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Home My WebLink AboutGMC Data Report No. 280 Geochemical analysis of cuttings from the following North Slope oil/gas exploratory wells: Sahio Alaska Petroleum Co. Nechelik No.1 (8,520'-8,790'), U. S. Navy (Husky Oil NPR) Atigaru Point No.1 (7,190'-8,600'), U. S. Navy (Husky Oil NPR) East Teshekpuk No.1 (7,090'- 8,850'), U. S. Navy (Husky Oil NPR) South Harrison Bay No.1 (5,700' -9,200'), and U. S. Navy (Husky Oil NPR) West Fish Creek No.1 (7,290'-9,500'). ~ , ~".'~......'..'<~~~''''~~~~'\...', ,., \' £.~.' . ~~, ,JJ;;wj . ~ ~-.:~ ,.".T. '," · a , ~. ,- . . '.' ....""" .... ,~ . ',\ . .- ... Received 13 February 1998. Total of 126 pages in report. Alaska Geologic Materials Center Data Report No. 280 GMC Data Report 280 LGC GEOCHEMISTRY Geochemical Analysis of Cuttings Samples from Nechelik-l, Atigaru Point-l, East Teshekpuk-l, South Harrison Bay-l and West Fish Creek-l, Alaska by : M.P. Dee LGC (Teddington) Ltd. Ref.: LFX/228/56 Prepared for: Neil Piggott BPX Sunbury Chertsey Road Sunbury on Thames Ref.: L Vll1452 Authorised by: SR Andrews Date: 14-Nov-97 C /Vt c t3a4.~"y ¿ gt) Page1õf 126 Summary List of Tables List of Figures Tables Figures Appendices Appendix A Appendix B Appendix, C GMC Data Report 280 Contents Vitrinite Reflectance Codes Molecular Parameter List Biomarker Identification Page 2 of 126 LFX/228/56 CONFIDENTIAL Summary Summary This report details geochemical analytical data for cutting samples from Nechelik-l, Atigaru Point-l, East Teshekpuk-l, South HalTison Bay-l and West Fish Creek-I, Alaska. Source potential (pyrolysis PlP2 and Total Organic Carbon) has been detennined on mudstone and limestone samples from the five wells. Thennal maturity by vitrinite reflectance has been detennined on limited samples from each of the wells. A number of the richer samples from each of the five wells have been solvent extracted to attempt to characterise the hydrocarbon extracts 'by total soluble extract (TSE) GC, high resolution GC-MS and stable carbon isotope analysis of the kerogen and total soluble fractions. Additionally, two oil shows in sandstones at 5700ft and 5800ft from South HalTison Bay-l have been extracted, and the soluble hydrocarbons characterised by total soluble extract (TSE) GC, high resolution GC-MS and TSE stable carbon isotopes. The hydrocarbon recoveries for the two oil shows were very low, consequently the TSE GC chromatograms are poor. The chromatograms display an unresolved 'hump' that is probably column. bleed rather than a characteristic of the sample. GMC ðgt~e~gpsJ9!80 Page 3 of 126 ~ e: -= I:: c: -= I: I:: It It I: I: I: It: It: It: It: I: Ie Ie Ie -= II::: Ie -= -= It: It: II: II: I:: II:: .-= -= "LFX/228/56 Table No. 1 2 3 4 5 6 7 8.1- 8.2 9 10 11 12.1 - 12.2 13 14 15 16.1 - 16.4 17 18 19 20.1 - 20.2 G11~~~t280 CONFIDENTIAL List of Tables List of Tables Nechelik-l - Lithology and Stratigraphy Nechelik-l - Optical Source Rock Maturity Indicators Nechelik-1 - Source Rock Quality Indicators Nechelik-1 - Sediment Extract Analysis Atigaru Point-! - Lithology and Stratigraphy Atigaru Point-1 - Optical Source Rock Maturity Indicators Atigaru Point-l - Source Rock Quality Indicators· Atigaru Point-l - Sediment Extract Analysis East Teshekpuk-l - Lithology and Stratigraphy East Teshekpuk-l - Optical Source Rock Maturity Indicators East Teshekpuk-l - Source Rock Quality Indicators East Teshekpuk-l - Sediment Extract Analysis . South Harrison Bay-l - Lithology and Stratigraphy South Harrison Bay-l - Optical Source Rock Maturity Indicators South Harrison Bay-l - Source Rock Quality Indicators South Harrison Bay-l - Sediment Extract Analysis West Fish Creek-l - Lithology and Stratigraphy West Fish Creek-l - Optical Source Rock Maturity Indicators West Fish Creek-l - Source Rock Quality Indicators West Fish Creek-l - Sediment Extract Analysis Page 4 of 126 LFX/228/56 Figure No. 1 2 3.1 - 3.3 4 5 6 7 8.1 - 8.2 9.1 - 9.6 10.1 - 10.2 11.1 - 11.2 12.1 - 12.2 13 14.1 - 14.6 1 5.1 - 15.2 16.1 - 16.2 1 7.1 - 1 7.2 18.1-18.2 19 20.1 - 20.4 21.1 - 21.12 22.1 - 22.4 23.1 - 23.4 24.1 - 24.4 25 26.1 - 26.2 27.1 - 27.6 28.1 - 28.2 29.1-29.2 30.1 - 30.2 G~¿~~f~~6~i80 CONFIDENTIAL List of Figures List of Figures Nechelik-l - Vitrinite Reflectance Thermal Maturity Plot Nechelik-1 - Whole Oil GC Chromatogram Nechelik-1 - Sterane and Triterpane Ion Chromatograms Nechelik-l - Aromatic Sterane Ion Chromatograms Nechelik-l - Phenanthrene and Methyl Phenanthrene Ion Chromatögrams Nechelik-1 - Biphenyl and Dibenzothiophene Ion Chromatograms Atigaru Point-l - Vitrinite Reflectance Thermal Maturity Plot Atigaru Point-l - Whole Oil GC Chromatograms Atigaru Point-l - Sterane and Triterpane Ion Chromatograms Atigaru Point-1 - Aromatic Sterane Ion Chromatograms Atigaru Point-1 - Phenanthrene and Methyl Phenanthrene Ion Chromatograms Atigaru Point-1 - Biphenyl and Dibenzothiophene Ion Chromatograms East Teshekpuk-1 - Vitrinite Reflectance Thermal Maturity Plot East Teshekpuk-1 - Whole Oil GC Chromatograms East Teshekpuk-1 - Sterane and Triterpane Ion Chromatograms East Teshekpuk~ 1 - Aromatic Sterane Ion Chromatograms East Teshekpuk-1 - Phenanthrene and Methyl Phenanthrene Ion Chromatograms East Teshekpuk-1 - Biphenyl and Dibenzothiophene Ion Chromatograms South Harrison Bay- 1 - Vitrinite Reflectance Thermal Maturity Plot South Harrison Bay-l - Whole Oil GC Chromatograms South Harrison Bay-1 - Sterane and Triterpane Ion Chromatograms South Harrison Bay-l - Aromatic Sterane Ion Chromatograms South Harrison Bay-! - Phenanthrene and Methyl Phenanthrene Ion Chromatograms South Harrison Bay-1 - Biphenyl and Dibenzothiophene Ion Chromatograms West Fish Creek-l - Vitrinite Reflectance Thermal Maturity Plot West Fish Creek-l - Whole Oil GC Chromatograms West Fish Creek-l - Sterane and Triterpane Ion Chromatograms West Fish Creek-l - Aromatic Sterane Ion Chromatograms West Fish Creek-l - Phenanthrene and Methyl Phenanthrene Ion Chromatograms West Fish Creek-l - Biphenyl and Dibenzothiophene Ion Chromatograms Page 5 of 126 ,e:; I:: It: It:I I:: I:: r:: It: II:: I:: I:: I:: It: I:: It: It: :d -= ~ II: -= -= :d II: II: -= -= I' N echelik-l Data GMC Data Report 280 Page 6 of 126 CJ ~ (') Ö P' ...-+ P' ?:1 CD Þ¡:j o ~ N 00 <:) TABLE 1 LITHOLOGY AND STRA TIGRÁPHY COUNTRY: WELL: Alaska Nechelik-l DEPTH ft DEPTH RANGE ft FORMATION AGE LITHOLOGY PICKED LITHOLOGY SAMPLE TYPE 8520 8610 8700 8790 MDST -dk gy shale 40%:MDST -dk gy calcareous 40%:SST -It bn 25% MDST-dk gy shale 20%:MDST-dk gy calcareous 50%:SST-It bn 30% LST-It gy 700Æ.:MDST-m gy calcareous 30% LST-It gy mddy 70%:MDST-m gy calcareous 30% Mudstone Mudstone Limestone Limestone CUT CUT CUT CUT I-c:J P' (JQ CD -....] o H-¡ Þ--' N 0\ . ___ ..___ _____ . ____ _______~____...______._ ~._ -1-- __" _. - ._--~_.._'.. =" _._ __::-::;-_~-...;:.::-~..;=:;-~.:.~-:;-_-:--.-~--_-_~_-=----- __ - _.~._ . - ~ _- . _'. _. .. _, . .' . _.-. _-__ ._. '_ _':. ...........~..... "'," ._. ._._ _~~ _-. - . -:-.. .___~ -:--_._--:--___._-.:.. .::.~-.-.--.:::::..:......;...--. n..'._~· ;.-_. - '.. .,. :"-", --- '-"~- -- .....,.. . - _- .- .,. , . u_ _.-__-+_~._..._._.-~~-._._~_ .r.~~_~__ C) ~ (J t1 p.) ~ p.) ~ (1) '"d o ::¡ tv 00 o TABLE 2 OPTICAL SOURCE ROCK MATURITY INDICATORS COUNTRY Alaska WELL: Ncchelik-I DEPTH (ft) FORMA TION VITRINITE NO. of CONFIDENCE (%Ro) READINGS COMMENTS 8610 0.49 20 o L-MOD;IPAR 90% VPAR+WPAR 10%;BS MOD+STR BW MODIRI;AMORPH L.O. MOD/RI SP Y/O+L Con fidence A=Excellent B=Good C=A verage D=Poor E=Unreliable I¡j p) (JQ (1) 00 o H-¡ ......... tv 0\ " " " " IUf " " Il1r " " " Il.1I " " " " R R R n " Rlt R 0 OR II II U o 1000 2000 3000 4000 -ï= .c 5000 C. Q) C· 6000 7000 8000 9000 10000 0.1 Vitrinite Reflectance Thermal Maturity Plot Well Name: Nechelik-1 ! . I / I I 3 0/0 Ro GMC Data Report 280 Page 9 ofi~tge 1 Cl 2:: (J t) Po) .-t- Po) ~ (1) ~ o ::¡ N 00 o ~ P' Oq (1) o o H) ~ N 0\ TABLE 3 SOURCE ROCK QUALITY INDICATORS COUNTRY: Alaska WELL: NecheIik-l DEPTH DEPTHRANGE FORMATION PICKED LITHOLOGY PI PI P2 (ft) (ft) (kg/t) (mg/gC) (kg/t) 8520 Mudstone 1.16 36.4 11.12 8610 Mudstone 1.09 46.0 10.47 8700 Limestone 1.00 61.7 6.42 8790 Limestone 1.55 58.3 11.65 -~.- -.-.. ~. -.--. ...-... -.- - --~--- -~- Toe TMAX HI (%) degC 3.17 441 350 2.37 442 441 1.62 438 395 2.66 438 438 GOGI CARBT S (%) (%) 10.49 1.61 25.86 1.67 69.72 0.96 52.88 0.89 .- --- --- --- _ ___._ .. . . _ ~ _ __----------------:---_ __ _. . _.,~_' _. . _ _ __:-_~ _._. -.- ____ -.'- _- - _ .-. ·-..r-..r-- - --_._r _ ~ __,- 1_- -.' -,:- - -_~ _ _ ___.... .______"~_n__.____.--o__ ~ ____ C1 ~ (J tJ ~ -- ~ ïO (t) >a o ::¡ N 00 <=> Inspection Properties API: Density @ 15 deg C : Wax Content ·/ewt : Wax Melting Point deg C: Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOHlg : Asphaltenes ·Iowt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : III : 112 : 113 : 114: liS: 116: 117: 118: ÞO¡j 119 : p:¡ (fQ 1110 : (!) ~ UII: ~ 0 1112: ~ 1113: ~ N 1114 : 0\ illS: 1116 : 1117: 1118 : 'Veil name: Suite name: Country Of Origin: Depth (m) : Sample.name: 0.57 0.55 0.87 o 100:66:44:28: 17:8 0.51 0.61 9.20 3.24 0.00 6.77 0.00 0.00 31.91 0.00 - '.- - - , __r·· ._ - ~ . -_ _ ,_. C--_'~-:_,=__---==-"--==="""_~~-=""_ '-c'·' ... Sediment/Extract Analysis Nechelik-1 NPRA Study Alaska 8520 Extraction TSE %wt: 0.349 HPLC Saturates °/ewt: Aromatics %wt : Residues %wt : Asphaltenes (Micro Method) %wt : Saturates GC PristanelPhytane : Pristane/nC17 : Phytane/nC18 : CPI: ALKIND : R22 : Biomarker Ratios SI : 051 M2 : 0.57 S2 : 0-44 M3: 0.57 S3: 35:28:35 M4: 65.16 84: 32:24:42 M5: S5 : 30.35 At: 0.79 S6: A2 : 0.78 A3 : 0.32 S7 : 50.02 A4: 0.17 88: 23.44 AS : 0.34 S9 : A6: 0.66 S10 : MDR: 1.26 MBP: 5.57 Light Hydrociubons MCR % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : Aromatics : Residue: Asphaltenes : Kerogen : -31 -30 STANDARD: NBS22 -29.8 Table 4 n'"""""""" R.R ".R""""" ø n n ø.O If 111111 n fI 0 .flO I·I~. pMÇ: P~tq ¡~~~9n (f~Q¡ : 000 ~ (j) CO Ii 6 ,..... I I o to ! 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OEO 24 : 00 26 : 00 28 : 00 30 : 00 Time I I I I I 22:00 ~ -- ---'~~---...-.-.. .. _n ----~--~__.__.__=c=..--==-=-~__=_-...;_ _:.-_--_-_~_~_.:-:-:- ~_ Page 19 of 126 GMC Data Report 280 Atigaru Point-l Data a ~ n t::J p) .-+ p) 10 CD ~ o ::¡ N 00 o TABLE 5 LITHOLOGY AND STRATIGRAPHY COUNTRY: WELL: Alaska Atigaru Pt-l DEPTH ft DEPTH RANGE ft FORMATION AGE LITHOLOGY PICKED LITHOLOGY \- 7190 7280 7370 7460 7550 7640 7730 7820 7910 8000 8090 8180 8360 8450 8540 8600 Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone MDST-m bnlgy 70%:SLTST-It-m bn sndy 30% MDST-m bnlgy-45%:SLTST-It-m bn sndy 55% MDST-m-dk gy 80%:SL TST -m gy 20% MDST-dk gy shaley 95%:SLTST-m gy 5%:MDST-orTr MDST -dk gy 1 OO%:SL TST -m gy Tr:MDST -or Tr MDST-dk gy 100%:SL TST -m gy Tr.MDST -or Tr MDST -dk gy I OO%:SL TST -ffi gy Tr:MDST -or Tr MOST-dk gy lOO%:SLTST-m gyTr MDST-dk gy 100%:SLTST-m gy Tr MDST-dkgy/bk lOO%:SLTST-mgyTr MDST-dkgy/bk lOO%:SLTST-m gyTr MOST -dk gy/bk 1 OO%:SL TST -m gy Tr MOST-elk. gy calcareous 40%:SST -It gy slty 60% MDST -dk gy calcareous 60%:SST-lt gy slty 40% MDST -dk gy calcareous 60%:SST -It gy slty 40% MDST -dk gy calcareous 70%:SST -It gy slty 30% I¡j p) (JQ CD N o o H; I--' N 0\ -- - - -.._--,--.- ......~..........=~~~-----~- ,- ....-.- ".--" ~--. - -~-.----.'-';.._-~'----~--~---~._-...,;:.-,.::::::;..~.-~".-~--"'--,=~_.--=--.;:----:---,,-.--:--:- -. - - SAMPLE TYPE CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT --- - -- -------- - -- _:..:=_-:-- :_:.~.._-",,-~~_., ------:-:: -- _ - __. _. .. .., _ .__ ___. _ ,___ __~_ _ ...,.. _ ____ _ . . . -.- -Iv ,-. "_ I _ . _ _ . --.- - --- ~~---~_ -. - -- ~- ~ .- _ - -.. . ~.. _...... . - - . - . ' -, - . .-~~. . ..-.....-' - '. --~-....-. L' -.-..;.-.....-..-- '---. '_..;=:.-~- -~..;';... - --..,.-..;:-':;::' - -----.. . ----~-~ ------.-.-.-, .-- . . .. .._--------~'....~~--,,-~..:-.- -.>--.-..-.- -----'----" ~ ~----- - _.'. ...--_ -._-","~~o..'__~~-"-"-I__ ___ _~ _ - - - ---'--~.~_."---- a ~ n t::I p:¡ .-t- p:¡ Id (1) "'d o ::4- N 00 o TABLE 6 OPTICAL SOURCE ROCK MATURITY INDICATORS COUNTRY Alaska WELL: Atigaru Point-I DEPTH (ft) FORMATION VITRINITE NO. of CONFIDENCE COMMENTS (%Ro) READINGS 7280 7910 8450 0.67 20 C MOD;IPAR 90% VPAR+W 10% ;BS MOD/STR BW MODIRI;SP L.O. LIMOD HYD SPE L.O. MOD 0.64 20 D L-MOD;IPAR 100% VPAR+WPAR TR;BS MOD/RI BW LIMOD;SP Y/O+L.O. MODIRI ALG Y TR 0.67 10 D L;IPAR+WPAR 100% VWPAR TR;BS MOD/STR BW MOD;HYD SPE L.O. MOD Amorphinite M.O. M Confidence A=Excellent B=Good C=Average D=Poor E=Unreliable Þ-d p:¡ (JQ <1> N o ~ ~" N 0'\ nnnnnnnnnn.nnnnnnnnnnnnnnnnnnftnnnnl o 1000 2000 3000 4000 :;:: ..c: . 0. 5000 Q) C· 6000 7000 8000 9000 10000 0.1 Vitrinite Reflectance Thermal Maturity Plot Well Name: Atigaru Pt-1 . . . ¡ I 1 3 0/0 Ro GMC Data Report 280 Page 22 'of 12ligure 7 - - --'- -~----~~- ~ PJ {Jq (t) N W o I-t; ........ N 0'\ Q ~ n TABLE 7 t:1 Pù -- SOURCE ROCK QUALITY INDICATORS Pù :;;0 (!) '"d COUNTRY: Alaska 0 ::¡ WELL: Atigaru Pt-l N 00 <:> DEPTH DEPTHRANGE FORMA nON PICKED LITHOLOGY PI PI P2 TOC TMAX HI GOGI CARBT S (ft) (ft) (kg/t) (mg/gC) (kg/t) (%) degC (%) (%) 7190 Mudstone 1.52 133.4 1.92 1.14 451 168 17.19 0.57 7280 Mudstone 1.33 107.4 1.74 1.24 447 141 16.42 0.97 7370 Mudstone 1.45 126.1 1.98 L15 439 172 12.65 0.43 7460 Mudstone L06 83.2 2.27 1.27 441 178 9.06 0.95 7550 Mudstone 0.93 76.5 2.25 1.22 438 185 9.61 1.15 7640 Mudstone 1.32 99.1 2.97 1.33 441 223 7.52 1.16 7730 Mudstone 1.07 78.9 3.26 1.35 443 241 7.13 1.03 7820 Mudstone 0.91 65.5 4.05 1.38 441 292 7.11 1.06 7910 Mudstone 0.94 71.3 3.16 1.32 441 239 7.53 0.98 8000 Mudstone 1.00 84.2 2.57 1.19 441 217 7.26 0.85 8090 Mudstone 1.09 73.8 3.35 1.47 441 228 6.73 1.03 8180 Mudstone L19 60.0 5.54 1.98 442 280 7.97 1.51 8360 Mudstone 1.72 77.7 6.21 2.22 446 280 31.85 1.15 8450 Mudstone 1.31 67.0 6.21 1.95 441 318 61.18 0.99 8540 Mudstone 1.20 62.8 4.74 1.91 444 248 53.60 L21 8600 Mudstone 1.72 48.7 9.21 3.54 446 260 33.05 1.39 Biomarker Ratios III: 0.57 SI : 0.53 M2: 0.68 112: 0.55 S2 : 0.42 M3: 0.68 113: 0.86 S3 : 35:28:36 M4: 62.83 114: 0 MS: liS: 100:79:53:44:26:9 S4: 36:24:39 0.41 SS: 34.53 AI: 0.76 116: 117: 0.61 A2: 0.77 86 : 88: A3 : 033 119: S7 : 48.71 I-¡j A4: 0.16 p) litO: S8: 26.90 AS: 0.52 (JQ CD 1I1l: 1.81 89 : A6: 0.83 N 1112 : 3.19 ..þ.. S10 : MDR: 1.50 0 ·1113 : 0.00 H) 1114 : 9.56 MBP: 5.10 ~ N illS: 0.00 0'\ 1116 : 0.00 H17 : 26.67 H18 : 0.00 C1 ~ n .t:1 p) r+ p) 10 CD '""d o :4 N 00 o \Vell name: Suite name: Country or Origin: Depth (m) : Sample name: Atigaru Pt-l NPRA Study Alaska 7820 Extraetion TSE ·Iowt: 0.100 HPLC Saturates %wt: Aromatics %wt : Residues %wt : Inspection Properties API: Density @ IS deg C : Wax Content %wt : Wax Melting Point deg C : Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOIUg : Asphaltenes %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : AsphaJtenes (Micro Method) o/.wt : Saturates GC Pristane/Phytane : Pristane/nC17 : Pbytane/nC18 : CPI: ALKlND : R22 : Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates: Total Oil : -30.9 Aromatics: Residue: Asphaltenes : Kerogen: -30.6 STANDARD: NBS22 -29.8 Table 8.1 -----=----_----:...--~---_. . --~._--_. -- .- Biomarker Ratios III : 0.58 SI : 0.52 M2: 0.63 112: 0.55 S2 : 0.49 M~ : 0.61 113: 0.86 M4: 68.58 S3 : 31:25:43 114: 0 liS: 100:74:53:41 :25: 12 S4: 32:23:43 M5: 116: 0.56 S5 : 43.80 AI: 0.79 117: 0.61 S6: A2 : 0.80 118 : A3 : 039 I-c;: 119: S7 : 41.76 PJ A4: 020 (JQ 1110 : S8 : 26.46 (1) AS : 0.42 N 1111: 3.10 S9 : v-. A6: 0.76 0 1112: 3.56 S10 : MDR: 2.09 Þ-+¡ "13: 0.00 ~ N 1114 : 11.62 MBP: 4.74 0\ 1115 : 0.00 11I6 : 0.00 1117 : 32.81 1118 : 0.00 Cl ~ (j o PJ .-+ p:¡ 10 () I-d o ::4- N 00 o SedimentlExtract Analysis Well name: Suite name: Country Of Origin: Depth (m) : Sample .,ame : Atigaru Pt-I NPRA Study Alaska 8090 Extraction TSE %wt: 0.117 HPLC Saturates %wt: Aromatics %wt : Residues %wt : Inspection Properties API: Hensity @ IS drg C : Wax Content "fewt: Wax Melting Point drg C : Pour Point deg C : Viscocity cSt @ 20 drg C : Total Acidity mg KOIllg : Asphaltenes -fowl (IP Method) : Nitrogen ppm : Sulpbur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : Asphaltenes (Micro Method) ÐJ.wt : Saturates GC PristaneJPhytane : Pristand'nCl7 : PbytanelnCl8 : CPI: ALKIND : R22 : Lightllydrocarbons MCH%: HER HXR Stable Carbon Isotopes Saturates : Total Oil : -30.9 Aromatics : Residue: Aspbaltenes : Kerogen : -29.6 STANDARD: NBS22 -29.8 Table 8.2- - n n n n " n ILft__1l n n n n n n n n n n n In nnn n n n n n n n n rL I .- :.........It) ;,~ It) ¡- I L I 1-0 Lit) ~ ¡- ru¡ r~ ~ !- _0 '¢ [ _It) (V) _0 (V) !.... _It) N I-~ _U') ~ \--.-0 T"" -U') I I J I o f I \ ) i ( ( 1 ¡ ? { ? -) ':'i '\ ~- .5 ~ 7 .::;; ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~-. ~ ~- . ---- L r-::,n ~ - ""- " ~ --- ~ .._-'~ ~ ... ~ '"ft. 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I ' 30:00 3S:00 40:00 45~Oo' ~ 0 .080 1 I Time :"'2.387 :"'2.087 ~ 1 .7£7 :"'1.4£7 ¿1.187 :-8.586 :"'5.786 :"'2.8£6 ~2.8E7 :"'2.6E7 :"'6.5£7 :"'5.2E7 :"'3.9E7 :"'2.687 :"'1.3E7 : 0 . OEO Time :"'7.8£7 ':"'1.0£8 :"9.1£7 ~1.3E8 :"'1.2E8 ---~- - ------- --------- -- ? "'1'1 6Q" s:: '"t ~ ~ N 0\ '"'0 ~ (JQ (1) w .þ. o H) a ~ n t:I ~ .-+ ~ ?:1 (1) '1:::j o ::4- N 00 o 11;05:00' 30': f'1-J ;¡ : ~ ~ 20": (-'), N'j : I l~i~'-J'h_~_~.AJ -4 I"J~" I I 1 , I I I 1 1 I ' I I , I ' , , I I ' , , I I ' I I , 1 I I 30:00 35:00 40:00 45:00 50:00 55:00 1:00:00 vz..1.: 70': 60': 50': 40": f~ µ\.¡'\").. ff 40": 30": 20': 10': o~ - ~~~~ I ,-... f ~~-;- 1- I ..' I I I , 30:00 35:00 40:00 45~00 253.1955 8:8 F:2 10 CJ!l 90': 80": ~0...~Lt~~_ 55~OO I I 1~ob:oo I 'l~O!:OO I 50~OO Vó"'\ .{~ 0'1 90": 80": 70": 60'-: 50': f!Þ ç.t\ø f\~ ç-z..( File:MPDMI000693 #1-3081 Acq:22-SEP-199~ 19:39:36 GC EI+ Voltage SIR ïOSE Samp1e#8 Text:ATIGARU POINT-1 7820' $9708SEDOOSS008$ Fi1e Text:8000RP Exp:GCMS_HRSIR 231.1173 8:8 F:2 10~ M1rt~ C1 3: (J t:1 P' -- P' :::0 () ~ o ::4- N 00 o Þ¡: P' (JQ () VJ VI o H-¡ ........ N 0\ 'Tj óQ" ¡:: '"""1 <Ð File:MPDMI000693 #1-308~ Acq:22-SEP-199~ 21':20:48 GC EI+ Voltage SIR 'lOSE Sample#9 Text:ATIGARU POINT-l 8090' $97088ED0058011$ File Text:8000RP Exp:GCMS_HRSIR 231.1173 8:9 F:2 100% 90": ?\""þ1~ _8.6£7 :"'7.7£7 - 80": 70": 60-= 50-= 40-= 30-= 20": - :"'6.9£7 :"'6.0£7 :"5.1£7 :"'4.387 :"'3.487 :"2.6£7 :"1.7£7 :"8.6£6 : 0.0£0 Time k"\ ýl\ "Iq- V't-P "s f\tr - 10~ I . . u. ~ L 0= ~v~~,~ I "'Y ì , I I I I I I I I I I I I 30:00 35:00 40:00 45:00 253.1955 8:9 F:2 10 <r!£ 90": 80": 70": 60-= 50": 40": 30": 20": ~~J lv~~_ I I I I I I I 1 I I I I 1 I , 55:00 1:00:00 1:05:00 , I I f 50~OÒ I po..-l1 _1.7E7 :"'1.6E7 - ~1.4E7 f( - :"'1.2£7 (t \ t'1.o- - :"1.087 :"8.7£6 :"6.9E6 ~~ y'..... fu~ - :"5~286 - 10~ ~~ 0='· , I I I I I I 30:00 35:00 t'~ ~ ~ ffl - 1 :"3.586 ,,~I~yll,J ) ""'~ "_ r ~1.7E6 -" .-.. "'. - .... "-n~. "---: O. OEO I I I I I I I 1 I I I I 1 : 00 : 00 1 : 05 : 00· Time I I I I I 40:00 I I I I , 45:00 f I I I I 50:00 I I I 55:00 o tv n'" n " " " n n " " n n " n n n n n n n n nn " n n n " R n n R R· If a ~ (J t.:1 ~ .-+ ~ ~ (1) '"d o ::4- N 00 o ~ ~ (JQ (1) VJ 0\ o I-t) --- ~ - NùQ" O\t: '"1 (tI File:MPDMI000693 #1-1291 Acq:22-SEP~199'1 19:39:36 GC EI+ Voltage SIR ~OSE Sample#8 Text:ATIGARU POINT-l 7820' $97088ED005S008$ File Text:9000RP Bxp:GCMS_HRSIR 178.0782 8:8 100?£ 90-': - 80--= 70--= 60-= - 50-= 40-= - 30-= - 20-= 10--= 0=_ I-I , I I I ' I 18:00 19:00 192_0938 8:8 100% 90-= 80-= 70-= 60-= 50-= 40-= 30-= - 20-= 10-= 0= I I 18:00 II~('I rï rr-fIïI I~I I~I I I I 20:00 21:00 22:00 23:00 - I ' , I 24:00 ~- I I I I I I I I I ' I I I I I I I 25:00 26:00 27:00 =-.. I , I I I I I I , I I I , 19:00 20:00 I ?'" I I I 21:00 I I I I I I I I I I I ,- I I I I I I ( I I I I I I 22:00 23:00 24:00 25:00 "--., , ., I' I I 26:00 "-- I I I I I 27:00 - ---- - - --. -' - ---- - -- - ~----'---- -- -=--- ---~ --. ...::.. _3.2E8 ~2.9B8 - :"2.6E8 :"2.328 =-1.928 :"1.628 ~1.3B8 - :"9.7B7 - ~6.5E7 - :"3.227 - ~0.020 I I , I I I I I I I I I I I I 28 : 00 29 : 00 30 : 00 Time _3.128 ~2 .7B8 - ~2.4E8 :"'2.1E8 - :"1.828 :"1.528 :"1.228 - :"9.2B7 :"6.1E7 - =-3.1B7 I I t I I I I 28:00 - ~ _ __,: O.OBO I , I I I I I I 29:00 30:00 ~ime 'T õQ' s::: '"t (1 a ~ n t1 PJ .-f'- PJ ?=1 (ì) '"d o ~ N 00 o File:MPDMI000693 #1-1291 Acq:22-SEP-199'1 21:20:48 GC EI+ Voltage SIR 10SB Sample#9 Text:ATIGARU POINT-l 8090' $9708SEDOOSSOll$ File Text:8000RP Exp:GCMS_HR8IR 178.0782 8:9 10~ 90'-: 80'-: 1 I I I 1 I I I I I I I 19:00 20:00 - 70~ 60": 50": 40": 30'-: 20~ ~ - ~- 119, I FI i. f I I I I I I I 111 I I 20:00 21:00 22:00 23:00 I I T I I I I 21:00 I I I 1 I 22:00 I I I I I I 23:00 I I I I I I I 24:00 I I I I I I I 24:00 - ---..- I I I I I I I r I I I I I ) r I I 25:00 26:00 27:00 I I I I I 25:00 , '--.. I I I I I I I 26:00 '-- I I I r I 27:00 ~5.7E8 ~5.1E8 ~4.5E8 =-'4.0E8 =-'3.4E8 :"2.8E8 =--2.3E8 :"1.7E8 =-'1.1E8 - :"5.7E7 ~:O.OEO I I I I I I I I I I 1 I 1 I I 28 : 00 29 : 00 30 : 00 Time _4.5E8 =-4.0E8 :'3.6E8 =-3.128 :"2.728 ;"2.228 =-1.8E8 =-1.328 =-8.9E7 :"4.527 c::>- 1.....- -, I : 0 - OEO I I I I I I I I I I I I 28 : 00 29 : 00 30 : 00 Time nnnnnnnnnnnnnnnnnnnnnnnßßnnøonnøRø - 10": ~ PJ (JQ (t) w --..) o H) ~ N 0\ - 0: - I I I I I I I I 18:00 19:00 192.0938 S:9 10 CY!f. 90": 80": 70~ 60-= 50'-: 40": 30": 20~ 10-= 0= I I 18:00 ..... ..... N a ~ (J t) :I) ~ :I) ~ (þ '"d o ;¡ tv 00 <:> '"'0 :I) (Jq (þ w 00 o I-t) ........ N 0\>Tj òQ' c .... (þ File:MPDMI000693 #1-1291 Acq:22-SEP-1991 19:39:36 GC EI+ Voltage SIR ~OSE Sample#8 Text:ATIGARU POINT-l 7820' $9708SEDOOSS008$ File Text:8000RP Exp:GCMS_HRSIR 168.0939 8:8 1000: 90~ 80~ 70~ 60": 50-': 40-': 30'-: 20": 10-': o ~ , , , , I 't I ~ ( f' I ~ ~, , 10:00 12:00 14:00 198.0503 8:8 10O?f 90": _4.0E7 :"3.6E7 -='-3.2E7 :"2.8E7 -=-2.4£7 :"2.0£7 =-1.6E7 , , , J I I , , , J ' , , I , J ' , I , I I ' I , , , J ' , , , I J ' I I , I J I I , 16:00 18:00 20:00 22:00 24:00 26:00 28:00 - :"1.2E7 ~8 .1E6 =--4 . OE6 - O. OBO , , 30: 00 Time _3_0E7 :"2.7B7 - 80": 70~ 60~ 50'-: 40": 30-': 20-': 10": 0: , I 10:00 - :"2.4E7 :"2.1E7 :"'1.8£7 - :"1.5E7 :"1.227 I I , J ' I , , I J I , I I I J I I , I , I I I I , I I ' , , , I I ' I , 12:00 14:00 16:00 18:00 20:00 22:00 . ~ '-- '--- · , I ' , , , , J 1 "I 24: 00 26: 00 - :"9.0£6 :"'6.0£6 ~3.0E6 . I^-'~ ^r I {'- 1-' : 0 .OEO 28:00 30 :00 Time !'> ..--_.-...-....... " _._."-.._~.-_....-___=-___~:.:..o__--:....=-..c....;-__~___-.-_.__::.. _" Cl ~ o t::} PJ ..-+- PJ ~ (1) 'd o ~ N 00 <:> ~ PJ (JQ (þ VJ \D o ~ ~ N 0\ >Tj òQ" t:: ""'I () ----.------~------------'"_-..::_--~~-~-..-- .: File:MPDMI000693 #1-1291 Acq:22-SEP-199~ 21':20:48 GC BI+ Voltage SIR ïOSE Sample#9 Text:ATIGARU POINT-1 8090' $9708SBD005S011$ File Text:8000RP Exp:GCMS_HRSIR 168.0939 8:9 100% 90": 80": 7 0": 60": 50'-: 40~ - 30": 20": 10": 0: ^ . I I , I'· I ... J'" I 10:00 12:00 198.0503 8:9 100% 90": 8 0": 70": 60": 50": 4 0": 3 0'-: 20": 10": - 0= 10:00 t I ~ J I I I 14:00 I I I I I I 16:00 I I I I I 18:00 I I I , I I 20:00 J J J I I I I I J I I I , I I I I I I I I I I I I 22:00 24:00 26:00 28:00 , I I I I I I I J I I . I I I I I . I I I I I I I I J , I I I 12:00 14:00 16:00 18:00 20:00 I I I I I 22:00 - N N ~8.0E7 :"7.2E7 :"6.4E7 :"5.6E7 :"4.8B7 - :"4.0£7 :"3.2&7 :"2.4£7 :"1.6&7 :"8.0£6 - 0 . 020 I I 30: 00 Time J~~ I r I I I I I I J I I I I 24:00 26:00 '^'-l Y, 28:00 _5.3&7 :"4.8E7 - :"4.2B7 :"3.7B7 :"3.227 - :"2.6&7 :"2.127 :"1.6&7 ~1.1E7 :"5.3E6 f rl : O.OEO 30: 00 Time n n n n n n n n n n n _ n n R n n n n n -n- R_ n R R R R R R n n R R R IL East Teshekpuk-l Data GMC Data Report 280 Page 40 of 126 Q s;:: n t) PJ r-t- ~ ~ (t) >0 o ::¡ N ex) o DEPTH ft 7090 7180 7270 7360 7450 7540 7630 7720 7810 7900 7990 8080 8170 8260 8350 8440 8550 8650 8740 8850 ""0 PJ (JQ (t) -Þ- ¡...-o. o ~ ¡...-o. N 0\ . . - p- . -~------~- COUNTRY: WELL: DEPTH RANGE ft TABLE 9 LITHOLOGY AND STRATIGRAPHY Alaska E. Teshekpuk-t FORMATION AGE LITHOLOGY PICKED LITHOLOGY MOST-m gy 100% MDST-dk gy shale 60%:SLTST-m gy 30%:SST-lt bn 10% MOST -dk gy shale 60%:SL TST -m gy 30%:SST -It bn 10% MOST-dk gy shale 60%:SLTST-m gy 30%:~ST-lt bn 10% MDST -dk gy shale 40%:SL TST -ill bn 60% MOST-dk gy shale 40%:SLTST-m bn 60% MDST-m-dk gy shale 70%:SL TST-m -bn 30% MDST-m-dk gy shale 800Io:SLTST-m bn 20% MDST-m-dk gy shale 90%:SLTST-:m bn 10% MDST-dk gy shale 95%:SLTST-m bn 5% MOST -dk gy shale 100% MDST-dk gylbk shale 9O%:SLTST-m bn 10% MDST-dk gy shale 80%:SLTST-m bn 20% MOST -dk gy shale 8OÐÆ:SL TST -m bn 20% MOST -dk gy shale 80%:SL TST -m bn 20% MOST -dk gy calcareous occ. sndy 55%:QTZ-5%:LST-lt gy 40% MOST -dk gy occ. sndy 10001'0 MDST-dk gy calcareous OCC. sndy 15%:LST-m gy mddy 85% MOST -dk gy OCC. sudy 30%:LST-m gy mddy 70% - MOST -dk gy OCC. sridy 40%:LST -m gy mddy 60% Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone SAMPLE TYPE CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT ·.... _____._ -·.---..------.--...-0-.- _.... ____~_o_.____._._ . . . - -. -. -----------=--- -'-------=-----=---'--"~-:..:..-~~---..:---.--'----.- _.- - --- --------- . a s;:: (") t::1 ~ ~ ~ Id (!) "'d o ::4- N 00 o TABLE 10 OPTICAL SOURCE ROCK MATURITY INDICATORS COUNTRY Alaska WELL: E Teshekpuk-l DEPTH (ft) FORMATION VITRINITE (%Ro) NO. of CONFIDENCE COMMENTS READINGS 7180 7900 8350 0.63 0.73 0.84 20 C L-MOD; IPAR+WPAR 100% VWPAR+W TR;BS MOD+STR BW MOD;SP M.O. MOD 20 D MOD; IPAR 90% VW+WPAR lO%;BS MOD+STR BW MOD;SP M+D.O. Very L 20 D L-MOD; ¡PAR 100% VPAR+WPAR TR;BS MOD+STR BW MOD;SP M-D.O. L Amorphinite M.O. MOD Confidence A=Excellent B=Good C=A verage D=Poor E=Unreliable ~ ~ (JQ (!) .þ. N o Þ-t) ........ N 0\ n " " " " " n n n " ß " n " " n" -" n n It fiR fI__uR R R R n n It If-If If , .~ Vitrinite Reflectance Thermal M~turity Plot Well Name: E. Teshekpuk-1 o 1000- 2000 3000 4000 I,; .:t: ..c: 5000 'õ. CJ) 0 6000 ¡ ,I I 7000 :1 . 8000 . . 9000 10000 . 0.1 \ I 1 3 % Ro GMC Data Report 280 Figure 13 Page 43 of 1 LQ CJ ~ (') TABLE 11 t:1 P' .-+ SOURCE ROCK QUALITY INDICA TORS P' ~ (1) COUNTRY: Alaska '"d 0 WELL: E. Teshekpuk-l '""i .-+ N 00 0 DEPTH DEPTHRANGE FORMA nON PICKED LITHOLOGY PI PI P2 TOC TMAX HI GOGI CARBT S (ft) (ft) (kg/t) (mg/gC) (kglt) (%) degC (%) (%) 7090 Mudstone 2.21 54.4 7.61 4.07 445 187 11.04 2.01 7180 Mudstone 2.71 104.5 4.31 2.60 449 166 10.30 1.17 7270 Mudstone 1.77 69.2 3.16 2.56 450 124 8.49 0.94 7360 Mudstone 2.10 92.3 3.40 2.27 451 150 11.14 1.16 7450 Mudstone 1.91 72.1 3.17 2.65 450 120 7.14 1.20 7540 Mudstone 2.20 89.9 3.21 2.45 454 131 7.52 0.89 7630 Mudstone 1.62 89.7 2.76 1.81 453 152 7.32 0.96 7720 Mudstone 1.44 105.4 2.09 1.37 455 153 7.76 0.86 7810 Mudstone 1.30 107.2 1.81 1.22 454 149 7.59 1.16 7900 Mudstone 1.44 127.7 1.80 1.12 455 160 8.19 0.93 7990 Mudstone 1.46 114.8 1.90 1.27 454 150 7.84 1.10 8080 Mudstone 1.48 129.2 1.88 1.14 456 164 7.56 0.96 8170 Mudstone 1.66 132.2 2.19 1.26 455 174 7.39 0.94 8260 Mudstone 1.28 137.5 1.56 0.93 454 168 7.30 1.32 8350 Mudstone 1.37 109.3 1.86 1.25 455 148 9.38 0.98 8440 Mudstone 1.58 135.7 1.93 1.16 472 166 23.36 0.90 8550 Mudstone 1.87 75.1 2.40 2.49 456 96 6.87 1.63 8650 Mudstone 0.58 213.8 0.00 0.27 460 0 6.79 0.22 8740 Mudstone 1.22 148.6 1.40 0.82 451 171 15.95 0.45 ~ Mudstone 1.72 84.7 1.92 460 p:> 8850 2.03 95 36.17 1.09 (JQ CD .þ. .þ. 0 Þ--I) ........ N 0\ --- ---~- --- - - + - - . . . - - . - - -- .__ _ ~_____~~ _~__ ___ ._.__________-__.___....... _____ .__ ~__._u~____,_ . --_.._~-- - -. a ~ n t:1 ~ ~ ~ :::a () ÞOtj o ::1- N 00 O. \Vell name: Suite name: Country Of Origin : Depth (m) : Sample name: E. Teshekpuk-l NPRA Study Alaska 7090 Extraction TSE %wt: _o.279 HPLC Saturates %wt: Aromatics %wt : Residues %awt: Inspection Properties API: Density @ 15 deg C : Wax Content %wt : Wax Melting Point deg C : Pour Point deg C : Viscocity cSt @ 20 d~ C : Total Acidity mg KOlllg : AsphaUenes %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NirkelNanadium : Asphaltenes (Micro Method) %wt : Saturates GC PristaneIPhytane : PristanelnCI7 : PhytanelnCI8 : CPI: ALKlND : R22: Biomarker Ratios III : 0.56 51 : 0.60 M2: 059 112 : 0.55 S2: 0.57 M3: 0.64 113 : 0.89 S3: 46:29:23 M4: 52.64 114 : 0 M5: 115: 100:51 :41 :22: 14:5 S4: 37:26:35 32.56 AI: 0.80 116: 0.76 SS: 117: 0.60 A2 : 0.85 S6: 118: M: 0.81 S7 : 66.39 Þ-c:1 119 : A4: 0.62 p.) 1110: S8: 2955 AS: 0.41 (JQ () 1111 : 7.05 S9 : A6 : 1.25 .+;:.. 1112 : 4.05 u. SIO: MDR: 4.30 0 1113: 0.00 H) 1114 : 23.39 MBP_: 5.24 ~ N illS: 0.00 0\ 1116 : 0.00 1117 : 28.30 1118 : 0.00 Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -28.2 Aromatics: Residue: Asphaltcnes : Kerogen: -26.9 5T ANDARD: NBS22 -29.8 Table 12.1 Biomarker Ratios III : 0.57 SI: 0.54 M2 : 0.81 112: 0.53 S2 : 0.53 M3: 0.70 H3: 0.87 M4: 70.62 114: 0 S3 : 41:24:33 115: 100:98:62:32: 17:8 S4: 32:28:38 M5: 116: 0.55 S5 : 44.28 AI: 0.92 87 : 0.61 S6: A2 : 0.89 118 : A3 : 0.80 ""t:1 89: S7 : 55.09 pJ A4: 0.56 (JQ 1110 : S8: 8.58 (t> AS : 0.62 .þ. 1111 : 10.09 S9 : 0\ 1112: 12.34 A6: 1.94 0 SIO: H-¡ 1113: 0.00 MDR: 5.18 ~ N 1114 : 30.67 MBP: 17.77 0\ IllS: 0.00 1116 : 0.00 1117 : 31.69 1118 : 0.00 C) ~ n o pJ ~ pJ ~ '"d o ., ~ N 00 <=> .. "--- -~-=--- -----'- - .. ~ -- - . -. --._- ~--..-- ------. ---- ------_.- .-.-.--------... SedimentlExtract Analysis \Vell name: Suite name: Country or Origin: Depth (m) : Sample ~ame : Extraction E. Teshekpuk-I NPRA Study Alaska 7540 TSE %wt: 0.091 HPLC Saturates %wt: Aromatics %wt : Residues %wt : Inspection Properties API: ()ensity @ IS deg C : Wax Content %wt: Wax Melting Point deg C: Pour Point deg C : Viscocity cSt @ 20 dtg C : Total Acidity mg KOH/g : Asphaltenes %wt (IP Mdhod) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickdNanadium : Asphaltenes (Micro Method) ~.wt : Saturates GC PristandPhytane : Pristane/nCI7 : Phytane!nC18 : CPI: ALKIND : R22 : Light Hydrocarbons MCR % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -26.6 Aromatics : Residue: Asphaltenes : Kerogen: -23.7 STANDARD: NBS22 -29.8 Table 12.2 ftftftftftftnnftftftftftftftnlftnnnnftlftftftftftftnnlft I , !- Ì-Ll) :Ll) ¡ L. I Lo ILl) I r ~ _Ll) ~ - ~O L~ - -~ - - -g - - -~ _0 N - 1- _Ll) ..... _0 ..... - -- ~ f- I r- - 4 II o Fi!!ure < ! ¡ i I I ( ) ) ! _I l .) 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I I I I I I I ¡ I I I I i I I I.-T-T--TT--¡--T-T--, T- r ¡- ! - I n II n " " II " IU 1ft 11112°11 IIrr II II It n n311 n If" lilY If n S~ n Ifs" If , CJ ~ o t} ~ .-+ ~ :::0 (!) '"d o ::¡ N 00 C> ~ ~ (JQ (!) .þ.. 1..0 o Þ-+¡ ....... N'T 0\ åQ" s:: ..., (I) File:MPDMI000693 #1-3081 Acq:22-SEP-1991 23:02:0~ GC EI+ Voltage SIR ïOSE Samp1e#10 Text:E TESHEKPUK-l 7090' $9708SED006S001$ Fi1e Text:8000RP Exp:GCMS_HRSIR_ 191.1799 8:10 F:2 100%. if _3.9£7 ~3.5E7 90~ - ~3.1B7 ~2.7E7 ~2.3E7 =-1.9B7 =-1.6E7 =-1.2E7 =-7.8E6 =-3.9E6 - - - - 0 .OEO Time - BO~ 70~ - 60~ 50~ 40~ ~ <!> - ~~ 30~ 0 J 20 : /\<"\ v G( ~ ~ ~ 10~~,~~L ~.,..~..L.MJ~~,,~µ 0-1 - . 30:00 I I I I 40~OO I I I I 50~00' I I 1:06:00 I I 1:1b:oo 217.1956 8:10 F:2 10003 90'-: lC"> _B.5E6 - ~7.6E6 =-6.BE6 :"'5.9E6 =-5.1E6 ="4.2E6 =-3.4E6 =-2.5E6 =-1.7E6 =-B.5E5 -': O. OEO Time 1J.A - 80~ \l - 70~ 1-1 ~3 - 60~ qO \\ 50~ 40~ 1V- 'f t 30~ 20~ . I I . t .., " I. . A.ø.. ~~I ~ 10~ ~J \II ~ w.~.~y,pl' 1 !{ ~ J 1. ~r I ~~ .. ~~ ~~ - - .'.",,^,- ,-,... - 1- "",...~... _ ,._. "'. I ...- _~.. .¡~. _ ,. __ - o : 30:00 I 40:00 I 50~00 I 1:06:00 1:1b:oo' ~ -- - - --. - - -~. - - - -- - - - - - un _ _ _ ______ _ _ __ _ _ _ . _ . -~~..,..-......_-...-.~---~...~-=- ~ - - - -- - - - --' . ---- -- - - - - - __~~--------..-....--,-=--____..o.__hC.~____~_________~__-'-____---'-__ ______ __'~----,--,,___-_~ __ ~-"------ -- - -------- -------~ -.---- .-.... ..._.-.-.-- o ~ o t:1 p:¡ .-t- ~ ~ o "d o ::¡ N 00 o Þ-¡j þ) OQ CD V'I o o H-¡ ....... N 0\ 'T1 riQ' t: '"1 CD File :MPDM:I000693 #1-308", Ace:¡: 22-SEP-199"1 23 ': 02: 0:> GC £:I+ Vo1.tage S:IR "lOSE Sample#10 Text:R TRSHRKPUK-1 7090' $9708SRD006S001$ File Text:8000RP Rxp:GCMS_HRSIR 177.1643 8:10 F:2 100% _8.026 80-= 60-= =-6.4E6 - =-4.8E6 ~.~~~~,. .......r\'\.&A:,.=-· ..........'a.....__._'a :...3.226 40-= - :...1.6E6 ~ 20-= o- J I J 30:00 40:00 191.1799 S:10 F:2 10 Q?6, O.OEO Time 1:00:00 1:10:00 J 1 1:20:00 J50~00' _3.9E7 80-= 60-= 40-= - :...3.1E7 :...2.3E7 =-1.6E7 20-= o : ~' ~ ..~ -," ",II............ I ......- 30:00' J J '40~00' 205.1956 8:10 F:2 100?£ ~~ ,....I\l......l~ _ . 1:00:00 i:10:00 - =-7.8E6 I I ' 50:00 I 1 I 1:20:00 - 0 .OEO Time _5.5E6 80-= 60-= - =-4.426 - =-3.326 40-= :...1.126 :...2.226 20-= 0-_ 30:00 ] 50:00 ~,~ ''''!J>I.r""\. ,:t : ~, . ,.',"" '" '. -, - \ - ...' -': 0.020 i : 00 : 0 <> . i: 10 : 0 <> i : 2 b : 00 I 'J'ime , I ' 40:00 VI tv n'R ft ft n ft ft ft ft n I n ft ft n n n ft ft n n nn n n n n n n n n ft n I a s;: (') t) p) .-+ p) ~ (I) '"d o ::¡ tv 00 o ~ p) (JQ (I) Vt ...-- o 1--1-) ...-- tv 0\ File:MPDMI000693 il-308ï Acq:22-SEP-l99ï 23:02:0~ GC EI+ voltage SIR 'lOSE Sample#10 Text:E TESHEKPUK-l 7090' $9708SED006S001$ File Text:8000RP Exp:GCMS_HRSIR 218.2033 S:10 F:2 10mr _4.8E6 80...: - =-3.8E6 60...: - :..2.9E6 40...: =-1.9£6 ~ J{ Jlll\IJI\J\. ~~~. - - 0 .OEO Time - :..9.6£5 20~ _ ~ 'Mw.JWM O_~w I I I I I I I I I I I 30:00 35:00 40:00 217.1956 S:10 F:2 10005 .. .,..,...... I" I I I 45:00 I I I 50:00 I I I 55:00 I 11:00:ÒO I _8.5E6 - 80...: 60...: - =-6.8E6 - :..5.1E6 40...: ~ ::..3 .4E6 .,J..,.JII.. ~\,. M'VIJ.. j ~ ~1. 7E6 ~..,... ~ ~.JL ..... ..,¿N - ~,_.. ........ 20~ _-^-~~_ Jwl.Ä~~ o - r---~-- - I I I I I I I I I I I 30:00 35:00 40:00 231_2111 8:10 F:2 1000¡ 80...: - 0 .OEO Time I I I 45:00 I I r 50:00 I I I 55:00 I I 1 I I 1:00:00 _2.5E6 - L^.aA ul ~ . II :..2 .OE6 "'WItJ1U ''\Yp h y,\ \oJ.. L .~1. SE6 1"VW~9.9E5 60...: 40~ ~~~.J.fl 20...: - ':-5 . OEs '"T1 óQ" f;: >-t (þ 0- I 30:00 - - 0 . OEO Time I I J 35:00 I I J 40:00 I I I 45:00 I I I 50:00 I I I 55:00 I I 1 I I 1:00:00 U¡ w - .--.----- ---.. _ ------- .- -' . . .- - - . - -. - - - - - ~--~---_.~--..,,-~..-->"'-- --;-.-.-.,..- - -.....-.. ----=-"'~--- .'-~~---' --=--:--------=-- ."- - .~ ....~-..._~..:..-_-..,-;--..;.... - -. -----.- -~-~-_.~_.-~-.~-- -----.--- - - -. -- - --- -- -- . .- a ~ (") tJ P' ~ P' ~ (1) '""d o ::¡ N 00 o ~ P' (JQ (1) VI N o I-t) ~ N 0\ "T1 åQ0 c: ""t (1) File:MPDMI00069~ #1-30Bï Acq:24-SEP-199ï 14:21:5~ GC EI+ Voltage SIR ïOSE Sample#5 Text:E TE8HEKPUK-l 7540' $9708SED006S006$ File Text:8000RP Exp:GCM8_HRSIR 191.1799 8:5 F:2 10œn (5 _1.3E7 :"1.1E7 - 90": 80": - :"1.0E7 :'8.9E6 =-7_6E6 - 70": 60": 50": 40"': ~ tS - :'6.3E6 :'5.1E6 o -1 1(,.. -{.. u - :"3.8E6 - 30": 20": v - :"2.5E6 ~ ~ ~ A f ~ ~-~ 14tl1.JL ~."""-~ 1:00:00 1:16:00 /.'5 - :"1.3E6 - 10": 0=_ 30:00 217.1956 10~ - - 0 _ OEO Time I I ' 40:00 I 50:00 S:5 F:2 1° _2.0£6 :"1.8E6 :"1.6E6 :"1.4E6 :"1.2E6 :"1.0E6 - 90": 80": ~IA. 1\ - 70": 60": 50": '}.1. "J"> 'to 4\ 'f'V ~ ,_ ,S "" 3'- - d , =.. 6 · 0&5 ' · - - ~ ~"~oJ'"~"""bþ' t: : ~:: ~ ./'P;,/J,-..'\"-'t:.... \/"I - - . o_.-f".,_ 0 . OEO I I 1 I I I I 1:10:00 ~ime - 40-': - :"8.0E5 - 30-': ~~} ~JJW -NW--~ ~ - 0= 30:00 I I ' 40:00 I 50:00 I 1 I 1:00:00 >-' \JI ~ " II II II II n II rut II II II II II 1111 rr n n II n nn " nn II n UJUIft ,( CJ ~ n t) ~ -- ~ ~ (þ ~ o ~ tv 00 o ~ ~ (Jq (þ VI LN o H-¡ ........ tv O\'T åQ' t:: "1 (þ File:MPDMI0006~~ #1-308ï Acq:24-SEP-199i 14~21!~ï GC EI+ Voltage SIR "lOSE sample#5 Text:E TESHEKPUK-1 7540' $9708SED006S006$ File Text:8000RP Exp:GCMS_HRSiR 177.1643 5:5 F:2 10~ 80-=: 60-=: 40-=: 20-=: 0- 30:00 191.1799 5:5 F:2 1000~ I 40:00 , I -' 50:00 80-=: 60-=: 40-=: 20-=: ~~~~~~ i:oo:oo i:10:00 - 0 _ OED Time 0- 30:00 205.1956 5:5 F:2 100?6 80--= I 40:00 I I ' 50:00 60--= 40-=: 20- :~W\~~.A/'t'\. o -I . 30:00' I I '40~00' I 50:00 ~ VI V. ----~ - - - ----- _3.9E6 - :..3.1E6 - :..2.3E6 . I. I. :..1. 5£6 .l...~.. . ::-7.7£5 ~ . "'. ~~....' ...I_U"X_L- /P. ,).... JJ... I -l.¡ . I,.jJ L\'l..~ I - O.OEO i:oo:oo i:10:00 1:20:00 Time _1.3E7 :..1.0E7 - :-7.6E6 :..S.lE6 :..2.SE6 1:20:00 _2.4E6 :..1.9E6 :..1.4E6 :..9.4ES ~l~ "N~- "~r..~__.., ...~. :..4.7ES 1\_~ " oAr·'.... ,..r O.OEO Time i:oo:oo i:10:00 1:20:00 ---~----'---=- .~,,------o:"":~,-':":"'-,---=-=~.....~. "",,~__-_~'--~--.=oo:.-->_-.=-_-=~~-- -- ._.----~--_._. ----- --- . --~----- ----------- ---~~.::-;~..--: -~-~----------~-------- ---~-.--~-------- ----~~--- - --- -:---,,"--- _..--;----=-..::-===-=-==--....:;~--=-=---.-----;-- a ~ n t) ~ ~ ~ :::0 CD >a o ::¡ N 00 o Þ-tj ~ (JQ CD U1 ~ o ~ ......... N 0\ File :MPDMI00069~ #1-308-, Acq: 24-SEP-199", 14: 21: 5', GC EI+ Voltage SIR -lOSE Sample#5 Text:E TESHEKPUK-l 7540' $9708SED006S006$ File Text:8000RP Exp:GCMS_HRSIR 218.2033 8:5 F:2 10m: 80-= - 60-= 40-= ,.¡v~ _1.0E6 =-8.0ES - =-6.0ES =-4.0E5 L - ~ JWy '¥\ '¡"~~2.0E5 - 0.0£0 Time I I I 55:00 '1':00:0'0 ' 20~~. \A A .11 = I>/tIMJ '~WW 0- . , r , I I I I I I I I 30:00 35:00 40:00 217.1956 S:5 F:2 1 0 O'!f¡ I I ' 45:00 I I I 50:00 _2.0£6 - =-1.6E6 - =-1.2£6 20~~~ 0-1· .. 30~00r I 1 '35~00' 231_2111 S:5 F:2 10~ Jv~,.,J/v· ^"~, "'~ . ~::::: ~""'..,.,,r~= - 0 . OEO Time I I I 55:00 I 11:00:00 I 80-= 60-= 40-= I I I 40:00 I I I 45:00 1 I I 50:00 _9.0£5 - =-7.2£5 ~~.~~,~~~::::: =-1.8E5 I I ' 55:00 - - 0.0£0 Time 80-= 60-= 40--= 20=~ 'I': 00: 0'0 ' ft ft n n n n n n n n n n n n n n n n n n n nn n n·n n n n n n I R~I "T] åQ" t: .., CP - 0- I 30:00 I I I 45:00 , I I 50:00 I I I 40:00 , I I 35:00 V\ ~ C) ~ n t:1 PJ ...... PJ ïO CD ~ o ~ N 00 o ""d P' (JQ (I) V\ V\ o ~ I--' N 0\ File:MPDMI000693 #1-3"08-¡ ACQ:22-SEP-199"¡ 23:02:0~ GC El+ Voltage SIR "JOSE Sample#10 Text:£ TESHEKPUK-l 7090' $9708SED006S001$ File Text:8000RP Exp:GCMS_HRSIR 231.1173 8:10 F:2 10 O?l, 90"': f,<j _2.887 =-2.5£7 :"2.2E7 :"'2.0E7 :"1.7£7 =-1.4£7 :"1.1£7 (.<1 - 80"': 70"': ~ 60"': 50-= 40"': ~,-\"\" - 30"': - :"8.4£6 =-5.6£6 :"2.8E6 -c 0 .OEO Time 1''2 \ N1 iff> ~:] I~ V'}I M~ O-~V I I r r I r . r I I I I I . I I I 30:00 35:00 40:00 45:00 253_1955 8:10 F:2 10Œf fl" -"~~ I I r . . 50:00 r 55~OÒ · I 1~ob:òo I · l~O~:ÒO I ~3.6£6 :"3.2£6 ~~-¡... 90"': vi~ - 80"': 70"': - :"2.986 :"2.526 :"2.1£6 :"1.8£6 :"'1.4£6 V6"'" - 60-= (oS ::~ ~J1JJ.,¡ ~ I" 30.ë ~·-VI .. "~ 20"': 10-= ø (.\.\:~\-¡- (IJ- ~l fP ,,1f;1J I IJ JÌ~ f\3 - :"'1.1£6 :"7.1B5 #r't¡'IJ-'\,~\,,¡~,. J~'~3 . 685 'T1 riQ' ¡:: .... (I) - 0: . 30:00 - : 0 . OBO ,-ime r r I I ..- I I I I I I I I I I I I I I I I I 1 I I 40:00 45:00 50:00 55:00 1:00:00 I l~OS:OO I I I I I I I I 35:00 0\ ______________ _____u___ . - --- - ----- - - -- - -- - - --- -----------~---------,...------- - --- ---- _.-.._- ~ - -- -- -- ---- ,- --._--- ---- ft n n n ft n n n n n n n ø ft n n n n nn n n:n n-n-n n n n nn n ø I =--2.3E5 =--1.5E5 -¿7.5E4 : O. OEO Time ~4.5E5 =--3.8E5 =--3.0E5 =-5.3E5 ~7.5E5 =--6.8E5 =--6.0E5 =--1.6E6 ~1.1E6 ~5.5E5 ~ 0 .OEO I Time =-'4.4£6 =--3.8£6 ~3.3E6 =-'2.7E6 =--2.2E6 _5.5E6 =--4.9E6 30-= 20-= 1 0 ~ . A ~ A_ J 1 o : ~'wJ\/'V"" I I I I I I 30:00 35:00 253.1955 8:5 F:2 1 0 0'!tJ I 1~0~:00 I I I I I I I I I I I I I ' J I 35:00 40:00 45:00 10-= 0: I I 30:00 01- 90-= 80-= 70-= 60-= 50-= ::J~ 20-= 0\ N 'TJ åQ" s:: '""'1 CÐ I-cJ ~ (Jq (t) V\ 0\ o H) >-'" N 0\ a ~ (J tj ~ ~ PJ ¡o ([) '"d o ::¡ N 00 o -~---.-- --~------ ... I l~OO:OO I I I I I I 55:00 50 ~ 00 J ~~l'~~ . ~.\\ ,,\0 \'~ j4 ~ ~1- "~~~~.~~ (tl~\1.- t') (.-"\;~ f6 I I 1 I I J I 1 I I J 1:00:00 1:05:00 ! I J 55:00 J J I I I I I J 45:00 50:00 ~0 I I J I 40:00 ~ J . ~ \hJ1,,1 I~,~....,I ~plu..v~.._,_..,,~ l ~ ~ (;.1Á f\'I pI" {/"JÞ ~,\""l( p( 50-= 40-= 60-= 70-= 90-= 80-= File:MPDMI00069~ #1-308'l Acq:24-SEP-199'l 14:21:~'l GC EI+ Vo1tage SIR 'lOSE Sample#5 Text:E TESHEKPUK-l 7540' $9708SED006S006$ File Text:8000RP Exp:GCMS_HRSIR 231.1173 S:5 F:2 1 0 0'!tJ fI'I a s;:: (J tJ p) .-+ p) ~ (t> ~ o ~ tv 00 o '"'d $:I) (JQ (t> VI -....) o H) ~ N 0\ 'T1 üô" C '1 () File :MPDMI000693 #1-1291 Acq:22-SEP-199-' 23-: 02: O~ GC EJ:+ voltage SIR "JOSE Sample#10 Text:E TESHEKPUK-1 7090' $9708SED006S001$ File Text:8000RP Exp:GCMS_HRSIR 178.0782 S:10 10~, 90": 80": 70": 60": 50": 40": - 30-= 20-= 10": 0: I I J I I I I I 18:00 19:00 192.0938 S:10 1000: 90-= 80-= 70-= - 60": 50": 40": - 30": 20-= 10-': 0: I I 18:00 I ~I -r--"f'l Fir I r ,''' I I I I I ~Ï I I I 1 '1 Î I I 20:00 21:00 22:00 23:00 24:00 IIIIIIII-~I 25:00 26:00 --1 -' I I I I I I I I I I I I I I I J I I I I I I I I I I I I I I 19:00 20:00 21:00 22:00 23:00 "-- I I I I I I I I I I I I I I I I I I I 24:00 25:00 26:00 ~ I I' r I ( I I I I I I I I I I J I I 27:00 28:00 29:00 '-- I I I I I I I . I I I I 27:00 28:00 .Î I T? I 29:00 _S.3E8 :"4.BE8 - :"4.2E8 - -:"3.7E8 ~3.2E8 :"2.6E8 :"2.1E8 :"1.6E8 :"1.1E8 ... ~S.3E7 ~ 0 . OEO I I 30:00 Time _6.0EB :"S.4E8 :"4.8E8 :"4.2E8 ~3.6E8 :"3.0E8 :"2.4E8 - :"1.8EB ~1.2E8 ~6.0E7 I I : 0 . OEO 30: 00 Time Q ~ n ö ~ ~ þ) Id (1) Þ-d o ::¡ N 00 C> ~ þ) CJQ (1) v-. 00 o ~ ~ N 0\ "T1 åQ' c:: ~ CÐ ...................~I"-~--~,...,.. ..-- --.-----~--..-.-.-...,....----.-~. .,,~.__ ...-_c~...._~''''-_'>-"._ _~ ........____ ...........-....._.~.......__._...... ...,-...;___-:_-__.:0--- ,~_. .- _~_~ ',__.~ -- _. - u_ . ~~...~......:;.:.....:_.~,....:o.:-r-~.~-,-..=::::;-~-==_~=.:::'~.,..;~.=_.~~~.~_~--:-~~ File:MPDMI00069~ #1-1291 Acq:24-SEP-199"' 14':21:~", GC EI..... Voltage SIR ",OSE Sample#5 Text:E TESHEKPUK-1 7540' $9708SED006S006$ File Text:8000RP Exp:GCMS_HRSXR 178.0782 8:5 1 0 0C!1í 90-= - 80"': - 70-= - 60-= 50-= 40-= 30-= 20-= 10"': 0= , I , I I I ' I , 11")'r f , "I I 1-' 18:00 19:00 20:00 21:00 192.0938 8:5 1 0 <Y!£ 90": 80-= 70-= - 60-= - 50": 40": 30-= 2 0"': 1 0"': 0= , , I I , I I I I , I I I I I ," I I I 18:00 19:00 20:00 21:00 -..} IV ~ I , I I I I I I I I ' I n---r-¡- I I I I I I \ , I 22:00 23:00 24:00 25:00 I I I I I r I I , I I I I I , I I I rl I "\ I I 22:00 23:00 24:00 25:00 , f I .---;-- J 26:00 '-- , , I ' , I 26:00 _S.4E8 ~4.9E8 ~4.3E8 ~3.8E8 - ~3.2E8 - =-2 _ 7E8 =-2.2E8 - =-1.6E8 =-1.lE8 ::'5.4E7 I I I ' , ~I ('--"¡-ro, 1'1 , 27:00 28:00 29:00 - = 0 .OEO I I I 30: 00 Time '-- I J I I, I I I I I J , I 27:00 28:00 _3.3E8 =-3.0E8 =-2.6E8 =-2.3E8 =-2.0E8 - ~1.6E8 =-:i.3E8 =-9.9E7 =-6.6E7 ::'3.3E7 _ -"..,. : 0 . OEO , I I I , I J , 29: 00 30: 00 ~ime n n n n n n n n n n n n n n n n n n n n n nn rr n - n n n n n q n II fl a s: n t:J Pù ...-t- Pù 10 CD ~ o ~ N 00 o t-c::1 ~ (JQ (!) V"I \.0 o H) ÞO--' N 0\ File:MPDMI000693 #:f-1291 Acq:22-SEP-199'¡ 23:02:0!> GC XI... VOltage SIR "JOSE Sample#10 Text:E TESHEKPUK-1 7090' $970aSED006S001$ Fi1e Text:8000RP Exp:GCMS_HRSIR 168.0939 8:10 10O?f 90-': 80-= 70-= _1.1E8 :"1.0E8 :"9.1E7 :"8.087 :"6.8E7 :"5.7E7 :"'4.6E7 :"'3.4E7 :"2.3E7 :"1.1E7 I , I I I I I I I I I I I I I I I I I I I I I . I I I J ' I I I I I I I , I I I I .1..-) 'r (l J I , I ,^ r J T, r I~' ; 0 .OEO 12:00 14:00 16:00 18:00 20:00 22:00 24:00 26:00 28:00 30:00 -rime - 60-= - 50: -:! 40-= - 30-= 20-= 10-= 0- - "1 I I' ,^t 10:00 12:00 198.0503 8:10 10 <r!£ 90-= - 80-= 'Tj õõ· s:: '"1 (þ - 70-': 60-= 50-': 40-=: 30~ 20~ 10": 0= 10:00 ?O _1.7E8 :"1.5E8 :"1.328 :"1.2£8 :"1.028 :"8.4E7 ~ 6 . 1£7 - :"5.0E7 :"3.4E7 . I 'IJ~, " 14:00 16:00· - :"1.7E7 - O. 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OEO I I I - 1 I I I I 28: 00 30: 00 .Time '-.. \.-..., '-- I I I I ' I t I I I I I J I I I I I I I I I I I I I I I I I I I I I I I , I I I I' I I I I I I I 12:00 14:00 16:00 18:00 20:00 22:00 24:00 26:00 10-= 0: I 10:00 30-= 20-= ::"3.0E7 :"2.6B7 =-2.3E7 :"1.9E7 :"1.5E7 50-= 40"': 70-= 60'-: 80"': ::"3.4E7 90-= _3.8E7 10"': o ~ I I I I I ~ J ~ 10:00 12:00 198.0503 S:5 1 0 <Y!lJ I I I I' ~I-Y--~ -fI~(' f-;-¡-~ 1""'- I I I) I , ~ ~ ñ~ f" ---rTï ,.~ f O.OEO 14:00 16:00 18:00 20:00 22:00 24:00 26:00 28:00 30:00 Time ::"5_0E7 ::"3.3E7 ::"1.7E7 50-= 40'-: 30-= 20"': :"1.3E8 :"1.2E8 =-1.0E8 :"8.3E7 ::"6.6E7 70"': 60": 80-= _1.7E8 :"1.5E8 File:MPDMI00069~ #1-1291 Acq:24-SEP-199ï 14:21:Sï GC EI+ Vo1tage SIR ïOSE Sample#5 Text:E TESHEKPUK-1 7540' $9708SED006S006$ File Text:8000RP Exp:GCMS_HRSIR 168.0939 S:5 10~ 90"': 00 tv "T1 {iQ" ~ (þ I¡j ~ (JQ CD 0\ o o I-+¡ Þ--' tv 0\ o ~ n C1 p:> .-t- ÇI) ¡o (t) "'d o :4- tv 00 o ..... _____4 _ ___. ~_ _____. - .."_ _-__-'-_____ South Harrison Bay-l Data GMC Data Report 280 Page 61 of 126 CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT SAMPLE TYPE ___....----,--___--c-_____ ___ _ _.______.___~___ , ____ Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Limestone Limestone SST-It-m bn slty 65%:SST-It bnlgy 30%:QTZ-5% SST-It-m bn slty 65%:SST-It bnlgy 30%:QTZ-5% MOST-m-dk gy 70%:SST-It-m bn slty 30%:MDST-or Tr MOST -m-dk gy 70%:SST -It-m bn slty 30%:MDST -or Tr MDST-m-dk gy 80%:SST-It-m bn slty 10%:MDST-or 10% MDST -m~dk gy 80%:SST -It-m bn slty 20% MDST-m-dk gy 70%:SST-lt-m bn slty 30% MOST -m-dk gy 80%:SST -It-m bn slty 20% MOST -m-elk gy 90%:SST -It-m bn slty 10% MDST-dk gy 800Jó:SST-It-m bn slty 10%:MDST-or 10% MOST -m-dk gy 80%:SST-It-m bn slty 20%:MDST-or Tr MDST-m-dk gy 70%:SST-It-m bn slty 20%:MDST-or 10% MOST -m-dk gy 70%:SST -It-m bn slty 20%:MOST -or 10% MDST-rn-dk gy 70%:SST-lt-m bn slty 30% MDST-m-dk gy 70%:SST-It-m bn slty 30% MOST -dk gylbk shale 100% MOST -dk gy Ibk shale 100010 MOST-die gylbk shale 100% MDST -dk gylbk shale 100% MOST-dk gylbk shale 100% MOST -dk gylbk shale 80%:SST -It gy 20% MDST -bk shale 95%:LST -dk gy mddy 5% MDST -bk shale 95%:LST -dk gy mddy 5% DEPTHRANGE ft COUNTRY: WELL: ~ N 0\ 5700 5800 7200 7300 7400 7500 7600 7700 7800 7900 8000 8100 8200 8300 8400 8500 8600 8700 8800 8900 9000 9100 9200 Þïj P' (Jq (I) 0\ N o H) PICKED LITHOLOGY LITHOLOGY AGE FORMA nON DEPTH ft Q ~ n t:1 P' -- P' :::0 (t) '"d o ::¡ N 00 o Alaska S. Harrison Bay-t LITHOLOGY AND STRATIGRAPHY TABLE 13 · . ______ _u.. a ~ (J t:;j PJ r-t-- PJ :;0 (þ '"d o '"""i r-t-- TABLE 14 OPTICAL SOURCE ROCK MATURITY INDICATORS tv 00 C> COUNTRY Alaska WELL: S Harrison Bay-l DEPTH (ft) FORMATION VITRINITE (%.Ro) NO. of CONFIDENCE COMMENTS READINGS 7200 8100 9200 0.59 0.63 0.92 20 C MOD;IPAR 90% VWPAR+PAR 10% ;BS MOD BW MOD;SP L.O. L Amorphinite L.O. MOD 20 C MOD;IPAR 90% VWPAR+PAR 10% ;BS MOD/STR BW MOD;SP L+M.O. L Amorphinite L.O. MOD 10 E TR;IPAR 100% VPAR+WPAR TR;BS STR;HYD SPE Y/O-L.O. MOD Amorphinite L-M.O. L Confidence A =Excellent B=Good C=A verage D=Poor E=Unreliable ~ PJ (JQ (þ <J\ UJ o I--t) ~ tv 0\ ,n " II...JUUlD n n n n ß " " " If If n q , l...lL1l1f If If If If rr If IlI..JJI. o 1000 2000 3000 4000 ¢: -=5.. 5000 Cl> C' 6000 7000 8000 9000 10000 0.1 Vitrinite Reflectance Thermal Maturity Plot GMC D:=¡t:=¡ R\'-rnrt ?gn Well Name: S. Harrison Bay-1 . . . 1 3 0/0 Ro Figure 19 fug~~~ ofl2-G CJ ~ n tJ TABLE 15 P>J -- P>J ~ SOURCE ROCK QUALITY INDICATORS (l) "ö 0 COUNTRY: Alaska ::4- WELL: S. Harrison Bay-l tv 00 0 DEPTH DEPTHRANGE FORMA nON PICKED LITHOLOGY PI PI P2 TOC TMAX HI GOGI CARBT S (ft) (ft) (kg/t) (mg/gC) (kg/t) (%) degC (%) (%) 5700 Sandstone 5800 Sandstone 7200 Mudstone 1.17 92.0 1.67 1.28 496 131 20.37 0.13 7300 Mudstone 0.93 80.1 1.31 1.16 460 113 15.80 0.02 7400 Mudstone 0.97 87.1 1.42 1.12 478 127 14.11 0.78 7500 Mudstone 0.99 91.4 1.45 1.08 448 133 10.26 1.15 7600 Mudstone 0.85 85.6 1.50 0.99 436 150 10.27 1.50 7700 Mudstone 1.07 98.5 1.83 1.08 441 169 8.70 1.52 7800 Mudstone 0.70 58.4 1.56 1.21 441 129 8.40 1.04 7900 Mudstone 0.94 72.6 2.16 1.29 493 168 8.48 0.43 8000 Mudstone 1.07 89.8 1.90 1.20 445 159 9.75 0.31 8100 Mudstone l.12 80.1 2;09 1.40 447 149 10.05 0.32 8200 Mudstone 0.90 67.2 1.59 1.34 451 119 10.08 2.10 8300 Mudstone 1.31 83.1 . 2.15 1.57 445 137 7.94 2.03 8400 Mudstone 0.93 58.4 2.35 1.60 443 147 9.76 1.48 8500 Mudstone 1.18 57.4 4.23 2.06 446 205 13.85 0.78 8600 Mudstone 1.61 71.3 4.72 2.26 447 209 6.47 0.86 8700 Mudstone 1.41 63.8 5.36 2.20 446 243 7.21 0.84 ÞOt:J 8800 Mudstone 1.43 61.5 5.02 2.32 447 216 8.60 0.96 P>J (JQ 8900 Mudstone 1.31 51.6 5.50 2.53 450 217 7.13 0.98 (!) 0\ 9000 Mudstone 1.10 51.9 3.99 2.12 448 188 6.76 1.10 V'I 0 9100 Limestone 1.53 106.5 2.41 1.44 455 168 75.83 0.66 I--t) 9200 Limestone 1.21 75.1 2.49 1.62 444 154 65.49 0.69 .......... N 0\ ---- -"------------ ---. . Biomarker Ratios lIt : 0.49 SI : 0.31 M2: 0.56 112: 0.46 S2 : 0.42 M3: 0.51 "3: 0.80 S3 : 24:20:54 M4: 65.19 114: 0 MS: 115: 100:82:43: 19: 14:8 S4: 27:29:42 42.75 AI: 0.18 116: 0.28 SS: 117: 0.48 A2: 0.23 S6 : 118: A3: 0.39 S7 : 31.29 119: A4: 0.19 Þ¡: 1110 : S8 : 15.32 AS: 032 f;I) (JQ 1111: 4.27 S9 : A6: 1.11 (t) 0\ Hl2: 2.99 SIO: 0\ MDR: 1.75 1113: 4.76 0 9.05 MBP: 18.40 M) 1114 : ~ IllS: 0.00 N 0\ 1116 : 0.00 "17: 38.03 1118 : 0.00 Cl æ:: (') t:1 ~ r-+ ~ 10 ([) ~ o ~ 1'0 00 o Well name: Suite name: Country or Origin: Depth (m) : Sample name: s. Harrison Bay-} NPRA Study Alaska 5700 Extraction TSE %wt: 0.035 HPLC Saturates %wt: Aromatics "/uwt : Residues %wt: Inspection Properties API: Density @ IS deg C : Wax Content ~uwt : Wax Melting Point deg C : Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOlIIg : Asphaltenes %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : Asphaltenes (Micro Metbod) %wt : Saturates GC Pristane/Pbytane : PristanelnC17 : Pbytane/nCI8 : CPl: ALKlND : R22 : Lightllydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -283 Aromatics: Residue: Aspbalteoes : Kerogen: STANDARD: NBS22 -29.8 Table 16:1 _ _ _ _ ___- _r ,-._ _ -.-..~' ~ - -- -------....'-----~---. _. _~... .&L- _.~_::";,:~__~.....;;!.:..--"",,, ,_ '"_"'__ _" _ _ ___ _ _ _,,_··,__-_·~·~-_::-_'"':'_--............~,-__=___~__-."..::_-n__ ',,:____ -_ ·____n·-~.::--_- .Þ.,. ------ '- -~--- -- . Biomarker Ratios III : 0.54 SI: 0.47 M2: 0.51 112: 0.52 S2 : 0.47 M3: 0.54 113: 0.86 M4: S3 : 30:27:41 58.95 114: 0 liS: 100:65:43:24: 17: 1 0 S4: 28:29:42 M5: 116: 0.41 S5 : 35.46 At: 0.35 117: 0.55 S6 : A2 : 0.38 118: A3: 0.23 ~ 119: S7 : 42.25 p:¡ A4: 0.13 (JQ 1110 : 88: 18.17 (þ A5: 0.22 0\ 1111: 3.86 S9 : --...) 1112: 2.61 A6: 0.84 0 1113: 0.00 SIO: MDR: 1.88 P--tj >--' 1114 : 9.03 MBP: 78.77 N 0\ IllS: 0.00 1116 : 0.00 11I7 : 38.07 1118 : 0.00 C> ~ n tJ p:¡ ~ PJ Id (þ "'d o ::4- N 00 o SedimentlExtract Analysis Well name: Suite namr : Country Of Origin: Depth (m) : Sample name: Extraction S. Harrison Bay-I NPRA Study Alaska 5800 TSE %wt: 0.043 HPLC Saturates %wt: Aromatics %wt: Residues 'Yowt : Inspection Properties API: Uensity @ IS deg C : Wax Content %wt: Wax Melting Point deg C : Pour Point deg C : Viscority cSt @ 20 deg C : Total Acidity mg KOHlg : AsphaJtenes %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : Asphaltenes (Micro Method) %wt : Saturates GC PristanelPhytane : PristaneloCI7 : PhytanelnCI8 : CPI: ALKIND : R22 : Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -28.9 Aromatics: Residue: Asphaltenes : Kerogen: STANDARD: NBS22 -29.8 Table 16. 2 R n n II q II R R R II II II It lilt R It 1111 H ß "ß :, 1·' ~ R n q n II...JLI. a S:: () t.::' PJ -- PJ Id (D ""d o ::¡ N 00 o 'Veil name: Suite name: Country Of Origin : Depth (m) : 5am)le name: S. Harrison Bay-I NPRA Study Alaska 8600 Extraction TSE %wt: 0.191 HPLC Saturates %wt: Aromatics %wt : Residues %wt : Inspection Properties API: Density @ 15 deg C : Wax Content %wt : Wax Melting Point deg C : Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOlIIg : Asphaltcnes %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickellVanadium: Asphaltenes (Micro Method) OJ.wt : Saturates GC Pristane/Phytane : Pristane!nC17 : Phytane/nCI8 : CPI: ALKlND : R22 : Biomarker Ratios III : 0.56 SI: 0.60 M2: 0.62 112 : 0.53 S2 : 0.56 M3 : 0.67 113: 0.89 S3 : 40:31 :27 M4: 55.64 114: 0 MS: liS: 100:64:61 :34:25: 13 S4: 32:27:39 31.90 Ai: 0.78 116: 0.58 SS: 117 : 0.59 A2 : 0.84 S6: 118: A3 : 0.76 119 : S7 : 59.45 0.61 ~ A4: PJ 1110 : 58 : 33.49 AS : 0.38 (JQ (D lit I : 4.51 S9 : A6 : 0.77 0\ 1112 : 5.14 00 S10 : MDR: 5.34 0 1113: 2.08 ~ 1114 : 45.\2 MBP: 5.22 ......... N illS: 0.00 0\ 1116 : 0.00 1117 : 35.62 HI8 : 0.00 Lightllydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil: -29.1 Aromatics: Residue: Aspbaltenes : Kerogen: -29 STANDARD: NBS22 -29_8 Table 16.3 Sediment/Extract Analysis a ~ (') t:1 ~ r-t- ~ ~ () '1::$ o ::¡ tv 00 o Well name: Suite name: Country or Origin: Depth (m) : Sample name: S. Harrison Bay-I NPRA Study Alaska 8700 Extraction TSE %wt: 0215 HPLC Saturates %wt: Aromatics %wt : Residues %wt : Inspection Properties API: Density @ 15 deg C : Wax Content %wt: Wax Melting Point deg C: Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOll/g : Asphaltenes %wt (IP Method) : Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : Asphaltenes (Micro Metbod) %wt : Saturates GC Pristane/Pbytane : PristaneJnC17 : PbytanelnCl8 : CPI: ALKIND : R22 : Biomarker Ratios III : 0.57 SI : 0.55 M2 : 0.61 112 : 0.53 S2: 0.59 M3: 0.65 IIJ: 0.89 114: 0 S3 : 37:27:35 M4 : 61.53 115: 100:67:60:34:23: 12 84: 33:27:38 M5: 116: 0.52 SS: 44.24 AI: 0.84 87: 0.58 S6: A2 : 0.87 118: A3 : 0.77 119 : S7: 51.l7 I-c; A4: 0.62 ~ 1110 : S8: 27.38 (JQ M: OAl () 1111: 4.70 S9 : 0\ 1112: 5.l1 A6: 0.79 \0 S10 : 0 1113: 2.54 MDR: 5.59 Þ-+-¡ 11I4 : 44.03 Þ--" MBP: 4.79 N illS: 0.00 0\ 816 : 0.00 1117 : 34.24 1118 : 0.00 . Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -30.3 Aromatics : Residue: Aspbaltenes : Kerogen: -29-4 STANDARD: NBS22 -29.8 Table 16.4 " " If It " It If It I'Ll If II 11ft " 11·11 " n n H Hit I ,I[ 17.0-=' ~~ ~ =(1 16.0-~::J --1'0 - ..-t- -~ ~ 15.0-(]) ::'Iid =-0 -::::+ 14.0~~ :=0 -- 13.0~ - 12.0 -= - 11.0-= -- 10.0-=- - - 9.0-::: - - 8.0-= - 7.0-:= -, ?'d 6.0-i-~ =«1> ~ I .=:::> 5.0~ ____J -=-------~----- ~ JJ\ 4.0-:_ ~ ? ~ 3.0-= ..) ::> - - ! )~) ~IJ \~I)I þ~ ' :~~ ~---------- ~ I , I I I 1 I. r-I I I I I I I 5 10 15 I ¡ I I I 1 I I I I I I I I I I I I I I I 1 I I ¡--¡- I I I I I 20 25 30 35 40 45 I ¡-¡-r--T--T- T·r r--, 1 50 5'5 9708SED007S001 S Harrison Bay-1 5700' - Whole Oil GC j~ JJ / rf u__ __ _______ . ----- - - -.-.---..___ --~-~___-_ ______u_._ ~ 20Z ~-n =:; ~ - .-t- -~ ~.~ 18-(1) ~ -::> ~-Ã - --..) ---:xJ -=::::> 16::' 1r 970SSED007S002 S Harrison Bay-1 5800' - Whole Oil GC 14- :~ .h 8--= -> ,",~VI\Á P '4 ,j A\\~ I . t ~ hJ~ ~ A ~ ~~---J-------L ¡- I ~J. \ ; li.,J~~1 . 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OEO ~ime " " It " " " II II 1 " If 1·1 " It" 1 oft II " It lilt " II ··It " It II II It If It I File:MPDMI000693 #1-3086 Acq:23-SEP-199'l 02:24:31 GC EI+ Vo1tage SIR 'lOSE Sample#12 Text:S HARRISON BAY-1 5700' $9708SED007S001$ File Text:8000RP Exp:GCMS_HRSIR 177_1643 S:12 F:2 10U!í 80-= - 60-= 40-= 20~~" ~ ,~,,, ~. ..~~~~\vkJlQ~_AA-^~~H'" 0-/'" .. 30:00' , , '40~00' I I '50~00' I , 1:00:0Ò ' I 1:10:00 191.1799 S:12 F:2 10~ i:20:0Ò 80-= 60-= 40-= 20-= ,~~~"",-,-- ~- I l' '1 I I 1 ' 50:00 1:00:00 1:10:00 I 1 I 1:20:00 o ---" ; - I ~ I 30:00 40:00 205_1956 S:12 F:2 10O?f 80-= 60-=: ~.. - I I 40-= 20-= ._....~~lL',~~_ . i:oo:oò 1:20:0Ò 0-[ 30:00 -' Á .Þ-j.. ~, -..., -- --. '40~00' I I I 50:00 i:10:0Ò a ~ n t::) $:I) .-+ $:I) :::a ("D '"d o ::¡ N 00 o 'ï:1 $:I) (Jq (1) -.....) 0'\ o I-t¡ ~ N 0'\'T1 àQ' ~ '""1 (I) N W File:MPDMI000693 #1-3086 Acq:23-SEP-1997 02:24:31 GC BI+ voltage SIR ïOSE Sample#12 Text:S HARRISON BAY-1 5700' $9708SED007S001$ Fi1e Text:8000RP Exp:GCM8_HRSIR 218.2033 8:12 F:2 10~ _5.7E6 - 80~ ~4.6E6 - 60~ ~3.4E6 40~ ~2.3B6 20~ ~ V '¡.¡..¡ 'M oJ\¡ Jl . ~1.1E6 _~~~._~_~ '~O.OEO , , I 1 ' , t I r I I I I I I I , I I ' , I , I ' , I I 1 I I I I 35:00 40:00 45:00 50:00 55:00 1:00:00 8:12 F:2 0- r , 30:00 217.1956 1 0 O?I¡ Time _1.2E7 - ~9.8E6 80-= - ~7.4E6 60-= 40-= ~4.9E6 '-^'l JJ V'" ~ ~ ,J\~' ~ - ~2.5E6 O.OEO Time 20~ t I I 45:00 '50 ~ 001 , I I 55:00 I 1': 00: 010 I 0- I I r I ' 30:00 35:00 231.2111 8:12 F:2 100% r. I I I 40:00 _3.626 - ~2.9E6 80-= 60~ 40-= 20-= ~ ihA ~2.2E6 V'YiV\ i ~ ~, I. \. \. t. I. ~1. 4E6 'J~7.2E5 I I ' 45:00 , I ' 50:00 I I I 55:00 I 1':00:00 I - - O. OEO ,Time 0- I 30:00 I I I 35:00 , I ' 40:00 ftWftWWWftftWftftlftWftØftlftftlft·ßftftftftftlllftll :"2.7E7 :"'2.4E7 =-2.0£7 :"1.7E7 :"1.4£7 :"1.0£7 :"6.8£6 =-3.4E6 -: 0 .OEO ,Time 1:10:00 1:00:00 I 50~OO I I , I 40:00 40-= 30-= 20-= 10~ I. . O:~~ I , I 30:00 Jv~' ~. ~ \~----- --- ( I ~ ?Jo -zS 50-= \.' ...¡\ )lf~ 70-= 60~ \.{.O lO 'L.1 80-= 402.- _3.427 :"3.1£7 ,"'> 30-= 20-= 10~ 0: __ 30:00 217.1956 1 0 O'!£ 90-= 'l,p. :"'4.827 :"'2.4E7 ;:. 0 _ OEO Time "\) ~n .-{ v 0< 11"A " P ~~ ~~~~~~~~~ . I I I I , 1 I I I I 1 ' 50:00 1:00:00 1:10:00 LJ I I ' 40:00 8:13 F:2 -« :"'7.227 v () :"'1.4E8 :"'1.228 :"'9.6E7 50-= : ~ 40-= ~ File:MPDM1000693 #1-3086 Acq:23-SEP-199ï 04:0~:43 GC E1+ Voltage SIR 10SB Sample#13 Text:S HARRISON BAY-1 5800' $9708SBD007S002$ File Text:8000RP Exp:GCMS_HRSIR 191.1799 S:13 F:2 100'!6 & 90-= 80-= 70-= 60~ _2.428 :"'2.2£8 :"'1.928 :"'1.728 ------- ._----"- - --.-----, ----~-- ~ ~ (JQ (1) --.) --.) o Þ-+¡ ~ N 0'\>Tj 6Q' s:: .., G N - ~ C) ~ n t) ~ ..-t- ~ ~ (1) '""d o ::¡ N 00 o _4.2E7 - :...3.4E7 - - :...2.5E7 - - :...1. 7£7 - - :...8.SB6 - - - I - O. OBO i:20:00 Time _2.4£8 - - :...1.9£8 - - :...1.4£8 - - :...9.6£7 - - :...4.8£7 - - _ . - O. OEO i:20:00 J Time _3.1£7 - - :.2.5£7 - - :...1.9£7 - - :...1.3£7 - - :...6.3E6 - - I - O. OEO i:26:00 .Time 1:16:00 1:00:00 150~00' '40~00' o - I 30:00 _.~ ___"d_,,~~t~ 40..:: 20..:: 60...: __ .~-.lL.~ -Lv ISO~OOI I I 1:06:00 I J i:16:00 J 0- ~. A..-J. - I I J I I I 30:00 40:00 205.1956 8:13 F:2 10 0?6 80..:: II...--J.. AI J I 20...: 40...: 60...: 80..:: i:16:00 0-(· ------^ J J I J I I 30:0040:00 191.1799 8:13 F:2 100% i:06:00 'SO~OO' ~~~,,~~.~- . ..,,,.., - 20...: 40...: File:MPDMI000693 #1-3086 Acq:23-SEP-1991 04,:05:43 GC EI~ Voltage SIR ïOSB Sample#13 Text:S HARRISON BAY-1 5800' $9708SED007S002$ File Text:8000RP Exp:GCMS_HRSZR 177.1643 8:13 F:2 10~ 80~ 60..:: ÞOyj öõ" c: -t n> N ........ V. >--' tv 0\ ~ Po) (JQ () -.....) 00 o ~ C) ~ n t:1 pù .-t- Po) ~ (þ '"d o ::¡ tv 00 o ___-_-.. __. ._______~ _". _.._ .._ _. _. . __ _ _ n.-__-. _.." _ __. _._...-.- _____- :__._.. ::-:-:.._-_---_-:-._--:.~=~-_-._::.~__;..__;:_-:,~=~-__=__--_ :__-'-.._::-=-=-_-:_:--.:--_----:":--~-~-~---~. :-': _n_ -_H. ,.:_L_______p_ ..____~~~_.._ . --':~_ .. :--~:__~.::.-:- __ i:~-~~n: - . ----~----.--- -------------- Q ~ n t) ~ r-+- ~ ~ (1) ~ o ~ N 00 o ""0 ~ aq (1) --.) I.D o H-¡ ....... ~ s::: '"'1 (I) N 0\ ---------; .".--.-.-- ~_ _____.._4~--.".--..-----.-__--·.--_--,.- File:MPDMI000693 #1-3096 Acq:23-SEP-199ï 04:0~:43 GC EI+ Voltage SIR 'JOSE Sample#13 Text:S HARRISON BAY-1 5800' $9708SED007S002$ File Text:8000RP Exp:GCMS_HRSIR 218.2033 8:13 F:2 10~ _2.1£7 :..1.7E7 80..:: 60..:: 40..:: 20...:: 0- . - -~ 1 , I I ' 30:00 35:00 217.1956 8:13 F:2 10~ 80..:: 60...:: 40..:: 20..:: o - l I I I 1 30:00 35:00 231_2111 S:13 F:2 100% 80..:: 60..:: 40..:: 20...:: O- J 30:00 135 ~ 00' - :..1.3E7 :..8.5E6 ~ .j{' I'N J\fI .J-.JL. ~4.3E6 \0 ~O.OEO 1 I 1 I I 1 1 , 1 1 ' , , , 50:00 55:00 1:00:00 Time , I I 40:00 I I I 45:00 _3.4£7 :..2.7E7 - :..2.0£7 :..1.4E7 '\I~\'M \,A ",,1M I... ..)vil'V' ¡ \J.~ :..6.8£6 - 0 .OEO Time , I 1 40:00 I I I 55:00 , 1':01,:0'0 ' , I I 45:00 , I I 50:00 _1.0E7 - :..8.4E6 - V ~'~"Jh · ~6.3E6 V ~~4.2E6 _2.126 - ,. O. OEO ,Time I· I ' 50:00 40~OO 45~OO I I I 55:00 1 1':00:0'0 J ftftftøøftftftftftftftllftftlftftnftftlftnnftftft~øftl~ :"1.526 -= 0 .020 ,Time _1.527 :"1.327 :"1.2E7 :"1.0E7 :"8.726 :"7.3E6 =-5.8£6 =-4.4E6 :"2.926 :"1.527 =--7.726 ,- 0 .020 Time :"2.327 :"4.6E7 ~3.9E7 :"3.1B7 ~7.7B7 :"6.9B7 :"6.2£7 :"5.4E7 60~ SO"': 4 O~ o¡Þ~1 30~ ~ "l~ >'t l' 20 : .' . ~ . ~'" 1~1~~~~\~.~H'J · I', ~ V~ 30: 00 ' , , .j . 40~00' , , · ..~ 5 I I 0: 00 ' , , .~ " 1:00:00 ' " --- ,~. 1:10:00' ~ 30"': 20"': 10~ o ~~.. ~---"" I I , I I I 30:00 40:00 217.1956 8:14 F:2 ,lO0?6 90"': 80"': 70"': "T1 ãQ" ç: .... (þ tv ...... ~ I-' N 0\ Þ¡: ~ (JQ (!) 00 o o I--t) o ~ (J tJ ~ ~ ~ 10 (!) ""d o ::4- N 00 o If '2.ì 1\{>.. (0 " 0< f> rx 'lib L t ð'S "- --- jJ ~,'W" "'v.. ~ ~ I I I I I 1 ' , I , 1 I 50:00 1:00:00 1:10:00 '1Í 1"s '* rÍ oJ 'þ 0 r,-", SO"': 40"':' File :MPDMI000693 #1-30êï ACQ:23-SEP-199rl Ob:46: b4 GC EI.¡. Voltage SIR -lOSE Sample#14 Text:S HARRISON BAY-1 8600' $9708SED007S017$ Fi~e Text:8000RP Exp:GCMS_HRSIR 191.1799 5:14 F:2 10~ b- 90-= 80"': 70"': 60~ Cl ~ n t:1 ~ .-+ ~ ?J (t) >a o ~ N 00 o ~ p) (JQ CD 00 ~ o I--t) ~ N 0\ "Tj åQ" c: '"""t (þ tv 00 ._-~---- -----_._---------~----- --- -...----- -.-"-,----------- .- -~ -- . . - - . ---- - .- - - .--..- -- -.-.---~ .--_.---.---- ---. -- - ---. File:MPDMI000693 #1-308-, Acq:23-SEP-1997 O~:46:~4 GC EI.... Voltage SIR "JOSE Sample#l4 Text:8 HARRISON BAY-1 8600' $9708SED007S017$ File Text:8000RP Exp:GCMS_HRSIR 177.1643 8:14 F:2 10 {1!f _2.2B7 - =-1.7£7 =-1.3£7 - ::.8.6B6 - 80: - 60-= 40: 20: 0- , I I 40:00 191.1799 8:14 F:2 10~ 80: - 60: 40: 20-.:: - o -,..,. i....,. , Á.-.J _.- , I I I 40:00 205.1956 8:14 F:2 1000£ 80-.:: 60-.:: 40-.:: - 20- ~-."-^,.,).".,,., '..- ....,.~......... .." 0- I I I 40:00 - =-4.3B6 I I I 50:00 1:20:00 - - 0 . OBO Time i:oo:oo I 1 ' 1:10:00 _7.7B7 - ::.6.2B7 - ::.4.6B7 ::.3.1£7 ~~~~~""'"~ 1:00:00 1:10:00 - =-1.5£7 I J I 50:00 1:20:00 - .. - 0 .OBO Time _1.1E7 - ::.9.1£6 - =-6.8£6 ':...4.6£6 ~;~ - =-2.3E6 ft."':'" .~_ - - O. OEO ;Time '50~00' I 1 I 1:10:00 i:oo:oo 1:20:00 11"1111111111 n n II It lilt rt lilt n II II It It n·1Lll II .,;1 ,;1 1111 ~ CJ ~ n Ö ~ ~ p) Id (t) ~ o ::¡ N 00 o ~ p) (fQ (t) 00 N o t-+¡ ~ N 0\"11 òQ. ~ >; 0> IV ...... \0 File:'MPDMIOOOõ93 #1-309", Acq:23-SEP-199"¡ O!:>,:46:!:>4 GC HI.... voltage SIR "JOSE Sample#14 Text:S HARRISON BAY-l 8600' $9708SED007S017$ File Text:8000RP Exp:GCMS_HRSIR 218.2033 S:14 F:2 10~, _7.586 - - 80~ ~6.0B6 - 60~ ~4.5B6 40~ - :.3.0B6 . IIi !" Jr )J..¡ '~ . A. I . ~1. 5:£6 .Jv )J'V'V'f-I ~ ~V\J "- ~: - 0 . 080 Time 20.--: = . . A 'Ww'MJ.. ~ o - ~\,.J , , , , , . , , , I I 30:00' 35:00 40:00 217_1956 8:14 F:2 10~ 80~ I I 1 45:00 '50 ~ 00' I I ' 55:00 , 1':00:0'0 ' _1.5E7 - :.1.287 60.--: - :.8.786 40.--: :' · ~ Jt.v \A Jv"'.J wJ~ :.5_886 - ~2.9E6 20~ 1 J.J,~~~ o - ~\N#Y'W . I , I I I , I , I 1 30:00 35:00 40:00 231.2111 8:14 F:2 100% 80.--: ~ 0 .OEO Time I I ' 45:00 1 I I 50:00 's5~001 '11:00:0'0 ' _6.4B6 - :... 5 .186 60~ \~V~JvJ\\\nJ· t::::: 'V'~1.3B6 40.--: 20~ ~~..J< o -I , , , 1 I 1 1 1 1 I ' 30:00 35:00 40:00 I I ' 45:00 1 I ' 50:00 I I ' 55:00 1 1':00:010 . - - 0 . ORO .Time -~~------.. ---- -~- -- ~-- --~---------- ---~--=_.~----------- -~ ----.. _. _.----.~ - ---- _u___ .__ .____.._________.___.. - ------------ - - o ~le:MPDMI000693 #1-3081 Acq:23-SEP-199, 01:28:08 GC EI+ voltage SIR ïOSE SSmple#15 Text:8 HARRISON. BAY-1 8700' $9708SED007S018$ File Text:8000RP Exp:GCMS_HRSIR ~1.1799 8:15 F:2 !O~. if ~90~ '"d - ~80~ N : ~O~ 60~ 50-= 40-= 30-= 20-= _S.8B7 - ~S.2E7 "\<, '01< ,J J /í.... ]) D . - ~4.6B7 ~4.0B7 ~3.SE7 ~2.9E7 ~2.3B7 10-= O~~ I I I I I 30:00 40:00 217.1956 8:15 F:2 10005 90": /,5" ~I p( ~ ~ç ,. ~"J~.j1J J....JJ.l ~.A~~ 1.:00:00 1:10:00 I 50:00 - ~1.7E7 ~1_2E7 =-S.8E6 ~ 0 .OEO Time IV' _1.1E7 400 \.If '" ,~l ,1- - =-9.6E6 =-8.6£6 ~7.SE6 =-6.4£6 ~S.4B6 ~4.3E6 "j' Po "Tj úõ" t:: -t CD ~ ~ o - 80-= 70~ 60-= ~O~ J:I) - ~O~ ~O: ~:j lÞl., JA.M ~~~_jj.JJJ ð. o:rl I I I I I I I I I I I 30:00 40:00 50:00 \I 'l.Î 1~ 1S ~ / VI .~ ~ ~l. 'I"'~.....\ .....". "." - -. ....'---LI,.,..._ 1.:00:00 1:10:00 - =-3.2£6 =-2.1B6 =-1.1E6 :.= 0 . OEO Time ..... _ l "lI"lI""rrn"""""""""""nnnftltllftltlllf"It"'1 a ~ (J t) PJ ~ p:¡ ~ CD "'d o ~ tv 00 o Þï:1 PJ (JQ (t) 00 ..þ.. o ~ ~ N 0\ "T1 òQ. c: -t 0> ~ File:MPDMI000693 #1-308"' Acq:23-SEP-199'/ 0-/:28:08 GC EI+ Voltage SIR "JOSE 8ample#15 Text:S HARRISON BAY-1 8700' $9708SED007S018$ File Text:8000RP Exp:GCMS_HRSXR 177.1643 8:15 F:2 10~ _1.6B7 80~ ~1.3B7 - 60~ ~9.5E6 40~ ~6.3B6 20~ . - 0 . OBO Time - ~3.2B6 .,. - - 0- , I ' 30:00 40:00 191.1799 8:15 F:2 1 0 <Y!f¡ 80~ 60~ , 1 ' 1:10:00 i:20:00 I 50:00 I 1 1 1:00:00 _s.8E7 - ~4.6E7 - ~3.5B7 ~2.3E7 40~ 2 O~ . 1 1 I 11 I 0: ~ -' -. - _ Å-J _. ~.Ji.....JutuJ""'JJl. ~~ -. 30:00 40~00 sO~OO 1:00:00 1:10:00 205.1956 8:15 F:2 100% 80~ ~1.2B7 , 1 ' 1:20:00 - - O. OEO Time _8.7E6 - ~6.9E6 .:..5.2E6 60~ 40~ 20~ ~3.5B6 ~1.7B6 ~ .~~" ......~ ,-. - - ,... 0 .OBO ,Time 0: 30:00 1:10:00 i:20:00 '40~00' , I ' 50:00 1:00:00 - CJ s;: n d ~ ........ ~ ~ (l) ""d o =:4. tv (X) o ~ ~ (JQ (t) 00 V\ o I---iJ >--' tv O\"T úQ" ~ '"1 <Ð tv ..- ..- tv - --~-----~-.~~--------=~ -------~._~~--_._--~: -~:--:-.~~~~~-:--~ ~--=-~-=~-:~~:-.,.~:-_:~~~~;-::.:::~- :~~_.--".~~. - ._~~=-- File:MPDMI000693 #1-308"/ Acq:23-SEP-199"' 0",:28:08 GC EI+ Vo1.tage SIR "JOSE Sample#15 Text:S HARRISON BAY-1 8700' $9708SED007S018$ File Text:8000RP Exp:GCM8_HRSIR 218.2033 8:15 F:2 10~ _4.9E6 - 80~ ~3.9E6 - 60~ ~2.9E6 40~ 20~ O:~M~~ I , , , I ' , I , I ' 30:00 35:00 40:00 217.1956 8:15 F:2 100% .M ~1.9E6 ~L~9.7E5 - O. OEO I 1': 00: 0'0 ' Time J.,;/MJ Jf'inJ /41, '50 ~ 00 , 1 ' 55:00 , 1 ' 45:00 _1.1E7 80~ - ~8.6E6 60~ 40~ - ~6.4E6 - =-4.3£6 ~I',"'~ Vr ~ \4, - :..2.1E6 20~~ ¡LA : JVWl.M.,"~ 0- , I , I I I , I , I I 30:00 35:00 40:00 231.2111 8:15 F:2 100% - O. OEO Time , I I 50:00 I I ' 55:00 , 1':00:0'0 ' I I I 45:00 _4.686 80~ - :..3.7E6 60-= ~ ~IW j ml I ~2.8E6 ~ 1,^~1.8E6 _9.2£5 ::]~~ 0-1 , , , , I ' I 30:00 35:00 , I I 50:00 , I I 55:00 I , 1 ' , 1:00:00 - - O. OEO Time , I I 40:00 I I I 45:00 ftøftøØftftftftØllllllnnftnnnftlnnnnnnnn.~ ,^---<- 0 .OEO ,Time "J..J~ __-' , , I I I , I I ' I 35:00 . 40:00 11~OS:00' I f1. ~J^Jkl i~ }'^'~, I I ' I , I I ' I I I I ' , I I 1 I I 45:00 50:00 55:00 1:00:00 30:00 I 1 O=r :"2.8E6 20~ t~. 101 " Jv .IVY"" ~ I'J.,) o:~ - , , , , I I I I I I I I I I J I 30:00 35:00 40:00 45:00 253.1955 8:12 P:2 10~ 90"': ..J 80"': 70": 6 0": 50"': 40": 30": 20": 10": :"'2.2£7 ¿1.9£7 ¿1.7£7 :"1.4£7 :"1.1E7 r- :"'8.3£6 :"5.5£6 f\~ fÓ f\o fltil fl \ 11'\1. c;.t; _2.8£7 ':"2.5£7 v\l~ _1.1E7 :"'1.0E7 :"'9.2£6 :"8.0£6 :"6.9E6· :"'5.7£6 :"'4.6£6 i-3.4E6 :"2.326 :"1.1£6 . -: 0 .OEO Time WVþl~'~~ -. ...... -.... ... 55 ~ 00 I I 1 ~ 00: 00 I I 1 ~ OS: ÒO ' I I r 50:00 I I fI~ Í"t 80": 70-': 60-': 50-': 40"': 3 0"': / 1<) flc" FtÐ ñ\ f\~(( File:MPDMI000693 Sample#12 Text:8 231.1173 S:12 F:2 10O?f - . 90-': #1-3086 Acq:23-SEP-199-/ 02.:24:31 GC BI4- Voltage SIR "lOSE HARRISON BAY~l 5700' $9708SED007S001$ File Text:8000RP Exp:GCMS_HRSIR '""'0 ~ {JQ (þ 00 0\ o ~ ~ N O\'T ðQ' ~ ""1 (1 N N a ~ n t) pj s- ~ (þ ~ o .:::¡ tv 00 o n " n " " " rr n " " " " " " rr " " n " n " nn II nn n n liD DI_-_I_.~ ~1.1E7 =-7.3£6 :"3.6£6 ^--':. o. 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O£O Time ~8.9E6 ~5.9E6 :"3.0E6 ~2.4B7 ~2.1E7 :"1.8E7 -=-1.5£7 :"1.2E7 _3.0E7 :"2.7B7 I J 1 I I 1:05:00 . _~ ..-,_. ,~.u,J¡,.,)v I~~_. ._ I I I I I I I I I I I I I I I I I I I t I I I I I I I 1 I I 35:00 40:00 45:00 50:00 55:00 1:00:00 O=r I I 30:00 ""d ~ (JQ (þ 00 --.) o HJ ~ N 0\'"1'1 òQ" c:: '"1 CD N N N o ~ n tj ~ .-t- ~ 10 (1) '"d o ::¡ N 00 o ~1"~'1;i:\W:: ,_~oç¡r- -~. .-"'" 70~ 60-= 50-= 40-= 30-= 20-= 10~ {-ot.~ fto ,~ ~1 f(I4-\J- f-S 80-= I I I l;O!:ÒO 1 I l~ob:òo I t I I 50:00 ~ 0= I 30:00 253.1955 10 a!Jj 90-= t 45~OÒ 40 ~ OÒ I I I I I 35:00 8:13 F:2 : "--""" 0 .J I I I I 55:00 ~ ~~~ 90-= 80-= 70-= 60~ 50~ 40-= 30-': 20-": 10~ ~\I" f1{ ~I't ('¡þ (1"\ h..I Fi1e:MPDMX000693 #1-3086 Acq:23-SEP-199ï 04:0~:43 GC EX+ Vo1tage SIR ïOSE Sample#13 Text:B HARRISON BAY-1 5800' $9708S£D007S002$ File Text:8000RP Bxp:GCMS_HRSIR 231.1173 8:13 F:2 10 O?lí ft"1-f\ 't' a ~ (') t1 p) r-t- p) ¡o (I) '""d o ::¡ N 00 o "ï::1 p) (fQ (I) 00 00 o H-¡ N 0\ File:MPDMI000693 #1-3081 Acq:23-SEP-199ï 0~-:46:~4 GC E~+ Vo1tage S~R ~OSE Sample#14 Text:S HARRISON BAY-l 8600' $9708SED007S017$ File Text:8000RP Exp:GCMS_HRSIR 231.1173 8:14 F:2 10 a!f. 90-= 80": 70": f'~ _3.6E7 :"3.3E7 :"2.9E7 :"2.5E7 :"2.2£7 :"1.8£7 :"1.4£7 :"1.1E7 r- :"7.2£6 =-3.6£6 .;: O. OEO Time fl't - 60-= 50-': 40-': ¡''1-t1~ - 30-= 20: 1:1 . IUI ilk ,JA,J ~~ ~'V ,~~~ I I I I I I ( I I I 30:00 35:00 40:00 45:00 253.1955 8:14 F:2 10 cr!f. rs-'L 90-': ~~ (0.'\ I't\ 1-1" ý1Þ --~~- I I I I I I I 1 I I 55:00 1:00:00 I I I 50:00 I l~OS:ÒO I ¡16f1 ~3.1E6 :"2.8£6 :"2.5£6 :"2.2£6 :"1.9£6 :"1.6£6 :"1.3E6 :"9.4£5 :"6.3£5 =-3.125 : 0 . OED ~ime - 80-= 70-': ~ f> ~\,!,1. 'T1 tiQ" s::: -t (1) tv tv W - 60": ::~ I hllJ~ ~' ~o ~~ 3 oj .h,i...tfV1" · ~ JI . f~! ~ r I 20~ l"'1' '\.\Vf .A ~ .; I ~W ~ \. JI ~>¿~~. 10-= 0= I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I I I I 1 I I 30:00 35:00 40:00 ,.45:00 50:00 55:00 1:00:00 1:05:00 " n n n n n n n n n n n n n n n n n n n -n nn n nn n n n nn n ILIL , I 1 I I I I 1:05:00 :"2.2E6 :"1.9E6 =-1.6E6 :"1.426 ~ :"1.1E6 :"8.225 :"5.5E5 ,- ~'N""~2. 725 : 0 . OEO Time _2.7E6 :"2.5E6 I , I I I , I I I I I I I I I I I I I ' I I I I I I I I 1 I I 35:00 40:00 45:00 50:00 55:00 1:00:00 30-': 20-= 10-= 0: , 30:00 ~ r.~' JJ~~i ~I" ~i\,1 80-': 70-': 60-= 50-= 40-': (-; pO tv1 o \-" î. f} ft'!. v~tJ P'" S5~OO I '1~OÓ:OO I '1~OS:ÒO' 50~OO (-5 30-': ~:L__~-~~^ V, \ ^ ~ r , r J I I I , , I J I I I I I 30:00 35:00 40:00 45:00 253.1955 8:15 F:2 1000¡ 90-': Fi1e :MPDMI000693 #1-308-' Ac<;[:23-SEP~199-/ OT:28: 09 GC EI+ Voltage SIR "JOSE Sample#15 Text:S HARRISON BAY-1 8700' $9708SED0078018$ File Text:8000RP Exp:GCMS_HRSIR 231_1173 8:15 F:2 1000¡ 90-': :"1.8E7 -:"1.6E7 =--1.4E7 :"1.2E7 :"9.2E6 :"6.9E6 :"4.6E6 =-2.326 -': O. OEO Time _2.3E7 :"2.1E7 "-^.~~- f4'" f2-- fo1~C¡ f< c, n' 80-': 70-': 60-': 50-': 40-': f-I'f {<{ ---- -- --,--_-.&.--". 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I 24:00 25:00 26:00 27:00 28:00 29:00 #1-1291 Acq:23-SEP-199ï 04:0~:43 GC EX+ Vo1tage SXR ïOSE HARRISON BAY-1 5800' $9708SED0078002$ File Text:8000RP Bxp:GCM8_HRSIR File:MPDMI0006§-3 Sample#13 Text:S 178.0782 8:13 10~ 90":' 80":' 70":' 60": 50-= 4 0": 30-= 20-= o ~ o t) p) ...... p) Id (I) '"ö o ::4- N 00 o ~ p) (JQ (I) \0 N o Þ-t; ~ N 0\ 'T ùQ' ~ '""t (II tv w W File:HPDM1:000693 Sample#14 Text:S 178.0782 8:14 1000¡ 90": 80": 70": #1-1290 Acq:23-SEP-199"' 0~.:46 :~4 GC E1:+ Voltage SJ:R "lOSE HARRISON BAY-1 8600' $9708SED007S017$ File Text:8000RP Exp:GCMS_HRSXR - 60~ 50": 40": - 30-= 20": 10-': 0: ......1:'-- ~ Î J - ( , I I , I I r I I I J I I I I I I I 18:00 19:00 20:00 21:00 192.0938 8:14 10a!f 90": 80-= 70-= 60-': 50": 40-= .~ I I I I , , , I I ' , 22:00 23:00 I , \ I I I . 24:00 , I I t I 25:00 - 30-': 20-': 10-': 0: 18:00 I . , , . ,-. {', I I I 23:00 24:00 , , I I · I , , , ,-, I 21:00 22:00 . , , I ' I 19:00 I . 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I I 19:00 20:00 I I I I , I 25:00 I I I I I I I " I II 28:00 29:00 _5.6E6 :"5.186 :"4.586 ':"'4.086 :"3.4E6 :"2.8E6 ':"'2.3E6 :"1.7E6 :"1.1E6 If\. \ ~5.6E5 ~:O.080 I I 1 I I I I I I I I I I I I I I I I I 24 : 00 26 : 00 28 : 00 30 : 0 0 ~ime I I : 0 . OEO 30: 00 Time ~3.2B7 :"2.987 :"2.687 :"2.3B7 -:"1.9B7 :"1.6E7 :"1.387 :"9.7B6 ':"6.586 :"3.2E6 I I I I I I I I I I I 1 I I I I I I I I I 1 I I I I 1 I I I I I I I I 12:00 14:00 16:00 18:00 20:00 22:00 80-': 70-': 60"'=: 50-': 40": 30"': 2 0": 10": 0: . 10:00 ~ PJ (Jq (1) \0 ..¡::.. o ~ ~ N 0'\ '"T1 üQ0 ¡:; 0; G tv .þ. ...- o ~ (] t:1 ~ -- PJ ~ (1) '"ö o ::4- N 00 o 90"'=: I I I I I I , 1 , { I , , 26:00 28:00 I , I I I 24:00 ~J.~ (, I' I I I I ' I I , , I I I I I I I I I 14:00 16:00 18:00 20:00 0: I I I I I~ ,./} I 10:00 12:00 198.0503 8:12 100% I I . I ' I I 22:00 File:MPDMI000693 #1-1291 Acq:23-SEP-199? 02:24:31 GC EI+ Voltage SIR 10SE Samplei12 Text:S HARRXSON BAY-1 5700' $9708SED007S001$ Fi1e Text:8000RP Exp:GCMS_HRSIR 168.0939 8:12 100% 90"': 80"'=: 70~ 60": 50": 40": 30-= 20"': 10": "ØI"'1 30: 00 .Time _1.3B7 ~1.2B7 :"'1.1B7 ~9.3B6 :"'7.9B6 ~6.6B6 ~S.3E6 ~4.0E6 :"'2.6E6 :"1.3E6 : 0 . OEO ~2.4B7 ~2.1E7 :"1.8B7 ¿1.SE7 ~1.2E7 ~9.1E6 ~6.1E6 :"3.0E6 :: O. OEO 30: 00 Time 0= I I · , · r . ~ · 10:00 12:00 198.0503 8:13 10O?E 90": 80": 7 0": 6 0": 5 0": 4 0": 30": 20": 10": 0= . . I I , I ' . . . I I · I I . I I I . , 10:00 12:00 14:00 16:00 "---'- I , 1 IY^;-'-l 28:00 \1\.. ~ ~ I . I I I . . I I . I I 24:00 26:00 I I I I I 18:00 I I \ r ' I . I I I . I I 20: 00 22: 00 . I I I . I I . . I . · I I . I I . I 24:00 26:00 28:00 . . I I . 22:00 ~lf.~ " I I I I . I . I . f I I I . . . . I I . 14 : 00 16 : 00 18 : 00 20 : 00 _3.0E7 :"2.787 *1-1291 Acq:23-SEP-1991 04:0~:43 GC &1+ VOltage SIR 10SE HARR7S0N BAY-1 5800' $9708SED007S002$ File Text:8000RP Exp:GCMS_HRSIR ~- ~ . --- - :'=:'--:..:.:;--- :.:.._____ -~-=·06~-i:-:.:-=...:=_, -'~~;-,. _< .:.~~':":":::'_.-~'=..-~_ ·}.....;-.'__n _.__ ~ .______.____~__. __.,.___.__ .__." . _n File:MPDMI000693 Sample#13 Text:S 168.0939 8:13 1000¡ 90": 80": 7 0": 60': 50": 4 0": 30-': 20": 10-= ~ ::¡) aq (1) \0 VI o ~ ........ N C"I'T ùõ' t: '"f (þ IV .þ. N o ~ (") t) PJ S- Id (1) "d o ::¡ N 00 o --------~ --...- . -~ - . ---... --- o ~ (1 t:1 p:¡ s- :::0 (t) "ö o ::¡ N 00 o I-d p:¡ (JQ (!) \D 0\ o I-+¡ ~ N 0\ "Tj riQ' C '"1 (þ tv ~ W File:MPDMI000693 Sample#14 Text:S 168.0939 8:14 10m: 90': - 80-= 70-= 60-': - 50-= . 40-= - 30-': - 20-': 10-= - 0: I , I , I I I '\ 10: 00 12: 00 198.0503 8:14 100?6 90-= 80-= 70': - 60-= 50"': 40': 30-= 20-= 10~, 0: I 10:00 #1-12~0 Acq:23-SEP-199"¡ 0:»,:46: ~4 GC BI+ Voltage SIR 10SE HARRISON BAY-l 8600' $9708SED007S017$ File Text:8000RPExp:GCMS_HRSIR _1.4B8 1 " I I I I I I I 14:00 - ~1.3B8 ~1.1B8 ~1.0B8 :"8.6£7 ~7.1B7 ~5.7B7 =-4.3B7 ~2.9£7 :"1.4E7 - 0 . OEO I I 30:00 Time I I I I I 26:00 I I I I I I I 28:00 , I I I I I 24:00 I I I I I I I I I I I I I I I I I . 16:00 18:00 20:00 22:00 _1.0E8 ~9.1E7 ~8.1E7 ~7.1E7 ~6.0E7 =-5.0£7 =-4.0£7 =--3.0£7 . I..... ¡I.. 'l I I I I I I I \ I I I I 24:00 - 26:00 - =-2.0£7 ~1.0B7 ^- ~ : 0 . 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O£O 30: 00 .Time ,^-r I "î , 28:00 RRRnRRßRRnRRRRRRnl Page 98 of 126 West Fish Creek-] Data -------- GMC Data Report 280 cur cur cur CUT CUT CUT CUT CUT CUT cur CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT CUT cur cur CUT SAMPLE TYPE Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone Mudstone LimeStone Limestone MOST -dk gy shaley 50%:MDST-rdlbn 10%:SST -It-m bn 40% MOST -dk gy shaley 70%:MÐST -rdlbn lO%:SST -It-m bn 20"10 MDST -dk gy shaley 90%:SST -It-m bn 10% MOST-dk gy shaley 65%:SST-lt-m bn 35% MDST-dk gy shaley 70%:SST-lt-m bn 30% MOST-dk gy shaley 50%:MDST-m-dk bn slty JO%:SST-It-m bn20% MOST -dk gýlbn shaley 50%:MDST~m-dk bn slty 30%:SST-lt-m bn 20%:MDST -or Tr:QTZ-Tr MDST-dk gylbn shaley 75%:MDST-m-dk bn slty 20%:SST-lt-m bn 5%:MDST-orTr:QTZ-Tr MOST -dk gylbn shaley 90%:MDST -m-dk bn slty 5%:SST -It-m bn 5%:QTZ- Tr MOST -dk gylbn shaley 90%:MDST -m-dk bn slty 5%:SST-lt-m bn 5%:QTZ-Tr MDST-dk gy shaley 30%:SLTST-lt-m bn 60"1o:SST-It-m bn 10% MDST-dk gy shaley JO%:SLTST-It-m bn 6O%:SST-lt-m bn 5%:QTZ-5% MDST-dk gy shaley 70%:SLTST-lt-m bn mddy 30%:QTZ-Tr MDST-dk gy shaley 60"/o:SLTST-lt-m bn J5%:QTZ-5% MDST-dk: gy shaley 70%:SLTST-lt-m bn mddy 30% MOSt -dk gy shaley 60%:SL TST -It-m bn mddy 30%:QTZ-IO% MOST -dk gy shaley 30%:SLTST-lt-m bn mddy 70% MDST -dk gy shaley 50"/o:SL TST -It-m bn mddy 50% MDST-dk gy shaley 50%:SLTST-lt-m bn mddy 40%:MDST-m bnlor 5%:QTZ-5% MDST-dk gy shaley 55%:SLTST-lt-m bn mddy 40"/o:QTZ-5% MDST-dk gy shaley 80"1o:SLTST-lt-m bn mddy 1O%:SST-lt bn Tr:QTZ-IO"/o MDST-dIe gy shaley 70%:SLTST-lt-m bn mddy 30% - MDST -dk gy shaley 30"/o:SL TST -It-m bn mddy 40%:LST -It bn mddy 30% LST -dk gy mddy 40%:LST-lt gy 30%:SST-lt bnlgy 30% LST-dk gy mddy 85%:LST-bk oolitic wh cement Tr:LST-ltgy 15% --- N 0\ 7290 7380 7470 7560 7650 7740 7830 7920 8010 8100 8190 8280 8370 8460 8550 8640 8730 8820 8910 9000 9090 9180 9270 9360 9500 Þ-d ~ {JQ (1) \0 \0 o >-+:i PICKED LITHOLOGY LITHOLOGY FORMATION AGE DEPTH DEPTHRANGE It It o ~ (') t:1 pj ~ ~ :::0 (!) '""d o ;4. N 00 o Alaska W, Fish Creek-I LITHOLOGY AND STRATIGRAPHY TABLE 17 COUNTRY: WELL: · --~- -.----------_.- a ~ n t) PJ ~ PJ ?:' (t) '"d o ::¡ 1'-.) 00 o TABLE 18 OPTICAL SOURCE ROCK MATURITY INDICATORS COUNTRY Alaska WELL: W Fish Creek-I DEPTH (ft) FORMA nON VITRINITE NO. of CONFIDENCE COMMENTS (%Ro) READINGS 7290 8370 9500 0.61 20 D MOD;IPAR 100% VPAR+WPAR TR;BS MOD BW MOD;Amorphinite L-M.O.MOD ALG Y/O-L.O. Very 0.6 20 C L-MOD;IPAR 90% VW+WPAR 10%;BS MOD/STR BW MOD;Amorphinite M-D.O. RI ALG Y/O-L.O. T 0.92 6 D TR;IPAR 100% VPAR+WPAR TR;BS STR;Amorphinite M.O, L SP M-D.O. TR Confidence A=Excellent B=Good C=Average - D=Poor E=Unreliable I-c; PJ (fQ (t) o o o Þ-+¡ ........ N 0\ 1000 2000 3000 4000 4;: -=5. 5000 c¡, Q 6000 7000 8000 9000 10000 0,1 Vitrinite Reflectance Thermal Maturity Plot Well Name: West Fish Creek-1 o . . . , I 1 3 0/0 Ro GMC Data Report 280 Page 101 of f~re 25 ---.- ----- ------ ----------- -- . ~--------- --- -----~------------------ ----........--- 0 ~ n t) TABLE 19 ~ .-t- ~ ?;J SOURCE ROCK QUALITY INDICATORS (D 'ïJ 0 COUNTRY: Alaska ::¡. N WELL: W. Fish Creek-l 00 <=> DEPTH DEPTHRANGE FORMATION PICKED LITHOLOGY PI PI P2 TOC TMAX HI GOGI CARBT S (ft) (ft) (kg/t) (mg/gC) (kg/t) (%) degC (%) (%) 7290 Mudstone 1.39 101.4 1.83 1.37 445 134 11.33 0.90 7380 Mudstone 1.19 78.5 1.95 1.51 443 129 20.05 1.10 7470 Mudstone 0.79 48.1 1.72 1.65 443 104 8.32 0.78 7560 Mudstone 1.31 77.0 2.16 1.71 442 127 7.99 0.96 7650 Mudstone 1.14 71.8 1.93 1.58 443 122 9.37 0.70 7740 Mudstone 1.43 82.5 2.27 1.73 439 131 .8.96 0.90 7830 Mudstone 1.04 69.2 1.80 1.50 444 120 11.10 0.78 7920 Mudstone 0.00 0.0 0.84 1.39 445 60 7.87 0.83 8010 Mudstone 0.00 0.0 0.00 1.60 445 0 7.41 0.90 8100 Mudstone 0.89 57.8 1.85 1.54 445 121 7_78 0.91 8190 Mudstone 1.06 71.5 2.14 1.48 446 145 9.32 0.83 8280 Mudstone 0.96 66.4 1.98 1.44 445 137 9.08 0.72 8370 Mudstone 1.00 63.6 2.30 1.57 . 445 147 8.40 0.86 8460 Mudstone 0.89 56.9 2.10 1.56 447 135 8.54 0.73 8550 Mudstone 0.97 64.7 2.39 1.51 441 159 9.45 0.70 8640 Mudstone 0.95 63.9 2.31 1.49 445 155 9.63 0.69 8730 Mudstone 1.28 83.9 2.30 1.52 445 151 9.32 0.63 >-0 8820 Mudstone 1.14 71.3 2.59 1.60 442 162 9.49 0.53 PJ 8910 MudStone 0.97 64.8 2.18 {Jq 1.50 448 146 9.49 0.65 (D ....... 9000 Mudstone 1.81 84.4 2.97 2.15 450 138 8.25 1.03 <=> 9090 Mudstone 1.93 60.6 6.01 3.18 451 189 6.54 1.16 N 0 9180 Mudstone 1.31 48.8 4.47 2_68 446 167 7.93 0.86 ~ 9270 Mudstone 0.54 135.3 0.83 0.40 450 210 6.70 0.26 N 9360 Limestone 1.25 96.s- 2.00 1.29 489 155 75.50 0.56 0\ 9500 Limestone 1.77 63.2 3.20 2.79 452 115 38.42 1.82 G) S:':: () t) PJ .-+ PJ ~ (!) '""d o ::¡ N 00 o \Vell name: Suite name: Country Of Origin : Depth (m) : Sample name: W. Fish Creek-l NPRA Study Alaska 8550 Extraction TSE %wt: 0.1I1 HPLC Saturates %wt: Aromatics °/ewt : Residues %wt : Inspection Properties API: Density @ 15 deg C : Wax Content %wt : Wax Mdting Point deg C: Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOWg : Asphaltenes -/owt (IP Method) : 'Nitrogen ppm : Sulphur %wt : Nickel ppm : Vanadium ppm : NickelNanadium : Aspbaltenes (Micro Method) %wt : Saturates GC PristaneIPhytane : Pristane/nCl7 : Pbytane/nCl8 : CPI: ALKlND : R22 : Biomarker Ratios III : 0.59 SI: 0.51 M2: 0.74 112: 0.52 S2 : 0.51 M3: 0.66 113: 0.88 S3 : 34:19:46 M4: 88.54 114: 0 MS: 115: 100:73:42:28: 14:4 S4 : 33:21:45 0.47 43.62 AI: 0.84 116: S5 : 117: 0.62 A2: 0.85 S6: I¡;; U8: A3: 0.56 PJ S7 : 42.70 {JQ 119: A4: 035 (!) 11I0 : S8: 0.00 ~ A5: 036 0 1111: 0.78 S9 : \.H A6: 0.91 0 1112: 4.97 SIO: ~ IÍl3 : 0.00 MDR: 2.93 ~ N 11I4 : 15.01 MBP: 12.29 0\ 1115 : 0.00 1116 : 0.00 11I7 : 23.27 11I8 : 0.00 Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil : -26 . Aromatics : Residue: Asphaltenes : Kerogen : -23.6 STANDARD: NBsn -29.8 Table 20.1 __~_,. _ ~~__~_ ___._ _.." . ..~.___~_ .__.__"_ ."___...:.____..:.____... _ ,__.. .~_.,......----__._~______~=--~- ___.__--:=:--_~-.-~--'_--. ~_~=_:..-. _~_~_______=_::-~-------:~._:_-.~-_-~-___:__:::_-- :-:~_d __~_--_----..~__:._--.--.--___:___-~ ~- .'..' .-roo··m .~-_-._ Biomarker Ratios III: 0.58 SI : 0.53 M2: 0.74 112: 0.53 S2 : 0.44 M3: 0.66 113 : 0.88 M4: 85.61 114 : 0 S3 : 36:24:38 liS: 100:70:40:27: 14:4 S4: 33:23:42 M5: 116: 0.51 S5 : 37.44 AI: 0.85 117 : 0.60 S6: A2: 0.85 ~ 118: AJ : 0.53 pJ S7 : 48.80 (JQ H9: (1) A4: 0.35 ........ 1110 : S8: 0.00 C> AS: 0.31 ..p. 1111 : 0.69 S9 : A6: 0.95 0 1112 : 4.71 t-+¡ S10 : MDR: 2.71 ........ 1113: 0.00 N 1114 : 16.05 MBP: 11.61 0\ 11I5 : 0.00 11I6 : 0.00 1117: 23.25 1118: 0.00 o ~ n t:J pJ .,-+ pJ ïO (1) '""d o ~ N 00 C> SedimentÆxtract Analysis \\'ell name: Suite name: Country Of Origin : Depth (m) : Sample name: W. Fish Creek-I NPRA Study Alaska 8820 Extraction TSE %wt: 0.119 HPLC Saturates %wt: Aromatics %wt : Residues "¡'wt : Inspection Properties API: Density @ 15 deg C : Wal Content %wt : Wax Melting Point deg C : Pour Point deg C : Viscocity cSt @ 20 deg C : Total Acidity mg KOH/g : Asphaltenes %wf (IP Method) : Nitrogen ppm : Sulphur "/awf : Nickel ppm : Vanadium ppm : NickellVanadium : Asphaltenes (Micro Method) %wt : Saturates GC PristaneIPbytane : PristanelnCI7 : PhytanelnCI8 : CPI: ALKIND : R22: Light Hydrocarbons MCH % : HER HXR Stable Carbon Isotopes Saturates : Total Oil: -25.7 Aromatics : Residue: Aspbaltenes : Krrogen : -25.5 STANDARD: NBS22 -29.8 Table 20.2 . n· n " n II II n nit" " " II " " " " " "" II ø n II II IT " " " II UJI-'l u (!) õ Q) õ ~ o Lt) I() CO '""" ~ ~ U J:: en u: - en ~ I() ,... o (f) ~ o o w (f) co o "'" 0> I ¡ CTWr D?\~ 1~~rr)1?~P 000 o 0> CO ,... ) j o f'-. , 1 o <D ! ¡ o I() I o "I:t Ii..f, ¡ ì Ò C") Il?fg~: 1 ps. pf¡ 12,6 . o 0 N T""" JOI: ............. } ! ~ l f ~~ 5 j ",,-'f --,. ~ ~. -SÇ ~ ~ .~ ~ ~ ~ ~ ~-- .............. cn'- -- ~ ...& -~ ,........ 9~ ~ ~- : l 1 ~----::- ~~ -:~. ~ 1 Figure 26. r ~ L I I I I o - _0 ,..... -I() ..... - -I() N -~ ;- ,I() -I() ,... i- t to ¡--I() ~ ~ rl() -"I:t ~~ t ~ I() -C't) o -C't) ¡ ,GMC.Data . !' ,<" ( , I ; o Ò o 0) ~ u c.!) õ CD õ ~ I b N 00 00 ~ ~ Q) U .c. 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N (J\'T1 áQ' ¡:: ""1 C1I W o i-.J File:MPDMI00069~ #1-1291 Acq:24-SEP-199ï 12:40:3'l GC EI~ Voltage SIR 10SR Sample#4 Text:WEST FISH CREEK-l 8820' $9708SED008S018$ File Text:8000RP Exp:GCMS_HRSIR 168.0939 5:4 10 0?6 90-': - 80-': 70':' 60-': SO.:. 40": 30": 20-': 1~-= I - I , I I I J~ I ~ 10:00 12:00 198.0503 5:4 100% 90-': 80-': 70": 60-': 50": 40": 30-': 20':' 10-': 0: 10:00 _9.3E7 =-8.4E7 - =-7.5E7 =-6.5E7 - -:"'5.6E7 J v I , , , ' I 14:00 - :"4.7E7 :"3.7B7 :"2.8B7 :"'1.9E7 =-9.3B6 ~ ^ ~ - . - - ^ ,;. 0 . OEO I ï'J',~~;--- 26 : 00 28 : 00 30 : 00 Time --_.....-~ I I J ' I I , I J I I , 22:00 24:00 I I I , I , " '" I I I I ' , I 16:00 18:00 20:00 _2.3E7 :'2.0E7 :"'1.8E7 :"'1.6E7 :"1.4E7 =-1.1E7 =-9.126 =-6.8E6 , I I" I I I I , I t I I I I ' I , , I I I I , I I I I , I , I , I , I 12:00 14:00 16:00 18:00 20:00 22:00 "-' 0 '- I I I J I I I . I I ,- I 24:00 26:00 - :"'4.5E6 ~2.3E6 ('- F I"" I ~ y- I ,: 0 .OEO 28:00 30:00 Time lI"rr""""rrnn""lTnIlIIlIlIlLlI~ Appendix A Vitrinite reflectance Codes GMC Data Report 280 Page 119 of 126 -.---.-.- ---.---.----------..------- -.-- _.----~---- VITRINITE ABBREVIATIONS ANS . Anisotropic BAR . Virtually Barren BS . Bitumen Staining CARB - Carbargllite COR . Corroded DD . Differentiation Difficult DMA . Drilling Mud Additive F - Few FR - Fragments G - Good HI - High IGN . Igneous Traces IRON· Iron Oxides LGN - Lignite LT· Light M - Mostly NOP - No Determination Possible OBS Overall Bitumen Staining OX . Indications of Oxidation PAR - Particles PL - Plentiful or Plenty PY - Pyrite RES - Resin RM - Reworked Material S Some SH Shale SM L - Small STC - Structure SUB - Subordinate TEL - Telinitic V - Vitrinite VL - Very Low Organic Content VST - Vitrinite Stringers W - Wisps or 'Nispy Allocthonous ? - Questionable B - Bitumen BL . Bleb's BW . Bitumen Wisps CA V - Caved CTGS· Cuttings DEC Decomposed DOM Dominant FL . Fluorescence GN - Gnarled HAE - Haematite I . Inertinite INST Interstitial L . Low LOW Low Reflectances MAT Maturity MOD Moderate NTV - No True Vitrinite oce Occasional P - Poor PHY . Phytoclast content POS Possibly R - Reworked RI . Rich RO - Reflectance Measurement se - Scruffy , SL T - Siltstone '. SPE . Specks STR - Strongly T8 - Turbo-drilled TR . Trace V AR - Variable RO VL T - Very Light VW - Vitrinite Wisps WH - Wholly = Equal Proportions SPORE FLUORESCENCE COLOURS UNDER ULTRAVIOLET LIGHT G - Green o - Orange L T - Light D - Deep ALG Algae HYD - Hydrocarbon RH - Rhombs Y - Yellow R - Red M - Mid P - Pale CAR - Carbonate RES - Resin SP - Spores GMC Data Report 280 Page 120 of 126 --.,---....-----------..---.-- --~_._--_._._------------ --_"0_- Appendix B Molecular Parameters List GMC Data Report 280 Page 121 of 126 --- LGC CODE Hl H2 H3 H4 HS H6 H7 H8 H9 H10 Hll H12 H13 H14 H15 H16 H17 H18 Sl S2 83. S4 S5 S6 S7 S8 89 S10 Al A2 A3 A4 AS A6 M2 M3 MBP MDR M4 ALKIND R22 . NOTES: l. 2. ~OT.~CU'I'.A~ PJ\.~T~R T·¡ST PARAMETER C32 HOPANE 22S/(22S+22R) C31 HOPANE 22S/(22S+22R) C30 HOPANE/(C30 HOPANE+C30 MORETANE) ßß HOPANES PRESENT/ABSENT C30:C31:C32:C33:C34:C35 HOPANE DISTRIBUTION C27 HOPANES Ts/(Ts+Tm) C33 HOPANE 22S/(22S+22R) C34 HOPANE 22S/(22S+22R) C35 HOPANE 22S/(22S+22R) RESIN DITERPANES % RELATIVE TO C30 HOPANE (PEAK G) C23 EXT TRICYCLIC TERPANE % RELATIVE TO C30 HOPANE (PEAK G) C24 TETRACYCLIC TERPANE % RELATIVE TO C30 HOPANE (PEAK G) 28,30 BISNORHOPANE (PEAK X) % RELATIVE TO C30 HOPANE (PEAK G) PENTACYCLANE n % RELATIVE TO C30 HOPANE (PEAK G) OLEANANE % RELATIVE TO C30 HOPANE (PEAK G) GAMMACERANE % RELATIVE TO (PEAK G) HOPANES C3S/(C34+C3S) % 25-NORHOPANE/C30 HOPANE % C29 aaa STERANES 20S/(20S+20R) C29 STERANES aßß/(aßß+aaa) STERANES aaa C27:C28:C29 STERANES aßß C27:C28:C29 ßa DIASTERANES/(SAME+aaa+aßß STERANES) % LOW MOLECULAR WEIGHT STERANES RELATIVE TO C29 STERANES STERANE INDEX C27/(C27+C29) % (FROM S3) 4-ME C30 STERANE % RELATIVE TO C29 20R aaa STERANE (PEAK 42) 4-ME STERANES INDEX C28/(C28+C30) % BICADINANES PRESENT/ABSENT C28 20R TRIAROM. STERANE/(SAME+C29 20R MONOAROM. STERANE) SUM TRIAROM. STERANES/(SAME+SUM MONOAROM. STERANES) C20 TRIAROM. STERANE/(SAME+C28 20R TRIAROM. STERANE) C20+C21 TRIAROM. STERANE/(SAME+SUM C26-C28 TRIAROM. STERANES) C26 20S TRIAROM. STERANE/c28 208 TRIAROM. STERANE C27 20R TRIAROM. STERANE/C28 20R TRIAROM. STERANE PHENANTHRENES (3ME+2ME) I (9ME+1ME) MPI [(3ME+2ME)/(PHENANTHRENE+9ME+1ME)] * 1.5 3-METHYL BIPHENYL/2-METHYL BIPHENYL 4-METHYLDIBENZOTHIOPHENE/l-METHYLDIBENZOTHIOPHENE 8UM C27-C3S HOPANES/(SAME+ SUM C27-C29 STERANES) % ALKANE INDEX n-C17/(n-C17+n-C27) % R22 INDEX (2 * n-C22)/(n-C21+n-C23) 8=SOURCE PARAMETER, M=MATURITY PARAMETER. TRIAROM. STERANE=MONOMETHYL TRIAROMATIC STERANES MONOAROM. STERANE=DIMETHYL MONOAROMATIC STERANES. (13/11/92 ) GMC Data Report 280 Page 122 of 126 USE M M MS M S M8 M M M S 8 S S 8 S 8 8 B M M 8 8 8M 8 S 8 S S M M M M 8 8 M M M M 8 8 8M Appendix C Biomarker Identifications GMC Data Report 280 Page 123 of 126 LGC CODE I Ts Tm Q W X Y D D2 7t A B G H K N o S P R U V J a ß L Y 8 E ç BIO~~KRR TD~NTIFICATTÒ~ - PENTACYCLIC HYDROCARBONS TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 191) 9-DODECYLPERHYDROANTHRACENE [INTERNAL STANDARD] 18a(H)-22,29,30-TRISNORNEOHOPANE 17A(H)-22,29,30-TRISNORHOPANE 17ß(H)-22,29,30-TRISNORHOPANE 17A(H)-25,30-BISNORHOPANE 17a(H) ,18a(H) ,21ß(H)-28,30-BISNORHOPANE 17a(H)-25-NORHOPANE 17a(H) ,21ß(H)-30-NORHOPANE 18a(H)-30-NORNEOHOPANE 17a (H) ,lSa (Me) -27-NORHOPANE ("DIAHOPANE") 17ß(H) ,21a(H)-30-NORMORETANE 18a(H)-OLEANANE 17a(H) ,21ß(H)-HOPANE 17ß(H) ,21ß(H)-30-NORHOPANE 17ß(H) ,21a(H)-MORETANE (22S)-17a(H) ,21ß(H)-30-METHYLHOPANE (22R)-17a(H) ,21ß(H)-30-METHYLHOPANE GAMMACERANE 17ß(H) ,21ß(H)-HOPANE 17ß(H) ,21a(H)-30-METHYLMORETANE (22S) -17a(H) ,21ß(H)-30-ETHYLHOPANE (22R)-17a(H) ,21ß(H)-30-ETHYLHOPANE 17ß(H) ,21ß(H)-METHYLHOPANE (22S)-17a(H) ,21ß(H)-30-n-PROPYLHOPANE (22R)-17a(H) ,21ß(H)-30-n-PROPYLHOPANE 17ß(H) ,21ß(H)-ETHYLHOPANE (22S)-17a(H) ,21ß(H)-30·n-BUTYLHOPANE (22R) -17a(H) ,21ß(H) ·30-n-BUTYLHOPANE (22S)-17a(H) ,21ß(H)-30-n-PENTYLHOPANE (22R)-17a(H) ,21ß(H)-30-n-PENTYLHOPANE GMC Data Report 280 -------- ------..- Page 124 of 126 ~rO~ð~KR~ r~ENTIFrCATION - STERANES 11:I -= -= II:: 8: It: It: .. It: It: It: -= II:: II: It: B: II: II:: II:: It: II:: It: a: II:: II: II: IC -= &: II: II:: II:: -= II:: LGC CODE TENTATIVE ASSIGNMENT EASED ON MASS SPECTROMETRY (m!e 217) 10 (20S)-13ß{H) ,17a{H)-DIACHOLESTANE 11 (20R)-13ß(H) ,17a(H)-DIACHOLESTANE 13 (20S)-13a(H) ,17ß(H)-DIACHOLESTANE 14 (20R)-13a(H) ,17ß(H)-DIACHOLESTANE 15 (24S!R)-(20S)-13ß(H) ,17a(H)-24-METHYLDIACHOLESTANE 16 (24S!R)-(20S)-13ß(H) ,17a(H)-24-METHYLDIACHOLESTANE 18 (24S!R)-(20R)-13ß(H) ,17a(H)-24-METHYLDIACHOLESTANE 19 (24R!S)- (20R)-13ß(H) ,17a(H)-24-METHYLDIACHOLESTANE 20A (24S!R)-(20S)-13a(H),17ß(H)-24-METHYLDIACHOLESTANE 20B (20S)-sa(H) ,14a(H) ,17a(H)-CHOLESTANE 21A (24R+S)-(20S)-13ß(H),17a(H)-24-ETHYLDIACHOLESTANE 21B (20R) -Sa (H) ,14ß (H) ,17ß (H) -ISOCHOLESTANE 22 (20S)-sa(H) ,14ß(H) ,17ß(H)-ISOCHOLESTANE 25 (20R) -Sa (H) ,14a (H) ,17a (H) -CHOLESTANE 27 (24S+R)-(20R)-13ß(H) ,17a(H)-24-ETHYLDIACHOLESTANE 29 (24S+R)-(20S)-13a(H) ,17ß(H)-24-ETHYLDIACHOLESTANE 33A (24S+R)-(20R)-Sa(H) ,14ß(H)17ß(H)-24-METHYLISOCHOLESTANE 33B (24S+R)- (20R)-13a(H) ,17ß(H)-24-ETHYLDIACHOLESTANE 34 (24S+R)-(20S)-sa(H) ,14ß(H) ,17ß(H)-24-METHYLISOCHOLESTANE 36 (24S+R)- (20R)·5a(H) ,14a(H) ,17a(H)-24-METHYLCHOLESTANE 39 (24S+R)- (20S)-Sa(H) ,14a(H) ,17a(H)-24-ETHYLCHOLESTANE 40 (24S+R)-(20S)-Sa(H) ,14ß(H) ,17ß(H)-24-ETHYLISOCHOLESTANE 41 (24S+R)- (20R)-sa(H) ,14ß(H) ,17ß(H)-24-ETHYLISOCHOLESTANE 42 (24S+R)- (20R)-sa(H) ,14a(H) ,17a(H)-24-ETHYLCHOLESTANE 46 (24S+R) - (20R) C30 STERANE GMC Data Report 280 Page 125 of 126 ---" --~----- --.-."--- --- -.-..- BIQM~K~R rD~NTIFTCATTON - AROMATIC STEROIDAL HYDROCARBONS (AROMATIC STERANES) LGC CODE TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 253 mass fragmentogram) F22 F23 F2 F3 F4 FS F6 F7 F8 F9 F10 F11 F12 F13 C21 DIMETHYL MONOAROMATIC STEROID C22 DIMETHYL MONOAROMATIC STEROID C27(20S) Sß(H) DIMETHYL MONOAROMATIC STEROID C27(20R)sß(H)DIMETHYL MONOAROMATIC STEROID C27(20S) Sa (H) DIMETHYL MONOAROMATIC STEROID C2s(20S)sß(H)DIMETHYL MONOAROMATIC STEROID C27(20R) Sa (H) DIMETHYL MONOAROMATIC STEROID C2s(20S)sa(H)DIMETHYL MONOAROMATIC STEROID C2S(20R)sß(H)DIMETHYL MONOAROMATIC STEROID C29(20S)5ß(H)DIMETHYL MONOAROMATIC STEROID C29(20S)sa(H)DIMETHYL MONOAROMATIC STEROID C2S(20R) Sa (H) DIMETHYL MONOAROMATIC STEROID C29(20R)sß(H)DIMETHYL MONOAROMATIC STEROID C29(20R) Sa (H) DIMETHYL MONOAROMATIC STEROID (m/e 231 mass fragmentogram) F14 F15 F16 F17 F18 F19 F20 F21 C20METHYL TRIAROMATIC STEROID C21METHYL TRIAROMATIC STEROID C26(20S)METHYL TRIAROMATIC STEROID C26(20R)METHYL TRIAROMATIC STEROID C27(20S)METHYL TRIAROMATIC STEROID C2s(20S)METHYL TRIAROMATIC STEROID C27(20R)METHYL TRIAROMATIC STEROID C2S(20R)METHYL TRIAROMATIC STEROID BIO~~~K~R ID~NTrFrCATro~ - NORHOPANES LGC CODE TENTATIVE ASSIGNMENT BASED ON MASS SPECTROMETRY (m/e 177) W 17a(H)-2S,30-BISNORHOPANE Y 17a(H)-25-NORHOPANE D 17a(H) ,21ß(H)-30-NORHOPANE C1 (22S)-17a(H)-25-NOR-30·METHYLHOPANE G 17a(H) ,21ß(H)HOPANE C2 (22R)-17a(H)-25-NOR-30-METHYLHOPANE C3 (22S)-17a(H)-2S-NOR-30-ETHYLHOPANE C4 (22R) -17a(H)-2s-NOR-30-ETHYLHOPANE C5 (22S)-17a(H)-25-NOR-30-n-PROPYLHOPANE C6 (22R)-17a(H)-25-NOR-30-n-PROPYLHOPANE C7 (22S)-17a(H)-25-NOR-30-n-BUTYLHOPANE C8 (22R)-17a(H)-25-NOR-30-n-BUTYLHOPANE C9 (22S)-17a(H)-2S-NOR-30-n-PENTYLHOPANE C10 (22R)-17a(H)-25-NOR-30-n-PENTYLHOPANE GMC Data Report 280 Page 126 of 126 ------- -------- .------ _._._...._-_._~~-