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Home My WebLink AboutGMC Data Report No. 209 Source rock potential and geochemical characterization (total organic carbon, rock- eval, and gas chromatogram mass spectrography of extracted organic matter) of the Tenneco Oil Company oes Y~0943-1 (Aurora No.1) well as determined from unwashed cuttings (6,960' - 14,190'). ~f ~ GEO¡- r0~;- ~Q (... ~ ~ .¿( ~ 0 ~¡ALS -- Received 18 March 1993 Total of 29 pages in report Alaska Geologic Materials Center Data Report No. 209 Q ~ n tJ ~ ~ :;:d ~ o ::+ z o N o \0 TENNECO AURORA.1 (APII551410000400) GEOCHEMICAL ANALYSIS - performed by by DGSI, Houston, July 1992 Sample Code DGSI Sample t# Sample Type Sample Depth Approx. Age roc S1 52 53 TMAX HI 01 52/53 F1 Source Potential Thermal Maturity _Y~J__~Y~~i~__~~~!__~~~l~Q__~~~~~~-~~~--~~s_~~l__~Q~_-~~--y~---~~---~~-_~~~_~~~~__~~~_ __T~~_ _ ~Y~2j)i-~_. _~!!i~! _ J~6~Q-l=rr.!~ _E~.Y~~!'tl_J~!!_ _~ª-5___0~~_ _~.Q5__ _~Z_ _ _7..?__ _L5~_ _~j§._ _º-=~7__ ~r.t..~~ __mji~~_ TA 3 92/2284-3 cuttings 14010-14190 Paleocene 1.33 0.18 0.79 0.67 448 59 50 1.18 0.19 poor, gas mature ...... - tv \0 .~ MISCELLANEOUS SAMPLES DGSI/92/2284 .. .. '.....' '. ..-c". ~ ....', ,,,,,, ". .. ~ ,::.." .., ..' .'.. ::;;...,,;.....o:'.::,,~..:..~;.:_.....~;,...'"..;..... ~,~k.~::·,~; ...... . " /:."'h ~~'" '~~ ~';~:!¿.~:~~...i..; ;,~:,^,ß~;.:'.~../,... .. LIQUID CHROMATOGRAPHY DGSI Satur.t.. Aromatics NSO Asphalt Sample Identification No. (%) (%1 (%) (%) TA1 1 38.9 22,2 22.2 16.7 TA2 2 43.9 23.0 23.0 10.2 TA3 3 45.9 24.5 21.8 7.7 .. . .. . .I.. . STABLE CARBON ISOTOPE . , Sample Identification DGSI No. Saturates 0/00 Aromatics 0/00 TA1 TA2 TA3 1 2 3 -28.3 -27.4 -28.1 -27.9 -26.6 -26,S GMC Data Report No. 209 2/29 MISCELLANEOUS SAMPLES DGSI/92/2284 ..'"~,,,,''Io''¡¡Iwo ~",,2~.,_ .... I" ...~~w_:,~..:-,..'~""'· ·......:.,..:,.·,i" ~I'~ ..".,.".'~~~l';,:~.~·.~" .':'..,,,,,,,,,,:..,,,,,,,, .". ~ ~./I"" ~ ,.·,...."....,',)....·..·.·.......et" ~......."._ ........ ~:(lf EXTRACT CALCULATIONS EXTRACT Semple Identificetion No, PPM IOC Pr /Ph Pr/C17 Ph/C18 CPI TA1 1 290 0,030 1.5 1.00 1.32 2.11 TA2 2 840 0,065 2.8 0,85 0.31 1.38 TA3 3 566 0.043 3.5 0,89 0.26 1,44 EXTRACT DATA SAMPLE EXTRACT No. wt. wt. TOC C17 Pr C18 Ph C28 C29 C30 1 1 2.070 0.004 0.96 182039 181334 90934 120364 35205 75064 36045 2 38.078 0.032 1.29 1354220 1154617 1318615 408915 427352 457374 235943 3 47.017 0.027 1.33 . 2179298 1946152 2083261 548860 844601 988100 527700 NORMALIZED ISOPRENOID DATA No. iC13 iC14 iC1S iC16 iC18 iC19 iC20 1 3.6 17.6 2.8 10.6 13.3 31.3 20,8 2 4.6 22.3 6.5 15.4 14.9 26,8 9.5 3 5.2 21,6 9.0 16.4 13,6 26.6 7.5 AREA DATA No. iC13 iC14 iC1S iC16 iC18 iC19 iC20 1 20865 101810 16190 61174 76892 181334 120364 2 196337 960687 280872 664805 640241 1154617 408915 3 381405 1579360 655765 1201401 991756 1946152 548860 GMC Data Report No, 209 3/29 . Extract. Q ~ n ~B4-1 ...,. ~ :;:d ~ o ~ Z I:=> N o \0 TA1 þ 15 'í 3p ,~J~.~.~. 20 ~ .,~ t ~ - N \0 &- . 30 ~ 25 20 15 ~ TA2 I - II II.JI~ 10 Ext.ract Ut - tv \0 Q ~ n Ö ~2B4-2 ~ ~ ~ o ::¡ Z o ~ o \0 1 ~ -, - 1\, ~ , I J' .' I II~ ~~~J u:r~'~;~,~~f~~~'~~~~~ 35 ." ~. TA3 0'\ - N \0 ·30 ~ 10 25 þ 15 20 --I Q s: n tJ 1284-3 Extr'Bct :;:d (1) "0 o ~ Z o -Il.> o \0 GC/MS ANALYSIS TERPANES (m/z 191) Composition and selected ratios TOTAL % COMPOSITION TA1 TA2 TA3 Tricyclic Teroanes C19-C29 11,53 20.55 18,50 C30-C36 1.06 2.82 1.24 Pentacyclic Terpane~ Hopanes 79,97 69,37 70,63 Non-Hopanes 6.38 5.23 7,75 RATIO Tricyclic Index 57.30 110.50 97,18 C 19 Tricyclic / C23 Tricyclic 0.36 0,79 0,60 C23 Tricyclic / C24 Tetracyclic 2.05 1.55 1,62 Tm / Ts 1.81 0.55 0.58 C28 Hopane / C29 Hopane 1.23 0.23 0.28 C28 Hopane / C30 Hopane 0,63 0,10 0,11 C28 Hopane !(C28 + C30 Hopanes) 0.39 0.09 0,10 C29 Hopane ! C30 Hopane 0,51 0.43 0.40 C30 Moretane ! C30 Hopane 0.18 0,14 0,13 C30 Oleanane / C30 Hopane 0.26 0.24 0.41 Gammacerane Index 5.56 4.58 0.00 225 / (225 + 22R) C31 Hopane (%) 41.67 43,61 43.98 22S / (225 + 22R) C32 Hopane (%) 50.64 59.66 60,97 C35 / C34 Extended Hopanes 1.42 0.64 0.61 Tricyclic /17aH - Hopane Ratio 0.05 0.06 0,07 C35-Homohopane Index (%) 10.36 5.35 5.09 GMC Data Report No. 209 7/29 GC/MS ANALYSIS STERANES (m/z 217) Composition and selected ratios TOTAL o~ COMPOSITION TA' TA2 TA3 Reaular steranes C27 20,00 22,69 26,26 C28 21.45 12.68 8,58 C29 32.71 26.29 18,88 Total 74.16 61.66 53,72 Rearranoed (diasteranes¡ C27 11,76 11,59 14.25 C28 6.10 8.31 12.22 C29 7.98 18,44 19,80 Total 25,84 38,34 46,28 NORMALIZED PERCENTAGE C27 aaa (20R) 21.93 16,78 21.11 C28 aaa (20R) 33.01 36,13 28.25 C29 aaa (20R) 45,06 47,09 50,64 NORMALIZED PERCENTAGE C27 aaa (20R + 20S) 25.88 16.65 21.34 C28 aaa (20R + 205) 29,98 27.22 22,71 C29 aaa (20R + 205) 44.15 56,13 55,95 RA TJO Diasterane Index . 43.47 203.47 266,49 Diasteranes I regular steranes 0.35 0.62 0.86 C27 aaa (20R) I C29 aaa (20R) 0,49 0.36 0,42 C29 aaa (20S) I C29 aaa (20R) 0,15 1.06 1.53 C29 abb (20R) I C29 aaa (20R) 0.17 1.00 1.36 205 I (20S + 20R) C29 aàa sterane (%) 13.16 51,38 60.54 abb I (aaa + abb) C29 sterane (%) 31.29 49,17 51,22 abb ! (aaa + abb) C27 sterane (%) 34.12 82,54 86,63 Hopanes! 5teranes ( TT I ST ) 1.14 2.36 3.02 (Steranes + Diasteranes)! C27-C30 hopanes 1.45 0,77 0.60 GMC Data Report No. 209 8/29 TERPANES (m/z= 191) TA1 Peak ID, Compound Name CarbonI Ret Time Area Area % 1 A C19-Tricyclic Terpane 19 25.382 157581 0,79 2 8 C20-Tricyclic Terpane 20 29.869 210043 1.05 3 C C21-Tricyclic Terpane 21 34.568 205796 1.03 4 D C22-Tricyclic Terpane 22 39.138 73528 0.37 5 E C23-Tricyclic Terpane 23 44.577 434088 2,17 6 F C24- Tricyclic Terpane 24 47,653 261568 1,31 7 G C25-Tricyclic Terpane #1 25 53.763 119509 0.60 8 G C25-Tricyclic Terpane #2 25 53,943 128891 0,64 9 H C24- T etracyclic T erpane 24 57.746 212159 1.06 10 I C26-Tricyclic Terpane #1 26 58.276 105360 0,53 11 I C26-Tricyclic Terpane #2 26 58.692 86414 0,43 12 J C28-Tricyclic Terpane #1 28 68,42 138295 0.69 13 J C28-Tricyclic Terpane #2 28 69,143 119594 0.60 14 K C29-Tricyclic Terpane #1 29 71.35 115237 0.58 15 K C29-Tricyclic Terpane #2 29 72.203 152464 0,76 16 L 18aH-Trisnorhopane (Ts) 27 74.261 361740 1.81 17 M 17aH-Trisnorhopane (Tm) 27 76.092 654502 3.27 18 N C30-Tr.icyclic Terpane #1 30 0 0.00 19 N C30-Tricyclic Terpane #2 30 0 0.00 20 Q 17aH, 18aH,21 bH-8isnorhopane 28 80.353 2526810 12,62 21 p C31-Tricyclic Terpane #1 31 0 0,00 22 P C31- Tricyclic Terpane #2 31 0 0.00 23 Q 17aH,21 bH-Norhopane 29 82.528 2059840 10,29 24 R 17bH,21 aH-Normoretane 29 84,634 1072183 5.36 25 5 1 8aH-Qleanane 30 85.982 1052829 5.26 26 T 1 7aH,2 1 bH-Hopane 30 86.416 4028500 20,13 27 U 17bH,21 aH-Moretane 30 88,136 738874 3.69 28 V C33-Tricyclic Terpane #1 33 0 0,00 29 V C33-Tricyclic Terpane #2 . 33 0 0.00 30 W 17aH,21 bH-Homohopane (22S) 31 91.285 897572 4.48 31 X 1 7aH,21 bH-Homohopane (22R) 31 91.91 1256471 6.28 32 y Gammacerane 30 92.489 224042 1.12 33 Z C34-Tricyclic Terpane #1 34 0 0.00 34 Z C34-Tricyclic Terpane #2 34 0 0,00 35 a 17aH,21 bH-Bishomohopane (225) 32 95.66 502984 2,51 36 b 17aH,21 bH-Bishomohopane (22R) 32 96.664 490253 2,45 37 c C3S-Tricyclic Terpane #1 35 98.811 118957 0,59 38 c C35-Tricyclic Terpane #2 35 100.517 93487 0,47 39 d 17aH,21 bH-Trishomohopane (225) 33 101.529 285627 1,43 40 e 17aH,21 bH-Trishomohopane (22R) 33 1 03. 1 61 326564 1.63 41 f C36-Tricyclic Terpane #1 36 0 0.00 42 f C36-Tricyclic Terpane #2 36 0 0.00 43 g 17aH,21 bH-Tetrahomohopane (225) 34 108.747 165246 0.83 44 h 17aH,21 bH-Tetrahomohopane (22R) 34 111 .128 166664 0.83 45 17aH,21 bH-Pentahomohopane (22S) 35 117,267 194734 0,97 46 17aH,21 bH-Pentahomohopane (22R) 35 , 20.756 278209 1.39 GMC Data Report No. 209 9/29 I 120.00 "'I ""1""1" 90.00 100.00 110.00 --- ------- de . - - -- , I ' 80.00 , , , I ' 70.00 "1""1""1""1 30.00 40.00 50.00 60.00 ._ .. __. _..__ .... _ _ h __. _. _. _..._ _ _ . _.. o Time -> ..II >AJ ~,./VI/'!' , ~,MoW. ab UW x J K L s M R Q o Ion 191.00: DG2284-1.D T """""" F 2:37 pm 2284-1 TAl ...... o - N \0 c 5000 - A B E 10000 - 15000 - 20000 - 25000 - 30000 - 35000 - 40000 - 45000 - Q ~ () tJ ~ .-+ ~ :;d ~ o ::¡ Z o N o \0 Abundance Date Acquired: 10 Jun 92 Sample Name: Mise Info: ,-, I · , , · I · , , , , ' , , , J 90.00 100.00 110.00120.00 '-'-1 80.00 """'1""1 ""1""1 30.00 40.00 50.00 60.00 70.00 - -- - . --. o Time -> - - - N '-0 .- -.-.. --- - ~,,,~\jJ.~ _ _~ 5000 ~ ~ ~'''''JÞ Ion 177.00: DG2284-1.D 2:37 pm 2284-1 TAl 10000 - 15000 - 20000 - 25000 - 30000 - 35000 - 40000 - 45000 - 50000 - C) ~ () o ~ ~ :;:d ~ o ::+ z o N o \0 Abundance Date Acquired: 10 Jun 92 Sample Name: Mise Info: STERANES (m/z = 217) TA1 Peak JD, Sterane Name Ret Time Area Area% 1 A C27 ba diasterane (205) 63,215 583986 3,09 2 B C27 ba diasterane (20R) 65,049 497936 2.64 3 C C27 ab diasterane (205) 66,429 282349 1,49 4 D C27 ab diasterane (20R) 67,474 857630 4.54 5 E C28 ba diasterane (205) 67,874 876491 4,64 6 F C28 ba diasterane (20R) 69.81 275607 1.46 7 G C27 aaa (20S) + C28 ab dia-(20S) 71.245 694214 3.67 8 H C27 abb (20R) + C29 ba dia-(20S) 71.559 981532 5.20 9 I C27 abb (20S) + C28 ab dia-(20R) 71.962 307653 1.63 10 J C27 aaa sterane (20R) 73,171 1794783 9.50 11 K C29 ba diasterane (20R) 73.689 1042164 5,52 12 L C29 ab diasterane (20S) 74,613 465416 2.46 13 M C28 aaa sterane (20S) 75.827 182525 0.97 14 N C28 abb .sterane (20R) 76.475 712321 3,77 15 0 C28 abbsterane (205) 76.849 457035 2.42 16 p C28 aaa sterane (20R) 78.308 2701078 14.30 17 Q C29 aaa sterane (205) 79.69 558700 2,96 18 R C29 abb sterane (20R) 80,433 622527 3.29 19 S C29 abb sterane (205) 80.654 1311520 6.94 20 T C29 aaa sterane (20R) 82.497 3687630 19.52 GMC Data Report No. 209 12/29 Q ~ n Date Acquired: 10 Jun 92 ~ Sample Name: ~ Misc Info: ~ ~ o ::¡ Z o N o \0 2:J7 pm 2284-1 TAl Abundance Ion 217.00: DG2284-1.D J5000 - 30000 - 25000 - 20000 - 15000 - 10000 - .A D B E F 5000 - c ~ \ ~~~J~'~ U· - w - tv \0 o -> "1""1""1""1""1" 62.00 64.00 66.00 68.00 70.00 J H K N p Q ~J - - .--. ~ -- , , I ' , , , r-"-' -r , 1 ' , , , I ' , , , r ' 72.00 74.00 76.00 78.00 80.00 -.- .-- ---_.._._----~ , , , I ' , 82.00 Time G· L 0 ~r lld,^, s R \ T ~~ r I I ' ,., 84.00 0"1 "'"1'""'1""1'""1.",,1'"'1""1""1""'"1 Time_n-> -- ._--~~ ._~t? ._.___~_~.~_!>.O__. ._~~.._~_~ _. __. .69 ..O~__. __. ...?o. 00.. _ _080.00 90 ~ ~O __~O~_.~_º 110.00 120.00 .. -- -- -... -.. - . - \ 'I.^ I JvJt.~ \. . '1\1 '~ J ~~\v~ "or-- ...... .¡:.. - N \0 ~ 5000 - 10000 - 15000 - 20000 - 25000 - 30000 - 35000 - Ion 217.00: DG2284-1.D Abundance Q ~ n t:J ~ ~ ~ ~ o ~ Z o N o \0 2:37 pm 2284-1 TAl Date Acquired: 10 Jun 92 Sample Name: Misc Info: Q ~ n Date Acquired: 10 Jun 92 ~ Sample Name: ~ Mise Info: ~ ~ o ::t. Z o 2:37 pm 2284-1 TAl Abundance Ion 218.00: DG2284-1.D ~ 18000 - \0 16000 - 14000 - 12000 - 10000 - 8000 -. 6000 - 4000 - 2000\~~~ V,-VJt"/IA. rr ~I\JA ,/1\, vJ v AJJ ~~, -- u. - N \0 o Time -> , , I ' , , , I ' , , , I ' , I I I ' I , , I I , , I I . , '~-rï-- -y--, I I I I , I I I I I I I I , , I ' I , I I ' , , 62.00 64.00 66.00 68.00 70. 9~?2. OO_?~_~_~g__-.?~_~_~~ 78.00 80.00 82.00 84.00 TERPANES (m/z= 191) TA2 Peak ID, Compound Name CarbonI Ret Time Area Area % 1 A C19-Tricyclic Terpane 19 25,713 450416 2.47 2 B C20-Tricyclic Terpane 20 30,141 690018 3.79 3 C C21-Tri~yclic Terpane 21 34.809 482421 2.65 4 D C22-Tricyclic Terpane 22 39,35 109221 0,60 5 E C23- Tricyclic Terpane 23 44,776 573636 3,15 6 F C24-Tricyclic Terpðne 24 47,854 364893 2,00 7 G C25-Tricyclic Terpane #1 25 53.948 109975 0.60 8 G C:¿5- Tricyclic Terpane #2 25 54,137 139649 0,77 9 H C24-Tetracyclic Terpane 24 57,95 368914 2.02 10 I C26-Tricyclic Terpane #1 26 58.475 130723 0.72 11 I C26-Tricyclic Terpane #2 26 58,893 104386 0,57 12 J C28-Tricyclic Terpane #1 28 68,628 196576 1.08 13 J C28-Tricyclic Terpane #2 28 69,348 136419 0,75 14 K C29-Tricy~lic Terpane #1 29 71.581 178691 0.98 15 K C29-Tricyclic Terpane #2 29 72.431 78486 0,43 16 L 1 8aH- Trisnorhopane (Ts) 27 74.477 1160619 6.37 17 M , 7aH-Trisnorhopane (Tm) 27 76.3 633989 3.48 18 N C30-Tricyclic Terpane #1 30 0 0.00 19 N C30-Tricyclic Terpane #2 30 0 0,00 20 0 17aH, 18aH,21 bH-Bisnorhopane 28 80,523 334362 1.83 21 P C31-Tricyclic Terpane #1 31 0 0,00 22 P C31-Tricyclic Terpane #2 31 0 0,00 23 Q 1 7aH,21 bH-Norhopane 29 82,718 1456583 7.99 24 R 17bH,21 aH-Normoretane 29 84.809 278502 1.53 25 S 18aH-Oleanane 30 86,04 798199 4.38 26 T 17aH,21 bH-Hopane 30 86,605 3389670 18,60 27 U 17bH,21 aH-Moretane 30 88.345 471018 2.58 28 V C33-Tricyclic Terpane #1 33 0 0.00 29 V C33-Tricyclic Terpane #2 33 0 0,00 30 W 1 7aH,21 bH-Homohopane (225) 31 91.532 1002656 5,50 31 X 17aH,21 bH-Homohopane (22R) 31 92.156 1296255 7,11 32 y Gammacerane 30 92.736 155115 0.85 33 Z C34-Tricyclic Terpane #1 34 0 0.00 34 Z C34-Tricyclic Terpane #2 34 0 0,00 35 a 17aH,21 bH-Bishomohopane (225) 32 95.936 688802 3,78 36 b 17aH,21 bH-Bishomohopane (22R) 32 96.931 465743 2.56 37 c C35-Tricyciic Terpane #1 35 99.1 i 3 141711 0,78 38 c C35-Tricyclic Terpane #2 35 100,806 83133 0.46 39 d 17aH,21 bH-Trishomohopane (225) 33 101,827 461524 2.53 40 e 1 7aH,21 bH-Trishomohopane (22R) 33 103,462 330739 1.81 41 f C36-Tricyclic Terpane #1 36 105,268 120885 0,66 42 f C36-Tricyclic Terpane #2 36 107.379 168161 0.92 43 g 1 7aH,2 1 bH-Tetrahomohopane (22S) 34 109.07 237974 1,31 44 h 1 7aH,21 bH-Tetrahomohopane (22R) 34 111.464 172100 0.94 45 17aH,21 bH-Pentahomohopane (22S) 35 1 1 7,644 155752 0.85 46 1 7aH,2 1 bH-Pentahomohopane (22R) 35 121.145 107536 0.59 GMC Data Report No. 209 16/~9 Q ~ n tJ ~ ~ :;0 ~ o ::4 Z o Date Acquired: Sample Name: Mise Info: B Jun 92 3:11 pm 2284-2 TA2 Abundance Ion 191.00: DG2284-2.D T ~ 35000 - \0 30000 - 25000 - 20000 - L 15000 - A B M 10000 - E c K Q x w s a 5000~\ (~J~ ./ ~ F G H: ~ -M.Jl~~~1 R , ~~~~~W - -.1 - N \0 o 'I I ' , , , I ' , , I I ' I , I , ' , , 'I--r-"'--'--'--r---'--' 'I'im~.__~~_ _...._.__30. ..0~.___.__~Q~.c.>_~_~~_q_~_9.Q __~~._~<?_º__..___~º. .00 80.00 b U d ~ , , ¡ 1 ~,!\.,,~ve 'I I"" I" 90.00 100.00 ---- ---.---- , , I ' , 110.00 , , I 120.00 Q ~ n tj ~ ~ ~ ~ (t) "0 o ~ Z o tv o \0 14000 :. Date Acquired: Sample Name: Mise Info: Abundance 15000 :. 13000 .:. 12000 :. 11000 -j -u 10000 :. 9000 ~ : I 8000 :. 7000 :. 6000 .:. 5000 ~ 4000 :. 3000 :. 2000 :. 1000 :. ...... 00 - N \0 o Time -> """-...---- 8 Jun 92 ~I ,~ ~ I ~WA . . I · 30.00 . I · 40.00 3:11 pm 2284-2 TA2 Ion 177.00: DG2284-2.D ~I ~ d~~ 1\·~Å~~~~r 1 I 1 50.00 1 I 1 1 1 1 I 1 60.00 70.00 I ¡ q ~ I, l, -"" " . 1 I I I" I 1 I'... I" I 8 0 . 0 0 9 0 . 0 0 1 0 0 . 0 0 110. 00 120 . 00 STERANES (m/z = 217) TA2 Peak ID, 5terane Name Ret Time Area Area % 1 A C27 ba diasterane (20S) 63,414 468159 5.38 2 8 C27 ba diasterane (20R) 65,252 233304 2.68 3 C C27 abdiasterane (20S) 66.631 176497 2,03 4 D C27 ab diasterane (20R) 67,596 129828 1.49 5 E C28 ba diasterane (205) 68.086 520247 5,98 6 F C28 ba diasterane (20R) 70,017 202938 2.33 7 G C27 aaa (205) + C28 ab dia-(20S) 71.394 143298 1.65 8 H C27 abb (20R) + C29 ba dia-(20S) 71. 774 1472923 1 6.93 9 I C27 abb (205) + C28 ab dia·(20R) 72.173 156359 1.80 10 J C27 aaa sterane (20R) 73.37 201449 2.32 11 K C29 ba diasterane (20R) 73.9 1206718 13,87 12 L C29 ab diasterane (205) 74,81 5 397494 4,57 13 M C28 aaa sterane (205) 76.043 130076 1.50 14 N C28 abb sterane (20R) 76.691 229871 2,64 15 0 C28 abb sterane (205) 77.061 309126 3,55 16 P C28 aaa sterane (20R) 78,483 433656 4,99 17 Q C29 aaa sterane (205) 79,854 597229 6,87 18 R. C29 abb sterane (20R) 80,652 562567 6.47 19 S C29 abb sterane (205) 80,883 561844 6,46 20 T C29 aaa sterane (20R) 82,648 565204 6.50 GMC Data Report No, 209 19/29 o ~ (') tJ ~ ..... ~ :;:d (1) Þö o :4 Z o -N o \0 N o - tv \0 Date Acquired: Sample Name: Mise Info: 8 Jun 92 J:11 pm 2284-2 TA2 Abundance 16000 :. 15000 :. 14000 ~ 13000 ~ 12 000 ~ 11000 ~ 10000 ~ 9000 ~ 8000 :. A 7000 :.. 6000 ~ 5000 :. 4000 :. 3000 :. Ion 217.00: DG2284-2.D H K T RS L E Q o B p I J N F G c D M v\\ Jß 1^ ~\A~ ""V\,. \~ \,,\\rJ 2000~~ ~\Wvv 1000 . 1 ,-, ' , 1 I. , 1 1 , 1 , ' 1 , , , ' , , , , ' , 1 , , ' , T im~_~~o 6_4~~0_ ~-~Q~~.~_c?º____?..Q..~_~.9.___? ~_~ 00 , , , ' 1 74.00 "" ',"",",.". 76.00. _". _78.~_0º_~0~~~!~~ 00 . . , . . . 84.00 Q ~ d ~ ~ ';d ~ o ~ Z o oate ACquired: sa1t\ple Na1t\e: Misc Info: ß Jun 92 3:11 pm 2284-2 TA2 bundance ~ 16000 .:. 15000 .:. 1.4000 .:. 13000 .:. 1.2000 .:. 11000 .:. 1.0000 .:. 9000 .:. 8000 :.. 1000 .:. 6000 ~. 5000 .:.. 4000~ \ 3000 ~~~~. :. ' 2000 ~: ~~,hk ~. 1000 .:. t---> I"'"""' t6 Ion 2~'00: OG2284-2.O I , - I Þ~' \ \ I ~ k \ :, L \ \ ,~ \ " h'~ \ ~ 90.00 1.00. 00 ----- - ------~ 11.0.00 1.20.00 0- Î ):!,~~~~~~.<0>_o.__~Q~~Q--~_<!~_O()-- 80. 00 , , J ' , , 84.00 o ,"1""1""1""1""1""1""1""1""1""1""1' ~~~e.._~~. ____.62 .~.OO ____~~.~~_.~___ ~.~.~_º.º-__~~_~_~_2____?0 ~_.0~____.J2_~.~_0 ___? 4 ~_OO 76 ~_oo. _ 7~. ~O 80.00 82.00 N N - N \0 .vvJ '0 ~ \. 1\,/ J' jl.f\Ah . l ¡ V'^I' ¡.JJJ \ V ^~\ · ¡if .~ Ion 218.00: DG2284-2.D 3:11 pm 2284-2 TA2 8 Jun 92 1000 :.~ 500 .:. 2000 ..: 1500 ..: 2500 .:. 3500 ~ 3000 ..: 4000 ~ 5500 :. 5000 ~ 4 500 ~ 6000 ..: 6500 ~ 7000 ..: 8000 ..: 7500 ..: Q a:: n tJ ~ ~ :;:d ~ o ~ Z o N o \0 Abundance Date Acquired: Sample Name: Misc Info: TERPANES (m/z= 191) TA3 Peak ID. Compound Name Carbon # Rat Time Area Area % 1 A C1 9-Tricyclic Terpane 19 25,747 408369 1.84 2 B C20-Tricyclic Terpane 20 29,862 580074 2.62 3 C C21 -Tricyclic Terpane 21 34.828 478422 2.16 4 D C22-Tricyclic Terpane 22 39,382 138367 0.62 5 E C23-Tricyclic Terpana 23 44,819 675175 3.04 6 F C24- Tricyclic Terpane 24 47.908 471357 2,13 7 G C25-Tricyclic Terpane #1 25 53.995 142353 0.64 8 G C25-Tricyclic Terpane #2 25 54,183 134842 0,61 9 H C24- Tetracyclic Terpane 24 57,998 417799 1,88 10 I C26-Tricyclic Terpane #1 26 58,522 163917 0.74 11 I C26-Tricyclic Terpane #2 26 58,933 131290 0.59 12 J C28-Tricyclic Terpane #1 28 68,683 224335 1,01 13 J C28-Tricyclic Terpane #2 28 69,382 141701 0.64 14 K C29-Tricyclic Terpane #1 29 71,635 249415 1.12 15 K C29-Tricyclic Terpane #2 29 72.471 163284 0,74 16 L 18aH-Trisnorhopane (Ts) 27 74.525 1463862 6.60 17 M 17aH-Trisnorhopane (Tm) 27 76,159 848087 3,82 18 N C30-Tricyclic Terpane #1 30 ° 0.00 19 N C30-Tricyclic Terpane #2 30 0 0,00 20 0 17aH,18aH,21 bH-Bisnorhopane 28 80,558 475293 2.14 21 P C31-Tricyclic Terpane #1 31 ° 0,00 22 P C31-Tricyclic Terpane #2 31 0 0.00 23 Q 17aH,21 bH-Norhopane 29 82,74 1686306 7.60 24 R 17bH,21 aH-Normoretane 29 84.833 329620 1.49 25 5 18aH-Oleanane 30 86,064 1718646 7.75 26 T 17aH,21 bH-Hopane 30 86.627 4222131 19,04 27 U 17bH,21 aH-Moretane 30 88.36 534144 2.41 28 V C33-Tricyclic Terpane #1 33 ° 0,00 29 V C33-Tricyclic Terpane #2 33 0 0.00 30 W 17aH,21 bH-Homohopane (225) 31 91.546 1260832 5.69 31 X 17aH,21 bH-Homohopane (22R) 31 92.17 1606177 7.24 32 y Gammacerane 30 ° 0.00 33 Z C34-Tricyclic Terpane #1 34 0 0.00 34 Z C34-Tricyclic Terpane #2 34 0 0.00 35 a 17aH,21 bH-Bishomohopane (22S) 32 95.944 877189 3.96 36 b 17aH,21 bH-Bishomohopane (22R) 32 96,937 561444 2.53 37 c C35-Tricyclic Terpane #1 35 99.118 166264 0.75 38 c C35-Tricyclic Terpane #2 35 , 00,81 2 108336 0.49 39 d , 7aH,21 bH-Trishomohopane (22S) 33 , 0' .83 587809 2.65 40 e , 7aH,21 bH-Trishomohopane (22R) 33 , 03.469 391965 1.77 41 f C36-Tricyclic Terpane #1 36 0 0.00 42 f C36-Tricyclic Terpane #2 36 0 0.00 43 g 17aH,21 bH-Tetrahomohopane (225) 34 109.07 314574 1.42 44 h 17aH,2' bH-Tetrahomohopane (22R) 34 , , 1 ,45 191364 0.86 45 17aH,21 bH-Pentahomohopane (225) 35 117.608 186022 0.84 46 17aH,2' bH-Pentahomohopane (22R) 35 121.11 124469 0.56 GMC Data Report N,o. 209 23/29 C) ~ n tJ ~ -- ~ :;:d ~ o ::¡ Z o N o \0 Date Acquired: Sample Name: Mise Info: 9 Jun 92 11:07 am 2284-3 TA3 Abundance Ion 191.00: DG2284-3.D T 45000 - 40000 - 35000 - 30000 - 25000 - Q L 20000 - s x 15000 - A M w B E c K a o 10000 - F R U _ H JIb 5000~\..IW~~L G: jj1tJ'4~-~)I,~PJ . vJ...""""'......L~ ' M..^--oJ~~ ~ 0 Ñ Time-> \0 d e "I "~'I I ""I' 30.00 40.00 50.00 , I ' , , , I ' , r-"--r--r-' , , I ' , , , I ' , , , I " I 60.00 70.00 80.00 90.00 100.00 110.00 120.00 _._._. __J I 120.00 , , , , , 110.00 JI<- , I I I , 100.00 --------- ---.- -------- , , -" --..------------ o Time -> , J I' I' "II'", 70.00 80.00 90.00 ~. \ ~, t '. I I I I I I I I I 30.00 40.00 I I I I I 60.00 , , I 50.00 , I 'I ~ \ þ J..v..I {. '.b I ~.A r T"~ W" \I ~ ~'~I~ 1'JiNJ''{'. , Ion 177.00: DG2284-3.D 9 Jun 92 11:07 am 2284-3 TA3 - ----.. . ----. N VI - tv \0 14 000 ~ 13000 .:. 12000 .:. 11000 ~ 10000 ~ 9000 ~~- 8000 -: ) 7000 .:. 6000 .:. 5000 :.. 4000 ~ 3000 ..: 2000 ..: 1000 -: C') ~ ~ Date Acquired: ~ Sample Name: S Mise Info: þd ~ o ~ Z o N o \0 Abundance STERANES (m/z = 21 7t TA3 Peak ID. Sterane Name Ret Time Area Area % 1 A C27 ba diasterane (205) 63,463 554245 5.74 2 8 C27 ba diasterane (20R) 65,301 349024 3,62 3 C C27 ab diasterane (20S) 66,686 254904 2.64 4 D C27 ab diasterane (20R) 67,636 217157 2.25 5 E C28 ba c.Jiasterane (205) 68,13 932107 9.66 6 F C28 ba diasterane (20R) 70.054 247728 2,57 7 G C27 aaa (205) + C28 ab dia-(20S) 71,437 192717 2,00 8 H C27 abb (20R) + C29 ba dia-(20S) 71,826 1826287 18,92 9 I C27 abb (205) + C28 ab dia-(20R) 72,209 369222 3.83 10 J C27 aaa sterane (20R) 73,409 146239 1,52 11 K C29 ba diasterane (20R) 73.943 1332036 13,80 12 L C29 ab diasterane (20S) 74.861 579387 6.00 13 M C28 aaa sterane (20S) 76.093 165180 1. 71 14 N C28 abb sterane (20R) 76,734 176720 1,83 15 0 C28 abb sterane (205) 77.098 290761 3,01 16 P C28 aaa sterane (20R) 78.542 195661 2,03 17 Q C29 aaa sterane (205) 79.885 538162 5.58 18 R C29 abb sterane (20R) 80,673 478387 4.96 19 S C29 abb sterane (205) 80.924 454797 4.71 20 T C29 aaa sterane (20R) 82.664 350724 3,63 GMC Data Report No. 209 26/29 """'1'" 82.00 84.00 ~~ T -__..___ _0____. _____ ___ __ __....__.. _ . _ _____ ------- -----.. tv -.l - N \0 ··1····1····1····1····1····1····1····1·· 66.00 68.00 70.00 72.00 74.00 76.00 78.00 80.00 ~\¡ J p Q R S j\\jJ\ M N o L o .i. . 1 . . . . I . . rime -> 62.00 64.00 F' c D1 G I JJJvv~i } f1J~ \J B E K Ion 217.00: DG2284-3.D H 11:07 am 2284-3 TA3 9 Jun 92 2000 ~Á 4000 - 6000 - 8000 - A 10000 - 12000 - 14000 - 16000 - 18000 - Q ~ n tJ ~ ~ :;:d ~ o ::¡ Z o N o \0 Abundance . Date Acquired: Sample Name: Misc Info: Q ~ n ,t:j ~ ~ ,c (t) '"0 o ::+ z o tv o \0 Date Acquired: Sample Name: Misc Info: 9 Jun 92 11:07 am 2284-3 TA3 Abundance Ion 217.00: DG2284-J.D 18000 - 16000 - 14000 - 12000 - 10000 - 8000 - 6000 - 4000 -~ . , I \ ~ 2000- \~~\lWJ~.~~\}/~ ~ \. W..~ tv 00 N \0 o Time -> , , I ' 30.00 , I ' , 50.00 , , I .--.-, I I ,-·r -,-r--r--1-'-" , I ' , 60.00 70.00 BO.OO 90.00 , , , I ' 40.00 , , _._---- ----.---- ------.--- . .. - -.---- I ' , 100.00 I ' , 110.00 , I I 120.00 Q 3:: n t:1 ~ ~ þd ~ o ::+ z o Date Acquired: Sample Name: Misc Info: 9 Jun 92 11:07 am 2284-3 TA3 Abundance Ion 218~00: DG2284-3.D ~ 7500 :. \0 7000 :. 6500 ..: 6000 ..: 5500 .:. 5000 :, 4500 ~ 4000 ..: 3500 ~ 3000 ..: 2500 ..: 2000 ~ 1500 .:. If ft vN" JJ J \ '-\ ^ vA 1000 ..:~ 500 ~ N \0 - N \0 o Time -> , , I ' , , I I ' , , , I ' .' , · I · , · · I ' , , , I ' , , · I ~-f'-'- -'-1-' , , , I ' , · · I · , · · I ' , · , I ' , , ~~~~O___~_~~_C?_O 66~_Q.~~~.~_0__:?_C?_~C?_q__?~~_<?0 _7.4 ~.~o __ 7~.._O_O __~~ºQ_~-º. 00 82.00 84.00 #' 'V j\ fvt ~ ~ \. "\ f .J' ~^J~