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GMC Data Report No. 287
TOC, Rock-Eval, vitrinite reflectance, and gas chromatography of cuttings from the following: Chevron USA Inc. Jeanette Island No.1 (9,850' - 11,200'), Chevron USA Inc. Karluk No.1 (8,900' - 10,400'), Exxon Company U.S.A. OCS Y-0191-1 [BF-37-01] (8,400' - 9,360'), and Husky Oil NPR Operations (U. S. Geological Survey) Ikpikpuk T. W. No.1 (6,000' - 10,500'). ¡:f,~~NT 01= l:~ .....<?- .I¡i\ * ;If ~¿ Q:' . ~ ¿j'*~", ,~~ , -a ~. ",... 0 ~ ::JO ~:f. *~*p;.;::.~ . oS' -to: * .~ 'G ~v 4$'OLOG\C~\" ~ -..,;." <;J.~ ~,-#.. ,.....;"þ.... ~ ~ . Received 23 Marchl999. Total of 61 pages in report. Alaska Geologic Materials Center Data Report No. 287 I { ',y ,] -'. . ...J l .J ] l J ] 1 1· 1 OC$ Y 1'1-1 ~ BF-37-01, Karluk #1 Jeanette #1 and Ikpikt-01 I kf /k¡J'l k 7. t/. -11 I /'/ ....~''''' ! .{.I 1.......,...." GMCData Report 287 Page 1 of61 - . . r' ___ ~.,(, ~ .. ,_ __J ~ I d . AI On r_rL~__~L-~__~__~~H~~_J~~~ ,~ ~ -~ ~ -- ..----.J _____J ~_I i-":_~I à. __ J ;i _ Q ~ ·n t:1 TSE Data p:> .-t- p:> 10 Client 10 Depth labld Sample Wt. TSE Wt. %TSE KGlTon (t) '"0 (ft) (WFXXXX) (gms) (mgs) _ TSE 0 ::4- tv Ikpikt-01 6000-100 9126 43.781 15.2 0.0347 00 0.347 -1 Ikpikt-01 6600-700 9127 62.37 14.4 0.023 0.23 Ikpikt-01 6700-900 9128 93.827 28.4 0.0302 ' 0.302 BF-37-01 8400-550 9162 19.020 11.6 0.0609 0.609 BF-37 -01 8550-800 9163 51.408 26.3 0.0511 0.511 BF-37 -01 9090-360 9164 42.554 16.9 0.0397 ' 0.397 Karluk #1 8900-150 9165 17.369 21.4 0.1232 1.232 Karluk #1 10200-400 9166 11.578 9.1 0.0786 0.786 Jeanette #1 9850-10150 9167 54.057 51.2 0.0947 0.947 Jeanette #1 10850-11200 9168 60.935 36.8 0.0603 0.603 SARA Data Client 10 Depth _ Labld Saturate % Aromatic % Polar % Asph. % (ft) (WFXXXX) Ikpikt-01 6000-100 9126 44.9 24.0 24.0 7.1 Ikpikt-01 6600-700 9127 44.3 29.4 23.3 3.0 Ikpikt-01 6700-900 9128 38.6 32.2 24.4 4.9 t¡j BF-37-01 8400-550 " 9162 62.1 9.3 26.4 2.2 ~ (JQ BF-37 -01 8550-800 9163 67.5 12.5 19.5 0.5 (t) N BF-37 -01 9090-360 9164 68.9 8.6 21.7 0.9 0 Karluk #1 8900-150 9165 63.1 13.7 22.6 0.7 H") 0'\ Karluk #1 10200-400 9166 44.3 9.9 44.2 1.6 ~ Jeanette #1 9850-10150 9167 53.0 19.6 27.1 0.3 Jeanette #1 10850-11200 9168 60.5 17.2 22.0 0.4 WESTPORT TECHNOLOGY CENTER INTERNATIONAL - ~ ,. ,. ~ ~ . ~ . . . . . ~ . -- -- II --. I \ i . , i '. j -- .. ì .. Î iii __ - L, -__j ~__ __I .__J t---Î '---ì 1_ o ~ () t:1 p:> -- p:> .10 ,(t) "'0 o ::4- tv 00 --...) Ikpikt-01 Kerogen' Isotope Data " Client 10 Depth Labld Whole Kerogen (ft) (WFXXXX) õ13C(%o) õ13C(%o) Ikpikt-01 8300-400 9140 -27.88 -27.17 Ikpikt-01 8400-500 9141 -27.1 Ikpikt-01 8500-600 9142 -26.63 Ikpikt-01 8600-700 -9143 -26.91 Ikpikt-01 8700-800 9144 -26.55 Ikpikt-01 8800-900 9145 -26.92 I kpikt-O 1 8900-9000 9146 -28.37 -28.04 Ikpikt-01 9000-100 9147 -27.74 Ikpikt-01 9100-200 9148 -27.47 Ikpikt-01 9200-300 9149 -27.43 Ikpikt-01 9300-400 9150 -27.47 -28.01 Ikpikt-01 9700-800 9154 -28.23 -28.88 Ikpikt-01 9900-10000 9156 -27.97 -27.98 Þ-tj Ikpikt-01 10200-300 9159 -26.63 -29.02 p:> ~ (t) v..> 0 ~ 0\ -... WESTPORT TECHNOLOGY CENTER INTERNATIONAL L-.J L-J w u u l! , L.J rL.-J ~~Ii""""r--,....,--,--,-.,--,-, L-J L-.J íi-J L-J -L-J L-J L....J L-J L-J L-i L-J L-.J Q ~ (') Ikpikt-01 RockEvallTOC and Carbonate Data t) p:> .-I- p:> ~ Client aD Depth SAMPLE ID (t) "0 0 (ft) (WFXXXX) TOC S1 S2 S3 TMAX HI 01 52/53 PI %C03 °Ic.C* ::¡ N 00 Ikpikt-01 7200-300 9129 1.68 0.23 2.01 0.45 439 120 27 4.47 0.10 84.93 10.1gJ Ikpikt-01 7300-400 9130 1.77 0.21 1.83 0.41 441 103 23 4.46 0.10 84.95 10.19 Ikpikt-01 7400-500 9131 1.32 0.21 1.03 0.33 444 78 25 3.12 0.17 86.40 10.37 Ikpikt-01 7500-600 9132 2.01 0.38 2.25 0.45 443 112 22 5.00 0.14 89.27 10.71 Ikpikt-01 - 7600-700 9133 1.85 0.40 2.17 0.56 443 117 30 3.88 0.16 88.59 10.63 Ikpikt-01 7700-800 9134 1.51 0.36 1.69 0.55 443 112 36 3.07 0.18 87.56 10.5~ Ikpikt-01 7800-900 9135 1.49 0.31 1.43 0.54 447 96 36 2.65 0.18 88.53 10.ð?J Ikpikt-01 7900-8000 9136 1.50 0.35 1.33 0.73 447 89 49 1.82 0.21 88.99 1 0.6~ Ikpikt-01 8000-100 9137 1.08 0.23 0.68 0.54 445 63 50 1.26 0.25 85.10 10.2~ Ikpikt-01 8100-200 9138 1.04 0.21 0.81 0.37 446 78 36 2.19 0.21 88.93 10.6~ Ikpikt-01 8200-300 9139 1.12 0.22 0.76 0.45 448 68 40 1.69 0.22 87.15 10.46 Ikpikt-01 8300-400 9140 1.70 0.54 4.58 0.58 423 269 - 34 7.90 0.11 85.53 10.26 Ikpikt-01 8400-500 9141 14.61 4.86 92.68 2.56 426 634 18 36.20 0.05 89.28 10.71 Ikpikt-01 8500-600 9142 3.19 1.24 14.22 0.57 424 446 18 24.95 0.08 83.94 10.07 Ikpikt-01 8600-700 9143 2.66 0.89 9.06 0.84 426 341 32 10.79 0.09 88.79 10.65 Ikpikt-01 8700-800 9144 1.70 0.60 3.30 0.57 436 194 34 5.79 0.15 - 90.00 10.80 Ikpikt-01 8800-900 9145 3.35 1.21 13.81 0.69 424 412 21 20.01 0.08 88.03 10.56 Ikpikt-01 8900-9000 9146 . 3.40 1.23 14.26 0.53 426 419 16 26.91 0.08 89.71 10.77 Ikpikt-01 9000-100 9147 2.33 1.11 10.16 0.58 421 436 25 17.52 0.10 91.27 10.95 Ikpikt-01 9100-200 9148 1.77 0.83 6.43 0.59 420 363 33 . 10.90 0.11 87.77 10.53 Ikpikt-01 9200-300 9149 1.39 0.54 3.17 0.59 423 - 228 42 5.37 0.15 88.28 10.59 Ikpikt-01 9300-400 9150 1.74 0.59 3.95 0.70 431 227 40 5.64 0.13 90.47 10.86 Ikpikt-01 9400-500 9151 1.33 0.41 1.32 0.36 452 99 27 3.67 0.24 90.52 10.86 Ikpikt-01 9500-600 9152 1.30 0.46 1.64 0.39 445 126 30 4.21 0.22 90.46 10.86 Ikpikt-01 9600-700 9153 1.10 0.31 0.97 0.61 454 88 55 1.59 0.24 90.86 10.90 WESTPORT TECHNOLOGY CENTER INTERNATIONAL u r L..J f L-J u , r-- ~ ~ r-- ~ ~ ~ ...., ~ -., ...., ~ .., I L.JL-JL-JL.JL-JL-JL-JL-JL..JL...JL-.jL-JL....lt--1~ C1 ~ (") t:1 p:> .-+- p:> ~ (t) '"0 0 ::¡ tv 00 Ikpikt-01 RockEvallTOC and Carbonate Data --J Client ID Depth SAMPLE 10 (ft) (WFXXXX) TOC 81 S2 53 TMAX HI 01 S2IS3 PI %C03 %.C* Ikpikt-01 9700-800 9154 1.61 0.60 3.99 0.53 423 248 33 7.53 0.13 87.98 10.56 Ikpikt-01 9800-900 9155 0.93 0.41 0.90. 0.25 438 97 27 3.60 0.31 90.89 10.91 Ikpikt-01 9900-10000 9156 1.42 1.36 4.10 1.60 427 289 113 2.56 0.25 71.40 8.57 Ikpikt-01 10000-100 9157 0.92 0.50 1.97 0.62 429 214 67 3.18 0.20 87. 16 10.46 Ikpikt-01 10100-200 9158 1.08 0.40 1.33 0.55 433 123 51 2.42 0.23 61.68 7.40 Ikpikt-01 10200-300 9159 6.18 3.10 4.96 0.36 468 80 6 13.78 0.38 41.62 4.99 Ikpikt-01 10300-400 9160 0.85 0.38 0.78 0.37 436 92 44 2.11 0.33 54.43 6.53 Ikpikt-01 10400-500 9161 1.25 0.28 0.93 0.67 427 74 54 1.39 0.23 83.24 9.99 T9C = weight percent organic carbon HI 51,82 = mg hydrocarbon/g rock 01 83 = mg carbon dioxide/g rock PI Tmax = Degree C ""d PJ .. ~sumes 12% Carbon in Calcium Carbonate only VI o H) 0\ Þ--' = 52*100rrOC = 53*100rrOC = 81/(81+82) WE5TPORT TECHNOLOGY CENTER INTERNATIONAL '---.-1 L.J L-J '--.J L-J. L-J iL-J It-.-J õL--.J ii--J ~ "'---' iCJ '~ () t:I p:> ....... ~ TSE Data Phase 2 Ikpikt-01 ~ (t) Þ-tJ 0 Client ID Depth Labld Sample Wt. TSE Wt. %TSE KGlTon ::¡ N (ft) , (WFXXXX) (gms) (mgs) TSE 00 -..) I kpikt #1 6000-100 9126 43.781 15.2 0.0347 0.347 Ikpikt #1 6600-700 9127 62.37 14.4 0.023 0.23 I kpikt #1 6700-900 9128 93.827 28.4 0.0302 0.302 Ikpikt #1 8200-300 9139 44.8641 24.6 0.548 5.483 I kpikt #1 8300-400 9140 49.9036 227.0 4.549 45.488 I kpikt #1 8400-500 9141 41.3903 2904.4 70.171 701.710 I kpikt #1 8500-600 9142 38.2165 429.6 11.241 112.412 Ikpikt #1 8600-700 9143 30.1832 220.9 7.319 73.186 I kpikt #1 8100-800 9144 26.2627 72.9 2.776 27.758 Ikpikt #1 8800-900 9145 26.9829 476.2 17.648 176.482 Ikpikt #1 8900-9000 - 9146 26.6080 285.3 10.722 107.223 Ikpikt #1 9000-100 9147 24.0706 218.1 9.061 90.608 I kpikt #1 9100-200 9148 21.7971 119.0 5.459 54.594 I kpikt #1 9300-400 9150 23.4710 66.6 2.838 28.375 I kpikt #1 9700-800 9154 27.6599 69.6 2.516 25.163 Ikpikt #1 900-1000 9156 17.3919 97.6 5.612 56.118 Ikpikt #1 10200-300 9159 26.2053 112.1 4.278 42.778 BF-37-01 8400-550 9162 19.020 11.6 0.0609 0.609 BF-37 -01 8550-800 9163 51.408 26.3 0.0511 0.511 BF-37 -01 9090-360 9164 42.554 16.9 0.0397 0.397 ~ Karluk #1 8900-150 9165 17.369 21.4 0.1232 1.232 p:> (JQ Karluk #1 10200-400 9166 11.578 9.1 0.0786 0.786 (t) 0\ Jeanette #1 850-1015 9167 54.057 51.2 0.0947 0.947 0 H) Jeanette #1 0850-1120 9168 60.935 36.8 0.0603 0.603 0\ ......... WESTPORT TECHNOLOGY CENTER INTERNATIONAL ,"--p---' ,"---1 Ie---J 1L-----1 <J... .J ;.¡ ,-' n.J ¡J. _ J .. _ J oJ, _ J J Q ~ 0 t) p:> . .-+ p:> ~ (1) "d .0 ::¡. N SARA Data 00 -...) Client ID Depth Labld Saturate % Aromatic 0¡ó Polar % Asph. % (ft). . (WFXXXX) Ikpikt #1 6000-100 9126 44.9 24.0 24.0_ 7.1 Ikpikt #1 6600-700 9127 44.3 29.4 23.3 3.0 Ikpikt #1 6700-900 9128 38.6 32.2 24.4 4.9 Ikpikt #1 8300-400 9140 50.7 16.0 10.5 22.7 Ikpikt #1 8900-9000 9146 40.9 13.0 8.8 37.2 I kpikt #1 9300-400 9150 53.3 16.8 15.2 14.7 Ikpikt #1 9700-800 9154 58.9 17.0 16.3 7.8 Ikpikt #1 9900-10000 9156 61.2 20.5 14.0 4.3 Ikpikt #1 10200-300 9159 51.9 33.3 13.6 1.2 BF-37 -01 8400-550 9162 62.1 9.3 26.4 2.2 BF-37 -01 8550-800 9163 67.5 12.5 19.5 0.5 BF-37-01 9090-360 9164 68.9 8.6 21.7 0.9 Karfuk #1 8900-150 9165 63.1 13.7 22.6 0.7 Karfuk #1 10200-400 9166 44.3 9.9 44.2 1.6 Jeanette #1 9850-10150 9167 53.0 19.6 27.1 0.3 r-o Jeanette #1 10850-11200 9168 60.5 17.2 22.0 0.4 p:> (JQ (t) -1 0 HJ 0\ WESTPORT TECHNOLOGY CENTER INTERNATIONAL ~ .J J .1 -JII JII~ ~ ~JI ~u·Jlu-L ·u·L ~ ~ ~~ ~ ~I c:;J ~ () t:j Ikpikt-01, BF-37 -01 ,Karluk-1, Jeanette-1 RockEvallTOC of Extracted Samples ~ ~ ïO (t) "'d 0 Client 10 Depth SAMPLE 10 TOC ANO ROCK-EVAl DATA INTERPRETIVE RA TI08 ~ N (ft) (WFXXXX) TOC 81 S2 83 TMAX HI 01 82183 PI 00 -1 Ikpikt -01 6000-100 9126 0.99 0.09 0.61 0.75 438 62 76 0.81 0.13 Ikpikt -01 6600-700 9127 1.12 0.08 0.63 0.72 435 56 64 0.88 0.11 I kpikt -01 6700-900 9128 1.06 0.07 0.61 0.66 438 58 62 0.92 0.10 Ikpikt-01 8200-300 9139 0.98 0.10 0.71 0.46 448 72 47 1.54 0.12 Ikpikt-01 8300-400 9140 1.21 0.12 1.49 0.50 440 123 41 2.98 0.07 Ikpikt-01 8400-500 9141 1.30 0.23 2.29 0.41 439 176 32 5.59 0.09 I kpikt-O 1 8500-600 9142 1.42 0.19 2.20 0.43 440 155 30 5.12 0.08 Ikpikt-01 8600-700 9143 1.70 0.21 2.85 0.80 442 168 47 3.56 0.07 Ikpikt-01 8700-800 9144 1.50 0.14 1.76 0.46 446 117 31 3.83 0.07 Ikpikt-O 1 8800-900 9145 1.80 0.25 2.81 0.61 440 156 34 4.61 0.08 Ikpikt-01 8900-9000 9146 1.66 0.33 2.72 0.43 446 164 26 6.33 0.11 Ikpikt-01 9000-100 9147 1.38 0.21 2.19 0.43 442 159 31 5.09 0.09 Ikpikt-01 9100-200 9148 1.03 0.16 1.54 0.44 436 150 43 3.50 0.09 BF-37-01 8400-550 9162 1.28 0.07 0.66 1.99 434 52 155 0.33 0.10 BF-37-01 8550-800 9163 0.98 0.08 0.53 0.96 434 54 98 0.55 0.13 BF-37 -01 9090-360 9164 0.90 0.08 0.38 1.04 428* 42 116 0.37 0.17 Karluk #1 8900-150 9165 2.01 0.14 1.24 1.87 434 62 93 0.66 0.10 ~ Karluk #1 10200-400 9166 1.45 0.10 0.62 1.89 438 43 130 0.33 0.14 ~ ~ Jeanette #1 9850-10150 9167 2.83 0.17 1.91 2.32 438 67 82 0.82 0.08 00 Jeanette #1 10850-11200 9168 1.71 0.17 1.12 1.08 438 65 63 1.04 0.13 0 H) 0'\ TOe = weight percent organic carbon HI = S2*1001T0e 81,82 = mg hydrocarbon/g rock 01 = 83*100rrOC 83 = mg carbon dioxide/g rock PI = S1/(81 +S2) Tmax = Degree e * Tmax data not reliable due to low kerpgen 82 value J J J J ~] ] ,J 'i] . ' ] Vitrinite Reflectance Report Attached are vitrinite reflectance histograms for samples WF9132, 9141,9146 and 9159. Reflectance ranges from 0.63 to 0.88 Ro and placing those samples in the ,early to peak oil generation stage. J J ] ] ] ] ] ] ] ] GMC Data Report 287 . Page 9 of 61 ï-J ..J .J .-J .J .-J I:·"J ..J .-J ... -j ."J I':J ...~ IL- .' ,J "-J' ~~ LJ LJ ¡ L~ , J L¡ I J Sample ID: WF9132 Mean depth: 100 Sample type: CUTTINGS I Immature/' Oil zone / Gas zone [ill fndigenous 20--------------·1~---------------------------------------------------------------. i::::::: :::;:;:; i~~f¡~ i:;:i:;: :::¡:~:: 'I'I' ÞJi'r3¡ 1'1'1"'1'.1'1'1'1'1'1'1'1" (1'111'1' 0.50 \ 1.00 1.50 2.00 2.50 Vitrinite Reflectance Ro % . ,.... " Indigenous population statistics 1:··Meari::Ò:6~·:::1 Min: 0.55 Max: 0.71 Std. Dev.: 0.04 Count: 56 Total population statistics Mean: 0.63 Min: 0.5.5 Max: 0.71 Std. Dev.: 0.04 Count: 56 01 - 0.55 < 02 - 0.56 < 03 - 0.57 < 04 - 0.5 7 < 05-0.57< 06 - 0.57 < 07 - 0.58 < 08 - 0.58 < 09 - o.s 8 < 10-0.59< 11 - 0.59 < 12 - 0.59 < 13 - 0.60 < 14 - 0.60 < 15 - 0.60 < 16 - 0.60 < 17 - 0.60 < 18-0.61< 19-0.61< 20-0.61< GMC Data Report 287 41-0.G6< 42 - 0.67 < 43 - 0.67 < 44 - 0.68 < 45-0.68< 46 - 0.68 < 47 - 0,69 < 48 - 0.69 < 49 - 0.70 < 50 - 0.70 < 51 - 0.70 < 52 - 0.70 < 53 - 0.70 < 54 - 0.70 < 55 - 0.71 < 56 - 0.71 < 21-0.61< 22.. 0.62 < 23 .. 0.62 < 24 .. 0.62 < 25 - 0.62 < 26 - 0.62 < 27 .. 0.63 < 28 .. 0.63 < 29 - 0.63 < 30.. 0.63 < 31 - 0.63 < 32 - 0.64 < 33 - 0.64 < 34 - 0.64 < 35 -0.65 < 36- 0.65 < 37 - 0.65 < 38 - 0.65 < 39.. 0.66 < 40 - 0.66 < Note: Refledacoe values COtmded to nearest hW1dredth, [< J indicates indigenous reflectance value Page 10 of 61 . r] r] r] r] r] ] r 1..1 r] [J [J .'J L\: 5 ~ I Sample ID: WF9141 Mean depth: 100 Sample type: CUTTINGS I Immature/" / . Gas zone Oi 1 zone [ill Indigenous 20--------------------------------------------------------------------------------. 15--------------------------------------------------------------------------------. 10---------------------------~----------------------------------------------------. :::::;:: s-----------IIÎlïtlll1t~~-------------------------------------------------------- 1 I I I I I I I I I I I I ' I I I I I I I I I I I I I I I I I I I I I I I I o . 50 1 .00 1. 50 2.00 2 . 50 Vitrinite Reflectance ~ % I ".' ',', .,., Indigenous population statistics !'.::Mêåíi:::~.64':;·1 Min: 0.50 Max: 0.79 Std. Dev.: 0.09 Count: 30 Total population statistics Mean: 0.67 Min: 0.50 Max: 0.89 Std. Dev.: 0.11 Count: 35 01 w OjO < 02 - Oj1 < 03 - 0 j 1 < 04 - 0.5 1 < 05 - 0.52 < 06 - 0.54 < 07 - OJ 7 < 08 - 0,57 < 09 - 0.5 7 < 10 - 0.58 < 11 - 0.60 < 12 - 0,60 < 13 - 0,61 < 14 - 0.63 < 15 - 0.65 < 16 - 0.65 < 17 - 0.66 < 18 - 0.68 < 19 - 0.68 < 20 - 0.69 < 21 - 0.69 < 22 - O. 7 1 < 23-0.72< 24,-0.72< 25 - 0.73 < 26 - 0.74 < 27 - 0.76 < 28-0.77< 29 - 0.77 < 30 - 0.79 < 31- 0.80 32 - 0.81 33 - 0.81 34 - 0.88 35 - 0.89 Note: Refled.ance values rounded to nearest hundredth, [< J indicates indigenous refleamce value GMC Data Report 287 Page 11 of 61 - r'~ .] r] r] .] r] .J .:] [.J I] [.J [J ("J1] [:.. ~ ~ Sample ID: WF9146 Mean depth: 1 ÓO Sample type: CUTTINGS I Immature / Oi I zone / Gas zone 20--------------------------------------------------------------------------------. !ill Indigenous 15- -'- -- ---- --------- H}----- -------- -------------------------------------------- ----. ','.',' ::;.:.: :::;':: ,',:.;.; 10-----------------~i~---------~--------------------------------------------------. .;,;.:. I I I I ,·:,:",,':':':"";"";':';·:':':'í'··:. I I I I I I I I I I I 1 I I r ' I I I I I I I I I I I I I I I I o . 50 1.00 1. 50 2.00 2. so Vitrinite Reflectance Ro % I ." In~i.genous population stati~tics i !\{ean. '0.681 Mm. 0.55 Max. 0.79 Std. Dev.. 0.06 Count: 40 Total population statistics Mean: 0.70 Min: 0.46 Max: 0.91 Std. Dev.: 0.09 Count: 47 01-0.46 02 - 0.55 < 03 -0.56 < 04 - 0.57 < 05 - 0,59 < 06 - 0,60 < 07 - 0.61 < 08 - 0.62 < 09 - 0.62 < 10 - 0.62 < 11 - 0.62 < 12 - 0.63 < 13 - 0.64 < 14 - 0.65 < 15 - 0.65 < 16 - 0.66 < 17-0.67< 18 - 0.67 < 19 - 0.68 < 20 - 0.70 < GMC Data Report 287 21-0.70< 22.. 0.70 < 23 - 0.71 < 24 .. 0.71 < 25 - 0.7 1 < 26 - 0.71 < 27 - 0,71 < 28 - 0.72 < 29 - 0.72 < 30 .. 0.72 < 31 - 0.72 < 32.. 0.74 < 33 - 0.74 < 34-0.74< 35-0.74< 36 - 0.75 < 37 .. 0.77 < 38 - 0.77 < 39 - 0.78 < 40 .. 0.78 < Note: Refled3nce values rowlded to nearest hundredth, [<] indiC3t.es indigenous refledM1ce value 41-0.78< 42 .. 0.80, 43 - 0.80 44 - 0.85 45 - 0.86 46 - 0.90 47-0.91 Page 12 of 61 a-J .-J r] r] .-J r [J .-1 [J (] .",'l ~'l ~ I~] ~ ~ , Sample ID: WF9159 Mean depth: 100 Sample type: CUTTINGS r Immature / / Oi1 zone Gas zone I]] Indigenous 20---------------------------------~----------------------------------------------. 15----------------------------------------------------~---------------------------. 10--------------------------------------------------------------------------------. 5- -- - - - ____m___,_~ II,:,¡----- --- ___m -- --- --- --- ___m_ -- -------- c- - - -- ---- I I I I I I I I I I I I ' I I I ( I r I I I I I I I II I I I I I I I I I I I 0.50 1.00 1.50 2.00 2.50 Vitrinite Reflectance Ro % . . ~ ,,,..': ,'...., ..' Indigenous population statistics 1:'~&iean:,:~ø:,88.,~1 Min: 0.75· Max: 0.98 Std. Dev.: 0.08 COWlt: 19 Total population statistics Mean: 0.91 Min: 0.74 Max: 1.09 Std. Dev.: 0.11 Count: 25 01 .. 0.74 02.. 0.75 < 03 - 0.76 < 04 - 0.78 < 05 .. 0.78 < 06.. 0.80 < 07 .. 0.83 < 08 .. 0.83 < 09 - 0.84 < 10.. 0.87 < 11-0,90 < 12-0.91< 13 - 0.93 < 14.. 0.93 < 15 - 0.95 < 16 - 0.95 < 17-0.95< 18 .. 0.96 < 19.. 0.98 < 20.. 0.98 < 21 .. 1.02 22 - 1.05 23 .. 1.07 24.. 1.08 25 .. 1.09 Note: Refleå.ance values rounded to nearest hundredth, [<] indicates indigenous refleáance value GMC Data Report 287 Page 13 of61 ·, r] r] WHOLE OIL GAS CHROMATOGRAPHY ~ N-ALKANES AND ISOPRENOIDS rJ SAMPLE : IKPIKT 6000-100"" DATA FILE 9126_WHO.D,,,, CPI VALUE 1.22 PRISTANE/PHYTANE 1.55 r] N·C9/N-C19 0.00 PRISTANE/N-C17 0.61 N-C15/N-C25 5.58 PHYTANE/N~C18 0.98 RFTFNTION E.E.ðK. AB.f8 EEAK. HFIGHT r] COMPOUND IlME AB.f6 N~C15=1 HFIGHT N-Ç15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0,000 0 0.000 r] N-C6 0.00 0 0,000 0 0.000 N~C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0,000 0 0.000 rJ N-C9 0.00 0 0.000 0 0.000 N-C10 15.25 468 0.082 172 0.132 N~C11 17.59 2288 0.401 816 0.628 "J N-C12 20.19 4450 0,781 1757· 1.353 N~C13 22.61 6782 ' 1.190 2490 1.917 N-C14 24.88 8106 1.422 2976 2.291 J N-C15 27.03 7261 1.274 2471 1.902 N-C16 29.06 5202 0.913 1761 1.356 N~C17 30.99 5700 1. 000 1299 1.000 N-C18 ,32.82 2298 0.403 804 0.619 :-] N-C19 34.57 1986 0,348 569 0.438 N-C20 36.24 2517 0.442 743 0.572 N-C21 37.84 2191 0.384 761 0.586 L] N-C22 39.36 2495 0.438 859 0.661 N-C23 40.83 4017 0,705 1296 0.998 í' N-C24 42.24 1381 0,242 503 0.387 '-] N-C25 43.59 1301 0,228 404 0.311 N~C26 44.90 611 0,107 205 0.158 ~'-' N~C27 46.15 631 0.111 211 0.162 N-C28 47.36 804 0.141 228 0.176 l N~C29 48.54 712 0,125 237 0.182 N~C30 49.67 373 0.065 129 0.099 N-C31 50.77 655 0,115 198 . 0.152 ~J N-C32 51.83 392 0.069 102 0.079 N-C33 0.00 0 0.000 0 0,000 N-C34 0.00 0 0,000 0 0.000 l N-C35 0.00 0 0.000 0 0,000 N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N -C38 0.00 0 0.000 0 0.000 -1 N·C39 . 0.00 0 0.000 0 0.000 N-G40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 l N~C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0,00 0 0.000 0 0.000 l Pristane 31.18 3490 921 Phytane 33.04 2252 580 l GMC Data Report 287 Page 14of61 WESTPORT TECHNOLOGY CENTER INTERNATIONAL I --1!lin ------- 6b I 50 4b I 30 -, 20 1b o o-~' 5000 - 10000 - 15000 - ~ 25000 - J¡:J ~ rJQ (1) Þ--" v- 0 H) 20000 - 0\ Þ--" 30000 - C1 ~ n tJ p:> .-+ ~ ¡o (1) ÞOd o ::4- tv 00 --.} counts _ J-ID2~g-f26:wHO:D) Ikpikt 6000-100 , Í--.-J , L-..J L , L-J f L...J L , L...J ~ , L-.J . I L-.J \ t I I L-J L-J L-l 1 1 I I L-J L...J --.J-~- ~ ---J - ~ ~ r- r- ~ ~ ~ ~ ~ -~ ...., r-; ...., -, -, , ! -y - &.--JL.-JL-J&--JL-JL..JwL-JL-JL-JL-JL-JL-JL...JL-JL-JL...JL-Jt......J Ikpikt 6000-100 a ~ (1 tJ p:> .-t- p:> ¡o (I) "0 o :4- N 00 ........:¡ FILJl B. (9T2~Wff(J])) counts - 5000 - 4000 - ÞOQ P' (JQ (t) I--' 0\ 0 H) 3000 - 0\ I--' 2000 - J.~ \ .II . ~iJ¡ '1 ~Jrl"i11 i'~: '~'J.~'¡,\J.,W/. Lw,~hL».~ _ _ ~J~JI",^..~ 1 000 - 0- 0--,---.----··--·--·-..----1'0·.··· --,-·-------r---.-----r 2'0 I ----,- I I -.----.-..-. 30 4'0 I -y---,.--~-~-- -r~--,---r-- - --...-----I~----~I-----I--~·_------ -1-- 50 60 mlo WESTPORT TECHNOLOGY CENTER INTERNATIONAL _J .J WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS .-J SAMPLE : IKPIKT 6600-700"" DATA FILE 9127_WHO.D"" CPI VALUE 3.21 PRISTANE/PHYTANE 1.65 II[J N-C9/N-C19 0.00 PRISTANE/N-C17 0.86 N-C15/N-C25 0.40 PHYT ANE/N-C18 0.85 RFTFNTION E.fAK. ABEA EEAK. HFl~HT .J ÇOMPOUND IIMf AB.E8 N-C15=1 HFIGHT N-C 15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 .-J N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 .J N-C9. 0.00 0 0.000 0 0.000 N-C10 15.25 360 0.079 131 0,090 N-C11 17.59 2430 0.531 864 0.596 .J N-C12 20.19 4909 1.073 1974 1.362 N-C13 22.61 7399 1.618 2657 1.834 N·C14 24.88 9016 1.972 3328 2.297 N-C15 27.03 8534 1.866 2837 1.958 -=] N-C16 29.06 6429 1.406 2078 1.434 N-C17 30.99 4573 1.000 1449 1.000 N-C18 32.83 2800 0.612 993 0.685 .J N-C19 34.57 3122 0.683 900 0.621 N-C20 36.24 2821 0.617 924 0.638 N-C21 37.84 3437 0.752 1019 ·0.703 N-C22 39.37 3132 0.685 1135 0.783 .~J N-C23 40~84 6822 1.492 2050 1.415 N-C24 42.24 1971 0.431 723 0.499 N-C25 43.63 21290 4.656 6576 4.538 1L1 N-C26 44.90 1075 0.235 360 0.248 N-C27 46.15 1102 0.241 374 0.258 N-C28 47.36 1094 0.239 320 0.221 .] N-C29 48.53 950 0.208 309 0.213 N-C30 49.67 345 0.075 133 0.092 N-C31 50.77 741 0.162 211 0.146 ',J N-C32 0.00 0 0.000 0 0.000 N-C33 0.00 0 0.000 0 0.000 N-C34 0.00 0 0.000 0 0.000 N-Q35 54.76 576 0.126 127 0.088 N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 11-' N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 Ò 0.000 Pristane 31.18 3930 1155 Phytane 33.05 2389 640 L GMC Data Report 287 Page 17 of 61 -~...~.~..~~......~..~~.... L-J ---J L-J ---J L-.J ----.J L-J t---1 L-J L-J .-J L.J L-J L-.J L-J L-J L-J L-J L--J Ikpikt 6600-700 C1 ~ () ö ~ .-+ ~ ¡o (J) '"0 o :.4- tv 00 -1 HDll::i, (912/_WRU.U) counts - 50000 - 'ï:j p:> (JC¡ (t) 4000b - ........ 00 o H") 0\ ........ 30000 - 20000 - 10000 - o-~ --~-~ ~~~~L 3'0 ---- I 40 _____~____~_= 6~-==~--==-rJ; ---.- .---,---, I o ___ ____.--.1º-_____ __________20 -- -, ... ~ fill. ~ ,~ ~ ~ ~ ~ ~ __ ~ ~ ~ ~ ~ ~ "'" J ~ ~ L-J LJ ~ L-' L-J L-.J L-J L-J L.J L-J L-J L....J L-J L-J L....J L...J L.....J Ikpikt 6600-700 Q ~ () ö p:> ..-t- ~ id (t) -g¡ ::1- N 00 -1 J- ID2tr,\91ZCWROTIJ counts - 5000 - 4000 - ~ p:> OCI (t) ÞO--" \0 0 ÞOO+,¡ 0\ 3000 - ÞO--" 2000 - -l~\- 11 J!' r ~ \~, \ \ ~' ,i¡UA ''IIJ>\J''~. J. v..ft J ". J~ ' ~'w ~ \M Mv -J.......Mv ~ h..).A..J,J ~;"~ 1 000 - 0- ~'. o I . 10 I 20 , 30 . , 40 . I 50 . I ' 60 min - -- - - ,.....-- ~------- -...-------~-..-_------ J J WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS ] SAMPLE : IKPIKT 6700-900,, DATA FILE 9128_WHO.D"" CPI VALUE 1.24 PRISTANElPHYTANE 1.77 -- ~J N-C9/N-C19 0.02 PRtSTANElN-C17 0.82 N-C 15/N-C25 3.83 PHYTANElN-C18 0.76 -~ RFTFNTION WK. ABE.ð ~ HFlGHT " J COMPOUND IlM.E 8B.E6 N-C15=1 HFIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 .. Î N-C5 0.00 0 0.000 0 0.000 .~. J N-C6 0;00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8," 0.00 0 0.000 0 0.000 .' ... N-C9 11.67 ! 159 0.012 '68 0.018 , \. N-C10 15~24 633 0.049 243 0.064 N-C11 17.59 3982 0.310 1458 0.383 "l N-C12 20.18 8808 0.685 3458 0.909 r N-C13 22.61 15644 1,217 5820 1.529 , I,'" N-C14 24.89 23000 1.790 8320 2.186 'l N-C15 27.04 23534 1.831 7348 1.931 N-C16 29.07 15185 1.182 5238 1.376 -,. 1" N-C17 30.99 12850 1,000 3806 1.000 N-C18 32.83 7838 0,610 2487 0.653 --l N-C19 34:57 9041 0.704 2421 0.636 N-C20 36.24 8850 0.689 2458 0.646 \ \'fII N-C21 37.84 8309 0.647 2750 0.723 "'J N-C22 39.37 9240 0.719 3180 0.836 N-C23 40.84 13711 1.067 4104 1.078 ....' \', N-C24 42.24 6769 0.527 2329 0.612 N-C25 43.59 6149 0.479 1934 0.508 ",] N-C26 44.89 2842 0.221 975 0.256 N-C27 46.15 2971 0.231 948 0.249 N-C28 47.36 3070 0,239 740 0.194 -'J N-C29 48.53 2486 0.193 794 0.209 N-C30 49.67 1090 0,085 379 0.100 N-C31 50.77 1780 0.139 534 0.140 ,-,] N-C32 51.83 909 0.071 228 0.060 N-C33 52.86 1868 0.145 417 0.110 I N-C34 53.86 1610 0.125 519 0,136 L] N-C35 54.76 856 0.067 252 0.066 N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 L] N-C38 0.00 0 0.000 0 0.000 N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 L' N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 ] N-C43 0.00 0 0.000 0 0.000 ~ N-C44 0.00 0 0.000 0 0.000 Pristane 31.18 10484 2855 Phytane 33.05 5922 1399 ,J GMC Data Report 287 Page 20 of61 WESTPORT TECHNOLOGY CENTER INTERNATIONAL I ~ I 60 I 50 I 40 3'0 I 20 1'0 o 1J'i4~I'~V"¡)jJtt, J i;'~'~\~w. "'''''"~, I. .~.JI.~' ~~ -L..- 0- 2000 - 4000 - 6000 - 14000 - ~ 12Qo.O - p:> (JQ (t) tv ~ 0 H) 10000 - 0\ ~ 8000 - <:) ~ (J tJ p:> .-t- p:> ¡o CD '"d o ::¡ tv 00 -.....J 16000 - counts HO~ tl, (91~tl_WHU.U) Ikpikt 6700-900 I ," ¡ ! 1 I", I , WW~UU~~~~~~~~~~~~~~ ----J L-f L-' FID2't1:-,\9TZ8yvRODj counts h 10000 - 8000 - 6000 - 4000 - 2000':" J..~ 0- o . I II-- , , ~ L-! 4-J \ . ,II ,.N'~} ~)~ 1b 2b á.-J L-.1 I cÍ-J L-J ~ t:l...--..1 i-J Ikpikt 6700-900 , V ~ J I ~, ,:~ I " )l¡ rJw.\I"~'~ wi. ,.I\,.y \W¡.JJ).,~~JM 3b 4b I 50 WESTPORT TECHNOLOGY CENTER INTERNATIONAL L-J L-J L-1 I 60 ~ I i..-..-J Q ~ () t;;I ~ .-t- p:> ~-- "'d o ::4- N 00 -1 ~ p:> (JQ CD N N o ÞOOOO+) 0\ ~ mID - _J _J WHOLE OIL GAS CHROMATOGRAPHY.. N-ALKANES AND ISOPRENOIDS .J SAMPLE : IKPIKT -01 83004,,,, DATA FILE 9140_WHO.D,,,, CPI VALUE 1.14 PRISTANE/PHYTANE 1.79 .] N-C9/N-C19 0.00 PRISTANElN-C17 0.52 N-C15/N-C25 5.23 PHYTANElN-C18 0.41 RFTFNTION ~ AfiE8 WK. HFIGHT .-J COMPOUND IlMf ðRE8 N-C15=1 HFIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 J N.;C6 0.00 0 0.000 0 0.000 . N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 ..] N-C9 0.00 0 0.000 0 0.000 N-C10 14.79 726 0,112 226 0.112 N-C11 . 17.59 4183 0.645 1532 0.759 N..c12 20.18 8593 1.325 3338 1.654 .J . N-C13 22.61 12937 ' 1.995 4922 2.439 N-C14 24.88 15922 2.455 5525 2.738 N-C15 27.03 13168 2,031 4056 2.010 .J N..c16 29.06 8192 1.263 2604 1.290 N·C17 30.99 6485 1.000 2018 1.000 N-C18 32.82 4664 0.719 1650 0.818 ''-'J N-C19 34.57 4603 0.710 1483 0.735 , N-C20 36.24 4064 0.627 1349 0.668 -j N-C21 37.84 4216 0.650 1429 0.708 N-C22 39.36 4294 0.662 1513 0.750 N-C23 40.83 5615 ' 0.866 1927 0.955 ." N-C24 42.24 3206 0.494 1115 0.553 N-C25 43.59 2516 0.388 812 0.402 ~ N-C26 44.89 1634 0.252 591 0,293 N-C27 46.15 1457 0.225 511 0.253 N..c28 47.36 1281 0.198 398 0.197 N-C29 48.54 1204 0.186 388 0.192 N-C30 49.67 757 0.117 242 0.120 -- N-C31 50.77 753 0.116 271 0.134 N-C32 51.84 929 0.143 197 0,098 .] N-C33 52.88 1788 0.276 354 0.175 N-C34 53.89 1580 0.244 318 0.158 N-C35 54.93 1912 0.295 301 0.149 ] N-C36 55.83 541 0,083 117 0.058 N-C37 56.71 1117 0.172 249 0.123 R: N-C38 57.62 753 0.116 217 0.108 N-C39 58.51 1850 0.285 384 0.190 ..J N-C40 59.38 2303 0.355 508 0.252 N-C41 60.23 1597 0.246 607 0.301 N-C42 0.00 0 0.000 0 0.000 ~ N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 Pristane 31.17 3381 888 Phytane 33.05 1892 476 R: II] GMC Data Report 287 Page 23 of 61 ~ L-' '--Î t-IOTB:t914U_WHU.U} counts " 25000 - 20000 ...J 15000 - 10000 - 5000 - o _-------t-l o - I ,- I iL.-- ,--1 - I L-' '-- L-' L..J L..J L...J Ikpikt-Ol 8300-4 ~~~~~' 1'0 20 I 30 i-J L..J L.J ~ L....J L-.J L-.J L-...J Cl ~ (J t:1 ~ .-+- ~ :;:0 (t) "'d o :4- N 00 , ........) '1:1 p:> (Jq (t) N - ~ o t-+;¡ 0\ ÞOOO-'- 4'0 5'0 do ¡ mio WESTPORT TECHNOLOGY CENTER INTERNATIONAL '-..r r 'f / '--I '-, L- r '---! ; f LJ'---.; ¡ L-! L....J L-1 I L-J i-J ~ L L.....J I L...J I L..J L-., , ~ A0213,(H14U_ VVHU.U) Counts _ Ikpikt-Ol 8300-4 ~ () t::1 p:¡ -- p:¡ þØ ('!) ~ o ::¡ N 00 -J 14000 _ 12000 - ~, ~ (fQ (þ 10000 _ N v.. 0 I-fJ 0\ ...... 8000 - 6000 - 4000 - o--+- ~ "J,#J,J.JJI4 jIJ\UJJw.~~\-w ~ 2000 - o 10 20 30 40 50 WEST PORT TECHNOLOGY CENTER INTERNATIONAL 60 mi I r.1 I ] WHOLE OIL GAS CHROMATOGRAPHY· N·ALKANES AND ISOPRENOIDS rJ SAMPLE : IKPIKT -01 8900-9"" DATA FILE 9146_WHO.D"" CPI VALUE 1.23 PRISTANElPHYTANE 2.98 r- .J N-C9/N-C 19 0.00 PRISTANElN·C17 0.47 N-C15/N-C25 6.01 PHYTANElN·C18 0.21 RFTFNTION ~ ARf8 fE8K HFIGHT 1 ÇOMPOUND IlME 8B.E8 N-C15=1 HFIGHT N-C15=1 I ,.. N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 rJ N-C6 0.00 0 0.000 0 0.000 N-G7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 ,1 N-C9 0.00 0 0,000 0 0.000 N-C10 14.79 330 0.099 99 0.091 N-G11 17.59 2155 0.648 765 0.701 N-G12 20.18 4756 1 .431 1890 1.732 ,l N-C13 22.60 6512 1.959 2483 2.276 N-C14 24.88 6569 1.976 2398 2.198 N-C15 27.03 5508 1.657 1814 1.663 [J N-C16 29.06 3880 1.167 1336 1.225 N-G 17 ' 30.99 3324 1.000 1091 1.000 N-C18 32.83 2439 0.734 850 0.779 "l N-C19 34.57 2374 0.714 722 0.662 N-C20 36.24 1675 0.504 634 0.581 L' N-C21 37.84 1768 0.532 573 0.525 N-G22 39.36 1400 0.421 528 0.484 r: N-C23 40.83 2267 0.682 743 0.681 N-C24 42.24 931 0.280 366 0.335 N-C25 43.60 916 0.276 309 0.283 LJ N-C26 44.90 713, 0.215 240 0.220 N-C27 46.15 563 0.169 194 0.178 N-C28 47.36 546 0.164 192 0.176 N-C29 48.54 601 0.181 189 0.173 I,J N-C30 49.68 295 0.089 128 0.117 N-C31 50.79 550 0.165 200 0.183 N-C32 51.83 1193 0.359 253 0.232 .. -1 N-C33 52.90 1442 0.434 294 0.269 N-C34 53.89 1384 0.416 250 0.229 ~ N-G35 54.95 1707 0.514 259 0.237 N -C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 N-C39 0.00 0 0.000 0 0.000 L_J N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 LJ N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 Pristane 31.17 1552 411 LJ Phytane 33.05 520 191 J GMC Data Report 287 Page 26 of 61 -. . ~ . ~ ~ ~ ~ ~ ~~ ~ ~ ~ ~ ~ ~ -: ..., . u U L.J U-LJ LJ LJ ~ ----.J ---.J LJ 4-.J .i-J LJ L-J L..J L..J '-.J ~ Ikpikt-Ol 8900-9 Q ~ (j I;:) ~ .-+ ~ ~ ( ) '1:j o ::¡ 10 00 -1 t-IU¿ H. (9'146_WHO.U) counts 100000 - 80QQO - Þ¡: ~ (JQ (t) 10 --J o I-+) 0\ ~ 60000 - 40000 - 20000 - . I . I 1..~1..0 .. J...-J . ~- 0-- 3'0 4'0 5'0 6'0 I 0 1'0 2'0 min - ¡-- r-- r- r- ,---1 , L.J L-J LJ ~ L-J L.J r ID2-a-:\9146:.WAO.IJ) counts ' 10000 -- 8000 - 6000 - 4000 ~ 2000 - -",,-1-1 0- I LJ ~ ~ f ~ ~ L-.J ~ . , ~ L-.J I \ ~--~. ! . ~ L-.J I ..-~....... ~ Ikpikt-Ol 8900-9 ~ (J t) ~ l""'t- ~ ~ '"0 o ~ N 00 -.) I¡j p:> OQ (t) N 00 o ""'"" 0'\ - , .~ ~lJ~~l~~'lL~ ...~ -- ---,.-------. - J .,.--r~~r- o 10 I 20 3~ 4~ WESTPORT TECHNOLOGY CENTER INTERNATIONAL do ®' Olin WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE : IKPIKT.()1 9300-4,," DATA FILE 9150_WHO.D"" CPI VALUE 1.06 PRISTANElPHYTANE 1.77 N-C9/N-C19 0.00 PRISTANE/N-C17 0.37 N-C15/N-C25 2.07 PHYTANE/N-C18 0.26 RFTFNTION E.E.ðK. AREA E.E8K; 1FIGHT COM.POUND IlME ðBEA N-C15=1 HF GHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 N-C10 16.63 248 0.034 97 0.040 N-C11 17.59 1388 0.191 473 0.195 N-C12 20.18 3165 0.435 1275 0.525 N-C13 22.60 .4972 0.683 1843 0.759 N-C 14 24.88 6791 0.933 2478 1.021 N-C15 27.03 7869 1.082 2667 1.098 N-C 16 29.06 6561 0.902 2439 1.005 N-C17 30.99 7276 1.000 2428 1.000 N-C18 32.83 5729 0.787 2076 0.855 N-C19 34.58 6231 0.856 1987 0.818 N-C20 36.25 5012 0.689 1718 0.708 N-C21 37.84 4763 0.655 1739 0.716 N.;C22 39.37 4846 0.666 1710 0.704 N-C23 40.84 4403 0.605 1564 0.644 N-C24 42.24 4557 0.626 1325 0,546 N-C25 43.60 3796 0.522 1171 0.482 N-C26 44.91 2268 0.312 803 0.331 N-C27 46.16 1993 0.274 714 0.294 N-C28 47.38 1507 0.207 533 0.220 N-C29 48.55 1491 0.205 500 0.206 N-C30 49.68 938 0.129 325 0.134 N-C31 50.79 1167 0.160 378 0.156 N-C32 51.84 1433 0.197 265 0.109 N-C33 52.89 1340 0.184 250 0.103 N-C34 0.00 0 0.000 0 0.000 N-C35 0.00 0 0.000 0 0.000 r N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 ! N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 ] N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 ] Pristane 31.17 2656 785 Phytane 33.05 1503 401 J - GMC Data Report 287 Page 29 of 61 U!W I 0,9 ....-I \0 ~ o <=> ~ ( ) bI) CIJ P-t t- oo N t o 0.. Qj ~ CIJ ~ CIJ Q U ~ tJ '1VNOIJ,1l.ffiI3.1NI t£3J,N3;J ÃÐOflONHJ:iJ.. ..Ld.Ud..Lti~lV.l 0.9 o.z o o.v 0.£ o~ I ~~-o - 0000 I. - OOOOZ -0000£ - OOOOt- - 00009 - 00009 - S¡Un03 (rrOHM-Oc; ~6) 'SLOH v - 00 E 6 "IO - :P(1: dJ[ I ~~~~~~~~~~~~~~~r~~r · i- ~ ~ í... ~ ~ ~ ~ ~ ;..¡ ~. ~.~ ~ ~ ... .... IIIÎ .. COunts - 10000 _. DZB~ Ikpikt-Ol 9300-4 ~ (J t:1 tIJ -- 8000 _ ìt1 {j o ;:¡ tv 00 '-J 6000 _ '"t; ~ (JQ (þ w 4000 _ o ~ 0\ ....... 0- r 1 ' . . . ~ ~~J¡n~,J';"v.W~~,WJ~ 2000 _ '~---'-~-'---r-'--~'_ -~-'--'-~'-.--..-~--..~_..-..__..-~~ 1-' ..~-. --- -~~--r---.---_, --":--'~--r-'-~ _ '-~'--'--'---r---_...__.. __~__~.__.. '------~~--~-~ 20 -~-~_~_________ 50 60 ---------...J!!i. WESTPORT TECHNOLOGY CENTER INTERNATIONAL J ] WHOLE OIL GAS CHROMATOGRAPHY ~ N~ALKANES AND ISOPRENOIDS J . SAMP'LE : IKPIKT..o1 9700-8"" DATA FILE 9154_WHO.D"" CPI VALUE 1.00 PRISTANElPHYTANE 1.51 ] N-C9/N-C19 0.00 PRISTANE/N-C17 0.41 N-C15/N-C25 4.40 PHYTANE/N-C18 0.30 ] RFTFNTION E.E8K. ~ E..EAK. HFIGIiT COMPOUND IJ.ME A8.EA N-C15.=1 HFIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 J N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 ] N-C9 0.00 0 0.000 0 0.000 N-C10 14.79 460 0.034 155 0.035 N-C11 17.59 3786 0.282 1417 0.320 N-C12 20.19 10307 0.769 4070 0.918 ' ] N-C13 22.61 19168 1.429 6823 1.539 N-C14 24.89 21647 1.614 7854 1.772 N-C15 27.04 19028 1.419 6586 1.486 ] N-C16 29.07 14888 1.110 5320 1.200 N-C17 31.00 13409 1.000 4432 1.000 N-C18 32.84 12075 0.901 3809 0.859 ] N-C19 34.58 10934 0.815 3220 0.727 N-C20 36.25 8569 0.639 2844 0.642 N-C21 37.85 7281 0.543 2544 0.574 N-C22 39.38 7416 0.553 2536 0.572 ] N-C23 40.84 6489 0.484 2341 0.528 N-C24 42.25 6187 0.461 1772 0.400 N-C25 43.60 4327 0.323 1342 0.303 ] N-C26 44.91 2971 0.222 1038 0.234 N-C27 46.16 3505 0.261 877 0.198 N-C28 47.38 3613 0.269 773 0.174 J N-C29 48.55 1846 0.138 588 0.133 N-C30 49.68 1198 0.089 417 0.094 N-C31 50.79 1596 0.119 432 0.097 N-C32 5'1.84 1602 0.119 322 0.073 ] N-C33 52.89 1719 0.128 356 ,0.080 N-C34 53.90 1112 0.083 244 0.055 N-C35 0.00 0 0.000 0 0.000 J N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 ] N -C3,9 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 J N-C43 0.00 0 0.000 0 0.000 N-C44 0,00 0 0.000 0 0.000 ] Pristane 31.18 5527 1520 Phytane 33.06 3656 876 J GMC Data Report 287 Page 32 of 61 rTUl H, (91 tJ4YVHO.U) counts _ 80000 - 60000 - 40000 - 20000 ~ o~~ o 1'0 ~~~ 2'0 Ikpikt-Ol 9700-8 3'0 I 40 WESTPORT· TECHNOLOGY CENTER INTERNATIONAL do o ~ (J tJ ~ ~ ~- :::u (D ~ o ::¡ N 00 -1 ~ ~ {JQ (D v.> w o t-1j 0'\ ~ 6'0 mk Ikpikt-01 9700-8 o ~ (') t:1 p:> .-t- p:¡ :;0 (t) Þ-O o ::4- N 00 -1 t-IU2 I:i. (91b4_WHO.fJ) counts - 20000 - 17500 - 15000 -, ~ p:¡ {JC¡ 12500 - (D tÑ .þ. 0 I--t-) 0\ þoooooL 10000 -- 7500 - 5000 -- 0--' l _ ~lÞl~ I~NJt'"Jv.~.~.1-v.4<J,..,,^,~w~ 2500 -, o 1'0 I 20 3'0 4'0 I 50 I 60 mtQ WESTPORT TECHNOLOGY CENTER INTERNATIONAL WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS J SAMPLE : IKPIKT.()1 9900-1"" DATA FILE 9156_WHO.D"" CPI VALUE 1.35 PRISTANE/PHYTANE 0.65 ] N-CS/N-C19 0.00 PRISTANE/N-C17 0.67 N-C15/N-C25 0.16 PHYTANE/N-C1S 1.06 RFTfNTION EEðK. A8EA .E.EAK. HFIGHT ] COMPOUND IlMf ABEA N-C15=1 t FIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 J N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N..cS 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 ] N-C10 0.00 0 0.000 0 0.000 N-C11 0.00 0 0.000 0 0.000 N-C12 0.00 0 0.000 0 0.000 J N-C13 22.61 372 0.641 126 0.653 N-C14 24.89 464 0.800 183 0,948 N-C15 27.03 575 0.991 200 1.036 .J N-C16 29.07 468 0.807 177 0.917 N-C17 31.00 580 1.000 193 1.000 N..c18 32.83 568 0.979 202 1.047 N-C19 34.58" 847 1.460 214 1.109 ] N.c20 36.25 690 1.190 237 1.228 N-C21 37.84 659 1.136 267 1.383 N-C22 39.37 796 1.372 306 1.585 "J N-C23 40.84 1056 1.821 329 1.705 N-C24 42.25 788 1.359 248 1.285 N-C25 . 43.63 3706 6.390 1044 5.409 '] N-C26 44.91 639 1.102 180 0,933 N-C27 46.17 905 1.560 155 0.803 N-C28 47.38 1969 3.395 459 2.378 N-C29 48.56 973 1.678 269 1.394 1 N-C30 49.99 1473 2.540 348 1,803 N-C31 50.79 1448 2.497 302 1.565 N-C32 51.85 995 1.716 243 1.259 ,..J N-C33 52.89 1544 2.662 318 1.648 N-C34 53.91 1401 2.416 242 1.254 N-C35 54.95 1115 1.922 200 1.036 1 N-C36 55.82 551 0.950 136 0.705 N-C37 56.73 662 1.141 163 0.845 N-C38 57.63 246 0.424 101 0.523 N-C39 58.52 711 1.226 164 0.850 -J N-C40 '59.37 625 1.078 160 0.829 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 l N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 l Pristane 31.18 390 132 Phytane 33.06 601 179 -1 GMC Data Report 287 Page 35 of 61 L--.J L-..J L--J L-.-I L-J L-J L--J L-J L-....j L-1 L-J Ikpikt-Ol 9900-1 flOZ ti, (Hlb6_WHO.U) counts - 50000 - 4000J) - 30000 - 20000 - 10000 - O--~- ~,.. I' , -, I &_--------- ~ & 10 I 30 4b 0 20 L-.J L-1 WESTPORT TECHNOLOGY CENTER INTERNATIONAL L-J L-.J L-.l 50 60 --, L-...J L...-..J t.--l o ~ n tJ ~ Í'~ ~I (t), g/ N 00 -1 '"t1 p:> (JQ (t) VJ 0\ o Þ-+) 0\ ÞOOOOOO'- I min ~ COUnts I 1000Ò _ Ikpikt -01 9900_1 10 ·~k/ 20 WES1'PORT 1'E: CIlJv¡ OLOGY CENTER. 50 INT'E "R1vAT:r ONAL 60 I mi WHOLE Oil GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE : IKPIKT -0110200-"" DATA FILE 9159_WHO.D,,,, CPI VALUE 0.85 PRISTANE/PHYTANE 1.36 N-C9/N-C19 0.01 PRISTANE/N-C17 0.38 N-C15/N-C25 #DIV/OI PHYTANE/N-C18 0.35 RFTFNTION E.E.ðK. ~ E.EAK. HFIGHT COMPOUND IlMf 8B.E8 N-C15=1 HflGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 11.77 120 0.014 60 0.021 N -C 10 14.80 1241 0.145 451 0.161 N-C11 17.59 5012 0.585 1847 0.658 N-G12 20.19 7602 0.887 3075 1.095 N-C13 22.61 9271 1.082 3584 1.276 N-C14 24.89 10335 1.206 3698 1.316 N-C 15 27.04 10172 1.187 3211 1.143 N-C16 29.07 7490 0.874 2813 1.001 N-C17 31.00 8572 1.000 2809 1,000 N-C18 32.84 6856 0.800 2449 0.872 N-C19 34.58 8679 1.012 2343 0.834 N-C20 36.26 6164 0.719 2176 0.775 N-C21 37.85 6698 0.781 2141 0.762 N-C22 39.39 7823 0.913 2481 0.883 N-C23 40.86 11643 1.358 2863 1.019 N-C24 42.27 14836 1.731 3531 1.257 N-C25 0.00 0 0.000 0 0.000 N-C26 0.00 0 0.000 0 0.000 N-C27 0.00 0 0.000 0 0.000 N-C28 0.00 0 0.000 0 0.000 N-C29 0.00 0 0.000 0 0.000 N-C30 0.00 0 0.000 0 0.000 N-C31 0.00 0 0.000 0 0.000 N-C32 0.00 0 0.000 0 0.000 N-C33 0.00 0 0.000 0 0.000 N-C34 0.00 0 0.000 0 0.000 N-C35 0.00 0 0.000 0 0.000 N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 GMC Data Report 287 Page38of61 ~. Ikpikt-Ol l0200- o ~ n d f'~ .-+- p:> ~ (t) "'0 o ::4- tv 00 --.J HDn),\9"159_WHO.U) counts - 80000 - 70000 - 60000 - ~ p:> {JQ (t) 50000 - VJ \D 0 ~ 0\ ¡.......o. 40000 - 30000 - 20000 - 1'0000 - 0-- o I 10 2'0 -' 3'0 I 40 5'0 6'0 I mir WESTPORT TECHNOLOGY CENTER INTERNATI ONAL- . . Ikpikt-Ol 10200- t-IDZ'B:-{9i59 _ WHO. U) counts - 20000 - 17500 - 15000 - 12500 - 10000 - 7500 - t", '[\ j~\ ~ I j Y l/ lJLJ i.;LiJI,LIoJ/'II I.~..# · '~"r)~ ·5000 - 2500 - 0--.... 1 . o 1b 2b 3b 4b WESTPORT TECHNOLOGY CENTER INTERNATIONAL " a ~ (1 ö ~ ...... ~ ~ (t) "0 o ::4- N 00 -1 Þ¡: ~ (fC¡ (t) ~ o o H) 0\ ~ 5b 6b mir WHOLE OIL GAS CHROMATOGRAPHY· N-ALKANES AND ISOPRENOIDS SAMPLE : BF378400..550'"" DATA FILE 9162_WHO.D"" CPt VALUE 1.21 PRISTANElPHYTANE 1.31 N-C9/N-C19 0.01 PRISTANE/N-C17 0.84 N-C15/N-C25 3.38 PHYTANE/N-C18 0.64 RFTFNTION E..EAK. 8Bf8 ~ HFIGHT COMPOUND IlME ABE8 N-C15=1 HFIGHt N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0,000 0 0,000 N-CS 0.00 0 0.000 0 0.000 N-C7 0.00 0 0,000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 11.66 342 0.010 130 0.013 N-C10 15.25 . 491 0.015 156 0,015 N-C11 17.61 435 0.013 138 0.014 N-C12 20.19 2570 0,079 1060 0.104 N-C13 22.62 5237 0.161 1954 0.191 N-C14 24.90 13028 0.400 5054 0.495 N-C15 27.05 25964 0.797 6424 0.825 N-C16 29.09 30461 0.935 10060 0.986 N-C17 31.02 32592 1.000 10206 1,000 N-C18 32.85 32500 0.997 7498 0,735 N-C19 34.60 26551 0.615, 5534 0.542 N-C20 36.27 16238 0.498 3908 0.383 N-C21 37.86 13639 0.418 4181 0.410 N-C22 39.39 15039 0.461 5126 0.502 N-C23 40.86 12375 0.380 4098 0.402 N-C24 42.26 6977 0.214 2457 0.241 N-C25 43.62 7672 0,235 2259 0.221 N-C26 44.91 2829 0.087 981 0.096 N-C27 46.17 3582 0.110 1215 0.119 N-C28 47~38 2593 0.080 788 0.077 N-C29 48.55 3766 0.116 1186 0.116 N-C30 49.69 1176 0.036 435 0.043 N-C31 50.79 2275 0.070 760 0.074 N-C32 51.85 1160 0.036 265 0.026 N-C33 52.88 2190 0.067 434 0.043 N-C34 53.89 309 0.009 98 0.010 N-C35 54.86 287 0.009 95 0.009 N-C36 0.00 0 ' 0.000 0 0,000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 N-C39 0.00 0 0,000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0,000 0 0.000 N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 Pristane 31.21 27323 6850 Phytane 33.08 20834 4592 GMC Data Report 287 Page 41 of 61 ~., BF37 8400-550' a ~ () t:1 ßJ .-t- p:> ¡o (t) '"0 o :¡ N 00 -1 ADTB';\'9T62:WHO.U) counts 80000 - 70000 - 60000 - Þ¡j pj (JQ 50000 - (t) ..¡:::. N 0 ÞOOOOOI) 0'\ Þ--' 40000 - 30000 - 20000 - 10000 - o~_l ~~JJ.l.~LLuJJ^_LLL-<ÌL~--' o 10 2'0 3'0 I 40 50 '-1 I ___,_u__ __~ ____,_________,____1)110. WESTPORT TECHNOLOGY CENTER INTERNATIONAL BF37 8400-550' a s;:: () tJ ~ , I ~ :::ø (t) >0 o ::¡ N 00 -1 t-IIJ2 H, (9T62_WHU.U) counts 20000 - 17500 - 15000 - ~ p:> (JQ 12500 - (t) .þ. w 0 I--+) 0\ 10000 - 7500 - 5000 - -___~I.... . 0- ,d I. ¡Iii)' ,A,.~.1~'-'Ji.'VJ II I I . II I I. I(IIl~ ~NJ~· ~"VvJJl~~ ~'M....fvJ- 2500 - -------r o 1'0 2'0 3'0 4'0 5'0 I 60 rn.in WESTPORT TECHNOLOGY CENTER INTERNATIONAL J ] WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS ] SAMPLE : BF37 8550-800'"" DATA FILE 9163_WHO.D"JI CPI VALUE 1.17 PRISTANElPHYTANE 1.47 ] N-C9/N-C 19 0,02 PRISTANE/N-C17 0.64 N-C15/N-C25 6.16 PHYTANE/N-C18 0.59 ] RFTFNTION E..EAK. AB.E8 E.EêJS.. HFIGHT COMPOUND IlMf AREA N-C15=1 HFI~HT N-C15=1 N·C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 ] N-C6 0.00 0 0.000 0 0.000 N·C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 ] N·C9 11.66 326 0.009 122 0.010 N·C 1 0 15.25 1804 0.051 718 0.061 N-C11 17.60 3893 0.110 1380 0.117 J N·C12 20.19 5781 0.163 2314 0.197 N-C13 22.62 12463 0.351 4312 0.366 N-C14 24.90 27780 0.783 9952 0.845 N-C15 27.06 39692 1.119 13062 1.109 ] N-C16 29.09 36551 1.031 12583 1.069 N-C17 31.02 35469 1.000 11773 1.000 N-C18 32.85 26332 0.742 8161 0.693 ] N-C19 34.60 18945 0.534 5162 0.438 N-C20 36.27 11048 0.,311 3607 0.306 N-C21 37.86 13293 0.375 4463 0..379 ] N-C22 39.39 17281 0.487 5489 0.466 N-C23 40.86 13845 0.390 4415 0.375 N-C24 42.26 7609 0.215 2527 0.215 N-C25 43.61 6440 0.182 2058 0.175 ] N-C26 44.91 3656 0.103 1163 0.099 N-C27 46.17 4642 0.131 1547 0.131 N-C28 47.38 3855 0.109 1097 0.093 ] N-C29 48.56 5495 0.155 1755 0.149 N-C30 49.69 1329 0.037 402 0.034 N-C31 50.7~ 2983 0.084 839 0.071 J N-C32 51.84 1876 0.053 387 0.033 N-C33 52.89 3590 0.101 734 0.062 N-C34 53.90 564 0.016 162 0.014 N-C35 0.00 0 0.000 0 0.000 ] N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 ] N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 J N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 ] Pristane 31.20 22783 6256 Phytane 33.08 15465 3526 GMC Data Report 287 Page 44 of 61 "" BF37 8550-800' Cl ~ () tj PJ ri- p:> ::u ( ) Þ-Q o :4- N 00 -1 1-102 tl, {9163_WHU.LJ) counts 50000 -. 40000 - 30000 - I-d p:> (fQ (t) +:>. v. o H) 0\ - 20000 - 10000 - 0-- - I. ____~L~~Jh-~JJ~~~ 0-------·- ,---' T- -, ---',----- ",-- 1h" -",--'-----,----- ·,,--'--.---io-.----'-- . -·-3IÕ--~--,-----r---,·---r---4b--r-=_-~~-=~ ---50-~-r-u,- - '--_-~'==~6IÕ·---~~=-=-==~~n ~~ ------- WESTPORT TECHNOLOGY CENTER INTERNATIONAL BF37 8550-8001 o ~ () t:1 ~ .-+- p:> ïO (i) '"0 o ::4- N 00 -1 HD2 tit (9~U.D) counts - 20000 - 17500 - 15000 -- ÞOt; p:> (Jq (t) 12500 - ~ 0\ 0 ~ 0\ Þ-"- 10000 - 7500 - 5000 - -.-J.,#.. I 11 0- '¡III 'H¡,~·~N-~· I I . . ^^---,-~~M¡'~ ~rr ,1\ . ~-"~"'"^^"~~ 2500 - ----r o 10 20 30 I 40 I 50 I 60 __min WESTPORT TECHNOLOGY CENTER INTERNATIONAL WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE : BF379090-360'"" DATA FILE 9164_WHO.D"" CPI VALUE 1.12 PRISTANE/PHYTANE 1.33 N-C9/N-C19 0.00 PRIST ANE/N-C17 0.66 N-C15/N-C25 5.74 PHYTANE/N-C18 0.63 RFTFNTION EEAK. ðRE8 .E.EAK. HFIGHT COMPOUND 'IlMf ðREð N-C15=1 HFIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 N-C10 15.24 535 0.019 200 0.022 N-C11 17.60 773 0.027 273 0.030 N-C12 20.19 1986 0.070 790 0.086 I N-C13 22.61 5475 0.193 2047 0.223 N-C14 24.89 14105 0.497 5257 0.572 N-C15 27.04 22777 0.802 7797 0.849 N-C16 29,08 25268 0.890 8557 0.932 N-C17 31.01 28388 1.000 9183 1.000 N-C18 32.84 22468 0.791 6739 0.734 N-C19 34.59 19267 0.679 4323 0.471 N-C20 36.25 10756 0.379 3124 0.340 N-C21 37.85 9723 0.343 3328 0.362 N-C22 39.38 12307 0.434 4167 0.454 N-C23 40.84 9547 0.336 3159 0.344 N-C24 42.25 4633 0.163 1569 0.171 N-C25 43.60 3966 0.140 1231 0.134 N-C26 44.90 2049 0.072 700 0.076 N-C27 46.16 1914 0.067 706 0.077 . N-C28 47.37 2554 0.090 490 0.053 N-C29 48.54 1638 0.058 534 0.058 N-C30 49.68 776 0.027 200 0.022 N-G31 50.78 ~04 0.032 315 0.034 N-C32 51.84 503 0,018 111 0.012 N-C33 52.88 994 0.035 202 0,022 N-C34 53.87 350 0.012 104 0.011 N-C35 54.77 685 0.024 173, 0.019 N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0,000 N-C38 0.00 0 0.000 0 0.000 N-C39 0.00 0 . 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 N -C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 Pristane 31.19 18719 4711 Phytane 33.07 14118 3206 GMC Data Report 287 Page 4? of 61 WESTPORT TECHNOLOGY CENTER INTERNATIONAL I min 6'0 5'0 4'0 3'0 2'0 1'0 o ~~J"~'''"~'~~~'-Q 0----'- I . 5000 - 1 ooåo - 25000 - . . 20000 - ~ p:> OQ (t) ~ 00 0 ~ 15000 -. 0\ Þ--' Ç¡ ~ (') t:1 ~ .-+ p:> :;0 (t) ÞOQ o ~ N 00 -1 30000 -, t-IDTB~-(9-104::'WFfO-:D) counts . BF37 9090-360' f-1D2tr.\9Tõ4~FfCJ.D) counts _ 14000 - 12000 - 1 0000 - 8000 - 6000 - 4000 .. 2000 - ....I... I. I 0- ._-~--r- o , --I 10 BF37 9090-3601 .. 1JJtJt,! ~ ~,tlkl~ ¡ I 20 3b ¡. ~,~.~~ . .' ~ l'-v'~~ I 40 I 50 WESTPORT TECHNOLOGY CENTER INTERNATIONAL a ~ () tJ !"~ .-t- ~ ~ (t) 'ö o ~ tv 00 -...) ~ p:> (JQ (t) ~ \0 o ÞOOOO+) 0'\ ........ I 60 mid WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE : KARLUK 8900..9150"" DATA FILE 9165_WHO.D,,,, CPI VALUE 1.42 PRISTANElPHYTANE 2.21 N-C9/N-C19 0.00 PRISTANE/N-C17 0.90 N-C15/N-C25 20.90 PHYTANE/N-C18 0.76 RF-TFNTION EfAK. ðB.E8 E.EM. HFIGHT COMPOUND I1Mf AREA N-C15=1 HFIGHT N-C15=1 N-C4 0.62 200 0.010 142 0.022 N-C5 0.00 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 N-C 1 0 15.24 820 0.039 311 0.048 N-C11 17.60 659 0.031 219 0.034 N-C12 20.18 2001 0.095 811 0.126 N-C13 22.61 10941 0.522 3884 0.602, N-C14 24.91 73388 3.500 22987 3.564 N-C15 27.07 100058 4.772 27380 4.245 N-G16 29.09 44095 2.103 13977 2.167 N-C17 31.01 20969 1.000 6450 1.000 N-C18 32.84 11240 0.536 3097 0.480 N-C 19 34.58 8840 0.422 1998 0.310 N-C20 36.25 5909 0.282 1937 0.300. N-C21 37.85 4907 0.234 1585 0.246 N-G22 39.38 3047 0.145 1021 0.158 N-C23 40.84 4295 0.205 1267 0.196 N-C24 42.24 1540 0.073 444 0.069 N-C25 43.61 4788 0.228 1121 0.174 I N-G26 44.90 933 0.044 294 0.046 N-C27 46.16 1864 0.089 662 0.103 N-C28 47.36 3045 0.145 396 0.061 ¡ N-C29 48,54 2055 0.098 623 0.097 N-C30 49.68 361 0.017 140 0.022 N-C31 50.78 1010 0.048 332 0.051 N-C32 51.82 770 0.037 147 0.023 N-C33 52.87 1049 0.050 243 0.038 N-C34 0.00 0 0.000 0 0.000 N-C35 0.00 0 0.000 0 0.000 J N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 j N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 ·0.000 ] N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N -C44 0.00 0 0.000 0 0.000 1 Pristane 31.20 18802 4921 Phytane 33.06 8522 2019 GMC Data Report 287 Page 50 of61 KARLUK 8900-9150 Q ~ () t:1 p:> ....... p:> :;:0 (1) "'d o ~ N 00 -....l - rDZ1J:-{9'f6s:wRCY.D) counts , 30000 - 25000 - Þ-d Ç¡j (JQ (1) 20000 - VI ~ 0 H') 0\ ~ 15000 - 10000 - o --'- . . .\ \ ~, . .. . ~fl~1 . '\, t. .J¡-..WJlw~ 5000 -- o 1'0 2'0 3'0 I 40 5'0 6'0 J min WESTPORT TECHNOLOGY CENTER INTERNATIONAL counts 14000 - 12000 - 10000 - 8000 - 6000 - 4000 - . 2000- J-/U£ I:i, (~HOJJ) '-J-.I.I 0- o .~ ' I 10 2'0 KARLUK 8900-9150 t1 11 J I '~~I~\'.Y.JM~,~,~ 3'0 4'0 I 50 WESTPORT TECHNOLOGY CENTER INTERNATIONAL Q ~ () tJ ~ ~ þ) :;0 (t) '"0 o ::4- tv 00 -....) Þ-C ~ f/C¡ (t) V\ tv o ÞO-t) 0\ ÞOO-'o I 60 min I ] WHOLE OIL GAS CHROMATOGRAPHY w N-ALKANES AND ISOPRENOIDS 1 SAMPLE : KARLUK 10200-400"" DATA FILE 9166_WHO.D,It, CPI VALUE 1.19 PRISTANE/PHYTANE 2.08 ] N-C91N-C19 0.00 PRISTANEIN-C17 0.75 N-C15/N-C25 22.21 PHYTANE/N-C18 0.73 ] RFTFNTION ~ ARE8 ~ HFIGHT COMPOUND IlMf ABfA N-C15=1 H FIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-CS 0.00 0 0.000 0 0.000 ] N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 J N-C9 0.00 0 0.000 0 0.000 N-C10 0.00 0 0.000 0 0.000 N-C11 0.0'0 0 0.000 0 0.000 ] N-C12 20.19 431 0.037 176 0.057 N-C 13 22.61 4008 0.342 1525 0.498 N-C14 24.90 25079 2.141 8419 2.750 N..c15 27.05 32298 2.757 9347 3.054 ] N-C16 29.07 17911 1.529 5274 1.723 N-C17 31.00 11716 1.000 3061 1.000 N-C18 32.83 5800 0.495 1776 0.580 ] N-C19 34.58 4456 0.380 1142 0.373 N-C20 36.25 3856 0.329 1012 0.331 N..c21 37.84 2421 0.207 820 0.268 ] N-C22 39.37 1665 0.142 590 0.193 N-C23 40.84 2138 0.182 681 0.222 N-C24 42.24 1396 0.119 282 0.092 N-C25 43.61 1454 0.124 400 0.131 ] N-C26, 44.90 490 0.042 156 0.051 N-C27 46.16 665 0.057 235 0.077 N-C28 47.36 499 0.043 145 0.047 ] N-C29 48.54 757 0.065 236 0.077 N-C30 49.56 356 0.030 106 0.035 N-C31 50.78 447 0.038 152 0.050 ] N-C32 0.00 0 0.000 0 0.000 N-C33 0.00 0 0.000 0 0.000 N-C34 0.00 0 0.000 0 0.000 N-C35 0.00 0 0.000 0 0.000 ] N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0,000 N-C38 0.00 0 0.000 0 0.000 ] N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 ] N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 J Pristane 31.19 8819 2103 Phytane 33.06 4247 952 J GMC Data Report 287 Page 53 of61 rrDTB;l'glo~O.U) counts 25000 - 20000 - 15000 - 10000 - 5000 - 0--'- --, o ----...J------.,~II.----..J---.,C___....i_____.J&..__.._JL__l KARLUK 10200-400 o ~ (') ö p:> .-t- f'~ :::0 (t) "0 o ::¡ N 00 -1 ""'d p:> aq (t) U'I .þ. o H) 0\ J¡~jßAtJ.~L 1'0 I 20 3'0 4'0 5'0 do I min WESTPORT TECHNOLOGY CENTER INTERNATIONAL min ! i-...J Þ-O p:> (JQ (þ V\ V\ o Þ-fo) 0\ ~ a ~ n t;; p:> -- p:> ~ (t) ~ o ::¡ tv 00 -1 1 L...J I 60 5'0 WESTPORT TECHNOLOGY CENTER INTERNATIONAL 4'0 I 30 I, ¡Ii 1'~I.¡/,¡J¡ø¡),/~'i-IlL~w~ ! t..-.J ! L-J , L-.J I L-...J L-.J KARLUK 10200-400 L-.J L...J 1 Ï--J L.J L-.J 2'0 ~~' w . I i.-.J w 1'0 ..J.LI_I o 0- 2000 - 4000 -- 6000 - 8000 - 10000 - HUl tl, (91ôs:::,wHO.U) counts - w ---.J LJ L.J J ] WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS J SAMPLE: JEAN 9850-10150'"" DATA FILE 9167 _WHO.D"" CPI VALUE 1.24 PRISTANElPHYTANE 1.65 .] N-C9/N-C19 0.00 PRISTANElN-C17 0.73 N-C 15/N-C25 7.93 PHYTANElN-C18 0.69 .] RFTFNTION E.EAK. AB.E.ð f.EAK. HFIGHT COMPOUND IlM.E 8B.E.ð N-C15=1 HFIGHT N-C15=1 N-C4 0,00 0 0.000 0 0.000 N-C5 0,00 0 0.000 0 0.000 .] N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 J N-C9 0.00 0 0.000 0 0.000 N-C10 15.24 4327 0.045 1510 0.060 N-C11 17.60 8011 0.083 2395 0.096 J N-C12 20.19 13649 0.142 5069 0.203 N-C13 22.68 85099 0.886 19439 0.778 N-C14 24.92 78268 0.815 24983 1.000 N-C15 27.08 124255 1.293' 33818 1.354 ] N-C16 29.11 113258 1.179 30890 1,237 N-C17 31,04 96072 1.000 24979 1.000 N-C18 32.86 61531 0.640 15766 0.631 ] N-C19 34.60 46829 0.487 10815 0.433 N-C20 36.27 30509 0.318 8329 0.333 N-C21 37.86 23946 0.249 7060 0.283 J N-C22 39.39 21645 0.225 6978 0.279 N-C23 40.85 23429 0.244 7404 0.296 N-C24 42.25 15613 0.163 5373 0.215 N-C25 43,61 15663 0.163 5219 0.209 ] N-C26 44,90 8439 0.088 2807 0.112 N-C27 46.17 1 0467 0.109 3440 0.138 N-C28 47.37 7509 0.078 2108 0.084 J N-C29 48.55 12386 0.129 3196 0.128 N-C30 49.59 3478 0.036 565 0.023 N-C31 50.78 5039 0.052 1547 0.062 N-C32 51.84 1562 0.016 425 0.017 :J N-C33 52.88 4733 0.049 996 0.040 N-C34 53.88 683 0.007 173 0.007 N~C35 54.76 1325 0.014 360 0.014 J N-C36 55.80 264 0.003 92 ·0.004 N-C37 56.72 880 0.009 130 0.005 N-C38 0.00 0 0.000 0 0.000 l N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 "J N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 l Pristane 31.22 70360 15811 Phytane 33.08 42688 7764 J GMC Data Report 287 Page 56 of?1 ~IL.-.-Ia--JIL--...IIL.--..JL-J----.JL-....-,/L--JL--JL-.JL-..JÌ--Ji--..JL-JL-.JL-..Ji.--J JEAN 9850-101.50' a ~ n t1 ~ M- ~ ~ (t) "'0 o :4- N 00 -...) F-IUL U, (~) counts - 90000 - 80000 - 70000 - 50000 - Þ¡: ~ (JQ (1) v. -...) o Joo-io') 0\ ...... 60000 - 40000 - 30000 - 20000 - 10000 - O.....r--'- ~. Á L \J ~~. .Ål(1' UJ ¡.'1J......¡, ..<!.;.J.J I II. I. .~µ ~ Jv.J.~ . -------. o I 10 I 20 3'0 4'0 5'0 6'0 I rnir WESTPORT TECHNOLOGY CENTER INTERNATIONAL -rIU2 H, (915f_WHO.U) counts - 50000 - 40000 - 30000 - 20000 - 10000 - o _.-L. o JEAN 9850-10150' J \ J¿l1 -\ ~ H rJvh ~. I .. ~. _ I I i I ~ I frJ. '~.~ iv~ L . II ~À~'~fi '-..Jw~ L--,,-,-Jw. . I 10 2'0 3'0 I 40 WESTPORT TECHNOLOGY CENTER INTERNATIONAL L---I L.--...I a---J '----' I 50 Q ~ n tJ p:> .-t- PJ ïO (t) 'ï;j o ::4- tv 00 -1 ""'0 ~ (JQ (t) V\ 00 o H:I 0\ ........ 6'0 min ] ] WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS ] SAMPLE : JEAN 10850..11200,," DATA FILE 9168_WHO,D,ltt CPI VALUE 1.64 PRISTANE/PHYTANE 1.77 J N-C9/N-C19 0.00 PRISTANElN-C17 0.90 N-C15/N-C25 3.32 PHYTANE/N-C18 0.72 ] RFTF-NTION fEAK. AREA .E.EAK. 1FIGHT ÇOMPOUND II.Mf ~ N-C15=1 HFIGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 ] N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 ] N-C9 0.00 0 0.000 0 0.000 N-C10 15.57 3821 0.103 1092 0.115 N-C11 17.60 14037 0.378 4934 0.521 ] N-C12 20.20 25547 0.688 9752 1.029 N-C13 22.63 75908 2.043 22620 2.387 N-C14 24.92 83479 2.247 27324 2.883 N-C15 27.,06 79097 2.129 21917 2.312 ] N-C16 29.09 53048 1.428 13647 1.440 N-C17 31.02 37157 1.000 9478 1.000 N-C18 32.85 26280 0.707 6413 0.677 ] N-C19 34.59 27192 0.732 5357 0.565 N-C20 ·36.26 16050 0.432 4319 0.456 N-C21 37.85 13920 0.375 4152 0.438 N-C22 39.38 11180 0.301 3775 0.398 J N-C23 40.85 15210 0.409 4739 0.500 N-C24 42.25 8210 0.221 2529 0.267 N-C25 43.62 23849 0.642 5854 0.618 J N-C26 44.90 5340 0.144 1629 0.172 N-C27 46.16 7934 0.214 2680 0.283 N-C28 47.37 6459 0.174 1324 0.140 ] N-C29 48.55 7061 0.190 2168 0.229 N-C30 49.57 1323 0.036 229 0.024 N-C31 50.78 2996 0.081 932 0.098 N-C32 51.84 1398 0.038 . 292 0.031 ] N-C33 52.88 2817 0.076 556 0.059 N-C34 53.88 990 0.027 208 0.022 N-C35 54.76 355 0.010 114 0.012 ] N-C36 55.80 342 0.009 112 0.012 N-C37 0.00 0 0.000 0 0.000 N-C38 0.00 0 0.000 0 0.000 ] N-C39 0.00 0 0.000 0 0.000 N-C40 0.00 0 0.000 0 0.000 N-C41 0.00 0 0.000 0 0.000 N-C42 0.00 0 0.000 0 0.000 ] 'N-C43 0.00 0 0.000 0 0.000 N -C44 0.00 0 0.000 0 0.000 ] Pristane 31.20 33497 8029 Phytane ' 33.07 18973 3550 J GMC Data Report 287 Page 59 of61 counts ' 60000 - 50000 - 40000 - 30000 - 20000 - 10000 - rIOL~. (9f68_WHO.U) o --'- o --- 1'0 JEAN 10850-11200 . J I _I µI.. ~,I\,~ ~J.. 1..v.w.l.JJJJ UJ.--Il ..Ao--~J¡i.lJÞ,.,J,IIIf .... 2'0 I 30 4'0 WESTPORT TECHNOLOGY CENTER INTERNATIONAL 5'0 Q ~ (J tJ þ.J .-+ p:> :;;0 (t) "'0 o ::¡ N 00 -1 Þ¡:; p:> (JQ (t) 0\ o o I--t) 0\ 6'0 I rnin FID~(g-f6B_WHU.U) counts - 25000 -- 20000 - 15000 - 10000 - 5000 - o _ .J.. o JEAN 10850-11200 ;'_ 'II~ ~ ~1. (I' r~ ~»ll~¡.tJ\ 1'0 3'0 2'0 I ~~A.\h.~ ,,",,-,WU~ 4'0 5'0 WESTPORT TECHNOLOGY CENTER INTERNATIONAL a ~ (J tj p:> .-t- p:> ïO (t) 'U o ::¡ tv 00 -1 ~ p:> (fQ (t) 0\ -.. o H-) 0\ I 60 min
