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GMC Data Report No. 302
Petroleum geochemistry of extracts from cuttings of the following northern Alaska exploratory wells: Husky Oil NPRA Operations (D. S. Navy) East Teshekpuk No.1 (7,090'-7,180'), and Husky Oil NPRA Operations (D. S. Navy) West Fish Creek No.1 (5,520'-5,780'; and 7,460'- 7,580'). , .~K'~:··;';;,;,;~~.~"'· >~. ,¡ ~..;. .;"~~. '",,-..ë;,.(;t . "'.,~-""'..~.~. '. ";J-.7· . IL"':":'Jo;:'$ ~.:-.,'~.... . ~'. r'~ . ... .. .,: '. ~II·.-'§. ~'/'~""'~ .. ,..- .. .;.. -;.. . . ~ ....·f;. "'... .. ..:- Received 29 March 2002 Total of 49 pages in report Alaska Geologic Materials Center Data Report No. 302 GMC Data Report 302 Page 1 of 49 IE81PORT TEC..IL..' CEI'U '''TEI.AnOIAL Petroleum Geochemistry PF-99-061 JunE: 1999 ~'.t~ ~-!!f ~ EAST TESHEKPUK AND WEST FISH CREEK EXTRACTS Author: R.J. Drozd Work by: R.J. Drozd and J. Scholten Westport Technology Center International 6700 Portwest Drive Houston, Texas 77024 (713) 479-8400 (713) 864-9357 (Fax) www.westport1.com Prepared for BP-Amoco (Alaska), Inc. W.O.#: D103690000 Westport Technology Center International makes no representations or warrantIes, either express elr Implied, and specifically provides the results of this report Has IsH based on the Information provided by client. WESTPORrport 302 Page 2 of 49 TECHNOLOGY CENTER INTERNATIONAL 6700 Portwest Drive, Houston, TX 77024 (713) 479·8400 (713) 864-9357 fax June 14, 1999 Mr. Gary Pelka BP-Amoco (Alaska) Inc. 900 E. Benson Blvd. Anchorage, AK 99519-6612 Subject: Issue of East Teshekpuk and West Fish Creek Extracts Dear Gary: Enclosed are two (2) copies of the subject report; one copy has also belen sent to Stephan directly. All three samples were heavily contaminated with what appears to be drilling mud base oil. The chromatograms illustrate this directly, as do the normal alkane distributions for each oil (Figures 1 and 2). The high level of contamination makes comparisons of the oils difficult, not only because the wholle sample chromatogram is impacted, but also because the additive may have picked up biomarkers from other intervals in the well. This could be a larger consideration with the Teshekpuk well sample, because biomarker yields were lower. However, the normal alkane distributions above N-C25 are roughly similar for all three samples, particularly the Fish Creek extracts. Biomarkers show that the Teshekpuk sample has a different compound distribution, particularly in the tricyclics, than the Fish Creek extracts. Thank you for the opportunity to be of service to BP-Amoco (Alaska), Inc. If you should have any questions, please call me at (713) 479-8454. ~5: ~cS~ - ~~holten JS/pd cc: Mr. Gary Pelka (2) Mr. Stephan Duppenbecker, BP-Amoco (Houston) - (1) Files (2) PF-99-061 0103690000 WEs¥~~Pt~~W8CJæ CENTER INTERNATIONAL Page 3 of 49 Table 1. Summary Data Client ID E. Teshekpuk #1 W, Fish Creek #1 W. Fish C:reek #1 Depth (ft) 7090-7180 5520-5780 7460·'7580 Lab ID WF9759 WF9760 WF9761 L TSE Wt. (mgs) 12.4 32.6 25.1 0/0 T5 E 0.36 0.27 0.~~1 KGlTon TSE 3.60 2.71 2.115 Saturate % 14.2 47.7 33.4 Aromatic % <0.2 1.0 1.3 Polar % 85.8 51.3 65.3 Asphaltene % 0 0 01 Ô13C (%0) SOturate -29.56 -29.48 ' -29,,69 (3 t3C (%0) Aromatic -26.93 -27,16 -26,,96 Prepared for BP-Amoco (Alaska), Inc. 6/14/99 PF-99-061 Page 1 WESTPORT TECHNOLOGY CENTER INTERNATIONAL 9.0 8.0 - 7.0 - """ 0 £ 6.0 o- N 0 o I ~ B 5.0 --' c:: ra 'C c:: .5 4.0 --- ~ (þ > .. ra Q; 3.0-- 0::: 2.0 1.0 -- 0.0 5 ,~~ 10 Prepared for BP-Amoco (Alaska), Inc. 6/15/99 Normal Alkane Distribution - Figure 1. Normal alkane distributions showing the large contaminant peaks between N-C13 - and N-C24 - .....- East Teshekpuk#1 7090'-7180'- ___ West Fish Creek#1 5520'-5780' West Fish Creek#1 7460'-7580'_ 4 , \ -.or--- --- , ~~ -,..- - -- --"- -- ..... I ." ¥' -:-~ ==-t:...----" 15 25 35 20 30 Carbon Number PF-99-061 Q ~ (") tJ ~ <""t- P, ?:1 (t) '"d o ~ w o N 40 Þ-C p, OQ (t) ..¡:::.. o H) ..¡:::.. \0 Page 2 WESTPORT TECHNOLOGY CENTER INTERNATIONAL 10.00 -- - - ~ 1.00-- N o . ~ Q) o C ftS 'C C ::s .a « Q) > ~ ftS di 0.10· ~ û.ûÎ I 5 Prepared for BP-Amoco (Alaska), Inc. 6/15/99 Normal Alkane Distribution - "'--j 10 20 25 15 Carbon Number PF-99-061 Figure 2. Normal alkane distribution on a logarithmic abundance scale. Above N-C25 the distributions are similar. -+- East Teshekpuk#1 7090'-7180' --- West Fish Creek#1 5520'-5780' West Fish Creek#1 74601-7580' 30 35 C1 ~ (') t:I. p:¡ .-+ p:¡ ïO (I) þU o =::t.- v..> o 1'0 . 40 ~ p:¡ (JQ (I) V\ o ~ .þ. \0 Page 3 GMC Data Report 302 Page 6 of 49 WHOLE SAMPLE CHROMATOGRAPHY GMC Data Report 302 Page 7 of 49 WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE: East Teshekpuk#1 7090'..7180' DATA FILE: WF9759.D CPI VALUE 1.41 PRISTANElPHYTANE 2.24 N-C9/N-C 19 0.00 PRISTANElN-C17 0.10 N-C15/N·C25 3.88 PHYTANE/N-C18 0.05 RETENTION AREA PEAK HE GHT COMPOUND TIME PEAK AREA N-C15=1 HEIGHT N-C15=1 N-C4 0.00 0.00 0.000 0.00 0.000 N-C5 0.00 0.00 0.000 0.00 0.000 N-C6 0.00 0.00 0.000 0.00 0.000 N-C7 0.00 0.00 0.000 0.00 0.000 N-C8 0.00 0.00 0.000 0.00 0.000 N-C9 0.00 0.00 0.000 0.00 0.000 N-C10 0.00 0.00 0.000 0.00 0.000 N-C11 7.73 0.21 0.028 0.19 0.027 N-C12 8.79 0.57 0.076 0.49 0.069 N-C13 9.83 0.54 0.072 0.41 0.057 N-C14 10.73 19.06 2.548 15.25 2.143 N-C15 11.50 7.48 1.000 7.12 1.000 N-C 16 12.44 12.90 1.725 11.21 1.576 N·C17 13.16 13.03 1.742 9.32 1.310 N -C 18 13.97 10.79 1.443 8.80 1.236 N-C19 14.78 15.60 2.086 12.24 1.720 N-C20 15.36 3.38 0.452 2.69 0.378 N-C21 16.01 6.32 0.845 4.53 0.637 N-C22 16.64 8.56 1.144 7.01 0.985 N-C23 17.24 6.88 0.920 5.33 0.749 N-C24 17.81 4.31 0.576 3.40 0.477 N-C25 18.37 1.93 0.258 1.80 0.253 N-C26 18.90 1.82 0.243 1.32 0.186 N-C27 19.42 1.23 0.164 1.00 0.141 N-C28 19.91 0.75 0.100 0.58 ' 0.082 N-C29 20.39 1.00 0.134 0.79 0.111 N-C30 20.86 0.55 0.074 0.45 0.063 N-C31 21.31 0.42 0.056 0.37 0.052 N-C32 . 21.75 0.22 0.029 0.21 0.029 N-C33 22.17 0.84 0.112 0.49 0.068 N-C34 0.00 0.00 0.000 0.00 0.000 N-C35 0.00 0.00 0.000 0.00 0.000 N-C36 0.00 0.00 0.000 0.00 0.000 N-C37 0.00 0.00 0.000 0.00 0.000 N-C38 0.00 0.00 0.000 0.00 0.000 N-C39 0.00 0.00 0.000 0.00 0.000 N-C40 0.00 0.00 0.000 0.00 0.000 N-C41 0.00 0.00 0.000 0.00 0.000 N-C42 0.00 0.00 0.000 0.00 0.000 N-C43 0.00 0.00 0.000 0.00 0.000 N-C44 0.00 0.00 0.000 0.00 0.000 Pristane 13.22 1.30 1.19 Phytane 14.05 0.58 0.61 WESTPORT TECHNOLOGY CENTER INTERNATIONAL ~ ~ (Jq (!) 00 ~ +::-. \0 I 25 I 20 Q ~ (J o ~ .-t- ~ :::0 (!) ~ o :4. w o N I 15 I 10 .J. ..J ..~.IJJ¡/uHWJ'.dJ.L~ --L East Teshekpuk #1 7090-7180' ---.--- I 5 û-, o 10-~__~ 20-· 30 - 40- 50- 60 - 70- 80 - 90-· FID2 B, (WF9759.D) pA ~ FID2 B, (WF9759.D) pA _ 45- 40- 35- 30- 25-' 20- 15 - 10- . --"- --..Lo--..... 5- - o -t---.---,----,.-- . o East Teshekpuk #1 7090-7180' ~J Jj:N ~i1JJ.AI\ J.-,J..dl,~,-..L~Lut../ I 5 I 15 I 20 I 10 WESTPORT TECHNOLOGY CENTER INTERNATIONAL a ~ (J t:; p:I ...-t- ~ ~ (1) '1::S o ::t. lJ..) o N I 25 ~ p:I (Jq (t) \D '~ ~ \D 1'\ v -,_. o , 5 WESTPORT TECHNOLOGY CENTER I 10 INTERNATIONAL I 15 i 20 I 25 ~ ~ (JQ (i) ~ o o mil , I) -- +::-. \0 20- ø c Q) N 15 - c I/)Q)<O OcnO o E - E C\ CD I/) It) -m 0 ~ 10-I1DS 10 E E .. ~o IDO - ~~ ~~ 5- .- .- o z tC: UAc N M 2 {) {) JA _ ......,k.. flJ '<T Ü z (£ [ 2 « c: ~ <1J £ C Ú «1 1~~ I"- .- o Z ro E z m .- o z ~ C ~ 2 o 2 ræ~ N N o Z <D (f) lOO (jZ '<t'Z (f) o ~Z NO (f) .-0 Z 25- m (f) or- coO 0 ~ (f)Z ~ 0 o .Ü z ~Z ,~ ~ o 0 z 30- 35- 40 - pA -:- 45 -. FID2~{I:\GEOCHEM\HPCHEM\6B90\WF9759.D) East Teshekpuk#l 7090 -7180 Q ~ (1 t::1 ~ .....,.. p:¡ :::0 (1) "d o ::¡ w o N GMC Data Report 302 Page 11 of 49 WHOLE OIL GAS CHROMATOGRAPHY· N-ALKANES AND ISOPRENOIDS SAMPLE: West Fish Creek#1 5520'~5780' DATA FILE: WF9760.D CPI VALUE 0.85 PRISTANElPHYTANE 1.18 N-C9/N-C19 0.10 PRIST ANE/N-C17 1.34 N-C15/N-C25 1.22 PHYTANE/N-C18 0.54 RETENTION AREA PEAK HEIGHT COMPOUND TIME PEAK AREA N·C15=1 HEIGHT N-C15=1 N-C4 0.49 0.13 0.005 0.16 0,009 N-C5 0.66 0.03 0.001 0.06 0.003 N·C6 1.19 0.02 0.001 0.07 0.004 N-C7 2.48 0.04 0.002 0.07 0.004 N-C8 3.97 0.22 0.009 0.17 0.009 N·C9 5.35 0.89 0.036 0.79 0.042 N-C10 6.59 3.43 0.139 2.39 0.127 N-C11 7.73 6.06 0.246 4.07 0.216 N-C12 8.79 6.87 0.279 5.97 0.316 N·C13 9.78 9.61 0.390 8.40 0.445 N-C14 10.73 48.84 1.981 34.51 1.830 N-C15 11.59 24.66 1.000 18.86 1.000 N-C16 12.43 48.03 1.948 38.16 2.023 N·C17 13.16 20.12 0.816 13.62 0.722 N-C18 13,97 42.24 1,,713 32.67 1.733 N·C19 14.78 9.27 0.376 7.07 0.375 N-C20 15,36 32.87 1.333 26.10 1.384 N-C21 16.01 44.45 1.803 34.38 1.823 N-C22 16.64 58.39 2,368 46.89 2.486 N-C23 17.24 49.21 1.996 38.60 2.047 N-C24 17.82 32.91 1.335 26.96 1.430 N·C25 18.37 20.20 0,819 16.25 0.862 N-C26 18.90 16.82 0.682 13.51 0.716 N-C27 19.42 13.52 0.548 10.97 0.582 N-C28 19.91 11.59 0.470 8.22 0.436 N-C29 20.39 10.95 0.444 8.38 0.445 N-C30 20.86 7.42 0.301 5.31 0.282 N·C31 21.31 6.54 0.265 4.63 0.245 N·C32 21.74 4.25 0.172 3.14 0.167 N-G33 22.17 4.69 0.190 3.37 . 0.179 N-G34 22.58 1.87 0.076 1.41 0.075 N·C35 22.98 1.58 0.064 1.31 0.070 N·C36 23.36 1.74 0.071 1.38 0.073 N-C37 23.77 0.23 0.009 0.25 0.013 N·C38 24.10 1.60 0.065 1.21 0.064 N-C39 24.50 0.03 0.001 0.11 0.006 N-C40 24.87 1.06 0.043 0.76 0.040 N ·C41 0.00 0.00 0.000 0.00 0.000 N·C42 0.00 0.00 0.000 0.00 0.000 N·C43 0.00 0.00 0.000 0.00 0.000 N·C44 0.00 0.00 0.000 0.00 0.000 Pristane 13.21 26.95 20.68 Phytane 14.07 22.90 15.46 FID2 ß. (WF9760.0) pA -:: 90- 60- 70 - 60- 50 - 40- 30- 20- 10 ~ \ --~. o -t--.---~'-- 0__-- west Fish Creek 5520-5780' ..._~w ,~11'\ jl ~. ,1~~,1J¡J..-",^~",.>J,j.....-1 1 20 I 5 I 10 115 ~ WESTPORT TECHNOLOGY CENTER INTERNATIONAL . 25 Q ~ o e ~ -- p:¡ g: "d o :4- t;.J C N I¡j p:¡ (JQ CD I--" ~ -Þ \.0 FID2 8. (WF9760.D) pA -= 45 - 40- 35 - 30 - 25- 20- 15 - 10- _ ~ --1.1..-- 5- o -f o --r--- . West Fish Creek 5520-5780' ~ j~i h thl'IN .1..JJ.~\J ~ '.iI,.~~~ ~~¡wd' ..JJ I 5 I 10 I 15 I 20 WESTPORT TECHNOLOGY CENTER INTERNATIONAL a ~ (') t:1 ~ ....... ~ ?:1 (þ '"d o ::¡ Vol o tv ~ ~ (JQ ( ) 25 ......... w ~ ~ \.0 West Fish Creek#l 5520'-5780' FID2 B. (1:\GEOCHEM\HPCHEM\6890\WF9760.D) pA --:- <0 C\I (W) [) c;: C\I C\I ° ° Z «' C Z Z 2 '<:' 0 45- 0 2 Z 0 ~ 40- (\. C\I 0 ° Z Z CD 35- c «I êii .C: II) a.. 0 z Q Ie¡ 30- N c 0 r--- 4 Z "S<- O .r L <0 Z C\I 0 25 - Z I'- C\I ° 0..- Z ro~~~ C\I Q, <0 æ 1'-«)0°0 ~ «) C\I ° (W)OzZz 0 ~ 20- c.. o Z <DOZ~Z 0 -; Z 0...- (W) II)Mz I Z M «)M M MO 0 OCC\lO~02 C1J Z 2 8 28 z c Z Z Z ( ) C\I 15 - N 0 . ¡ If~ ~ '1~,þ.Jl J.'I}J.,J ,H1.,O¡,,¡,hIjJJlÞi- ~ c: II)<D ..... Z Om 0 r ~ u E 0 2 -i <3 CD 0 IJ, 10 -= ¡~ ({)~I'- Z .JJ¡w lJ , I .vI I'- O::JU ro ,(] - ~ o ~E 0 c. --~ Z --q- Z i- 5 -- Û. I I r I -----. 0 -- S 10 15 20 25 WESTPORT TECHNOLOGY CENTER INTERNATIONAL ~ þ:) OCI (1) ~ ~ o ~í +::. . \0 a ~ (J tJ p:¡ ~ p:¡ ~ (þ '"d o :::4- w o N , GMC Data Report 302 Page 15 of 49 WHOLE OIL GAS CHROMATOGRAPHY - N-ALKANES AND ISOPRENOIDS SAMPLE: West Fish Creek#1 7460'..7580' DATA FILE: WF9761.D CPI VALUE 0.97 PRISTANEJPHYTANE 1.18 N-C9/N-C19 0.04 PRISTANEJN-C17 0.64 N-C15/N-C25 2.59 PHYTANEJN~C18 0.37 RETENTION AREA PEAK HEIGHT COMPOUND TIME PEAK AREA N-C15=1 HEIGHT N-C15=1 N-C4 0.49 0.10 0.004 0.19 0.010 N-C5 0.66 0.10 0.004 0.16 0.008 N-C6 1.20 0.19 0,008 0.23 0.011 N-C7 2.49 0.05 0.002 0.08 0.004 N-C8 0.00 0.00 0.000 0.00 0.000 N-C9 5.29 0.50 0.020 0.47 0.024 N-C10 6.59 1.09 0.043 0.88 0.044 N-C11 7.73 8.52 0.338 6.72 0.339 N-C12 8.79 14.65 0.581 12.59 0.636 N-C13 9.78 22.02 0.873 20.00 1.011 N-C14 10.73 64.90 2.574 44.18 2.232 N-C15 11.59 25.21 1.000 19.79 1.000 N-C 16 12.44 44.81 1.777 35.00 1.769 N-C17 13.16 19.92 0.790 14.15 0.715 N-C18 13.97 28.95 1.148 24.59 1.242 N-C19 14.78 12.28 0.487 9,89 0.500 N-C20 15.36 14.25 0.565 12.25 0.619 N-C21 16.01 20,68 0.820 16.29 0.823 N-C22 16.64 20.44 0.811 16.27 0.822 N-C23 17.24 17.69 0.702 13.67 0.691 N-C24 17.81 13.91 0.552 10.36 0.524 N-C25 18.37 9.72 0.386 8.42 0.425 N-C26 18.90 9.00 0.357 6.89 0.348 N-C27 19.42 8.37 0.332 6.55 0.331 N-C28 19.91 6.78 0.269 5.28 0.267 N-C29 20.39 6.82 0.271 5.13 0.259 N-C30 20.86 4.30 0.171 3.23 0.163 N-G31 21.31 3.68 0.146 2.64 0.133 N-C32 21.74 1.93 0.077 1.60 0.081 N-C33 22.17 3.13 0.124 2.08 0.105 N-C34 22.58 0.80 0.032 0.68 0.035 N-C35 22.97 0.31 0.012 0.33 0.017 N-C36 23.36 0.58 0.023 0.36 0.018 N-C37 23.73 0.69 0.027 0.53 0.027 N-C38 24.11 0.64 0.025 0.35 0.018 N-C39 24.48 0.18 0.007 0.19 0.010 N-C40 24.87 0.11 0.004 0.11 0.006 N-C41 0.00 0.00 0.000 0.00 0.000 N-C42 0.00 0.00 0.000 0.00 0.000 N-C43 0.00 0.00 0.000 0.00 0.000 N-G44 0.00 0.00 0.000 0.00 0.000 Pristane 13.21 12.75 11.29 Phytane 14.07 10.84 9.73 FID2 B, (WF9760.D) pA -:: 90- 80- 70 - 60 - 50 --- 40 -. 30- 20-' 10- o -r--r-- º-- West Fish Creek7460-7580' . . ~¡j ~ ,.}>J ~ j ¡qj.J ~~."~.J J....vA.-i.,"".,AJ."'J I 5 I 10 I 15 r 20 WESTPORT TECHNOLOGY CENTER INTERNATIONAL Q ~ () t; ~ -- ~ ~ <1> '"0 o ::¡ V-.) o N '"ti ~ (JQ <1> -- (1\, rbìd ..¡:::.. \0 I 25 FID2 S, (WF9760.D) pA _ 45- 40- 35- 30- 25 -, 20- 15- 10- -~ 5- ö-t o ,_~JJl¡wÁ. ~ West Fish Creek7460-7580' j.J ~. , ~ vir ~. ,h">H }.J I ,J .AIItI)J.Jf'# ~~ oJI' ..)i..NNJ"P· a ~ (') t) t::ù r--I' t::ù 10 (t) "d o ~ w o N ~ t::ù (JQ (t) -- I I f i .....J 5 10 15 20 25 (ija ...-t) ~ \0 WEST PORT TECHNOLOGY CENTER INTERNATIONAL _ FID2 B. (1:\GEOCHEM\HPCHEM\6890\WF9761.D) West Fish Creek#l 7460'-7580' pA _, " 0 co 45 - z 0 z 40~ a:. 35 - é 2 I/) {) 30- z C') {) Z f' ~ N ~ C\I C 0 25 - 2 Z (;j GI 0 (W) 'c C\.. C\.. 11.. (: 0 0 0; ~ ()) 2 Z N i' 20- 0 c.. {) v Z Z N o lQ Z COil CD U Z c ..- <0 f' 0> C> ..- 15 -, CD ~ (\ coC')õ v ~ ~ N {) I/)C zgææ t;;2g~00 0(1) Z om I/) o 0 C') CD 0 ~_Z Z -CD E 0 .... z z C> C;; C') 10 C') Z - en I/) U C')CNO~C')O 10-&D L."}O E J, I,J, ¡ IJ. ~J ~ z § z § ~ z _I~ .~f' §~~.M ~. i 1 ~. I _ ,- ..- 0 W I "'vJ.".J, ~~. _____ u z \¡J . ....,J~,..NvJ 5- 0-1 0 I 5 I 10 I 15 I 20 I 25 WESTPORT TECHNOLOGY CENTER INTERNATIONAL t¡j P' (JQ ('D Þ----< 00 d ~ ml ..þ. - \0 a ~ (J t:1 P' ...... P' :;;0 CD "'d o ~ w o N GMC Data Report 302 Page 19 of 49 SATURATE FRACTION BIOMARKERS - ., ..........-.. ....-........,..." ,--.' . ... ,_., .... _.. .,._'0...' 0...... '. GMC Data Report 302 WF9759 Page 20 of 49 Saturate' Biomarker Report DATA FILE: WF9759.D DATE ACQUIRED: 7 Apr1999 10:34 MISC. INFO: E. Teshekpuk #1 7090-7180' PEAK # RET TIME AMU COMPOUND NAME AREA 1 27,62 191 C 19 Tricyclic (Cheilonthane) 6755 2 29.27 191 C20 Tricyclic (Cheilonthane) 10792 3 31.07 191 C21 Tricyclic (Cheilanthane) 12662 4 32,78 191 C22 Tricyclic (Chej anthane) 6487 5 34.83 191 C23 Tricyclic (Cheilanthane) 333ßl 6 35.97 191 C24 Tricyclic (Cheilanthane) 22705 7 38.28 191 C25 Tricyclic (Cheilanthane) 214ß3 8 39.87 191 C24 T etracyclic 125'15 9 40,01 191 C26 Tricyclic R (Cheilanthone) 6898 10 40.16 191 C26 Tricyclic 8 (Cheilanthone) 6746 11 43,96 191 C28 Tricyclic R (Cheilanthone) 7147 12 44.23 191 C28 Tricyclic 8 (Cheilonthane) 4914 13 45.08 191 C29 Tricyclic R (Cheilanthane) 4392 14 45.41 191 C29 Tricyclic 8 (Cheilonthone) 4408 15 46.26 191 Ts (22,29,3Q-Trisnorhopane"lI) 169,30 16 46.87 191 C26 Tetracyclic 3621 17 47.00 191 Tm (22,29,3Q-Trisnorhopone) 17681 18 47.26 191 C30 Tricyclic R 2206 19 47.65 191 C30 Tricyclic 8 1707 20 48.72 191 28,30 Blsnorhopane 53~~6 21 49,51 191 17 a, 21 b(H)-3Q-norhopone(C29 Nor) 39590 22 49.63 191 180(H)-3Q-nomeohopone (C29 Ts) 11516 23 49.93 191 170(H)-diohopane 4914 24 50,39 191 Normoretane 4544 25 50,82 191 Oleanane 19'16 26 51.05 191 170,21 b(H)-hopone (C30 Hopane) 44744 27 51.13 191 17a(H)-3D-nor"29"homohopane 5284 28 51.73 191 17b,21a(H)-hopane (Moretone) 58:33 29 52,81 191 170,21 b(H)"homohopone 228 (C31) 17625 30 53.04 191 170,21 b(H)"homohopane 22R (C31) 14605 31 53.23 191 Gammacerone 11 :30 32 54.21 191 17 a, 21 b(H)-bishomohopone S 8118 33 54,51 191 170,21 b(H)-bishomohopane R 68Ó9 34 55.82 191 170,21 b(H)-trishomohopone 8 52;35 35 56.24 191 170,21 b(H)-trishomohopane R 50.33 36 57.53 191 170,21 b(H)-tetrakishomohopane 8 3415 37 58.04 191 17a,21 b(H)"tetrok¡shomohopane R 1941 38 59.38 191 170,21 b(H)pentokishomohopone 8 2017 39 60.16 191 170,21 b(H)pentakishomohopone R 1321 40 31.52 217 C21 Diopregnane 5213 WESTPORT TECHNOLOGY CENTER INTERNATIONAL _.-." .-... '-"~""-', ."',.., -..'-' GMC Data Report 302 WF9759 Page 21 of 49 Saturate Biomarker Report 41 31.94 217 LMW Sterane 322i5 42 32.45 217 LMW Steran 215:7 43 33.08 217 C21 Pregnane 821:7 44 33.19 217 C22 Diahomopregnane 4853 45 35.16 217 LMW Sterone 2251 46 35.39 217 C22 Homopregnane 6035 47 41.98 217 C27S ba Diasterane 11 5CJ4 48 42.66 217 C27R ba Diosterane 6399 49 43.16 217 Peokl0 3659 50 43.54 217 Peak 11 4014 51 43.67 217 Peak 12 5069 52 43.78 217 Peak 13 6051 53 44.11 217 Peak 14 2809 54 44.50 217 Peak 15 3493 55 45,04 217 C27S aaa Sterane 10062 56 45.21 217 C27R abb Ster +C29S Diasterane 11060 57 45.37 217 C27S abb Sterane 5178 58 45.80 217 C27R aaa Sterane 111'15 59 46.01 217 C29 ba Diasterane 8676 60 46.80 217 C28S aao Sterane 1794 61 47.11 217 C28R abb Sterane 3129 62 47,29 217 C28S abb Sterane 36Ô9 63 47.45 217 Diasterane 147'6 64 47.81 217 C28R 000 Sterane 5448 65 48.37 217 C29S aao Sterane 3903 66 48.70 217 C29R abb Sterane 6232 67 48.81 217 C29S obb Sterone 2686 68 49.48 217 C29R aao Sterane 7515 69 49.59 217 C30S aaa Sterane 79'7 70 50.02 217 C30R abb Sterane 386 71 50.06 217 C30S abb Sterane 379 72 50.82 217 C30R aao Sterone 647 73 45.21 218 C27R ebb Sterane 8846 74 45.37 218 C27S abb Sterane 64t)8 75 47.13 218 C28R abb Sterane 4228 76 47.29 218 C28S abb Sterane 4295 77 48.70 218 C29R abb Sterane 5577 78 48.82 218 C29S abb Sterone 4814 Westport Biomarker Ratios WESTPORT TECHNOLOGY CENTER INTERNATIONAL -··_·~··'··__.'M ._..__..._..... __.__..".,,_.~.,..,. _,,~___. '---'--"- "-"~"--'-'-'-'.'-'-~""-"" '~""'-"-'--" .'. _d... MO.. ...,,_ GMC Data Report 302 WF9759 Saturate Biomarker Report Page 22 of 49 Homohopane Profile: Value C31 =(Peaks 29 +30)/(Peaks 29 +30 +32 through 39) 0.486 C32=(Peaks 32 +33)/(Peaks 29 +30 +32 through 39) 0.227 C33=(Peaks 34 +35)/(Peaks 29 +30 +32 through 39) 0.156 C34=(Peaks 36 +37)/(Peaks 29 +30 +32 through 39) 0.081 C35=(Peaks 38 +39)/(Peaks 29 +30 +32 through 39) 0.050 Oleanane Ratio= Peak 25/Peak 26 0.043 Gommocerane Ratio 1 = Peak 31 /Peak 26 0.025 Gommocerone Ratio 2: Peak 31 /Peak30 0.078 Bisnorhopcme Retio= Peak 20/Peak 26 0.119 30·nor-29-homo+2a-methyl Ratio Peak 27/Peak 26 0.118 C29 Ts/(C29 Norhopone + C29 T5= Peak 22/(Peaks 21 + 22) 0.225 C30 to Norhopane & Homopane Indices: Norhopane/Hopane = Peak 21 /Peak 21 +26 Hopane/Hopane+Hopane C31 /Hopane = Peaks 29 + 30/Peaks 29 + 30 + 26 C32/Hopane = Peaks 32 + 33/Peaks 32 + 33 + 26 C33/Hopane = Peaks 34 + 35/Peaks 34 + 35 + 26 C34/Hopane = Peaks 36 + 37/Peaks 36 + 37 + 26 C35/Hopane = Peaks 38 + 39/Peaks 38 + 39 + 26 0.469 0.500 0.418 0.251 0.187 . 0.107 0.069 Ts/Tm= Peak 15/Peak 17 0.958 C23 Tricyclic/Hopone Ratio: Peak 5/Peak 26 0.746 C23 Tricyclic/C24 Tricyclic Ratio= Peak 5/Peak 6 1.470 C24 Tetracycllc/C25 Tricyclic Ratio: Peak 8/Peak 7 0.583 C24 Tetracyclic/C26 Tricyclic Ratio: Peak 8/Peaks 9+ 10 0.917 Moretcne Index: Peak 28/Peaks 26+28 0.115 Normoretane Index: Peak 24/Peaks 24+26 0.092 Tricycllc/Hopane Ratio: 0.456 BP Sunbury Traditional Biomarker Ratios WESTPORT TECHNOLOGY CENTER INTERNATIONAL ~. .-.. .... - ._-". . . . '" ..-.....--.. ......,.........,....-...-...............--- '.... ........- GMC Data Report 302 WF9759 Saturate Biomarker Report Page 23 of 49 S3 aao 20R Steranes C27 46. 16% 0.342 0.47'6 C28 C29 22.63% 31,2'1% 24.91 % 30.37% 40.39% 71.56% 0.542 0.549 0.885 0,4139 Sl C29S/C29S+C29R Sterane S2 C29R&S abb/C29S&R aoo + C29R&S abb S4 obb 20S&20R Steranes 44.72% S5 Dia bo/(Dia+Non-Diasteranes) (Calculated) M4 C27-35 Hopanes/(Hopanes + Steranes C27-29 H 1 C32S/C32s + R Hopane H2 C31 S/C31S + R Hopone H3 C30 Hopane/Hopane + Moretane H6 18AI18A + 17 A Hopane BPX Source Indicators 1920Tri23 Index «C19+20 Trls)/(C19+20+23 Tris» 0.3/45 23TriHo Index (C23 Tri/(C23 Tri + Hopane) 0.427 24TetHo Index (C24 Tetro/(C24 Tetro + Hopone) 0.219 TmTs Index (Tm/(Tm+Ts» 0.511 Bls Index (Blsnorhoponef(Blsnorhopone + Hopone) 0.107 Moretane Index (Moretone/(Moretone + Hopone) 0.115 Ol30Ho Index (Oleonone/(Oleonane + Hopone) 0.041 BP G2 Index (G2/(G2 + Hopone) 0.106 G2 = coelution of17a(H)-3D-nor-29-homohopane and 2a-methyl-17a(H),21 b(H)-hopane Go30Ho Index (Gommocerone/(Gommocerane+Hopone) 0.025 35Ho34 Index (C35 Homohopone/(C35 +C34 Homohopones» 0.384 HoSt Index (M411 00) 0.716 WESTPORT TECHNOLOGY CENTER INTERNATIONAL ,__. ."~" "'u "_n,. .... .~ ...._ GMC Data Report 302 WF9759 Saturate Biomarker Report Page 24 of 49 295t27 Index (C29 5terones/(C27+29 steranes from 53) 0.403 Dlost Index (C27 Dlasterones/(C27 Dlas + C27 Stercnes) 0.404 DMH Index (Demethyloted Hopone/(Dem. Hopane + Hopane) nrn Hopcne Profile Indices (N hopane or homohopone/(5um C29-C35 Hopanes) C29= 0.263 C30= 0.297 C31= 0.214 C32= 0.100 C33= 0.069 C34= 0.036 C35= 0.022 BPX Maturity Indicators 51 C29S/C29S+C29R Sterane 0.342 52 C29R&S abb/C29S&R aaa +C29R&S abb 0.476 Hl C32S/C32s + R Hopane 0.542 H2 C31 S/C31 S + R Hopane 0.549 pnf = peak not found *** = no value due to missing peaks WESTPORT TECHNOLOGY CENTER INTERNATIONAL .~._."~'-' ,-. '. -' -"'-"" .' - WESTPORT LABORATORY Data File: WF9759.D Sample: E. Teshekpuk #1 7090-7180' Abundance Ion 191.00 (190.70 to 191.30): WF9759.D 1600 1500 1400 1300 1200 1100 1000 900 000 700 600 500 400 I )'\I/J \ ~ JJ )' "'^ \} VV ~.~t\Jw 300 Jk ~ 200 .~¡'¡'f\A~.,.M..... vJ,., ~ ~-'-'-r-r-.-.--r-I ' . I . I . I . I I . I , . r . , , , I ' . , , I I , I . I . . ILf!:I~:.-> 2!ºº_?.§.:ºº_~8.00 30.00 32.00 34.00 36.00 30.00 40.00 , I I t I 40.00 . , I . . 50.00 I I I I I 52,00 I . I . I 42.00 I I I I I 44.00 I I I 1 I 46.00 ~ Þ ...//1' I I I I I I I I I . 54.00 56.00 a ~ (J tJ ~ -- ~ ~ CD '"d o :4- w o N v~ ~ . I I ' I 58.00 I I I I I I 60.00 roo ~ ~ ''-0,,) u-. '1 ê. ~ \0 WESTPORT LABORATORY Data File: WF9759.0 ª~!!)12l:~~~.:---T_esþekpuk #1 7090-7180' Abundanco Ion 217.00 (216-70 to 217.30): WF9759.D a ~ n t:1 p) f"'i- p) ~ (!) '"d o ;4. w C> N 450 400 350 300 250 200 150\.N~J'r-ÀI ~~ ~v ~ I~ \1 ~ ~'}\J"~wJv J~~~ . , r I I I I , I r T 1 I I I I I I . I I I . . I ' . I I I I I . , I I . I I I I r I" I J I , I . , 1 I' I I I I r I I I I . . I ' I I . I I I I I I f I , . I ' I I I I I I 1 . I I I I I I I . I I I I t I I I I I' I I I I r I I I I , I Time--> 28.00 29.00 30.00 31.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 Ãbundanco Ion 218.00 (217-70 to 218.30): WF9759.D 450 400 350 300 250 200 ~ ~ . tQ 150 I Î ! . !. fl A A I . ¡ .~ 100 ~~Aw- ~ ~\Aij~ilJ'\;JJ~ij\JVNU~~ ~...........-r I I , . I I r . I r I r . . . I . I . I I I . . , I I I I I I . , . . I . I . . I I I I . I I . 1 . I . . . I I . . . . I I r . I I I I I I I . . . , I . . . . I I . . I I . . I . I . . . I I I . . . I . , .-r- næ~.--> 2.E!:.ºº---_~~º_O_~º.OO 31.00 32.00 33.00 34.00 35.00 36.00 37.00 3!!.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 WESTPORT LABORATORY Data File: WF9759.D Sample: E. Teshekpuk #1 7090-7180' Abundanéo Ion 217.00 (216.70 to 217.30): WF9759.D a ~ (') :J ~ r-t- ~ ;::0 {t) "':j ":) ::¡ w <:> -v 480 460 440 420 400 380 360 340 320 300 280 260 240 220 200 100 ::: ~, .JI'~~I' ~V ~,~'~ ~~ t ,k 'r ~ I I ~ ,1\ · ~ Þ/i~~~ 120 MJv ,1M h. ~I w~.Jt#f'W ~ JII/II'/1¡{ ~\Nvvh, . ~ \ t . ~ --J ....-rr I r r , I I ' I , , (' , I , I I r , I I I , I I I . , , r I' r I . I ' I . I I ' I J J J J . r I . . , . I I , . I I I . I' J I "1 I , . . I" . 'I' , r, I " . , 1'1' . I . . . . I I I. . I' . . . I I I , , I I . J , I . . . , !. Time--> 27.00 28.00 29.00 30.00 31.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46,00 47.00 48.00 49.00 50.00 51.00 .~ -------------- - \0 Data File: WF9759.D ~Qle~~ Te~~~ 7090-7180' Abundance WESTPORT LABORATORY 1600 Ion 191.00 (190_70 to 191.30): WF9759.D 1400 ~ o b ~ E) ?::1 ~ o ::¡ l.I..> o N 1200 tOoo 800 600 _ ~~ 400 ~ I. I. I. ~AÞAA~'A" 200~~ ^""-'~~ ~ILM,µ..J Timo--> 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46.00 48.00 50.00 52.00 54.00 56.00 ÄbîÎndanco --_.~ Jon 217.00 (216.70 10 217.30): WF9759.0 450 400 350 300 250 200 -, . /" ~~;;,o 150'~LkUJkL ,J. j~VJ~~ vJJM~\..JwJt~ .... ... ¡¡þivu1nt 4 NI tIPi }\¡,~"'.~~ . ; 1 00 ðJV" ··,"'vv....,'" "'IU",^"",,'W' . ,. .. '" '\MJ~ ;: ._, .......,., \0 !L~2..?4.90 26.00 28.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46.00 48.00 50.00 52.00 54.00 56.00 58.00 WEST PORT LABORATORY Data File: WF9759.D ~~~~~~~~ Teshekpuk #1 7090-7180' Abundance 800 Ion 177.00 (176.70 to 177.30): WF9759.D CJ ~ () t:1 ~ .-+- ~ ïO (t) "0 o ~ w o to 700 600 500 J JMv~~~~ 200,~\~ ' , . I ' , , , I ' , , , I . . , . I . , , , I ' , , , I ' , , . I . , , . I ' . , , I ' , . , I ' , 26.00 28.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46.00 Ion 191.00 (190.70 to 191.30): WF9759.D 300 /~~ ~ .,j.,þ'¡' ~ 400 Tlma--:> 24.00 Ãbündance "III~IJIIII'II'III'IIIIIII'I 48.00 50.00 52.00 54.00 56.00 58.00 1600 1400 1200 1000 800 400 uwvJ )JJVV Wt,,, ,~ 600 200 ':~_-.-..-. Il.l'!!e-·~ 24.0_~~.00 28.00 40.00 . . I . . . . [ . . . . I . I I . I . . . . I . . . . I . I . . I I . . . I . . 42.00 44.00 46.00 48.00 50.00 52.00 54.00 56.00 . . I 58.00 I I r I r I 30.00 I I I J . 32.00 . . I . . . I I . , . . I I . 34.00 36.00 38.00 I . I I . GMC Data Report 302 Page 30 of 49 WF9760 Saturate Biomarker Report DATA FILE: WF9760.D DATE ACQUIRED: 7 Apr 1999 11 :49 MISC. INFO: West Fish Creek #1 5520-5780' PEAK # RET TIME AMU COMPOUND NAME AREA 1 27.64 191 C 19 Tricyclic (Cheilanthane) 63819 2 29.28 191 C20 Tricyclic (Cheilanthane) 66992 3 31.09 191 C21 Tricyclic (Cheilanthane) 77297 4 32.81 191 C22 Tricyclic (Cheilanthane) 25736 5 34,86 191 C23 Tricyclic (Cheilonthane) 95959 6 35.98 191 C24 Tricyclic (Cheilonthane) 78322 7 38.35 191 C25 Tricyclic (Cheilanthane) 56679 8 39.89 191 C24 T etracyclic 50699 9 40.02 191 C26 Tricyclic R (Cheilanthane) 19043 10 40.17 191 C26 Tricyclic S (Cheilonthane) 20163 11 43.97 191 C28 Tricyclic R (Cheilanthane) 31268 12 44.24 191 C28 Tricyclic S (Cheilanthane) 20404 13 45.10 191 C29 Tricyclic R (Cheilanthane) 26229 14 45.43 191 C29 Tricyclic 5 (Cheilanthane) 20976 15 46.29 191 Ts (22,29,3D-Trisnorhopane-ll) 85269 16 46.80 191 C26 T etracycllc 11695 17 47.02 191 Tm (22, 29, 3D- Trisnorhopane) 78213 18 47.27 191 C30 Tricyclic R 17409 19 47.66 191 C30 Tricyclic 5 23708 20 48.74 191 28,30 Bisnorhopone 21535 21 49.52 191 17a,21 b(H)-3D-norhopane(C29 Nor) 198734 22 49.66 191 18a(H)-3Q-nomeohopane (C29 Ts) 65420 23 49.94 191 17 a(H)-diahopane 51695 24 50.41 191 Normoretane 33546 25 50.84 191 Oleanane 2073 26 51.06 191 17a,21 b(H)-hopone (C30 Hopane) 392982 27 51.15 191 17 a(H)-3D-nor-29-homohopane 21652 28 51.75 191 17b,21 o(H)-hopane (Moretane) 62086 29 52.83 191 170,21 b(H)-homohopane 225 (C31) 163'757 30 53.05 191 170,21 b(H)-homohopone 22R (C31) 123217 31 53.31 191 Gammocerone 13132 32 54.21 191 17 a, 21 b(H)-bishomohopane 5 84241 33 54.51 191 1 7 a, 21 b(H)-bishomohopane R 66438 34 55.83 191 17 a, 21 b(H)-trishomohopane 5 58518 35 56.24 191 170,21 b(H)-trishomohopane R 39849 36 57.52 191 17a,21 b(H)-tetrakishomohopane S 38379 37 58.05 191 17a,21 b(H)-tetrakishomohopane R 27036 38 59.40 191 17a,21 b(H)pentakishomohopane S 18986 39 60.16 191 1 7 a, 2 1 b(H)pentakishomohopane R 17852 40 31.53 217 C21 Diapregnane 36051 WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9760 Page 31 of 49 Saturate Biomarker Report 41 31.96 217 LMW Sterane 20526 42 32.46 217 LMW Steran 13374 43 33.11 217 C21 Pregnane 56405 44 33.22 217 C22 Diahomopregnane 34174 45 35.18 217 LMW Sterane 14021 46 35.40 217 C22 Homopregnane 32707 47 41,98 217 C27S ba Diasterane 65833 48 42.68 217 C27R ba Diasterane 38879 49 43.18 217 Peak 10 19072 50 43.54 217 Peak 11 25865 51 43.69 217 Peak 12 25456 52 43.81 217 Peak 13 33055 53 44.12 217 Peak 14 13592 54 44.51 217 Peak 15 21526 55 45,06 217 C27S aaa Sterane 34108 56 45.22 217 C27R abb Ster +C29S Dlasterane 79557 57 45.39 217 C27S abb Sterane 25927 58 45.82 217 C27R aaa Sterane 32035 59 46.01 217 C29 ba Dlasterane 70225 60 46,81 217 C28S aaa Sterane 6424 61 47.12 217 C28R abb Sterane 19247 62 47.30 217 C28S abb Sterane 28581 63 47.50 217 Dlasterane 20698 64 47.84 217 C28R aaa Sterane 211 08 65 48.36 217 C29S aaa Sterane 34901 66 48.71 217 C29R abb Sterane 50269 67 48.82 217 C29S abb Sterane 25095 68 49.50 217 C29R aaa Sterane 72218 69 49.62 217 C30S aaa Sterane 6308 70 50.02 217 C30R abb Sterane 8487 71 50.09 217 C30S abb Sterane 6255 72 50.86 217 C30R aaa Sterane 7609 73 45,22 218 C27R abb Sterane 48852 74 45.39 218 C27S abb Sterane 28802 75 47.14 218 C28R abb Sterane 24050 76 47.30 218 C28S abb Sterane 29623 77 48.71 218 C29R abb Sterane 48036 78 48.82 218 C29S abb Sterane 40918 4814 Westport Biomarker Ratios WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9760 Saturate Biomarker Report Page 32 of 49 Homohopone Profile: Value C31 =(Peaks 29 +30)/(Peaks 29 +30 +32 through 39) 0.450 C32=(Peaks 32 +33)/(Peaks 29 +30 +32 through 39) 0.236 C33=(Peaks 34 +35)/(Peaks 29 +30 +32 through 39) 0.154 C34=(Peaks 36 +37)/(Peaks 29 +30 +32 through 39) 0.102 C35=(Peaks 38 +39)/(Peaks 29 +30 +32 through 39) 0,058 Oleanane Ratio= Peak 25/Peak 26 0,005 Gammacerane Ratio 1: Peak 31 /Peak 26 0.033 Gammacerane Ratio 2: Peak 31 /Peak30 0.107 Bisnorhopane Ratio: Peak 20/Peak 26 0.055 30-nor-29-homo+2a-methyl Ratio Peak 27/Peak 26 0,055 C29 Ts/(C29 Norhopane + C29 Ts= Peak 22/(Peaks 21 + 22) 0.248 C30 to Norhopane & Homopane Indices: Norhopane/Hopane = Peak 21 /Peak 21 +26 0.336 Hopane/Hopane+Hopane 0.500 C31 /Hopane = Peaks 29 + 30/Peaks 29 + 30 + 26 0.422 C32/Hopane = Peaks 32 + 33/Peaks 32 + 33 + 26 0.277 C33/Hopane = Peaks 34 + 35/Peaks 34 + 35 + 26 0.200 C34/Hopane = Peaks 36 + 37/Peaks 36 + 37 + 26 0.143 C35/Hopane = Peaks 38 + 39/Peaks 38 + 39 + 26 0.086 Ts/Tm= Peak 15/Peak 17 1.090 C23 Tricyclic/Hopone Ratio= Peak 5/Peak 26 0,244 C23 Tricyclic/C24 Tricyclic Ratio= Peak 5/Peak 6 1 .225 C24 Tetracyclic/C25 Tricyclic Ratio: Peak 8/Peak 7 0.894 C24 Tetracyclic/C26 Tricyclic Ratio= Peak 8/Peaks 9+ 10 1.293 Moretane Index: Peak 28/Peaks 26+28 0.136 Normoretane Index= Peak 24/Peaks 24+26 0.079 Tricyclic/Hopane Ratio: 0.319 BP Sunbury Traditional Biomarker Ratios WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9760 Saturate Biomarker Report Page 33 of 49 S4 obb 20S&20R Sterones 35.25% O.~~26 0.454 C28 C29 16.84% 57.61% 24.37% 40..38% 48.84% 75.69% 0.559 0.571 0.864 0.522 Sl C29S/C29S+C29R Sterone S2 C29R&S abb/C29S&R aoo + C29R&S obb S3 aao 20R Steranes C27 25.55% S5 Dia ba/(Dia+Non-Olasteranes) (Calculated) M4 C27-35 Hopanes/(Hopanes + Steranes C27-29 Hl C32S/C32s + R Hopane H2 C31 S/C31 S + R Hopane H3 C30 Hopane/Hopane + Moretane H6 18A/18A + 17 A Hopane BPX Source Indicators 1 920Tri23 Index «C19+20 Tns)/(C19+20+23 Tris» 0.577 23TriHo Index (C23 Tri/(C23 Tn + Hopone) 0.196 24TetHo Index (C24 Tetra/(C24 Tetro + Hopone) 0.114 TmTs Index (Tm/{Tm+Ts» 0.478 Bls Index (Bisnorhopane/(Blsnorhopone + Hopone) 0.052 Moretcne Index (Moretane/(Moretane + Hopone) 0.136 Ol30Ho Index (Oleonone/(Oleonane + Hopone) 0.005 BP G2 Index (G2/(G2 + Hopane) 0.052 G2 = coelution of17a(H)-3Q.nor-29-homohopone and 2a-methyl-17a(H),21 b(H)-hopane Go30Ho Index (Gommocerone/(Gommocerane+Hopone) 0.032 35Ho34 Index (C35 Homohopone/(C35 +C34 Homohopones» 0.360 HoSt Index (M4/l 00) 0.757 WESiPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9760 Saturate Biomarker Report Page 34 of 49 295t27 Index (C29 5tercnes/(C27+29 steranes from 53) 0.693 Dla5t Index (C27 Dlasteranes/(C27 Dias + C27 5tercnes) 0.488 DMH Index (Demethylcted Hopane/(Dem. Hopcne + Hopane) nm Hopane Profile Indices (N hopcne or homohopcne/(5um C29-C35 Hopanes) C29= 0.162 C30= 0.320 C31 = 0.233 C32= O. 123 C33= 0.080 C34= 0.053 C35= 0,030 BPX Maturity Indicators 51 C29S/C29S+C29R Sterane 0.326 52 C29R&S abb/C29S&R 000 +C29R&S abb 0,454 H1 C32S/C32s + R Hopane 0,559 H2 C31 S/C31 S + R Hopane 0.571 pnf = peak not found *** = no value due to missing peaks WESTPORT TECHNOLOGY CENTER INTERNATIONAL WESTPORT LABORATORY Data File: WF9760.D Sample: West Fish Creek #1 5520-5780' Abundance---- 12000 Ion 191.00 (190.70 to 191.30): WF9760,D Q ~ (J tj Ç¡) .-+ Ç¡) ~ CD ~ o ::¡. VJ o N 11000 10000 9000 8000 7000 6000 5000 4000 3000 2000 Þ¡j ~ 1000 ~~ ~v -.~'"^'~ ~-'- "~^~^,~",^J.~.,¡,JJiJvtJ ) '"' JrlVv. Æ _,J,J JJl,A ~ '; ~r-rr , , , I . -.-0-'-, . , I , I I I I I I ' . I , I . , I I I . , I -, I ' , . 1 I I , I I I I I , . I I I , I I . I I I I . I I , I I I . I I ' I . I , I , I I I ' I , I I I I I , I s.. Iime=~. ~~ºº_ 26.0º_~8.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46.00 46.00 50.00 52.00 54.00 56.00 58.00 60.00 ~ WESTPORT LABORATORY Data File: WF9760.D Saf!1.21~-=__~~st Fish Creek #1 5520-5780 I Abundance Ion 217.00 (216.70 to 217.30): WF9760.D Q ~ n :J ::I) ..-t- ~ 2500 2000 ;;0 CD ""::j o ;:¡ ~ => '-J 1500 1000 500,~~~i/lV' ~J JJJV~ '1\ V ~I/~II~'V\ J J~ --r...,---y--r-r't'·I""IIIIIIII"I'I"II·"I'.I'I".II'III_I'.,1I""IIIIIJ'IIIII"'IIII'I"III'II'IIIIIJ"I'IIIIIIIII'I'II'I'I~ Time--> 28.00 29.00 30.00 31.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 Abundance Ion 218.00 (217.70 to 218.30): WF9760.D 2000 1500 1000 JooO ~ (,.~ Ò) ~ 0\ o ~ ..þ.. \0 500~,~~,~,~~IM\M"l:~\0,~I,~g~ T!!!I.~::?_~f!=-ºº-~9.00_ 30.QO 31.00 32.00 33.00 34.00 35,00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 ::: ~n~ I,A ,f,~ ~ ~,~ ,I"~,, ~,~,~ ,I, ~'~~~~~~M 4,~~' ,:~,:'.~,. ~,\" ~ , ' ,/, ,J,!, ' , ~, ~.'.. :~, \~J~ Timo--> 27.00 28.00 29.00 30.00 31.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 .¡::,. .--.----.-.----~--------- - \D 800 1000 1200 1400 1600 1800 2000 2200 a ~ (J t:1 ~ ~ PJ ~ CD '"d o ::4- w o tv 2400 2600 Ion 217.00 (216.70 to 217.30): WF9760.D Abundanée--- Data File: WF9760.D Sample: West Fish Creek #1 5520-5780' WESTPORT LABORATORY WEST PORT LABORATORY Data File: WF9760.D ~amp!e: West Fish Creek #1 5520-5780' Abundance 12000 Ion 191.00 (190.70 to 191.30): WF9760.D Q ~ ':1 ::1 ~ ,-t- ~ ;0 !1) '"::S a :¡ j.) =::> '-.) 10000 8000 6000 4000 2000 ~~~~~~ ·~I~III'IIII'11111·lrlllll"'1 Time--> 24.00 26.00 28.00 30.00 32.00 34.00 36.00 Abundanco'-- ~~k~.Æ.~_ . . I I I I . I I I I I I . I I I I J I I I I I 1 . I I I J I I r I I I I I I I I 1 I I I I ( I I I I I I . I 38.00 40.00 42.00 44.00 46.00 48.00 50.00 52.00 54.00 56.00 58.00 Ion 217.00 (216.70 to 217.30): WF9760.D 2500 2000 1500 ,I.. I 500 ~~,~~~~,'~~,~:~,~:.J.:. ~ Time--> 24.00 26.00 20.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 -----------~-~ - ~ } ~ \ Jj \ U ''ïj ~ ~ (1) v.> 00 o I-t) ...:::::.. \0 1000 I I I I I I I I I I I I I 1 I I . I 1 . I I I I I 46.00 48.00 50.00 52.00 54.00 I I I 1 I 56.00 . . I I . 58.00 WEST PORT LABORATORY Data File: WF9760.D Sam21e: West Fish Creek #1 5520-57801 Abuñdanco-----.--- 3500 Ion 177.00 (176.70 to 177.30): WF9760.D Q 2ลก:: (J tJ ~ ~ ~ ~ (1) "ö o ::¡ w o t'0 3000 2500 2000 1500 Nt,-,,- Time·-:> 24.00 Abundance 12000 26.00 . . . I . . . . J . . . , I . . I I I . . I . I I I 28.00 30.00 32.00 34.00 36.00 I I I I I 1 . I I I , . I I I I r J . I . I I I I 38.00 40,00 42.00 44.00 46.00 Ion 191.00 (190-70 to 191.30): WF9760.D . . I ' . . . I I . . , I . . 48.00 50.00 52.00 . I I r I 54.00 I I I I , I I I _I I 56.00 58.00 10000 BODO 6000 . . I I I . . I . . . . I . . . , I . . 38.00 40.00 42.00 44.00 ~ ~ ('"Q (1) w ~~WJL.AL~~ '1IIIIIIIIIIill"rlll'IIIIII'I'III~~- 46.00 48.00 50.00 52.00 54.00 56.00 58.00 4000 2000 ~~~~~ -='- 1 '11~111"'IIII'I'II'llf''''1 T!~~.--:> ?!!~~6.Qº_ 28.00 30.00 32.00 34.00 36.00 GMC Data Report 302 WF9761 Page 40 of 49 Saturate Biomarker Report DATA FILE: WF9761.D DATE ACQUIRED: 7 Apr 1999 13:04 MISC. INFO: West Fish Creek #1 7460-7580' PEAK # RET TIME AMU COMPOUND NAME AREA 1 27.66 191 C 19 Tricyclic (Cheilonthone) 93600 2 29.29 191 C20 Tricyclic (Cheilonthane) 130637 3 31.09 191 C21 Tricyclic (Cheilanthane) 120094 4 32.81 191 C22 Tricyclic (Cheilanthane) 39777 5 34,86 191 C23 Tricyclic (Cheilanthane) 145827 6 35.98 191 C24 Tricyclic (Cheilanthane) 98184 7 38.30 191 C25 Tricyclic (Cheilanthane) 57294 8 39.89 191 C24 Tetracycllc 110287 9 40.02 191 C26 Tricyclic R (Cheilanthane) 15077 10 40.17 191 C26 Tricyclic S (Cheilanthane) 17674 11 43.97 191 C28 Tricyclic R (Cheilanthane) 42080 12 44.23 191 C28 Tricyclic S (Cheilanthane) 10830 13 45.10 191 C29 Tricyclic R (Cheilanthane) 18642 14 45.43 191 C29 Tricyclic S (Cheilanthane) 11304 15 46.27 191 Ts (22,29,3G-Trisnorhopane-ll) 90989 16 46.80 191 C26 T etracyclic 30058 17 47.02 191 Tm (22,29,30-Trisnorhopane) 230304 18 47,27 191 C30 TricyclIc. R 10308 19 47.68 191 C30 Tricyclic S 27899 20 48.75 191 28,30 Bisnorhopane 23286 21 49.52 191 17 a, 21 b(H)-3Q-norhopane(C29 Nor) 559311 22 49.64 191 18a(H)-3G-norneohopane (C29 Ts) 98152 23 49.94 191 17 a(H)-diahopane 67837 24 50.41 191 Normoretane 11 0467 25 50.83 191 Oleanane 3233 26 51.05 191 17a,21 b(H)-hopane (C30 Hopane) 804096 27 51.15 191 17 a(H)-3Q-nor- 29-homohopane 36701 28 51.75 191 17b,21 a(H)-hopane (Moretane) 195344 29 52.82 191 17 a, 21 b(H)-homohopane 228 (C31) 369472 30 53.04 191 17 a, 21 b(H)-homohopane 22R (C31) 265222 31 53.27 191 Gammacerane 30357 32 54.21 191 17 a, 21 b(H)-bishomohopane 8 194466 33 54.52 191 17a,21 b(H)-bishomohopane R 133401 34 55.83 191 17a,21 b(H)-trishomohopane 8 125116 35 56.23 191 170,21 b(H)-trishomohopane R 86303 36 57.52 191 170,21 b(H)-tetrakishomohopane 8 72140 37 58.05 191 170,21 b(H)-tetrokishomohopane R 43270 38 59.39 191 170,21 b(H)pentakishomohopane S 30186 39 60.16 191 170,21 b(H)pentokishomohopane R 25061 40 31.54 217 C21 Diapregnane 46097 WE8TPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9761 Page 41 of 49 Saturate Biomarker Report 41 31.96 217 LMW Sterane 22840 42 32.46 217 LMW Steran 17403 43 33.11 217 C21 Pregnane 74399 44 33.21 217 C22Diahomopregnane 40452 45 35.17 217 LMW Sterane 14074 46 35.40 217 C22 Homopregnone 35907 47 41.98 217 C27S ba Diasterane 42717 48 42.66 217 C27R ba Diasterane 22965 49 43.17 217 Peok10 11281 50 43.54 217 Peak 11 14451 51 43.67 217 Peak 12 15254 52 43,79 217 Peak 13 19582 53 44.12 217 Peak 14 8803 54 44.51 217 Peak 15 12206 55 45.06 217 C27S aaa Sterane 27597 56 45.21 217 C27R abb Ster +C29S Dlasterane 42079 57 45.39 217 C27S abb Sterane 13829 58 45.82 217 C27R aaa Sterane 42803 59 46.02 217 C29 ba Dlasterane 39498 60 46.81 217 C28S aaa Sterane 9381 61 47.12 217 C28R abb Sterane 16178 62 47.29 217 C28S abb Sterane 14855 63 47.47 217 . Diasterane 10523 64 47,82 217 C28R aaa Sterane 39854 65 48.36 217 C29S aaa Sterane 43231 66 48.71 217 C29R abb Sterane 34053 67 48.81 217 C29S abb Sterane 13559 68 49.48 217 C29R aao Sterane 74888 69 49.64 217 C30S aao Sterane 4373 70 50.02 217 C30R ebb Sterane 3131 71 50.10 217 C30S abb Sterane 4296 72 50.86 217 C30R aaa Sterane 4262 73 45.21 218 C27R abb Sterane 27941 74 45.39 218 C27S abb Sterane 17335 75 47.14 218 C28R abb Sterane 16588 76 47.30 218 C28S abb Sterane 16998 77 48.71 218 C29R abb Sterane 28493 78 48.82 218 C29S abb Sterane 24904 4814 Westport Biomarker Ratios WESTPORT TECHNOLOGY CENTER INTERNA T10NAL GMC Data Report 302 WF9761 Saturate Biomarker Report Page 42 of 49 Homohopane Profile: Value C31 =(Peaks 29 +30)/(Peaks 29 +30 +32 through 39) 0,472 C32=(Peaks 32 +33)/(Peaks 29 +30 +32 through 39) 0,244 C33=(Peaks 34 +35)/(Peaks 29 +30 +32 through 39) 0.157 C34=(Peaks 36 +37)/(Peaks 29 +30 +32 through 39) 0.086 C35=(Peaks 38 +39)/(Peaks 29 +30 +32 through 39) 0.041 Oleanane Ratlo= Peak 25/Peak 26 0.004 Gammacerane Ratio 1 = Peak 31 /Peak 26 0.038 Gommacerane Ratio 2= Peak 31/Peak30 0.114 Bisnorhopone Ratio= Peak 2O/Peak 26 0.029 30-nor-29-homo+2o-methyl Ratio Peak 27/Peak 26 0.046 C29 Ts/(C29 Norhopcne + C29 Ts= Peak 22/(Peaks 21 + 22) 0.149 C30 to Norhopane & Homopane Indices: Norhopane/Hopane = Peak 21/Peak 21+26 0.410 Hopane/Hopane+Hopane 0.500 C31/Hopane = Peaks 29 + 3D/Peaks 29 + 30 + 26 0.441 C32/Hopane = Peaks 32 + 33/Peaks 32 + 33 + 26 0,290 C33/Hopane = Peaks 34 + 35/Peaks 34 + 35 + 26 0,208 C34/Hopane = Peaks 36 + 37/Peaks 36 + 37 + 26 0,126 C35/Hopane = Peaks 38 + 39/Peaks 38 + 39 + 26 0.064 Ts!Tm= Peak 15/Peak 17 0.395 C23 Tricyclic/Hopone Ratio= Peak 5/Peak 26 0.181 C23 Tricyclic/C24 Tricyclic Ratio= Peak 5/Peak 6 1 .485 C24 Tetracyclic/C25 Tricyclic Ratio= Peak 8/Peak 7 1.925 C24 Tetracyclic/C26 Tricyclic Ratio= Peak 8/Peaks 9+ 1 0 3.367 Moretane Index= Peak 28/Peaks 26+28 0.195 Normoretane Index= Peak 24/Peaks 24+26 0.121 Tricyclic/Hopone Ratio= 0.235 BP Sunbury Traditional Biomarker Ratios WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9761 Saturate Biomarker Report Page 43 of 49 51 C29S/C29S+C29R Sterane S3 aaa 20R Steranes C27 27. 17% 0.366 0.311 C28 C29 25.30% 47.53 % 25.39% 40.37% 42.72% 88,91 % 0.593 0.582 0.805 0.283 52 C29R&S abb/C29S&R aao + C29R&S abb 54 abb 20S&20R Steranes 34.23% 55 Dia ba/(Dia+Non-Diasteranes) (Calculated) M4 C27-35 Hopanes/(Hopanes + Steranes C27-29 H 1 C32S/C32s + R Hopane H2 C31 S/C31 S + R Hopane H3 C30 Hopane/Hopane + Moretane H6 18A/18A + 17 A Hopane BPX Source Indicators 1920Tri23 Index «C19+20 Tris)/(C19+20+23 Tris» 0.606 23TriHo Index (C23 Tri/(C23 Tri + Hopone) 0.154 24TetHo Index (C24 Tetro/(C24 Tetro + Hopone) 0.121 TmTs Index (Tm/(Tm+Ts» 0.717 Bis Index (Blsnorhopone/(Blsnorhopone + HoponG) 0.028 Moretone Index (Moretone/(Moretone + Hopone) 0.195 Ol30Ho Index (Oleanone/(Oleanone + Hopone) 0.004 SF G2 Index (G2/(G2 + Hopone) 0.044 G2 = coelutlon of17a(H)-3D-nor-29-homohopane and 2a-methyl-17a(H),21 b(H)-hopane Ga30Ho Index (Gommocercne/(Gommocerone+Hopone) 0.036 35Ho34 Index (C35 Homohopone/(C35 +C34 Homohopones» 0.324 Host Index (M411 00) 0.889 WESTPORT TECHNOLOGY CENTER INTERNATIONAL GMC Data Report 302 WF9761 Saturate Biomarker Report Page 44 of 49 295t27 Index (C29 steranes/(C27+29 steranes from 53) 0.636 DiaSt Index (C27 Diasteranes/(C27 Dies + C27 Steranes) 0.427 DMH Index (Demethylated Hopane/(Dem. Hopane + Hopane) nm Hopane Profile Indices (N hopone or homohopone/(Sum C29-C35 Hopanes) C29= 0.207 C30= 0.297 C31 = 0.234 C32= 0.121 C33= 0.078 C34= 0.043 C35= 0.020 BPX Maturity Indicator$ 51 C29S/C29S+C29R Sterane 0.366 52 C29R&S abb/C29S&R aaa +C29R&S abb 0.311 Hl C32S/C32s + R Hopane 0.593 H2 C31 S/C31 S + R Hopane 0.582 pnf = peak not found *** = no value due to missing peaks WESTPORT TECHNOLOGY CENTER INTERNATIONAL WEST PORT LABORATORY Data File: WF9761.D Sample: West Fish Creek #1 7460-7580' Ãbundance Ion 191.00 (190.70 to 191.30): WF9761.D o ~ () -t:1 p) ~ p) ~ (t> "d o ;+ w <=> '-J 22000' 20000 18000 16000 14000 12000 10000 8000 6000 4000 -0 ~ C"Q 'D 2000 ~. ^ to>- ~.~.~~,... I' ,~,~~~~,"~>~~.', .~:~~~~~~~~~~ '!lrpe-~?4.º9_~().00 28.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46.00 48.00 50.00 52.00 54.00 56.00 58.00 60.00 -D WESTPORT LABORATORY Data File: WF9761.D Sample~~est Fish Creek #1 7460-7580' Abundance Ion 217.00 (216.70 to 217.30): WF9761.D a ~ (') tJ ~ .-t- ~ :::0 (þ I-Q o :::¡ w o N 2500 2000 1500 1000 '^'- Jw I ^~)I,v( At \1\1 J ,\J .'-~"'I""I""JTJ"I""I'J"IT"'I""I""I""I'IJ'I"'II'II'I""I'I"I""I"I'III"I"'JI"'TI"'~ Time--> 28.00 29.00 30.00 31.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40,00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 Abun~tr Ion 218.00 (217.70 to 218.30): WF9761.D I l J ~ ,t I I 500' ~/~\VVVV"" {)y J\,~~ 2500 2000 1500 1000 '"'0 ~ fJQ CD ..þ. 0\ o I-t-¡ ~ \0 500~l\"v ~ . ,~vJ'n^,\JV0 '-^ -r"-"-r"'~' . . 1 I . . . I I . . . I I . . I . I . . . . I I . , I I . . . I I . . . . I . I . . I ' , I I I I . . . I . . I . I ' 1 . , I I . . I . . . . I . . I . I . . . I I . . , . I . , I , I . . ~ . , , . !..Ll!!e--~_g,f!:º9~~ßO 3~ºº-ª-1.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43.00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 WEST PORT LABORATORY Data File: WF9761.D Sample: West Fish Creek #1 7460-7580' 'Abundance ----¡00-217.00 (216.70 to 217.30): WF9761.0 a ~ (') tj ~ .-+ ~ 10 CD "'0 '0 '::4- V-J 00 N 2600 2400 2200 2000 1800 1600 1400, 1200 1000 400~", I"" I"" I'" """ I"" I'" 'I"" I""" "',"" I~'" """ I'" "~ ~',~,,~ Y., '~"! \',,~,:.,~ ,~, \~~:~ ~ Tìme--> 27.00 28.00 29.00 30.00 31.00 32.00 33.00 34.00 35.00 36.00 37.00 38.00 39.00 40.00 41.00 42.00 43,00 44.00 45.00 46.00 47.00 48.00 49.00 50.00 51.00 J..þ.. .-------~~---- - ~ \0 WESTPORT LABORATORY Data File: WF9761.D Sample: West Fish Creek #1 7460-7580' Abundance ----- Ion 191.00 (190.70 to 191.30): WF9761.D a ~ (J t:1 ~ .-t- -pj ?:1 (1) "d o ::¡ w o N 20000 15000 10000 5000 ~~.~~~~'....'....'....'.' Tlme--> 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46.00 Abundance ---.-. Ion 217.00 (216.70 to 217.30): WF9761.D ~-ilJ¡v~.ÆJJÁ-r~~ , . I I I I I I I I . I I I I I 1 I I I I r I ' I r I I I I 48.00 50.00 52.00 54.00 56,00 58.00 2500 2000 1500 500i.~.~~~~.ÁJI~~,~~,\~,~~, :N',\',~:~:",~, I'" Tlme--~ 24:º~6.00 28.00 30.00 32.00 34.00 36.00 38.00 40.00 42.00 44.00 46,00 48.00 50.00 52.00 "'"'d :lJ ~ ..þ.. 00 o ~ ..þ.. \0 1000 , , I ' , , I I I , I I I ' 54.00 56.00 58.00 WEST PORT LABORATORY Data File: WF9761.D Sample: West Fish Creek #1 7460-7580' Abundaõce-- Ion 177_00 (176.70 to 177.30): WF9761.D Q ~ (1 tJ ~ .-t- ~ ~ (J) I-Q o ::4- w o :'0 7000 6000 5000 4000 3000 2000~,~ 1000 ---r-T( r, "1 "1 I "1 Time--> 24.00 26.00 28.00 30.00 Abundance .rv-.lv , I I ' I · I J t I I I J I I I , I I . I I I . I . I I I r I I I I I I I I . I I . t . f . I I I , I I I I . I I I I I I I I I I . I I I I 32.00 34.00 36.00 38.00 40_00 42.00 44.00 46.00 48,00 50.00 52.00 54.00 56.00 58.00 Jon 191.00 (190.70 to 191.30): WF9761.D 20000 15000 10000 ~~~~~.~, TIæ~=~~'!.:º~6.oo _gª=.oo 30.00 32.00 34.00 36.00 38.00 40.00 ""d p) \Q (1) .þ. \D o ~ ~-ltlj¡v~.~~~~ ~ , I I I , I I I I I I . I . I I r I I I I I I I I I I I I I I r I I I I I I 1 I I I I . I I I 42.00 44.00 46.00 48.00 50.00 52.00 54.00 56.00 58.00 5000
