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Home My WebLink AboutGMC Data Report No. 288 Gas chromatography of the following well materials: Gulf Oil Corporation Beaufort Sea BLK 54 No.1 (Cross Island No.1) cuttings (9,560' - 13,980'), and Amoco Production Co. No Name Island No.1 cuttings (10,890' - 12,900'), and core (12,936' - 13,869'). ,\~~NT O,F ì:~' , ,,?-«' ¥ * ... ~ q:.. y; '(2; *~, -fe', ,,::A o ~ <1.' *õ ::J :II '~¥ *~*#' .} . oS' ,.¡.; * . .g; '(i SV }"Ol.OG\cþ..\r· ' Received 23 March1999. Total of 21 pages in report. Alaska Geologic Materials Center Data Report No. 288 TECHNOLOGY CENTER INTERNATIONAL No Name Island and G Cross Island Extracts ,ß(?t1,t-(fPrt 5"1!"~ ell{ ~-y-! ~ GMC Data Report 288 Page 1 of21 1 ~- ~- -- IL-J L-J LJ L-J fL-J fi-J IL......i L-J L.....J L......J WESTPORT TECHNOLOGY CENTER INTERNATIONAL Prepared for 8P~Alaska 10J5/98 No Name Island & Cross Island Fractional Isotopes Client ID Sample Depth lablD õ13C%o õ13C%o Type (ft) (WFXXXX) Saturate Aromatic No Name Island #1 Cuttings 10890-10950 9194 -29.18 -27.21 No Name Island #1 Cuttings 12830-12900 9195 -30.56 -28.42 No Name Island #1 Core Chip 12936 9196 -30.53 -28.52 No Name Island #1 Core Chip 13668-13672 9197 -32.11 -30.5 No Name Island #1 Core Chip 13869 9198 -31.83 -30.25 Cross Island #1 Cuttings 9560-9650 9199 -29.82 ~27.2 Cross Island #1 Cuttings 9660-9750 9200 -28.13 -27.51 Cross Island #1 Cuttings 13240-13280 9201 -29.58 -26.82 Cross Island #1 Cuttings 13930-13980 9202 -30.44 -28.41 PF-9B-071 L-J L.......l: a ~ (j t:1 ~ ~ ~ id CÐ ÞOtj o ::4. tv 00 00 ~ ~ (JQ CÐ tv o I-+¡ tv Þ--" ~ L-! L-J LJ LJ IL..J W L..J L...J L...J IL..J L...J L-J L..:..J L-.a ~ ~ I.--j '-'" WESTPORT TECHNOLOGY CENTER INTERNATIONAL Q ~ (j d No Name Island and Cross Island TSE Data ~ - ~ id Client ID Depth· Labld Sample Wt. Vial Wt. Vial + TSE T$E Wt. 0/0 TSE KGlTon CÐ 'U (ft) (WFXXXX) (gms) (mgs) TSE 0 :4- tv 00 No Name Island #1 10890-950 9194 3.8074 0.7611 0.7642 0.0031 0.08 0.81 00 No Name Island #1 12830-900 9195 13.4139 0.8006 0.8265 0.0259 0.19 1.93 No Name Island #1 12936 9196 39.4794 0.7786 0.9416 0.1630 0.41 4.13 No Name Island #1 13668-672 9197 35.7578 0.7947 0.9933 0.1986 0.56 5.55 No Name Island #1 13869 9198 40.4321 0.7666 0.9176 0.1510 0.37 3.73 Cross Island #1 9560-650 9199 21.5119 0.7868 0.7975 0.0107 0.05 0.50 Cross Island #1 9660-750 9200 18.3613 0.7769 0.7851 0.0082 0.04 0.45 Cross Island #1 13240-280 9201 6.8262 0.8001 0.8032 0.0031 0.05 0.45 ~ ~ Cross Island #1 13930-980 9202 6.7334 0.7681 0.7723 0.0042 0.06 0.62 f1Q CÐ w 0 ~ N Þ--" No Name Island and Cross Island SARA Data Client ID Sample Depth LablD Saturate % Aromatic 0/0 Polar % Asphaltene % Type (ft) (WFXXXX) No Name Island #1 Cuttings 10890-10950 9194 48.9 24.0 18.4 8.7 . No Name Island #1 Cuttings 12830-12900 9195 65.7 15.4 17.5 1.4 No Name Island #1 Core Chip 12936 9196 73.6 12.6 12.5 1.3 No Name Island #1 Core Chip 13668-13672 9197 59.2 24.4' 14.7 1.7 No Name Island #1 Core Chip 13869 9198 49.8 29.2 15.4 5.6 Cross Island #1 Cuttings 9560-9650 9199 47.4 20.4 30.9 1.3 Cross Island #1 Cuttings 9660-9750 9200 50.4 21.8 24.8 3.0 Cross Island #1 Cuttings 13240-13280 9201 38.0 31.7 19.2 11.1 Cross Island #1 Cuttings 13930-13980 9202 47.8 22.6 21.3 8.3 Prepared for BP-Alaska 10/5/98 PF-9B-071 ]' GMC Data Report 288 Page 4 of21 ]' -- WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS .J SAMPLE : No Name Island #1 DATA FILE WF9194.D 10890-1290010' cuttings CPI VALUE 1.59 PRISTANEJPHYTANE 1.30 N-C9/N-C19 0.00 PRISTANEfN-C17 0.71 J' N-C 15/N-C25 0.27 PHYTANEfN-C18 0.67 RFTFNTION EfðK. ABfð E2K. HFIGl-IT J' COMPOUND I.lMf 8Ef8 N-C15=1 HFIGHT N-C15=1 N-C4 0,00 0 0.000 0 0.000 N-C5 1.04 0 0.000 0 0.000 ..J N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 ] N-C10 0.00 0 0.000 0 0.000 N-C 11 0.00 0 0.000 0 0.000 N-C12 0.00 0 0.000 0 0.000 .:] N ~C 13 0.00 0 0.000 0 0.000 N~C14 25.41 714 0.085 294 0.098 N-C15 27.56 3920 0.467 1415 0.474 ,-,] N-C16 29.60 7478 0,891 2850 0.955 N-C17 31,54 8392 1.000 2985 1.000 N-C18 33.38 6805 0.811 2312 0.775 ;-] N-C19 35.13 4361 0.520 1580 0.529 N-C20 36.80 4008 0.478 1522 0.5,10 N-C21 38.40 3962 0.472 1360 0.456 N-C22 39.93 4356 0.519 1649 0.552 N-C23 41.40 4763 0.568 1725 0.578 -J N-C24 42.81 3852 0.459 1390 0.466 N-C25 44.20 14732 1.755 4017 1.346 N-C26 45.47 2127 0.253 744 0.249 LJ N-C27 46.73 1700 0.203 577 0.193 N-C28 47.94 1377 0.164 440 0.147 N-C29 49.12 2089 0.249 602 0.202 ,] N-C30 50.25 1329 0.158 424 0.142 N-C31 51.35 1502 0.179 480 0.161 N-C32 52.42 1456 0.173 333 0.112 N-C33 53.46 836 0.100 263 0.088 [J N-C34 54.46 533 0.064 173 0.058 N-C35 55.43 363 0.043 129 0.043 N-C36 56.38 305 0.036 86 0.029 L:~ N-C37 57.31 392 0.047 94 0.031 N-C38 58.20 202 0.024 63 0.021 N-C39 59.07 128 0.015 42 0.014 N -C40 59.94 80 0.010 24 0.008 N -C41 0.00 0 0.000 0 0.000 LJ N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 l Pristane 31.73 5980 1808 J Phytane 33.61 4587 1126 ['''' .J ¡¡; ~ ~·H-~~--~~~~...,....,--,-==, ;~ L- ~~ L....! ;i-J :ì-J .L-J J...... L.....JW L t.....;J L-.J L-.J \......J .L..J \......J L-J L-J . . u ..- -- - FID2 B: (C:\HPCHEM\WHOOll\WF919~~D)----- ---- - _u"__'___ - .---- _u' counts .-.--------- .--"_._- ..---.- ____ __ __u Q ~ () tJ PJ ~ PJ id CÐ "'d o ~ tv 00 00 No Name Island #1 10890-10950 6000 .. 5000· 4000 i¡j PJ (JQ CÐ V\ o I-+¡ tv 3000 .. 2000 - o f'.~~i'~,\~V~If.v~'\Iw~\w.. I U I l.. ._/~ I I . II, h -Nl I.."""",^",^, ¡.,JJ)'vv..JV~~-_. I I IJ) ~L~ -. " ~~jU _ 1000 10 .- -.... ---.- --.- I 20 - . ,..- .... - - -. r- . . 30 -.-..-.-.--- --------~-------- I' 40 T '. ... ,. -. I 50 .-- . - - -- ...---. - -.---.. -~-- -- . I 60 __.__min - -- --- .---- ---- --- ---- -- . .-- WR~'T'P()R'T' 'T'R~HNOT.OGY ~EN'T'ER TN'T'"RRNA'T'TONAT. ] GMC Data Report 288 Page 60f21 ] WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS -J SAMPLE : No Name Island #1 DATA FILE WF9195.D 12830..12900 10' cuttings CPI VALUE 1.02 PRISTANEJPHYTANE 0.97 ;] N-C9/N~C 19 0.00 PRISTANEJN-C17 0.66 N-C15/N-C25 0.43 PHYTANElN-C18 0.53 RFTFNTION E.EðK. ðB..Eð EEAK. HF.IGHT 1 COMPOUND IIME ðEEA N-Ç15=1 HEI~HT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 1.06 37 0.001 47 0.003 rJ N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.0.00 I J N-C10 15.38 404 0.008 145 0.008 N-C11 18.11 462 0.009 114 0.006 N-C12 20.69 474 0.009 244 0.013 I] N-C13 23.12 2883 0.055 1153 0.062 N-C14 25.40 9143 0.173 3693 0.197 N-C15 27.56 25186 0.477 8513 0.455 N -C 16 29.61 34200 0.648 12715 0.680 I] N-C17 31.55 52816 1.000 18704 1.000 N-C18 33.40 67629 1.280 22245 1.189 N-C19 35.16 57772 1.094 20477 1.095 .] N-C20 36.83 59711 1.131 20554 1.099 N-C21 38.43 ' 59304 1.123 20019 1.070 N-C22 39.96 61611 1.167 20575 1.100 ..] N-C23 41.43 63905 1.210 21322 1.140 N-C24 42.84 59186 1.121 18914 1.011 N-C25 44.19 58769 1.113 18699 1.000 N-C26 45.50 47048 0.891 16361 0.875 l~ N-C27 46.75 33614 0.636 11320 0.605 N-C28 47.96 26313 0.498 8250 0.441 N-C29 49.14 26359 0.499 8323 0.445 N~C30 50.27 18675 0.354 6106 0.326 N-C31 51.37 15862 0.300 5303 0.284 IJ N-C32 52.43 10765 0.204 3590 0.192 N-C33 53.47 10513 0.199 3444 0.184 N-C34 54.47 8239 0.156 2571 0.137 1] N-C35 55.44 7801 0.148 2596 0.139 N-C36 56.39 6270 0.119 2002 0.107 N-C37 57.31 7082 0.134 2070 0.111 N-C38 58.21 5693 0.108 1871 0.100 1] N-C39 59.08 4733 0.090 1491 0.080 N-C40 59.94 4401 0.083 1396 0.075 N -C41 60.77 3011 0.057 1076 0.058 I J N-C42 61.63 3555 0.067 1035 0.055 N-C43 62.59 3345 0.063 839 0.045 N-C44 63,65 2940 0.056 611 0.033 pristane 31.74 34875 10779 -.-J Phytane 33.63 35938 9090 7J · ~ \-Ii .~ r- .~. ~ ~ ~ - ~ -- ~ - - -, - ....., :L..-..!1.......J1-.J1-.J1-J1-.J1-.JL-.lL-.lL-JL-JL-Ji.-JL-.lI--IL-.lI..-II..-II..-I ---------~-----~-- a ~ () tj ~ ~ ~ ------------?e--- CÐ "'d o ::4. tv 00 00 No Name Island #1 12830-12900 -----FID2-B-;-(G:\HPGHEM\WR001[\WFHf95:D) counts 30000 - 25000 - 20000· ~ ~ (JQ CÐ --:t o I--t) tv Þ--" 15000, 10000· 50oot~,~·~l'~M~d.. . ~. ~ ~~~,~~JJ.'À<rM^,~l<."~,~UJJ,^-l¡, M~J¡}, ~~ o .~___ __.A.....-..-'_.L.L......J¡¡j)J...J¡· ),. \ V' ~. 10 I 20 I 30 I 40 I 50 I 60 _ min. - ------------------------ - --.---,. _.___u________ -r.T,-,r-rro....."'.....rn mT1r"1TT1'Tr\T r\ro~T rop1>Tmr:>n -r1>Tmron",-T7\ mTr'\~T7\ T I .J GMC Data Report 288 Page 80f21 ] .. WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS . SAMPLE : No Name Island #1 DATA FILE WF9196.D .J 12936 Core Chip CPI VALUE 0.97 PRISTANEJPHYTANE 0.94 N-C9/N-C 19 0.00 PRISTANEJN-C17 0.64 . ] N-C15/N-C25 0.14 PHYTANElN-C18 0.43 RFTfNTION E.EAI$... ðßE.ð E.fAK. HFIGHT .] COMPOUND Il.Mf ð.Bf8 N-C15=1 HFIGHT N-C15=1 N-C4 0,00 0 0.000 0 0.000 N-C5 1.06 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 .J N-C7 0.00 0 0.000 0 0.000 N-C8 0,00 0 0.000 0 0.000 N-C9 12,22 200 0,003 81 0.004 .] N-C10 15,27 1635 0,026 433 0.020 N-C11 18,08 3734 0,060 1269 0.059 N-C12 20.68 6638 0,107 2587 0.121 .J N-C13 23.12 11536 0.186 4590 0.214 N-C 14 25,50 3529 0,057 952 0,044 N-C15 27,56 34998 0,565 11929 0.556 N-C16 29.61 40189 0.649 14901 0.694 .J N-C17 31.55 61958 1.000 21467 1.000 N-C18 33.40 98145 1.584 33200 1,547 N-C19 35.18 129572 2.091 44107 2.055 .-J N-C20 36.87 196204 3,167 56914 2.651 N-C21 38.48 232505 3.753 64622 3.010 N-C22 40,03 268490 4.333 71382 3,325 N-C23 41.50 276668 4.465 70400 3.279 .J N-C24 42.91 276540 4.463 69089 3.218 N-C25 44.27 243783 3.935 61202 2,851 N-C26 45.58 240345 3.879 62371 2.905 .J N-C27 46,83 163697 2,642 47029 2.191 N-C28 48.04 138227 2.231 38937 1,814 N-C29 49,21 118557 1.914 34846 1.623 1-] N-C30 50.34 93811 1.514 27056 1.260 N-C31 51.43 81356 1,313 23934 1.115 N-C32 52.49 53284 0.860 16274 0.758 N-C33 53.53 51288 0,828 15337 0.714 ,J N-C34 54.53 35359 0.571 11083 0.516 I_J N-C35 55.49 36346 0.587 11461 0,534 N-C36 56.44 29083 0.469 8769 0.408 N-C37 57.36 34430 0.556 10271 0.478 N-C38 58.25 26273 0.424 8792 0.410 l] N-C39 59.12 21418 0.346 6862 0.320 N-C40 59.98 19284 0.311 6163 0.287 N-C41 60.80 13486 0.218 4721 0.220 IJ N-C42 61.67 15809 0.255 4544 0.212 N-C43 62.62 13981 0.226 3337 0.155 N-C44 63.70 11139 0.180 2446 0.114 L Pristane 31.73 39413 12055 --~ Phytane 33.63 42017 12167 ~. ~ 1-..; ~ 1--' L-' I-' L.-' L-' L.-..J I-...i ........., L-....J ......., ___ __ ..-----FI02-a-,--'(C:YRPCHEM\WHOOIC\WF9-196:0r---- counts 100000 ---~----_. ---~---.------------~----------~-------..--.-~._--~-.-~------~.--_. ----.---..---.--- ."---.--- Q ~ (j ____t1 . ~ ~ ~ id CÐ ÞOtj o ::t N 00 00 No Name Island #1 12936 80000 - 60000 -. 'ïj ~ (JQ CÐ \0 o I-+¡ tv 40000 20000 J1J \¡ ~..~ #J, \' ~MfhI ~M'~ Nvfwl\lVv.....}A..L.~L~ JJJ~ ~,JÞ)Å. . ~~'^-~~~ o _ ._,__.~...____ --,_.__~__......J__.--J._~_L ~I}\A - _ ·-·---r--·----·I--~- I 2'0 -----r--------.-- -.------- 3'0 '_=:- --.-:~=_-=.·4C_~~:_-:==~- ·---:~b-~~_=_~_====~~ ~.:~.~___..~~_-=~=_~-.~~~_T_~_-m¡n 10 ---. ----~.._- ----- ----,_. ---_.. -----._-- .---- WESTPORT TECHNOLOGY CENTER INTERNATIONAL ] GMC Data Report 288 Page 10 of21 ] .- WHOLE Oil GAS CHROMATOGRAPHY - N-AlKANES AND ISOPRENOIDS -J SAMPLE : No Name Island #1 DATA FILE WF9197.D 13668w13672 Core Chip CPI VALUE 1.02 PRISTANE/PHYTANE 0.95 N-C9/N-C19 0.00 PRISTANElN-C17 0.58 ] N-C15/N-C25 0.21 PHYTANElN-C18 0.45 RFTFNTION E.E.ðK. ðBE6 ~ HfJGHT 1 COMPOUND IlM.E ð8.EA N-C15=1 HFLGHT N-C15=1 N-C4 0.00 0 0.000 0 0.000 N-C5 1.05 0 0.000 0 0.000 r] N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 ,] N-C10 0.00 0 0.000 0 0.000 N-C 11 18.10 670 0.007 174 0.005 N-C12 20.69 624 0.006 227 0.007 rJ N-C13 23.11 905 0.009 377 0.011 N-C14 25.40 3724 0.037 1530 0.045 N-C15 27.56 22784 0,229 7145 0.209 N-C 16 29.62 57223 0.574 20349 0.596 r] N-C 17 31.57 99698 1.000 34141 1.000 N-C 18 33.43 136341 1.368 42388 1.242 N -C 19 35.19 108650 1.090 36971 1.083 I] N-C20 36.87 97585 0.979 34223 1.002 N-C21 38.47 114294 1.146 34945 1.024 N-C22 40.01 109965 1.103 35796 1.048 N-C23 41.48 127595 1.280 38657 1.132 1-3 N-C24 42.90 123893 1.243 37249 1.091 N-C25 44,26 111130 1.115 33578 0.984 N~C26 45,56 106389 1.067 34045 0.997 ] N-C27 46.82 99705 1.000 30669 0.898 N-C28 48.04 85890 0.862 25374 0.743 t] N-C29 49,22 70583 0.708 22527 0.660 N-C30 50.34 72383 0.726 21663 0.635 N-C31 51.45 59767 0.599 19276 0.565 I ] N-C32 52.50 39152 0.393 13250 0.388 N-C33 53.54 36441 0.366 11666 0.342 N-C34 54.54 19241 0.193 6566 0.192 1_] N-C35 55.51 18127 0,182 6321 0.185 N-C36 56.45 1.1857 0.119 3849 0.113 N-C37 57.36 11946 0.120 3814 0,112 N-C38 58.27 12549 0.126 4040 0.118 LJ N-C39 59.15 10892 0.109 3517 0.103 N-C40 59.99 8281 0.083 3002 0.088 N-C41 60.82 5498 0.055 1732 0.051 I J N-C42 61.69 8101 0.081 2155 0.063 N -C4 3 62.66 5286 0.053 1310 0.038 N -C44 63.73 3209 0.032 762 0.022 L] Pristane 31.75 58024 17642 Phytane 33.65 61103 15846 ~J . ~ ~ ~ ~ ~- - ~- - - - ~ ~ - ~ ~ - ~ - ~ ~ . L..J LJ LJ L.J L..J L-J L..J L...J L-J - L....J i-J L-J L-J L...J L-J L-I I-J L-.I ~ --------FID2-S;--(C:'lFJPCHEM\WRU01DWF9T9TDJ-=----------------- - __u -- . - ------ - -------- -- ----- ---- --- - ------.----------- ---. -----. ____ _ .______~v___________·________ ---- a ~ n t1 ~ ~ ~ id --------------- (þ- - "'d o ::4. tv 00 00 No Name Island #1 13668-13672 counts 60000 u 50000 - Þ-O ~ (JQ 40000 CÐ Þ--" Þ--" 0 ÞO-fo) tv Þ--" 30000 -- 10000 - . ~ J I \~ IJwt 1M + i 'ih.~~ ~ J\hh~ f;¡ f\~ ~~\~14 I f1 ~\J_ \ t I~~^ _ II -~_ ~#-J - o _ _ _ __,_"-___.. _ _ _-" .^__,_,_.__^L.~~--).,~_.kA-JJ 20000 - 10 - _,_ .. .. .....----.-- - -I'· _.... "'1·_------:"1----.-----,--.-- ----r--.-------.-~-------.-- _u__ roo -- -.' or --- - I --- ---y------,-- I r--u---r------,-----'---. r---'u- - --- .-----.~-.-.-- - - ---I ---'- - .. _u_ ___u_____.___1º___u________________ 30 ________ ___ __ .__ _____. _ ___~u_ _____ ______ ___~__________ .._____u _______ 60 ___ .,..._______________________-1]1io - - --.-- ____A f_1V(""tmTtf"'T'\rT"1 rT'Il'r"fTT""-Tr'\.T r"\."""""I[T r-w.....-.....T,......,,.....,T""'I. --........----------~ -- ------- I, I ] GMC Data Report 288 Page 12 of21 ] - WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS I SAMPLE : No Name Island #1 DATA FiLE WF9198.D r] 13869 Core Chip CPI VALUE 1.36 PRISTANE/PHYTANE 1.36 N-C9/N-C 19 0.00 PRISTANE/N-C17 0.70 .J N-C 1 S/N-C25 0,22 PHYTANElN-C18 0.76 RFTFNTION ~ 8.B.E8 EEAK. HFIGHT I] COMPOUND IlMf ðRE8 N-C15=1 HFIGHT N-C15=1 N-C4 0.72 0 0.000 0 0.000 N-C5 1.05 0 0.000 0 0,000 N-C6 0.00 0 0.000 0 0.000 .J N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 .] N -C 1 0 15.40 407 0.041 112 0.031 N-C11 18.13 183 0.019 61 0.017 ' N-C 12 20.73 298 0.030 104 0.029 .- ] N-C13 23.15 369 0.038 158 0.044 N-C14 25.44 1187 0.121 484 0.134 N-C15 27.60 3257 0.332 1093 0.302 N-C16 29.64 5965 0.607 2202 0.609 I"] N-C 17 31.58 9822 1.000 3616 1.000 N-C18 33.43 6598 0.672 2285 0.632 N-C19 35.29 8403 0.856 2654 0.734 ""] N-C20 36.96 3739 0.381 1016 0.281 N-C21 38,48 14915 1.519 3183 0.880 . N-C22 40.01 7839 0.798 3070 0.849 .J N-C23 41.49 13047 1.328 4505 1.246 N-C24 42.90 12933 1.317 4666 1.290 N-C25 44.26 14581 1 .485 4264 1.179 N-C26 45.57 15012 ,1.528 4313 1.193 ] N-C27 46.84 15005 1.528 4487 1.241 N-C28 48.05 3705 0.377 1626 0,450 --J N-C29 49,23 4190 0.427 1943 0.537 N-C30 50.37 13928 1.418 3819 1.056 N-C31 51.29 12532 1.276 4115 1.138 I] N-C32 52.54 981 0.100 569 0.157 N-C33 53.44 4335 0.441 1652 0,457 N-C34 54.37 1385 0.141 640 0.177 .' N-C35 55.34 998 0.102 405 0.112 N-C36 56.49 1668 0.170 832 0.230 , -] N-C37 57.42 1998 0.203 760 0.210 N-C38 58.31 1620 0.165 594 0.164 --J N-C39 59.04 1095 0.111 541 0.150 N-C40 60.05 1954 0.199 647 0.179 N-C41 60.72 544 0.055 404 0.112 1_] N-C42 61.56 523 0.053 271 0.075 N-C43 62.71 536 0.055 264 0.073 N-C44 63.67 327 0.033 138 0.038 LJ Pristane 31.77 6853 2175 Phytane 33.82 5043 1354 .] - L-JL-!'--'L-'~L.....:L-...:i--i.-..IL-...J---""""" -- - FIOTS;' -(G:\HPCHEM\WHOOIl\WF9.f98:0r------------------- ---.-- --- - - "-- -----_.- ...-- ---- .---- --- - - ------.-.+._- '- __ .".__ ___. ._. .___,___ n__________."," a ~ (1 a --~- ~ ~ id CÐ ÞO(j o ::4. tv 00 00 No Name Island #l l3869 counts 30000 25000 20000- 5000- \tl 1\ ~ 'I) \ o· ___~___ .A_M__k~_'~..L-L~J~~,1 · ~I'; ~ ~"l I rA~ \' IV f'ftI 'I\:I ~II., lJM¡Vpr ~~~~~\ J~' ß ",.(lil \ ~ ...~~ ~~ ~'- -~ ~ PJ (JQ CÐ 15000 u ~ v.> o I-+¡ tv Þ--" 10000 ------y---- -'-r~'- ---,----'-r- -----T---- I 10 20 - ---.---...--'.-----....-.-.-. --.-..-_..---_._-._-~.-.-._--- 30 I - --~-~- ~ r----r--··---~r_---.----,-~-.--- r 40 ---+--- ---- .'-------------.-- -- . ~--- 50 u=:~ ~=-=-__==_=~6Ó __~.-~ -.~.----~=_-_~~-~=~m¡~ WESTPORT TECHNOLOGY CENTER INTERNATIONAL ) GMC Data Report 288 Page 14 of21 ] .. WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS ) SAMPLE: Cross Island #1 DATA FILE WF9199.D 9560-9650 10' cuttings CPI VALUE 1.25 PRISTANEJPHYTANE 2.17 N-C9/N-C 19 0.00 PRISTANE/N-C17 0.66 J N-C15/N-C25 8.65 PHYTANEJN-C18 0.47 RFTFNTION E.E8K. , 88.f.ð .Ef8K. HFIGHT J COMPOUND II.Mf AB.E8 N-C15=1 HFIGHT N-C15=1 N-C4 0.73 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 J N-C6 0.00 0 0.000 0 0,000 N-C7 0.00 0 0,000 0 0.000 N-C8 8.89 128 0.004 88 0.007 N-C9 0,00 0 0.000 0 0.000 I N-C 10 15,39 1657 0.050 711 0.060 N-C 11 18.12 4100 0.125 1468 0.124 N-C12 20.72 10805 0.328 4220 0.356 J N-C 13 23,16 24417 0.742 9541 0.805 N -C 14 25.45 52382 1.592 19955 1.684 N-C15 27.62 73742 2.241 24988 2.108 N-C16 29.65 48181 1 .464 18082 1,526 J N-C17 31.58 32906 1.000 11852 1.000 N-C18 33.42 21225 0.645 6962 0,587 N-C19 35,17 11473 0.349 4239 0.358 J N-C20 36.84 8383 0.255 3026 0.255 N-C21 38.44 9890 0.301 3033 0.256 N-C22 39,97 6867 0.209 2492 0,210 J N-C23 41.44 8280 0.252 2894 0,244 N-C24 42.85 4240 0.129 1575 0.133 N-C25 44.21 8528 0.259 2138 0,180 N-C26 45.36 4908 0.149 1235 0.104 I N-C27 46.77 6296 0.191 2163 0.183 N-C28 47,98 7109 0.216 1325 0.112 N-C29 49.16 6654 0.202 2039 0.172 I N-C30 50.30 2974 0.090 973 0.082 N-C31 51.41 4764 0.145 1538 0.130 N-C32 52.47 2766 0.084 743 0.063 I N-C33 53.51 3617 0.110 720 0.061 N-C34 54,50 794 0.024 294 0.025 N-C35 55.48 1455 0.044 519 0.044 N-C36 56.43 408 0.012 158 0.013 N-C37 57.35 761 0.023 153 0.013 N-C38 58.26 439 0.013 137 0.012 N-C39 59.11 155 0.005 45 0,004 N-C40 59.93 151 0.005 67 0.006 N-C41 60.67 345 0,010 47 0.004 N-C42 61,67 317 0.010 85 0,007 N-C43 62.55 371 0.011 90 0.008 N-C44 63.76 314 0.010 74 0.006 Pristane 31.77 21702 6755 Phytane 33.65 9998 2571 ~L-.JL-..:IL-...Ji-.JI.-..Ji..-.JL-..JL....JL-JL-..J&....-.J'--''---''''--I_____ Cross Island #1 9560-9650 Q ~ (l a ~ ....... ~ id CÐ ÞOtj o :¡ tv 00 00 FID2-S; (C:\HPCHEM\WHOOIL\WF9199:0r-.----.... --------.--,-. _u. ----. counts _ 30000 25000 20000· ~ ~ (JQ CÐ ...... v-. 0 I-+¡ 15000, tv Þ--" 10000 5000 . If I,~ w'f ¡ ~wMl~, ~.t"'^'w..UÀ__J~'~dJ.1j)J~ ~~~~-~~-- o _,__~~l^J,,_JL~~4~M ~l' 10 ~-rn__-, ~~2b _,_ -_.,~--.-~~= _._______.~º-_~'------ -,---,- ----- -T" n --40· :- . . .' ~.=:-==__~_.______'=--_~-_-~~=~~~. -=-~~- _~'_.~§º'---_-' -~_~--I--- -'--.-:--' -- -~¡~ WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 288 Page 16 of21 WHOLE all GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE : Cross Island #1 DATA FILE WF9200.D 9660-9710 10' cuttings CPI VALUE 1.29 PRISTANE/PHYTANE 2.54 N-C9/N-C 19 0.00 PRISTANElN-C17 0.71 N-C 15/N-C25 3.48 PHYTANE/N-C18 0.38 RFTFNTION fEAK. AB.E.ð E.EAK. HFIGHT COMPOUND IJ.ME. ðB.f.ð N-C15=1 HFIGHT N-C15=1 N-C4 0.73 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 N-C7 0,00 0 0.000 0 0.000 N-C8 0.00 0 0.000 ° 0.000 N-C9 0.00 0 0.000 0 0,000 N -C 1 0 0.00 0 0,000 0 0.000 N-C 11 0,00 0 0.000 0 0.000 N-C12 20.71 1527 ' 0.062 611 0.065 N -C 13 23.14 8802 0.358 3473 0.370 N-C14 25,44 29159 1.185 11744 1.250 N-C15 27.60 52762 2.144 17945 1.910 N-C16 29.64 38218 1.553 14114 1.502 N-C17 31,58 24606 1.000 9397 1.000 N-C18 33.41 18057 ,0.734 5910 0.629 N-C19 35,16 11205 0,455 4065 0.433 N-C20 36,84 9845 0.400 3331 0.354 N-C21 38.43 11580 0.471 3483 0.371 N-C22 39,97 8069 0.328 3015 0.321 N-C23 41 .44 11 042 0.449 3845 0.409 N-C24 42.84 8104 0.329 3026 0.322 N-C25 44,21 15148 0.616 3943 0.420 N-C26 45,35 5859 0.238 1491 0.159 N-C27 46,77 7939 0.323 2616 0.278 N-C28 47,98 7720 0.314 1351 0.144 N-C29 49.16 5894 0.240 1966 0.209 N-C30 50.29 2541 0.103 743 0.079 N-C31 51.39 2594 0.105 898 0.096 N-C32 52.46 1686 0.069 419 0,045 N-C33 53.50 1632 0.066 503 0.054 N-C34 54.50 476 0.019 175 0.019 N-C35 55.47 1043 0.042 281 0.030 N-C36 56.42 272 0,011 101 0.011 N-C37 57.35 289 0.012 103 0.011 N-C38 58.24 542 0.022 111 0.012 N-C39 59,12 220 0.009 89 0.009 N-C40 59,97 974 0,040 194 0.021 N-C41 60.80 1656 0.067 357 0.038 N-C42 61.68 1840 0,075 436 0.046 N-C43 62,63 1926 0.078 454 0.048 N-C44 63,71 1937 0.079 421 0,045 Pristane 31.76 17511 5402 Phytane 33.64 6895 1907 WESTPORT TECHNOLOGY CENTER INTERNATIONAL mir¡ -. -.,------"'T-~ ---'''I'''--~'--- r----'o.'" r - . --- -y---------r- -. .--- r -- --1-----1- ---- ----I -- . 50 60 ---- -" -.-.-.--.-.._- .'---' .- -- ----- . ---- -,- ·4h-- .------ --J'- --, ..-.,-- --~'r-- ----r---- --.- - ----.....-- 20 30 10 ~! JM} " j' k 4 ~ tAil ,'^'" I,J. \M.. . JJ..J.., __~.J~....AJ~' ' W>"^,,,,\.rv"l,J1I.._L,J,j~ - ~'--^--^--_.~^- 0- 2500 - 5000 - 15000 - 12500 ~ ~ (JQ CÐ ¡......L -......J 10000- 0 I-+¡ N Þ--" 7500 - 17500 - Q s:: o ..tJ- ~ ~ ~ ¡o (1) "d o ::4. N 00 00 20000- . ----- -" --- -- -"- - ---- - - - '--' ---------.-- -"---"---- ---~--~---_.. - -- ----····FID2- B: ·(G:\HPCHEM\WHOOIL\WF9200~D)-·------ counts - Cross Island #1 9660-9710 ~ ""---' ......- '--' ......... L;.... '--' L-J L-J '---I L-J ~ GMC Data Report 288 Page 180f21 WHOLE Oil GAS CHROMATOGRAPHY - N-AlKANES AND ISOPRENOIDS SAMPLE : Cross Island #1 DATA FILE WF9201.D 13240-13280 10' cuttings CPI VALUE 1.22 PRISTANElPHYTANE 1.74 N-C9/N-C 19 0.00 PRISTANElN-C17 0.55 I N-C 15/N-C25 1.74 PHYTANElN-C18 0.36 RFTFNTION ~ ~ EfA1i HflGHT I COMPOUND IlME AB.E6 N-C15=1 HF1~HT N-C15=1 N-C4 0.71 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 I N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 I N-C10 0.00 0 0.000 0 0.000 N-C 11 0.00 0 0.000 0 0.000 N-C12 20.71 1523 0.017 516 0.017 ] N-C13 23.15 29496 0.336 10605 0.350 N -C 14 25.46 86352 0.983 32426 1.071 N-C15 27.63 118168 1.346 38091 1.258 ] N-C16 29.66 93599 1.066 32809 1.084 N-C17 31.60 87815 1.000 30273 1.000 N -C 18 33.44 77923 0.887 25388 0.839 N-C19 35.20 55101 0.627 18283 0.604 ] N-C20 36.88 48388 0.551 17054 0.563 N-C21 38.47 42406 0.483 15151 0.500 N-C22 40.00 43653 0.497 15483 0.511 ] N-C23 41 .46 44542 0.507 15022 0.496 N-C24 42.87 34949 0.398 12714 0.420 N-C25 44.29 67904 0.773 25326 0.837 N-C26 45,53 24473 0.279 8341 0.276 J N-C27 46.78 20584 0.234 7398 0.244 N~C28 48,00 14605 0.166 4873 0.161 N-C29 49.17 15748 0.179 5000 0.165 ] N-C30 50.30 11149 0.127 3710 0.123 N-C31 51.23 14217 0.162 4592 0.152 N-C32 52.46 5130 0.058 1602 0.053 ] N-C33 53.38 6717 0.076 2192 0.072 N-C34 54.51 2155 0.025 804 0.027 N-C35 55.48 3475 0.040 1192 0,039 N-C36 56.43 2477 0.028 836 0.028 ] N-C37 57.35 5276 0.060 1621 0.054 N-C38 58.25 7508 0.085 2331 0.077 N-C39 59.13 7940 0.090 2453 0.081 ] N-C40 59.98 8081 0.092 2756 0.091 N-C41 60.81 8340 0.095 2604 0.086 N-C42 61.68 10364 0.118 2912 0.096 ] N-C43 62.65 7811 0.089 1915 0.063 N-C44 63.72 7487 0.085 1605 0.053 Pristane 31.78 48564 15123 ] Phytane 33,69 27965 10273 \!!II __ iL..__ IIL-lá-""--___ie---ooiw.-....,,¡~~........__ ..- -- - --FID2-S-; (C:\HPCHEM\WHOOIl\WF920r:O}--- counts 50000 - ____ __ _ ___ _ __ _ __ 4_. _._ _____ _.____.~.___...____ .. CJ ~ (') -J:1 ~ ~ ~ :;0 CÐ '1:S o :4- tv 00 00 Cross Island #1 13240-13280 40000- ~ ~ 30000 - O'Q CÐ \D 0 Hj tv Þ--" 20000 - , ,l 'J d. ¡\ ~ " o-._.____~~~_~ .., ~ ¡' ~ ~ ~ : 1 \ ~ \ · f¡.~. I ~ W Jv~ Ifh . d . I. . I I I I I .JßVVlv~MW~~-l~L-._A 10000 - 10 ---~---~---_._._-- ------ I 20 .._--------~-~~- 3h 4'0 I 50 ,-----.---- I -.---------.--- 60 -------- ------~--- --.---- __min WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 288 Page 20 of21 WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE : Cross Island #1 DATA FILE WF9202.D 13930-13980 10' cuttings CPI VALUE 1.16 PRISTANElPHYTANE 1.74 N-C9/N-C 19 0.00 PRISTANE/N-C17 0.57 N-C 15/N-C25 6.32 PHYTANE/N-C18 0.49 RFTFNTION f.EAK. ðB.EA ff8K. HFIGHT COMPOUND II.Mf ðaf8 N-C15=1 HFIGHT N-C15=1 N-C4 0.73 0 0.000 0 0.000 N-C5 0.00 0 0.000 0 0.000 N-C6 0.00 0 0.000 0 0.000 N-C7 0.00 0 0.000 0 0.000 N-C8 0.00 0 0.000 0 0.000 N-C9 0.00 0 0.000 0 0.000 N-C10 15.42 137 0.015 60 0.017 N-C 11 18.10 314 0.034 136 0.040 N-C12 20.71 1620 0.175 638 0.186 N-C 13 23.14 5110 0.553 1978 0.576 N-C14 25.43 14063 1.522 5673 1.652 N-C15 27.59 19985 2.163 6859 1.998 N-C16 29.62 13742 1.487 5038 1.468 N-C17 31.56 9241 1.000 3433 1.000 N -C 18 33.40 6165 0.667 2140 0.623 N-C19 35.15 4120 0.446 1454 0.424 N-C20 36.82 3201 0.346 1188 0.346 N-C21 38.43 3547 0.384 1197 0.349 N-C22 39.95 3225 0.349 1022 0.298 N-C23 41.43 2707 0.293 973 0.283 N -C24 42.83 2441 0.264 877 0.255 N-C25 44.20 3164 0.342 828 0.241 N-C26 45.50 1385 0.150 481 0.140 N-C27 46.76 1002 0.108 365 0.106 N-C28 47.97 873 0.094 254 0.074 N-C29 49.15 902 0.098 271 0.079 N-C30 50.28 593 0.064 203 0,059 N-C31 51.20 1435 0.155 402 0,117 N-C32 52.45 544 0.059 139 0.040 N-C33 53.36 425 0.046 151 0.044 N-C34 54.49 199 0.022 69 0.020 N-C35 55.46 304 0.033 83 0.024 N-C36 0.00 0 0.000 0 0.000 N-C37 0.00 0 0.000 0 0.000 N-C38 58.24 191 0.021 42 0.012 N-C39 0.00 0 0.000 0 0.000 N-C40 59.97 106 0.011 34 0.010 N-C41 60.80 14 0.002 17 0.005 N-C42 0.00 0 0.000 0 0.000 N-C43 0.00 0 0.000 0 0.000 N-C44 0.00 0 0.000 0 0.000 Pristane 31.75 5290 1687 Phytane 33.64 3034 791 · ~ .... ~. ,.... ~. ~ ~ -~ ~ ¡-¡ --, r-: ~ ~LJL.JL.JL-.JL.JL-JL-JL-JL-JL...JL....JL-JL...J I-J , I L-J L...J L...J , L-J - t-ID2t3~C:mPCREM\WAOOIL\WF9Z0LD) counts - 10000 - ------_.---- --- - ------------,----- --~---------_.._------_._- Q ~ (j ö ~ .-t" ~ ~ CÐ ÞOtj o ~ tv 00 00 Cross Island #1 13930-13980 8000 - 6000 - ~ ~ (JQ CÐ tv Þ--" o H") tv Þ--" 4000 -- 2000 -' o ~~~.,"1 j ,-j., I, J M I,. /w! .~ \ tu..,-4 .1 ~-M.~l.-,~ ------1- ·-....-_····--r-· ~. ----r·--T--·----r-·----ï----r---.-~-r------~.----~---T-------r-----l-- ~-- . -----r-------,-------,----~--T·-----.-----r_------T------- -,-----------y------- -,- --"- - . __ ___._~º_______._ __ .______ _. ____ ~º__________ __ .___________~___ _____ _______ ______u_______~u__u_ __________~__ _____ ______ _____________.60 ___ _ _ ___ n_._ ___ __ .miL WESTPORT TECHNOLOGY CENTER INTERNATIONAL