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GMC Data Report No. 309
Characterization of hydrocarbons extracted from two intervals in the North Aleutian COST No.1 well as follows: cuttings composited (15,700' - 16,800') as one sample, and core composited (16,006.0' - 16,029' and 16,701.2' - 16,720') as one sample. Received 23 January 2004 Total of 49 pages in report Alaska Geologic Materials Center Data Report No. 309 f 1 j ~ J,' 'I ~ ~ ~_BASELINE CGSI ANALYTICAL LABORATORIES r'l, '. r" i j "1 ',," ~ ' i rJ :'] ~ . ì.. " b [] .I] II Characterization of Hydrocarbons Extracted From Two Intervals in the North Aleutian COST 1 Well Prepared For: Minerals Management Service Alaska Geological Materials Center (AGMC) Report No. 309 : ~ . :) '1 . , P.O. Box 772805 18205 Fish Hatchery Road Eagle River, AK 99577·2805 PH 907 696 0079 ~," ], 1 rJ r J 11 Performed By: Baseline DGSI T 1 i \ L1 + 1 : ¡ 1 i ~ , ~ t , 1 Project: 03-529-A November, 2003 BASELINE DG S I, U.S.A. 8701 New Trails Drive, The Woodlands, Texas 77381-4241, Tel: 281.681.2200, Fax: 281-681~326 E-mail:info(á)baselinedQsi.com. BASELIN E 0 GSI, Brasil Rua Jardim Botânico 674/413, Jardim Botånico, 22460~30 Rio de Janeiro (RJ) - Brazil TeVFax: + 55.21/2259.5992 E-mail: office<ID.reslabsolintec.com.br , . Web: http://www.baselinedqsi.com ~'l ,'1 ~ Li r1 ;, ~ j } , f"" "'1 ',I i J [J f. '''] :1 t' u rl ìI., 1\ 1. ..,·1 :j i r -., :\ / i ~, . í.. ii ~ ~,,', "'1 ii' :¡ ~ { 1 ,\ \ tJ 11 1 ; r 1 I J . 1 SOXHLET 1:"/, ':',. ' '''''':, ' ~,,' . J , . ,Co.mpaoy: MI~ERALS MA~AGEMENT SERVICE Projéct,#: 03..~2~"A". ~:I cr ent ID L b ID Rock Net Extract % EOM I a. .. ~. (9) , .. _. " _ Extract (ppm) ..., MM$A~QØ~~1" MMSAK2003-2 , MMOOOOQ1' MM000002 53::S3ç2 52.3323 lIaseUne/OGS' . USA 8701 New Trails Drive. The Woodlands. TX 77361-4241 Telephone: 261-681-2200 Facsimile: 281-681{)326 E-mail: info@base~nedgsi.com Web Site: http://www.boselinedgsi.com 0.0347 0.0609 ,ô;oø:, 0.12 ,,:'.~~:(::~::: 1164 ..', Baseline DGSI . IIro:lI Ruo Benjamin Bo'is'o 55 /301 Jordim Bo'6nico. 22461-120 Riede Janeiro (RJ} -6razil Tel/Fox: + 55.21 /5377693 E·mail: sspCWsoGntec.com.br Jl ~ 1 f} J i f.,' ,of ::1 1 j r, "] ~ ~ . r'· ;~, i ¡ :[1 ,J U~",'" ~ IJ if] t r 1:\ ! L ~.. ] ',' J ~ 1 :¡ I 1,.1 ~,',:1 ,) 1 f¡ ,] i. r 1 ) ¡ i 1 i J ¡ , , ; , . I ., j SULFUR ,'','::' : ~;" ' ,,' , ":,:""":,.,,, """"',"M' ''''IEþ;: f ",'M' 'N G~fJlE ",'tSE· ".CE ",..:i~~Q:m,~,«"~~.::\"I~ì;,j~~$:" "A, A" ç.,,:N· ',',"'~.;~.",,',' ProJ~"çt #: 03~52~~A , .', ., ..I Client ID lab ID :~~r Method Comments '" ,t¡jt:',':,(:j¡:,'^iU:'I')'A'n-~ :..', ' . ·:::'~"':~VI~~'~\~~~:~;'I.:··. MMSAK2003-2 " , "MMoÒPØO,1, MM000002 <Òi'1'þprh" " <0.1 ppm ~~~ßO~o EPA 6020 . ' ," "I , ' lasellne/OGSI . USA 870 I New Trails Drive. The Woodlands. TX 7738 -~2~ 1 Telephone: 281-681-2200 Facsimile: 281-681-0326 E-mail: info@boseUnedg51.com Web Site: hllp://www.baselinedgsi.com Baseßne DGSI . lraD! Rua Benjamin Balista 55/301 Jardim Bo'ðnico. 22~61-120 Rio de Janeiro (RJ - Brazil Tel/Fox: + 55.21 /5377893 E-mail: ssp~oHntec.com.br rl ,( j' :'¡ ,:I; If" 1 j r~ ; ì rl [ l 1'1 1'1 u [] rJ r' l ' L T'J Ii fi ¡ L, r,',',,¡ i 1,',1 1 I I J 1 J .! ¡ i ¡ T 1 ~ ì ; i '. J , 1 j , i , } tI !!~~~I!~~I!!,~..,~_~.~ I I Comp,any: .-MINERALS MANAGEME~ METALS , '".:,~," 'I ProJe~t,#: 03-529·A Client 10 Lab ID Ni V (p ~ I (ppm) ",:. :'N1tØ~~~ø.:øª~r MMSAK2003-2 ,MMøoþqP1' ~M000002 1.'7 1.4 I:: . ":,~:Z~:;~i!::,', :,:~:;:::,:'(~~,';v:}::};!: 273.7 , , BasellnefOGSI . USA 8701 New TraUs Drive. The Woodlands. TX 77381-4241 Telephone: 281-681-2200 Facsimile: 281·681-0326 E-mail: info@baseUnedgsi.com Web SI'e: hllp://www.baselinedgsl.com Baseline OGS' . Bl'azII Rua Benjamin Bollsla S5 f 301 Jardim BotOnico. 22461-120 Rio de Janeiro (RJ) - Brazil Tel/Fax:'" 55.21 /5377893 E-mail: ssp@sonn.ec.com.br ~--";;';'~~____~6"'" ¡.;.o~ --..i ----.I __ ...".~ -- ~ ~ ~ -----..... ~ --...J ~~ ~ ~~ ~.::~ ';;'<~'---":-~ ----.J _......... ~ tI ~~~_-='=J~.~..-~~.? I MPLC CompalJY: MINERALS:MANAGfS~~,*T:$~8MtQJ;S··. . . " . :~-~-Øj~~t'~r,' ··":~tª~$~QMl~,:' ',' ,. . . . "'1 . , Client ID Lab ID Sa~pre S~ T A~O N~O A~PH % % % % , . · I 1 a · I , . ~ I . a .. , . . I SAT ARO NSO ASPH MMSAK2003-1 MMSAK2003-2 MM000001 MM000002 0.4832 0.0609 0.0281 0.0267 0.0048 0.0044 0.0137 0.0086 0.3656 O~0078 5.82 43.84 0.99 7.23 2.84 14.12 75.66 12~81 ' BaseIine/DGSI a USA 8701 New Trails Drive. The Woodlands. TX 77381-4241 Telephone: 281-681-2200 Facsimile: 281-681-0326 E-maI: infa@baselinedgsicom Web Site: http://Www.baselnedgsÏ.c:om IaseIfne DGSJ - Irazl Ruo Benjamin Bo'ista 55 /30 1 Jordim BotOnico. 22-461-120 Rio de Janeiro (RJI-BraziI TeIIFax: + 55.21/5377893 E-maIl: ssp@SQintec.com..br ~ ; ,........~ ~ y,,,,u,_«¡ -----...; ~-'-"~ ---- ~ ---- ~ -----... ~T'-l ~ --...i ---... 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"::':,--' "",..I :11 ' - .--:<--, :J 'c -:~:~,Æ, c-r~ :-_-..-_-",',:--, ._c :'~ --c ,-:, ,_~c;, :', cu-'::" '..:=- ,,'~ --,:" ",-:' c_:, _,"~---: "_~ :~~:, \:,,-,-,;.,;,' :c:,,{:~- ,-~ ' :- -''=':c---<~ ,_"":~..; ~_______'~~:-c.:~;.. ,- J:~~-:~~" ,~-}lJ~t~:,-t·,JL~' le:::::-~~_~þ:;:-,~i ;-?y;-/~ -~ ,:~~;~;-,~',~::~:,-,? ~ 7~F,'_:;~~~f~;~~~~ ~ ~".~ -';' -:-<. ,. :_ ";~~..::-___ ~~(-:~" -_._, of:' ---,: ~~ ,_=,,== _c~~,----=D~M,MIIOOOO 1 North Aleutian Cost 1 BaselineDGSI Project: 03/529 -, .. ' , , Saturate NSO + Asphaltene FIGURE 3 . Distribution of major compound groups from IIqiud chromatography data. ~~ ""--oIIoÍ ~ ~ ~.;....~~ ---..¡ l,,··J J ' n r~ f] r: n D [] [] r,..,] t r] 1. [] [ IJ u r ' 1 I ,; 1 , ¡ j BASEL.INE CGSI __1_..".'. ~~_ ....,__ .....!...,-.-:...1._... ..._-... ISOTOPES :, ',,:<:',øø:m'p:¡'6Y;·:MJN,~~,L$::11"INÄGe:Me.NT$,$~"',Q$$.. , "n' .."'J"",.t"~ '0' '~"'5!!t'd"i~' ',r:a:øøq .,:~} "",,~~',~;P.~Ij~/ Client 10 L b 10 Ö' ,)C Ö1')C Õ1')C Ò I,)C ò1JC a .. , ',. Ar. II ~ . Resin Asph Whole : ',,',,'MNts'*~,QØ:~~1' MMSAK2003-2 MNiQÕQQOt' MM000002 -2ä~Q -28.0 727.3 -26.9 , . Salellne/DGSI . USA 8701 New Trails Drive. The Woodlands. TX 77381-'2' 1 Telephone: 281-681-2200 Facsimile: 281-681.{)326 E-maH: inlo@basellnedgstcom Web Site: http://www.baselinedgsi.com lalellne OGSI . Irazll Rua Benjamin Balis'a 55 1 30 I Jardim Bo'ðnico. 22'61-120 Rio de Janeiro (RJ - Brazil TeVFox: + 55,21/ 537 7893 E-mail: ssp@solin.ec.com.br Saturate Fraction Carbon Isotope Composition -25.0 -26.0 -27.0 -28.0 -29.0 -30.0 -31.0 -33.0 -32.0 -34.0 Carbon Isotope Composition of Extracted Hydrocarbons from the North Aleutian Basin COST # 1 Well Sòoi-:.";"'-':4:'~ ..--"--._-,,, -....J ~.!.-~~ ~ ---....; :..=J :c:::Jc::::J .~ ---..I r-~--"1 r '.., ~ ~ I ---.. ~4 --- ........-...., -... ~ --- -35.0 -35.0 -34.0 c: .2 -27.0 ...-. .; o Q, E -28.0 o o CD Q, , .s -29.0 o .!!l c: .8 -30.0 .. co o ð -31.0 ; C.) ns .. ~ -32.0 ; ca E e -33.0 < -26.0 ..25.0 r1j~ ~ ~ r) ~ , WHOLE EXTRACT GAS CHROMATOGRAPHY 1"1 North Aleutian Cost 1 BaselineDGSI Project: 03/529 u Sample Identification TOC GAS CHROMATOGRAPHY RATIOS 10 I Depth(Feet) Wt% PPM Ext.ITOC Pr/Ph Pr/Ci7 Ph/Ci8 OEP MMOOOO01 MMSAK2003-1 I NA 648 N.A., 2.6 0.45 0.19 1.10 MMOOOO02 MMSAK200~ 15700 168001 NA 1164 NA 3.7 0.83 0.23 1.22 Sample Extract AREA DATA 10 Weight Weight Ci7 Pr Ci8 Ph C28 C29 C30 MMOOOO01 53.5,362 0.0347 104613 47231 95257 17843 31740 28748 20578 MMOOOO02 52.3323 0.0609 109244 90946 104231 24276 49461 49531 31843 ~ . [] n r: r 1 ¡ , ¡ I. " Sample Identification NORMALIZED ISOPRENOID PERCENT ID . I Oepth(Feet) ICi3 ICi4 ICiS ICi6 ICiS ICi9 IC20 MMOOOO01 MMSAK2003-1 1.2 2.9 12.0 22.1 16.9 32.6 12.3 MMOOOO02 MMSAK200~ 15700 16800 1.3 3.3 10.6 18.6 15.3 40.2 10.7 Sample Identification AREA DATA ID I Oepth(Feet) IC13 ICi4 ICi5 IC16 ICiS ICi9 IC20 i MMSAK2003-1 1746 4180 17363 32010 24546 47231 17843 MMOOOO01 168001 MMOOOO02 MMSAK200~ 15700 2904 7435 24051 42050 34626 90946 24276 I [] r] L ;1 I l, , [] ! I r 1 LJ ¡ 1 LJ ! 1 ; I [,1 I I I \ .; j ~ 1 rl 1 j rl rJ 1"'1 r] [ rJ f] i,' "'] /\ L j I t rl t" T, 'I 1 i fJ II 1. 1'1 i 1 [ [1 l ¡ : J ¡, j tI ~~~"'=~,";..."!.~.,,e.~.~ I Company: Co~ntry: Basin: Lease: Block: Field: Well Name: Latitude: Longitude: MINERALS MANAGEMENT SERVICES UNITED STATES NORTH ALEUTIAN COST 1 Extract GC Trace 11'I r-f ~ \0 ~ ~ ~ Client ID: Project #: ' Lab ID: Sample Type: Sampling Point: Formation: Geologic Age: Top Depth: Bottom Depth: co r-f U :z; 0'\ ~ <:> <'-I ~ ~ ~ ~ u :z: M ~ ..,. ~ 11'I <'-I U :z; ~ ,U :z; r- N ~ EXTRACT GC MMSAK2003-1 03-529-A MM000001 CORE G2030480.D 0:> t1~ :z; ~ \0 <:> ~ co 8~ 11'I H ,~ :Z:8N ~ H ~ ZM~.~~ I- ~ ' ~UM8MM co 0'\ <:> ~ .... . :Z;~:z;uCJº M ..,. .. ~ ~ ¡J..,L...aL4A~JJl~~-~~· ,-~- ¡< ~ Råti6~ ' Prlstane/Phytane Pristane/ri C17 Phytaneln c,a !1Ct8l:11C19 , nC17'n~ CPIMarz¡4 2.65 0.45 0.19 0.96 3.64 1.03 ... ~ C""I ~ 4> ... ... ... [ 'Thompson, K.F.M., 1983.GCA:V.47, pJ03. 2Mango, F.D.,1994.GCA: V.S8, p.89S. )Halpern,H.I., 1995,AAPG Bull.: V.79, p.801. 4Marzi, 1993.0rgG;20, 1301. Re$ålved .Cômb<:>nðntS{%) Normal Paraffins 34.9 Isôprenolds' 4.0 Resolved unknowns 61.1 ,""'1 :¡ ! :~ j fl ;¡ ~ [J r: ..','-,]" " r , ~ , n rl i,~ [? 1J i.. I ,I 1. T" "] "I ¡ L r' ] ( L [] ! 1 II 1 \ ! j ! J Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 Client ID: Project #: Lab ID: File Name: MMSAK2003-1 03-529-A MM000001 G2030480.D Peak Compound Ret. label ,Name Time Area I .. U Î ..0 I Hght% NC9 , :~,ø~:Q' IP11 ,N~~'1;-' NC12 '¡'Þ:1;~', IP14 ,;;Nc;1,ä ' " IP15 :NC::1\4', IP16 ,¡t4:¢H~' NC16 ',tR.1:$":: ' NC17 ,:> :"ff11~:,::, NC18 :- '::JP~Qi, NC19 ;,>\N~~Q'" ,: , ' NC21 "Nê2~~:', ' NC23 >t;lÇ24: NC25 " '.:N¢g6' NC27 ',N¢2S;"'. ' NC29 ~qß,ø NC31 N¢32:': NC33 Nq~4, NC35 N036 NC37 'NC~ß' NC39 NOtO' NC41 Normal Alkane C9 :NØØ1i~#t~k~ij~:¢,1Ø ' , Isop~en~id ~ 11 , " :'NøtWatAI~a~~;C11 Normal Alkane C 12 ,J~~þtØM6idi¢43 ' lsopren~id C14 :Nårmijt'i'JS ~ahe"'C13 ' Isoprenoid C15 ',:::N.~~.I¡:~"~Ønè:G14 " " Isoprenoid C16 , ,,': :N,qrTr\~I;~I.k~oe'al5 ' Normal Alkane C16 , "',, ,;,'~~t~hQJp::Ø1:ª Normal Alkane C17 , , ': "'J~Ptø'Òpi#)Ø19':(~fistánè) Normal Alkane C 18 ,,', :; 'JsØþ,(ðhø¡d\bØ()'(Þ~YtahØ) ~ormal A~k~re C 19 , ""NØ~J,:~~a:n~i:~ß~p , Normal Alkane C21 ,', : 'Nq.rtriåt~lka~e:¢22, . Norma'! Alkane C23 , , Noli11aj'ÂI~anßC?4 Normal Alkane C25 Nø'ri11:åFA!~anèÖ26 ' Normal Alkane C27 , "N:Q~1.:A1kané'C~8 Normal Alkane C29 NdrmaFAI,k~ne 'C30 Normal Alkane C31 ' N9~IAf~r\E:t032 Normal Alkane C33 ~Qnna 'AlkanøC34 Normal Alkane C35 'Norrna,IAlkaneC36 ' Normal Alkane C,37 Normal Alkane C38 Normal Alkane C39 Norm~IAtkane C40 , Normal ,Alkane C41 3,t¡,¡:Øa 36.593 37:4~2 40.069 ,4"tA7,5 ' 44.622 " , 4~,;4~7 48.127 , '4Ø,¡~ôQ 53.402 5~;3Ò.8' 57.042 57.3øa 60.498 , 60~å'6'1 63.790 , ,aßi92'9' 69.929 72.799 75.548 ,78;1'91 80.732 , '83:'1.75' 85.532 87:ØØ¡; 90.008 92.126 94.183 96:1'72' , 98.110 ',99J~78 101.806 103.709 105.824 108;230 110.971 114.158 117.862 8fT 5054 1746'" 4180 ,2:7674, 17363 ,701;$(;) , 32010 1'(),1990' ' 106552 .24~6 ' 104613 4723+~ ' 95257 1784à ;, 99155 ,9,02$3 80527 72224 67727 5869? 51570 44499 39092 :31,740 ' 28748 20578 ' 16968 11.001 10132 ,6458 5841 3816' 3346 2954 2673 2770 1947 ~2Q , 1637 , 4:$7 985 '92VQ;'.., 4718 :21'.Ø,2~,:", 6189 2Q~'$L' ' , 32328 ,6Z~d, 30985 , ','Q224,: 28841 341'9' " 27370 , , ,2$20.5:",,':' ,'" ' 23102 20$25':' ,'" 18963 167'49 ' 14724 1~7~9: ' ' 11038 820P, " 7604 ~5a'$1 4305 2:&Ø9 2368 1514, 1294 831 630 47,4 381 295 206 , ,,',O~:02:·" ·,',",:,:,":::"Ø:íøi~!:';\ 0.14 0.18 ·':Q'j:dš ,',' ',:'.'.'.,~,þ!¡Q,~!::<',:.: 0.12 0.11 , , ,:O',~6": ";;i: ~!:¡!~~y:,',\ 0.48 0.53 ::';1;iØ# :,':,,::;,:':/~i~~\i:<!" 0.88 0.70 ": 2';~~':':" /, ';/:'i~j~I,,:(,'n: 2.94 3.64 , " , ,,:,,:,,:ijl~i:::< :,I,:~"":døA~~J.':,:;;:: 2.89 3.49 " ,';' :,1;~Ø>, ,,:::.':~.f¡~;,~,<?¡' 2.63 3.25 · :()'¡4~ 0:', :;,:<:&,ja~}>/, 2.74 3.09 "~¡4Ø: i"'i:~!;~Vti;! 2.22 2.60 :: ~¡t)();" 1.87 1.~2,:' 1.42 , ',." 1;~a.', 1.08 , ".:Q;,8,Š:' 0.79 ,O;~l" " 0.47 '. ':O~30 0.28 OJ,8 0.16 0.11' 0.09 Q ;()8, 0.07 0.08 0.05 2.14 ':1·';ØS'..: 1.66 ",:',::;t:~~,>,:: 1.24 '.'.:,Ø}~2':";:/: 0.86 "'·Q;'ø:~:>:'':.: 0.49 " ":..ó';:ä:~;,:"! 0.27 ".Ó>1,í::,::··· 0.15 '0~O.9:,;,',., 0.07 Q;05, 0.04 0.0.3 0.02 '--.- 5 - o o o o - >< ( ) fb C o C. fb ( ) a:: o o 10 . o...--.a.; ~ North Aleutian Cost 1 MMSAK2003-1 ~~ - ----- >......--...< ~ ~ ...J...-...i ~ -- 15 20 25 Pr Ph ~.......J. J ,j.,JA I.. ~ "",1.\I.k" ~>4..JJ.".LJ.JJ.L...~ 20 30 40 50 60 90 70 80 Retention Time ~ ~ ~ 30 100 ......~ """''''''=-''''I "",,",-'-o'~-4 --....; --....1 ---..¡ 03/529 - MM000001 Extract 110 l'l ! ì :{ ,) r} 1 r;; 1.! 1"1 í] ,-..,. it ~"". r'J [] [I r t,~ r i. r . l..J f'] 'J J J ] ¡ ,.1 fI ~~~_~='I~.!..2.~.~ I Company: Country: Basin: Lease: Block: Field: Well Name: Latitude: Longitude: Extract GC Trace MINERALS MANAGEMENT SERVICES UNITED STATES Client ID: Project #: Lab ID: Sample Type: Sampling Point: Formation: Geologic Age: Top Depth: Bottom Depth: NORTH 'ALEUTIAN COST 1 \D ~ .... u g :z¡ 0::> .... U") ~ C7\ ...... .... g g C) (',¡ !ii .... <"I ..... g <"I ~ <"I ~ ...... (',¡ g ..... <"I U Z U") <"I ~ \D ~ <"I r- U '" Z <"I .... g M .... g \D ...... ~ EXTRACT GC· - MMSAK2003..2 03-529-A MM000002 CUTTINGS 15700 FT 16800 FT G2030481.D ex> C7\ ~~ o ...... g.... ~ ~ 0.. U") 1-1 <"I ...... ~ ~ ............ 1-1 ~ ~g~~ :: ggiJ M ex> C7\ zu............ 0:> ~ ..... .Ill J :z¡ g g ~ u ~S ~ m, ~.J~~Ju1~_'^·ll.- ,-. = ~ ~ Ratibs' ',' PrlstanelPhytane þ~~~n~nG1j Phytaneln C18 óGi'¡nC19 nC17/n C29 CPIMårz~ 3.75 0.83 0.23 1.03 2.21 1.07 ResolVedCOrrlponents (%) Normal Paraffins 46.1 I~oprenoids 6.6 Resolved unknowns 47.2 , IThompson, K.F.M.,1983.GCA:V.47, pJ03. 2Mango, F.D.,1994.GCA: V.58, p.895. 3Halpem,H.I.,1995,AAPG Bull.: Y.79, p.801. 4Marzi,I993,OrgG;20.\301. ~,,'l J } ['] I'-'~ ' , - 1:'" ~ I' ~ f' ~ ' L n [4 n f] .... r· ;:1"".. ] 1 r- * I L f] L f] 1 ¡ ] ~ 1 1 ¡ ~ \ i j ~ ~ . I ~ ~ .: 1 Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 15700 -16800 FT Client ID: Project #: Lab ID: File Name: MMSAK2003-2 03-529-A MM000002 G2030481.D Peak Compound Ret. label Name Time Area. ., I t ~. 0 . Hght% Nce '!~,~!1Ø:,: "',,, IP11 ";':":'N,~4,i ' NC12 ::;iJ~1,:~/ ' IP14 !;,~;:::!64,~;1~:'. IP15 i¡::::'::~~;1'4"" , >:,:;~êi~S ' NC16 ",< :!:':'1~4~~,',:,,:;" NC17 :fi'\1:e~""Ø0,.':" :, NC18 ?i':::"í8~Q'::', " NC19 ::,:::';ij,øgQ:·,:, ," ' NC21 :,;:;iN,~~?; ,: NC23 ;:'::::N'¢?4': NC25 '::"'::~~~;~::": NC27 ·,,:':;$ØZ~:\ NC29 ::"..:~,¢;$Ø\" NC31 :,:',;N~,~~ NC33 "Nß3'4", NC35 ':':N03$.. .. NC37 "Nd$,8 NC39 NG4(): , NC41 Nannal Alkane C9 ,,:;~~'~~nM~~inø:'OH)'" ' Isoprenoid C 11 , "~9~1;~I~~rtØ'C.1f Normal Alkane C 12 ':i$þ,þr~,6:ø'[ø~ø1'~':' Isoprenoid C 14 , :;,,', :":NQ~~'l:i;Slk~~Ø:þ1à I~,oprenoid ~15 , :, ,'"N.qffl1ø.t:f~'~~ne::b14 ' , Is()prenoid C 16 ,':'~Ormal,~~aÓ'e..GJ5 ' Nonnal Alkane C16 : ',.. :::,':I~º,~çØ~Ø¡~i:Q;1iå ' Nonnal Alkane C17 ':'I$Ó:øtøJ,i<ii~::G1;~':'(þ,rt$tahð)' .. Nonnal Alkane C18 'j$~ßt~hØ¡,~>Q~(),(Þhytäne ) Nonnal Alkane C 19 ',',. :'t;¡q:iThª,iÁlkØ:ø~:C~O Nonnal Alkane C21 , '::,~Þrfu~I:AI~åhs,:Ö~:? Nonnal Alkane C23 t~øÂ11~IAlka'haC~4 ' Nonnal Alkane C25 .' 'Nbrmál:::ÅJkå'h~<C26 . .,',.,,' ,'''', ':,",: ',,' ,', : Nonnal Alkane C27 ·:~(:)miaì;-:~~h.é'C28' , Nonnal Alkane C29 , ,,'~c)rmªi'AJ,k~nøC30" Nonnal Alkane C31 ,:NbrmårA.!kan~·"C3~ Normal Alkane C33 Norm'äl Alk.áne, C34 Normal Alkane C35 Normal:ÄlkaneC'36 Normal Alkane C37 , Not1l1ål:AikaneC38 Normal Alkane C39 Nqrmal Alkane C40, Normal Alkane C41 , ~~~4å41 27.758 3:j;§S7 36.585 "':3t~24' 40.064 , ,41,~1:714 44.609 , "45¡4'9Ò" 48.130 4~;556 53.399 ,', &5~302 57.036 ,57;3Ø:5 60.496 60.932 63.790 ,66;Q28 69.932 72;8Ø4 ' 75.552 78.'198 80.737 83A80 85.536 87.J~03, 90.003 92~ 122 94.180 96.16,5 98.103 99.979 101.799 103.704 105.822 108.210 110.970 114.126 117.840 ,229: 93 2()11 14379 29Ø4: 7435 44149 ' 24051 , 82:Ø38 42050 1068,01' 110377 34626, 109244 90946, 104231 24276 101417 103599'" ' 94536 9053,2 89279 , 80378 76653 66413' 63774 49461 ' 49531 31843 28816 16267 , 17455 ,10359 8672 4412 4379 3708 3424 3271 2716 ,,32',' 24 ,p:1'(),' 4891 :897- ,', 2332 14:~;a4' 6100 26476: " 9649 , a044~" ' 32204 7~$ô 32344 1:aøø~)', ' 30821 "45t,Ö' , 29756 2a9,4:§",~ 27236 , 2~6,~;~' 24079 , 22499' 20956 ,,18~~4 ' 17344 '132,50 13101 '8652' 7245 4'1'35' 3779 '2486 1877 10~2 839 610 480 353 266 ,,' '.' ,~\'Ø-iº:j;:·:. :::;':,J;L/~t~l[Qh:i)\ 0.00 0.00 : :: ·":::ø1,g~:{i:}:,:,:,::(h~;~ßMJ¡)i;';;\ 0.42 0.58 , ,', ","btq9:,~~:' ',;,: i:' :'!:,;:(,¡;~~:~i1/{;:t 0.22 ' 0.28 ,:.,: :,::'1'::;~:Ø;~::':; ,:,:;"::i;;:?;;ijj~!~1~,\:\~; 0.10 0.72 ," ,::2¡i'~:'::'":,,,.\,:;);}~:~:~¡ª¡i/,;~ 1.23 1.14 :' ',' :'~'~~'ø) :;;':"'" ': ,::"i~:!iª~(§~~t¡:/~; 3.23 3.80 3:,2.0, " " 3.82 '/í~9'~>",'>::i",: :i~:;!~!!,~~'ii~::.iN 3.05 3.64 " ", ":Ø~~1,:,;:/:,'/ ':':,'S¡~~,ªj¡:<~~ 2.97 3.52 ":,,,,"::;;3.:;Qi,,;i:>i:{::t!::i~eti1::~~~ 2.77 3.22 :?~~$'\;::: :"::',"J:;~:ig~<;V;¡ 2.62 2.84 ',,:~'i;3:6>':< ,',.:;~"::;':2~~~\-;:,:~ 2.25 2.48 "1;~5, ", ", :/):,/i?~:1i~;;::,'i, 1.87 2.05 ," 1-:;45,>:','" ':';,,:>;1i;$~b',()\ 1.45 1.55 ';(i,9.~!,: ',,'.:, '".:\~i~Q~~;J·:',::: 0.84 0.86 O;4,:a:,;", ;' "'ø':~~$.:r-;::.'( 0.51 0.45 "'();~O': "":,q;i?~\:\'t 0.25 0.22 0.13."" . '.Q,~"Z;',: 0.13 0.10 ,0: 1·1 ", 'Q~Q,:t',:'o: 0.10 0.06 '0.10 O~Q4 0.08 0.03 4 ... o o o o T"" >< Q) ø c o Co en Q) ~ o o "':1_~ -._'..... ,.,....~....:.J.....J~ 10 20 10 ~...:..,..;~ ~ ~.~ ~-~Ìf F.-~~ ""~~..... ,~ ~ :::::J ~ ~~ ~ "'>o;..=."'""t ~..., --- ---..... --- --.. '"----' '----i ~ --...¿ -- --..,¡ ---..; ----.¡ North Aleutian Cost 1 MMSAK2003-2 15700 - 16800 Ft. . 03/529 - MM000002 Extract 15 20 25 Pr 30 Ph . , 35 ~1~.lU~j~w.¥ ,j.~J~.~~Jj,A~~. , I 30 40 50 ' 60 80 100 70 90 110 Retention Time ~..-.. ~ ~~ ~ ~ ------.. "'~-"=., =~-"'4 ~ .----.J ~ "----i ,¡U_~J :..::J ~-'-~>;-~ ---...øJ ~ -...J ---- '----oJ ~ 10.0 North Aleutian Cost 1 BaselineDGSI Project: 03/529 A Whole Extract / ~\o~ , ~~ ~~ ,.... Ü I c: OJ 1.0- c: .!9 (/) .¡:: a.. ~ ~\O ~~ (v0# ~O<:) ~ A - TERRIGENOUS ORGANIC MA TIER B - PEAT-COAL ENVIRONMENTS C - MIXED ORGANIC SOURCES D -AQUATIC ORGANIC MATTER (ALGAUBACTERIAL) 0.1 0.1 I 1.0 Phytane / n-C18 10.0 FIGURE 2· Plot from chromatography data showing organic matter type, source rock depositional environment and thermal maturity. ..:. , fl ); ~ ,f f", :¡-, ¡ r" ~ L~ ,......,. ! ~, :~ ~~~.. ¡ 1.." !'...., ! ' :1 ' ~...; '...1 r~ ? ' ~ ¡, r': t.! [J ] I .: ¡ í l . !~~-';.;.~~.~.~E.2.~ I Company: Country: Basin: Lease: Block: Field: . Well Name: Latitude:, Longitude: MINERALS MANAGEMENT SERVICES UNITED STATES NORTH ALEUTIAN COST 1 m/z 191: Tri- and Pentacyclic$ M2031232.D ~~~ ' ~.~,.)¡..~ , m/z 217: Steranes M2031232.D ~#VrJ ~¥.I.JI M,~J''Mf~ m/z 218: ßß Steranes M2031232.D ~~~,¡~¡),.~ SATURATE GCMS Client ID: Project #: Lab ID: Sample Type: Sampling Pòint: Formation: Geologic Age: Top Depth: Bottom Depth: MMSAK2003·1 03-529-A MM000001 CORE .. · (on Areas)' Appl¿ TEV.) t~. (m/z . 1: ,....~.:' ...;'..-,,', I.'," .:,:..",!.;::.~:"....",:"\':~"'.'''': . "'~fl~.'''!'''~'''~,,:~:,,~::'''.'':''';''::''.:'I.r:'I.',:~ %C~7 aßßS (216) %C28 aßßS (218) ~qQ29#Øß'$!::(~:~øJ', %C27 aa:aR (217) %:C~~'Q«~R(2'1r) %C29aaaR (217) $I($:+~l:,(C~«~H217.) , " ' ' ßßSI(~~S+aaR) (C29) (217) (ê21 ~22)1(C27tC2ij+C29')'i(~17) C27/C29 (aßßS) (218) C2iC:~:«(ißß$J(2:1 S), Diaster/aaa Ster (C27 )(217) " Q~Ó:~ß~:SS~f~n~,'.Jnd~x,:,(~'1Øl, C30 S+R Sterane Index 218) øiø.ariønøHøparié ' G~mmacerane/Hopane Nórb.QP~hêlHopane Bisnomopane/Hopane Dlah()þ~ne/HÒpåne Moretane/Hopane ~~nÞr+hþparieðiö,pa"e' Ts/(Ts+ Tm) trisnorhopanes è2~T~p29HOþanê H32 S/(R+S) Homohopanes H3'5/H34"H()mohQpanes' C24 TetracycliclHopane C24 fetracycliclC26 TricYclicS C23/C24 Tricyclic terpanes C19/t23 ,Tricyclic terpanes C26/C25 Tricyclic terpanes (è2ß+C29 Tn ,'eliC$)lTs ' stèr~nèSlHopanes Tricyclic terpanesIHopanes Tricyclic terpanes/$teraJ)es 'Definition and utility of the ratios can be found on our website www.8aselineDGSl.com 2A=Source Age; D=Oepositional environment; M= Maturity; B=Possible Biodegradation ~hermal equilibrium value of the biomarker ratio and in brackets 'the approximate VR value at which this value is reached , ,3t·:i:J, :,~ø·",·,,"":' ",,'¡ ,:".":. 29.1 D , :>39.$,::' ",'ct.: :" 33.9, 0 ,,::?~:¡:$F\~.":D:~ "..,::: ,..'; 43.6 D .',' O~á9'" ~i..: ~ ,; Ò,;,~,5:'(Q~ð~)" 0.50 M 0.70 (0.9%) , , ::ø;,'j,ij::;,,:::':: ':',:: ":"?i:':::/ :::::\:,~!i:>~,;:,;:,;~,;,;;';,:t~! 0.80 D , ',,'~;~':;:i:: ','p." 1.52 MID ,~.OO ~~ ..~~~ ",',,:~~,Q/" ,,'{(: ..."" <, ': 2.7 D , ~. L, ::' 0.09 0 , :,' ',:':'º.§s,;:":~{~':'·;';:::':::'\!:;-/\:'~':';:'1ni;',; 0.14 M 0.05 (0.7%) ,.·",<Q>1;~:: ::::' ::~!$'(:,/··x/::i.r'i}i~';,:':':('/Oi;,::,\S;i¡ 0.59 MID 1.00 (1.4%) ,:Q.#7::' ,:,i":M:' ' ': '~O::,":(;i,: 0.54 M 0.60 (~.6%)' , ,:CÚ8à',<':ri::,::"', ",,"'( 0.20 D , :o.t~:'b 1.67 D 0;43 0 0.73 0 ': ,'",Q~~7 ,:" ::A: ,,;:./, , ..,,':Ô~ß9;·' "'Q"'" 0.80 M 1.00 (1.4%) 1.17 MID '1ßO(t,4%) r'" ¡ I ¡ j f'" "-, ' I, ~ r L r"? f ( , , .. ...... \ i I ~, .1 ~'l -, r"" 'J ] Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 Client ID: Project #: Lab ID: File Name: MMSAK2003-1 03-529·A MM000001 M2031232.D Peak Compound Ret. ppm ppm Ion label Name Time Area I . i ~ (Area) (Hght) ~~~?;:::'"i¡~: " ' , ",~~~:~ne(¡~tefl1al standa,?) 123 RIMU rimuane ,~~~~+ : :":",::,êfM::.', . , ,', '. ',':'Pjh1a.t~n~" 123 ,ENTBEY ,~nt-beye~a~~, " ~;~~\,,:::,,'-:.i$~~I,M ",i~þplöij3~nø:':, ~,2,~" ",B~~HYLLO ß:~hY,II~a~ane ~;~ø,::::;;:f;e~~!4,r{;" ",ß~~Q(M~,.'" ~,23 , ~.,..PHYLLO, (X~p,~YII<>eladane ¡1'::~S\;:,):i::~éAfiøf:: ,', ' '·ß.~(qtð~e: 187 4MDIAM ,,4-methyldia~~~tane, ~::~7:i ," ,:1':MØI~" ,1'"nî~W>1cUª~ntåïi~ ,', ' 187 3MDIAM 3-methyldlamantane ;t~:: ""t¡).I~f:: 'd,i~:f1'1:;10,~l1é,:. ',' ",' 191 TR19 ~19 b1CY~iC te~a~~, , ~¡~t, ':::T~Q: ' 'C~Qitrlqyþl¡ó'Jøh).~'Øè,' ' 191 TR21 C21 tricyclic terpane ';1:~~::;,:':,,:>:~~~::: ",' '::e~YtìiÞY¢lld,:~èfP,án~' " ' 191 TR23 ,C23tricx~lIct~rpane ~;ø;j.t:}:::}:'1!~4\' ' " '; ',¢24::¡tn{¡ÝGUè':tøhi~'o:è'" " 191 DESAOL des-A-o/eanane ~~~:1;:i,' 'ioä:$.~LQ,d~$~A~jlip~nè " ," 191 TR25A C25 triCycli~terpane ~~) , , ~,!Qi!::'" ,; '.',t~~,$:' :d2$:'Þiçy~,id,·te¡:pan~,(þ)" 191 DESEHOP , des-E-ho~a~e " '" ' . #;~'f:,)' ':"'~$A "'C2~:~triCy¢li~:tØfp~O~($o)' 191 TR26B C26 tricyclic terpane (b) H;~;f:,:': "t~ØA' Ç;2ð;tòÞYØ!i¢..'t~r~åri~'(ä) '. 191 TR28B C28 trlc:yclic terpane (b) '~~1:;: .'.' '¥WJ,~Ä' 'C~ø:tncy~lc,t$'rPanèO{é:i) 191 TR29B C29 tr¡~clict~rpa~e (b) 1$H' .,TB30A G~Ø~cy¢li¿'te:rpai1E3',{a)., ' 191 TR30B C30 tricyclic ,~~rpane (b) '~~f, TS: T~t~(Hrtri$(1qrhop'áné 191 TM Tm 17a{H)-trisnorhopane 191 'H2S, C28 .17a.1 &.121 ß(H)-blsnorhopane 191 NOR25H C29 Nor-25-hopane Üh ,H2S C29 Tm 17a.{H)21ß{H)-norhopane 191 C29TS C29 Ts 16a.{H)-nomeohopane 1'9,1 DH30 C30 17'd(H)-<jiahópane ' 191 M29 C29 normoretane '191 OL oleanane 191 H30 C30 17a{H)-hopane 191 'M30 C30 r11oi'etane 42.282 9.415 ,,1 O:;q~5,' 10.409 ~I25,9 19.017 " 21;~ 25.169 , " :lð:i$ø 32.780 " ,', ,3$i2Q4' . 37.714 40.242 4Q,.3â2' 43.485 44.1'13 44.479 53;ÔO~ 53.632 , 55;~O 56.282 60.484 61.286 57/712' 59.334 63.919 65.105 65.384 66.133 67.11 0 67 ;964 68.557 70.126 16530 4829 4381.' 4346 3,~,1, 3017 , '48~Ö, 4764 16,$ß' 7031 '4'199.' 370 1675 .,t5$1',' 1846 1154- 1213 796, 887 669 1014 1Q53 637 ~3 2455 1090 6373 2993 4963 1017 2728 9294 1290 2594 100.0 100.0 I"" 1347 ,943' 1005 , ,11"65,,', 501 , 7:~!-~ ,," , 500 214.." 1016 6&$:';: 62 256 Zß5, 270 , 1~2' 157 1~r ,: 109 f14' 151 1:51 ' 111 54Ø: 372 29.2 , :'2~~$:>'i 26.3 ',~~:j,~:::", 18.3 51.9 ~·';:"i,.,:,\:':::,~~~t:;:';,:2; 38.7 \'::;;~~,;i'i;; 19.3 28.8 19.3 , '. 1iÞ~~):'>;:' ' 42.5 39.2 ,,;,':::·':~~á;:'>::.>i:,:':!:';i~~;ji·~¡:!:ii 2.2 2.4 113 861 394 708 176 312 1337 184 10.1 , ,,:,:~;4:;,: 11.2 i¡Q':::,' 7.3 'Æ~', 5.4 , "",4~Q",' 6.1 :, ',ij¡~!: 3.9 '9.9 .:':;i':':/:#)'~~:/ 10.4 :':si1':': ,\: 6.1 "" '., ':'4~é'::::-i 4.2 5.8 4.3 14.9 14.3 6.6 "'38.6 18.1 . '30.0' 6.2 16.~, 56.2 7.8 4.4 ,",~a;2,· ' 15.2 ,2t3 6.8 ','12:0:. ' 51.5 7:1' ,,1,'-] ¡ 1 r i , .,..,... ¡ ~ i . r'" 1.1 r: r 'I ~. r·..... , L~ r~ :r-' r t,"'J [I \"~ ~ .J lJ "1 ] I ì , j Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 Client ID: Project #: Lab ID: File Name: MMSAK2003·1 03·529·A MM000001 M2031232.D Peak Compound Ret. ppm ppm 1011 ,Label Name '. Area Hci. ht (Area) (Hght) 191 H31 S ' C31, ~~,17 et~H) hopane "'$;1:' :':Jlt,~:;~,'R" ", :;:Q31~Fi::'17a(H)iHþpánø: , ,,' 191 GAM , ,9, ~111,' m'" 'a, ' cera,~e, ' ,1Ø:1.:::,: ';~~:~S;: . ",',',q3~'~g$\i7~(H}høþa~e', ' 191 H32R , ~3~2,2R:,~!.a(l-i) ~opane 1~:1'::)H~ß.~",' ,,', ';P~~:::~$>1/r#(ß),:Hø~n~", 191 H33R C33 22R 17a(H) hopane :~:øi{ :::~:~$<" "":&$4:~~$":i1i7#{H)hqp~:n~,r , ' 191 H34R "C:,3;4 2~:~1,!a(H~ hopa~e :~;~1\':,;::'::it4~i$:S;::', :','¢ªª;~ªJ1:14{H):6()p~óø" 191 H35R ~~5 22R17a(~)h~pa~e ~Þ:~:< :",¡H~~£~~'$:' " ,',';::'C~;1~;;~<i~~~~hp.þ~n¢ , ' ~05 H31S~2~5" C3122517'et(H) hopane ~º~;:,~~.~fÚ2QS:," ,: :Ø3,1i,2.~~:,:17~(H)lhøp~nø:' 205 H31_3ME, C313~~~e~ylhopane g:~,~' .',"':$.~,,~~,::,',' "'Ø2:1.':$t~rø:l1e: : 217 522 C22 sterane ?~:#,! , :':,Q,J~~$;,,' 'Ç?,i;ißa::?Q$",ø4i~(~t!in~' 217 DIA27R C~.r~et~O~ diaste~ane, ~~:t~:;'r,::!~;J~~~; ,,:, ':'~~a';ø~)~ºS;'4!~$,té~rlØ::å ' 217 DIA285B ,C2~ ,~et 2~S.diast~rane b ~~:'t::::! :,:" ':øI&~~'~::',:':;:Ø?ß;;p~:~q~~d~~~~rié,~'":,, 217 DIA28RB ,,928,ßa2~R~iaster~ne b , '~~';7'.:<,,' '(i~žs'" ' ,d,i.~,q.~~qS:"ster~n,e", 217 BB_D295 ,~2~PP~0~+ C29dia20S ~;1;r~'::~~,~~~,$:, ,,' ',P'?,:tøß~ZÖ$:'~tøt~nø: 217 C27R C27 eta 20R sterane ~+7:;'" .:ipiÅ29R ' '" :¢2ø::ßti¡~9:R::~i~~tør~né. 217 C285 C28 aa 20S sterane ~,~,;t :¢~iߪR: :ê2&}Ø~'):2Øß,¡~i~tªri~( tSpacx;:) 217 C28BBS C2~Pß ~~~.;st~rane ~H7"'·":' , 'ø~ß.W',C2~;:a~~QR';$~~~ånø 217 C295 C29 eta 205 sterane ~~'i/ ,.:'Q~~Båf{ "':q~:ß'ß'2ÓFt~~~~,,~(+5pna)' 217 C29BBS C29PP 20S ~terane g+7, "',¿~~ä... 'C~9;åa:'2ÖFtste,rarie 218 C27ABB'R C27 PP 20~sterane ~i8 ~?lAJ3BS C~7ßß:20Sster~,O~ 218 C28ABBR C28 Pß 20R sterane g18,G2åABB5' C28ßØ20$'st~rane 218 C29ABBR C29 Pß 20R sterane 218' C29ABB5C29Pß20S.sterane 218 C30ABBR C30 PP 20R sterane ~18 C30AsB5 C30 Plf20S sterahe 72.619 3419 500 20.7 19.3 7~;107 2ß~1'" .. :M3:",: :1:~~~'::': :,':jY;,\1"~\~j¡::~,i:~¡ 73.561 861 107 5.2 4.1 75¡~5 2133' 3~~r ' ";1::ft)~', :,;: '<\\::;,H~î~ij:,%; 76.524 1.788 265 10.8 10.2 i~~5¥it 1449 ~Q,3':' "::~i~i' 80.482 1104 160 6.7 6.2 '8)~'3$4':' 9Q9; 1:~Ø:· .. : :~!,$; 84.527 641 92 3.9 3.5 . 87 ;'108 ,74'Q' t~:$" .. ';4<$"i::'i:', i;;:,.ii,:j>:ì;;j¡~:~:¡;{ 88.433 545 73 3.3 2.8 6a~923' 422',' "ßf,i' " ·"',i~~~:::'": ':,(:XP;;¡:!\~~~¡i;:¡¡) 72.619 1204 175 7.3 6.7 " 73,~1b7 ~2' f1~", 73.874 114 27 0.7 1.0 ~9¡1()Ø .4222: 5Ø1',',' ~$¡~'..:: ,", ";::6::1;~i~,:(::¡h 33.826 1742 243 10.5 9.4 48~4$4, 264ß' .':3$ß;· ' :' : A~'~!() ..:::.,! ',',':./~>;,,\:i\t:~~~:1;:':;;[¡ 50.023 1640 272 9.9 10.5 52,~~$.5 11$1 ;1$1.:' 1.0 ''''':ß~;::,': 52.517 1608 161 9.7 6.2 ,'~~~ØØ4 >&53:: ,$2"" $~:2 ", ,:',:i:\~;':'~:: ',' 54.155 564 82 3.4 3.2 55::t~1 '1~Q4· ,1$'t 7.1àr: 55.690 3098 236 18.7 9.1 56.056 198.5' '~1 t~':O 56.945 1512 173 9.1 6.7 51,$73 2658-, 210 ,,16;1: 59.281 869 101 5.3 3.9 59:961." 9,85 1Q7.' ,'~i'():'" 60.380 1605 180 9.7 6.9 et443 1006 93 ,e.f: 62.751 1251 129 7.6 5.0 63~57-() 232Ø ~49 1~tt 63.867 1914 223 11..6 8.6 65.314 1948 180 1ta ::Ø:i$:' 55.655 2363 285 14.3 11.0 56~O56 2023 283 12~2 '1P;~',:" 59.979 1344 152 8.1 5.9 60.386 1875 205 11.3 7¡~,': ,". 63.570 2697 343 16.3 13.2 63.884 2544 317 15.4 Jî~i, 66.587 194 28 1.2 1.1 66.796 169 24 1.0 0.9, :,' .., , I \ ! 4.' rJ :t, ¡ II n' r"- \ I ¡ .. . r'~ " .: L' r ¡ I "'. ~ ~'., ¡ ~~:; ....., ¡ ¡ !"'.. ,(- I . ,J r,',] t f' i j 1... f-- L. n :1 U .. I Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 Client ID: Project #: Lab ID: File Name: MMSAK2003-1 03-529·A MM000001 M2031232.D Peak Compound ReI. ppm ppm Ion . ~ Name Time Area I .. 4! I (Area) (Hght) 259 0278 ~$~> :',):Ø~7~~,' 259 D28SA ,~ø9" ,:'ø,~ø,~ø, 259 028RA '~5~;": '"i~'~~Rf3:>:, 259 0298 ~$~". ,)'b:~Ø~;~":',,, 259 C30TP1 i~Ö.:i-:' " ,; :.::çØ.:ØWeø::: t .' C27 ßa 208 diasterane , ;,"¢?i:ø~:'ZØ,~':~i~~tij~hè C28 ßa 208 diasterane a ":,G'28":ßct!;~O$:::d~~:tet~øeÞ , C28 ßa 20R diasterane a , ,;~~~ØWø~:;~q~:;~~$t~ran~ b' C29 ßa 208 diasterane .,,:,pgø.;;ß~;,;~Q~~Øi~¢~~~ªMe ", C30 tetracyclic polyprenoid "::"~:åø;t~~ª'¢yÇ!IPJ>QtYpr~~qld ' . ',' ,,: " ' 48.454 1577 ,227 9.5 8.8 "'!, &O;O?~ 989 1:57" 52.255 711 104 4.3 4.0 , 52~$~1" ~~4' ',$~, 53.964 593 72 3.6 2.8 54L-155 : 445, ,:5~,' 55.794 1506 128 9.1 4.9 , : 57:¡:573 ,1tSZ ::,$:\'.,::...., 67.075 244 34 1.5 1.3 ':øt~2a2 20$:,::" :aø(: ~,,'''~ " , ; ¡ ~ r ~ _l ! I. " {1 f ¡",J r 1. r'" ~ ! r'" ~ , , r-' ~j ( Þ-,.'. ...... ~_.~ }'.., ¡ , I ~..... [] f'- j ~'d" [] n I'] l' : ! : I : ,J Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 Client ID: Project #: Lab ID: File Name: MMSAK2003-1 03-S29-A MM000001 M2031232.D Miscellaneous Ratios By Areas By Heights , , Steroids , ';:o/~d2,7,:"~Ø~'$:'~11,~) %~~,8cxßß~(218) ',%P29~~ߧ~'(2J~)':, ' , , ,,~3?cxßß~, ~t~,ranelnd,e~(218) , ,'@~ø::;~*~;~~,~~f~h~J~ºex,(2;1 å} .' , , ,C~7/C29 ~,cx:~ß~) (~~,8) , ,ç:!atq~'i(~øø'$r(zta),·, " C-¿gIC27 (cxßßS) (218) at4: 29.1 ",',~9'5, 2.6 :2~7 , 0.80 ":0;74:, ' 1.26 , , %C27 cxcxcxR (217) %Ç2Ø,~~I~::::(:~~i~): %C29 cxcxcxR (217) :$lß:'(G~:~~~)"{~ti)",' , S/~S+~,>',(~29,~CXCX) (21!) , ß.ß/(q;%*ß~1{çi9)(~17) , , cxßßS/cxcxcxR (C2Q) (217) : '(q21fC22V(¢~7..tG2Ø,tc29}(~17) Diaster/cxcxcx Ster (C27)(217) 33.9 ',:,~2~5 43.6 , "'O~64' 0.39 ,0;57 0.98 0;19, 1.52 ,T~r,~enold~ ",', ,',' ¡,~"(>1~l¢2~,:T!icYc:!Îc;,'t~.c:p~Ms C23/C24 Tricydic terpanes ,:ç2e/C25:TdcYCllc:terþ~nå's , ,OA3, 1.67 0;;7,3 ,'q24Tett$'¢ycl clC46, TriCydics' . ' '" , C24 T etracyclidHopane 0;78 0.20 TslTm trisnorhopanès ',T~Œ$~Tm)Jéi$hoí:hopanes , C29Ts/C29 Hopane 1.41 0;59 0.47 ~i,s~Orhopa~e/Hopane , ,,"N9rt)QpaÍie/~QP~nt) , Diahopane/Hopane , 'QIE,anØne/Hþpane Gamm,acerane/Hopane Moretanel(Moretane+Hopane) H32 S/(S+R) Homohopanes H3snH34 Hornohopanes 0.69' , 0.53 0,29 0.09 '0.12 0.54 0.83 [SteÎ13nes )l[Hopanes] [Tricyclic terpanes]/[Hopanes] [TricyClic terpanes ]/[Steranes] ,0.69 0.80 1.17 ., '~5;:~,'C;" 25.5 '~~,;4.;,~,: ' 2.9 ·ä~2(: ' 0.89 "',":9'¡6~:,'.': 1.12 38.8 '?9~ø.'" ' ' , 40.4 ;wt~(' 0.42 , ,:'();6:Q',:, 1.24 'Q';~' 2.00 :QA~,:,,', 1.55 ,0:55::' " O:.9~', 0.20 '1.48 ,.O;():ø'·' 0.46 ~;ß4: 0.53 , 0;23 0.08 0:12; 0.55 0.81 0.53 0.81 1.53 ,.......,1,' J .; ~ I'f"T f \ i , r EXTRACT SUMMARY SHEET f"'... .. ~ I i . '1 L r~ L. r'~ ¡ ,",.-( [, ... .., """, 1/ : I L... fT ,L It", 'j 1,," [] IJ L ç 1 tJ 1 .. 1 ' 1 ' l, .. r 1 ~ ! 1 ) ...j North Aleutian Cost 1 Other ID: MMSAK2003-1 API Gravity %S ppmV ppmNI N.A. N.A. N.A. N.A. BULK PROPERTIES %C15 + Compo I! Sat 6.82 Arom 1.16 [ NSO 3.32 t~~f);;:~ Asph 88.69 I 100 50 oSat/Arom 5.85 GAS CHROMATOGRAPHY Pr/Ph OEP Pr/nC17 Ph/nC18 2.65 1.10 0.45 0.19 Õ13C -28.50 -27.30 BaselineDGSI Project: 03/529 S'ample No. MM000001 Isoprenoid Distribution ~ I I I I I «) oq- 2 2 It) <0 CD Q.. 2 2 º .r::. Q. I' I I, '. 11.111 j.1 lJ...I-' . . . I~'W"JJI" _ ..~ .I La.. . SATURATE BIOMARKERS m/z = 191 'Wi4~Jv.~~~.~~~ m/z = 217 ~ Copyright ©DGSI, 1997 Terpane Ratios C24 TetracycliclC26 Tricyclics C19 + C20 Tricyclics/C2a Tricyclic Tsffm C28 Hopane/Cao Hopane C29 Norhopane/Cao Hopane Cao Oleanane/Cao Hopane Gammacerane/Cao Hopane Tricyclics (%) CaslC34 Extended Hopanes C25 Tricyclics/C26 Tricyclics Sterane Ratios Diasteranes (%) 20S C29 Steranes (%) aßß C29 Steranes (%) Hopanes/Steranes C21 Sterane (%) C22 Sterane (%) C27 Sterane (%) C28 Sterane (%) C29 Sterane (%) Cao Sterane (%) 0.00 1.11 1.41 0.00 0.69 0.29 0.09 41.05 0.83 1.36 34.36 39.11 57.00 1.31 11.44 4.72 28.83 23.45 31.56 0.00 J,..'J ¡¡ ',i' 1 r] GAS CHROMATOGRAPHY - MASS SPECTROMETRY r"'-~ Preliminary Interpretive Guidelines of Saturate Biomarker Ratios I ì.. . r-' ~ 1 ~,. North Aleutian Cost 1 Other 10: MMSAK2003-1 r' 1 i. BasellneDGSI Project: 03/529 Sample No. MM000001 r' ORGANIC FACIES AND DEPOSITIONAl. ENVIRONMENT Í' l ~ Ratio Value r" ..". 11...,. C19 + C20 Tricyclics I C2a Tricyclic C24 T etracyclic I C26 Trlcyclics C25 Tricyclics I C26 Tricyclics C28 Bisnorhopane I C30 Hopane C29 Norhopane I CaG Hopane CaG Diahopane I CaG Hopane CaG Oleanane I CaG Hopane Gammacerane I CaG Hopane % C31 - C35 Extended Hopanes CaslC34 Extended Hopanes HopanelStêrane % C27 Steranes % C29 Steranes Diasteranes Isosteranes (abb) Short-chain steranes Pristane/phytane 1.11 0.00 1.36 0.00 0.69 0.53 0.29 0.09 31.8 0.83 1.31 28.8 31.6 34.4 28.1 16.2 2.6 r~'~ 'j . r', L, [J r- ;¡ I L ~,·"I L THERMAL MATURITY [] , Ts I Tm % C30 Moretane 22S I (22S+22R) C31 Hopane (%) % 20S/(20S + 20R) % abb/(abb + aaa) Odd Even Preference Pristane/nC 17 Phytane/nC18 1.41 12.19 56.5 39.1 57.0 1.10 0.5 0.2 1. ] L ] Interpretation Not diagnostic Not diagnostic Not diagnostic Not diagnostic Not diagnostic Siliciclastic and/or terrigenous Terrigenous angiosperm input Not lacustrine or hypersaline Marine maturity-influenced Not diagnostic Marine Mixed source Not higher plant dominated Mixed Source Not diagnostic Carbonate or hypersaline Marine terrigenous influence Mature Facies-influenced Greater than 0.5% Ro equivalent Between 0.5 and 0.6% Ro equivalent Between 0.6% and 1.0% Ro equivalent Mature Paraffinic Paraffinic Copyright©, DGSI, 1997 ~.-...J '---i ..,......,----~ ~ ____ i........-.-oí -- .......-.-, i....---i ~, 1 ~ --...ì ~ --..í ~ --J --, ~"'""I - ----J ~~O-~~~~ --""..i . ---...4 ~ ;¡ ---.J m/z = 191 North Aleutian Cost 1 MMSAK2003-1 03/529 - MM000001 1800 - 1600 ~ w 1400 ~ E 1200 ... B R 1000 - A F T c ^ L a VI 'S V b e ·f 800 ~ 600 -\ L~ 400 - D G 200 ~ I K N U Y h j j I,m ~~I*~~~ ^ i ^ ^ Q .. . c. k.)J ~-N\. ~.J~'M~~\wJ\, '·-\~"\~:'~'I,A~vJN..,IJ<~~ o I I 1 [ [ I I. I 1 I ( 1 I 1 1 I I 1 I I I f I I f I I I I 1 1 1 I 1 I I 1 1 \. I I 1 I I .. 1 . I I I I . 1 1 1 u. I I . 1 1 1 , 1 1 . 1 1 .1 . 20 30 40 50 60 70 80 90 r} TRITERPANE REPORT (m/z 191) -1 r North Aleutian Cost 1 1 BaselineDGSI Project: 03/529 r Sample No. MMOOOOO1 Other ID: MMSAK2003..1 No. ID Triterpane Name Ret Time Area' Area% PPM r~, l.: 1 A C19 Tricyclic Terpane 19.017 3017 3.43 18 2 B ~o Tricyclic Terpane 21.858 4820, 5.48 29 r 3 C ~1 Tricyclic Terpane, 25.169 4764 5.41 29 4 0 Cz.2 Tricyclic Terpane 28.550 1656 1.88 ' 10 5 E Cz3 Tricyclic Terpane 32.780 7031 7.99 43 r 6 F ~4 Tricyclic Terpane 35.204 4199 4.77 25 7 G Cz5 Tricyclic Terpane (22R) 40.242 1675 1.90 10 8 G Cz5 Tricyclic Terpane (225) 40.382 1551 1.76 9 9 H C24 Tetracyclic Terpane 0 0.00 <1 r~' 10 I C26 Tricyclic Terpane (22R) 44.113 1154 1.31 7 11 I ~6 Tricyclic Terpane (225) 44.479 1213 1.38 7 .,.; 12 ~8 Tricyclic Terpane (22R) J 53.005 796 0.90 5 [J 13 J C28 Tricyclic T erpane (225) 53.632 887 1.01 5 14 K ~9 Tricyclic Terpane (22R) 55.550 669 0.76 ,4 15 K C2Q Tricyclic Terpane (225) 56.282 1014 1.15 ' 6 16 L C27 18aH·Trisnorhopane (Ts) 57.712 3463 3.93 21 r', 17 M ~717aH·Trisnorhopane (Tm) 59.334 2455 2.79 15 , , L.. 18 N ~ Tricyclic Terpane (22R) 60.484 1053 1.20 6 19 N C30 Tricyclic Terpane (225) 61.286 637 0.72 4 [] 20 0 ~8 17aH,18aH,21 bH·28,3()"Bisnorhopane 0 0.00 <1 21 P C31 Tricyclic Terpane (22R) 0 0.00 <1 22 Q C2917aH,21bH 25-Norhopane 63.919 1090 1.24 7 23 P C31 Tricyclic Terpane (22S) 65.105 0 0.00 <1 r'~ 24 R ~ 17aH,21 bH·Norhopane 65.105 6373 7.24 39 L 25 5 C29 18aH-Norneohdpane (29Ts) 65.384 2993 3.40 18 26 T C30 17aH Dlahopane 66.133 4963 5.64 ' 30 [~ 27 U, ~ 17bH,21aH·Normoretane 67.110 1017 1.16 6 28 V C30 18aH+18bH-Oleanane 67.964 2728 3.10 17 "J 29 W C30 17aH,21bH·Hopane 68.557 9294 10.56 56 30 X C30 3()"Nor -29-homo-- 17 aH·hopane 0 0.00 <1 r '~ 31 Y C30 17bH,21aH·Moretane 70.126 1290 1.47 8 " 32 Z ~ Tricyclic Terpane (22R) 0 0.00 <1 t,. 33 Z ~ Tricyclic Terpane (22S) 0 0.00 <1 r 34 a ~117aH,21bH·Homohopane (225) 72.619 3419 3.88 21 L, 35 b C31 17aH,21bH·Homohopane (22R) 73.107 2631 2.99 16 36 c ~ Gammacerane 73.561 861 0.98 5 37 d C34 Tricyclic Terpane (22R) 0 0.00 <1 [J 38 d C34 Tricyclic Terpane (225) 0 0.00 <1 39 e C32 17aH,21bH·Bishomohopane (225) 75.845 2133 2.42 13 40 f C32 17aH,21 bH-Bishomohopane (22R) 76.524 1788 2.03 11 ¡ ] 41 9 C35 Tricyclic Terpane (22R) 0 0.00 <1 'I 42 C35 Tricyclic Terpane (225) 0 0.00 <1 9 t. 43 h C33 17aH,21 bH· Trishomohopane (225) 79.541 1449 1.65 9 :r } 44 C33 17aH,21bH·Trishomohopane (22R) 80.482 1104 1.25 7 ì ~ 45 j C34 17aH,21bH·Tetrahomohopane (22S) 83.394 909 1.03 5 , , L1 46 k C34 17aH,21bH·Tetrahomohopane (22R) 84.527 641 0.73 4 47 I C35 17aH,21bH·Pentahomohopane (22S) 87.108 740 0.84 4 ~ ¡ 48 m C35 17aH.21bH-Pentahomohopane (22R) 88.433 545 0.62 3 ! ~ , , Copyrigh~, DGSI, 1997 , \ .I.,..) ~ 1 \ fJ' .~ r·; ~ J r..... 1800 - m/z = 191 1600 - 1400 - 1200 - 1000 - 800 - '600 - North Aleutian Cost 1 MMSAK2003-1 03/529· MM000001 ['" i. 1 t, . f' ~ ~ " ~ .. ." ..-. 400 -~.-..J'~ l J.VIj~~... JßL,. 200 - ",'-" o 'I I I I I I I I I I I I I , I I , I 1" I , I I , , , I I , , , I I I I I k- ,. ..4 ro" '1 ' , 700 - mlz = 177 ! I,,~,, 600 - r¡ L 500 - !"'. l J 400 - 1'- L, 300 ~ ¡N/wy.~ ~\1f 200 - , I ........ 100 - r"~ r 0 ~, , o I' I , I , I I I , , , I I , I , , I , , , I , I I , I I , I I I I I I I , 350 ~' m/z = 205 r l 300 - 250 - 1..1 200 - 150 - ~I~~I~~~ ,~~ r 1 Ll 100 - r 1 :1 J' L 50 - o I I I I I I I I I I , I I I I , I I I I I I I I I I I I I , I I I , I I , I 55 60 65 70 75 80 85 90 ['"' " , f r~ ) i ¡) , STERANE REPORT (m/z 217) \.:. Ir""7 North Aleutian Cost 1 1 ~ :'1 .. " BaselineDGSI Project: 03/529 ~...... ~ ij ~ ..J Sample No. MMOOOOO1 r~ No. ID sterane Name Ret Time Area Area% PPM 1. , 1 A C21 diasterane 0 0.00 <1 2 B C21 abb sterane 29.11 4222 11.44 26 :c"-r : 3 C C22 diasterane 0 0.00 <1 l 4 D C22 abb sterane 33.83 1742 4.72 11 I, ,J 5 E C27 ba diasterane (205) 48.45 2646 7.17 16 r~' 6 F· C27 ba diasterane ,(20R) 50.02 1640 4.44 10 "<",,,< 7 G C27 ab diasterane (205) 0 0.00 <1 \ ,",'; C27 ab diasterane (20R) 8 H 0 0.00 <1 ¡r"", 9 I C28 ba diasterane (205) 52,26' 2769 7.50 17 ',I 10 J C28 ba diasterane (20R) 53.96 1417 3.84 9 ~,. i"" 11 K C28 ab diasterane (205) 0 0.00 <1 12 L C27 aaa sterane (205) 55.17 1304 3.53 8 f] 13 M C27 abb ster-(20R)+C29 ba dia-(205) 55.69 3098 8.40 19 L 14 N C27 'abb sterane (205) 56.06 \985 5.38 12 15 0 C28 ab diasterane (20R) 0 0.00 <1 ,......,... 16 P C27 aaa sterane (20R) 56.95 1512 4.10 9 ~ . 17 Q C29 ba diast(3rane (20R) 57.57 2658 7.20 16 ~../ 18 R C29 ab diasterane (205) 0 0.00 <1 19 S C28 aaa sterane (205) 59.28, 869 2.,36 5 r 20 T C29 ab, diasterane (20R) 0 0.00 <1 i 21 U C28 abb sterane (20R) , 59.96 985 2.67 6 22 V C28 abb sterane (205) 60.38 1605 4.35 10 1'''' 23 W C28 aaa sterane (20R) 61.44 1006 2.73 6 ~ . ) 24 X C29 aaa sterane (208) 62.75 1251 3.39 8 l_J 25 Y C29 abb sterane (20R) 63.57 2326 ' 6.30 14 r 26 ,2 C29 abb ste~ane (208) 63.87 1914 5.19 12 ¡. 27 a C29 aaa sterane (20R) 65.31 1948 5.28 12 i C30 aaa sterane (205) 0 0.00 <1 L... 28 b 29 c C30 abb sterane (20R) 0 0.00 ' <1 [] 30 d C30 abb sterane (205) 0 0.00 <1 31 e C3Q aaa sterane (20R) 0 0.00 <1 r" .. ' ~_J . . L, ri L o 2:IS I I I I 3D I 1 lias 1 I I 1 10 1 1 I I 1,5 1 I 1 1 ~ 1 I 1 I 5t5 1 1 I I. CIJ 1 1 I I ß6 I I I I 7fJ E 500 - D F I ~ Q . YZ . JL'~P V x, a ^ , Su w MAL'~~~___~. ~j~ B 1000 - 1500 - . 2000 - 2500 - 03/529 - MM000001 North Aleutian Cost 1 MMSAK2003-1 m/z = 217 3000 - ",x".'-..l'.'#~ --- f- ~j =....=J ' -. ... '1 ~-: í n' 1 .:.; :-J F"""--¡ ----..... r-=-! '----"" ~~ ~ I~ ---...,¡ =:J ~~ ~ ~ r¡ r¡ \ ' 600 - m/z = 217 North Aleutian Cost 1 MMSAK2003-1 03/529 - MM000001 r ¡ , ) , \." . 500 - r"' ¡ ~ , 400 - 300 - r" , , ~..,: ~::~~~ ~J¥' t\ ~1 ~ JV~~IJ\~Jh~VIMr~ r'" f ¡ o " " ,- , , ':'"...J 450 - m/z = 218 400 - 350 - 300 - 250 - 200 - [] r" t ~ c., ¡ I r. [I LJ ::::~ N~V  I~) ~ J j ~·I\A4~ 50 - o I I 350 - m/z = 259 300 - 250 - r - 4 - £. . 200 - j , ¡ ! l ,I 150 - V ~ 100~~~'~ fi,A ~ I L 50 - o I I 50 55 60 65 70 L '..,',..'.' '" " r' i,\ !'-~ ~ .~ ...... . .1".... ~ , . ., , .'-~ â:., J I~ ~ \., , r,") -, i "" [} r r l' t ~ - \ \'., [' rn'1 .. , 1.1 IJ tJ Ø-aASELINE CG~I '-'~_~_.1_ ....-:_ ....1_ _'__.. :_..-.lWl _.. :._:... Company: Country: Basin: Lease: Block: Field: Well Name: Latitude: Longitude: MINERALS MANAGEMENT SERVICES UNITED STATES NORTH ALEUTIAN COST 1 SA TU RATE GCMS Client ID: Project #: Lab ID: ~ample Type: Sampling Point: Formation: Geologic Age: Top Depth: ' Bottom Depth: MMSAK2003-2 03-529-A MM000002 CUTTINGS 15700 FT 16800 FT mlz 191: Trl- and Pentacyclics M2031201.0 , ,r.I~~ , _ %C2i aß 3S '(218) , ~OC28 aß.ßS(218), , "'C29'~~ì3$,(~,1'.ør, ' ,%C27 aaaR(217) o/JC~8:~«cXR',(2~i'7:'), " %C29 aaaR (217) §/(S~.R),(¢~ (1<i~)(~17) , ßßS/(ßßS+aaR) (C29) (217) (C;Z1+CZz)lCct;'fC2â+G29:):(2l7)" ' C27/C29 (aßßS) (218) P28fC2éIJÇ1~ß~)I(ZW) Oiaster/aa~ Ster (C27) (217) Ö~Oa'ß~$St~ranelnd~x.(~1~) ," C30 S+R Sterane Index 218) 'ill ~B 29.9 0 ',~~,14, '''0.. ',:": 46.7 0 ," ,"'(i.ø;#~,>:':: M' O;5.~i'(Ø:ß.~ï) 0.48 M 0.70 (0.9%) ,,:,':(i:Ø~:': ,,' ,'" :;};'::'('.~~t::,:;::::::!) 0.72 0 ,::0:;'76:'; '. 0 , : ' , .1.~,1, ..~/~ 1.00 (1.4%) , " "Z:$:: ',:..þ';,'>: .¡:'\¡.:i,i:;:;,;T:~i:;,f::jt,]r: 2,9 0 ~~w ~]~~ ßle~'ß~JiØlH¢p~he': .. ' Gammacerane/Hopàne Nbthopar1e1H9P~riè Bisnorhopane/Hopane p~hQpane/Hôþarié ~oretåne/Hopane , ' ~~";Qr·høp,an~lÞþp~ne ' Ts/(Ts+ Tm) trisnorhopanes þ29TslCZ9 HOPéJrle ' H32 S/(R+S) Homohopanes fi351H34"HbOJ9hopanøs C24 Tetracyclic'Hopane C24TøtracycliçlC26 Tricyclics C23/C24 Tricyclic terpanes C19/C23 Tricyclic terpanes C26/C25 Tricyclic terpanes (C2ß+Ç29TriCcliCS)(Js ',O;~7: 0.17 , :"':::Q';H~~:" 0.45 'Ô;26ii 0.57 q.6f 0.12 '()j36 1.73 0;75'" 0.77 . J;~~I, M 0.05 (0.7%) 'a" , .. ':":'. ':...', MID 1.00 (1.4%) :M;'.. ,'/ '.'i:\'':':'''i!,:;·,'}/~:,::'~: M 0.60 (0.6%) ;:'0: ; .." ,',': . :,':,,',,',,; D .r):: o 0" o A:: m/z 217: Steranes M2031201.0 StèfåneslHoPånes' ' Tricyclic terpanes/Hopanes Tricyclic terpaneStSteranes ;0 -':"""/'.>!,-:':'::: M 1.00(1.~o/.0~, . MID "q)~f<tAo/ø:l ~,v.~ ,\J ~ JI ~Jv,' lIJ<v Ñj¡~. m/z 218: ßß Steranes M2031201.0 10efinition and utility of the ratios can be found on our website www.BaselineDGSLcom I 2A=Source Age; O=Depositional environment; M= Maturity; B=Possible Biodegradation J Jrhermal equilibrium value of the biomarker ratio and in brackets the approximate VR value at which this value is reached ~~'JI\JvA\I~, W¡,~ ',!T",'..l j \ i ¡ j I fl 'I{ ~.-:: ~ ' , ...., i ;' " ~ i . [ ",...... ¡ ~ .......". r ~ ~- I.,.. ,[,"" .J [J r~ f ' :t.; r" Ii I :) . L" ~, ..,] 1 L D r' L' ~ ! .¡, 1 t ì 1 :\ "I ~ J ,¡ \ j ~ j ; J i ~ 1 , ~ Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 157,00 . 16800 FT Client ID: Project #: Lab ID: File Name: MMSAK2003-2 03-529·A MM000002 M2031201.D Peak Compound Ret. ppm ppm Ion label Name Time Area . .. . (Area) (Hght) 217 CHOL "'~ I!, ~h.o/a~e (internal stan~ard) , :~'~*'~ ,::'r:¢iijø)::'" ,,",:<~~Ø~~,; ""I 123 RIMU rimuane :;1~:~;:"::#l~::'>' i,::,: ,,',::::d).im;a,t~!i~>, 123 ENTBEY ent-beyerane ,i~ª :" :':')I~~,þtAA¿· ,;::>I$qp:I[q~tøh~'" ~~,~"" ~ ;7P~~~L<? ',' " ß-phrUC>CIad~ne ~}~~::::"::,,,':j~*~,~,F,{)::';,:, :'::øt~(¡~,t1~,j"::', ,,' ' 123 A.-PHYLLO a,-phyUocIadane 1:2.5' ,:a.9AR~T ,i:'i~::"jß@fø~;n~o; ,: ' ~ ~7, ,,~~91f'M ",' " 4~rn~~yldlal11antan? :,:~,¥:,:<:',',::rt,Ntq'j~';,:,' ::·;',,':;:,.1,ffii,~iji'~J~)~~~h'~oø 187 3MDIAM 3-methyldiamantane ~;~::<,:}i~I¡~:/'<:: ' ,:,,\:,:\::~j~m~~~O~;,:: " " ,1,91 ,!.~19 , ,..c; 1 ~triCYc:li~t~rpa~e , #:~'~:'::'/:'):1':~():". ,:' : ':':'<q~ø;i#'il~~,I9;:ijO>ØI1ß'" ' 191, !R21 G21 tricyclic terpane ~~~:::;j:::';m~;:::', ,', ,.,".,' ::"":\¢~¡;:~ ~$íø':~r~ªn~ ,~9.~, 'F' ,T~3" ",,' ,p2~~Icy'?i:~ terp'~ne , :1~~t·':::::',::<~m~;{:.. ,'::'; ';: :,..)Ø,?~!;'~ÄÝ,~)ç'::~"rø.;ihe: ,,' 191 DESAOL des-A-oleanane 1.91,:' ':'D~ŠALÙ:::' 'des~Å~lo~ne ' 191 TR25A C25 tricyclic terpane (a) 1'~'1\::, , >Tm~$' ,', ' "'¢~~;tn¢Y,e.uê'iø:(¡J~né';(b) 1,9.~~~S~HOPde~-E-hopane ,',',', , " ~ij~"", : ,'.:t~¡ä., ' , :" Ç2ß"tripyþtic¡t~rparle.(~),"" ,191" ,T~~B ,~26~o/cI~~ter~an~(b) 1'~,1:;\:, ','~:1!'~~A; ;" ,:G?ø!tti.êý~JÄ\~rP~I)~(al'" ,~~1, , ,T~~~B ,~2~ ~<1'cI.lcterpane, (b) '1,~~1:>,,:.:'·,:?1';ª,~~~::, :,', ',',' 'c;~~;~~~(Þ:tø't~ne"(~).",' ~:~1!~~~~:, ~29 tricyclic ~erpan~(b) :1,~,t~::,:,$~~9.\\" ' ',::Q~,~jtJ:içy9!ìC;~~rÞø'~~($)' ,~",~1" '.', .T~30B , . C,30tricycU~: te~:ane (b) '~~Ji' ,;,:t(ß':,' " ' >l;$.'iAa'ó:èHftJ1$n'Þmopanø ~91TM , Tm 17a(H)-trisno,rhopane 1~J: .,,:" ::f·t~ä:, "C2$'fTa,18(4fp(HH>ls"Ört10pane 191 N0R25H C29 Nor-25-hopane 4~J:-H2~ C2ØTIJl1 ta.(H)21 ß,(!7tþnôthoþane 191C29~S ,C29TS 18a.(H}-norneohopane 191',OH30 ,C,30,17a(Hrdiahopane 191 M29 G29 normoretane l~f ÒtOleanane 191 H30 C3017a,(H)-hopane 1,91: ' M30 ,C30niotetane 42.317 '20:t3$4 9.431 , ," tÓ.Ø~4: 10.407 ': QJ~7~ 19.034 2~)f3,14' 25.20;3 2~;:59Ø 32.797 3~;~38' , 37.749 ',3ß·oøa: : 40.295 4'c)A17 43.520 44J6,5 44.514 5~;Q39 53.650 5$:602 56.335 ,60.531 , 61.356 57/764 59.386 63.971 65.157 65.436 66.165 67.162 68;034 68.609 70.196 19106 2951 100.0 1ÒO.0 2475'&' , , ,,~~t' "',;:1:~~i;ß;:",:;·),,:.'::;;!1;~ª~i~)!~!~\¡ 5405 56,83,' 5001 ','442å': 6015 ,109$, 7122 '2407 8048 '~ß4,1' 1059 ,674/ 2186 2148' " 2874 1631, , 1702 1972", 2162 1854 2810 395~ 2020 5802, 7204 2962 17463 ' 4596 6489 3698 5242,· 23750 4081' 1497 1J~1 ,..' 1103 '1.~:t6': 975 , '~;~,$2: 696 '34~6, 1184 :i~l:, 148 1'~O< ' 343 , 3$fj 419 112 228 2t8::' 256 3~8 415 '4~t " 305 '8,Ø,7' 1055 28.3 50.7 ,'::.·,:2,~,~~:·;,"':;()};::;;;¡I\~j;D::;¡ 26.2 37.4 31.5 33,0 37.3 23.6 , , ""ì~~ß,<?;::,'.:;":;, 42.1 40.1 :;':~~A~i 5.5 '5.0 324 2470 584 1041. 577 581 3359 620 11.4 1.'1;2 15.0 , 8:5'" 8.9 "':"1þ;~:': 11.3 , 9i7¡:", 14.7 '::,20;7)' 10.6 "":åo')f';- 37.7 15.5 91A, 24.1 34~Q 19.4 27A 124.3 '21.4 11.6 14.2 ,'!<::~~i\<:~:; 7.7 8.7 14.1 :':":':?>~~~ª):~¡::i.;j , 10.3 35.8 11.0 ::',::,~)t;:':~':: 19.8 ,,':S.$:j3,\',. 19.6 '..·1.9,;t\'~ 113.8 :tf:<L, ,--, ,¡ '~ ! ¡ r.... , l ~ 'l , r~ ,~., . r ~ \, 1""? " î ,",,,. ~ r ¡ L Q 1 ~ ~, .' [] [)-'~ ....'~ [] o [] r' [I [J f'1 '. J J \ Ll T 1 i \ .i j Company: Well Nam,e: Depth: SamplinQ Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 15700 . 16800 FT Client ID: Project #: Lab ID: File Name: MMSAK2003-2 03·529·A MM000002 M2031201.D Peak Compound Ret. ppm ppm Ion label Name Time, Area I·: I (Area) (Hght) 191 H315 1'i~,1;¡;?:;::((~~:~~R':,: " 191 GAM :~\~1/':"~::::;;ffl~~$,:, ,,: 191 H32R 1:~ì/"')::)',~ª~:$:::·: ' 191 H33R ~:$:,~,::"'/"::~~$:::. 191 H34R ::~;iji:i: ",;}';:ß~~$,<~, 191 H35R ~~~\:::,:!'ffiª~lli~'~~ :::' ~05 , H31~,'ë~05 ?Ø~:;< >,:'::':~ª;1.i~ži9~:"'" ~~~,:< :,H~1~~ME ?)1,~'''':'i':::~~1:': ,: : 217 522 ~~iti, ' '"',,IiiÎ~7~'" " " 217 01A27R ~17:"~~':' '...Q,IÄ?QSA, , 217 01A285B ::--:1"::#\,:,:-,:,!.;<,\(\~b!~;', , ~,:,,'(¡, ",',w,~~~" ' 217 01A28RB ~~,7i:": ·i~~y.~:/:': 217 BB 0295 ~~;1i' :~~~~ßS:',"" '"," 217 C27R 2.1ii:: ',ci1~ØR' 217 C285 ~1.7' (~~,~'â~~ ' ' 217 C28BBS ~~:i:,: ,":::~~ª~>',' 217 C29S ?~::7' ':,¢:iä~ØR 217 C29BBS ~:{j., :,:C~'~R, 218 C27ABBR ?ts ,"cz7~á~s' 218 C28ABBR 21 å :'C;2å~B5 218 C29ABBR ~h,8 " 'CiQAåBS: 218 C30ABBR 218. " , C30ABBS C31 225 17a(H) hopane , " " :"d~~\~~R'~:'t~(8):høp~'~¢ 9~111~~cera~e ,',' . ,,':¢ø~:Ø!~::I~::r(i:(H)';hÓÞ~n~ C32 22R 17a(H) hopane , ":q~!~i::~~$;~1i~«(~):fi~~~~~,," .' f~~2~1:'17<x(~) h~pane e$4/?~$/1'?~(.ft)~pþ~~,e, ' ~~22R17<x(H), h~pane ":,Òá$¡ª$-:"1:?,ti('If,I,f~QÞ~né ' ,C35 ~2R17~(H)hopane ,,:,,:,.'.'¢,~o1.;:,¡?~~~~V1'~b<'pØrt~':: C31 225 1!a(H)hopane , /b~'1:t~Ri:t,:r(xt'~J;h<m~~é. " , C31" 3~-l11ethylhopane ,Q2'ti$~~.(än~', ' " C22 sterane , , ': :C2~)ffi:t;~Oß::d ~$~eÌ'$,ô.e, C27ßa, 2~R diasterane ,:, ·¢til:ß«;:~,Ø'$ið.,i~$tétà~ê"a C28,ß~,205di~sterëane b : '¢.~ø:~æx:~ØR;41~ste~tiø::a , ~2,8 ~a ~?~di~ster~ne b , :' ,:,b2iid;ti'~Q$:~~e,r~n~: ' ' C27 ßß 20R + C29 dia205 '¢~7,:jJPI~,Q~:'$~~t~ne , C27 aa 20R sterane . ". ,Ø29::~Ø4i2øR::diøst¢rane' , C28 aa 205 sterane q~á"ßP'\~QR,~,tør~ne(+p:ßdd) , C~8, ~ß 20~ ,sterane G~ð"#~::~QR$iøranø C29 aa 205 sterane " :C29.;ØØ~Q·~·:$tèr~ne(+5ßaa) C29 ßß 205 sterane ':C29~a2ÙR$.~rane C27 ßß 20R sterane C2tI3ß:' ?O$.$terane C28 ßß 20R sterane , ,c2áß.ß20Ss(erane C29 ßß 20R sterane C29ßß 205sterane C30 ßß 20R sterane , C3<)ßß ,205sterane 72.671 7~;'1':i7 ' 73.613 ,75:aS7' , 76.577 , ,?Ø\sâa, 80.552 , '8~';44$' 84.579 '8'7.'1'42 88.467 '6&19Ø3, 72.671 , 73;1.77 73.927 ,2~A24 33.861 , 4~:5t$' 50.058 ~z:.~9ó,'· ' 52.586 54:;033 ' 54.208 5$;2~9 55.777 §9;tøa ' 56.997 57';62$ , 59.299 6ê:t031 60.432 6t.495' 62.803 63;6?3 63.954 65;$6 55.107 56;108 60.048 600432 63.605 63.936 66.621 66.848 9334 '.":':" 827á:',,' 1236 , ,'~ª~ø:,:",,' 3989 "~3:' 2329 """'ZQQ~',, 1341 ',,1:~~"::'" 802 ,':1'~H$;::" , 3186 ,~5~$,' 365 '$052:: 1651 " "4Ø5Y," 3373 ',:, /.222a:::, ,,', ,,' 33~~ '1:6M,::" 1238 2~$':" 8460 4~92, ' 2951 14'75:' 2295 25G'5 4212 2317, 3306 S?$" 4258 4617' 5530 4443, 3329 4682' 6510 6156 ' 472 455 1400 ·1W'ª,., 166 iáØ~.:' 626 ,~$,ái: 346 ',·,':~Ø'1..:,,': · 195 7.0 1'9ß';o ,,;:.:,::::~~~;: 136 4.2 1.'øa,,..,,,,,:,"," 466 , ,,:$.$1":," 48 , ':SZS;",...,:" 217 ",,:'6ê~r::.,::',,·,,' 542 ":~3ii:'!,: 339 '242" 187 '3,$6,' 677 '$,1:7 407 513' .. 229, ~øt;',:·"" 464 ,1:tt:' 331 ~~';.\. '¡,' 517 "44,3: 665 698 410 , 594'· 775 ,819 64 63 48.9 47.4 '43,.~, ",':"'3.~>7:,::',': 6.5 5.6 20.9 21.2 12.2 11.7 6.6 :,; ',,:(:,:;;if~~;:;;:,~,·,' .\~ :~.~ 101 4.6 16.7 15.8 1.9 :,:.,:::~øj~;:?'... 8.6 : :2~i~~ 17.7 17.3 'a!ß~,:: 6.5 ':"':':';1?J4'::"': 44.3 "':~5j:1;- , 15.4 ,"?9.~;1 " 12.0 ';1'~;4':::':" : 22.0 ,1~;;1',> ' 17.3 ,":"'2'f:;t,', 22.3 .d~4';'~"" 28.9 ,?ã;::f 17.4 24;5: 34.1 . 32:2' 2.5 2A 1.6 ::':,':'".'...., :,::/;~g~~!,,'~:'~r 7.4 ',';: >,:~:,¡~~~:;iD')~ 18.4 11.5 :,,:,::,'::~;::i~2~'~:'r~\i 6.3 22.9 13.8 " '.' .' ':i:1~~4><:; 7.8 :·'~<;1Ø·j4::::;;"· 15.7 11.2 ,i," . (,,··i1:Øl§:,"., 17.5 , , ":\{j"$.,iþ:::,} 22.5 ",' ·'.~~~ß·!:·':: 13.9 ::':~ê).;f 26.3 ~2rß~: " 2.2 : 2;'1' "'",,-'] A 'II , J r' 1 ,,' !'""'I ) ;! \ ¡ ~ J a:o_, I L; r~ ? r,1 ti r-'" ! t., [] r-...., :1 . ' , I ¡...... f] ,\ L ¡,"J 1 D 1 J L 1.1 J 1 LJ ..1' I i Company: Well Name: Depth: Sampling Point: , MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 15700 - 16800 FT Client ID: Project #: Lab ID: File Name: MMSAK2003·2 03-529·A MM000002 M2031201.D Peak Compound Ret. ppm ppm Ion label Name . n A .i, I .. ~ I (Area) (Hght) 259 0278 ~~~t::':::·:p~~â:".'.. ,:' 259 028SA ?~$~;",'~y:ij~~~::,:,', 259 028RA ?'S9. "P2~Râ 259 0298 :~~~~Ii:';/'::';Ô~~~{':~: ': '. 259' C30TP1 ø~i,;i';~~QW~; ," 9.~? ~cx 208,~iélst~~~~ "'lJØ~7,:;ß~i2q~~¡~~~~~t~ne" ' :" ,~2,8, }a.20Sd ~sterane, a , i, : ::;\9g~:')P"!~O:$::ø.~jté~tlf{b: ' ' , 9~~, ,~,:~~~,~i~~t7rane a, ',',.!::$2~::!pìÎi;~Ø6::â~~~~~Á~:,b:,,: ~2,~ pa20,~ ,~I~st~ra~e ; ',',' ,,:,:,<º~':;'~'~~,P,~i,~¡ij$tø:rä~ø:' C30 tetracyclic pofyprenoid :'::;'Q3'Øj~~~ãçý~i'Ä:pQlYÞt~~Øid': ' " , . , . : . ",. ,\ 48.524 ,Sp¡ø~,' 52.307 ,":52~:~$ 54.016 '54i~Øà , , 55.829 ,:5t~6~$" ' 67.110 ",67:219, , ' 3209 2,~~~:::, " 1650 '2:t1~::, 1690 1;åÔÓ:' ",5530 , 4#§Ø'" 651 470" '" 454 '<~~7.:" 244 ,,2$~'::·i:,:,:: 205 , , ,,',,§&<',," 438 :$,24," 89 :lj1:,"," , ' 16.8 ,', '1~;,~::(:/. 8.6 ::,::/':1{1 ' '8.8 , 6.8 ' ' 28.9 ,:::~~iª;::'i:' 3.4 ,.:2:5.. ' 15.4 " :~)':(:'1~~i~i(~:!:~~~ 8.3 ",:' t:' iij,¡Ô:'~ ;;':':': 6.9 "~;~'Î"::: 14.8 3.0 . I';' 2íl:, . f'" 1) " : ~ , , ,....., i} ~ ~. ~ t: , r""' t ·1, .~ . . r i Î ):' , \,."" r" L~ L, r"" ~ L... [] fJ l [J r-¡ L, [] f'] J it" T I 'f L r 1 '¡ \ LJ ,:r- , ~ ~ ~ J :, ,/ Company: Well Name: Depth: Sampling Point: MINERALS MANAGEMENT SERVICES NORTH ALEUTIAN COST 1 15700 .. 16800 FT Client 10: Project #: Lab 10: File Name: MMSAK2003-2 , 03-529·A MM000002 M2031201.D Miscellaneous Ratios By Areas By Heights i',,",,:',", 'I":,:" Steroids "":;:"'%~~~\~~:~~';i(~1;,&)':' %C28 aßßS (218) ,. ;;r~g~~;;,~ßØ$:::(~ißl C30 aßßS Sterane Index (218) ': ':..',:ø~~:~$!*~:;$t~¡:~h~:IÒdØk;t*t8), ' C.2719~(~~~S) (~18) ,"'~¢~:¡(g:øß$jt(~fßJ" ' ~2dC27 (a~ßS) (218) ," I .~,::." ?,,',...:'.\.... "i ',: .:'':: "'~:, 'I ',' %C27 aaaR (217) ':':-)~Q.~á'#~;~Ff!'(~;fli) , ",,!~C~~~~a~ (2~7) " ,.;;i),; :,';":~t~:;,~~~í~44f.(~:~r:),:'· S/(S+R) (C2Q aaa) (217) "...',':::~::'PÁi(&#~Ør3),;,(,q~),(~:ftt,: ' aßßSlaaaR (C2Q) (217) ,,:,"\(,q~~:~~)I(¢~~~8+Ç~)(2'~ 7) Diasterla~~ Ster (C27) (217) Terpenolds ',' :"'¢;1~?6~3::~o6y~'f6't~ij;~nè$' "~,2~/924,,, :ri~d c,,~erpa~es " ',';¢?61q2q:~T.r!çýQliè:~e:rPaÌ1å$' . ',:,çø~ Têtï;~~C)IÇ/C;~6T~¢Y¢lics' ,C~4 Tetracydi~Hopane , !sl!~tri~no~op~ne5 ":r:st('T~~Ffrn),:trI~l1ørhoþ,aries' , C29TslC29 Hopane , BisnorhopanelHopane ::'NØrhÞPØ~fj¡HØp,~Âø D a~~pane/HoPåne .Øle~f.I~:~~IHÞ~n~ ' Ga~m~~ranelHo~ane . N1Øretanél(Moretane+Hopane) H32 S/(S+R) Homohopanes H351H34,:H~niòhopanes , [Ster~M~JI[Hopanes] [Tricyclic terpanes}/[Hopanes] (Tricyclic, terpanes }/[Steranes] ~9.1' 30~6 :,' ,.:4é);3, , 2.9 , '",2;S 0.72 'i,:"ö;iØ 1.39 29.9 "'23A' 46.7 "Q;72"., ' 0,42 "0,.55 0.92 ',Q;09: 1.51 :Ò.75 1.73 , .0;77' , 0;86 0.12 0.81 ;0.45' 0.26 -0)4 0.27 0.22 0.05 0;15 0.57 0.61 0.69 0.56 0.81 . / ,,'3"il.1:::'.i 28.5, 3~;4::,' 2.9 , ',::,"3,,¡,1,;", , ":":~;;~:/' 1.23 "':"'.:" . ",,',¡ ~';. 39.6 ,17~~:':< ,;;j~:: <:';-. " 0.43 ;:'()¡~:,' ;', 1.17 '0:1,0" ,': 1.61 , 'oj&~": 1.64 0;$7'" .. ,;1;Ø~::', 0.12 0.85 :0.46: 0.24 0.74' 0.31 '0.17, 0.05 0.16 0.56 0;10,' ,0;52 0.56 1.00' rJ "...., :'i { \ i. r"'1' ;. 1.", ~ ,.--0 t , L I' ~'" , r-' ~ .. '-.., [], 1..... 1'1 i L, (J [] :[',} L [I [J [] !] lJ r" 1 l.: LJ EXTRACT SUMMARY SHEET North Aleutian Cost 1 Other ID: MMSAK2003",2 15700· 16800 Ft. API Gravity %8 ppmV ppmNi BULK PROPERTIES N.A. N.A. N.A. N.A. %C1,5 + Compo t~fjii._i!l!~·~\ii) Sat 56.21 œ Arom 9.26 - NSO 18.11 _ Asph 16.42 oSatlArom 6.07 100 I 50 GAS CHROMATOGRAPHY Pr/Ph OEP Pr/nC 17 Ph/nC18 3.75 1.22 0.83 0.23 SATURATE BIOMARKERS m/z = 191 Õ13C -28.00 -26.90 , L II.JJ~ ~\\'·~~~dl.l,~ m/z = 217 ~~~ ! Copyright © DGSI, 1997 i ,,' BaselineDGSI Project: 03/529 Sample No. MM000002 Isoprenoid Distribution , (') .". 10 <0 Q; It g g g º º Terpane Ratios C24 TetracycliclCz6 Tricyclics C19 + Czo TricycUcs/C23 Tricyclic Tsffm CZ8 Hopane/C30 Hopane C29 Norhopane/C30 Hopane C30 Oleanane/C30 Hopane Gammacerane/C30 Hopane Tricyclics (%) C3s1C34 Extended Hopanes C25 Tricyclics/C26 Tricyclics Sterane Ratios Diasteranes (%) 20S ~9 Steranes (%) aßß C29 Steranes (%) HopaneslSteranes C21 Sterane (%) C22 Sterane (%) C27 Sterane (%) C28 Sterane (%) C29 Sterane (%) C30 Sterane (%) .s:: Q. 0.00 1.63 0.81 0.00 0.74 0.22 0.05 32.45 0.61 1.30 36.06 41.73 54.67 1.46 6.47 2.12 28.66 25.37 37.39 0.00 1"1 :,!, I i 1 f", i . GAS CHROMATOGRAPHY.. MASS SPECTROMETRY r Preliminary Interpretive Guidelines of Saturate BiQmarker Ratios r ~ ' , . North Aleutian Cost 1 Other 10: MMSAK2003-2 15700 - 16800 Ft. BasellneDGSI Project: 03/529 Sample No. MM000002 ,! l. ~ ORGANIC FACIES AND DEPOSITIONAL ENVIRONMENT í' ; l,. &!!Q ~ Interpretation r, t C19 + C20 Tricyclics / ~3 Tricyclic C24 Tetracyclic / C26 Tricyclics C25 Tricyclics / C26 Tricyclics C28 Bisnorhopane / C30 Hopane C29 Norhopane / C30 Hopane ' C30 Diahopane / C30 Hopane C30 Oleanane / C30 Hopane Gammacerane / C30 Hopane % C31 - C35 Extended Hopanes C3s1C34 Extended Hopanes Hopane/5terane % C27 Steranes % C29 8teranes Diasteranes Isosteranes (abb) Short-chain steranes Pristane/phytane 1.63 0.00 1.30 0.00 0.74 0.27 0.22 0.05 33.2 0.61 1.46 28.7 37.4 36.1 32.5 8.6 3.7 Not diagnostic Not diagnostic Not diagnostic' Not diagnostic Not diagnostic 8i1icidastic and/or terrigenous Terrigenous angiosperm input Not lacustrine or hypersaline Marine Not diagnostic Marine Mixed source Terrigenous Mixed Source Not diagnostic Not diagnostic Marine terrigenous influence [' ,[I 't·,,' ,',' , . , .j ,l,' "] ¡ t r L THERMAL MATURITY n [] Ts / Tm % C30 Moretane 22S / (22S+22R) C31 Hopane (%) % 208/(205 + 20R) % abb/(abb + aaa) Odd Even Preference Pristane/nC17 Phytane/nC18 0.81 14.66 53.0 41.7 54.7 1.22 0.8 0.2 Early mature to mature Facies-influenced Approx. 0.5% Ro equivalent Between 0.5 and 0.6% Ro equivalent Between 0.6% and 1.0% Ro equivalent Low maturity or plant wax influence Mature Paraffinic r] [,J Copyright@, DGSI, 1997 r-"-"~ r-._".........,~ ~.<;.~~ .............~ ~ c:.::J ~ r--j F~ ~ t 1 ~ ~ ~ ----., ~ :::::J ~ ~-- -----' ~ ~ ~ ~ i---......J ~ o..--...J -----.... ---.J ----..¡ ---- ~---- 4500 - North Aleutian Cost 1 MMSAK2003-2 15700 - 16800 Ft. 03/529 - MM000002 m/z = 191 4000 - w 3500 - 3000 - R 2500 - B 2000 - A a E \n T b 1500 - c L U N :3 UV Y 1000 -, ~It ~ F ~ ^ Q \ 0 G J h. ~~'of~~~~_,,~J~~:Ji ~ ~ ~',...J \. ~ ~ \¡ ~ 4.~J\VJ~1\ "I~~ e f 500 - o I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I , I I I I I I I I I I I I . I I I I I I 20 30 40 50 60 70 80 90 r TRITERPANE REPORT (m/z 191) L r North Aleutian Cost 1 I, ~ ; ~, J BaselineDGSI Project: 03/529 [ Sample No. MMOOOO02 Other ID: MMSAK2003·2 15700· 16800 Ft. No. ID Triterpane Name Ret Time Area Area% PPM ...-'.. , i 1 A C19 Tricyclic Terpane 19.034 6015 3.38 31 2 B ~D Tricyclic T erpane 21.874 7099 3.99 37 If....' 3 C ~1 Tricyclic Terpane 25.203 7122 4.00 37 ¡ ,> 4 D C22 Tricyclic Terpane 28.566 2407 1.35 13 5 E '~3 Tricyclic T erpane 32.797 8048 4.52 42 6 F C24 Tricyclic Terpane 35.238 4641 2.61 24 ; 7 G C25 Tricyclic Terpane (22R) 40.295 2186 1.23 11 1, L 8 G C25 Tricyclic Terpane (228) 40.417 2148 1.21 11 9 H C24 Tetracyclic Terpane 0 0.00 <1 [] 10 I C26 Tricyclic Terpane (22R) 44.165 1631 0.92 9 11 I ~26 Tricyclic Terpane (228) 44.514 1702 0.96 9 12 J C28 Tricyclic Terpane (22R) 53.039 1972 1..11 10 I....· 13 J C28 Tricyclic Terpane (228) , 53.650 2162 1.21 11 14 K C29 Tricyclic Terpane (22R) 55.602 1854 1.04 10 -,. 15 K C:29 Tricyclic Terpane (228) 56.335 2810 1.58 15 16 L C27 18aH- Trisnorhopane (Ts) 57.764 5802 3.26 30 [) 17 M C27 17aH- Trisnorhopane (Tm) 59.386 7204 4.05 38 18 N C3D Tricyclic Terpane (22R) 60.537 3955 2.22 21 19 N C3D Tricyclic Terpane (228) 61.356 2020 1.13 11 [l 20 0 C28 17aH,18aH,21 bH-28,30-Bisnorhopane 0 0.00 <1 21 P 'C31 Tricyclic Terpane (22R) 0 0.00 <1 22 Q C29 17aH,21bH 25-Norhopane 63.971 2962 1.66 16 23 P C31 Tricyclic Terpane (228) 65.157 0 0.00 <1 r"'- 24 R C29 17aH,21 bH-Norhopane 65.157 17463 9.81 91 '0:.." 25 5 C2918aH-Norneohopane (29Ts) 65.436 4596 2.58 24 26 T C3Q 17aH Diahopane 66.185 6489 3.65 34 [I 27 u ~9 17bH,21 aH-Normoretane 67.162 3698 2.08 19 28 V C3D 18aH+18bH-Oleanane 68.034 5242 2.94 27 , 29 W C3D 17aH,21 bH-Hopane 68.609 23750 13.34 124 30 X C3D 30-Nor-29-homo-17aH-hopane 0 0.00 <1 0 31 y CaD 17bH,21 aH-Moretane 70.196 4081 2.29 21 32 Z Ca3 Tricyclic Terpane (22R) 0 0.00 <1 33 Z Ca3 Tricyclic Terpane (228) 0 0.00 <1 [] 34 a C31 17aH,21 bH-Homohopane (225) 72.671 9334 5.24 49 35 b C31 17aH,21 bH-Homohopane (22R) 73.177 8273 4.65 43 36 c C3D Gammacerane 73.613 1236 0.69 6 [J 37 d C34 Tricyclic Terpane (22R) Ö 0.00 <1 38 d C34 Tricyclic Terpane (228) 0 0.00 <1 39 e C32 17aH,21bH-Bishomohopane (228) 75.897 5228 2.94 27 40 f C32 17aH,21 bH-Bishomohopane (22R) 76.577 3989 2.24 21 1J 41 9 C3S Tricyclic Terpane (22R) 0 0.00 <1 42 9 C3S Tricyclic Terpane (228) 0 0.00 <1 43 h Ca3 17aH,21bH-Trishomohopane (228) 79.593 3043 1.71 16 r 44 C33 17aH,21bH-Trishomohopane (22R) 80.552 2329 1.31 12 45 j C34 17aH,21bH-Tetrahomohopane (225) 83.446 2093 1.18 11 i .... 46 k C34 17aH,21bH-Tetrahomohopane (22R) 84.579 1341 0.75 7 47 I C3S 17aH,21 bH-Pentahomohopane (228) 87.142 1295 0.73 7 48 m C3S 17aH,21 bH-Pentahomohopane (22R) 88.467 802 0.45 4 Copyrighl©, OGSI, 1997 f': 'iÁ",j [ 4000 - mlz = 191 North Aleutian Cost 1 MMSAK2003-2 15700· 16800 Ft. 03/529 . MM000002 (-' 1 ¡ \, , 3500 - 3000 - 1"-' r I \,. 2500 - r' r ~ ~ l I..,~ 2000 - 1500 - ...,. 1 000 - ~ 500 -~'-. ~ l;""U~4vJu"" ......, I o I I I I I I , I I I I I I . , I . I I , , . , I . I , . , . . I I I I , , , ... . '...J r"" ! 1600 - m/z = 177 "--" 1400 - [) r' ,J L. [ D [] [j 1200 - 1000 - 800 - 600-~~~~\\ 400 - 200 - o I , , I I J I I I I I I " I I , I , I I , , I I , " , , , I , , . , I , I 700 - m/z = 205 600 - 500 - 400 - f' L~ 'IW~,~ 200 - , 'I L. 100 - o I , I I I , , I , , I , , I I , I I I 55 60 65 70 I I I I I I I , I , I I I , , , I I , 75 80 85 90 ¡ 1 ':, I LJ -1 \ í , J r~ : A \ ~. .,1 r STERANE REPORT (m/z 217) I . r~ North Aleutian Cost 1 I: _.,j BaselineDGSI Project: 03/529 ~' "" f 1 Sample No. MMOOOOO2 .. , ...... No. ID Sterane Name Ret Time Area Area% PPM f, I L 1 A C21 diasterane 0 0.00 <1 2 8 C21 abb sterane 29.12 5052 6.47 26 ,r-'" 3 C C22 diasterane J 0 0.00 <1 /..,' 4 D C22 abb sterane 33.86 1651 2.12 9 5 E C27 ba diasterane (208) 48.51 4657 5.97 24 I] 6 F C27 ba diasterane (20R) 50.06 3373 4.32. 18 7 G C27 ab diasterane (208) 0 0.00 <1 8 H C27 ab dlasterane (20R) , 0 0.00 <1 r.... 9 I C28 ba diasterane (208) 52.29 5534 7.09 29 10 J C28 ba diasterane (20R) 54.03 2876 3.68 15 ~ L" 11 K C28 ab diasterane (208) 0 0.00 <1 12 L C27 aaa sterane (208) 55.22 2365 3.03 12 r 13 M C27 abb ster-(20R)+C29 ba dia-(208) i..~ 55.78 8460 10.84 44 14 N C27 abb sterane (208) 56.11 4792 6.14 25 15 0 C28 ab diasterane (20R) 0 0.00 <1 r- 16 p C2i aaa sterane (20R) 57.00 2951 3.78 15 17 Q C29 ba diasterane (20R) 57.63 7475 9.58 39 .., 18 R C29 ab diasterane (208) 0 0.00 <1 19 5 C28 aaa sterane (208) 59.30 2295 2.94 12 [..I 20 T C29 ab diasterane (20R) 0 0.00 <1 21 U C28 abb sterane (20R) 60.03 2565 3.29 13 22 V C28 abb sterane (205) 60.43 4212 5.40 22 L 23 W C28 aaa sterane (20R) 61.50 2317 2.97 12 24 X C29 aaa sterane (205) 62.80 3306 4.24 17 25 Y C29 abb sterane (20R) 63.62 5296 6.79 28 n 26 Z C29 abb sterane (208) 63.95 4258 5.46 22 27 a C29 aaa sterane (20R) 65.37 4617 5.92 24 28 b C30 aaa sterane (208) 0 0.00 <1 29 c C30 abb sterane (20R) 0 0.00 <1 II 30 d C30 abb sterane (208) 0 0.00 <1 31 e C30 aaa sterane (20R) 0 0.00 <1 LI f ¡ i 1 t, . , 1 i ,: i L J :¡ , ,¡ ¡ LJ ~___.--J ,..-..~...... ~ ~ ~ ~ c::::J ~ ~ ,.............. ~ ~ c:::J ~ ! - - 1 --......, ~ ~ ~~~ ~ ~ i....-.-..; ~ ~ io....o--.-i ~ "----' ---..l --...J ~ --.J ---.J ,.. .-. -- - ._~ -t '-'-- .---.,- ,....,......~_.- 3500 ~. m/z = 217 North Aleutian Cost 1 MMSAK2003-2 15700 - 16800 Ft. 03/529 - MM000002 3000 - 2500 - 2000 - 1500 - 1000 - M N Q p ^ L J X J s 500-~JAJu ~~~~\Ø''v>J,it\~~\lh ilJ J)Mv WW~ B E F v Yz a o 2Jj I I , ,3IJ _ I I , I 3£ I I I I ~D. I . . ~õ I I I I 50 I . -. I SS I . . . GO I , . . C5. . I I 7D 1 I .1 T ì ,¡ ¡ LJ 70 65 60 55 50 o f' ! ~ L ::: ~vk ~ )J( ~ W At \'w JWw 100 - 400 - [I LI 500 - \ r L" 600 - 700 - mIz = 259 [ I , r'" ~ " L, 400 - 200-..JUv~ A l^,^~, viM ,,' ~ ~ o I I 'I I 1 , I I Ia.... r'" 600 - ~ r ,..~ r"o 800 - ¡-"J î L 1 000 - '-,..I 1200 - mIz = 218 ''''1 "..... , I' 100 - o L I ~ f\~J\ \J1~VVt\1iNV Ww~ 03/529 - MM000002 North Aleutian Cost 1 MMSAK2003·2 15700· 16800 Ft. 1000 - m/z = 217 900 - 800 - 700 - 600 - 500 - 400 - 300 - ~ 200-~~' 1/1,.;1 \ ....... , 1.:. j ....~ , J ,-. i: ~., !r r l. r t. r pr.c..' ~;-'~-.;"'1 f"' --..-....""< ~~-~ .....~~ ~ ~-~ ~ [-'- t ~ -----..i ~ W--,j ,.......-""", ~ ..=-~ ~ -=- f , ---... -""' ~ C28 Steranes Â. _'c :, ,W Ii::' ,c," '~: c;~ .'~' '-" ItE-;,t~c,:i~~~,~'~:' ¡a IC;I~~):~ ~.~:' ~':"~'c'< ~ /;';,<~~r~(~_~;~;'-~~:;~ :c-,:, :e,] c~~,~~~ii: ~,':e-~~iif.'t~"~,::'i~("~~~ ~,~~ cc,~~ c'_:,:_ "'",:"~:--ë:--:.t~ ~r;-_, ,;~:, +F~~::;'¡~)~;'c't-:'",-~ .. '-:"'è, ,~' '-:: ,~ J~-~~ i~;'?}' :~,,;f£:~ :,I,::; '~~~, [: ,: >~:;'~", ~~ :,~ ~:,,_, ' "':-, ;..;-:,,-~ [c;è' ~ r: ::..",- c:,' -, ~; :"_,': ,_c ,- , , ~c':-, ;:~ -." '':; ~:.,';: ::ic .4 :;~'~"-'- ~:-,,~ ~ ':--:.::~- ;i--""'" ;O:,","Cc J ::--' c, ,,',' ','-::,:,,- :;~, c"'- 'X:' ",;,:, ,;:':; '~-t:: ~~t -,',' ,~,',' ;; J :;-:;,,:::::- :;-"c'::: < 'c' ;~.,'- .-:::::- c:Si': ~/f,,-":;' ;:-~, ,', '~":-~' ',,, "O' "---,, .~':, ~::ç:i:,::J"',\, -x:,", ,--c.", 'c ,,' ". ,"=,-' 't:: J '~::;~ ,:~~~~ :::'~--':':"f-::~~:-0-""c--'.':::;'cj ;:-- ~~; ::;:,," ~~fl¡ii"-' --.. ,,-, , 'i ,,-,. ,-~c _:" ~. -":''--:;:; '';-3--: "'":.-:" -=-"" ~;~~ i>~'~'" ~,.:'] ',:;' r;:"",' f: ::;:c: ::~~,-::,,,è:~ 'J' "-" ,-'- ,':' ë:---:-c ¿:" :" c:¿· ;~~! ITif~ :-~,'-=~' North Aleutian Cost 1 BaselineDGSI Project: 03/529 .. C27 Steranes "- ,'- ':,""- ~",,:' f:~A. ;~.g~,- _ _'_ ?'~;';':~2:.' .~ ,.; , , := ,"'" ~. ..4[,'0 ~- ~i~;" :~c" L.~:~('f5(U,-: 0;""' L~"~J}'JC: I,c~, L-i.::){:. ,'-Co'"", ""~:': .,~?< -C::z. , /",.'0-',":"""':;:'" . ~::-'C"-;'.~: 'c:;::' ,oC", '" .,;,:-c:- .~ , 'à~:;c,~~i" ';~ '..~ ,;~':t:-~', C=:~~.~:"¿ _:::'.<'l;-"~ :,'i ::': '.(':,):-.:c:'-:';:, ,y:,,'l:" "'-.' , ,;~-.,. o'oi:=,'~ '::;::::,',-' ,c:, '-,', "<,__c-' :~~ '~~.:' ,c,-'-'':¡::,,~. ~:,.f C,'" -"':""~ ,,-~:';::' .~' _.;-':';:~', '_c', ., :2.'-' :':C ,c'; :; ~îl'" ~~ iJ ~ ......- .-=: ." .c -", '~c ~I~'_ },~~§,~.~, :1:'':.:-: ,?~ ':'c ,', =-~ ,;- '? ,,,. '~,' ~' .'--' .~:..::-i :c, ,~,~ ,~"'- , - , '::'C''': /'C'::'=,~,-~-: " Œ.' _. ¡i~l:, ~,;:u. -- FIGURE 9 - Distribution of C27 -C29 regular steranes from gc-ms data. :::::J o? ,';',;-'-.:;:.:-"."" J1i~ ~, ~:. " > ~:j. j~ ~ ---.J ---: - ~ ---' ~ ~\. ~ë ,~. :, :~ 0~.. ¡-',-, :,. ::X( ,::~ <' ,",' .. :,: j~~,~,,~)~-~j~ ..',' :, '... C29 Steranes ~4- -...... ~-4 ~ Isotope DataFrom: Bob Olson [BOlson@baselinedgsi.com] Sent: Wednesday, November 05, 2003 10:49 AM To: Sherwood, Kirk Subject: RE: Isotope Data--Confirming Receipt Kirk The weights are correctly reported. The samples sent were very large so we did not pulverize and split all of each sample. Furthermore, one is composed of chips taken from conventional cores between 16006.0 and 16029 and between 16701.2 and 16720 ft (approximately a 42 ft interval). In contrast, the second sample is a composite of cuttings between 15700 and 16800 (an 1100 ft interval) . These are not the same samples. I would expect some differences due to the differences in sample type, sampling process (core chips might be focused on concentrations of stain, fractures...) and due to sample 'not being homogeneous. Although the difference in amount of extract may be unexpected I believe it to be real. Regarding the differences in extract weight between the Soxhlet report and the starting weight in the MPLC report for sample #1 (core chips), we had such a small quantity of bitumen remaining after precipitation of asphaltenes that we had to extracted additional material in order to have enough bitumen, for the MPLC separation. Reported in the Soxhlet table are the quantities originally extracted. We did not quantify the additional extractions- only the amount of bitumen used in the MPLC/de-asphaltening process. Regarding the total of the Sat + Aro + NSO + Asph. not equaling the total weight put on the column in the MPLC report. We are never able to account for all of the sample. Some material is not eluted from the column and some material may be lost during evaporation of solvents. Allocation of that lost material is always difficult. I would be cautions about simply calling it NSOs and instead refer to it as 'Material Unaccounted for by this Process'. -----Original Message----- From: Kirk.Sherwood@mms.gov [mailto:Kirk.Sherwood@mms.gov] Sent: Wednesday, November 05, 2003 1:00 PM To: Bob Olson Subject: RE: Isotope Data--Confirming Receipt Thanks Bob. I looked at the MPLC data and' the two samples are very different-surprisingly so considering that they come from the same interval. Can you double-check the quantities to make sure that they are reported correctly? For sample MMSAK2003-1 the Soxhlet report lists a net extract weight of 0.0347 g. On the MPLC report the sample weight is reported as 0.4832, which seems to be inconsistent. For sample MMSAK2003-1 the net extract weight (Soxhlet) and the sample weight (MPLC) are both given as 0.0609 g, which seems consistent and correct. In the Soxhlet report, the sum of SAT+ARO+NSO+ASPH is less than the sample weight. Any thoughts about what is not accounted for? Resin? Kirk W. Sherwood, Geologist Minerals Management Service 949 E. 36th Ave., Veco Bldg., Suite 300 Anchorage, AK 99508-4362 Ph: 907-271-6085 Fx: 907-271-6565 e-mail: kirk.sherwood@mrns.gov MINERALS MANAGEMENT SERVICE Alaska Outer Continental Shelf Region 949 East 36th Avenue, Suite 300 Anchorage, Alaska 99508-4363 United States Department of the Interior 03 September 2003 Attn: Dr. Bob Olson Baseline DOSI 8701 New Trails Drive The Woodlands, TX 77381-4241 Tel: 281-681-2200 Re: Extraction and BiomarkerlIsotope Analyses, North Aleutian Basin COST 1 Well Dear Bob, I have separately forwarded via FEDEX two samples from the captioned well for extraction and biomarker and isotope analysis. A detailed list of the desired analyses', as per previous e-mail dialog between us, is attached. A copy of this letter will also accompany the samples. Sample MMSAK2003-1 is a composite of 47 conventional core samples from cores 18 and 19 and representing the intervals 16,006.0 to 16,029.0 feet and 16,701.2 to 16,720.0 feet (bkb). The composite sample weighs lib 14 oz. The only possible contaminant noted was some clear, amber-colored epoxy or plastic that coated the core slabs, I presume that the coating was applied to help keep core slabs together during handling. We tried to keep this material out of our composite, but some may have crept in anyway. Some of these core materials were extracted in previous studies and gas chromatograms of C15+ saturate fraction hydrocarbons were obtained by Robertson Research. Copies of these analyses are attached for your information. Sample MMSAK2003-2 is a composite of cuttings from 109 well cuttings samples representing 10-foot intervals from 15,700 to 16,800 feet (bkb), capturing a zone associated with high (>800/0) wetness ratios ([C2+C3+C4]1[C1+C2+C3+C4]) in headspace gas from canned cuttings samples. A copy of the headspace wetness ratios is attached. The composite sample weighs 3 lbs. These cuttings were delivered here as unwashed "wet" cuts that were subsequently dried at room temperatures by simply leaving the bags open. Regarding contaminants, in section 2.2 of their geochemical report for this well, EXLOG notes that: "Inorganic contaminants encountered in this well consisted'of cement, iron filings, aluminum filings, and mica. Organic contaminants included lubra beads, rubber, paint, wood, pipe dope, rope fibers, and walnut shells. These contaminants generally were easily removed and therefore did not hinder geochemical analysis." 2 These are public samples archived by the State of Alaska and they have granted us permission to carry out these destructive analyses contingent upon returning any unused and residual materials and submission of a copy of the data. Therefore, I ask that you please return any unused and/or residual materials to me at the address given at the letterhead. Unused materials might be, useful for future extractions and comparative studies by other parties. The 1\1MS contact for financial matters related to this work is Dr. Pulak Ray, Chief Geologist, Minerals Management Service, Resource Evaluation, 381 Elden Street, Herndon, VA, 20170- 4842, (Ph: 703-787-1511; e-mail pulak.ray@mms.gov)., Other questions should be referred to me at kirk.sherwood@mms.gov or by phone at 907-271-6085. Thanks! Kirk W. Sherwood 2 -----Original Message----- From: Bob Olson [mailto:BOlson@baselinedgsi.com] Sent: Monday, November 03, 2003 1:32 PM To: Sherwood, Kirk Subject: RE: Isotope Data--Confirming Receipt Kirk The zip file that I sent you contains a folder 'Minerals Management Service_092603' Within that folder are the following folders: GCMS_SAT folder REPORTS folder CD. KEY peakview.exe within the Reports folder are the Sat fraction GCMS reports. Their main function is to provide you with a tabulation of the identified peak areas and peak quantification along with some commonly used ratios. peakview.exe is a utility program that allows you to view and manipulate the GCMS ion chromatograms. More in a moment- CD.key is a security key that allows you to use Peakview. GCMS_SAT folder contains the GCMS raw data files that peakView reads. To view, enlarge or print an ion chromatogram (i.e. m/z191 or m/z217) do the following: 1) Open the GCMS SAT folder 2) Open either M2031201.d (sample MMSAK2003-2) or M2031232.d (sample MMSAK2003-1) 3) Double click on the DATA.MS file peakview should launch and the total ion chromatogram should be displayed. To view a specific ion chromatogram: 1) Click on the ION button on the Peakview tool bar Choose the ion(s) of interest by highlighting each on the list. To highlight more than 1 hold down the Ctrl button on the keyboard. 2) Click ok The ion chromatograms should be displayed. You can now enlarge, turn on or off retention times, annotation... Sorry that I did not explain all of this to you earlier- I assumed that you were familiar with our format but then came to realize the work we had done for you previously was before PeakView. Let me know if you have any additional problems. Let me know if you experience nay additional problems. Bob
