 - - :"4.6E7 - - :"4.1E7 - - :"'3.6E7 - - :"3.1E7 - - =-2.6£7 - - =-2.OE7 - - :"1.5E1 - - :"1.0E7 - - :"5.1E6 - - : 0 . OEO Time '. - 1 I 1 I 1 1:05:00 10~~ : ~. O-=-.. I I I I I I I I I I I 30:00 35:00 40:00 I I I 45:00 1. .~... l ~~_ I I I I I I I I I I I 1 I I 50:00 55:00 1:00:00 30 20 ~ ft~ f1-') ~'1.V I'V j\l'(I'\. 90.:' 80. 70 60.:. 50'-:: 40~ 1"..1 p ~ ~ 10~ o : I 30:00 253.1955 10~ I I I I I 1 40:00 I I I r 35:00 8:17 F:2 ¡~,~~u~._ 55~OO I r 1'~ob:o'o T ' I 1~0!:OO I r I 1 I 1 50:00 ~ II I 45:00 -I 1 - 20": f'~ 30~ f'2P vv. ft'\ ?'t 60~ 50": 40-': fll, ., ^ I U"':" "/OSE 'Exp:GCMS_HRS1R File:MPDMI000112 #1-308'l Acq:12-D£C-1991 00:14:29 GC £1+ VOltage SIR Sample#17 Text:FIORD-3A 8840' $971101LOOIS015$ File Text:6000RP GCMS 231.1173 S:17 F:2 1000¡ 90~ 80-= f''\.(\ \( ÞOrj åQ' ....... Ei 8 (1) _ 0\ ....... , U. ......:J ... Q ~ n u ~ ..... ~ þd .g o ::4- Z o N ......:J \0 ;. 0 . OEO Time ~7.4E6 =-2.2E7 :"1.5E7 :"5.9E7 :"5.2E7 ~4.4E7 =-3.7E7 =-2.9E7 :"6.6E7 _7.4E7 ~8.5E6 ;. O. OEO Time :"1.7E7 :"2.5E7 =--3.4E7 ~5.1E7 :"4.2E7 :"6.8E7 :"5.9E7 _8.SE7 :"7.6E7 I l~OS:ÒO · t'N~~ ,_ , · I I · · 1 ~ 00: 00 · 55:00 . f'0 fi} ft\t\'l. ~~N.w~ , 1 ~ 00 : <> 0 I . I 1 ~ O~ : Ò Ö f I I I 55:00 C-1\ W( UiJ I . ~II. ~Ñ'/o . µM I I I I 50:00 I I I I . 45:00 I ----...-Jv..L. LA-Ali I I I I . , I I I 35:00 40:00 0:. I 30:00 30~ 20-': 10": 4 0": 6 0": 5 0": " 7 0-': 90~ 80": o : I 1 30:00 253.1955 10 0?i3 30"': 20~ 10": An - ...V~ 80~ 70~ 60": 50": File:MPDM1000112 #1-3~81 Acq:12-DEC-1997 01:55:33 GC E1+ Voltage SIR 708& Sample#18 Text:FIORD-3A 9120' $97110IL001S016$ File Text:6000RP GCMS Exp:GCMS_HRSIR 231.1173 8:18 F:2 lOO'i {dt1~ 90": ~:rL (.-t.~ ft #' f1 ç{ f~ Lo - ~1~·~' I' - ¡ I. I I I I I 35:00 40:00 8:18 F:2 . . I · ." 50:00 ." . I · 45:00 f-<~ f'1 - o - - - Ut +:r.. l. ~ QQ' E; (!) ?' 00 / Q ~ (') ö ~ .-+ ~ :::0 ~ o :¡ Z o tv .......¡ \D :"2.4E7 I , II I r, , I. '. , , ) , . , r , , ~, I/) , (I Î, r-. ~ ~ I f I í . ~ ' i , . í""'I I ,-;: O. OE? 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 30:00 T1me :"7.3E7 :"4.8E7 :"9.7E7 :"1.2E8 :"1.5E8 :"1.7E8 :"'1.9E8 _2.4E8 :"2.2E8 ~1.2E8/, :"7.7E7 :"3.8E7 I 0 . OEO 30: 00 Time :"1.9E8 :"1.5E8 _3.8E8 :"3.5E8 :"3.1E8 :"2.7E8 :"2.3E8 , I I I I I 29:00 I I I , I , 28:00 " I ({"\~~Im '-~I'~'~'" I (;' I I" 21:00 22:00 23:00 24:00 25:00 26:00 27:00 I , I , I , I I I , I . , 19:00 20:00 30~ 20-': 10--': 0: , I 18:00 40-': - 80~ 70~ 60-': 50-': 90--= , I I ) , 20:00 0: ",ril"'" 18:00 19:00 192.0938 5:3 10~ 30--= 20-': 10~ 60--': 50~ 40-': 90-': 80-': 70-': File:MPDMI000112 #1-1291 Acq:l0-DEC-1997 15:41:11 GC EI+ Voltage SIR ?OSE Sample#3 Text:FIORD-3 4020' $97110ILOOlS001$ File Text:6000RP GCMS Exp:GCMS_HRSIR 178.0782 S:3 10~ -----------~---"_...' P7j õ~· No ;.::;-....} Ut . ~...... o ~ (') ~ ~ ~ þd ~ o ':4 Z o tv -....J \Ç) C) ~ n tJ ~ ~ .~ ( ) . "d o ::¡ z' o ··N -.) \0 ~ ôQ' E; (þ -...1 N i \ ----- - <=> W - - Ut .¡::.. File :MPDMIOOO"¡12 #1-1291 Acq: 10-DEC-199"' 1', :22 :26 GC EI+ Voltage SIR 70SE Sample#4 Text:FIORD-3 4140' $97110IL001S002$ File Text:6000RP GCMS Exp:GCMS_HRSIR 178.0782 S:4 10~ 90-= - 80-= 70-= - 60-= 50-= 40-= - 30": 20": - 10-= O~~-r,-¡-, I r, II I II I III ,),'~-~''rl-I~(I~II~ I II I 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 192.0938 5:4 1 0 001j 90": 80_~ 70-= 60": 50-= - 40": 30": - 20-= - 10-= I I I I I I I I I I I I I I I I I I I I I I I 11. L. I I I I I I , I r I ,I I II I I 19:00 20:00 21:00 22:00 23:00 24:00 25:00 ---- I I I I I I 26:00 If I I r ~ I ~ ~ I 27:00 28:00 - O~ 18:00 I I I t I I 28:00 I I I I I I I 29:00 .... - r I I I I I I 29:00 _S.2B8 - :"4.7E8 :"4.2E8 :"3.7E8 :"3.1E8 :"2.6E8 :"2.1&8 - :"1.6E8 ¡ :"1.0E8 - :"5.2E7 - I I - 0 . OEO 30: 00 Time _3.4E8 :"'3.1E8 :"2.7E8 - :"2.4E8 :"2.1E8 - :"1.7E8 - :"1.4E8 - :"1.0E8 :"6.9E7 - :"3.4E7 - : 0 . OEO I I 30: 00 Time C) ~ n H ~ ~ ~ :~ o ::¡ -z o ·N -l -~ I-rj ~. ~ - ~ ~ File:MPDMIOOO?12 #1-1291 Acq:10-DEC-1997 19:03:38 GC EI+ Voltage SIR ?OSE Sample#5 Text:FIORD-3 4740' $97110IL001S003$ File Text:6000RP GCMS EXp:GCMS_HR8IR 178.0782 8:5 10~ - 90"': 80"': - 70"': 60"': 50"': 4 0"': - 30"': 2 0"': - 10~ o =~I-r 11" II Y lì ) I I I I 18:00 19:00 20:00 192.0938 S:5 100~ 90"': 80-= - 70--= 60-': 50"': 40"': 30"': - 20--= - 10"': o = 18:00 . . I I I I . J . I . J I 19:00 20:00 '- ^ I , 11~'Tîî . ¡ ry. 1 21:00 22:00 23:00 ('' ~I'~ 1 ,-r-, 1("'- 24:00 25:00 26:00 27:00 . I I · · , 1 1 I . , , 28:00 29:00 A I 1 I I . 1 . I I "I I J , , I ' I , , I I ' J . I . (I 'î, r J í"ì' J - . r I ' ,1 , '¡- 0 1 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 ,'--. , I I Tì 29:00 -...,... . ^::=:i1r .---:t -~-- _7.2E8 :"6.SE8 - :"S.7E8 :"S.OE8 :"4.3E8 :"3.6E8 :"2.9E8 - :"2.2E8 j _ :"1.4E8 - =--7.2E7 - - 0 . OEO 1 1- 30: 00 Time _5.1E8 :"4.6E8 - :"4.1E8 :"3.6E8 - :"3.1E8 :"2.5E8 :"2-.0E8 :"1.5E8 :"1.OE8 - =--S.lE7 = 0 . OEO I I 30: 00 Time J. ___ _" ' ..", . .I. ~ I I I I I I I I I I I I r I I r I I I I I I I I , I I I ( , 1 I I 11 I I I I I 22:00 23:00 24:00 25:00 26:00 27:00 28:00 I I I I I I , , 1 I 1ft I I I ' I I 19:00 20:00 21:00 0: . . 18:00 :"'2.9E7 :"'2.0E7 :"'9.8E6 . _ . I ..............-: 0 . 0 E 0 I I I " I I 29: 00 30: 00 Time _9.8E7 :"'8.8E7 :"'7.8E7 :"'6.9E7 :"'5.9E7 :"'4.9E7 :"'3.9E7 ) t ;: 0 . OEO 30: 00 Time :"1.3E7 =-4.0E7 :"2.7E7 =-9.3E7 , :"'8. OE7 =-6.7E7 :"'5 ,,3E7 :"'1.1E8 =-1.2E8 _1.3E8 '-'I'J"'I~'~'~'~""'~""" 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 10-= 30 20 90-= 80-= 70-= 60-= 50-= 40-= 0: ,...., l' I -r I I t I "I 18:00 19:00 192.0938 S:6 100% 30-= 20-= 10-= 4û-= 60-= 50-= 90-= 80-= 70-= File:MPDMI000712 #1~1291 Acq:10-DEC-1997 20:44:50 GC EI+ Voltage SIR 70SE Sample#6 Text:FIORD-3 6240' $97110IL001S004$ File Text:6000RP GCMS Exp:GCMS_HRSIR 178.0782 8:6 1000¡ - o VI - - VI ~ Þï1 ðQ' E; (1) -...] ~ Q a:: n t1 Š ~ ~ o ::¡ Z o N -J \0 C) ~ n o ~ ~ ~ ~ ~ o :4 Z o N -.J \0 ~ dQ' ~ - (1) ~ - :---J - u. 't. File:MPDMIOOO'l12 #1-1291. Acq:l0-DEC-1997 22:25:~8 GC EI+ Voltage SIR 70SE Sample#7 Text:FIORD-3 6600' $97110IL001S005$ File Text:6000RP GCMS Exp:GCM5_HRSIR 178.0782 5:7 10~ 90-= 80-= - 70~ - 60-': 50-= - 40-= - 30-= - 20-= 10-': - 0: ~I ( I I I I I I 18:00 19:00 192.0938 S:7 100~ 90-= - 80-= 70-= 60_': 50-= - 40-= 30-= - 20-': - 10-': - 0: 18:00 11-' I ' I I II) "f")~1 mk í,,--r (I~ I r¡-, I I~I I I · 20:00 21:00 22:00 23:00 24:00 25:00 26:00 I I . I . I I I I I I I I 19:00 20:00 I~I 27:00 '\. ,,--,;.,,-,-y,'£"'-,-~~-_..- ~-' _6.4E8 :"5.7E8 :"5.1E8 - :"4.5E8 :"3.BE8 :"3.2EB - :"2.5E8 ;1.9E8 i . - :"1.3E8 - :"6.4E7 - ~ =O.OEO rll~ 2 B : 00 29 : 00 30 : 00 Time' A ~ 1 I I I I I I 1 I 1 I I I 1 I I I I 1 I I T 1 I"") I rr "1"" 1 r I í1" I I .....1 I '\ -I .. I . I I I 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 '-- -" I I 1 I I r I 29:00 _2.7E8 :"2.4E8 - :"2.2E8 - :"1.9E8 ¿ 1 . 6E8 ":"1.4E8 - :"1.1E8 - :"B.2E7 - :"5.4E7 - :"2.7E7 = 0 . OEO I I 30: 00 Time ...." ... ¿ ~ 'ì ...... _: 0 . OEO , , I · , 1 , , I I I r 'I"" r 27:00 28:00 29:00 30:00 Time ,r, I' "" 0"1, (, Ir. 24:00 25:00 26:00 ^ I , , I I I , J , I I I , I , I ' , J , , I J , I , I I I . 19:00 20:00 21:00 22:00 23:00 0: I , 18:00 :"'1.5E7 :"4.5E7 :"3.0E7 :"6.0E7 ¿1.3E8 :"1.2E8 :"1.0E8 :"'8.9E7 ¿7.4E7 _1.5E8 ~ O.OEO , I I J , , , , 29 : 00 30 : 00 Time ~ I , , I' , , , " I ' f , 27:00 28:00 ~./'-fi..~ ' ~ , I I · (. -, - I r ' , , , , r ' r, I , I .1 .' -, I. I.- I _' , , I , I J , 21:00 22:00 23:00 24:00 25:00 26:00 :"'2.3E7 :"4.6E7 :"6.9E7 ¡ :"1.8E8 :"1.6E8 :"'1.4E8 ¿ 1 . 1E8 :"9.2E7 _2.3£8 :"2.1E8 10"': 20-': 30-': 60-= 50-': 4 0-': 80-': 7 0-': 90-': o : ......., f I I , I ' , , I I I I I I 18:00 19:00 20:00 192.0938 S:8 10~ 20-': 10"': 30-': 40": 60-= 50-': 70"': 80"': 90-': File:MPDMIOOO-'12 #1-1291 Acq:ll-DEC-1997 00:07:06 GC EI+ Voltage SIR 708E Sample#8 Text:FIORD-3 6750' $97110IL001S006$ File Text:6000Rp·GCMS EXp:GCMS_HRSIR 178.0782 S:8 10~ - o -J - - U. .f::o. \- - ~ dQ' E; (tI :---J 0\ Q a: n t) ~ ~ ~ (t)- Þ'Cj o :4 Z o N -J 1.0 o a:: () t; .. ...,. ~ ~ ~ o :4 Z o N -.) \0 'Tj ôQ' - ~ 0 (I) ~ -.) - :..;.<t. '. - - - - - - - - - . - . . .-. . . . .- .-.-.- File:MPDMI000712 #1-1291 Acq:11-DEC-1997 09:05:10 GC EI+ Voltage SIR ?OSE Sample#9 Text:FIORD-3 6770' $97110IL001S007$ File Text:6000RP GCMS Exp:GCMS_HRSIR 178.0782 S:9 10a!E 90-= - 80-= - 70-= 60'-: 50": - 40-= - 30-': 20-= - 10'-: - 0= l' ,..-. I I . - . 18:00 19:00 192.0938 5:9 10~ " fl' I 20:00 · I . J .f' ~ f '} ~ 'TI"íT-'. 11""( 21:00 22:00 23:00 24:00 90-': - 80-= - 70'-: 60'-: 50-': - 40-= 30-= 20": 10'-: o : · , , · , I · · , , , J ' , I , , J ' I 18:00 19:00 20:00 21:00 ~" I I I I r , , I I 1 . 25:00 26:00 I' , I'"' A·, I ' , , 22:00 23:00 . . I ' · 24:00 I í, I --;--rr . r I ~ 25:00 26:00 _4.2E8 :"3.8E8 - : ":» A'DO _.,J . ...... u - :"3.0E8 - :"2.5E8 -=-2.1EB - :"1.7E8 - :"1.3E8/ - :"B.4E7 - :"4.2E7 ~O.OEO , ~-¡-¡- I I .- I . r I ,.. T I I I . I , , f 27-: 00 28: 00 29: 00 30: 00 Time _3.1E8 - :"2.8E8 - :"2.5E8 - :"2.2E8 - :"1.9E8 :"1.6E8 :"1.3E8 :"9.4E7 :"6.3E7 :"3.1E7 .- 'l r ,- .) I I~ I 27:00 28:00 - '- _: o. OEO . I I I ' I , 'I _ 29:00 30:00 Time ~. ,.., ^----.= O.OEO I I f I I I I I 1 ( I I I I 28: 00 29: 00 30: 00 Time I I 'r"""'" I r-rr ·,'1 I ') ,-¡ I II I f'IY"\ I'I~ r. I"";'"-í-I~'I~ 21:00 22:00 23:00 24:00 25:00 26:00 27:00 I I I I I ( 20:00 o : I I 18:00 :"1.187. :"'2.2E7 :"3.3B7 :"'8.887 :"7.7B7 :"6.687 :"'5.587 :"'4.4B7 _1.lE8 :"'9.9E7 , ( I I " I 19:00 30": 20": 10": 50": 4 0": 80": 7 0": 60": 90": :"'2.2E7 _' ;: 0 .OEO I I I I . I I . 29 : 00 30 : 00 Time I I 'f I 'I~I ( I I I I I 27: 00 28': 00 Ilr~~I'~I~II'"'" 21:00 22:00 23:00 24:00 25:00 26:00 o : ^ - r ,- - . . I I I ( I I (., I I I , 18:00 19:00 20:00 192.0938 S:10 1000~ :"4.4E7 :"6.5E7 / - ð .,~." =-a.'~' :"'1.7E8 :"'1.5E8 :"1.3E8 :"1.1E8 :"2.0E8 _2.2R8 30": 20-': 10": 40-= 60": 50": 70": 80-= 90": File:MPDMI000712 #1-12~1 Acq:11-DEC-1997 10:46:27 GC EI+ Voltage SIR 70SE Sample#10 Text:FIORD-3 7020' $97110IL001S008$ File Text:6000RP GCMS gxp:GCMS_HRSIR 178.0782 5:10 10~ ....... o ~ ....... Ut ..þ. Þ-r1 åQ' E; (1) :--J 00 ~ Q ~ (') t1 ~ ~ :;d (t) "0 o :4 Z o N -.J \.0 --> ...-... - I r ..... ^ ^ ~ ~ -, -------.) c -~: 0 .OEO I I I I 1 I 1 I. 1 1 I I 1 J I I 1 1 I I I I I I . I . I 1 I I I I I I I r I . 1- 1 1 I I I I I I 1 I I I 1 I 1 1 I I I 19:00 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 30:00 Time :"3.7E7 :"l.BE7 :"S.5E7 :"7.4E7 _l.BE8 :"l.7E8 :"1.5E8 :"l.3EB :"l.lE8 :"9.2E7 :"5.2E7 :"2.6E7 - 0 . OEO 30: 00 Time =- 7 . BE7 / =-l.OES :"l.6ES =-1.3ES- :"1.8E8 _2.6E8 :"2.3E8 :"2.lE8 0: . I 18:00 30 20 10 50 40 70 60 80-': 90-': I I 1 I . 1 I I I I 1 I 28:00 29:00 I I I I 27:00 .~ 1""'\lrllll~~I III'I " 21:00 22:00 23:00 24:00 25:00 rlr , I 20:00 0: ^ I r') r. I~ 18:00 19:00 192.0938 5:11 100~ I I I I 1 1 1 26:00 30-': 20-': 10-': 50-': 40-': 60'-: 7 Û-.: 90-': 80~ File:MPDMI000712 #1-1291 Acq:11-DEC-1997 l4:0~:l4 GC EI+ Voltage SIR 'lOSE Sample#11 Text:FIORD-3A 4800' $97l10ILOOlS009$ File Text:6000RP GCMS . Exp:GCMS_HRSIR 178.0782 5:11 10~ e_ ~. ":. "",.~""'-,--, "'T:"'~· - ~"'-~""'~-~~'~Y"'0 .-.~'-'" ~.'"-"j: -i~. ;'-~_i~'-;''''' I ~ ~. ....... o ....... 00 0 , - ....... ....... U'I ~ C) E:: n i ~ '" ~ o ::t. Z o N -.) \0 - : O. OEO I J 30: 00 Time :"9~6E7 :"6.4E7 :"'3.2E7 !- _3.2EB :"2.9EB :"'2.6EB =-2.2EB :"'1.9EB :"'1.6E8 :"1.3E8 :"'1.4E8 :"'7.1E7 ,= O. 0 E 0 30: 00 Time :"'2 . lE8 ¡ . - ~ A._A =-.¿.O.l!iO :"'5.7E8 :"'5.0E8 :"4.3E8 :"'3.6E8 _Î.1R8 :"'6.4E8 A. ~- .~ ---. . - ~ '... ~. ....,. ( I 1 I I I I I I I I I 1 I I I I I I',' 1 ( I I 1 I I I 1 1 I i I I I f 1 I J . I," (1' I' J , 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 I I I I I I I I 1'1 I I I I I I I 19:00 20:00 21:00 40--= 30--= 20--= 10": 0: . I 18:00 7 0": 60-': 50--= 90--= 80--= I I r 1 J I J 29:00 I I I I I I I I I ,~{\ '~î(-(' ì r (I~ I I rïl I~ I I r""'" I I I I I 1.1 J J 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 o : ......., ~ I , I I I I ., 18:00 19:00 192.0938 5:12 100% 30-= 20--= 10": 4û--= 70--= 60": 50--= 80--= 9 0": File :MPDMIOOO',12 #1-12~1 Acq: 11-DEC-199"' 1~ :48: 31 GC EI+ Voltage SIR -JOSE Sample#12 Text:FIORD-3A 8010' $97110ILOOISOIO$ File Text:6000RP GCMS - Exp:GCMS_HRSIR 178.0782 S:12 10~ - - - - - Ut .¡:.. 'Tj åèj' £; (þ 00 tv C) ~ (') tJ ~ .~ ~ ,(1) ~ o ::4- Z o ""tv -J \0 C) ~ n i ~ :;d ~ o ::+ z o N -1 \0 "'Tj åQ' ~ ( ) 00 W r.L.L~:MPDMIOo-U-/.l2 #1-1291 Acq:l:ì"':ÓEC-1997 17:29:47 GC EI+ Voltage SIR 70SE Sample#13 Text:FIORD-3A 8100' $97110IL001S011$ File Text:6000RP GCMS Exp:GCMS_HRSIR 178.0782 S:13 1 0 0C!f 90-= 80": 70": - 60-': 50-= 40-= 30": - 20": 10-= o : ~I - r 1 I 1 I ~ 1 "'I I I I 1 1 18:00 19:00 20:00 192.0938 8:13 10~ - 90": - 80-= / - 70-= 60-= 50-= 40-= 30-= 20-= 10-': 0= 18:00 _____~_~~.J'" _4.0E8 =-3.6E8 - =-3.2E8 : I) aDO _..... .....~u - :"2.4E8 - =-2.0E8 =-1.6E8 - :"1.2E8 - :"8.0E7 =-4.0E7 r--..J'. -..... ^ ~. ~ ~ _______________= O. OEO -' 1 II 1 1 1 1 ['1"-'1 ~ -' I -. _' ,-, I 1 . 1 -) 1 1 -I I" I 1 1 I "I 1 ... I 1 f I 1 1 I 1 1 I , I I I I ' I 1 _I I 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 30:00 Time _1.7E8 :"1.6E8 - :"1.4E8 - =-1.2E8 - :"1.0E8 =-8.7E7 =-7.0E7 - :"5.2E7 :"3.5E7 ^ - 1 . 1 Î 1 1 1 1 1 ' I 1 { 1 1 .- .- . -. . ~ I Î I ,---;-- 1 I 1'-' ,Î ~ 1 ~ 1 22:00 23:00 24:00 25:00 26:00 27:00 28:00 - :"1.7E7 1 I I I 1 1 1 . . 1 1 . 1 I" I 1 . I 19:00 20:00 21:00 - l --------.,=O.OEO I 1 1 I 1 1 1 1 I 29 : 00 30 : 00 Time - - N - - U\ .þ.. Q ~ n tj ~ ~ :;;d ~ o ::¡ Z o N -.) \0 "T1 ùQ' E; (1) 00 ~ File:MPDMI000713 #1-1291 Acq:16-DEC-1997 15:36:36 GC EI+ Voltage SIR 70SE Sample#5 Text:FIORD-3A 8130' $97110IL001S012$ File Text:6000RP-GCMS Exp:GCMS_HRSIR 178.0782 8:5 10m.; 90-= - 80-= 70-= - 60-= - 50-= - 40--= - 30-'-: 20-'-: 10--= 0: 1 I r I I I I 1 18:00 19:00 192.0938 8:5 1 0 001\ 90": - 80": - 70--= - 60-= 50": 40": 30--= 20-= 10-= 0: 18:00 _4.9E8 :"4.5E8 :"4.0E8 :"3.5E8 - :"3.0E8 :"2.5E8 :"2.0E8 - :"1.5E8 :"9.9E7 :"4.9E7 : 0 . OEO , I 30: 00 Time I , I ' · · · , Í' 1'Y'\ , f' ('Y. . 1 ' · · .~. , , ,", I r .""Y', , I ,", , n fl., , , I ' , , , , I ' , , 20:00 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 I r J I I I r . I I I 1 19:00 20:00 ~_..--...__. - - w - - VI .þ. I I I I I I 21:00 I I IT' f\-. 22:00 I r I I I I r I I I I I 23:00 24:00 I I ïî rl III I , '11 I' ( I 25:00 26:00 27:00 ~ l I I I I . r 28:00 _1.3E8 :"1.2&8 :"1.1E8 :"9.2E7 - :"7.9E7 :"6.6E7 :"5.3E7 :"4.0E7 :"2.6E7 =-1.3E7 "- : O.OEO I . I I I r I I 29 : 00 30 : 00 Time Q a:: () \0 (š ::;d ~ o :;¡ Z .0 N . ......,J \0 Iïj åQ' Ei (1) ::po .þ..¡¡ - - U\ ~ . ~.~ ............ -.-...... ,-·,->----'v., ,:¿¡.-...; - c-w ,'¡..v,... ~:etT-;.ji-"'~~;~ File:MPDMIOOO~12 #1-1291 Acq:ll-DEC-199~ 20:~2:12 GC EI+ Voltage SIR 10SE Sample#15 Text:FIORD-3A 8610' $97110IL001S013$ File Text:6000RP GCMS -Exp:GCMS_HRSIR 178.0782 8:15 100% - 90-= - 80-= - e'J1\: I u_ 60-= 50-= 40": - 30-= 20-= - 10": o:~ - ....... _ -\ I , ( . , r I I I . 'I I 18:00 19:00 20:00 192.0938 8:15 100% - 90-= - 80--=: 70": - 60-': 50--=: 4 O--=: - 30": - 20--=: 10": 0: 18:00 , , . I ' , · 19:00 , , I I · 20:00 f .-, I~~~IIII' IIIII I II J I II 21:00 22:00 23:00 24:00 25:00 26:00 I . I I ' r I 21:00 I I I-i I~ 22:00 I . I I I I 23:00 i I I . I 24:00 I I , I I 27:00 '-II~JI~J 25:00 26:00 27:00 I I J- I J I J 28:00 ~ J J I I I 28:00 _3.9E8 - =-3.5BS - =-3.1B8 - =-2.7E8 - =-2.3B8 =-2.0BS - =-1.6B8 - =-1. 2BS I. - =-7.8B7 - =-3.9B7 ~- ~ O.OBO . J I T J", J J 29 : 00 30 : 00 Time _1.7BS =-1.5B8 - =-1.3ES =-1.2BS - =-9.9E7 :"8.3E7 - =-6.6B7 - :"5.0E7 - :"3.3E7 =-1.7E7 ~:O.OEO I . I I J I , J J 29:00 30:00 Time Q a:: (") t:1 .~ ~ ~ þd ~ o ::¡ Z '-0 N ~ ~ äq' ~ (Ð 00 I 0\ I L_ Þ-" Þ-" VI - Þ-" VI .¡:.. File:MPDMIOOO"'12 #1-1291 Acq:11-DEC-199"¡ 22:33:22 GC EI+ Voltage SIR ",OSE Sarnple#16 Text:FIORD-3A 8800' $97110IL001S014$ File Text:6000RP GCMS -Exp:GCMS_HRSIR '178.0782 S:16 100% 90'-: - 80'-: 70": - 60'-: 50'-: - 40": - 30'-: 20": - 10'-: 0: ..ñ-, ( , , , I ' ,- , . -, I ' I 18:00 19:00 20:00 192.0938 8:16 10® 90'-: - 80'-: 70'-: 60'-: 50"': 40": - 30'-: 20'-: 10'-: - 0: . , 18:00 . I I I"Î~I ~~11~ IÎ '" I~I 1 rl 11~-Î-I' '--I 21:00 22:00 23:00 24:00 25:00 26:00 I I I I I , 1 I I r I 1 1 1 I I 1 I 1 19:00 20:00 21:00 A I I I I I 1 I 1 I 1 1 I I 1 I I I 1-' J (ì''' I 11 (!' I 22:00 23:00 24:00 25:00 26:00 I"' I 1- ,- I~' I I 1 I 27: 00 28,: 00 .Î I 1 1 '1 27:00 ~ 1 1 I 1 1 28:00 _5.3E8 - :"4.8£8 - :"4.2E8 :"'3.7£8 -=-3 .2£8 c :"2.6£8 - :"2.1E8 - :"1.6£8 / - :"1.1E8 - :"5.3E1 " ~O.OEO 1 1 I I ' , 1 1 1 29 : 00 30 : 00 Time _2.4E8 :"2.2£8 - :"1.9E8 :"1.7£8 :"1.5£8 :"1.2E8 - :"9.7£1 - :"1.3£7 - :"4.8£7 :"2.4£1.. - ~ r~,nT" r'-= 0 .OEO I 1 1 I 1 29: 00 30: 00 Time C) ~ ~ t") ~ þ) ~ ~ o ~ Z o tv -.J .\0 File:MPDMIOOO'/12 #1-1291 Acq:12-DEC-199ï 00:14:29 GC EI+ Voltage SIR Sample#17 Text:FIORD-3A 8840' $97110IL0018015$ File Text:6000RP GCMS 178.0782 S:17 10~ 90": - 80": 70~ 60": - 5 0": 40"': - 30"': 20": - 10'-: - o =c- I f I " I I "I '-I 18:00 19:00 192.0938 8:17 1000~ - 90": 80": 70': 6 0": 50": - 4 0": - 3 0": "'rj ciQ' ~ --00 ~ ~ - 20': 10"': 0= 18_ : 0 0 , ,......~ --~- ---.J '-^ 'I 11'1 I III I I I'" I 1'1 I' r" I II') 20:00 21:00 22:00 23:00 24:00 , , I ' , I , , I ' , I · · I I , 19:00 20:00 21:00 ¥ , I , I ' I ^ f I I ' , , 22:00 23:00 "lì~'I'1 25:00 26:00 , , II 1 ,", -I If I 24:00 25:00 "/ 0 SE Exp:GCMS_HRSIR I I , I 1 , I I I I I , I I , I I I I 27:00 28:00 29:00 11 I (f' . , I q. I · ,-) , ~ ' 26:00 27:00 28:00 ~ ~ ,-, , I ' r , 29:00 _4.4E8 - :"3.9E8 - :"3.5E8 :"3.0E8 - :"2.6E8 :"2.2&8 - :"1.7E8 - :"1.3E8 i - :"8.7E7 - :"4.4E7 =O.OEO , , 30: 00 Time _2.8E8 :"2.6E8 - :"2.3E8 :"2.0&8 :"1.7&8 - :"1.4E8 - :"1.1E8 - :"8.5&7 - :"5.7E7 -:"2.8E7-",. : 0 . OEO I , 30: 00 Time : 0 . OEO 30: 00 Time :"5.5E7 :"3.6£7 :"1.8E7 _1.8E8 :"1.6£8 :"1.5£8 :"1.3E8 :"1.1E8 ¿9.1E7 :"7.3E7 30: 00 Time :"1.6£8 ¿.1.2£8 :"8.2£7 ~4.1E7 - 0 .OEO :"3.3£8 :"2.928 :"2.528 :'2.0E8 _4.1£8 :"3.7£8 - - ......) -- - VI ~ ---,------ --"- ... "- I I I I , 29:00 ~ òQ' E; (Ð 00 00 ...,. <^- ~~..- --- ,~ , , I I I , I I , I ~. ~. I , , r J ì , r I r r I I , I I I , I 24:00 25:00 26:00 27:00 28:00 , , , I ' , I , I I ' I , , , I I , , , I I I " ( I , I I I 19:00 20:00 21:00 22:00 23:00 10 o 18:00 30~ 20": 40~ 50": 70": 60-= 80~ 90": I I ,";'"~,-lï^t r'Î', ~, ,~,',", , I' , '~, I,"' (, I"I~-') I ,"~,~ I 21:00 22:00 23:00 24:00 25:00 26:00 27:00 28:00 29:00 0: ^- I 1 I I I , ) , 18:00 19:00 192.0938 8:18 10 00:11 , ,- I , I ) , 20:00 30": 20": 10-= 4û..: Q ~ () t1 :I.) ..... ~ ~ (1) "'0 o :4- Z o N ......) \D File:MPDMI000712 #1-1~91 Acq:12-DEC-1991 01:5~:33 GC EI+ Voltage SIR -lOSE Sample#18 Text:FIORD-3A 9120' $97110IL001S016$ File Text:6000RP GCMS~ £xp:GCMS_HRSIR 178.0782 S: 18 10~ 90": 8 0"': 70-= 60-= SO": Q ~ ~ ö ~ ~ :;d ~ o :4- 'z o N . -.) '. \0 ~ ....' {JQ -Ei -cD ~ -' ~ .¡:. File:MPDMI000112 #1-1291 Acq:10-DEC-1991 1~:41:11 GC EI+ Voltage SIR 7GSE Sample#3 Text:FIORD-3 4020' $97110IL001S001$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 8:3 10m; - 90"': 80": "7n: , ,,- 60": 5 0": 4 0": 30"': 20": - 1 0": o~..... I' .~. ~I" "7"^r~¥'¡IM, 10:00 12:00 14:00 16:00 18:00. 198.0503 S:3 10005 ~ 90": - 80"': - 7 0": 6 0": 50": - 4 0": 30": - 2 0": - 10": 0: I I 10:00 ;-~. 20:00 I . I I I 14:00 I , I I I I I I I I . I I . I I I I I 16:00 18:00 20:00 I I I I - I I 22:00 I I I I I I I 12:00 I I I I I 24:00 ~ '. '-C-I -.' I-I~'- · 26:00 28:00 -. I I , 1'-^.1 ~ 'I ,"I I 26:00 28:00 - -. -~- -V'.',\ '¿1"-:-:'" .~..-.:"" _1.6E8 :"1.4E8 - :"1.2E8 =-l.lES - :"9.3B7 - =-7.8E7 - =-6.2E7 - :"4.7E7 / r- r- :"3.1E7 - =-1.6E7 ~ 0 .OBO ( r· 1- - 30 : 00 Time _1.0E8 :"9.1E7 - :"8.1E7 =-7.1E7 - =-6.1E7 :"5.1E7 - :"4.1E7 - :"3.0E7 :"2.0E7 =-1.0E7 - ^ ^ ~: 0 .OEO I ' ) I 30: 00 Time Q ~ () t:I ~ . ~ ~ .~ .(1) "t:j o ::¡ Z ..0 tv -.J \0 Þyj äQ' E; (þ \0 N ....... ...- \0 - ...- Vt .¡::.. File:MPDMIOOO'/12 #1-1291 Acq:10-DEC-1997 17:22:26 GC EI+ voltage SIR 70SE 8ample#4 Text:FIORD-3 4140' $97110IL001S002$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 5:4 100?£ 90"': - 80"': - 70"': - 60-': - 50'-: - 4û...: 30"': 20"': 10~ 0: I , I I , I ' , ~ 10:00 12:00 198.0503 8:4 100% - 90"': 80'-: 70"': 60": 50'-: 40_: - 30'-: - 20-': 10'-: o : 10:00 , ~ I ' ., ""^r~'\:"I A/l.~"I " 14:00 16:00 18:00 ·20:00 , I , I ' , I , I I I , I , I I I , , 12:00 14:00 16:00 I , I ' , , 18:00 , , I ' , 20:00 _2.4&8 - ~2.2E8 - ~1.9E8 :"1.7E8 - :"'1.4E8 :"'1.2E8 - ~9. 6E7 - =- 7 .2E7 ¡ =-4.8E7 :"2.487 =. 0 . OEO 30: 00 Time I , I I I , , I , , I , , , I , :",-,1 ~... I ' , 22:00 24:00 26:00 28:00 _1.8E8 :"1.6E8 :"1.4E8 :"1.2E8 ~1.1E8 :"8.8E7 ~7.0E7 - ~5.3E7 ~3.5E7 :"1.887 ^..._.=O.OEO ,-) , 30: 00 Time C> ~ n t1 ~ ~ ~ ~ o ::¡ Z o tv -J \0 "'T1 óQ' ~ I-' ( ) tv \0 ~ W ~ .þ.. File:MPDMI000712 #1-1291 Acq:10-DEC-1997 19:03:38 GC EI+ Voltage SIR ?OSE Sample#5 Text:FIORD-3 4740' $97110IL001S003$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 S:5 10~ 90-= 80-= - 70-= 60": 50": 40-= - 30~ 20": - 10: 01 . .. .. I .. ~ · ~ I .. 10:00 12:00 14:00 198.0503 S:5 10~ - 90-': 80": 7 0": 6 0": 5 0": - 4 0": - 3 0": 2 0": 1 0": 0: , I I 10:00 , I I I 1 12:00 I 1 , I 1 J 1 I , I I I I 1 , I ' I I I I I I , I 1 I I I I I 14:00 16:00 18:00 20:00 22:00 I J., -I ^I_~';"'^~~..A, ¥{\r.( ~^-1- 1 I I I , 16:00 18:00 20;00 22:00 I I I 1 , , , I I I I I I I I I , 24:00 26:00 28:00 I I I ' , 24:00 . . -} '. - 11"IIMltll 26:00 28:00 ~---""-'-__:''''''¿-:~f~--'':~~ -l-' ~~~~~ -~ _3.3E8 :"3.0E8 - ~2.7E8 '~2 .3E8 - :"2.0E8 - :"1.7E8 :"1.3E8 - :"1.0E8 / - :"6.6E7 - :"3.3E7 - 0 . OEO I -I 30: 00 Time _3..5E8 - ~3.1E8 - :"2.8E8 :"2.4E8 :"2.1E8 :"1.7E8 - :"1.4E8 :"1.OE8 - :"6.9E7 :"3.5E7 I 1\ ^I~ .= 0 . OEO 30: 00 Time o ~ (1 t::1 ~ ~ :::c ~ o ::¡ Z o N -.) \Ó '"rj òQ' ~ (1) \0 ~ I--" N I--" - I--" lit ~ File:MPDMI000712 #1-1291 Acq:10-DEC-1997 20:44:50 GC EI+ Voltage SIR 70SE 5ample#6 Text:FIORD-3 6240; $97110IL0015004$ File Text:6000RP ~CMS EXp:GCMS_HRSIR 168.0939 8:6 10® 90-= - 80-= 70-= ~ 60~ 50-= 40-= - 30-= 20-= 10-= 0: I I I I I I I ,~ ~ I I -, I 10: 00 12: 00 14: 00 198.0503 5:6 10005 90-= - 80-= 70-= 60~ 50-= - 40-= - 30-= 20-= 10~ 0: 10:00 I I I I I I I 12:00 I (' I I I 14:00 _6.8E7 :"6.1&7 - :"5.4E7 :"4.7&7 - :"4.1&7 :"3.4&7 - :"2.7E7 - :"'2.0&7 :"'1.4E7 - ~ :"6.8E6 ..~ ~-.. ~O.OEO 11~I"IIIIIIIIIIIIII"11111"111111111 . 16 : 00 18 : 00 20 : 00 22 : 00 24 : 00 26 : 00 28 : 00 30 : 00 T J.me . 1 I I I I I 16:00 u. J~, ._ I I 1 I I I I I I I I I 26:00 28:00 I I I I I 18:00 I I I I . I 20:00 I I I I I I 22:00 I I I I I . 24:00 _2.0E7 :"1.8E7 - :"1.6E7 :"1.4E7 :"1.2E7 :"1.0E7 :"'8.0E6 - :"6.0E6 :"4.0E6 - :"'2.0E6 - I A, ^ (' ¿= 0 .OEO 30: 00 Time \ ~ åQ' ~ - CD N \O~ V\G; .þ. Q ~ () ~ ~ ~ ~ ~ o ::¡ Z o N -1 \0 File:MPDMI000712 #1-1291 Acq:10-DEC-1997 22:25:58 GC EI+ Voltage SIR ?OSE Sample#7 Text:FIORD-3 6600' $97110IL001S005$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 S:7 10~ - 90-= - 80-= - 70-= - 60-= 50-= 40-= 30-= - 20-= - 10-= - o : I I I I I I I I 10:00 12:00 198.0503 8:7 1 0 0?íJ 90-= 80-= 70-= 60-= - 50-= 40-= 30-= - 20-= 10-= 0: 10:00 "~I" 14:00 .I¡-.~'Y~~~' 16:00 18:00 20:00 22:00 I I I I I I I I ," I I I I 12:00 14:00 I I I - I I I I I ,. I I I I I I I 16:00 18:00 20:00 I ( I I I - I I 22:00 I I I I I 24:00 I I I I I I 24:00 I I I I I I I 26:00 I I I I I 28:00 . ! I J, ~. I I I !V I I I I ' I 26:00 28:00 -f \ _1.7E8 :"1.5E8 :"1.3E8 - :"1.2E8 - :"1.OE8 :"8.4E7 :"6.7E7 - :.. 5 . lE7 / :"3.4E7 ~1.7E7 - O. OEO I I I 30:00 Time" _3.4E7 :"3.0E7 - :"2.7E7 :"2.4E7 - :"2.0E7 - :"1.7E7 :"1.3E7 - :"1.0E7 - :"6.7E6 - :"3.4E6 - I ^I ~f\-'J.: O. OEO 30: 00 Time C'.I ~ n tJ ~ ...... ~ .~ .~ o ;4- Z P N ~ File:MPDMIOOO"12 #1-1~91 Acq:l1-DEC-199" 00:07:06 GC EI+ Voltage SIR 70SE Sample#8 Text:FIORD-3 6750' $97110ILOOIS006$ File Text:6000RP.GCMS EXp:GCMS_HRSIR 168.0939 5:8 1 0 <Y!f 90": 80": 7 0": 60": 50": 4û..: - 30": 20": 10_~ - o : I , I I I I I I 10:00 12:00 198.0503 S:8 1 0 OO~ 90": 80": 70": 60": - 50": - 40": - 30": ~ åQ' ~ (Ð \0 0\ - 20": 10": 0: 10:00 , I I I I , I 12:00 l - N W - - u. ~ ,!, ,-,. ,~~~., I'" 14:00 16:00 18:00 20:00 22:00 _7.1E7 :"6.4E7 :"5.7E7 - :"5.0E7 :"4.3E7 :"3.6E7 :"2.9E7 - =-2 .IE7 ¡ - =-1.4E7 - ,... :"7.1E6 . O.OEO , I . 30: 00 Time I I , I I , J I I. I I , I I J I J 24:00 26:00 28:00 I '-" I I J' I' I I 111' I I , I I '" I" J I I I J I I 14:00 16:00 18:00 20:00 22:00 24:00 .AlvJ\. - I , I I , I , , I I I 26:00 28:00 _2.9E7 :"2.6E7 :"2.4E7 :"2.1E7 - :"1.8E7 :"1.5E7 :"1.2E7 - :"8.8E6 :"5.9E6 - :"2.9E6 - I ^t....t'" ð: O.OEO 30: 00 Time C) s= (") tJ ~ -- ~ :;d ~ o ::¡ Z o N -1 \D I-z1 åQ' s:: (i1 \0 ~ -- .- --~--- File:MPDMIOOO'l12 #1-1291 Acq:11-DEC-199~ 09:05:10 GC EI+ Voltage SIR 70SE Sample#9 Text:FIORD-3 6770' $97110IL001S007$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 S:9 10 Q?i, 90": 80": - "^- IV"':- 60": 50": - 40"': 30"': - 2 0": - 1 0": - 0: I I I I I , I I 10:00 12:00 198.0503 S:9 10œ¿ - 90": - 80": - ? 0"': 60-': 50"': 40": 30"': - 20"': - 10"': - 0: 10:00 ,", ~ I .""t 14:00 I I I , I I I I 1-' 12:00 14:00 ~ N ~ - ~ u. ~ .I.O~/,~" I;" 16:00 18:00 20:00 22:00 _l.lE8 :"9.9E7 :"8.8E7 =-ï.ïEï :"6.6E7 - :"5.5E7 :"4.4E7 :"3.3E7 ¡ I I ~ I I " I I , I J , . I I -, I I I I 24:00 26:00 28:00 - :"2.2E7 :"l.lE7 - 0 . OEO I I 30: 00 Time I I I I I I I I I I I I 16:00 18:00 I J I I I I I I I J ' I I 1- I I I I I 20:00 22:00 24:00 _7.6E? - :"6.8E7 :"6.1E7 :"5.3E7 :"4.6E7 - :"3.8E? :"3.0E7 - :"2.3E7 - :"l.5E7 :"7.6E6 , , I ,c!\ ,J, I ' , . '\ "t ~; 0 .OEO 26 : 00 28 : 00 30 : 0 0 Time o ~ n d ~ ...... ~ ..~ "0 '0 ;¡ Z o tv .- -J \0 '>1 üQ' E; o \0 00 I . tv U1 - - U1 ~ File:MPDMI000712 #1-1291 Acq:11-DEC-1997 10:46:27 GC EI+ Voltage SIR 70SE Sarnple#10 Text:FIORD-3 7020' $97110ILOOIS008$ File Text:6000RPGCMS Exp:GCMS_HR~IR 168.0939 S:10 1000~ - 90-': - 80'-: 70-': 60-=: - 50-': 40-': - 30-=: - 20-= - 10-': o : , I , I I I I I '" r' - I 10:00 12:00 14:00 198.0503 5:10 100'?ó - 90-': 80.: 70-= - 60--= - 50-= - 40-=: 30-=: 20'-: - 10_~ o : 10:00 , I r I ' I 12:00 A J I I I I I 14:00 ---~ ,~~f~"I'" 16:00 18:00 20:00 22:00 , I I ' , , I , I ' '. , , I I ' , , 24:00 26:00 28:00 _8.227 :"7.4E7 :"6.6E7 :"S.8E7 - :"4 .9E7 :"4.1E7 :"3.3E7 - :"2 . 5E7 / - :"1.6E7 - :"8.2E6 - 0 . OEO , , 30:00 Time _l.SE7 :"1.4E7 - :"l.2E7 - :"1.lE7 - ~ 9 .3E6 - :"7.7E6 :"6.2E6 - :"4.6E6 :"3.lE6 - ~ ~1.5E6 F, I ,A,.. I I""', ,..A..".\ ,,,-, ,,\-¡lL-:.O.OEO 22:00 24:00 26:00 28:00 30:00 Time I I . I ' I I 16:00 , I I' .' , , ), . r I \ - i 18: 00 20: 00 :"'8.9E6 . ~ _ v-vJ\ '''----' ^ ^ ~: O. OEO I I I I I I - r· I I . I . . { 'I 26 : 00 28 : 00 30 : 00 Time :"'2.7E7 :"'1.8E7 =-7.1E7 =-6.2E7 :"'5.3E7 =-4.4E7 :"'3.5E7 _8.9E7 =-8.0E7 I I I I . I I 24:00 I . I I ". 22:00 I I I . I . 20:00 I I . I . . I I I . . . 16:00 18:00 I . -I · I 14:00 , ~: O.OEO I I 1 . . . I . 1 I . I . I I I . . I I I . . . . I I . . . . I 20 : 00 22 : 00 24 : 00 26 : 0 0 28 : 00 3 0 : 00 Time :"'2.6E7 :"'1.3E7 =-3.8E7/ :"'6.4E7 :"'5.1E7 :"'7.7E7 :"1.0E8 =-B.9E7 :"'1.1EB _1.3EB I . ¡ I . . . .-"t t~"'r ~ I 14:00 16:00 18:00 . . I I I . I 12:00 50-= 40-= 30-= 20-= 10'-: o : . . 10:00 60-= 90": BO-= 70": 10'-: 0: I . . . . I I . 10:00 12:00 19B.0503 S:11 1000¡ 30": 2 0": 50": 4 0": 60": iû-= BO": File:MPDMI000712 #1-1291 Acq:11-DEC-1997 14:07:14 GC EI+ Voltage SIR 70SE Sample#11 Text:FIORD-3A 4BOO' $97110IL001S009$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 5:11 1 0 (Y!f 90'-: - - ON '0\ -- - VI ~ t-rj ôQ' ~ ( ) C1 ~ (l t;1~ _ ~ ~ þd ~ o ;:t Z o N -.J \0 Q ~ n t:I ~ ~ ~ ,c ~ o ,::4- Z o tv .;.;J \0 ÞOTj ôQ' E; o o tv ~ tv -J - ~ lJt ~ File :MPDMIOOO"/12 #1-li91 Acq: I1-DEC-1997 15 :48: 31 GC EI+ Voltage SIR 70SE Sample#12 Text:FIORD-3A 8010' $97110IL0018010$ File Text:6000RP GCMS 'Exp:GCMS_HR8IR 168.0939 8:12 10~ 90~ 80~ 70~ - 60~ 50~ - 40~ 30-": 20"': 10-': o : J I , I I r I I 10:00 12:00 198.0503 8:12 10m; ~ ~, 14:00 90~ 80-=: 70~ 60~ - 50"': 40~ 30-': 20-=: 10-=: o : I I I I I , I I , I I-I I , 10:00 12:00 14:00 --~- -.- --.. -. _3.028 - -=-2.7E8 :"2.4E8 :"'2.1E8 - :"1.828 - :"'1.5E8 - :"1.2E8 - :"9 .1E7 / , - :"'6.1E7 - :"3.0E7 , ¡1 ~I \-~I-')--) I ~ ~ "'~ ." rJ ~, í-. 16:00 18:00 20:00 22:00 24:00' - , .- , ^- ^ - - A_ . A ~ - - : 0 . OEO , I , I ,- ,,--'-¡-'"Iï'..-r-' 26 : 0 -0, 28 : 00 30 : 00 Time , I , , ' I . I , I ' , 16:00 18:00 , , , I ' , I I , , I , . 20:00 22:00 , , , ' I 24:00 , , , I ,.A.1 ~ \ r ' 26:00 28:00 _6.3E7 :"'5.7E7 :"5.1E7 :"'4.4E7 :"3.8E7 :"'3.2E7 :"2.5E7 - :"1.9E7 :"1.327 :"6.326, I ^'rY : 0.020 30: 00 Time r £:) ~ () t1 ~ ~ :;d ..g o :4 Z o N ......) \0 Þï"J ðQ' E; (þ ....... o N W ~ ....... tit ~ File:MPDMI000712 #1-1291 Acq:11-DEC-1997 17:29:47 GC EI+ Voltage SIR 70SE Sample#13 Text:FIORD-3A 8100' $97110IL001S011$ File Text:6000RP GCMS' Exp:GCMS_HRSIR 168.0939 8:13 1000~ 90": 80": - 7 0": 6 0": SO": - 40"': - 30"': 2 0": 1 0": 0= 10:0'0' , '12~0'O' 198.0503 8:13 1 0 ()%j / 90"': 80": 70": 60"': SO": 40"': 30": 20"': 1 0": 0: I , 10:00 , , , , I , I 12:00 I' , , I I , 14:00 , ,....., ' , 14:00 I_I ~ A ~~-^^--^~ A } ~ --.Iv.....A_~ "-A.J . , r ,.J'r - --,-"'-T-I I r"l r,·-.--(-,·, , , , I ' I , . , I I I 16:00 18:00 20:00 22:00 24:00 , I I I I . I I I I . . I , , I ' , , . I I I , I 16:00 18:00 20:00 22:00 . I , I . 24:00 I . I I . , 26:00 I . I I I , , 28:00 '^ l~ I , . I ' I , , T I I I 26:00 28:00 -, _1.8E8 :"1.6E8 - :"1.4E8 - :"1.3E8 :"1.1E8 - :"9.0E7 :"7.2E7 - :"5.4E7 :"3.6E7 - :"1.8E7 ,- 0 . 0 E 0 I _ I 30: 00 Time _4 .3E7 :"3.9E7 - :"3.5E7 :"3.0E7 :"2.6E7 =-2.2E7 :"1.7E7 :"1.3E7 :"B.6E6 - :"4.3E6 - ^ ~ ~ : 0 .OEO I ) I 30 : 0 0 Time File:MPDMI000713 #1-1291 Acq:16-DEC-1997 15:36:36 GC EI+ Voltage SIR 70SE Sample#5 Text:FIORD-3A 8130' $97110ILOOlSOl2$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 S:5 1000~ o s:: () t:1 ~ ~ :::e ~ o ~ Z o N -J \0 90"': 80"': 70"': 60'-: - 50"': - 40'-: 30"': 20"': 10= 01. ~ ~ - I I I I , I ' I I I 1\ I ' I 10:00 12:00 14:00 198.0503 S:5 10ms - 90"': - 80"': 70"': 60'-: 50"': - 40": - 30": 'T1 ôQ' q ( ) - 20": 10": 0= 10:00 I I I I I I , 12:00 I 1'- I I I 14:00 o ~ - N \0 - - u. ~ rv,~(A) ~n~, 16:00 18:00 20:00 22:00 24:00 , I I I I I , I " I I I I I I I I I ¡' I I I·' I I I I I ' I 16:00 18:00 20:00 22:00 24:00 _1.0ES :"9.1E7 - :"8.1E7 :.. 7 . lE7 - =-6.lE7 :"5.lE7 :"4.0E7 - :"3.0E7 :"2.0E7 =-1.0E7 -~:O.OEO I I I. I I I I , I . I I I I 26 : 00 28 : 00 . 30: 00 Time _2.9E7 :"2.6E7 - :"2.3E7 :"2.0E7 :"1.7E7 :"'1.4E7 :"'l.2E7 LA J -.J l -" I I I f 1 I I I I I 26:00 28:00 - :"8.7E6 :"5.8E6 :"2.9E6 - I'-r ? A: 0 .OEO 30: 00 Time C1 a:: () tJ ~ ~ ~ (1) "0 o ::¡ Z o tv -.) \0 File:MPDMIOOO,12 #1-1291 Acq:11-DEC-1997 20:52:12 GC EI+ Voltage SIR 70SE Sample#15 Text:FIORD-3A 8610' $97110IL001S013$ File Text:6000RP GCMS -Exp:GCMS_HRSIR 168.0939 S:15 10~ 90": - 80-= 7û-= 60": 50": - 40": - 30": - 2 0": - 1 0": o : . , I 1 1 I 1 . 10:00 12:00 I I - ~ , , . I ,-y ,/~>,~., ~~" , I' , ,',. I' , , 14:00 16:00 18:00 20:00 22:00 24:00 198.0503 8:15 10~ - - 90": - 80": - - 70": - - 60": - - 50": - - 40": - - 30": - - 2 0": - - 1 0": - ~ - ciQ. 0: . 1 1 1 1 1-' I 1 1 I 1 ~ Þ-" 10:00 12:00 14:00 w (1) 0 I--' - Þ-" 0 lit u-. ~ 1 1 1 I 1 1 I , 1 I ' , 1 , 1 I . .- . , . I ' 1 f , , I ' , 16:00 18:00 20:00 22:00 24:00 _1.5E1 :"6.1E1 :"6.0E1 :"5.2E7 - :"4.5E1 :"3.7E1 :"3.0E7 - :"2 .2E7 / , - :"1.5E7 - :"1.5E6 : 0 . OEO , -, I · -I r-, , I 1 -, - 1 -, 1 26 : 00 28 : 00 30 : 00 Time _5.7E7 :"5.1E7 - :"4.6E7 - :"4.0E7 ::'3.4E7 :"2.9E7 :"'2.3E7 - ~ 1 . 7 E7 :"'1.1E7 ~ ~5.7E6 I , , I .A), , ) -1'-' . ^' t-; O. OEO 26:00 28:00 30:00 Time File:MPDMI000112 #1-1291 Acq:ll-DEC-1991 22:33:22 GC EI+ Voltage SIR 'lOSE Sample#16 Text:FIORD-3A 8800' $97110IL001S014$ File Text:6000RP GCMS "Exp:GCMS_HRSIR 168.0939 8:16 ' 10~ 90~ Q ~ (J t; ~ ~ ::0 ~ o ~ ~ - 80-': 70-= 60--= 50--= N --, ~ - 4û..:- - 30-': 20--= - 10--= 0: I I , I , I ' I 10:00 12:00 , I I I - I I 14:00 198.0503 8:16 1 0 CY!íí - - 90-': - 80-': - ? 0-': 60--= - - 50-': - - 40-': - - 30-': - - 20-': - 10--= "Tj - - ùQ' 0: '-1 I ~ I I 12 ~ 0'0 I , I , (D 10:00 14:00 ...... 9 0'\ ...... w ...... - ...... Ut ~ T~'~~{~~" I I" 16:00 18:00 20:00 22:00 24:00 _1.5E8 - :"1.3E8 - ~1.2E8 - :"1.0E8 :"9.0E7 :"7.5B7 :"6.0E7 - :"4.5E7 i. :"'3.0E7 , , , I " , , , , I I I I 26:00 28:00 . :"'1.5E7 O.OEO , I 30: 00 Time A J 'I ___ _ , I , I ' I I 1 I ' I I , , I I , . I , I ' , , . I I I I -. I . I ~\, I I _ I' I 16:00 18:00 20:00 22:00 "24:00 26:00 28:00 _4.2E7 :"3.8E7 - , :"3.3E7 :"2.9£7 - :"'2.5E7 :"2.1E7 :"1.7£7 - ~1.3£7 ~8.4E6 :"'4.2E6 - I ^. - ¡V- 0 .OEO 30: 00 Time ÞOrj ciëi' E; CD ..- o ~ C1 a:: n t) ~ ~ ~ ~ o ~ Z o N ....... \0 File:MPDMIOOO~12 #1-1291 Acq:12-DEC-199'l 00:14:29 GC EI+ Voltage SIR 10SE Sample#17 Text:FIORD-3A 8840' $97110IL001S015$ File Text:6000RP GCMS Exp:GCMS_HRSIR 168.0939 8:17 10~ 90-= 80-': 7û~ 60": 50-': 40-= 30-= 20-= - 10-': 0: , , , , , 1 ' , 10:00 12:00 198.0503 S:17 1 0 OO~ - 90~ 80-': 70~ - 60~ - 50-= 40-= - W N - - Vt .þ. - 30-= 20-= 10": 0: 10:00 ,! I ,~. .Ji~~~' , I ' , · , · ,-, · , " I ' · , · , 1'-' , 14:00 16:00 18:00 20:00 22:00 24:00 26:00 28:00 , , I r ' I , , ,- I . · 12:00 14:00 - :"1.5E7 - O. OEO , . . 30: 00 Time _1.SE8 - :"1.3E8 :"1.2E8 :"1.OE8 - :"8.8E7 :"7.3E7 =-S.9E7 - -=-4.4E7 ¡ :"2.9E7 _S.1E7 :"4.6E7 :"4.1E7 -=-3 .6E7 - :"3.1E7 - :"2.6E7 - -=-'2.0E7 - :"1.5E7 - :"1.OE7 :"S.1E6 - . I , I ,-, I I I r I . I I I I I I I , I I ' I I I I 1 1 I , I I I rA.J ~... 1--' I I^-. ^(' ,,= O. OEO 16 : 00 18 : 00 . 20: 00 22 : 0 0 24 : 00 26 : 00 28 : 0 0 3 0 : 00 Time · I I I ' I I 24:00 , I I I ~ . 22:00 :"1.1E7 :"8.4E6 :"5.6E6 A ~2.8E6 I r )\, ~, ~ 1'-'\ '^I~,.J. o. OEO 26 : 00 28 : 00 30 : 00 Time :"2.0E7 ~1.7E7 :"1.4E7' :"2.2E7 :"2.5E7 _2.8E7 - 0 .OEO 30: 00 Time :"3.5E7 -:"2.3E7 :"1.2E7 :"4.7E7 :"5.8E7 :"8.2E7 =-7.0E7 :"9.3E7 _1.2E8 :"1.0E8 , I I I . . 1 'I I . I . I ·1 I , I 16:00 18:00 20:00 , ('" I ' I 14:00 I I I I . . I 12:00 o : I I 10:00 20'-: 10": 60": 50": 40": 3 0'-: 80'-: 70'-: 90": I~~~~)'~' I I' I I 16:00 18:00 20:00 22:00 L _ I I I . I 14:00 j I I I I I 12:00 B:18 10": 0: I I t 10:00 198.0503 10~ I I I I , I 28:00 I I I I I I . 26:00 I I I I . 24:00 30'-: 20": -d 0": 50": 60~ File:MPDMI000712 #1-1291 Acq:12-DEC-1997 01:55:33 GC EI+ Voltage SIR 10SE Sample#18 Text:FIORD-3A-9120' $97110IL001S016$ File Text:6000RP GCMS· Exp:GCMS_HRSIR 168.0939 B:18 100% 90": 80": 7 0": ~ w w - ~ UI .þ.. o 00 'ï1 aq" ¡:; o / Q ~ (') ö ~ Po> :;d ~ o ::¡ Z o N -....1 \Ö ¡ :i :a ..~ f ': ~ s f :JMC Data Report No, 279 Appendix A Molecular Parameter List 134/154 Sl S2 S3 S4 S5 S6 S7 S8 S9 S10 A1 A2 A3 A4 AS A6 M2 M3 MBP MDR M4 NO:rIF.CUT,~~ PARAMETER T.:Ts.¡ LGC CODE PARAMETER USE H1 H2 H3 H4 H5 H6 H7 HS H9 H10 H11 H12 H13 H14 H15 H16 H17 Hla C32 HOPANE 22S/(22S+22R) C31 HOPANE 22S/(22S+22R) C30 HOPANE/ (C3i 0 HOPANE+C30 MORETANE) ßß HOPANES PRE:SENT / ABSENT C30: C31: C32: C2¡3: C34: C35 HOPANE DISTRIBUTION C27 HOPANES TEJ/ (Ts+Tm) C33 HOPANE 22S/ (22S+22R) C34 HOPANE 22S/(22S+22R) C35 HOPANE 22S/(22S+22R) RESIN DITERPANES % RELATIVE TO C30 HOPANE (PEAK G) C23 EXT TRICYCLIC TERPANE % RELATIVE TO C30 HOPANE (PEAK G) C24 TETRACYCLJ:C TERPANE % RELATIVE TO C30 HOPANE (PEAK G) 28,30 BISNORHOPANE (PEAK X) % RELATIVE TO C30 HOPANE (PEAK G) PENTACYCLANE I1 % RELATIVE TO C30 HOPANE (PEAK G) OLEANANE % REI.iATIVE TO C30 HOPANE (PEAK G) GAMMACERANE % RELATIVE TO (PEAK G) HOPANES C35/(C34+C35) % 25-NORHOPANE/C30 HOPANE % M M MS M S MS M M M S S S S S S S S B C29 aaa STERANES 20S/(20S+20R) C29 STERANES aßß/(aßß+aaa) STERANES aaa C27:C28:C29 STERANES aßß C27:C28:C29 ßa DIASTERANES/(SAME+aaa+aßß STERANES) % LOW MOLECULAR WEIGHT STERANES RELATIVE TO C29 STERANES STERANE INDEX C27/(C27+C29) % (FROM S3) 4-ME C30 STERJillE % RELATIVE TO C29 20R aaa STERANE (PEAK 42) 4-ME STERANES INDEX C28/(C28+C30) % BlCADINANES PRESENT/ABSENT M M S 8 8M 8 8 8 S 8 C28 20R TRIAROM, 8TERANE/(8AME+C29 20R MONOAROM, STERANE) SUM TRIAROM, STERANE8/ (SAME+SUM MONOAROM, STERANES) C20 TRIAROM, STERANE/(8AME+C28 20R TRIAROM, STERANE) C20+C21 TRIAROM, STERANE/(8AME+SUM C26-C28 TRIAROM, 8TERANE8) C26 208 TRIAROM, 8TERANE/C28 20S TRIAROM, STERANE C27 20R TRIAROM, STERANE/C28 20R TRIAROM, STERANE M M M M 8 8 PHENANTHRENE8 (3ME+2ME)/(9ME+1ME) MPI [(3ME+2ME)/(PHENANTHRENE+9ME+1ME)] * 1,5 3-METHYL BIPHE~ITL/2-METHYL BIPHENYL 4-METHYLDIBENZOTHIOPHENE/1-METHYLDIBENZOTHIOPHENE SUM C27-C35 HOPANES/(SAME+ SUM C27-C29 STERANES) % M M M M S ALKIND R22 R22 INDEX (2 1, n-C22) / (n-C21+n-C23) ALKANE INDEX n-C17/(n-C17+n-C27) % SM NOTES: 1, S=SOURCE PARAMETER, M=MATURITY PARAMETER, :2. TRIAROM, STER1\NE=MONOMETHYL TRIAROMATIC STERANES MONOAROM, STEIUiliE=DIMETHYL MONOAROMATIC STERANES. (13/11/92) GMC Data Report No. 279 135/15'- I it ~ l- I ~ Appendix B GMC Data Report No, 279 Biomarker Identifications 136/154 APPENDIX CODE H~ H2 H3 H4 H5 H6 H7 H8 H9 S1 S2 'S3 S4 S5 A~ A2 A3 A4 AS A6 M2 M3 M4 i MOLECULAR PARAMETER LIST PARAMETER C32 HOPANE 22S/(22S+22R) C31 HOPANE 22S/(22S+22R) C30 HOPANE/(C30 HOPANE+C30 MORETANE) ßß HOPANES PR:ESENT/ABSENT C30:C31:C32:C33:C34:C35 HOPANE DISTRIBUTION C27 HOPANES Ts/(Ts+Tm) C33 HOPANE 22S/(22S+22R) C34 HOPANE 22S/(22S+22R) C35 HOPANE 22S/(22S+22R) USE M M MS M S MS M M M C29 aaa STE~'ES 20S.!(20S+20R) C29 STERANES aßß/(aßß+aaa) STERANES aaa C27:C28:C29 STERANES aßß C27:C28:C29 ßa DIASTERANES/(SAME + aaa+aßß STERANES) % M M S S SM C28 20R TRIAROM. STERANE/(SAME+C29 20R MONOAROM, STERANE) SUM TRIAROM. STERANES/(SAME+SUM MONOAROM, STERANES) C20 TRIAROM. STERANE/(SAME+C28 20R TRIAROM. STERANE) C20+C21 TRIAROM, STERANE/(SAME+SUM C26-C28 TRIAROM. STERANES) C26 20S TRIAROM, STERANE/C28 20S TRIAROM. STERANE C27 20R TRIARGM, STERANE/C28 20R TRIAROM, STERANE M M M M S S PHENANTHRENES (3ME+2ME) / (9ME+1ME) MPI [(3ME+2ME)/(PHENANTHRENE+9ME+1ME)] * 1.5 SUM C27-C35 HOPANES/(SAME+ SUM C27-C29 STERANES) % M M S ALKIND INDEX n-C17/(n-C17+Il-C27) % R22 R22 INDEX '(2 X n-C22)/(n-C21+n-C23) ALKANE S SM Notes: ' 1) FOR A FULL DISCUSSION OF THE USE OF THESE PARAMETERS CONSULT GCB/173/86 in summary S=SOUJ:ce parameter , M=maturity parameter 2) Aromatic Sterane~) ,TRIAROM, STERANE refers to monomethyl triaromatic steranes and MONOAROM, STERANE refers to dimethyl monoaromatic steranes, GMC Data Report No, 279 I I 13t /154 t ,j '~ - :i ,~ ~t ,.~ ,~ ~ ,Appendix C GMC Data Report No, 279 Whole Oil GC Peak Areas 138/154 V 13/6/97 C:\_DATA\B971100I\WOGCOOI.RAW Software Version: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amount: 4.1 <0007> 20/01/98 971 I OILOOI SOOI F-3,4020' C:\_DATA\B97 I I 00 I \WOGCOO I.RAW C:\_DATA\B971100J\WOGC8.sEQ WHOLE_On..s_GC I Date: Cycle: Rack/Vial: tion Factor 18/12197 10:04 2 Channel: A ° ° Operator: NSG I 17:11 Whole Oil GC Analysis Component Time Area Amount Name [min] [µV·s] [%] Propane 1.842 143.3 ° 2-methylpropane 2.445 0 0 n-butane 3.008 ° ° 2-methylbutane 4.561 ° ° n-pentane 5.248 ° 0 DCM 5.744 0, ° 2.2-dimethylbutane 6.081 ° 0 Cyclopentane 6.715 ° 0 2,3-dimethylbutane 6.859 0 0 2-methylpentane 7.024 0 0 3-methylpentane 7.369 ° 0 n-hexane 7.978 methylcyclopentane 8,376 274.8 0 2,4-dimethylpentane 8,646 1211 0.02 Benzene 9.036 483.4 0.01 cyc:lohexane 9.144 169.6 ° 2-methylhexane + 1,2-DMP 9.539 2266.8 0,03 3-methylhexane 9.849 334.2 0 l,3-cis-dimethylcyclopentane 9.923 43.8 6,OOE-04 I ,2-trans-dimethy Icycl"pentane 9.964 ° ° I ,3-trans-dimethylcycl,~pentane 10,01 203.5 0 n-heptane 10.396 0 o . methylcyclohexanc 10.857 242 0 ethylcyclopentane 11.015 ° 0 Toluene 11.57 ° ° n-Octane 12.7 0 0 n-Nonane 14.801 ° 0 n-Decane 16.742 221.37 0 n-CII 18.547 208.9 ° n-C12 20.136 1299.7 0,02 n·C13 21. 737 454355.8 6.22 n-C14 23.251 1312470 17,98 n-C15 24.585 324850,4 4,45 n,CI6 25.871 62789.84 0,86 n-C 17 27.107 88365.9 1.21 Pristane 27.226 112699.1 1.54 n-C18 28.283 42329.82 0,58 Phytane 28.399 8524.98 0.12 n-C19 29,401 40827.71 0.56 n-C20 30,472 34573.24 0.47 n-C21 31.494 34720.65 0,48 n-C22 32,475 37030,7 0,51 n-C23 33,412 34542,4 0,47 n-C24 34.309 25607,43 0.35 n-C25 35,174 22298.4 0.31 n-C26 36,002 35227.45 0,48 n-C27 36,807 24041.3 5 0,33 n-C28 37,595 1 597 \.6 0,22 n-C29 38,402 30473.81 0.42 n-C30 39.242 12888,8 0.18 n-C31 40.136 16003,09 0.22 n·C32 41.116 11596.54 0.16 n-CD 42.21 13009.47 0,18 n-C34 43.451 9063.96 0,12 n-C35 44,882 5933,4 0,08 n-C36 46.54 5379,1 0,07 7300911 100 Batch Code Data File MCH (MeCyC6 as % all C7 aJkanes) HER (Heptancl(Hp...MeCyC6) HXR (Hexanei(H.'(+CyC6) Thompson's Heptane Rati" Thompson's Iso Heptane Index Note: ,I denotes not c.aJculalcd 97110lLooISOOl C:\_DATA\B97I 1001\WOGCOO1.RAW GMC Data Report No, 279 971 1 OlLOOISOOI 139/154 V 13/6/97 Software Vmion: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amount: Whole Oil GC Analysis Component Name Propane 2-methy ¡propane n,butane 2'methylbutane n-pentane DCM 2,2-dimethylblltane Cyclopentane 2,3-dimethylblltane 2-methylpentane 3-methylpentane n-hexane methylcyclope~tane 2,4-dimethylpe:ntane Benzene cyclohexane 2·methylhexane + 1,2-DMP 3-methylhexane I,J-cis-dimethylcyclopentane 1,3,trans-dime hylcyclopentane 1 ,2-trans-dime1hy Icyclopentane n-heptane methylcyclohCJW1e etJ1ylcyclopentane Toluene n-octane n-Nonane n-Decane n,CII n-C12 n-C13 n-C14 n·C15 n-C16 n-C17 Pristane n-C18 Phytane n-C19 n-C20 n-C:Z I n-C22 n-e23 n-e24 n-C25 n-e26 n-e27 n-e28 n-e29 n-e30 n-e31 n-en n-e33 n-cJ4 n-C35 n-e36 I I I BlUch Code I Data File MCH (MeCyC6 as % all C7 alkanes) ¡ HER (Heptanel(Hp+MeCyC6) I HXR (Hexanel( Hx+CyC6) r Thompson's Heptane Ratio Thompson's Iso Heptane Index G C Data Report Nò~1279notCalculated C:\_DATA\B971100I\WOGCOO2,RAW 4, 1<0007> 20101/98 97110ILOOISOO2 F-3, 4140' C:\_DATA\B971100I\WOGCOO2.RAW C:\_DATA\B971100I\WOGC8,SEQ WHOLE_OILS_GC I Time [mini 1.858 2.445 3.008 4.561 5.248 5.744 6.081 6.715 6.859 7.024 7.369 7,945 8,351 8,618 9.01 9.12 9,512 9.828 9.844 9.907 9.992 10.498 10.845 11.015 11.592 12.7 14.801 16.744 18,589 20.136 21.76 23.268 24.589 25,872 27.107 27,226 28.283 28.448 29.401 30.471 31.493 32.471 33.409 34.307 35,316 36.001 36.808 37.594 38.402 39,241 40.136 41.115 42.21 43,452 44.874 46.525 971 I OILOOI S002 C:\ßATA\B971100I\WOGC002.RAW Date: Cycle: RacIc/V ial: tion Factor 281.2 1400.9 , 485.2 167.3 2021.4 362.6 o o 191.1 143.2 131.3 o 209.4 o o 501.73 4261.16 6298.53 906961.4 1919474 376196.6 95564.23 104045.1 132221.5 53494.93 43375.83 58775.3 43980.89 33897.8 40177.6 36563.58 30446.07 29290 34109.5 22653.79 18166,58 22240,4 11000.2 13881.37 10385.81 11864,39 6937.82 703.5 3666.4 4380166 100 97110lLOOIS002 17:23 18/12/97 II: 17 3 Channe!: A o 0 OperatOr: NSG I Area [µV's) Amount [%) 162.1 o o o o o o o o o o o o o o o o o o o o o 0,01 0.03 0.01 o 0,05 0.01 o ° o o o o o o o 0.01 0.1 0.14 20.71 43,82 8.59 2.18 2.38 3.02 1.22 0.99 1.34 1 0,77 0.92 0.83, 0,7 0,67 0,78 0.52 0.41 0,51 0.25 0.31 0.24 0.27 0.16 0.02 0.08 140/154 V 13/6/97 Software Version: Date: Sample Name: Data File: Sequence File: Instrument Sample Amount: Whole Oil GC Analysis Component Name Propane 2-methylpropane n-butane 2-methylbutane n-pentane DCM 2,2-dimethylbutane Cyclopentane 2,3-dimethylbutane 2,methylpentane 3-methylpentane n-hexane methylcyclopentane 2,4-<limethylpentane Benzene cyclohexane 2-methylhexanc + 1,2-DMP 3-methylhexane 1,3-cis-dimethy Icyclopen'tane 1,3-trans-dimethy Icyclopcmtane 1,2-træJs-dimethylcyclopcmtane n-heptane methyicyclohexane ethylcyclopentane Toluene n.octane n-Nonane n-Decane n.ell n.e12 n-C13 n-C14 n-C15 n-e16 n-e17 Pristane n-C18 Phy1æle n-C19 n-C20 n-e21 n-C22 n-C23 n-C24 n-C25 n-e26 n-C27 n-C28 n-C29 n-C30 n·C31 n-en n-C33 n-e34 n-e3S n-C36 Batch Codc DwFilc MCH (MeCyC6 as % aJl <:7 alkanes) HER (HeptaneJ(Hp+MeC:/C6) HXR (He)(.ll1e1(Hx-+CyC6) Thompson's Heptanc Ratio Thompson's Iso Heptane Index NOle: -1 donoles nOI calcu latcd GMC Data Report No, 279 C:\_DATA\B9711001\WOGCOO3.RAW 4.\ <OG07> 20/01/98 97\ I OILOO I SOO3 4740' C:\_DATA\B971100I\WOGCOO3.RAW C:\_DATA\B971100I\WOGCI.SEQ WHOLE_On..5_GC I Time [min] 1.84 2.445 3.008 4,561 5.248 5.744 6,081 6.715 6,859 7.024 7.369 7.922 8.328 8.593 8.982 9.151 9.488 9.831 9.844 9.907 10.002 10.396 10,772 11.015 11.57 12.675 14.801 16.752 18.568 20.154 21. 784 23.256 24.594 25,895 27.14 27.253 28.321 28.479 29,446 30,517 31.537 32.514 33.45 34,348 35.213 36,041 36,844 37,635 38,442 39.285 40,184 41.17 42.273 43.522 44.948 46.621 97110lLOO1SOO3 C:'-DATA\B97! 1001\WOQC003.RAW . 17:26 Date: Cycle: RacklViaJ: tion Factor 12/12/97 12:51 2 Channel: A ° 0 Operator: NSG I Area Amount [µV·s] [%] 123.7 0 0 ° 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ° 0 346.4 0.01 1368.2 0,02 456,6 0.01 149.6 ° 1608.2 0.03 304,93 0,01 0 0 0 ° 101.8 0 0 0 0 0 0 0 0 0 78.8 0 0 0 948.82 0.02 3400.31 0.06 130516.6 2.32 1489920 26.51 1217043 21.65 253327.3 4.51 \30738.5 2.33 121230.4 2,16 113331.3 2.02 137638.2 2.45 71570.8 1.27 180550,5 3.2\ 143982.7 2.56 112310.9 2 1\3282.4 2.02 92851.16 1.65 81801.7 1.46 92365,86 1.64 78828,47 1.4 53293,16 0,95 43410.85 0.77 31446,4 0,56 19978.28 0.36 21099.42 0.38 16615.4 0.3 12475,1 0.22 8068,96 0,14 2826.92 0,05 3715.4 0,07 5620916 100 97110ILOOIS003 1411154 V 13/6/97 C:\_DATA\B97 I I 00 I \WOGC004 ,RAW 97110lLOOISOO4 Software V~5ion: Date: Sample Name:: Data file: Sequence File:: Instrument: Sampll: Amount: 4, 1<0007> 20/01198 971 I OILooI SOO4 6240' C:\ßATA\B971100I\WOGCOO4,RAW C:\_DATA\B97 I I 00 I\WOGC I.SEQ WHOLE_OILS_GC I 17:28 Date: Cycle: R.ack/Vial: tion Factor 12/12197 14:10 3 Channel: A o 0 Operator: NSG I Whole Oil GC Analysis Component Time Area Amount Name (min] (¡¡V's] W·] Propane 1.818 0 0 2'methylproplme 2.445 0 0 n-butane 3.008 0 0 2-methylbutaue 4,561 0 0 n-pentane 5.248 0 0 DCM 5.744 0 0 2,2-dimethylbutane 6.081 0 0 Cyclopentane 6.715 0 0 2,3-dimethylbutane 6,859 0 0 2-methylpenullle 7,024 0 0 3-methylpentilllle 7,448 n,hexane 7.888 methylcyclo~mtane 8.33 23,02 4.00E-04 2,4-dimethylpentane 8.618 1759.3 0.03 Benzene 9.024 385 0,01 cyclooexane 9.138 125.2 0 2-methylhexane + 1,2-DMP 9.545 1607.6 0.03 3-methylhexane 9,765 0 0 1,3-cis-dimeth ylcyclopentane 9.844 0 0 1,3-trans-dimc:thy lcyclopentane 9.907 0 0 1,2-trans-dimc:thylcyclopentane 9,964 0 0 n'heptane 10,396 0 0 methylcyclohcJXane 10.879 96.1 0 ethylcyclopenl:ane 11.015 0 0 Toluene 11.57 0 0 n-Octane 12.7 0 0 n-Nonane 14,925 187.2 0 n·Decane 16.746 1148.16 0.02 n..ell 18.679 1098.27 0.02 n..e12 20.145 110557.3 1.99 n-C13 21.775 2122807 38.14 n-C14 23.25 1633447 29.35 n-C15 24.58 285964.7 5.14 n-C16 25,874 66056.44 1.19 n-C17 27,115 94598.25 1.7 Pristane 27.234 92622.65 1.66 n-C18 28.294 71474.83 1.28 Phytane 28.456 47910,58 0.86 n·C19 29.417 89138.98 1.6 n-C20 30.488 65334.7 1.17 n-C21 31.51 57526.4 1.03 n-C22 32.49 58023.09 1.04 n-C23 33.428 53607.82 0.96 n-C24 34.326 47444,21 0.85 n..e25 35.19 39682.12 0.71 n-C26 36.02 46191.4 0,83 n-C27 36.824 30932. 6 0,56 n-C28 37.612 33143.17 0.6 n-C29 38.422 30500.3 0.55 n-C30 39,264 18463.1 0.33 n-C31 40.16 22281.59 0.4 n-C32 41.143 14966.8 0,27 n-C33 42,251 16438.6 0.3 n-C34 43.498 11864,38 0,21 n-C3S 44.932 105&3.02 0.19 n-C36 46.593 5891 0,11 5566157 100 Batch Code Data File MCH (MeCyC5 as % all C7 alkanes) HER (Heptanei(Hp+MeCyC6) HXR (Hexanei(H;(+CyC6) Thompson's Hc:ptane Ratio Thompson's IS<I Heptane Index Noce: -I denotes not calculated 971 I OILOO ISOO4 C:\_DATA\B971100I\WOGCOO4.RAW G~ Data Report No, 279 142/154 VI3/6/97 C:\ßATA\B971100I\WOGC005.RAW Software Version: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amount: 4.1 <0007> ZO/O 1198 97110ß.OOIS00566OO' C:\_DATA\B971100I\WOGCOO5.RAW C:~DATA\B9711001\WOGC1.SEQ WHOLE_Ou.s_GC 1 17:30 Date: Cycle: Rack/Vial: lion Factor 12/12/97 15:21 4 Channel: A o 0 Operator. NSG 1 Whole Oil GC Analysis Component Time NeA Amount Name [miri] [µV's] [%] Propane 1.85 162.4 0 Z-methylpropanc 2,445 0 0 n-butane 3,008 0 0 2-methylbutane 4.561 0 0 n-pentane 5.248 0 0 DCM 5,744 0 0 2,2-dimethylbutane 6.081 0 0 Cyclopentane 6.715 0 0 2,3-dimethylbutane 6.859 0 0 2-methylpentane 7.024 0 0 3-methylpentane 7.369 0 0 n-hexane 7;863 methYlcyclopentane 8.42 193.55 0 2,4-dimethylpentane 8.6\7 624.06 0.01 Benzene 8;986 0 0 cyclohexane 9,198 149,6 0 2-methylhexane + 1,2-DMP 9,516 11789.94 0.14 3-methylhexane 9,765 0 0 1,3-cis-dimethylcycloper.ltane 9,844 0 0 1,3"trans-dimethylcyclopentane 9,903 329,71 0 I ,2,trans-dimethylcyclop~tane 9.978 65.19 8.00E-04 n-heptane 10.324 207.8 0 methYlcycloheWle 10,772 0 0 ethylcyclopentane 11.015 0 0 Toluene 11.S35 578.6 0.01 n..Qctane 12.7 0 0 n-Nonane 14,801 0 0 n,Decane 16.745 192.93 0 n-Cll 18.473 3373 0.04 n-C12 20.176 388380.3 4.64 n-C13 21.852 3334825 39,85 n-C14 23.3 2400345 28.68 n-C15 24.599 393935.7 4.71 n-C16 25.883 102026,9 1.22 n-C17 27.123 107166.3 1.2S Pristane 27.243 169053.3 2,02 n-CIS 28.294 72559.27 0,87 Phytane 28.·m 71525,48 0,85 n-C19 29.413 127149.3 1.52 n-C20 30,482 67752,45 0,81 n-C21 31.503 97173.64 1.16 n-C22 32,481 92938.22 1.\1 n-C23 33,422 109020.6 1.3 n-C24 34.318 71965.04 0.86 n-C25 35.19 132126,8 1.58 n-C26 36.015 79282.88 0,95 n-C27 36,826 122595.9 1.46 n-C28 37.61 67631.9 0,81 n-C29 38423 87684.92 1.05 n-C30 39.256 31326 0.37 n-C31 40.157 47435,44 0,57 n-C32 41.287 30646.56 0.37 n-C33 42.238 28955,91 0.35 n-C34 43.578 11882,99 0.14 n-C35 44 ,904 12276,% 0,15 n-C36 46.689 90 1.07 0.01 8368593 100 B81Ch Code Data File MCH (MeCyC6 as "I. IJI C7 alkanes) HER (Heptanel(Hp+MeCyC6) HXR (Hexanel(Hx+CyC6) Thompson's Heptane Ratio Thompson's Iso Heptane Index Note: -1 denotes not calculated GMC Data Report No, 279 97110lLOOISOOS C:\_DATA\B9711001\WQGCooS.RAW 9711 OILOO 1 8005 143/154 I VIJ/6I97 C:\_DATA\B97 I 100 1 \WOGCOO6B ,RAW '~ :I r ~ ~ Software Y cr:lion: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amo~:nt: 4, 1<0007> 2210 I /98 91110lLOOISOO6 675C1 Splillsplidess C:\_DATA\B971100I\WOGCOO6B,RA C:\_DATA\B911100I\WOGC3,SEQ WHOLE_orLS_GC 1 13:29 Date: Cycle: Rack/ViaJ: ticn Factor 16/12/91 08:31 I Channel: A o 0 Operator. NSG I Whole Oil GC Analysis Component Time Area Amount Name (min) (µY's) ["II) Propane 1.853 194.2 0 2-methylprop211e 2.445 0 0 n-butane 3.008 0 0 2-methylbutane 4.561 0 0 n-pentane 5.248 0 0 DCM 5.744 0 0 2,2-dimethylblltane 6.081 0 0 Cyclopentane 6.715 0 0 2,3-dimethylblltane 6.859 0 0 2-methylpentane 7,024 0 0 3-methylpentane 7.384 n-hexane 1,839 methy¡cyclopel~tane 8.294 263.8 0 2,4-dimethylpentane 8.5!7 2252.2 0.02 Benzene 9.001 493.8 0 cyclohexane 9.117 157,5 0 2-methylhexan'~ + 1,2,DMP 9.602 869.31 0.01 3-methylhexanl~ 9.761 77.8 6.00E-04 1,3-cis-dimethylcyclopentane 9.849 371.9 0 1,3-trans-dimethylcyclopentane 9,907 0 0 1,2-trans-dimethylcyclopentane 9.964 0 0 n-heptane 10.396 0 0 methylcyclohC):ane 10.874 415.8 0 ethylcyclopentli/1e 11.015 0 0 Toluene 11.709 75 6,OOE-D4 n,Octane 12.675 113.8 9,OOE-04 n-Nonane 14.801 0 0 n-Decane 16.754 638.3 0.01 ",CII 18.48 14133.19 0.11 n-C12 20.179 521610.9 4.19 n-C13 21.814 2268094 18,21 n-C14 23.269 1494810 '\2 n-C15 24,606 384593.7 3.09 n-C16 25.91 227850 1.83 n-C17 21.159 267474.5 2.15 Pristane 27.281 235068 1.89 n-e18 28.338 281962.1 2.26 Phytane 28.491 148290.9 1.19 n-e19 29.462 346560,2 2.78 n-e20 30.529 255722.2 2.05 n-e21 31.S5 218321.9 1.75 n-en 32.53 233700.9 1.88 n-C23 33.475 276690.1 2.22 n-e24 34.379 260743.4 2.09 n-e25 35.251 316110.8 2.54 n-e26 36.086 282977.4 2.27 n-C27 36.892 257686.8 2.07 n-e28 37,682 199836.1 1.6 n-<:29 38.497 195203.8 1.57 n-e30 39.336 114072.8 0.92 n-e31 40,239 107991.8 0,87 n-e32 41..226 74445.05 0.6 n-e33 42334 84521.26 0,68 n-C34 43.586 38413.16 0.31 n-e35 45.027 32825.06 0,26 n-e36 46.694 19262.7 0.15 12452759 100 Batch Code Data File MCH (MeCyC6as % all C7 allcan=) HER (Heptane/(Hp+MeCyC6) HXR (Hexane/(Hx+CyC6) Thompson's Heptane Ratio Thompson's Iso Heptane Index Note: -I denotes 110t calculated 9711 OILOO I SOO6 C:\_DATA\B9711001\WOGC006B.RA W GMC Data Report No. 279 97110ILOOISOO6 144/154 V 13/6/97 C:\_DATA\B9711001\WOGCOO7.RAW Software Version: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amount: 4. I <0G07> 21/01/98 9711 On.oo I S007 6770' splitlsplitless C:'-DATA\B9711001\WOGC007.RAW C:\ßATA\B9711001\WOGC3.SEQ WHOLE_OILS_GC I 15/12/97 17:17 2 Channel: A o 0 Operator: NSG 1 17:20 Dale: Cycle: Rack/Via1: tion Factor Whole Oil GC Analysis Component Time Area Amount Name [min] [µY-s] ["/oj Propane 1.858 217.8 0 2-methylpropane 2,445 0 0 n-butane 3.008 0 0 2-methylbutane 4.561 0 0 "'pentane 5.248 0 0 DCM 5.744 0 0 2,2-dimethylbutane 6.081 0 0 Cyclopentane 6,715 0 0 2,3-dimethylbutane 6,859 0 0 2-methylpentane 7.024 0 0 3,methylpentane 7.369 0 0 n-hexane 7.87 3,62 methylcyclopentane 8.413 0 0 2,4-dimethylpentane 8.584 1516,6 0.02 Benzene 8.996 421.2 0.01 cyclohexane 9.112 152.4 0 2-methylhexane + 1,2-DI¡,fi> 9.52 2171.2 0,03 3-methylhexane 9.754 37.6 5,00E-04 1,3-cis-dimethylcyclopen.tane 9,841 320.6 0 1,3-trans-dimethylcyclopentane 9.907 0 ° 1,2-trans-dimethylcyclopc:ntane 9.964 0 ° n-heptane 10.396 ° ° methylcyclohexane 10,869 168.7 ° ethylcyclopentane 11.015 0 0 Toluene 11.533 237.7 ° n-Octane 12.661 77.3 0 n-Nonanc 14.801 0 0 n-Decane 16,744 345.56 0 n-CII 18.47 1161.08 0,02 n,CI2 20,146 86444.73 1.23 n-C 13 21.772 1036903 14.79 n-C14 23.246 939393.4 13,4 n-C15 24.594 297555.8 4,24 n-C16 25,899 206954.7 2.95 n-C17 27.148 325088.6 4.64 Pristanc 27.268 279512.1 3,99 n-C18 28,326 242082 3,45 Phytane 28.481 137296.9 1.96 n-C19 29.452 325461 4,64 n-C20 30.522 238579.5 3,4 n-C21 31.544 233991.9 3.34 n-C22 32.524 247090 3.52 n-C23 33.467 282467,7 4,03 n-C24 34.263 35304.38 0.5 n-C25 35.244 323249.5 4,61 n-C26 36.08 271892,6 3,88 n-C27 36,888 269970.3 3,85 n-C28 37.682 206166,6 2.94 n-C29 38,497 221589,4 3.16 n-C30 39.339 145259.7 2.07 n-C31 40.244 127967.9 1.83 n-C32 41.231 91771.71 1.31 n-C33 42.344 107790,9 1.54 n-C34 43 459 2874.69 0,04 n-C35 45.038 42371.96 0,6 n-C36 46.707 24743.2 OJ5 7010612 100 Batch Code Data File MCH (MeCyC6 as O¡. aH C7 alkanes) HER (Heptanel(Hp+MC':yC6) HXR (Hexanel(Hx+CyC:6) Thompson's Heptane ~tio Thompson's Iso Heptane: Index Nole: -I denotes not calc:ulated 971 I OiLOOlSOO7 C:\_DATA\B971 I 00 I \WOGCOO7.RAW GMC Data Report No, 279 971 1 OILOOI S007 I 145V154 VI3/6/97 C:\ßATA\B97 1 100 I \WOGC008,RAW Software Yer.lion: Dale: Sample Name: Data File: Sequence File: Instrument: Sample Amount 4, I <0007> 21/01/98 97110lLOOIS008 7020' splitlsplitJess C:\_DATA\B9711ool\WOGCOO8,RAW C:\ßA T A \B9711 00 I \WOGC3,SEQ WHOLE_On..s_GC I 14:21 Date: Cycle: Rack/Vial: tion Factor 16/12/97 09:58 3 Channel: A ° ° Operator. NSG I Whole Oil GC Analysis Component Time Area Amount Name [min) [µY'sJ [%J Propane 1.85 567,2 0.01 2-mcthylpropane 2.445 ° 0 n-butane 2.931 161.8 0 2-mcthylbutan.c 4,561 0 ° n-pentane 5.248 0 0 DCM 5.744 0 0 2,2-dimethylblltane 6.081 0 0 Cyclopentane 6.715 0 ° 2,3-dimethy ¡butane 6.859 0 0 2-methylpentane 7.024 0 0 3-methylpentane 7.369 0 ° n,hexane 7.942 mcthylcyclopentane 8.362 382.8 0,01 2,4-dimethylpe:ntane 8.646 1890.73 0,03 Benzene 9.05 390.9 0.01 cyclohexane 9.222 177 0 2,methylhexane+ 1.2-DMP 9.483 11889.16 0.17 3-methylhexane 9.79 399.1 0.01 1.3-cis-dimethl' I cyclopentane 9.878 325.5 0 1.3-trans-dime1hylcyclopentane 9.907 0 0 1.2-trans-dimelhylcyclopentane 9.952 93.8 0 n-heptane 10.396 0 0 metltylcyclohe:cane 10.772 0 0 ethylcyclopentnne 10.904 127.6 0 Toluene 11.725 68.9 ° n-Octane 12.675 57.2 8.00E.Q4 n-Nonane 14.801 0 0 n-Dec:ane 16.749 645.68 0,01 n-e11 18.592 2294,68 0,03 n-e12 20.16 224616.7 3.27 n-e13 21.819 1514951 22.09 n-e14 23.298 1728178 25.19 n-C15 24,635 623127.9 9,08 n-e16 25.902 167215.3 2.44 n-C17 27.14 138068.8 2.01 Pristine 27.261 279316.8 4.07 n-e18 28.309 91679,7 1.34 Phytane 28.469 67977.96 0,99 n-e19 29.427 158953,3 2.32 n-C20 30,494 90756.51 1.32 n-e21 31.516 104571.6 1.52 n-e22 32.496 93634,89 1.37 n-e23 33.435 110869,3 1.62 n-C24 34.336 116603,2 1.7 n-C:ZS 35,209 146009.9 2.13 n-C:Z6 36.043 139571.1 2.03 n-e27 36.852 153060,2 2.23 n-C28 37,644 130036,9 1.9 n-C29 38.461 154386.7 2.25 n-C30 39.301 95104,03 1.39 n-C31 4O.20S 99165.91 1.4S n-en 41.191 69588,27 1.01 n-C33 42.299 72898.64 1.06 n-C34 43.546 23543.1 0.34 n-C35 44.989 30782 0.45 n-C36 46.647 17407,4 0.25 6859332 100 Batch Code Data File MCH (MeCyC6 as % all C7 alkanes) HER (Heptanel(Hp+MeCyC6) HXR (Hexanel(Hx+CyC6) Thompson's Hl!;: lane Ra.tio Thompson's Iso Heptane index Note: -I denote:1 not calculated 97110n.OOIS008 C:\_DATA\B971100I\WOGCOO8.RAW CMC Data Report No, 279 97 I OILOO 5008 146/154 V I 3/6/97 C:\_DATA\B971Iool\WOGCOO9.RAW Software Version: Date: Sample Name: Data File: Sequence File: Instrument: Sample: Amount: 4.1<0007> 21/01/98 97110ILOOISOO9 F-3A 4800 C:\_DATA\B971 I 00 I \WOQCOO9.RAW C:\_DATA\B971100I\WOGC4,SEQ WHOLE_On.sßC I 14:19 Date: Cycle:: RaclcJV ial: tion Factor 16/12/97 13:36 2 Channel: A ° ° Operator: NSG I Whole Oil GC Analysi.s Component Time Area Amount Name [min] [µY's] [%] Propane 1.849 1149.8 0,01 2-methylpropane 2.445 ° 0 n-butane 3.008 0 0 2-methylbutane: 4.561 0 0 n-pentane 5.248 0 0 DCM 5,744 0 0 2,2-dimc:thylbutane 6.081 0 0 Cyclopentane 6.715 0 0 2.3-dimethylbutane: ·6.859 ° ° 2-methylpentane 7.024 0 0 3-methylpentane 7,404 n-hexane 7.937 mc:thylcyclopentane 8.474 219.6 0 2,4-dimc:thylpentane: 8.572 280.2 0 Benzene: 8.986 0 0 cyclohe:xane 9.132 444.6 0 2-methylhc:xane: + 1,2-[)MP 9.551 13207.91 0.15 3-methylhexane 9,703 976.09 0.01 1.3-cis-dimethylcyclopc:ntane: 9.844 ° 0 1 ,3-trans-dimc:thy ¡cyclo pentane: 9.847 126.2 0 1,2-trans-dimc:thy Icyclope:ntane: 9,933 438 0 n-heptane 10.332 119706.2 1.33 mc:thylcyclohexane 10,826 76.1 8.00E-04 ethylcyclopentane 11.008 4128.84· 0.05 Toluene: 11.567 1115.25 0,01 n-OCtane 12.577 123.6 0 n-Nonane 14.801 ° 0 n-Dc:cane 16.746 180.24 ° n-CII 18.641 3908.36 0.04 n-C12 20.146 32229.25 0.36 !!-CI3 21.796 1213516 13.46 n-C14 23.29 1702234 18,88 n-C15 24,611 440415.2 4.89 n-C16 25,897 158601.5 1.76 n-C17 27,131 163505.9 1.81 Pristane: 27.252 201397.1 2.23 n-C18 28.303 55408,4 0,61 Phytane 28,469 56114,77 0,62 n-C19 29.42 81516.5 0.9 n-C20 30,492 44153.45 0,49 n-C21 31.512 41531.63 0,46 n-C22 32,492 47539.24 0,53 n-C23 33.429 38270.1 0.42 n-C24 34.328 35418.1 0.39 n-C25 35.116 102480.5 1.14 n-C26 36.021 38544.27 0,43 n-C27 36,824 28732.6-4 0.32 n-C28 37.614 25227.58 0.28 n-C29 38,423 27914 0,31 n-C30 39,261 12064.8 0.13 n-C31 40,158 20734.07 0.23 n-C32 41.146 10057.9 0,1 ] n-C33 42,245 12018.4 0.13 n-C34 43.5 8346.89 0,09 n-C35 44.929 6068 0.07 n-C36 46.588 5183.4 0,06 9014389 100 Balch Code DaLa File MCH (MeCyC6 as "I. all C7 alkanes) HER (HeptancJ(Hp+McCyC6) HXR (Hexanel(Hx+CyCti) Thompson's Heptane RaIjo Thompson's Iso Heptane Index Note' -I denotes not ca!c\¡)a1ed 971 I OlLOO I S009 C:\_DATA\B97 I I 00 I \WOGCOO9,RAW GMC Data Report No, 279 97110IL001S009 1'-7/154 VIJ/6197 C:\_DATA\B97 I I 00 I\WOGCO 1 O.RAW Sotìware Yersåc,n: Dale: Sample Name: Data File: Sequence File: InstrUment Sample Amounl~ 4, I <0G01> 21101/98 97110ILOOISOIO F-JA 8010 C:\_DATA\B971IooI\WOGCOI0,RAW C:\_DATA\B971Iool\WOGC4,SEQ WHOLE_OILS_GC I 16112/97 14:53 3 Channel: A o ° Operator: NSG 1 14:14 Date: Cycle: Raçk/Vial: tion Factor Whole Oil GC Analysis Component Time Area AmoW1t Name [min [µY's] [%] Propano 1.818 0 0 2-methylpropanl= 2.445 0 0 n-butane 3,008 0 0 2-methylbutane 4.561 0 0 n-pentane 5.248 0 0 DCM 5.744 0 0 2.2-dimethyI butnne 6,081 0 0 Cyclopentane 6.73 2,3-dimethylbuullIe 6,848 2-methylpentane 7.024 0 0 3-methylpentane 7,369 0 0 n-hexane 7,92 methylcyclopental1e 8.373 302.8 0 2,4-dimethylpenl:ane 8.642 1244.7 0.01 Benzene 8.976 63.93 5.00E.Q4 cyclohexane 9,146 156.75 0 2-methylhexane + 1,2-DMP 9.468 10283.98 0.07 3,methylhexane 9.765 0 0 1 ,3-cis-dimethy c:yclopentane 9.87 279.8 0 1,3-trans-dimethJ¡ cyclopentane 9.907 0 ° 1,2-trans-dimethylcyclopentane 10.033 178 0 n-heptane 10,396 0 0 methylcyclohexane 10.772 0 0 etbylcyclopentan'c 10.998 320.4 0 Toluene 11.649 332.14 ° n-Octane 12.817 92.4 7,OOE.Q4 n,Nonane 14.936 148 0 n-Decane 16.733 2761.54 0.ß2 n-C11 18.594 3801.12 0.03 n-C12 20.148 347044.9 2.52 n-C13 21.804 1976300 14.36 n-C14 23.261 2670077 19.4 n-C15 24.574 357386.3 2.6 n-C16 25.865 79915,37 0.58 n-C17 27.106 69843.87 0.51 Pristane 27,227 73518.79 0.53 n-C18 28.284 47402.11 0.34 Phytane 28.449 48646.09 0.35 n-C19 29.406 63655.39 0.46 n-C20 30.478 45523.22 0.33 n-C21 31.501 39281.37 0,29 n-C22 32.481 38202.46 0.28 n,C23 33.421 35898 0.26 n-C24 34,318 32887.71 0.24 n-C25 35.326 41243.93 0.3 n-C26 36.011 35951.49 0.26 n-C27 36.816 21598.81 0.16 n-C28 37.603 25730.1 0.19 n-C29 38.411 39384.9 0.29 n-C30 39,25 12850.9 0.09 n-C31 40,145 22703.91 0.16 n-cn 41.123 1381S 0.1 n-C33 42.222 16029,13 0.12 n-C34 43.467 7660.15 0.06 n-C35 44.899 10535.57 0.08 n-C36 46.548 8255,09 0.06 13763146 100 Batch Code Data File MCH (MeCyC6 ~I % all C7 alkanes) HER (Heptanel(H )+MeCyC6) HXR (Hexanel(~;+<:yC6) Thompson's Heptane Ratio Thompson's !:so HI~ptane Index NolO: -I denotes Mt caJculaled 97110lLOOISOI0 C:\_DATA\B971100I\WOGCOI0.RAW GMC Data Report No. 279 97110lLOOISOI0 148/154 V 1316/97 C:'-.DATA\B9711001\WOGC01I.RAW Software Version: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amount: 4.1<0007> 21101/98 97110ILOOIS011 P-3A 8100 C:\_DATA\B971 lOOI\WOGCOI I.RAW C:'-DATA\B97 I 1 00 I \WOGC4.SEQ WHOLE_OlLS_GC I 16/12/97 16:10 4 Channel: A o 0 Operator: NSG I 14:13 Date: Cycle: RacldViaÌ: ûon P~r Whole Oil GC Analysis Component Time Area Amount Name [min] [µV's] [%] Propane 1.841 121.8 I.00E.()3 2-methyJpropane 2,445 0 0 n-butane 3.008 0 0 2-methylbutane 4.561 0 0 n-pentane 5.248 0 0 DCM 5.744 0 0 2,Z-dimethylbuæne 6,081 0 0 Cyclopenæne 6,715 0 0 2.3-dimethylbutane 6.859 0 0 2-mcthylpcntanc 7.024 0 0 3-methylpentane 7.369 0 0 n,hexane 7.957 methylcyclopentane 8.369 j55.76 0 2,4-dimcthylpentane 8,648 1302.44 0,01 Benzene 9.049 432.8 O· cyclohexane 9.22 164.2 0 2-methylhcxane + I.:Z-DMP 9.479 10312.69 0.08 3-methylhcxane 9.765 0 0 1.3-cis-dimethylcyc opentane 9.873 288.8 0 1,3-trans-dimethyICYI:!opentane 9.907 0 ° 1.2-trans-dimcthyICYI:lopentane 9.947 31.2 3.00E-04 n-heptane 10.299 390.05 0 methylcyclohcxane 10,879 97.2 8.00E-04 ethylcyclopentane 11.089 45.8 4.00E-04 Toluene 11.623 419 0 n..octane 12.7 0 0 n-Nonane 14.805 401.2 0 n-Oceane 16.743 1798 0.01 n-CII 18,472 16629.05 0.13 n-C12 20.194 676134.2 5.47 n-C13 21.892 5161172 41. 75 n-C14 23.336 4091588 33.1 n,C15 24.609 612489.3 4.95 n-C16 25.882 159275.9 1.29 n-C17 27.12 207926,4 1.68 Pristane 27.242 155172.2 1.26 n-C18 28.296 91168.3 0,74 Phytane 28.459 82759.58 0.67 n-C19 29.419 135330.8 1.09 n-C20 30.489 86117.6 0.7 n-C21 31.512 83527.4 0,68 n-C22 32.491 95246.57 0,77 n-C23 33.43 83726.9 0,68 n-C24 34.327 63141.9 0.51 n-C25 35,194 95359.27 0.77 n-C26 36,019 62446,89 0.51 n-C27 36.823 42906.8 0.35 n-C28 37.61 40692.35 0,33 n-C29 38,417 39969.39 0.32 n-C30 39,254 16793,69 0.14 n-C31 40,149 22863.82 0,18 n-cn 41.126 12745.91 0,1 n-C33 42.226 14703.27 0,12 n-C34 43,47] 7590.44 0.06 n-C35 44,897 6057.6 0,05 n-C36 46,547 4308,4 0.03 12361745 100 Batch Code Data File MCH (MeCyC6 as 0/. all C7 alkanes) HER (Heptancl(HpTMeCyC6) H.,XR (Hexancl(Hx+CyC6) Thompson's Heptane iùtio Thompson's Iso Heptane: Index Note: -I denotes not calc:ulatcd 971 IOILOOISOI 1 C:\_DATA\B971100I\WOGCOII.RAW GMC Data Report No, 279 97110IL001S011 149/154 V 13/6197 í; ~ .¡ ... ~ '. ~ r Software Version: Dale: Sampler Name: DaII File; Sequence file; Instrument: Sample Amount: Whole Oil GC Analysis Component Name Propane 2-methylprop8llle n-butane 2-methylbutane n-pentane DCM Z,2-dimethylbu1ane CycJopentane 2,3-dimethylbutane 2-methylpentan" J-metbylpentaM n-hexane methylcyclopen:tane Z, 4-dimethy I pen.tane Benzene cyclohexane 2-mctbylhexane + 1,2-DMP 3-metbylhcxane I.J-cis-dimethy Icyclopentane I ,2-trans-dimeth y Icycfopentane 1,3 -trans-dimeth y Icyclopentane n-heptane methylcyclohCJt lI1e etbylcyclopentallle Toluene n-Octane n-Nonane n-Decane n-C1l n-C12 n-C13 n-C14 n-C15 n-C16 n-C17 Pristane n-C18 Phytunc n-C19 n-C2D n-C21 n-C22 n-C23 n-C24 n-C2S n-C26 n-C27 n-C28 n-C29 n-C30 n-C31 n-C32 n-C33 n-C34 n-C35 n-C36 BalCh Code Dm File MCH (MeCyC6 3:\ 0/. all C7 alkanes) HER (Heptancl(H¡>+MeCyC6) HXR (Hexancl(H>;+<:yC6) Thompson's Heptane Ratio Thompson's Iso H,~tane Index Note: -I denotes Mt calculated GMC Data Report No, 279 C:\.QATA\B971100I\WOGCOI2.RAW 4, 1<0007> 21/01/98 97110rLool5012 f,JA C:\_DATA\B971100I\WOGCOI2.RAW C:\ßATA\B971100I\WOGC7.SEQ WHOLE_OrLS_GC I Time [minI 1.85 2.445 3.008 4,561 5.248 5.744 6,081 6,715 6.859 7.024 7.369 8.035 8.407 8.665 9.051 9.159 9.473 9.857 9,93 9.964 10.015 10.396 10.848 11.07 11.614 12.7 14.801 16,742 18,469 20,16 21.826 23.285 24,589 25.878 27.124 21.246 28.3 28.461 29.424 J0.497 31.S16 32.495 33.432 34,329 35,193 36,017 36,822 37.608 38.412 39.248 40.143 41.361 42.217 43.559 44,885 46.526 971101LOOIS012 C:\ßATA\B97 I I 00 I \WOGCO I 2.RAW 15:38 Date: Cycle: RackIVial: tion Factor 17/12197 16:32 1 Channel: A o 0 Operator. NSG I Area Amount [ .LV·s] [%] 170,3 0 0 0 0 ° 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2.19 149.2 0 1853.4 0.02 446 0.01 156 0 11587.78 0.15 294,8 0 26.4 3.00E-04 0 0 173,1 0 0 ° 104.7 0 40.4 5.ooE-04 402.4 0.01 0 0 0 0 328,6 0 2732.61 0,03 ,226278 2,86 2664670 33.62 2354028 29,7 387712 4.89 144468.2 1.82 144539.8 1.82 145320,2 1.83 131498.5 1.66 112343.6 1.42 217949.4 2.75 131825.3 1.66 125955.3 1.59 1255SI.S 1.58 115000.1 1.45 99590.96 1.26 129256 1.63 87587 1.11 69003.73 0,87 126978.8 1.6 81294,2 1.03 18457,7 0,23 25493.98 0.32 29182.68 0.37 14483.02 0.18 13222.31 0.17 7788.44 0.1 4389,34 0.06 79255 II 100 97110lLOOISOl2 150/154 V 13/6/97 C:\ßATA\B97 1 1001 \WOGCOI 3.RAW Software Version: Date: Sample Name: Data File: Sequence File: Instrument: , Sample Amount: 4.1 <OG07> 21/01/98 97110ILOOISOIJ f-JA 8610' C:'-DATA\B971 I 001 \WOGCOI J.RAW C:\_DATA\B971100I\WOGC6.sEQ WHOLE_On..s_GC I 17/12/97 09:59 I Channel: A o 0 Operator: NSG I 15:45 Date: Cycle: Rack/Vial: tion Factor Whole Oil GC Analysis Component Time Area Amount Name [min] [µY's] [%] Propane 1.848 136.1 0 2-methylpropane 2.445 0 0 n-butane 2.963 332.2 0 2,methylbutane 4.561 0 0 n-pentane 5.248 0 0 DCM 5,744 0 0 2,2-dimethylbutane 6.081 0 0 Cyclopentane 6.715 0 0 2,3-dimethylbutane 6.859 0 0 2'methylpentane 7,024 0 0 3,methylpentane 7.369 0 0 n-hexane 7.925 methylcyclopentane 8.355 199.4 0 2,4-dimethylpentane 8.639 1089,8 0,01 Benzene 9.042 411.8 0 cyclohexane 9.155 139.8 0 2-methylhexane + 1,2·J)MP 9,475 11811.8 0.12 3-methylhexane 9,765 0 0 I,J-cis-dime.thylcyclopentane 9,873 422.6 0 1,3'!rans-dimethylcyclopentane 9.907 0 0 1,2,trans-dimethylcycle,pentane 9.946 66.\ 7,00E-04 n-heptane 10.308 767183.8 7,68 methylcyclohexane 10.877 295.86 0 ethylcyc:lopentane 10.982 141383.5 1.42 Toluene 11.539 59776 0,6 n-Octane 12.7 0 0 n-Nonanc 14.801 0 0 n-Decane 16.741 1448.25 0.01 n-CII 18.471 27936,54 0.28 n-C12 20.193 664472.8 6.65 n-C13 21.858 3731407 37.36 n-C14 23.282 1997156 19.99 n-C15 24.59 290857 2.91 n-C16 25.88 111278.8 1.11 n-C17 27.123 166784.6 1.67 Pristane 27.261 326456.9 3.27 n-C18 28.295 80292.6 0,8 Phylalle 28.466 182562 1.83 n-C19 29,417 105359.6 1.05 n-C20 30.486 62477.6 0.63 n-C21 3 I. 508 75915.91 0.76 n-C22 32.487 69738.77 0.7 n-C23 33,425 81181.3 0,8] n-C24 34.322 64575,45 0,65 n-C25 35,191 93467.69 0.94 n-C26 36,022 64171.91 0.64 n-C27 36,831 64548.97 0.65 n-C28 37.619 52562.67 0.53 n-C29 38.431 58377,85 0,58 n-C30 39,263 13598,04 0,14 n-C31 40,155 29828.58 0.3 n-cn 41.279 19981.98 0,2 n-C33 42.234 18009.02 0,18 n-C34 43,48 3345.2 0,03 n-C35 44,908 5293,6 0.05 n-C36 46.56 5220.11 0,05 9988822 100 Bouch Code Data File MCH (MeCyC6 as 0/. all C7 alkanes) HER (Heptanel(Hp-+-MeCyC6) HXR (Hexanel(Hx+CyC6) Thompson's Heptane Ratio Thompson's Iso Heptane Index Note: - ¡ denotes not caJc.'Jloued 97110lLOO1S013 C:\_DATA\B971 1 00 I \WOGCO I 3,RAW GMC Data Report No, 279 97110110018013 151/154 i ~ !.. V 13/6/97 C:\ßATA\B971Iool\WOOCOI4,RAW Software Version: Dale: S¡¡mple NalTle: Dats File: Sequence Fi!le: Instrument: S¡¡mple Amclunt: 4, ¡ <0007> 21/01/98 97110lLOOISOl4 F-3A 8800' C:\_DATA\B971Iool\WOGCOI4,RAW C:\_DA T A\B9711001\WOGC6,SEQ WHOLE_OILSßC I Date: Cycle: RadclVial: tion Factor 17/12197 11:12 2 Channel; A o 0 Operator: NSG I 15:49 Whole Oil GC Analysis Component Time Area Amount Name [min] [µV's] WoJ Propane 1.865 191 0 2-mcthylpropane 2.445 0 0 n,butane 3.008 0 0 2·methylbutaJ~e 4,561 0 0 n-pentane 5.248 0 0 DCM 5.744 0 0 2,2-dimcthylb,utane 5.957 Cyclopentane 6.715 0 0 2,3-dimethylbutane 6,859 0 0 2-mcthylpenuLlle 7.024 0 0 3-mcthylpenuLlle 7:369 0 0 n-hexane 8.011 methylcyclopc:ntane 8,404 316.8 0 2,4-dimethylpentane 8.609 0 0 Benzene 8.986 0 0 cyclohexane 9.157 166.4 0 2-methylhcxarle + 1,2-DMP 9.476 11960.8 0.11 3-methylhCXIUle 9.765 0 0 1,3-cis-dimethylcyclopentane 9.844 0 0 1,3-trans-dimethy Icyclopentane 9,907 0 0 1,2,trans-dimethy Icyclopentane 9,945 41.9 4.ooE-04 n-heptane 10.396 0 0 methylcyclohe:(ane 10.875 125.8 0 ethylcycJopentUle 11. 096 86 8.ooE-04 Toluene 11.635 52.4 5.00£-04 n-Octane 12.7 0 0 n-Nonane 14.801 0 0 n,Decane 16,744 318.1 0 n-e11 18.472 18973.23 0.18 n-e12 20.193 597907,8 5.74 n-e13 21.869 3765306 36.16 n-e14 23.3 2410339 23,14 n-e15 24,603 <W8366.7 3.92 n-e16 25,895 265863.3 2.55 n-C17 27.137 293332.2 2.82 Pristane 27.262 298283.8 2.86 n-C18 28.31 216883.2 2.08 Phytane 28.468 154669.9 1.49 n-e19 29.432 261191.2 2.51 n-e20 30,499 185329.1 1.78 n-C21 31.519 171595,6 1.65 n-C22 32.495 144959,7 1.39 n-C23 33.433 152971.3 1.47 n-e24 34.326 108912.4 1.05 . n-C25 35.196 154490.1 1.48 n-e26 36.017 100816.4 0.97 n-e27 36.821 97765.4 0,94 n-e28 37.603 66438,95 0.64 n-e29 38.411 81468.18 0,78 n-e30 39,243 28742.74 0,28 n-e31 40.137 36477,91 0.35 n-e32 41.115 14821 0,14 n.o3 42.21 21246.72 0.2 n-C34 43.447 6793.97 0.07 n-C35 44.871 7356 0,07 n-e36 46.512 3017 0.03 10414107 100 Batch Code Data File MCH (MeCyC6 ¡IS % all C7 a1lcanes) HER (Héptanc:l(Hp+MeCyC6) HXR (Hexanel(Hx+CyC6) Thompson's HeptUle Ratio Thompson's Iso Heptane Index Note: -I denotes r.:ot calculated 97110lLOO1S014 C:\_DATA\B971100I\WOGCOI4,RAW GMC Data Report No, 279 97110lLooISOl4 152/154 Y13J6/97 C:\ßATA\B9711001\WOGCOIS.RAW Software Yersion: Date: Sample Name: Data File: Sequence File: Instrument: Sample Amount: 4,1<0007> 21/01/98 971IOILooISOI5 F-3A 8S4O' C:\_DATA\B9711001\WOGCOI5.RAW C:'-DATA\B971IOOI\WOGC6.SEQ WHOLE_Oll.S_GC I 15:53 Date: Cycle: RaclcNial: tion Factor 17/12/97 13:54 3 Channel: A o 0 Operator: NSG I Whole Oil GC AnalYilis Component Time Area Amount Name [min] [ lY'S} [%] Propane 1.871 941.2 0 2-methylpropane 2,445 ° ° n-butane 3.008 0 ° 2-methylbutane 4.561 0 ° n-pentane 5.248 ° 0 DCM 5,744 ° ° 2,2-dimethylbutane 6.081 0 ° Cyclopentane 6.715 ° ° 2,3,dimethylbutane 6,859 ° ° 2-methylpentane 7.024 ° ° 3-methylpentane 7.369 ° ° n-hexane 8.013' methylcyclopentane 8,416 232.51 9.ooE-04 2,4-dimethylpentane 8.609 165.33 7.ooE-04 Benzene 8.986 ° ° cyclohexane 9.26 187 7,00E-04 2-methylhc:xane + 1,2·ÐMP 9.515 3-methylhexane 9.82 99.5 4.00E-04 1,3-cis-dimethylcycloI'CI'Itane 9,906 332.8 ° 1,3-trans-dimethylcyclopentane 9,907 ° ° 1,2-tnlns-dimethylcyclopentane 9.982 92.2 4,00E-04 n-heptane 10.311 1653.56 0.01 methyJcyclohexane 10.733 88.7 4,ooE-04 ethylcyclopentane 10.912 179.6 7,ooE-04 Toluene 11.728 104,93 4.ooE-04 n.octane 12.686 88.4 4,00E-04 n-Nonane 14.902 126.3 5.00E-04 , n-Decarle 16.727 ]400.8 0,01 n-CII 18,455 95703.86 0.38 n-C12 20.249 991782.7 3.96 n-C13 21.932 3434782 13.71 n-C14 23.382 3331401 13.3 n-C15 24.696 1298603 5,18 n-C16 26.012 1206995 4.82 n-C17 27.282 1861977 7.43 Pristane 27,405 141741.6 5.66 n-C18 28,466 1334270 5.33 Phytane 28.612 654453 2,61 n-C19 29,602 1837643 7.33 n-C20 30,666 1196474 ,4.78 n-C21 31,678 1023698 4.09 n-CU 32.642 903884.4 3.61 n-C23 33.567 804 738.8 3.21 n-C24 34.448 625767 2.5 n-C2S 35.307 686143.1 2.74 n-C26 36,122 470735 1.88 n,C27 36,917 462494,6 1.85 n-C28 37,696 297741.5 1.19 n-C29 38,505 240608 0.96 n-C30 39.333 151302 0,6 n-C31 40.232 144533,6 0,58 n-cn 41.21 74489.3 5 0,3 n-C33 42.311 100404.2 0.4 n-C34 43,654 54969,96 0,22 n-C35 44,984 33088.98 0,13 n-C36 46,632 20726.57 0.08 25053947 100 Bau:h Code Data File MCH (McÇyC6 as % all C7 alkanes) HER (Heptanel(Hp+MeCyC6) HXR (Hexanel(Hx+CyC6) Thompson's Heptane &llio Thompson's Iso Heptane, Index Note: ,I denotes not calc:ula1cd 97110lLooISOl5 C:\_DATA\B97 I I 001 \WOGCO 1 5.RAW GMC Data Report No, 279 97110ILOOISOl5 ~53/154 1. ~ ,¿ r .~ ; V 13/6/97 C:\_DATA\B971100I\WOGCOI6,RAW 97110lLOOIS016 ~ Software Ver.¡ion: Dale: Sample Name: Data File: Sequence File: InstnJmeltt: Sample Amount: 4,1<0007> 21/01/98 97110lLOOISOl6 F-3A 9120' C:\_DAT A\B97 I I 00 I \WOGCO I 6.RAW C:\_DATA\B9711001\WOGC6,SEQ WHOLE_OILS_GC 1 15:57 Date: Cycle: RackIVial: tion Factor 17/12197 IS: II 4 Channel: A o 0 Operator. NSG I Whole OU GC Analysis Componet1l Time Area Amount Name [minI [µV·sl [% Propane 1.85 78.3 0 2-methylpropane 2.445 0 0 n-butane 3.008 0 0 2-methylb~tane 4.561 0 0 n-pentane 5.248 0 0 DCM 5.744 0 0 2,2-dimetltylbutane 6.081 0 0 Cyclopen~lI1e 6.715 0 0 2,3-dimethylbutanc 6.859 0 0 2-methylp~:ntane 7.024 0 0 3-methylptmtane 7.369 0 0 n-hexane 7,949 methylcyclopentane 8.349 277,8 0 2,4-dimethylpentanc 8.623 1268.2 0.02 Benzene 9.018 433.6 0,01 cycloheX3l1',e 9.129 155,2 0 2-methylh~xanc + 1,2-DMP 9,527 2078 0.03 3-methylhexane 9.848 283.4 0 1,3-cis-dimethylcyclopentane 9.921 48.8 7,OOE-04 1,2-trans-di methylcyclopentane 9.964 0 0 I,J,trans-di methylcyclopentane 10.013 181.9 0 n-heptanll 10.396 0 0 methylcycll)hexane 10.87 109 0 ethylcyclopentane 11.015 0 0 Toluene 11.57 0 0 n-octane 12.7 0 0 n-Nonane 14.883 120 0 n-Decane 16.741 1472.28 0.02 noC11 18.464 12621.17 0.18 noCI2 20,17 440760.3 6.19 noC13 21.83 3006149 42.24 noCI4 23,269 1781555 25.03 noCI5 24.583 275014 3.86 n-C16 25.873 98944.55 1.39 n-C 17 27.111 128284 1.8 Pristane 27.231 185993.3 2.61 n-C18 28,284 61976.6 0.87 Phytal1l:: 28.447 S7175.16 0,8 n-C19 29,4û4 87344,8 1.23 n-C20 30.473 57546.13 0.81 n-C21 31.494 57525.98 0,81 n-cn 32.471 57970.57 0.81 n-C23 33.409 63189,4 0.89 n-C24 34,307 56106,67 0.79 n-C25 35.177 78648.67 1.11 n-C26 36.005 54264.5 0.76 n-C27 36.813 51760.5 0,73 n-C28 37.601 43267,2 0,61 n-C29 38.412 53370 0,75 n-C30 39,249 25742.8 0.36 n-C31 40.148 29989.37 0.42 n-C32 41.127 19359 0,27 n-C33 42.224 25106.85 0.35 n-C34 43.326 4495.8 0.06 n-C35 44,896 14888,26 0.21 n-C36 46.546 780.2 0.01 7117154 100 Balch Code Data File MCH (MeCyC6 as % all C7 alkanes) HER (Heptar;eI(Hp+MeCyC6) HXR (HexaneJ(Hx+CyC6) Thompson's Heptane Ratio Thompson's Iso Heptane Index Note: -1 denotes not calculaled 97110lLOO1S016 C:\_DATA\B971100I\WOGCOI6,RAW G:,fC Data Report No, 279 154/154
